Alpha Analytical Deliverable Packagenewtowncreek.info/docs2/2 Remedial Investigation/Phase 1...Alpha Analytical Deliverable Package Alpha SDG: L1215002 Client: Anchor QEA, LLC Site:

Alpha Analytical Deliverable PackageAlpha SDG: L1215002Client: Anchor QEA, LLCSite: NEWTOWN CREEK RI

The original project report/data package is held by Alpha Analytical. This report/data package is paginated and should be reproduced only in its entirety. Alpha Analytical holds no responsibility for results and/or data that are not consistent with the original.

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Sample Receipt

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Sample Delivery Group Information

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Sample Delivery Group Form

L1215002Laboratory Job number:

COURIERSamples Delivered by:

TrackingnumN/ABill Of Laden

PresentCoc Present

IntactContainer Status Samples rec'd in Westborough 08/22/12@17:20-6c (5393)

Sample IDs

YesAll Containers Accounted For?

NoWere Extra Samples Received?

YesDo Sample Labels and COC agree?

YesAre Samples in Appropriate Containers?

YesAre Samples Received within Holding time?

N/ApH of Samples upon Receipt

Initial pH Final pHpreserved in house with

N/AChlorine Check

Other Issues

NoAre VOA/VPH Vials Present?

YesAre samples Properly Preserved?

Reagent H2O Preserved vials Frozen on

N/AFrozen by Client

N/A

N/ASoils: Is MeOHCovering the Soil?

N/AAqueous: Do Vials Contain Head Space?

B

A

Absent

Absent

Yes

Yes

No

No

No

No

No

No

Cooler SealIce Present

Blue IcePresent Temp. (Celsius)

Frozenupon Receipt

Delivered Direct fromSite

3.7 - IR Gun

4.1 - IR Gun

08/21/2012 17:44

Anchor QEA, LLCClient Account:

Received:

Call Tracker #

Project Number:

Project Name:

120782-01.01

NEWTOWN CREEK RI

Received by: DIANNE JANAK

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Sample Delivery Group Form

C Absent Yes No No No5.1 - IR Gun

Project Manager: Review Date:Chris Anderson 08/31/2012

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LIMS Chain of Custody

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ALPHA ANALYTICAL LABORATORIES, INC. LOGIN CHAIN OF CUSTODY REPORT

Sep 07 2012, 10:55 am

Login Number: L1215002Account: ANCHOR Anchor QEA, LLCProject: 120782-01.01 Newtown Creek RI

Received: 21AUG12 Due Date: 18SEP12 Sample # Client ID Mat PR Collected Container ______________________________________________________________________________________________________

L1215002-01 EK002SG-000015-2012 3 S0 21AUG12 09:06 1-Amber-A.1,1-Amber-A.25,1-Amber-A.5,1-Glass-A.06 "All data to be "J" qualified to the MDL" Metals Please digest 2 grams of sample for sediments A2-DPKG-FULL Package Due Date: 09/04/12

A2-DPKG-FULL,A2-FE-6020T,A2-MN-6020T,A2-TOC-9060-2REPS,A2-TS,ADR-FEE,DISPOSAL,NH3-4500,SULFIDE-9030

L1215002-02 EK002SG-000015-2012 3 S0 21AUG12 09:06 1-Amber-A.5 "All data to be "J" qualified to the MDL" Metals Please digest 2 grams of sample for sedimentsPackage Due Date: 09/04/12

SUB-GEOTESTING

L1215002-03 EK001SG-000015-2012 3 S0 21AUG12 09:31 1-Amber-A.1,1-Amber-A.25,1-Amber-A.5,1-Glass-A.06 "All data to be "J" qualified to the MDL" Metals Please digest 2 grams of sample for sedimentsPackage Due Date: 09/04/12

A2-FE-6020T,A2-MN-6020T,A2-TOC-9060-2REPS,A2-TS,ADR-FEE,DISPOSAL,NH3-4500,SULFIDE-9030


SUB-GEOTESTING




SUB-GEOTESTING

______________________________________________________________________________________________________

Page 1

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Sep 07 2012, 10:55 am



L1215002-07 NC071SG-000015-2012 3 S0 21AUG12 10:49 1-Amber-A.1,1-Amber-A.25,1-Amber-A.5,1-Glass-A.06 "All data to be "J" qualified to the MDL" Metals Please digest 2 grams of sample for sedimentsPackage Due Date: 09/04/12


L1215002-08 NC071SG-000015-2012 3 S0 21AUG12 10:49 1-Amber-A.5 "All data to be "J" qualified to the MDL" Metals Please digest 2 grams of sample for sedimentsPackage Due Date: 09/04/12

SUB-GEOTESTING




SUB-GEOTESTING

L1215002-11 NC1059SG-000015-201 3 S0 21AUG12 11:06 1-Amber-A.1,1-Amber-A.25,1-Glass-A.06 "All data to be "J" qualified to the MDL" Metals Please digest 2 grams of sample for sedimentsPackage Due Date: 09/04/12



SUB-GEOTESTING

______________________________________________________________________________________________________

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Sep 07 2012, 10:55 am






SUB-GEOTESTING

L1215002-15 NC046SG-000015-2012 3 S0 21AUG12 11:57 1-Amber-A.1,1-Amber-A.25,1-Amber-A.5,2-Glass-A.06 "All data to be "J" qualified to the MDL" Metals Please digest 2 grams of sample for sediments QC ONTHIS SAMPLE Package Due Date: 09/04/12

A2-DUP,A2-FE-6020T,A2-MN-6020T,A2-MS,A2-TOC-9060-2REPS,A2-TS,ADR-FEE,DISPOSAL,DUP,NH3-4500,SULFIDE-9030


SUB-GEOTESTING

L1215002-17 MC006SG-000015-2012 3 S0 21AUG12 13:48 1-Amber-A.1,1-Amber-A.25,1-Amber-A.5,1-Glass-A.06 "All data to be "J" qualified to the MDL" Metals Please digest 2 grams of sample for sedimentsPackage Due Date: 09/04/12


L1215002-18 MC006SG-000015-2012 3 S0 21AUG12 13:48 1-Amber-A.5 "All data to be "J" qualified to the MDL" Metals Please digest 2 grams of sample for sedimentsPackage Due Date: 09/04/12

SUB-GEOTESTING

______________________________________________________________________________________________________

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Sep 07 2012, 10:55 am



L1215002-19 MC002SG-000012-2012 3 S0 21AUG12 14:26 1-Amber-A.1,1-Amber-A.25,1-Amber-A.5,1-Glass-A.06 "All data to be "J" qualified to the MDL" Metals Please digest 2 grams of sample for sedimentsPackage Due Date: 09/04/12


L1215002-20 MC002SG-000012-2012 3 S0 21AUG12 14:26 1-Amber-A.5 "All data to be "J" qualified to the MDL" Metals Please digest 2 grams of sample for sedimentsPackage Due Date: 09/04/12

SUB-GEOTESTING

L1215002-21 EB008SG-000015-2012 3 S0 21AUG12 15:01 1-Amber-A.1,1-Amber-A.25,1-Amber-A.5,1-Glass-A.06 "All data to be "J" qualified to the MDL" Metals Please digest 2 grams of sample for sedimentsPackage Due Date: 09/04/12


L1215002-22 EB008SG-000015-2012 3 S0 21AUG12 15:01 1-Amber-A.5 "All data to be "J" qualified to the MDL" Metals Please digest 2 grams of sample for sedimentsPackage Due Date: 09/04/12

SUB-GEOTESTING

L1215002-23 EB006SG-000015-2012 3 S0 21AUG12 15:32 1-Amber-A.1,1-Amber-A.25,1-Amber-A.5,1-Glass-A.06 "All data to be "J" qualified to the MDL" Metals Please digest 2 grams of sample for sedimentsPackage Due Date: 09/04/12


L1215002-24 EB006SG-000015-2012 3 S0 21AUG12 15:32 1-Amber-A.5 "All data to be "J" qualified to the MDL" Metals Please digest 2 grams of sample for sedimentsPackage Due Date: 09/04/12

SUB-GEOTESTING

______________________________________________________________________________________________________

Page 4

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Sep 07 2012, 10:55 am






SUB-GEOTESTING

L1215002-27 SRM1650B 3 S0 21AUG12 12:00 0- | Package Due Date: 09/04/12

A2-TOC-9060-2REPS

______________________________________________________________________________________________________

Page 5

Logged By: Chris Anderson

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Container Tracking

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ALPHA ANALYTICAL LABORATORIESContainer Tracking Report

Transaction From ToContainer ID Type Status Date Response Location Operator Response Location Operator

L1215002-01A Amber-A.1 INTACT 27-AUG-12 CUSTODY A2-METALS PREP Bruce Hutchings A2-CUSTODY-NOAA3 A2-CUSTODY-NOAA3 Bruce Hutchings

L1215002-01A Amber-A.1 INTACT 27-AUG-12 A2-CUSTODY A2-CUSTODY-NOAA3 Bruce Hutchings A2-METALS PREP A2-METALS PREP Bruce Hutchings

L1215002-01A Amber-A.1 INTACT 23-AUG-12 CUSTODY A2-WET CHEMISTRY Kathy Bates A2-CUSTODY-NOAA3 A2-CUSTODY-NOAA3 Kathy Bates

L1215002-01A Amber-A.1 INTACT 23-AUG-12 CUSTODY A2-CUSTODY-NOAA3 Kathy Bates A2-WET CHEMISTRY A2-WET CHEMISTRY Kathy Bates

L1215002-01A Amber-A.1 INTACT 22-AUG-12 CUSTODY A2-CUSTODY-REFRIDGE Dianne Janak A2-CUSTODY-NOAA3 A2-CUSTODY-NOAA3 Dianne Janak

L1215002-01A Amber-A.1 INTACT 22-AUG-12 A2-LOGIN A2-LOGIN Dianne Janak A2-CUSTODY-REFRIDGE A2-CUSTODY-REFRIDGE Dianne Janak

L1215002-01E Amber-A.25 INTACT 31-AUG-12 CUSTODY CUSTODY Richard Scott R-28 FRIDGE R-28 FRIDGE Richard Scott

L1215002-01E Amber-A.25 INTACT 29-AUG-12 WETCHEM WETCHEM John D'Apollo CUSTODY CUSTODY John D'Apollo

L1215002-01E Amber-A.25 INTACT 29-AUG-12 CUSTODY CUSTODY John D'Apollo WETCHEM WETCHEM John D'Apollo

L1215002-01E Amber-A.25 INTACT 22-AUG-12 TRANSFER - WESTBORO TRANSFER - WESTBORO Richard Scott CUSTODY CUSTODY Richard Scott

L1215002-01E Amber-A.25 INTACT 22-AUG-12 CUSTODY A2-CUSTODY-REFRIDGE Dianne Janak TRANSFER - WESTBORO TRANSFER - WESTBORO Dianne Janak

L1215002-01E Amber-A.25 INTACT 22-AUG-12 A2-LOGIN A2-LOGIN Dianne Janak A2-CUSTODY-REFRIDGE A2-CUSTODY-REFRIDGE Dianne Janak

L1215002-01F Glass-A.06 INTACT 31-AUG-12 CUSTODY CUSTODY Richard Scott R-28 FRIDGE R-28 FRIDGE Richard Scott

L1215002-01F Glass-A.06 INTACT 25-AUG-12 WETCHEM WETCHEM Marc Pollard CUSTODY CUSTODY Marc Pollard

L1215002-01F Glass-A.06 INTACT 25-AUG-12 CUSTODY CUSTODY Marc Pollard WETCHEM WETCHEM Marc Pollard

L1215002-01F Glass-A.06 INTACT 22-AUG-12 TRANSFER - WESTBORO TRANSFER - WESTBORO Richard Scott CUSTODY CUSTODY Richard Scott

L1215002-01F Glass-A.06 INTACT 22-AUG-12 CUSTODY A2-CUSTODY-REFRIDGE Dianne Janak TRANSFER - WESTBORO TRANSFER - WESTBORO Dianne Janak

L1215002-01F Glass-A.06 INTACT 22-AUG-12 A2-LOGIN A2-LOGIN Dianne Janak A2-CUSTODY-REFRIDGE A2-CUSTODY-REFRIDGE Dianne Janak

L1215002-01X Amber-A.5 INTACT 22-AUG-12 CUSTODY A2-CUSTODY-REFRIDGE Dianne Janak A2-CUSTODY-FREEZ-1 A2-CUSTODY-FREEZ-1 Dianne Janak

L1215002-01X Amber-A.5 INTACT 22-AUG-12 A2-LOGIN A2-LOGIN Dianne Janak A2-CUSTODY-REFRIDGE A2-CUSTODY-REFRIDGE Dianne Janak

L1215002-02A Amber-A.5 INTACT 24-AUG-12 CUSTODY A2-CUSTODY-REFRIDGE Dianne Janak TRANSFER - SUB TRANSFER - SUB Dianne Janak Comments: Sent to GeoTesting Express




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L1215002-15F1 Glass-A.06 INTACT 31-AUG-12 CUSTODY CUSTODY Richard Scott R-28 FRIDGE R-28 FRIDGE Richard Scott

L1215002-15F1 Glass-A.06 INTACT 25-AUG-12 WETCHEM WETCHEM Marc Pollard CUSTODY CUSTODY Marc Pollard

L1215002-15F1 Glass-A.06 INTACT 25-AUG-12 CUSTODY CUSTODY Marc Pollard WETCHEM WETCHEM Marc Pollard

L1215002-15F1 Glass-A.06 INTACT 22-AUG-12 TRANSFER - WESTBORO TRANSFER - WESTBORO Richard Scott CUSTODY CUSTODY Richard Scott

L1215002-15F1 Glass-A.06 INTACT 22-AUG-12 CUSTODY A2-CUSTODY-REFRIDGE Dianne Janak TRANSFER - WESTBORO TRANSFER - WESTBORO Dianne Janak

L1215002-15F1 Glass-A.06 INTACT 22-AUG-12 A2-LOGIN A2-LOGIN Dianne Janak A2-CUSTODY-REFRIDGE A2-CUSTODY-REFRIDGE Dianne Janak





L1215002-16D Amber-A.5 INTACT 24-AUG-12 CUSTODY A2-CUSTODY-REFRIDGE Dianne Janak TRANSFER - SUB TRANSFER - SUB Dianne Janak Comments: Sent to GeoTesting Express

L1215002-16D Amber-A.5 INTACT 22-AUG-12 A2-LOGIN A2-LOGIN Dianne Janak A2-CUSTODY-REFRIDGE A2-CUSTODY-REFRIDGE Dianne Janak












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Chain of Custody

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L 12 I~O()2.

305 W Grand Ave Suite 300, Montvale, New Jersey 07645; ph: 201.930.9690

Client: Newtown Creek Group

* "ft. AN. CH OR\I..;, OE A ::::::::::; ENVIRONMENTAL SAMPLE CHAIN OF CUSTODY

Project: Newtown Creek

COCID:

Sample Custodian:

Lab:

AAL-20120821-163510

dp

Alpha Analytical Labs

CDCCollected # LabSample Field Sample ID Matrix Containers Analytical Program ac'Number Date Time

001 EK002SG.000015.20120821 SE 08/21/2012 09:06 5 Newtown Creek Surface Sediment 0002 EK001SG.000015.20120821 SE 08/21/2012 09:31 5 Newtown Creek Surface Sediment 0003 EK010SG.000015.20120821 SE 08/21/2012 10:14 5 Newtown Creek Surface Sediment 0004 NC071SG.000015.20120821 SE 08/21/2012 10:49 5 Newtown Creek Surface Sediment 0

0 005 NC059SG-000015.20120821 SE 08/21/2012 11:06 5 Newtown Creek Surface Sediment 0'l- 006 NC1059SG.000015-20120821 SE 08/21/2012 11:06 4 Newtown Creek Surface Sediment 0y 007 NC058SG-000015-20120821 SE 08/21/2012 11:33 5 Newtown Creek Surface Sediment 0(., 008 NC046SG-000015.20120821 SE 08/21/2012 11:57 7 Newtown Creek Surface Sediment [!]If 009 MC006SG-000015.20120821 SE 08/21/2012 13:48 5 Newtown Creek Surface Sediment 0

010 MC002SG.000012-20120821 SE 08/21/2012 14:26 5 Newtown Creek Surface Sediment 0'L 011 EB008SG-000015-20120821 SE 08/21/2012 15:01 5 Newtown Creek Surface Sediment 0<f 012 EB006SG.000015-20120821 SE 08/21/2012 15:32 5 Newtown Creek Surface Sediment 0

013 EK021SG-000015.20120821 SE 08/21/2012 16:07 5 Newtown Creek Surface Sediment 0

/,2-J.r.f5Ct:J

\

7,3'1, I

II, //3. ,15.1t 7,19,20

21.2

2-~.22..S;u.

Comment:

fLet~; c ~ted:

.•.....,\'-t -.M!C'tplLd-.A'<P~'8 122hz oiJ .~fJ1

ece'ved 8 .

11'L\ 4- OatelTime ti /~

8/21'OJ~9~-~~!o?~

eceived 8 .

sig~ur. ~

't?.(,~

Page 1 of 1

Page 27 of 296

FIELD _SAMPLE_IDEB006SG-0000 15-20 121EB006SG-0000 15-20 121EB006SG-0000 15-20 12(EB006SG-000015-2012(EB006SG-000015-2012(EB006SG-000015-2012(EB008SG-000015-2012(EB008SG-000015-2012(EB008SG-0000 15-20 12(EB008SG-000015-2012(EB008SG-000015-2012(EB008SG-000015-2012(EKOO1SG-OOOO15-20 121EK001 SG-000015-2012(EK001 SG-000015-20121EK001 SG-000015-20121EK001 SG-000015-20121EK001 SG-000015-20121EK002SG-000015-2012(EK002SG-000015-2012(EK002SG-000015-2012(EK002SG-000015-2012(EK002SG-000015-2012(EK002SG-000015-2012(EK010SG-000015-2012(EK010SG-000015-2012(EK010SG-000015-2012(EK010SG-000015-2012(EK010SG-000015-2012(EK010SG-000015-2012(EK021 SG-OOOO15-20 121EK021 SG-000015-20121EK021 SG-OOOO15-20 121EK021 SG-OOOO15-20 121EK021 SG-000015-20121EK021 SG-000015-20121MC002SG-000012-2012MC002SG-000012-2012MC002SG-000012-2012MC002SG-000012-2012MC002SG-000012-2012MC002SG-000012-2012MC006SG-000015-2012

MATRIXSESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESE

SAMPLE SAMPLE_DATE _TIME TEST_REQUEST8/21/2012 15:32 Ammonia8/21/2012 15:32 Archive8/21/2012 15:32 Grainsize8/21/2012 15:32 Iron & manganese8/21/2012 15:32 Sulfide8/21/2012 15:32 TOC8/21/2012 15:01 Ammonia8/21/2012 15:01 Archive8/21/2012 15:01 Grainsize8/21/2012 15:01 Iron & manganese8/21/2012 15:01 Sulfide8/21/2012 15:01 TOC8/21/2012 9:31 Ammonia8/21/2012 9:31 Archive8/21/2012 9:31 Grainsize8/21/2012 9:31 Iron & manganese8/21/2012 9:31 Sulfide8/21/2012 9:31 TOC8/21/2012 9:06 Ammonia8/21/2012 9:06 Archive8/21/2012 9:06 Grainsize8/21/2012 9:06 Iron & manganese8/21/2012 9:06 Sulfide8/21/2012 9:06 TOC8/21/2012 10:14 Ammonia8/21/2012 10:14 Archive8/21/2012 10:14 Grainsize8/21/2012 10:14 Iron & manganese8/21/2012 10:14 Sulfide8/21/2012 10:14 TOC8/21/2012 16:07 Ammonia8/21/2012 16:07 Archive8/21/2012 16:07 Grainsize8/21/2012 16:07 Iron & manganese8/21/2012 16:07 Sulfide8/21/2012 16:07 TOC8/21/2012 14:26 Ammonia8/21/2012 14:26 Archive8/21/2012 14:26 Grainsize8/21/2012 14:26 Iron & manganese8/21/2012 14:26 Sulfide8/21/2012 14:26 TOC8/21/2012 13:48 Ammonia

METHODSM4500NH3HNAASTM 0422EPA 6010B/6020EPA 9030BEPA 9060SM4500NH3HNAASTM 0422EPA 6010B/6020EPA 9030BEPA 9060

, SM4500NH3HNAASTM 0422EPA 601OB/6020EPA 9030BEPA 9060SM4500NH3HNAASTM 0422EPA 601 OB/6020EPA 9030BEPA 9060SM4500NH3HNAASTM 0422EPA 601 OB/6020EPA 9030BEPA 9060SM4500NH3HNAASTM 0422EPA 601 OB/6020EPA 9030BEPA 9060SM4500NH3HNAASTM 0422EPA 601 OB/6020EPA 9030BEPA 9060SM4500NH3H

Page 1 of 2

TURN_A CONTAINROUND_ TAT_UN ER_COUTIME IT NT30 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0

SAMPLE_CUSTO

LAB_QC COC_ID DIANNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL -20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dp

Page 28 of 296

MATRIXSESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESE

FIELD_SAMPLE_IDMC006SG-000015-2012MC006SG-000015-2012MC006SG-000015-2012MC006SG-000015-2012MC006SG-000015-2012NC046SG-000015-2012'NC046SG-000015-2012'NC046SG-000015-2012'NC046SG-000015-2012'NC046SG-000015-2012'NC046SG-0000 15-20 12'NC058SG-000015-2012'

; NC058SG-000015-2012' ;NC058SG-000015-2012'NC058SG-000015-2012'NC058SG-000015-2012'NC058SG-000015-2012'NC059SG-0000 15-20 12'NC059SG-000015-2012'NC059SG-000015-2012'NC059SG-000015-2012'NC059SG-000015-2012'NC059SG-000015-2012'NC071 SG-000015-2012'NC071 SG-000015-2012'NC071 SG-OOOO15-20 12'NC071 SG-000015-2012'NC071 SG-000015-2012'NC071 SG-000015-2012'NC1 059SG-000015-201;NC1 059SG-000015-201;NC 1059SG-0000 15-201:NC1 059SG-000015-201,NC1 059SG-000015-201,

SAMPLE SAMPLE_DATE _TIME TEST_REQUEST8/21/2012 13:48 Archive8/21/2012 13:48 Grainsize8/21/2012 13:48 Iron & manganese8/21/2012 13:48 Sulfide8/21/2012 13:48 TOC8/21/2012 11 :57 Ammonia8/21/2012 11 :57 Archive8/21/2012 11 :57 Grainsiie8/21/2012 11 :57 Iron & manganese8/21/2012 11 :57 Sulfide8/21/2012 11 :57 TOC8/21/2012 11 :33 Ammonia8/21/2012 11:33 Archive8/21/2012 11 :33 Grainsize8/21/2012 11 :33 Iron & manganese8/21/2012 11 :33 Sulfide8/21/201211:33 TOC8/21/2012 11 :06 Ammonia8/21/2012 11 :06 Archive8/21/2012 11 :06 Grainsize8/21/2012 11 :06 Iron & manganese8/21/2012 11 :06 Sulfide8/21/2012 11:06 TOC8/21/2012 10:49 Ammonia8/21/2012 10:49 Archive8/21/2012 10:49 Grainsize8/21/2012 10:49 Iron & manganese8/21/2012 10:49 Sulfide8/21/2012 10:49 TOC8/21/2012 11 :06 Ammonia8/21/2012 11 :06 Grainsize8/21/2012 11 :06 Iron & manganese8/21/2012 11 :06 Sulfide8/21/2012 11 :06 TOC

METHODNAASTM 0422EPA 60108/6020EPA 90308EPA 9060SM4500NH3HNAASTM 0422EPA 60108/6020EPA 90308EPA 9060SM4500NH3HNAASTM 0422EPA 60108/6020EPA 90308EPA 9060SM4500NH3HNAASTM 0422EPA 60108/6020EPA 90308EPA 9060SM4500NH3HNAASTM 0422EPA 60108/6020EPA 90308EPA 9060SM4500NH3HASTM 0422EPA 60108/6020EPA 90308EPA 9060

Page 2 of 2

TURN_A CONTAINROUND_ TAT_UN ER_COUTIME IT NT-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 230 DAYS 130 DAYS 230 DAYS 130 DAYS 0-1; DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 030 DAYS 130 DAYS 130 DAYS 130 DAYS 1

SAMPLE_CUSTO

LA8_QC COC_ID DIANNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpYES AAL-20120821-163510 dpYES AAL-20120821-163510 dpYES AAL-20120821-163510 dpYES AAL-20120821-163510 dpYES AAL-20120821-163510 dpYES AAL-20120821-163510 dpNO AAL-20120821-163510 dp

; NO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dp

Page 29 of 296

CHAIN OF CUSTODY PAGE1 OF'1 Date Rec'd in Lab:

!-iA.ANALYTICAL

Project Name: Newtown CreekWestborough,MATEL: 508-898-9220

FAX: 508-898-9193

Mansfield,MATEL: 508-822-9300

FAX: 508-822-3288

••..••• ra .1iut:U['

""

.'."IeI.

o FAX

o ADEx

-r:r.mF.ll'i1'i'lll:(:lo

Add'i Deliverables

al.""_.!"I.l.I.

Please provide ANCHOR EQUIS EDD and reference Newtown Creek

Other Project Specific Requirements/CommentslDetection Limits:

IS YOUR PROJECTMA MCP or CT RCP?

Client: Alpha Analytical

Address: 320 Forbes Blvd,Mansfield, MA 02048

Phone: 508-844-4122

Fax: 508-822-3288:,Email: [email protected]

o Thesesampleshavebeenpr~viOUSlyanalyzedbyAlpha

Sample SpecificComments •L1215002-02 1

L1215002-04 1

L1215002-06 1

L1215002-08 1

L1215002-10 1

SAMPLEHANDLINGFiltration

o Doneo Nol Neededo LabIa doPresetVation

o Lablodo(Please specifybelow)

L1215002-12

L1215002-14

L1215002-16

L1215002-18

L1215002-20

'~Il~~~"lurryai1:i(;rii;ltj~9~ willnot ,'.". fll!.r1'~~I,.,~nY.¥!Ji9jgUitieSa~~o;;r"S()!,ve(j,A1I.s~,~ples\> :':~u9!"itt.••d,i:I~,,-S,ub~I~'"-Alpha'sPaymenlTeims:' "

0 0 00 0 00 0 00 0 00 0 00 0 00 0 00 0 00 0 00 0 0. . .

. - .

Datemme

Criteria

Received By:

-"ml~'m.tJ=rn-1.RMiI!"ler.l"I::II.l~"[eI::II~:I.}i'.IiI.Are MCPAnalytical Methods Reguired?Are CT RCP (Reasonable Confidence Protocolsl Reauired?

o No

o No

ANALYSIS

DYes

DYes

MCP PRESUMPTIV

State/Fed Prooram

\

I I I I I I I I,

NN"!'I:)

:2I- W(/) I-« «w <..>N ::::iu; Q.

::>z I:)

~ 0Cl a

I I I I I I I

[gI 0 0 0 0 0 0 0 0[gI 0 0 0 0 0 0 0 0[gI 0 0 0 0 0 0 0 0[gI 0 0 0 0 0 0 0 0[gI 0 0 0 0, 0 0 0 0!Xl 0 0 0 0 D 0 0 0[gI 0 0 0 0 0 0 0 0[gI [gI 0- 0 0 0 0 0 0[gI 0 0 0 0 0 0 0 0[gI 0 0 0 0 0 0 0 0

. . .

- I--, .

ished By:

Time:

Sample I Sampler'sMatrix Initials

8/21112 0906 se'diment

8/21/12 0931 sediment

8/21/12 1014 sediment

8/21/12 1049 sediment

8/21/12 1106 sediment

8/21/12 1106 sediment

8/21/12 1133 sediment

8/21/12 1133 sediment

8/21/12 1348 sediment

8/21112 1426 sedimenti

Container Type

• Preservative

Due Date:

ALPHA Quote #.

Turn-Around Time

~ Standard 0 Rush (ONLYIF PRE-APPROVED)

Project Location:

Project#:

Proiect Manaaer: Chris Anderson

Sample ID-

ALPHA Lab ID.-.(L~b'U~'eon!~)A

FORM NO; 01-01(1)(reY.30-JUl-07)

EK002SG-000015-20120821

EK001 SG-000015-20120821

EK010SG-000015-20120821

NC071 SG-000015-20120821

NC059SG-000015-20120821

NC1059SG-000015-20120821

NC058SG-000015-20120821

NC046SG-000015-20120821

MC006SG-000015-20120821

MC002SG-000012-20120821

PLEASE ANSWER QUESTIONS ABOVE!

Page 30 of 296

mailto:[email protected]

Sample SpecificComments

SAMPLE HANDLING

Filtrationo Done

o Nol Neededo Lilblodo

Preservation


L1215002-22

L1215002-24

L1215002-26

DYesDYes

ANALYSIS

Time:

NNv0:2I-U)«wN

Sampler'sCi5Z

Initials ~C>

sediment ~ 0 0 0 0 0 0 0 0 0 0 0sediment ~ 0 0 0 0 0 0 0 0 0 0 0sediment ~ 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0.0 0 0 0 0' 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0

Container Type

Preservative

Receive.d By: DaterTime

o Rush (ONLY IF PRE.APPROVED)

1607

1532

15018/21/12

8/21/12

8/21/12

~ Standard

ALPHAQ t #

Due Date:

Project Location:

Pro'ect#:

• ¥. ~ , .' : ' - ~ '" .'. .."

ifurn-Around Time ,,' ."A,~'''',,',

CHAIN OF CUSTODY

Sample 10

EB008SG-000015-20120821

EB006SG-000015-20120821

EK021 SG-000015-20120821

I-iANAlYT1CAL

Please provide ANCHOR EQUIS EDO and reference Newtown Creek

Fax: 508-824-3288

Email: [email protected]

o These samples have been Previously analyzed by Alpha

Other Project Specific Requirements/Comments/Detection Limits:

Address: 320 Forbes Blvd

Mansfield, MA 02048

Phone: 508-844-4122

ALPHALabID;(Lab Use Oilly)'

FORM NO: 01-01(1)(re ••..30-JUL.Qr)



Page 31 of 296


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Metals

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ICPMS Analysis

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Sequence Logs

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Work Group

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ALPHA ANALYTICAL LABORATORIES, INC. Metals Batch Report - Total Metals (Mass Spec) - A2-6020T Batch WG557278 for dept. 5

Aug 31, 2012 14:08

As Ba Cd Cu Ni Ag Tl Ti Fe Ca Mg Na V Si Ha Zr Sample No. Client No. Sample I.D. Mat Due Sb B Be Cr Pb Se Sr Sn Zn Mn Al K Co Mo W W 60 _______________________________________________________________________________________________________________________________________________________________________________

L1215002-01 EK002SG-000015-20 3 0918 X X

L1215002-03 EK001SG-000015-20 3 0918 X X

L1215002-05 EK010SG-000015-20 3 0918 X X

L1215002-07 NC071SG-000015-20 3 0918 X X

L1215002-09 NC059SG-000015-20 3 0918 X X

L1215002-11 NC1059SG-000015-2 3 0918 X X

L1215002-13 NC058SG-000015-20 3 0918 X X

L1215002-15 NC046SG-000015-20 3 0918 X X

L1215002-17 MC006SG-000015-20 3 0918 X X

L1215002-19 MC002SG-000012-20 3 0918 X X

L1215002-21 EB008SG-000015-20 3 0918 X X

L1215002-23 EB006SG-000015-20 3 0918 X X

L1215002-25 EK021SG-000015-20 3 0918 X X

WG557278-1 Laboratory Method 3 X X

WG557278-2 Laboratory Contro 3 X X

WG557278-3 Duplicate Sample 3 X X

WG557278-4 Matrix Spike 3 X X

WG557278-5 Serial Dilution 3 X X

Comments:

WG557278-3 L1215002-15WG557278-4 L1215002-15WG557278-5 L1215002-15

_______________________________________________________________________________________________________________________________________________________________________________

Page 1

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Tune

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Sample Raw Data

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Digestion Logs ICPMS

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True Values

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Table IV: Initial Calibration Levels and ICV/CCV Concentrations

Analyte STD1 STD2 ICV,CCV (μg/L) (μg/L) (μg/L)

Ag 100 50 Al 10050 5050 As 100 50 B 100 50 Ba 100 50 Be 100 50 Ca 10100 5050 Cd 100 50 Co 100 50 Cr 100 50 Cu 100 50 Fe 10100 5050 K 10000 5500

Mg 10100 5050 Mn 100 50 Mo 100 50 Na 10000 5050 Ni 100 50 Pb 100 50 Sb 100 50 Se 100 50 Si 50 25 Sn 100 50 Sr 100 50 Ti 100 50 Tl 100 50 V 100 50 Zn 100 50

Interferent

ICSA, ICSAB (mg/L)

Cl- 2000 Ca 300

Fe, Na 250 Al, Mg, P, K, S 100

C 200 Mo, Ti 2

All analyte concentrations in ICSAB = 100 ppb except for Ag and Ba = 50 ppb

Page 123 of 296

Analyte LCS,MS

WaterLCS,MS

soilLCS,MS Tissue

(μg/L) (μg/L) (μg/L)

Ag 40 40 40 Al 5000 20000 5000 As 1000 4000 1000 B 1000 4000 1000 Ba 1000 4000 1000 Be 500 2000 500 Ca 5000 4000 5000 Cd 500 2000 500 Co 1000 4000 1000 Cr 1000 4000 1000 Cu 1000 4000 1000 Fe 5000 20000 5000 K 5000 20000 5000

Mg 5000 20000 5000 Mn 1000 4000 1000 Mo 1000 4000 1000 Na 5000 20000 5000 Ni 1000 4000 1000 Pb 1000 4000 1000 Sb 1000 40 1000 Se 1000 4000 1000 Si 1000 4000 1000 Sn 400 400 400 Sr 1000 4000 1000 Ti 1000 4000 1000 Tl 1000 4000 1000 V 1000 4000 1000 Zn 1000 4000 1000

Mercury: ICV, CCV, LCS and MS = 2.5 ppb. Arsenic Hydride, Selenium Hydride: ICV, CCV, LCS and MS = 5 ppb. Mercury by Method 1631: ICV,CCV = 0.005 ppb, LCS, MS = 0.005 ppb.

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Wet Chemistry

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Total Solids Analysis

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Sample Raw Data

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ALPHA ANALYTICAL LABS Last Change 04/09/09 GFF

WET CHEMISTRY DEPARTMENT File A2-TS_S.xltPERCENT TOTAL SOLIDS

Sample Number: _________________ Product: A2-TSAnalyte: Solids, Total

Client: _______________ Analysis Date: 8/23/2012 11:45Technician: KB

Analysis: %TOTAL SOLIDS Work group: WG556644in solids MDL: 0.10%

Method: STM 2540-B

105 degrees CTare Gross Net Net Net Net Net

Weight Weight Weight(1) Weight(2) Weight(3) Weight(4) Weight(5) RESULTSample Number (gm) (gm) (gm) (gm) (gm) (gm) (gm) %

1.32 3.5

1.33 3.14

1.34 2.45

1.32 2.65

1.33 3.05

1.32 3.47

1.32 3.37

1.33 3.09

1.33 3.48

1.32 4.26

1.32 6.1

1.32 2.44

1.34 2.34

1.33 4.5

Comments:

Page 128 of 296

Work Group

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ALPHA ANALYTICAL LABORATORIES, INC.

Alpha WORK GROUP REPORT (wk02)

Aug 25 2012, 08:51 am

Work Group: WG556644 for Department: 7 Wet Chemistry

Created: 23-AUG-12 Due: Operator: KB

Sample Client ID C Product Matrix Stat UA HOLD DUE PR Location ____________________________________________________________________________________________________________________________________

L1215002-01 EK002SG-000015-20120 S A2-TS SOIL DONE U 0828 0918 S0 Amber-A.1 L1215002-03 EK001SG-000015-20120 S A2-TS SOIL DONE U 0828 0918 S0 Amber-A.1 L1215002-05 EK010SG-000015-20120 S A2-TS SOIL DONE U 0828 0918 S0 Amber-A.1 L1215002-07 NC071SG-000015-20120 S A2-TS SOIL DONE U 0828 0918 S0 Amber-A.1 L1215002-09 NC059SG-000015-20120 S A2-TS SOIL DONE U 0828 0918 S0 Amber-A.1 L1215002-11 NC1059SG-000015-2012 S A2-TS SOIL DONE U 0828 0918 S0 Amber-A.1 L1215002-13 NC058SG-000015-20120 S A2-TS SOIL DONE U 0828 0918 S0 Amber-A.1 L1215002-15 NC046SG-000015-20120 S A2-TS SOIL DONE U 0828 0918 S0 Amber-A.1 L1215002-17 MC006SG-000015-20120 S A2-TS SOIL DONE U 0828 0918 S0 Amber-A.1 L1215002-19 MC002SG-000012-20120 S A2-TS SOIL DONE U 0828 0918 S0 Amber-A.1 L1215002-21 EB008SG-000015-20120 S A2-TS SOIL DONE U 0828 0918 S0 Amber-A.1 L1215002-23 EB006SG-000015-20120 S A2-TS SOIL DONE U 0828 0918 S0 Amber-A.1 L1215002-25 EK021SG-000015-20120 S A2-TS SOIL DONE U 0828 0918 S0 Amber-A.1 WG556644-1 Duplicate Sample S A2-TS SOIL DONE U

Comments:

WG556644-1 L1215002-15

____________________________________________________________________________________________________________________________________

Page 1

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Supporting Documentation

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Organic Carbon Analysis

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Sequence Logs

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Sample Raw Data

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ALPHA ANALYTICAL LABS Last Change 04/23/12 TJT

Wet Chemistry Department File A2-TOC9060-2REPS.xltTOTAL ORGANIC CARBON

SOP No.: W-028 Product: A2-TOC-9060-2REPSAnalyte: Total Organic Carbon

Analysis: TOC (2 Reps) Analysis Date: 8/28/2012 9:00Technician: SF

Method: EPA 9060 Work group: WG556725RDL: 0.01%

LCS/SRM Conc. (%): 4.4MS Rep 1 Conc. (%): 1.701 MSD Rep 1 Conc. (%): ____MS Rep 2 Conc. (%): 1.543 MSD Rep 2 Conc. (%): ____ REP1 REP2 FINAL RESULT FINAL RESULT

MDL RESULT RESULT REP1 % REP2 %Sample Number Multiplier mg/Kg mg/Kg COMMENTS

BLANK 0.0 0.0 0.0000

75440.0 92840.0 9.2840

66660.0 60520.0 6.0520

88550.0 86610.0 8.6610

62080.0 61990.0 6.1990

50880.0 50000.0 5.0000

54840.0 54840.0 5.4840

39540.0 37870.0 3.7870

37660.0 38640.0 3.8640

62730.0 62610.0 6.2610

35200.0 31200.0 3.1200

119300.0 110030.0 11.0030

89620.0 87520.0 8.7520

38420.0 37800.0 3.7800

17840.0 18190.0 1.8190

DUP 37900.0 39240.0 3.9240

Sample Number Conc %

REP1

mg/Kg

REP2

mg/KgREP1 Result

%REP2

% % RecoveryREP2 %

Recovery

SRM WG556725-2 4.4 43940 4.3940

Sample Number %

REP1

mg/KgREP2

mg/KgREP1 Result

%REP2

% % RecoveryREP2 %

Recovery

MS WG556725-4 1.701 55460 5.5460 115

1.543

Native Sample Result (%)

Notes

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Work Group

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Aug 29 2012, 06:20 am


Created: 23-AUG-12 Due: Operator: ES


L1215002-01 EK002SG-000015-20120 S A2-TOC-9060-2REPS SOIL DONE U 0918 0918 S0 Amber-A.1 L1215002-03 EK001SG-000015-20120 S A2-TOC-9060-2REPS SOIL DONE U 0918 0918 S0 Amber-A.1 L1215002-05 EK010SG-000015-20120 S A2-TOC-9060-2REPS SOIL DONE U 0918 0918 S0 Amber-A.1 L1215002-07 NC071SG-000015-20120 S A2-TOC-9060-2REPS SOIL DONE U 0918 0918 S0 Amber-A.1 L1215002-09 NC059SG-000015-20120 S A2-TOC-9060-2REPS SOIL DONE U 0918 0918 S0 Amber-A.1 L1215002-11 NC1059SG-000015-2012 S A2-TOC-9060-2REPS SOIL DONE U 0918 0918 S0 Amber-A.1 L1215002-13 NC058SG-000015-20120 S A2-TOC-9060-2REPS SOIL DONE U 0918 0918 S0 Amber-A.1 L1215002-15 NC046SG-000015-20120 S A2-TOC-9060-2REPS SOIL DONE U 0918 0918 S0 Amber-A.1 L1215002-17 MC006SG-000015-20120 S A2-TOC-9060-2REPS SOIL DONE U 0918 0918 S0 Amber-A.1 L1215002-19 MC002SG-000012-20120 S A2-TOC-9060-2REPS SOIL DONE U 0918 0918 S0 Amber-A.1 L1215002-21 EB008SG-000015-20120 S A2-TOC-9060-2REPS SOIL DONE U 0918 0918 S0 Amber-A.1 L1215002-23 EB006SG-000015-20120 S A2-TOC-9060-2REPS SOIL DONE U 0918 0918 S0 Amber-A.1 L1215002-25 EK021SG-000015-20120 S A2-TOC-9060-2REPS SOIL DONE U 0918 0918 S0 Amber-A.1 L1215002-27 SRM1650B S A2-TOC-9060-2REPS SOIL DONE U 0918 0918 S0 Glass-A.1 WG556725-1 Laboratory Method Bl S A2-TOC-9060-2REPS SOIL DONE U WG556725-2 Standard Reference M S A2-TOC-9060-2REPS SOIL DONE U WG556725-3 Duplicate Sample S A2-TOC-9060-2REPS SOIL DONE U WG556725-4 Matrix Spike S A2-TOC-9060-2REPS SOIL DONE U

Comments:

WG556725-3 L1215002-15WG556725-4 L1215002-15

____________________________________________________________________________________________________________________________________

Page 1

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Sample Preparation

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Total Sulfide Analysis

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Sample Raw Data

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ALPHA ANALYTICAL Last Change 10/29/10

WET CHEMISTRY DEPARTMENT File Sulfide-Total-S.xltSULFIDE, TOTAL

SOP No.: 07-30 Product: SULFIDE-9030Curve Calibration Date : 3/6/2012

Curve Identifier: 030612aAnalysis: Method:

Instrument: Wavelength: 664 nm Work group: wg557078

LCS Volume(ml): 1.0 RDL: 0.5 mg/kgLCS/MS Concentration (mg/l): 65.820 Cell: 1 cm

MS/MSD Volume(ml): 2

Standard ID Peak Area Dilution Calibration Curve ug/100ml abs Volume: 50ml

43.88 0.337 1.0 0.007129 0.015454722 r-919

Sulfide 1 Reagent:

ICV/LCS Concentration (mg/kg): 6.58 0.2N NaOH:

Sample FINALWeight Conc. Dilution RDL RESULT

Time Date Sample number (gm) Absorbance (ug S/100ml) Factor Multiplier (mg/kg)1:12pm 8/25/2012 10 0.326 1 Recovery1:13pm 8/25/20121:22pm 8/25/20121:14pm 8/25/20121:14pm 8/25/20121:15pm 8/25/20121:15pm 8/25/20121:22pm 8/25/20121:16pm 8/25/20121:17pm 8/25/20121:16pm 8/25/20123:21pm 8/25/20123:31pm 8/25/20123:22pm 8/25/20123:22pm 8/25/20123:23pm 8/25/20123:23pm 8/25/20123:24pm 8/25/20123:24pm 8/25/2012

1:12pm 8/25/20123:25pm 8/25/2012 10 35.060 200 DUP

Sample Sample Dilution Spike conc. RDL Spike RecoverySample number weight Absorbance Result mg/kg Factor mg/kg Multiplier Result mg/kg %

3:27pm 8/25/2012 10 691.46 13.16 766.15#DIV/0! #VALUE!

1:13pm 8/25/2012 10 6.58 5.26

Reagents/Media Information

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COMMENTS & OBSERVATIONS

BLANKICV/LCSL1215002-01L1215002-03L1215002-05L1215002-07L1215002-09L1215002-11ccbccvL1215002-13L1215002-15L1215002-17L1215002-19L1215002-21L1215002-23L1215002-25ccbccv

000000000

WG557078-1WG557078-3

WG557078-40

WG557078-2

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Work Group

Page 168 of 296



Sep 04 2012, 10:34 am


Created: 25-AUG-12 Due: Operator: mp


L1215002-01 EK002SG-000015-20120 S SULFIDE-9030 SOIL DONE U 0828 0918 S0 Glass-A.06 L1215002-03 EK001SG-000015-20120 S SULFIDE-9030 SOIL DONE U 0828 0918 S0 Glass-A.06 L1215002-05 EK010SG-000015-20120 S SULFIDE-9030 SOIL DONE U 0828 0918 S0 Glass-A.06 L1215002-07 NC071SG-000015-20120 S SULFIDE-9030 SOIL DONE U 0828 0918 S0 Glass-A.06 L1215002-09 NC059SG-000015-20120 S SULFIDE-9030 SOIL DONE U 0828 0918 S0 Glass-A.06 L1215002-11 NC1059SG-000015-2012 S SULFIDE-9030 SOIL DONE U 0828 0918 S0 Glass-A.06 L1215002-13 NC058SG-000015-20120 S SULFIDE-9030 SOIL DONE U 0828 0918 S0 Glass-A.06 L1215002-15 NC046SG-000015-20120 S SULFIDE-9030 SOIL DONE U 0828 0918 S0 Glass-A.06 L1215002-17 MC006SG-000015-20120 S SULFIDE-9030 SOIL DONE U 0828 0918 S0 Glass-A.06 L1215002-19 MC002SG-000012-20120 S SULFIDE-9030 SOIL DONE U 0828 0918 S0 Glass-A.06 L1215002-21 EB008SG-000015-20120 S SULFIDE-9030 SOIL DONE U 0828 0918 S0 Glass-A.06 L1215002-23 EB006SG-000015-20120 S SULFIDE-9030 SOIL DONE U 0828 0918 S0 Glass-A.06 L1215002-25 EK021SG-000015-20120 S SULFIDE-9030 SOIL DONE U 0828 0918 S0 Glass-A.06 WG557078-1 Laboratory Method Bl S SULFIDE-9030 SOIL DONE U WG557078-2 Laboratory Control S S SULFIDE-9030 SOIL DONE U WG557078-3 Duplicate Sample S SULFIDE-9030 SOIL DONE U WG557078-4 Matrix Spike S SULFIDE-9030 SOIL DONE U

Comments:

WG557078-3 L1215002-15WG557078-4 L1215002-15

____________________________________________________________________________________________________________________________________

Page 1

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Ammonia Analysis

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Sequence Logs

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Sample Raw Data

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Work Group

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Sep 04 2012, 10:34 am


Created: 30-AUG-12 Due: Operator: DM


L1215002-01 EK002SG-000015-20120 S NH3-4500 SOIL DONE U 0918 0918 S0 Amber-A.25 L1215002-03 EK001SG-000015-20120 S NH3-4500 SOIL DONE U 0918 0918 S0 Amber-A.25 L1215002-05 EK010SG-000015-20120 S NH3-4500 SOIL DONE U 0918 0918 S0 Amber-A.25 L1215002-07 NC071SG-000015-20120 S NH3-4500 SOIL DONE U 0918 0918 S0 Amber-A.25 L1215002-09 NC059SG-000015-20120 S NH3-4500 SOIL DONE U 0918 0918 S0 Amber-A.25 L1215002-11 NC1059SG-000015-2012 S NH3-4500 SOIL DONE U 0918 0918 S0 Amber-A.25 L1215002-13 NC058SG-000015-20120 S NH3-4500 SOIL DONE U 0918 0918 S0 Amber-A.25 L1215002-15 NC046SG-000015-20120 S NH3-4500 SOIL DONE U 0918 0918 S0 Amber-A.25 L1215002-17 MC006SG-000015-20120 S NH3-4500 SOIL DONE U 0918 0918 S0 Amber-A.25 L1215002-19 MC002SG-000012-20120 S NH3-4500 SOIL DONE U 0918 0918 S0 Amber-A.25 L1215002-21 EB008SG-000015-20120 S NH3-4500 SOIL DONE U 0918 0918 S0 Amber-A.25 L1215002-23 EB006SG-000015-20120 S NH3-4500 SOIL DONE U 0918 0918 S0 Amber-A.25 L1215002-25 EK021SG-000015-20120 S NH3-4500 SOIL DONE U 0918 0918 S0 Amber-A.25 WG558038-1 Laboratory Method Bl S NH3-4500 SOIL DONE U WG558038-2 Laboratory Control S S NH3-4500 SOIL DONE U WG558038-3 Duplicate Sample S NH3-4500 SOIL DONE U WG558038-4 Matrix Spike S NH3-4500 SOIL DONE U

Comments:

WG558038-3 L1215002-15WG558038-4 L1215002-15

____________________________________________________________________________________________________________________________________

Page 1

Page 186 of 296

Sample Preparation

Page 187 of 296

Page 188 of 296

Alpha Report

Page 189 of 296

L1215002

Anchor QEA, LLC

120782-01.01

NEWTOWN CREEK RI

Client:

Project Name:

Project Number:

09/11/12

320 Forbes Boulevard, Mansfield, MA 02048-1806

Lab Number:

Report Date:

508-822-9300 (Fax) 508-822-3288 800-624-9220 - www.alphalab.com

720 Olive Way

Suite 1900

Delaney PetersonATTN:

ANALYTICAL REPORT

Seattle, WA 98101

Certifications & Approvals: NY (11627), CT (PH-0141), NH (2206), NJ NELAP (MA015), RI (LAO00299), PA (68-02089), LA NELAP (03090),FL (E87814), TX (T104704419), WA (C954), DOD (L2217.01), USDA (Permit #P330-11-00109), US Army Corps of Engineers.

(206) 287-9130Phone:

The original project report/data package is held by Alpha Analytical. This report/data package is paginated and should be reproduced only in itsentirety. Alpha Analytical holds no responsibility for results and/or data that are not consistent with the original.

Serial_No:09111209:35

Page 1 of 76 Page 190 of 296

L1215002-01

L1215002-02

L1215002-03

L1215002-04

L1215002-05

L1215002-06

L1215002-07

L1215002-08

L1215002-09

L1215002-10

L1215002-11

L1215002-12

L1215002-13

L1215002-14

L1215002-15

L1215002-16

L1215002-17

L1215002-18

L1215002-19

L1215002-20

L1215002-21

L1215002-22

L1215002-23

L1215002-24

L1215002-25

L1215002-26

L1215002-27

Alpha Sample ID

EK002SG-000015-20120821

EK002SG-000015-20120821

EK001SG-000015-20120821

EK001SG-000015-20120821

EK010SG-000015-20120821

EK010SG-000015-20120821

NC071SG-000015-20120821

NC071SG-000015-20120821

NC059SG-000015-20120821

NC059SG-000015-20120821

NC1059SG-000015-20120821

NC1059SG-000015-20120821

NC058SG-000015-20120821

NC058SG-000015-20120821

NC046SG-000015-20120821

NC046SG-000015-20120821

MC006SG-000015-20120821

MC006SG-000015-20120821

MC002SG-000012-20120821

MC002SG-000012-20120821

EB008SG-000015-20120821

EB008SG-000015-20120821

EB006SG-000015-20120821

EB006SG-000015-20120821

EK021SG-000015-20120821

EK021SG-000015-20120821

SRM1650B

Client ID

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Not Specified

Sample Location

NEWTOWN CREEK RI

120782-01.01

Project Name:Project Number:

Lab Number: Report Date:

L121500209/11/12

08/21/12 09:06

08/21/12 09:06

08/21/12 09:31

08/21/12 09:31

08/21/12 10:14

08/21/12 10:14

08/21/12 10:49

08/21/12 10:49

08/21/12 11:06

08/21/12 11:06

08/21/12 11:06

08/21/12 11:06

08/21/12 11:33

08/21/12 11:33

08/21/12 11:57

08/21/12 11:57

08/21/12 13:48

08/21/12 13:48

08/21/12 14:26

08/21/12 14:26

08/21/12 15:01

08/21/12 15:01

08/21/12 15:32

08/21/12 15:32

08/21/12 16:07

08/21/12 16:07

08/21/12 12:00

Collection Date/Time

Serial_No:09111209:35


NEWTOWN CREEK RI

120782-01.01

Project Name:

Project Number:

Lab Number:

Report Date:L1215002

09/11/12

Case Narrative

The samples were received in accordance with the Chain of Custody and no significant deviations were encountered during the preparation

or analysis unless otherwise noted. Sample Receipt, Container Information, and the Chain of Custody are located at the back of the report.

Results contained within this report relate only to the samples submitted under this Alpha Lab Number and meet all of the requirements of

NELAC, for all NELAC accredited parameters. The data presented in this report is organized by parameter (i.e. VOC, SVOC, etc.). Sample

specific Quality Control data (i.e. Surrogate Spike Recovery) is reported at the end of the target analyte list for each individual sample,

followed by the Laboratory Batch Quality Control at the end of each parameter. If a sample was re-analyzed or re-extracted due to a

required quality control corrective action and if both sets of data are reported, the Laboratory ID of the re-analysis or re-extraction is

designated with an "R" or "RE", respectively. When multiple Batch Quality Control elements are reported (e.g. more than one LCS), the

associated samples for each element are noted in the grey shaded header line of each data table. Any Laboratory Batch, Sample Specific %

recovery or RPD value that is outside the listed Acceptance Criteria is bolded in the report. Performance criteria for CAM and RCP methods

allow for some LCS compound failures to occur and still be within method compliance. In these instances, the specific failures are not

narrated but are noted in the associated QC table. This information is also incorporated in the Data Usability format for our Data Merger tool

where it can be reviewed along with any associated usability implications. Soil/sediments, solids and tissues are reported on a dry weight

basis unless otherwise noted. Definitions of all data qualifiers and acronyms used in this report are provided in the Glossary located at the

back of the report.

In reference to questions H (CAM) or 4 (RCP) when "NO" is checked, the performance criteria for CAM and RCP methods allow for some

quality control failures to occur and still be within method compliance. In these instances the specific failure is not narrated but noted in the

associated QC table. The information is also incorporated in the Data Usability format of our Data Merger tool where it can be reviewed

along with any associated usability implications.

Please see the associated ADEx data file for a comparison of laboratory reporting limits that were achieved with the regulatory Numerical

Standards requested on the Chain of Custody.

HOLD POLICY

For samples submitted on hold, Alpha's policy is to hold samples free of charge for 30 days from the date the project is completed. After 30

days, we will dispose of all samples submitted including those put on hold unless you have contacted your Client Service Representative and

made arrangements for Alpha to continue to hold the samples.

Please contact Client Services at 800-624-9220 with any questions.

Serial_No:09111209:35


Case Narrative (continued)

NEWTOWN CREEK RI

120782-01.01

Project Name:

Project Number:

Lab Number:

Report Date:L1215002

09/11/12

Total Metals

All sediment samples have elevated detection limits for all analytes due to the additional dilutions (20x) required

by the elevated concentrations of target analytes in the samples.

The WG557278-4 MS recovery, performed on L1215002-15, is above the acceptance criteria for Total Iron

(193%); however, the spike does not apply because the sample concentration is greater than four times the

spike amount added.

Sulfide

All samples have elevated detection limits due to the dilutions required to quantitate the results within the

calibration range.

The WG557078-4 MS recovery, performed on L1215002-15, is above the acceptance criteria for Sulfide

(430%); however, the spike does not apply because the sample concentration is greater than four times the

spike amount added.

I, the undersigned, attest under the pains and penalties of perjury that, to the best of my knowledge and belief and based upon my personal inquiry of those responsible for providing the information contained in this analytical report, such information is accurate and complete. This certificate of analysis is not complete unless this page accompanies any and all pages of this report.

Authorized Signature:

Title: Technical Director/Representative Date: 09/11/12

Serial_No:09111209:35


METALS

Serial_No:09111209:35


FF

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

SAMPLE RESULTS

EK002SG-000015-20120821Client ID:08/21/12 09:06Date Collected:08/21/12Date Received:

Matrix: SedimentNot SpecifiedSample Location:

L1215002-01Lab ID:

Field Prep: Not Specified

Parameter ResultDilution FactorQualifier Units RL

DateAnalyzed

AnalyticalMethod Analyst

Date Prepared

Total Metals - Mansfield Lab

Iron, Total

Manganese, Total

34300

219

mg/kg

mg/kg

20

20

367

3.67

08/29/12 09:59

08/29/12 09:59

1,6020A

1,6020A

PD

PD

08/27/12 13:29

08/27/12 13:29

EPA 3050B

EPA 3050B

PrepMethod

Percent Solids: 26%

D

MDL

37.8

0.816

Serial_No:09111209:35


Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

SAMPLE RESULTS



L1215002-03Lab ID:



DateAnalyzed


Date Prepared


Iron, Total

Manganese, Total

33500

219

mg/kg

mg/kg

20

20

437

4.37

08/29/12 10:00

08/29/12 10:00

1,6020A

1,6020A

PD

PD

08/27/12 13:29

08/27/12 13:29

EPA 3050B

EPA 3050B

PrepMethod

Percent Solids: 22%

D

MDL

45.1

0.973

Serial_No:09111209:35


Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

SAMPLE RESULTS



L1215002-05Lab ID:



DateAnalyzed


Date Prepared


Iron, Total

Manganese, Total

32900

200

mg/kg

mg/kg

20

20

456

4.56

08/29/12 10:01

08/29/12 10:01

1,6020A

1,6020A

PD

PD

08/27/12 13:29

08/27/12 13:29

EPA 3050B

EPA 3050B

PrepMethod

Percent Solids: 22%

D

MDL

47.0

1.01

Serial_No:09111209:35


Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

SAMPLE RESULTS

NC071SG-000015-20120821Client ID:08/21/12 10:49Date Collected:08/21/12Date Received:


L1215002-07Lab ID:



DateAnalyzed


Date Prepared


Iron, Total

Manganese, Total

37500

304

mg/kg

mg/kg

20

20

398

3.98

08/29/12 10:02

08/29/12 10:02

1,6020A

1,6020A

PD

PD

08/27/12 13:29

08/27/12 13:29

EPA 3050B

EPA 3050B

PrepMethod

Percent Solids: 25%

D

MDL

41.0

0.886

Serial_No:09111209:35


Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

SAMPLE RESULTS



L1215002-09Lab ID:



DateAnalyzed


Date Prepared


Iron, Total

Manganese, Total

33300

306

mg/kg

mg/kg

20

20

331

3.31

08/29/12 10:05

08/29/12 10:05

1,6020A

1,6020A

PD

PD

08/27/12 13:29

08/27/12 13:29

EPA 3050B

EPA 3050B

PrepMethod

Percent Solids: 29%

D

MDL

34.1

0.736

Serial_No:09111209:35


Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

SAMPLE RESULTS



L1215002-11Lab ID:



DateAnalyzed


Date Prepared


Iron, Total

Manganese, Total

32600

300

mg/kg

mg/kg

20

20

326

3.26

08/29/12 10:06

08/29/12 10:06

1,6020A

1,6020A

PD

PD

08/27/12 13:29

08/27/12 13:29

EPA 3050B

EPA 3050B

PrepMethod

Percent Solids: 30%

D

MDL

33.6

0.726

Serial_No:09111209:35


Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

SAMPLE RESULTS



L1215002-13Lab ID:



DateAnalyzed


Date Prepared


Iron, Total

Manganese, Total

37100

433

mg/kg

mg/kg

20

20

371

3.71

08/29/12 10:07

08/29/12 10:07

1,6020A

1,6020A

PD

PD

08/27/12 13:29

08/27/12 13:29

EPA 3050B

EPA 3050B

PrepMethod

Percent Solids: 25%

D

MDL

38.3

0.826

Serial_No:09111209:35


Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

SAMPLE RESULTS



L1215002-15Lab ID:



DateAnalyzed


Date Prepared


Iron, Total

Manganese, Total

38700

468

mg/kg

mg/kg

20

20

334

3.34

08/29/12 10:08

08/29/12 10:08

1,6020A

1,6020A

PD

PD

08/27/12 13:29

08/27/12 13:29

EPA 3050B

EPA 3050B

PrepMethod

Percent Solids: 28%

D

MDL

34.4

0.743

Serial_No:09111209:35


Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

SAMPLE RESULTS

MC006SG-000015-20120821Client ID:08/21/12 13:48Date Collected:08/21/12Date Received:


L1215002-17Lab ID:



DateAnalyzed


Date Prepared


Iron, Total

Manganese, Total

22500

109

mg/kg

mg/kg

20

20

258

2.58

08/29/12 10:11

08/29/12 10:11

1,6020A

1,6020A

PD

PD

08/27/12 13:29

08/27/12 13:29

EPA 3050B

EPA 3050B

PrepMethod

Percent Solids: 38%

D

MDL

26.6

0.574

Serial_No:09111209:35


Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

SAMPLE RESULTS



L1215002-19Lab ID:



DateAnalyzed


Date Prepared


Iron, Total

Manganese, Total

13600

97.9

mg/kg

mg/kg

20

20

154

1.54

08/29/12 10:12

08/29/12 10:12

1,6020A

1,6020A

PD

PD

08/27/12 13:29

08/27/12 13:29

EPA 3050B

EPA 3050B

PrepMethod

Percent Solids: 61%

D

MDL

15.9

0.342

Serial_No:09111209:35


Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

SAMPLE RESULTS

EB008SG-000015-20120821Client ID:08/21/12 15:01Date Collected:08/21/12Date Received:


L1215002-21Lab ID:



DateAnalyzed


Date Prepared


Iron, Total

Manganese, Total

14400

71.7

mg/kg

mg/kg

20

20

505

5.05

08/29/12 10:13

08/29/12 10:13

1,6020A

1,6020A

PD

PD

08/27/12 13:29

08/27/12 13:29

EPA 3050B

EPA 3050B

PrepMethod

Percent Solids: 19%

D

MDL

52.1

1.12

Serial_No:09111209:35


Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

SAMPLE RESULTS



L1215002-23Lab ID:



DateAnalyzed


Date Prepared


Iron, Total

Manganese, Total

35600

174

mg/kg

mg/kg

20

20

542

5.42

08/29/12 10:15

08/29/12 10:15

1,6020A

1,6020A

PD

PD

08/27/12 13:29

08/27/12 13:29

EPA 3050B

EPA 3050B

PrepMethod

Percent Solids: 17%

D

MDL

55.9

1.21

Serial_No:09111209:35


Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

SAMPLE RESULTS



L1215002-25Lab ID:



DateAnalyzed


Date Prepared


Iron, Total

Manganese, Total

17900

174

mg/kg

mg/kg

20

20

204

2.04

08/29/12 10:16

08/29/12 10:16

1,6020A

1,6020A

PD

PD

08/27/12 13:29

08/27/12 13:29

EPA 3050B

EPA 3050B

PrepMethod

Percent Solids: 46%

D

MDL

21.0

0.453

Serial_No:09111209:35


FF


Method Blank AnalysisBatch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

DateAnalyzed


Date Prepared

09/11/12

Iron, Total

Manganese, Total

J2.39

ND

mg/kg

mg/kg

2

2

20.0

0.200

08/29/12 09:57

08/29/12 09:57

1,6020A

1,6020A

PD

PD

08/27/12 13:29

08/27/12 13:29

Total Metals - Mansfield Lab for sample(s): 01,03,05,07,09,11,13,15,17,19,21,23,25 Batch: WG557278-1

EPA 3050BDigestion Method:

Prep Information

MDL

2.06

0.045

Serial_No:09111209:35


Iron, Total

Manganese, Total

114

113

-

-

75-125

75-125

-

-

20

20

ParameterLCS

%RecoveryLCSD

%Recovery%Recovery

Limits RPD RPD Limits

Total Metals - Mansfield Lab Associated sample(s): 01,03,05,07,09,11,13,15,17,19,21,23,25 Batch: WG557278-2 SRM Lot Number: S1SPIKE

Lab Control Sample AnalysisBatch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

Qual Qual Qual

Serial_No:09111209:35


Iron, Total

Manganese, Total

38700

468.

42000

842

193

109

-

-

-

-

75-125

75-125

-

-

20

20

ParameterNative Sample

MS Found

MS%Recovery

MSD Found

MSD %Recovery

RecoveryLimits RPD

RPD Limits

Total Metals - Mansfield Lab Associated sample(s): 01,03,05,07,09,11,13,15,17,19,21,23,25 QC Batch ID: WG557278-4 QC Sample: L1215002-15 Client ID: NC046SG-000015-20120821

1710

342

MS Added

Matrix Spike AnalysisBatch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

Qual

Q

Qual Qual

Serial_No:09111209:35


Iron, Total

Manganese, Total

38700

468.

40400

488

mg/kg

mg/kg

4

4

20

20

Units RPDParameter Native Sample Duplicate Sample RPD Limits


NEWTOWN CREEK RI

120782-01.01

Project Name:

Project Number:

L1215002Lab Number:

Report Date:

Lab Duplicate AnalysisBatch Quality Control

09/11/12

Qual

Serial_No:09111209:35


Iron, Total

Manganese, Total

38700

468.

38900

462

mg/kg

mg/kg

1

1

10

10

Units % DParameter Native Sample Serial Dilution RPD Limits


NEWTOWN CREEK RI

120782-01.01

Project Name:

Project Number:

L1215002Lab Number:

Report Date:

Lab Serial Dilution Analysis

Batch Quality Control 09/11/12

Qual

Serial_No:09111209:35


INORGANICS&

MISCELLANEOUS

Serial_No:09111209:35


FF


Parameter ResultDilution Factor

Matrix: Sediment

Not SpecifiedSample Location:

L1215002-01Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified

Total Organic Carbon - Mansfield Lab

General Chemistry - Westborough Lab

General Chemistry - Mansfield Lab

Total Organic Carbon (Rep1)


Nitrogen, Ammonia

Solids, Total

7.54

9.28

250

26.2

%

%

mg/kg

%

1

1

1

1

0.010

0.010

27

0.100

08/28/12 09:00

08/28/12 09:00

08/31/12 16:53

08/23/12 11:45

1,9060

1,9060

30,4500NH3-BH

30,2540G

SF

SF

AT

KB

Date Prepared

-

-

08/30/12 13:03

-

09/11/12

MDL

0.010

0.010

4.8

0.100

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-01Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified

General Chemistry - Westborough LabSulfide 15000 mg/kg 400760 08/25/12 13:22 1,9030B MP

Date Prepared

08/25/12 11:45

09/11/12

D

MDL

170

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-03Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified






Nitrogen, Ammonia

Solids, Total

6.67

6.05

170

22.3

%

%

mg/kg

%

1

1

1

1

0.010

0.010

31

0.100

08/28/12 09:00

08/28/12 09:00

08/31/12 16:54

08/23/12 11:45

1,9060

1,9060

30,4500NH3-BH

30,2540G

SF

SF

AT

KB

Date Prepared

-

-

08/30/12 13:03

-

09/11/12

MDL

0.010

0.010

5.6

0.100

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-03Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified


Date Prepared

08/25/12 11:45

09/11/12

D

MDL

100

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-05Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified






Nitrogen, Ammonia

Solids, Total

8.86

8.66

240

21.6

%

%

mg/kg

%

1

1

1

1

0.010

0.010

35

0.100

08/28/12 09:00

08/28/12 09:00

08/31/12 16:55

08/23/12 11:45

1,9060

1,9060

30,4500NH3-BH

30,2540G

SF

SF

AT

KB

Date Prepared

-

-

08/30/12 13:03

-

09/11/12

MDL

0.010

0.010

6.2

0.100

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-05Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified


Date Prepared

08/25/12 11:45

09/11/12

D

MDL

100

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-07Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified






Nitrogen, Ammonia

Solids, Total

6.21

6.20

280

25.0

%

%

mg/kg

%

1

1

1

1

0.010

0.010

28

0.100

08/28/12 09:00

08/28/12 09:00

08/31/12 16:56

08/23/12 11:45

1,9060

1,9060

30,4500NH3-BH

30,2540G

SF

SF

AT

KB

Date Prepared

-

-

08/30/12 13:03

-

09/11/12

MDL

0.010

0.010

5.0

0.100

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-07Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified


Date Prepared

08/25/12 11:45

09/11/12

D

MDL

90.

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-09Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified






Nitrogen, Ammonia

Solids, Total

5.09

5.00

71

29.2

%

%

mg/kg

%

1

1

1

1

0.010

0.010

24

0.100

08/28/12 09:00

08/28/12 09:00

08/31/12 16:56

08/23/12 11:45

1,9060

1,9060

30,4500NH3-BH

30,2540G

SF

SF

AT

KB

Date Prepared

-

-

08/30/12 13:03

-

09/11/12

MDL

0.010

0.010

4.2

0.100

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-09Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified


Date Prepared

08/25/12 11:45

09/11/12

D

MDL

38.

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-11Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified






Nitrogen, Ammonia

Solids, Total

5.48

5.48

80

29.6

%

%

mg/kg

%

1

1

1

1

0.010

0.010

24

0.100

08/28/12 09:00

08/28/12 09:00

08/31/12 16:57

08/23/12 11:45

1,9060

1,9060

30,4500NH3-BH

30,2540G

SF

SF

AT

KB

Date Prepared

-

-

08/30/12 13:03

-

09/11/12

MDL

0.010

0.010

4.3

0.100

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-11Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified


Date Prepared

08/25/12 11:45

09/11/12

D

MDL

76.

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-13Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified






Nitrogen, Ammonia

Solids, Total

3.95

3.79

110

25.4

%

%

mg/kg

%

1

1

1

1

0.010

0.010

28

0.100

08/28/12 09:00

08/28/12 09:00

08/31/12 16:58

08/23/12 11:45

1,9060

1,9060

30,4500NH3-BH

30,2540G

SF

SF

AT

KB

Date Prepared

-

-

08/30/12 13:03

-

09/11/12

MDL

0.010

0.010

5.0

0.100

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-13Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified


Date Prepared

08/25/12 11:45

09/11/12

D

MDL

44.

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-15Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified






Nitrogen, Ammonia

Solids, Total

3.77

3.86

48

28.1

%

%

mg/kg

%

1

1

1

1

0.010

0.010

26

0.100

08/28/12 09:00

08/28/12 09:00

08/31/12 17:02

08/23/12 11:45

1,9060

1,9060

30,4500NH3-BH

30,2540G

SF

SF

AT

KB

Date Prepared

-

-

08/30/12 13:03

-

09/11/12

MDL

0.010

0.010

4.6

0.100

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-15Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified


Date Prepared

08/25/12 11:45

09/11/12

D

MDL

80.

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-17Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified






Nitrogen, Ammonia

Solids, Total

6.27

6.26

230

37.6

%

%

mg/kg

%

1

1

1

1

0.010

0.010

18

0.100

08/28/12 09:00

08/28/12 09:00

08/31/12 17:04

08/23/12 11:45

1,9060

1,9060

30,4500NH3-BH

30,2540G

SF

SF

AT

KB

Date Prepared

-

-

08/30/12 13:03

-

09/11/12

MDL

0.010

0.010

3.3

0.100

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-17Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified


Date Prepared

08/25/12 11:45

09/11/12

D

MDL

120

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-19Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified






Nitrogen, Ammonia

Solids, Total

3.52

3.12

53

61.0

%

%

mg/kg

%

1

1

1

1

0.010

0.010

12

0.100

08/28/12 09:00

08/28/12 09:00

08/31/12 17:05

08/23/12 11:45

1,9060

1,9060

30,4500NH3-BH

30,2540G

SF

SF

AT

KB

Date Prepared

-

-

08/30/12 13:03

-

09/11/12

MDL

0.010

0.010

2.2

0.100

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-19Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified


Date Prepared

08/25/12 11:45

09/11/12

D

MDL

37.

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-21Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified






Nitrogen, Ammonia

Solids, Total

11.9

11.0

500

19.4

%

%

mg/kg

%

1

1

1

1

0.010

0.010

38

0.100

08/28/12 09:00

08/28/12 09:00

08/31/12 17:06

08/23/12 11:45

1,9060

1,9060

30,4500NH3-BH

30,2540G

SF

SF

AT

KB

Date Prepared

-

-

08/30/12 13:03

-

09/11/12

MDL

0.010

0.010

6.8

0.100

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-21Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified


Date Prepared

08/25/12 11:45

09/11/12

D

MDL

120

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-23Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified






Nitrogen, Ammonia

Solids, Total

8.96

8.75

450

17.4

%

%

mg/kg

%

1

1

1

1

0.010

0.010

40

0.100

08/28/12 09:00

08/28/12 09:00

08/31/12 17:07

08/23/12 11:45

1,9060

1,9060

30,4500NH3-BH

30,2540G

SF

SF

AT

KB

Date Prepared

-

-

08/30/12 13:03

-

09/11/12

MDL

0.010

0.010

7.3

0.100

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-23Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified


Date Prepared

08/25/12 11:45

09/11/12

D

MDL

130

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-25Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified






Nitrogen, Ammonia

Solids, Total

3.84

3.78

44

45.5

%

%

mg/kg

%

1

1

1

1

0.010

0.010

15

0.100

08/28/12 09:00

08/28/12 09:00

08/31/12 17:08

08/23/12 11:45

1,9060

1,9060

30,4500NH3-BH

30,2540G

SF

SF

AT

KB

Date Prepared

-

-

08/30/12 13:03

-

09/11/12

MDL

0.010

0.010

2.8

0.100

Serial_No:09111209:35


FF



Matrix: Sediment


L1215002-25Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified


Date Prepared

08/25/12 11:45

09/11/12

D

MDL

49.

Serial_No:09111209:35


FF

SRM1650BClient ID:08/21/12 12:00Date Collected:08/21/12Date Received:


Matrix: Sediment


L1215002-27Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Field Prep:

DateAnalyzed


Not Specified

Total Organic Carbon - Mansfield LabTotal Organic Carbon (Rep1)


1.78

1.82

%

%

1

1

0.010

0.010

08/28/12 09:00

08/28/12 09:00

1,9060

1,9060

SF

SF

Date Prepared

-

-

09/11/12

MDL

0.010

0.010

Serial_No:09111209:35


FF


Method Blank AnalysisBatch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

DateAnalyzed


Date Prepared

09/11/12



Sulfide

Nitrogen, Ammonia

ND

ND

ND

ND

%

%

mg/kg

mg/kg

1

1

1

1

0.010

0.010

0.50

7.5

08/28/12 09:00

08/28/12 09:00

08/25/12 13:12

08/31/12 16:50

1,9060

1,9060

1,9030B

30,4500NH3-BH

SF

SF

MP

AT

-

-

08/25/12 11:45

08/30/12 13:03

Total Organic Carbon - Mansfield Lab for sample(s): 01,03,05,07,09,11,13,15,17,19,21,23,25,2 Batch: WG556725-1

General Chemistry - Westborough Lab for sample(s): 01,03,05,07,09,11,13,15,17,19,21,23,25 Batch: WG557078-1

General Chemistry - Westborough Lab for sample(s): 01,03,05,07,09,11,13,15,17,19,21,23,25 Batch: WG558038-1

MDL

0.010

0.010

0.11

0.01

Serial_No:09111209:35


Sulfide

Nitrogen, Ammonia

80

105

-

-

75-125

83-115

-

-

25

20

ParameterLCS

%RecoveryLCSD

%Recovery%Recovery

Limits RPD RPD Limits

General Chemistry - Westborough Lab Associated sample(s): 01,03,05,07,09,11,13,15,17,19,21,23,25 Batch: WG557078-2

General Chemistry - Westborough Lab Associated sample(s): 01,03,05,07,09,11,13,15,17,19,21,23,25 Batch: WG558038-2

Lab Control Sample AnalysisBatch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

Qual Qual Qual

Serial_No:09111209:35




Sulfide

Nitrogen, Ammonia

3.77

3.86

2500

48.

5.81

5.55

2700

1500

120

115

430

109

-

-

-

-

-

-

-

-

75-125

75-125

70-130

55-144

-

-

-

-

25

25

25

20

ParameterNative Sample

MS Found

MS%Recovery

MSD Found

MSD %Recovery

RecoveryLimits RPD

RPD Limits

Total Organic Carbon - Mansfield Lab Associated sample(s): 01,03,05,07,09,11,13,15,17,19,21,23,25,2 QC Batch ID: WG556725-4 QC Sample: L1215002-15 Client ID: NC046SG-000015-20120821

General Chemistry - Westborough Lab Associated sample(s): 01,03,05,07,09,11,13,15,17,19,21,23,25 QC Batch ID: WG557078-4 QC Sample: L1215002-15 Client ID: NC046SG-000015-20120821


1.7

1.54

46.8

1300

MS Added

Matrix Spike AnalysisBatch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

09/11/12

Qual

Q

Qual Qual

Serial_No:09111209:35


Solids, Total



Sulfide

Nitrogen, Ammonia

28.1

3.77

3.86

2500

48.

28.7

3.79

3.92

2500

47

%

%

%

mg/kg

mg/kg

2

1

2

0

2

10

25

25

25

20

Units RPDParameter Native Sample Duplicate Sample RPD Limits

General Chemistry - Mansfield Lab Associated sample(s): 01,03,05,07,09,11,13,15,17,19,21,23,25 QC Batch ID: WG556644-1 QC Sample: L1215002-15 Client ID: NC046SG-000015-20120821

Total Organic Carbon - Mansfield Lab Associated sample(s): 01,03,05,07,09,11,13,15,17,19,21,23,25,2 QC Batch ID: WG556725-3 QC Sample: L1215002-15 Client ID: NC046SG-000015-20120821



NEWTOWN CREEK RI

120782-01.01

Project Name:

Project Number:

L1215002Lab Number:

Report Date:

Lab Duplicate AnalysisBatch Quality Control

09/11/12

Qual

Serial_No:09111209:35


S.R.M. Standard Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1215002

Parameter

09/11/12

% Recovery QC CriteriaTotal Organic Carbon (Rep1)


96

100

75-125

75-125

Standard Reference Material (SRM): WG556725-2

Qual

Serial_No:09111209:35


*Values in parentheses indicate holding time in days

L1215002-01A

L1215002-01E

L1215002-01F

L1215002-01X

L1215002-02A

L1215002-03A

L1215002-03E

L1215002-03F

L1215002-03X

L1215002-04A

L1215002-05A

L1215002-05E

L1215002-05F

L1215002-05X

L1215002-06A

L1215002-07A

L1215002-07E

L1215002-07F

L1215002-07X

L1215002-08A

Amber 100ml unpreserved


Glass 60mL unpreserved


















B

B

B

B

B

B

B

B

B

B

B

B

B

B

B

B

B

B

B

B

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

3.7

3.7

3.7

3.7

3.7

3.7

3.7

3.7

3.7

3.7

3.7

3.7

3.7

3.7

3.7

3.7

3.7

3.7

3.7

3.7

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

A

B

C

Absent

Absent

Absent

CoolerCustody SealCooler Information

NEWTOWN CREEK RI

120782-01.01

A2-FE-6020T(180),A2-TS(7),A2-MN-6020T(180),A2-TOC-9060-2REPS(28)

NH3-4500(28)

SULFIDE-9030(7)

A2-FE-6020T(180)

SUB-GEOTESTING(28)


NH3-4500(28)

SULFIDE-9030(7)

A2-FE-6020T(180)

SUB-GEOTESTING(28)


NH3-4500(28)

SULFIDE-9030(7)

A2-FE-6020T(180)

SUB-GEOTESTING(28)


NH3-4500(28)

SULFIDE-9030(7)

A2-FE-6020T(180)

SUB-GEOTESTING(28)

Project Name:

Project Number:

L1215002Lab Number:

Report Date:

Sample Receipt and Container Information

Container ID Container Type Cooler pHTempdeg C Pres Seal

Container Information

Analysis(*)

09/11/12

Were project specific reporting limits specified? YES

Reagent H2O Preserved Vials Frozen on: NA

Serial_No:09111209:35



L1215002-09A

L1215002-09E

L1215002-09F

L1215002-09X

L1215002-10A

L1215002-11A

L1215002-11E

L1215002-11F

L1215002-12A

L1215002-13A

L1215002-13E

L1215002-13F

L1215002-13X

L1215002-14A

L1215002-15A

L1215002-15E

L1215002-15F

L1215002-15F1

L1215002-15X

L1215002-16A

L1215002-16D

L1215002-17A

L1215002-17E

L1215002-17F

L1215002-17X

L1215002-18A

L1215002-19A

L1215002-19E

L1215002-19F

L1215002-19X































A

A

A

A

A

C

C

C

C

A

A

A

A

A

C

C

C

C

C

C

C

A

A

A

A

A

A

A

A

A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

4.1

4.1

4.1

4.1

4.1

5.1

5.1

5.1

5.1

4.1

4.1

4.1

4.1

4.1

5.1

5.1

5.1

5.1

5.1

5.1

5.1

4.1

4.1

4.1

4.1

4.1

4.1

4.1

4.1

4.1

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

NEWTOWN CREEK RI

120782-01.01


NH3-4500(28)

SULFIDE-9030(7)

A2-FE-6020T(180)

SUB-GEOTESTING(28)


NH3-4500(28)

SULFIDE-9030(7)

SUB-GEOTESTING(28)


NH3-4500(28)

SULFIDE-9030(7)

A2-FE-6020T(180)

SUB-GEOTESTING(28)


NH3-4500(28)

SULFIDE-9030(7)

SULFIDE-9030(7)

A2-FE-6020T(180)

SUB-GEOTESTING(28)

SUB-GEOTESTING(28)


NH3-4500(28)

SULFIDE-9030(7)

A2-FE-6020T(180)

SUB-GEOTESTING(28)


NH3-4500(28)

SULFIDE-9030(7)

A2-FE-6020T(180)

Project Name:

Project Number:

L1215002Lab Number:

Report Date:



Analysis(*)

09/11/12

Serial_No:09111209:35



L1215002-20A

L1215002-21A

L1215002-21E

L1215002-21F

L1215002-21X

L1215002-22A

L1215002-23A

L1215002-23E

L1215002-23F

L1215002-23X

L1215002-24A

L1215002-25A

L1215002-25E

L1215002-25F

L1215002-25X

L1215002-26A

















A

A

A

A

A

A

C

C

C

C

C

B

B

B

B

B

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

4.1

4.1

4.1

4.1

4.1

4.1

5.1

5.1

5.1

5.1

5.1

3.7

3.7

3.7

3.7

3.7

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

NEWTOWN CREEK RI

120782-01.01

SUB-GEOTESTING(28)


NH3-4500(28)

SULFIDE-9030(7)

A2-FE-6020T(180)

SUB-GEOTESTING(28)


NH3-4500(28)

SULFIDE-9030(7)

A2-FE-6020T(180)

SUB-GEOTESTING(28)


NH3-4500(28)

SULFIDE-9030(7)

A2-FE-6020T(180)

SUB-GEOTESTING(28)

Project Name:

Project Number:

L1215002Lab Number:

Report Date:

Sent to GeoTesting Express












L1215002-02A

L1215002-04A

L1215002-06A

L1215002-08A

L1215002-10A

L1215002-12A

L1215002-14A

L1215002-16A

L1215002-16D

L1215002-18A

L1215002-20A

L1215002-22A



Analysis(*)

09/11/12

Container Comments

Serial_No:09111209:35



NEWTOWN CREEK RI

120782-01.01

Project Name:

Project Number:

L1215002Lab Number:

Report Date:



L1215002-24A

L1215002-26A



Analysis(*)

09/11/12

Container Comments

Serial_No:09111209:35


Report Format: DU Report with "J" Qualifiers

GLOSSARY

Project Name:

Project Number:

Lab Number:

Report Date:

L1215002NEWTOWN CREEK RI

120782-01.01 09/11/12

Acronyms

EPA

LCS

LCSD

LFB

MDL

MS

MSD

NA

NC

NI

RL

RPD

SRM

Environmental Protection Agency.

Laboratory Control Sample: A sample matrix, free from the analytes of interest, spiked with verified known amounts of analytes or a material containing known and verified amounts of analytes.Laboratory Control Sample Duplicate: Refer to LCS.

Laboratory Fortified Blank: A sample matrix, free from the analytes of interest, spiked with verified known amounts of analytes or a material containing known and verified amounts of analytes.Method Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated values, when those target analyte concentrations are quantified below the reporting limit (RL). The MDL includes any adjustments from dilutions, concentrations or moisture content, where applicable.Matrix Spike Sample: A sample prepared by adding a known mass of target analyte to a specified amount of matrix sample for which an independent estimate of target analyte concentration is available. Matrix Spike Sample Duplicate: Refer to MS.

Not Applicable.

Not Calculated: Term is utilized when one or more of the results utilized in the calculation are non-detect at the parameter's reporting unit.Not Ignitable.

Reporting Limit: The value at which an instrument can accurately measure an analyte at a specific concentration. The RL includes any adjustments from dilutions, concentrations or moisture content, where applicable.Relative Percent Difference: The results from matrix and/or matrix spike duplicates are primarily designed to assess the precisionof analytical results in a given matrix and are expressed as relative percent difference (RPD). Values which are less than five times the reporting limit for any individual parameter are evaluated by utilizing the absolute difference between the values; although the RPD value will be provided in the report.Standard Reference Material: A reference sample of a known or certified value that is of the same or similar matrix as the associated field samples.

-

-

-

-

-

-

-

-

-

-

-

-

-

Terms

Analytical Method: Both the document from which the method originates and the analytical reference method. (Example: EPA 8260B is shown as 1,8260B.) The codes for the reference method documents are provided in the References section of the Addendum.

Data Qualifiers

A

B

C

D

E

G

H

I

M

NJ

-

-

-

-

-

-

-

-

-

-

Spectra identified as "Aldol Condensation Product".

The analyte was detected above the reporting limit in the associated method blank. Flag only applies to associated field samples that have detectable concentrations of the analyte at less than five times (5x) the concentration found in the blank. For MCP-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank. For DOD-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank AND the analyte was detected above one-half the reporting limit (or above the reporting limit for common lab contaminants) in the associated method blank. For NJ-Air-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte above the reporting limit.Co-elution: The target analyte co-elutes with a known lab standard (i.e. surrogate, internal standards, etc.) for co-extracted analyses.Concentration of analyte was quantified from diluted analysis. Flag only applies to field samples that have detectable concentrations of the analyte.Concentration of analyte exceeds the range of the calibration curve and/or linear range of the instrument.

The concentration may be biased high due to matrix interferences (i.e, co-elution) with non-target compound(s). The result should be considered estimated.The analysis of pH was performed beyond the regulatory-required holding time of 15 minutes from the time of sample collection.

The RPD between the results for the two columns exceeds the method-specified criteria; however, the lower value has been reporteddue to obvious interference.Reporting Limit (RL) exceeds the MCP CAM Reporting Limit for this analyte.

Presumptive evidence of compound. This represents an estimated concentration for Tentatively Identified Compounds (TICs), where the identification is based on a mass spectral library search.

1 The reference for this analyte should be considered modified since this analyte is absent from the target analyte list of the originalmethod.

-

Footnotes

Serial_No:09111209:35


Report Format: DU Report with "J" Qualifiers

Project Name:

Project Number:

Lab Number:

Report Date:


120782-01.01 09/11/12

Data Qualifiers

P

Q

R

RE

-

-

-

-

The RPD between the results for the two columns exceeds the method-specified criteria.

The quality control sample exceeds the associated acceptance criteria. For DOD-related projects, LCS and/or Continuing CalibrationStandard exceedences are also qualified on all associated sample results. Note: This flag is not applicable for matrix spike recoverieswhen the sample concentration is greater than 4x the spike added or for batch duplicate RPD when the sample concentrations are lessthan 5x the RL. (Metals only.)Analytical results are from sample re-analysis.

Analytical results are from sample re-extraction.

J

ND

-

-

Estimated value. The Target analyte concentration is below the quantitation limit (RL), but above the Method Detection Limit (MDL). This represents an estimated concentration for Tentatively Identified Compounds (TICs).Not detected at the method detection limit (MDL) for the sample.

Serial_No:09111209:35


Alpha Analytical performs services with reasonable care and diligence normal to the analytical testinglaboratory industry. In the event of an error, the sole and exclusive responsibility of Alpha Analyticalshall be to re-perform the work at it's own expense. In no event shall Alpha Analytical be held liablefor any incidental, consequential or special damages, including but not limited to, damages in any wayconnected with the use of, interpretation of, information or analysis provided by Alpha Analytical.

We strongly urge our clients to comply with EPA protocol regarding sample volume, preservation, cooling,containers, sampling procedures, holding time and splitting of samples in the field.

LIMITATION OF LIABILITIES

1

30

Test Methods for Evaluating Solid Waste: Physical/Chemical Methods. EPA SW-846. Third Edition. Updates I - IIIA, 1997.

Standard Methods for the Examination of Water and Wastewater. APHA-AWWA-WPCF. 18th Edition. 1992.

Project Name:

Project Number:

Lab Number:

Report Date:


120782-01.01

REFERENCES

09/11/12

Serial_No:09111209:35


Certificate/Approval Program SummaryLast revised August 3, 2012 – Mansfield Facility

The following list includes only those analytes/methods for which certification/approval is currently held.For a complete listing of analytes for the referenced methods, please contact your Alpha Customer Service Representative.

Connecticut Department of Public Health Certificate/Lab ID: PH-0141.

Wastewater/Non-Potable Water (Inorganic Parameters: pH, Turbidity, Conductivity, Alkalinity, Aluminum, Antimony, Arsenic, Barium, Beryllium, Boron, Cadmium, Calcium, Chromium, Cobalt, Copper, Iron, Lead, Magnesium, Manganese, Mercury, Molybdenum, Nickel, Potassium, Selenium, Silver, Sodium, Strontium, Thallium, Tin, Titanium, Vanadium, Zinc, Total Residue (Solids), Total Suspended Solids (non-filterable). Organic Parameters: PCBs, Organochlorine Pesticides, Technical Chlordane, Toxaphene, Acid Extractables, Benzidines, Phthalate Esters, Nitrosamines, Nitroaromatics & Isophorone, PAHs, Haloethers, Chlorinated Hydrocarbons, Volatile Organics.)

Solid Waste/Soil (Inorganic Parameters: pH, Aluminum, Antimony, Arsenic, Barium, Beryllium, Cadmium,Calcium, Chromium, Hexavalent Chromium, Cobalt, Copper, Iron, Lead, Magnesium, Manganese, Mercury, Molybdenum, Nickel, Potassium, Selenium, Silver, Sodium, Thallium, Titanium, Vanadium, Zinc, Total Organic Carbon, Corrosivity, TCLP 1311, SPLP 1312. Organic Parameters: PCBs, Organochlorine Pesticides, Technical Chlordane, Toxaphene, Volatile Organics, Acid Extractables, Benzidines, Phthalates, Nitrosamines,Nitroaromatics & Cyclic Ketones, PAHs, Haloethers, Chlorinated Hydrocarbons.)

Florida Department of Health Certificate/Lab ID: E87814. NELAP Accredited.

Non-Potable Water (Inorganic Parameters: SM2320B, SM2540D, SM2540G.)

Solid & Chemical Materials (Inorganic Parameters: 6020, 7470, 7471, 9045. Organic Parameters: EPA 8260,8270, 8082, 8081.)

Air & Emissions (EPA TO-15.)

Louisiana Department of Environmental Quality Certificate/Lab ID: 03090. NELAP Accredited.

Non-Potable Water (Inorganic Parameters: EPA 180.1, 245.7, 1631E, 3020A, 6020A, 7470A, 9040, 9050A, SM2320B, 2540D, 2540G, 4500H-B, Organic Parameters: EPA 3510C, 3580A, 3630C, 3640A, 3660B, 3665A,5030B, 8015D, 3570, 8081B, 8082A, 8260B, 8270C, 8270D.)

Solid & Chemical Materials (Inorganic Parameters: EPA 1311, 3050B, 3051A, 3060A, 6020A, 7196A, 7470A,7471B, 7474, 9040B, 9045C, 9060. Organic Parameters: EPA 3540C, 3570, 3580A, 3630C, 3640A, 3660,3665A, 5035, 8015D, 8081B, 8082A, 8260B, 8270C, 8270D.)

Biological Tissue (Inorganic Parameters: EPA 6020A. Organic Parameters: EPA 3570, 3510C, 3610B, 3630C, 3640A, 8270C, 8270D.)


New Hampshire Department of Environmental Services Certificate/Lab ID: 2206. NELAP Accredited.

Non-Potable Water (Inorganic Parameters: EPA 180.1, 1631E, 6020A, 7470A, 9040B, 9050A, SM2540D, 2540G, 4500H+B, 2320B, 3020A, . Organic Parameters: EPA 3510C, 3630C, 3640A, 3660B, 8081B, 8082A, 8270C, 8270D, 8015D.)

Solid & Chemical Materials (Inorganic Parameters: SW-846 1311, 3050B, 3051A, 6020A, 7471B, 9040B, 9045C. Organic Parameters: SW-846 3540C, 3580A, 3630C, 3640A, 3660B, 3665A, 8270C, 8015D, 8082A, 8081B.)

New Jersey Department of Environmental Protection Certificate/Lab ID: MA015. NELAP Accredited.

Non-Potable Water (Inorganic Parameters: SW-846 1312, 3020A, SM2320B, SM2540D, 2540G, 4500H-B, EPA 180.1, 1631E, SW-846 7470A, 9040C, 6020A, 9050A. Organic Parameters: SW-846 3510C, 3580A, 3630C, 3640A, 3660B, 3665A, 8015D, 8081B, 8082A, 8270C, 8270D)

Serial_No:09111209:35


Solid & Chemical Materials (Inorganic Parameters: SW-846 1311, 1312, 3050B, 3051A, 6020A, 7471B, 7474,9040B, 9040C, 9045C, 9045D, 9060. Organic Parameters: SW-846 3540C, 3570, 3580A, 3630C, 3640A, 3660B, 3665A, 8081B, 8082A, 8270C, 8270D, 8015D.)

Atmospheric Organic Parameters (EPA 3C, TO-15, TO-10A, TO-13A-SIM.)

Biological Tissue (Inorganic Parameters: SW-846 6020A. Organic Parameters: SW-846 8270C, 8270D, 3510C, 3570, 3610C, 3630C, 3640A)

New York Department of Health Certificate/Lab ID: 11627. NELAP Accredited.

Non-Potable Water (Inorganic Parameters: SM2320B, SM2540D, 6020A, 1631E, 7470A, 9050A, EPA 180.1, 3020A. Organic Parameters: EPA 8270C, 8270D, 8081B, 8082A, 3510C.)

Solid & Hazardous Waste (Inorganic Parameters: EPA 6020A, 7471B, 7474, 9040C, 9045D. Organic Parameters: EPA 8270C, 8270D, 8081B, 8082A, 1311, 3050B, 3580A, 3570, 3051A.)

Air & Emissions (EPA TO-15, TO-10A.)

Pennsylvania Certificate/Lab ID: 68-02089 NELAP Accredited

Non-Potable Water (Inorganic Parameters: 1312, 1631E, 180.1, 3020A, 6020A, 7470A, 9040B, 9050A, 2320B, 2540D, 2540G, SM4500H+-B. Organic Parameters: 3510C, 3580A, 3630C, 3640A, 3660B, 3665A, 8015D, 8081B, 8082A, 8270C, 8270D .)

Solid & Hazardous Waste (Inorganic Parameters: EPA 1311, 3051A, 6020A, 7471B, 7474 9040B, 9045C, 9060.Organic Parameters: EPA3050B, 3540C, 3570, 3580A, 3630C, 3640A, 3660B, 3665A, 8270C, 8270D, 8081B,8015D, 8082A.)

Rhode Island Department of Health Certificate/Lab ID: LAO00299. NELAP Accredited via NJ-DEP.

Refer to NJ-DEP Certificate for Non-Potable Water.

Texas Commission of Environmental Quality Certificate/Lab ID: T104704419-08-TX. NELAP Accredited.

Solid & Chemical Materials (Inorganic Parameters: EPA 6020, 7470, 7471, 1311, 9040, 9045, 9060. Organic Parameters: EPA 8015, 8270, 8081, 8082.)

Air (Organic Parameters: EPA TO-15)

Virginia Division of Consolidated Laboratory Services Certificate/Lab ID:460194. NELAP Accredited.

Non-Potable Water (Inorganic Parameters:EPA 3020A, 6020A, 245.7, 9040B. Organic Parameters: EPA 3510C,3640A, 3660B, 3665A, 8270C, 8270D, 8082A, 8081B, 8015D.)

Solid & Chemical Materials (Inorganic Parameters: EPA 6020A,7470A,7471B,9040B,9045C,3050B,3051, 9060.Organic Parameters: EPA 3540C, 3580A, 3630C, 3640A, 3660B, 3665A, 3570, 8270C, 8270D, 8081B, 8082A,8015D.)

Washington State Department of Ecology Certificate/Lab ID: C954. Non-Potable Water (InorganicParameters: SM2540D, 180.1, 1631E.)

Solid & Chemical Materials (Inorganic Parameters: EPA 6020, 7470, 7471, 7474, 9045C, 9050A, 9060. OrganicParameters: EPA 8081, 8082, 8015, 8270.)

U.S. Army Corps of Engineers

Department of Defense, L-A-B Certificate/Lab ID: L2217.01.

Non-Potable Water (Inorganic Parameters: EPA 6020A, SM4500H-B. Organic Parameters: 3020A, 3510C,8270C, 8270D, 8270C-ALK-PAH, 8270D-ALK-PAH, 8082A, 8081B, 8015D-SHC, 8015D.)

Solid & Hazardous Waste (Inorganic Parameters: EPA 1311, 3050B, 6020A, 7471A, 9045C, 9060, SM 2540G, ASTM D422-63. Organic Parameters: EPA 3580A, 3570, 3540C, 8270C, 8270D, 8270C-ALK-PAH, 8270D-ALK-PAH 8082A, 8081B, 8015D-SHC, 8015D.


Serial_No:09111209:35


Analytes Not Accredited by NELAP Certification is not available by NELAP for the following analytes: 8270C: Biphenyl. TO-15: Halothane, 2,4,4-Trimethyl-2-pentene, 2,4,4-Trimethyl-1-pentene, Thiophene, 2-Methylthiophene, 3-Methylthiophene, 2-Ethylthiophene, 1,2,3-Trimethylbenzene, Indan, Indene, 1,2,4,5-Tetramethylbenzene, Benzothiophene, 2-Methylnaphthalene, 1-Methylnaphthalene.

Serial_No:09111209:35


Certificate/Approval Program Summary

Last revised August 16, 2012 - Westboro Facility

The following list includes only those analytes/methods for which certification/approval is currently held. For a complete listing of analytes for the referenced methods, please contact your Alpha Customer Service Representative.

Connecticut Department of Public Health Certificate/Lab ID: PH-0574. NELAP Accredited Solid Waste/Soil. Drinking Water (Inorganic Parameters: Color, pH, Turbidity, Conductivity, Alkalinity, Chloride, Free Residual Chlorine, Fluoride, Calcium Hardness, Sulfate, Nitrate, Nitrite, Aluminum, Antimony, Arsenic, Barium, Beryllium, Cadmium, Calcium, Chromium, Copper, Iron, Lead, Magnesium, Manganese, Mercury, Nickel, Selenium, Silver, Sodium, Thallium, Zinc, Total Dissolved Solids, Total Organic Carbon, Total Cyanide, Perchlorate. Organic Parameters: Volatile Organics 524.2, Total Trihalomethanes 524.2, 1,2-Dibromo-3-chloropropane (DBCP) 504.1, Ethylene Dibromide (EDB) 504.1, 1,4-Dioxane (Mod 8270). Microbiology Parameters: Total Coliform-MF mEndo (SM9222B), Total Coliform – Colilert (SM9223, Enumeration and P/A), E. Coli. – Colilert (SM9223, Enumeration and P/A), HPC – Pour Plate (SM9215B), Fecal Coliform – MF m-FC (SM9222D), Fecal Coliform-EC Medium (SM 9221E). Wastewater/Non-Potable Water (Inorganic Parameters: Color, pH, Conductivity, Acidity, Alkalinity, Chloride, Total Residual Chlorine, Fluoride, Total Hardness, Silica, Sulfate, Sulfide, Ammonia, Kjeldahl Nitrogen, Nitrate, Nitrite, O-Phosphate, Total Phosphorus, Aluminum, Antimony, Arsenic, Barium, Beryllium, Boron, Cadmium, Calcium, Chromium, Hexavalent Chromium, Cobalt, Copper, Iron, Lead, Magnesium, Manganese, Mercury, Molybdenum, Nickel, Potassium, Selenium, Silver, Sodium, Strontium, Thallium, Tin, Titanium, Vanadium, Zinc, Total Residue (Solids), Total Dissolved Solids, Total Suspended Solids (non-filterable), BOD, CBOD, COD, TOC, Total Cyanide, Phenolics, Foaming Agents (MBAS), Bromide, Oil and Grease. Organic Parameters: PCBs, Organochlorine Pesticides, Technical Chlordane, Toxaphene, Acid Extractables (Phenols), Benzidines, Phthalate Esters, Nitrosamines, Nitroaromatics & Isophorone, Polynuclear Aromatic Hydrocarbons, Haloethers, Chlorinated Hydrocarbons, Volatile Organics, TPH (HEM/SGT), CT- Extractable Petroleum Hydrocarbons (ETPH), MA-EPH, MA-VPH. Microbiology Parameters: Total Coliform – MF mEndo (SM9222B), Total Coliform – MTF (SM9221B), E. Coli – Colilert (SM9223 Enumeration), HPC – Pour Plate (SM9215B), Fecal Coliform – MF m-FC (SM9222D), Fecal Coliform – A-1 Broth (SM9221E), Enterococcus - Enterolert. Solid Waste/Soil (Inorganic Parameters: pH, Sulfide, Aluminum, Antimony, Arsenic, Barium, Beryllium, Boron, Cadmium, Calcium, Chromium, Hexavalent Chromium, Cobalt, Copper, Iron, Lead, Magnesium, Manganese, Mercury, Molybdenum, Nickel, Potassium, Selenium, Silver, Sodium, Thallium, Tin, Vanadium, Zinc, Total Cyanide, Ignitability, Phenolics, Corrosivity, TCLP Leach (1311), SPLP Leach (1312 metals only), Reactivity. Organic Parameters: PCBs, PCBs in Oil, Organochlorine Pesticides, Technical Chlordane, Toxaphene, CT-Extractable Petroleum Hydrocarbons (ETPH), MA-EPH, MA-VPH, Dicamba, 2,4-D, 2,4,5-T, 2,4,5-TP(Silvex), Dalapon, Volatile Organics (SW 8260), Acid Extractables (Phenols) (SW 8270), Benzidines (SW 8270), Phthalates (SW 8270), Nitrosamines (SW 8270), Nitroaromatics & Cyclic Ketones (SW 8270), PAHs (SW 8270), Haloethers (SW 8270), Chlorinated Hydrocarbons (SW 8270). ) Maine Department of Human Services Certificate/Lab ID: 2009024. Drinking Water (Inorganic Parameters: SM9215B, 9222D, 9223B, EPA 180.1, 353.2, SM2130B, 2320B, 2540C, 4500Cl-D, 4500CN-C, 4500CN-E, 4500F-C, 4500H+B, 4500NO3-F, EPA 200.7, EPA 200.8, 245.1, EPA 300.0. Organic Parameters: 504.1, 524.2.) Wastewater/Non-Potable Water (Inorganic Parameters: EPA 120.1, 1664A, 350.1, 351.1, 353.2, 410.4, 420.1, SM2320B, 2510B, 2540C, 2540D, 426C, 4500Cl-D, 4500Cl-E, 4500CN-C, 4500CN-E, 4500F-B, 4500F-C, 4500H+B, 4500Norg-B, 4500Norg-C, 4500NH3-B, 4500NH3-G, 4500NO3-F, 4500P-B, 4500P-E, 5210B, 5220D, 5310C, 9010B, 9040B, 9030B, 7470A, 7196A, 2340B, EPA 200.7, 6010B, 200.8, 6020, 245.1, 1311, 1312, 3005A, Enterolert, 9223D, 9222D. Organic Parameters: 608, 624, 625, 8081A, 8082, 8330, 8151A, 8260B, 8270C, 3510C, 3630C, 5030B, ME-DRO, ME-GRO, MA-EPH, MA-VPH.) Solid Waste/Soil (Inorganic Parameters: 9010B, 9012A, 9014A, 9030B, 9040B, 9045C, 6010B, 7471A, 7196A, 9050A, 1010, 1030, 9065, 1311, 1312, 3005A, 3050B. Organic Parameters: ME-DRO, ME-GRO, MA-EPH, MA-VPH, 8260B, 8270C, 8330, 8151A, 8081A, 8082, 3540C, 3546, 3580A, 3630C, 5030B, 5035.) Massachusetts Department of Environmental Protection Certificate/Lab ID: M-MA086. Drinking Water (Inorganic Parameters: (EPA 200.8 for: Sb,As,Ba,Be,Cd,Cr,Cu,Pb,Ni,Se,Tl) (EPA 200.7 for: Ba,Be,Ca,Cd,Cr,Cu,Na,Ni) 245.1, (300.0 for: Nitrate-N, Fluoride, Sulfate); (EPA 353.2 for: Nitrate-N, Nitrite-N); (SM4500NO3-F for: Nitrate-N and Nitrite-N); 4500F-C, 4500CN-CE, EPA 180.1, SM2130B, SM4500Cl-D, 2320B, SM2540C, SM4500H-B. Organic Parameters: (EPA 524.2 for: Trihalomethanes, Volatile Organics); (504.1 for: 1,2-Dibromoethane, 1,2-Dibromo-3-Chloropropane), EPA 332. Microbiology Parameters: SM9215B; ENZ. SUB. SM9223; ColilertQT SM9223B; MF-SM9222D.) Non-Potable Water (Inorganic Parameters:, (EPA 200.8 for: Al,Sb,As,Be,Cd,Cr,Cu,Pb,Mn,Ni,Se,Ag,Tl,Zn); (EPA 200.7

Serial_No:09111209:35


for: Al,Sb,As,Be,Cd,Ca,Cr,Co,Cu,Fe,Pb,Mg,Mn,Mo,Ni,K,Se,Ag,Na,Sr,Ti,Tl,V,Zn); 245.1, SM4500H,B, EPA 120.1, SM2510B, 2540C, 2340B, 2320B, 4500CL-E, 4500F-BC, 426C, SM4500NH3-BH, (EPA 350.1 for: Ammonia-N), LACHAT 10-107-06-1-B for Ammonia-N, SM4500NO3-F, 353.2 for Nitrate-N, SM4500NH3-BC-NES, EPA 351.1, SM4500P-E, 4500P-B,E, 5220D, EPA 410.4, SM 5210B, 5310C, 4500CL-D, EPA 1664, SM14 510AC, EPA 420.1, SM4500-CN-CE, SM2540D. Organic Parameters: (EPA 624 for Volatile Halocarbons, Volatile Aromatics),(608 for: Chlordane, Toxaphene, Aldrin, alpha-BHC, beta-BHC, gamma-BHC, delta-BHC, Dieldrin, DDD, DDE, DDT,Endosulfan I, Endosulfan II, Endosulfan sulfate, Endrin, Endrin Aldehyde, Heptachlor, Heptachlor Epoxide, PCBs-Water), (EPA 625 for SVOC Acid Extractables and SVOC Base/Neutral Extractables), 600/4-81-045-PCB-Oil. Microbiology Parameters: (ColilertQT SM9223B; Enterolert-QT: SM9222D-MF.) New Hampshire Department of Environmental Services Certificate/Lab ID: 200307. NELAP Accredited. Drinking Water (Inorganic Parameters: SM 9222B, 9223B, 9215B, EPA 200.7, 200.8, 300.0, SM4500CN-E, 4500H+B, 4500NO3-F, 2320B, 2510B, 2540C, 4500F-C, 5310C, 2120B, EPA 332.0. Organic Parameters: 504.1, 524.2.) Non-Potable Water (Inorganic Parameters: SM9222D, 9221B, 9222B, 9221E-EC, EPA 3005A, 200.7, 200.8, 245.1, SW-846 6010B, 6010C, 6020, 6020A, 7196A, 7470A, SM3500-CR-D, EPA 120.1, 300.0, 350.1, 350.2, 351.1, 353.2, 410.4, 420.1, 426C, 1664A, SW-846 9010B, 9030B, 9040B, SM2120B, 2310B, 2320B, 2540B, 2540D, 4500H+B, 4500CL-E, 4500CN-E, 4500NH3-H, 4500NO3-F, 4500NO2-B, 4500P-E, 4500-S2-D, 5210B, 5220D, 2510B, 2540C, 4500F-C, 5310C, 5540C, LACHAT 10-204-00-1-A, LACHAT 10-107-06-2-D, 3060A. Organic Parameters: SW-846 3510C, 3630C, 5030B, 8260B, 8270C, 8270D, 8330, EPA 624, 625, 608, SW-846 8082, 8082A, 8081A, 8081B, 8151A, 8330, 8270C-SIM, 8270D-SIM.) Solid & Chemical Materials (Inorganic Parameters: SW-846 6010B, 6010C, 7196A, 7471A, 1010, 1030, 9010, 9012A, 9014, 9030B, 9040B, 9045C, 9050, 9065,1311, 1312, 3005A, 3050B, 3060A. Organic Parameters: SW-846 3540C, 3546, 3050B, 3580A, 3630C, 5030B, 5035, 8260B, 8270C, 8270D, 8270C-SIM, 8270D-SIM, 8330, 8151A, 8015B, 8015C, 8082, 8082A, 8081A, 8081B.) New Jersey Department of Environmental Protection Certificate/Lab ID: MA935. NELAP Accredited. Drinking Water (Inorganic Parameters: SM9222B, 9221E, 9223B, 9215B, 4500CN-CE, 4500NO3-F, 4500F-C, EPA 300.0, 200.7, 200.8, 245.1, 2540C, SM2120B, 2320B, 2510B, 5310C, SM4500H-B. Organic Parameters: EPA 332, 504.1, 524.2.) Non-Potable Water (Inorganic Parameters: SM5210B, EPA 410.4, SM5220D, 4500Cl-E, EPA 300.0, SM2120B, 2340B, SM4500F-BC, EPA 200.7, 200.8, 351.1, LACHAT 10-107-06-2-D, EPA 353.2, SM4500NO3-F, 4500NO2-B, EPA 1664A, SM5310B, C or D, 4500-PE, EPA 420.1, SM510ABC, SM4500P-B5+E, 2540B, 2540C, 2540D, 2540G, EPA 120.1, SM2510B, SM2520B, SM15 426C, 9222D, 9221B, 9221C, 9221E, 9222B, 9215B, 2310B, 2320B, 4500NH3-H, 4500-S D, EPA 350.1, 350.2, SW-846 1312, 7470A, 5540C, SM4500H-B, 4500SO3-B, SM3500Cr-D, 4500CN-CE, EPA 245.1, SW-846 9040B, 3005A, 3015, EPA 6010B, 6010C, 6020, 6020A, 7196A, 3060A, SW-846 9010B, 9030B. Organic Parameters: SW-846 8260B, 8260C, 8270C, 8270D, 8270C-SIM, 8270D-SIM, 3510C, EPA 608, 624, 625, SW-846 3630C, 5030B, 8015C, 8081A, 8081B, 8082, 8082A, 8151A, 8330, 1,4-Dioxane by NJ Modified 8270, 8015B, NJ EPH.) Solid & Chemical Materials (Inorganic Parameters: SW-846, 6010B, 6010C, 6020, 6020A, 7196A, 3060A, 9010B, 9030B, 1010, 1030, 1311, 1312, 3005A, 3050B, 7471A, 7471B, 9014, 9012A, 9040B, 9040C, 9045C, 9045D, 9050A, 9065, 9251. Organic Parameters: SW-846 8015B, 8015C, 8081A, 8081B, 8082, 8082A, 8151A, 8330, 8260B, 8260C, 8270C, 8270D, 8270C-SIM, 8270D-SIM, 3540C, 3546, 3580A, 3630C, 5030B, 5035L, 5035H, NJ OQA-QAM-025 Rev.7, NJ EPH.) New York Department of Health Certificate/Lab ID: 11148. NELAP Accredited. Drinking Water (Inorganic Parameters: SM9223B, 9222B, 9215B, EPA 200.8, 200.7, 245.2, SM5310C, EPA 332.0, SM2320B, EPA 300.0, SM2120B, 4500CN-E, 4500F-C, 4500NO3-F, 2540C, SM 2510B. Organic Parameters: EPA 524.2, 504.1.) Non-Potable Water (Inorganic Parameters: SM9221E, 9222D, 9221B, 9222B, 9215B, 5210B, 5310C, EPA 410.4, SM5220D, 2310B-4a, 2320B, EPA 200.7, 300.0, SM4500CL-E, 4500F-C, SM15 426C, EPA 350.1, SM4500NH3-BH, EPA 351.1, LACHAT 10-107-06-2, EPA 353.2, SM4500-NO3-F, 4500-NO2-B, 4500P-E, 2540C, 2540B, 2540D, EPA 200.8, EPA 6010B, 6010C, 6020, 6020A, EPA 7196A, SM3500Cr-D, EPA 245.1, 245.2, 7470A, SM2120B, LACHAT 10-204-00-1-A, 4500CN-CE, EPA 1664A, EPA 420.1, SM14 510C, EPA 120.1, SM2510B, SM4500S-D, SM5540C, EPA 3005A, 3015, 9010B, 9030B. Organic Parameters: EPA 624, 8260B, 8260C, 8270C, 8270D, 8270C-SIM, 8270D-SIM, 625, 608, 8081A, 8081B, 8151A, 8330, 8082, 8082A, EPA 3510C, 5030B.) Solid & Hazardous Waste (Inorganic Parameters: EPA 1010, 1030, EPA 6010B, 6010C, 7196A, 7471A, 7471B, 9012A, 9014, 9065, 9050A, EPA 1311, 1312, 3005A, 3050B, 9010B, 9040C, 9045D. Organic Parameters: EPA 8260B, 8260C, 8270C, 8270D, 8270C-SIM, 8270D-SIM, 8015B, 8015C, 8081A, 8081B, 8151A, 8330, 8082 8082A, 3540C, 3546, 3580, 3580A, 5030B, 5035A-H, 5035A-L.)

Serial_No:09111209:35


North Carolina Department of the Environment and Natural Resources Certificate/Lab ID : 666. (Inorganic Parameters: SM2310B, 2320B, 4500Cl-E, 4500Cn-E, 9014, Lachat 10-204-00-1-X, 1010A, 1030, 4500NO3-F, 353.2, 4500P-E, 4500SO4-E, 300.0, 4500S-D, 5310B, 5310C, 6010C, 6020A, 200.7, 200.8, 3500Cr-B, 7196A, 245.1, 7471A, 7471B, 1311,1312. Organic Parameters: 608, 8081B, 8082A, 624, 8260B, 625, 8270D, 8151A, 8015C, 504.1, MA-EPH, MA-VPH.) Drinking Water Program Certificate/Lab ID: 25700. (Inorganic Parameters: Chloride EPA 300.0. Organic Parameters: 524.2) Pennsylvania Department of Environmental Protection Certificate/Lab ID : 68-03671. NELAP Accredited. Drinking Water (Inorganic Parameters: 200.7, 200.8, 245.2, 300.0, 332.0, 2120B, 2320B, 2510B, 2540C, 4500-CN-CE, 4500F-C, 4500H+-B, 4500NO3-F, 5310C. Organic Parameters: EPA 524.2, 504.1) Non-Potable Water (Inorganic Parameters: EPA 120.1, 1312, 3005A,3015, 3060A, 200.7, 200.8, 410.4, 1664A, SM2540D, 5210B, 5220D, 4500-P,BE, 245.1, 300.0, 3501., 350.2, 353.2, 420.1, 6010B, 6010C, 6020, 6020A, 7196A, 7470A, 9010B, 9030B, 9040B, Lachat 10-107-06-2-D, NJ-EPH, 2120B, 2310B, 2320B, 2340B, 2510C, 2540B, 2540C, 3500Cr-D, 436C, 4500CN-CE, 4500Cl-E, 4500F-B, 4500F-C, 4500H+-B, 4500NO2-B, 4500NO3-F, 4500S-D, 4500SO3-B, 5310BCD, 5540C. Organic Parameters: EPA 3510C, 3630C, 5030B, 625, 624, 608, 8081A, 8081B, 8082, 8082A, 8151A, 8260B, 8270C, 8270D, 8330, 8015B, ) Solid & Hazardous Waste (Inorganic Parameters: EPA 350.1, 1010, 1030, 1311, 1312, 3005A, 3050B, 3060A, 6010B, 6010C, 6020A, 7196A, 7471A, 7471B, 9010B, 9012A, 9014, 9040B, 9045C, 9050, 9065, SM 4500NH3-BH, 9030B, 9038, 9251. Organic Parameters: 3540C, 3546, 3580A, 3630C, 5035, 8015B, 8015C, 8081A, 8081B, 8082, 8082A, 8151A, 8260B, 8270C, 8270D, 8270C-SIM, 8270D-SIM, 8330, NJ-EPH.) Rhode Island Department of Health Certificate/Lab ID: LAO00065. NELAP Accredited via NJ-DEP. Refer to MA-DEP Certificate for Potable and Non-Potable Water. Refer to NJ-DEP Certificate for Potable and Non-Potable Water. Texas Commisson on Environmental Quality Certificate/Lab ID: T104704476-09-1. NELAP Accredited. Non-Potable Water (Inorganic Parameters: EPA 120.1, 1664, 200.7, 200.8, 245.1, 245.2, 300.0, 350.1, 351.1, 353.2, 410.4, 420.1, 6010, 6020, 7196, 7470, 9040, SM 2120B, 2310B, 2320B, 2510B, 2540B, 2540C, 2540D, 426C, 4500CL-E, 4500CN-E, 4500F-C, 4500H+B, 4500NH3-H, 4500NO2B, 4500P-E, 4500 S2¯D, 510C, 5210B, 5220D, 5310C, 5540C. Organic Parameters: EPA 608, 624, 625, 8081, 8082, 8151, 8260, 8270, 8330.) Solid & Hazardous Waste (Inorganic Parameters: EPA 1311, 1312, 9012, 9014, 9040, 9045, 9050, 9065.) Virginia Division of Consolidated Laboratory Services Certificate/Lab ID: 460195. NELAP Accredited. Drinking Water (Inorganic Parameters: EPA 200.7, 200.8, 300.0, 2510B, 2120B, 2540C, 4500CN-CE, 245.2, 2320B, 4500F-C, 4500F-C, 4500NO3-F, 5310C. Organic Parameters: EPA 504.1, 524.2.) Non-Potable Water (Inorganic Parameters: EPA 120.1, 1664A, 200.7, 2..08, 245.1, 300.0, 3005A, 3015, 1312, 6010B, 6010C, 3060A, 353.2, 420.1, 6020, 6020A, SM4500S-D, SM4500-CN-CE, Lachat 10-204-00-1-X, 7196A, 7470A, 9010B, 9040B, 2310B, 2320B, 2510B, 2540B, 2540C, 3500Cr-D, 426C, 4500Cl-E, 4500F-B, 4500F-C, 4500PE, 510AC, 5210B, 5310B 5310C, 5540C. Organic Parameters: EPA 3510C, 3630C, 5030B, 8260B, 608, 624, 625, 8081A, 8081B, 8082, 8082A, 8151A, 8270C, 8270D, 8270C-SIM, 8270D-SIM, 8330, ) Solid & Hazardous Waste (Inorganic Parameters: EPA 1010A, 1030, 3060A, 3050B, 1311, 1312, 6010B, 6010C, 6020, , 7196A, 7471A, 7471B, 6020A, 9030B, 9010B, 9012A, 9014 9040B, 9045C, 9050A, 9065. Organic Parameters: EPA 5035, 3540C, 3546, 3550, 3580, 3630C, 8260B, 8015B, 8015C, 8081A, 8081B, 8082, 8082A, 8151A, 8270C, 8270D, 8270C-SIM, 8270D-SIM, 8330.) Department of Defense, L-A-B Certificate/Lab ID: L2217. Drinking Water (Inorganic Parameters: SM 4500H-B. Organic Parameters: EPA 524.2, 504.1.) Non-Potable Water (Inorganic Parameters: EPA 200.7, 200.8, 6010B, 6010C, 6020, 6020A, 245.1, 245.2, 7470A, 9040B, 9010B, 180.1. 300.0, 332.0, 6860, 353.2, 410.4, 9060, 1664A, SM 4500CN-E, 4500H-B, 4500NO3-F, 4500CL-D, 5220D, 5310C, 2130B, 2320B, 2540C, 3005A, 3015, 9010B, 9056. Organic Parameters: EPA 8260B, 8260C, 8270C, 8270D, 8270C-SIM, 8270D-SIM, 8330A, 8082, 8082A, 8081A, 8081B, 3510C, 5030B, MassDEP EPH, MassDEP VPH.)

Serial_No:09111209:35


Solid & Hazardous Waste (Inorganic Parameters: EPA 200.7, 6010B, 6010C, 7471A, 6860, 1311, 1312, 3050B, 7196A, 9010B, 9012A, 9040B, 9045C, 3500-CR-D, 4500CN-CE, 2540G, Organic Parameters: EPA 8260B, 8260C, 8270C, 8270D, 8270C-SIM, 8270D-SIM, 8330A/B-prep, 8082, 8082A, 8081A, 8081B, 3540C, 3546, 3580A, 5035A, MassDEP EPH, MassDEP VPH.) The following analytes are not included in our current NELAP/TNI Scope of Accreditation: EPA 8260B: Freon-113, 1,2,4,5-Tetramethylbenzene, 4-Ethyltoluene. EPA 8330A: PETN, Picric Acid, Nitroglycerine, 2,6-DANT, 2,4-DANT. EPA 8270C: Methyl naphthalene, Dimethyl naphthalene, Total Methylnapthalenes, Total Dimethylnaphthalenes, 1,4-Diphenylhydrazine (Azobenzene). EPA 625: 4-Chloroaniline, 4-Methylphenol. Total Phosphorus in a soil matrix, Chloride in a soil matrix, TKN in a soil matrix, NO2 in a soil matrix, NO3 in a soil matrix, SO4 in a soil matrix. EPA 9071: Total Petroleum Hydrocarbons, Oil & Grease.

Serial_No:09111209:35


L 12 I~O()2.

305 W Grand Ave Suite 300, Montvale, New Jersey 07645; ph: 201.930.9690

Client: Newtown Creek Group

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Project: Newtown Creek

COCID:

Sample Custodian:

Lab:

AAL-20120821-163510

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Alpha Analytical Labs

CDCCollected # LabSample Field Sample ID Matrix Containers Analytical Program ac'Number Date Time

001 EK002SG.000015.20120821 SE 08/21/2012 09:06 5 Newtown Creek Surface Sediment 0002 EK001SG.000015.20120821 SE 08/21/2012 09:31 5 Newtown Creek Surface Sediment 0003 EK010SG.000015.20120821 SE 08/21/2012 10:14 5 Newtown Creek Surface Sediment 0004 NC071SG.000015.20120821 SE 08/21/2012 10:49 5 Newtown Creek Surface Sediment 0

0 005 NC059SG-000015.20120821 SE 08/21/2012 11:06 5 Newtown Creek Surface Sediment 0'l- 006 NC1059SG.000015-20120821 SE 08/21/2012 11:06 4 Newtown Creek Surface Sediment 0y 007 NC058SG-000015-20120821 SE 08/21/2012 11:33 5 Newtown Creek Surface Sediment 0(., 008 NC046SG-000015.20120821 SE 08/21/2012 11:57 7 Newtown Creek Surface Sediment [!]If 009 MC006SG-000015.20120821 SE 08/21/2012 13:48 5 Newtown Creek Surface Sediment 0

010 MC002SG.000012-20120821 SE 08/21/2012 14:26 5 Newtown Creek Surface Sediment 0'L 011 EB008SG-000015-20120821 SE 08/21/2012 15:01 5 Newtown Creek Surface Sediment 0<f 012 EB006SG.000015-20120821 SE 08/21/2012 15:32 5 Newtown Creek Surface Sediment 0

013 EK021SG-000015.20120821 SE 08/21/2012 16:07 5 Newtown Creek Surface Sediment 0

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Page 1 of 1

Serial_No:09111209:35


FIELD _SAMPLE_IDEB006SG-0000 15-20 121EB006SG-0000 15-20 121EB006SG-0000 15-20 12(EB006SG-000015-2012(EB006SG-000015-2012(EB006SG-000015-2012(EB008SG-000015-2012(EB008SG-000015-2012(EB008SG-0000 15-20 12(EB008SG-000015-2012(EB008SG-000015-2012(EB008SG-000015-2012(EKOO1SG-OOOO15-20 121EK001 SG-000015-2012(EK001 SG-000015-20121EK001 SG-000015-20121EK001 SG-000015-20121EK001 SG-000015-20121EK002SG-000015-2012(EK002SG-000015-2012(EK002SG-000015-2012(EK002SG-000015-2012(EK002SG-000015-2012(EK002SG-000015-2012(EK010SG-000015-2012(EK010SG-000015-2012(EK010SG-000015-2012(EK010SG-000015-2012(EK010SG-000015-2012(EK010SG-000015-2012(EK021 SG-OOOO15-20 121EK021 SG-000015-20121EK021 SG-OOOO15-20 121EK021 SG-OOOO15-20 121EK021 SG-000015-20121EK021 SG-000015-20121MC002SG-000012-2012MC002SG-000012-2012MC002SG-000012-2012MC002SG-000012-2012MC002SG-000012-2012MC002SG-000012-2012MC006SG-000015-2012

MATRIXSESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESE

SAMPLE SAMPLE_DATE _TIME TEST_REQUEST8/21/2012 15:32 Ammonia8/21/2012 15:32 Archive8/21/2012 15:32 Grainsize8/21/2012 15:32 Iron & manganese8/21/2012 15:32 Sulfide8/21/2012 15:32 TOC8/21/2012 15:01 Ammonia8/21/2012 15:01 Archive8/21/2012 15:01 Grainsize8/21/2012 15:01 Iron & manganese8/21/2012 15:01 Sulfide8/21/2012 15:01 TOC8/21/2012 9:31 Ammonia8/21/2012 9:31 Archive8/21/2012 9:31 Grainsize8/21/2012 9:31 Iron & manganese8/21/2012 9:31 Sulfide8/21/2012 9:31 TOC8/21/2012 9:06 Ammonia8/21/2012 9:06 Archive8/21/2012 9:06 Grainsize8/21/2012 9:06 Iron & manganese8/21/2012 9:06 Sulfide8/21/2012 9:06 TOC8/21/2012 10:14 Ammonia8/21/2012 10:14 Archive8/21/2012 10:14 Grainsize8/21/2012 10:14 Iron & manganese8/21/2012 10:14 Sulfide8/21/2012 10:14 TOC8/21/2012 16:07 Ammonia8/21/2012 16:07 Archive8/21/2012 16:07 Grainsize8/21/2012 16:07 Iron & manganese8/21/2012 16:07 Sulfide8/21/2012 16:07 TOC8/21/2012 14:26 Ammonia8/21/2012 14:26 Archive8/21/2012 14:26 Grainsize8/21/2012 14:26 Iron & manganese8/21/2012 14:26 Sulfide8/21/2012 14:26 TOC8/21/2012 13:48 Ammonia

METHODSM4500NH3HNAASTM 0422EPA 6010B/6020EPA 9030BEPA 9060SM4500NH3HNAASTM 0422EPA 6010B/6020EPA 9030BEPA 9060

, SM4500NH3HNAASTM 0422EPA 601OB/6020EPA 9030BEPA 9060SM4500NH3HNAASTM 0422EPA 601 OB/6020EPA 9030BEPA 9060SM4500NH3HNAASTM 0422EPA 601 OB/6020EPA 9030BEPA 9060SM4500NH3HNAASTM 0422EPA 601 OB/6020EPA 9030BEPA 9060SM4500NH3HNAASTM 0422EPA 601 OB/6020EPA 9030BEPA 9060SM4500NH3H

Page 1 of 2

TURN_A CONTAINROUND_ TAT_UN ER_COUTIME IT NT30 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0

SAMPLE_CUSTO

LAB_QC COC_ID DIANNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL -20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dp

Serial_No:09111209:35


MATRIXSESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESESE

FIELD_SAMPLE_IDMC006SG-000015-2012MC006SG-000015-2012MC006SG-000015-2012MC006SG-000015-2012MC006SG-000015-2012NC046SG-000015-2012'NC046SG-000015-2012'NC046SG-000015-2012'NC046SG-000015-2012'NC046SG-000015-2012'NC046SG-0000 15-20 12'NC058SG-000015-2012'

; NC058SG-000015-2012' ;NC058SG-000015-2012'NC058SG-000015-2012'NC058SG-000015-2012'NC058SG-000015-2012'NC059SG-0000 15-20 12'NC059SG-000015-2012'NC059SG-000015-2012'NC059SG-000015-2012'NC059SG-000015-2012'NC059SG-000015-2012'NC071 SG-000015-2012'NC071 SG-000015-2012'NC071 SG-OOOO15-20 12'NC071 SG-000015-2012'NC071 SG-000015-2012'NC071 SG-000015-2012'NC1 059SG-000015-201;NC1 059SG-000015-201;NC 1059SG-0000 15-201:NC1 059SG-000015-201,NC1 059SG-000015-201,

SAMPLE SAMPLE_DATE _TIME TEST_REQUEST8/21/2012 13:48 Archive8/21/2012 13:48 Grainsize8/21/2012 13:48 Iron & manganese8/21/2012 13:48 Sulfide8/21/2012 13:48 TOC8/21/2012 11 :57 Ammonia8/21/2012 11 :57 Archive8/21/2012 11 :57 Grainsiie8/21/2012 11 :57 Iron & manganese8/21/2012 11 :57 Sulfide8/21/2012 11 :57 TOC8/21/2012 11 :33 Ammonia8/21/2012 11:33 Archive8/21/2012 11 :33 Grainsize8/21/2012 11 :33 Iron & manganese8/21/2012 11 :33 Sulfide8/21/201211:33 TOC8/21/2012 11 :06 Ammonia8/21/2012 11 :06 Archive8/21/2012 11 :06 Grainsize8/21/2012 11 :06 Iron & manganese8/21/2012 11 :06 Sulfide8/21/2012 11:06 TOC8/21/2012 10:49 Ammonia8/21/2012 10:49 Archive8/21/2012 10:49 Grainsize8/21/2012 10:49 Iron & manganese8/21/2012 10:49 Sulfide8/21/2012 10:49 TOC8/21/2012 11 :06 Ammonia8/21/2012 11 :06 Grainsize8/21/2012 11 :06 Iron & manganese8/21/2012 11 :06 Sulfide8/21/2012 11 :06 TOC

METHODNAASTM 0422EPA 60108/6020EPA 90308EPA 9060SM4500NH3HNAASTM 0422EPA 60108/6020EPA 90308EPA 9060SM4500NH3HNAASTM 0422EPA 60108/6020EPA 90308EPA 9060SM4500NH3HNAASTM 0422EPA 60108/6020EPA 90308EPA 9060SM4500NH3HNAASTM 0422EPA 60108/6020EPA 90308EPA 9060SM4500NH3HASTM 0422EPA 60108/6020EPA 90308EPA 9060

Page 2 of 2

TURN_A CONTAINROUND_ TAT_UN ER_COUTIME IT NT-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 230 DAYS 130 DAYS 230 DAYS 130 DAYS 0-1; DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 0-1 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 130 DAYS 030 DAYS 130 DAYS 130 DAYS 130 DAYS 1

SAMPLE_CUSTO

LA8_QC COC_ID DIANNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpYES AAL-20120821-163510 dpYES AAL-20120821-163510 dpYES AAL-20120821-163510 dpYES AAL-20120821-163510 dpYES AAL-20120821-163510 dpYES AAL-20120821-163510 dpNO AAL-20120821-163510 dp

; NO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dpNO AAL-20120821-163510 dp

Serial_No:09111209:35


CHAIN OF CUSTODY PAGE1 OF'1 Date Rec'd in Lab:

!-iA.ANALYTICAL

Project Name: Newtown CreekWestborough,MATEL: 508-898-9220

FAX: 508-898-9193

Mansfield,MATEL: 508-822-9300

FAX: 508-822-3288

••..••• ra .1iut:U['

""

.'."IeI.

o FAX

o ADEx

-r:r.mF.ll'i1'i'lll:(:lo

Add'i Deliverables

al.""_.!"I.l.I.

Please provide ANCHOR EQUIS EDD and reference Newtown Creek

Other Project Specific Requirements/CommentslDetection Limits:


Client: Alpha Analytical

Address: 320 Forbes Blvd,Mansfield, MA 02048

Phone: 508-844-4122

Fax: 508-822-3288:,Email: [email protected]

o Thesesampleshavebeenpr~viOUSlyanalyzedbyAlpha

Sample SpecificComments •L1215002-02 1

L1215002-04 1

L1215002-06 1

L1215002-08 1

L1215002-10 1

SAMPLEHANDLINGFiltration

o Doneo Nol Neededo LabIa doPresetVation


L1215002-12

L1215002-14

L1215002-16

L1215002-18

L1215002-20

'~Il~~~"lurryai1:i(;rii;ltj~9~ willnot ,'.". fll!.r1'~~I,.,~nY.¥!Ji9jgUitieSa~~o;;r"S()!,ve(j,A1I.s~,~ples\> :':~u9!"itt.••d,i:I~,,-S,ub~I~'"-Alpha'sPaymenlTeims:' "

0 0 00 0 00 0 00 0 00 0 00 0 00 0 00 0 00 0 00 0 0. . .

. - .

Datemme

Criteria

Received By:

-"ml~'m.tJ=rn-1.RMiI!"ler.l"I::II.l~"[eI::II~:I.}i'.IiI.Are MCPAnalytical Methods Reguired?Are CT RCP (Reasonable Confidence Protocolsl Reauired?

o No

o No

ANALYSIS

DYes

DYes

MCP PRESUMPTIV

State/Fed Prooram

\

I I I I I I I I,

NN"!'I:)

:2I- W(/) I-« «w <..>N ::::iu; Q.

::>z I:)

~ 0Cl a

I I I I I I I

[gI 0 0 0 0 0 0 0 0[gI 0 0 0 0 0 0 0 0[gI 0 0 0 0 0 0 0 0[gI 0 0 0 0 0 0 0 0[gI 0 0 0 0, 0 0 0 0!Xl 0 0 0 0 D 0 0 0[gI 0 0 0 0 0 0 0 0[gI [gI 0- 0 0 0 0 0 0[gI 0 0 0 0 0 0 0 0[gI 0 0 0 0 0 0 0 0

. . .

- I--, .

ished By:

Time:

Sample I Sampler'sMatrix Initials

8/21112 0906 se'diment

8/21/12 0931 sediment

8/21/12 1014 sediment

8/21/12 1049 sediment

8/21/12 1106 sediment

8/21/12 1106 sediment

8/21/12 1133 sediment

8/21/12 1133 sediment

8/21/12 1348 sediment

8/21112 1426 sedimenti

Container Type

• Preservative

Due Date:

ALPHA Quote #.

Turn-Around Time

~ Standard 0 Rush (ONLYIF PRE-APPROVED)

Project Location:

Project#:

Proiect Manaaer: Chris Anderson

Sample ID-

ALPHA Lab ID.-.(L~b'U~'eon!~)A

FORM NO; 01-01(1)(reY.30-JUl-07)

EK002SG-000015-20120821

EK001 SG-000015-20120821

EK010SG-000015-20120821

NC071 SG-000015-20120821

NC059SG-000015-20120821

NC1059SG-000015-20120821

NC058SG-000015-20120821

NC046SG-000015-20120821

MC006SG-000015-20120821

MC002SG-000012-20120821


Serial_No:09111209:35



Sample SpecificComments

SAMPLE HANDLING

Filtrationo Done

o Nol Neededo Lilblodo

Preservation


L1215002-22

L1215002-24

L1215002-26

DYesDYes

ANALYSIS

Time:

NNv0:2I-U)«wN

Sampler'sCi5Z

Initials ~C>

sediment ~ 0 0 0 0 0 0 0 0 0 0 0sediment ~ 0 0 0 0 0 0 0 0 0 0 0sediment ~ 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0.0 0 0 0 0' 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0

Container Type

Preservative

Receive.d By: DaterTime

o Rush (ONLY IF PRE.APPROVED)

1607

1532

15018/21/12

8/21/12

8/21/12

~ Standard

ALPHAQ t #

Due Date:

Project Location:

Pro'ect#:

• ¥. ~ , .' : ' - ~ '" .'. .."

ifurn-Around Time ,,' ."A,~'''',,',

CHAIN OF CUSTODY

Sample 10

EB008SG-000015-20120821

EB006SG-000015-20120821

EK021 SG-000015-20120821

I-iANAlYT1CAL

Please provide ANCHOR EQUIS EDO and reference Newtown Creek

Fax: 508-824-3288

Email: [email protected]

o These samples have been Previously analyzed by Alpha

Other Project Specific Requirements/Comments/Detection Limits:

Address: 320 Forbes Blvd

Mansfield, MA 02048

Phone: 508-844-4122

ALPHALabID;(Lab Use Oilly)'

FORM NO: 01-01(1)(re ••..30-JUL.Qr)



Serial_No:09111209:35



Serial_No:09111209:35


Alpha Summary

Forms

Page 266 of 296

Inorganic Summary Forms

Page 267 of 296

U.S. EPA - CLP

COVER PAGE

Lab Name: Alpha Analytical

Lab Code: AAL SDG No.: L1215002

Client Sample No. Lab Sample ID.EK002SG-000015-20120821 L1215002-01EK001SG-000015-20120821 L1215002-03EK010SG-000015-20120821 L1215002-05NC071SG-000015-20120821 L1215002-07NC059SG-000015-20120821 L1215002-09

NC1059SG-000015-20120821 L1215002-11NC058SG-000015-20120821 L1215002-13NC046SG-000015-20120821 L1215002-15MC006SG-000015-20120821 L1215002-17MC002SG-000012-20120821 L1215002-19EB008SG-000015-20120821 L1215002-21EB006SG-000015-20120821 L1215002-23EK021SG-000015-20120821 L1215002-25

Prep Blank WG557278-1LCS WG557278-2

NC046SG-000015-20120821D WG557278-3NC046SG-000015-20120821S WG557278-4

NC046SG-000015-20120821SER WG557278-5

ICP-AES ICP-MS

Were ICP-AES and ICP-MS interelement Yes/No NA Yescorrections applied?

Yes/No NA YesWere ICP-AES and ICP-MS background correctionsapplied?

If yes-were raw data generated before application of background corrections? Yes/No NA No

Comments:

Page 268 of 296

U.S. EPA - CLP1-IN CLIENT SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET



Matrix (soil/water ): SOIL Lab Sample ID: L1215002-01

Analytical Method: 6020A Date Received: 08/21/12

% Solids: 26.2 Date Analyzed: 8/29/12 9:59

Concentration Units: mg/kg

CAS No. Analyte Concentration C

7429-90-5 Aluminum7440-36-0 Antimony7440-38-2 Arsenic7440-39-3 Barium7440-41-7 Beryllium7440-43-9 Cadmium7440-70-2 Calcium7440-47-3 Chromium7440-48-4 Cobalt7440-50-8 Copper7439-89-6 Iron 343007439-92-1 Lead7439-95-4 Magnesium7439-96-5 Manganese 2197439-97-6 Mercury7439-98-7 Molybdenum7440-02-0 Nickel7440-09-7 Potassium7782-49-2 Selenium7440-22-4 Silver7440-23-5 Sodium7440-24-6 Strontium7440-28-0 Thallium7440-62-2 Vanadium7440-66-6 Zinc7440-31-5 Tin7440-42-8 Boron57-12-5 Cyanide*END*

Comments:

FORM I-IN ILM05.0

EK002SG-000015-20120821

Page 269 of 296











Comments:

FORM I-IN ILM05.0

EK001SG-000015-20120821

Page 270 of 296











Comments:

FORM I-IN ILM05.0

EK010SG-000015-20120821

Page 271 of 296











Comments:

FORM I-IN ILM05.0

NC071SG-000015-20120821

Page 272 of 296











Comments:

FORM I-IN ILM05.0

NC059SG-000015-20120821

Page 273 of 296











Comments:

FORM I-IN ILM05.0

NC1059SG-000015-20120821

Page 274 of 296











Comments:

FORM I-IN ILM05.0

NC058SG-000015-20120821

Page 275 of 296











Comments:

FORM I-IN ILM05.0

NC046SG-000015-20120821

Page 276 of 296











Comments:

FORM I-IN ILM05.0

MC006SG-000015-20120821

Page 277 of 296










7429-90-5 Aluminum7440-36-0 Antimony7440-38-2 Arsenic7440-39-3 Barium7440-41-7 Beryllium7440-43-9 Cadmium7440-70-2 Calcium7440-47-3 Chromium7440-48-4 Cobalt7440-50-8 Copper7439-89-6 Iron 136007439-92-1 Lead7439-95-4 Magnesium7439-96-5 Manganese 97.97439-97-6 Mercury7439-98-7 Molybdenum7440-02-0 Nickel7440-09-7 Potassium7782-49-2 Selenium7440-22-4 Silver7440-23-5 Sodium7440-24-6 Strontium7440-28-0 Thallium7440-62-2 Vanadium7440-66-6 Zinc7440-31-5 Tin7440-42-8 Boron57-12-5 Cyanide*END*

Comments:

FORM I-IN ILM05.0

MC002SG-000012-20120821

Page 278 of 296










7429-90-5 Aluminum7440-36-0 Antimony7440-38-2 Arsenic7440-39-3 Barium7440-41-7 Beryllium7440-43-9 Cadmium7440-70-2 Calcium7440-47-3 Chromium7440-48-4 Cobalt7440-50-8 Copper7439-89-6 Iron 144007439-92-1 Lead7439-95-4 Magnesium7439-96-5 Manganese 71.77439-97-6 Mercury7439-98-7 Molybdenum7440-02-0 Nickel7440-09-7 Potassium7782-49-2 Selenium7440-22-4 Silver7440-23-5 Sodium7440-24-6 Strontium7440-28-0 Thallium7440-62-2 Vanadium7440-66-6 Zinc7440-31-5 Tin7440-42-8 Boron57-12-5 Cyanide*END*

Comments:

FORM I-IN ILM05.0

EB008SG-000015-20120821

Page 279 of 296











Comments:

FORM I-IN ILM05.0

EB006SG-000015-20120821

Page 280 of 296











Comments:

FORM I-IN ILM05.0

EK021SG-000015-20120821

Page 281 of 296

U.S. EPA - CLP2A-IN

INITIAL AND CONTINUING CALIBRATION VERIFICATION



Concentration Units: mg/L

Initial Calibration Continuing Calibration VerificationVerification M

Analyte True Found %R(1) True Found %R(2) Found %R(2)AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIron 5.05 5.324 105 5.05 5.320 105 5.298 105LeadMagnesiumManganese 0.05 0.0511 102 0.05 0.0522 104 0.0517 103MercuryMolybdenumNickelPotassiumSeleniumSilverSodiumStrontiumThalliumVanadiumZincTinBoronCyanide***

(1) ICV Control Limits: Mercury 90-110; Other Metals 90-110; Cyanide 85-115(2) CCV Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115

ILM05.0

Page 282 of 296

U.S. EPA - CLP2A-IN






Analyte True Found %R(1) True Found %R(2) Found %R(2)AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIron 5.05 5.288 105 5.311 105LeadMagnesiumManganese 0.05 0.0518 104 0.0520 104MercuryMolybdenumNickelPotassiumSeleniumSilverSodiumStrontiumThalliumVanadiumZincTinBoronCyanide***


ILM05.0

Page 283 of 296

U.S. EPA - CLP2A-IN






Analyte True Found %R(1) True Found %R(2) Found %R(2)AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIron 5.05 5.118 101 5.218 103LeadMagnesiumManganese 0.05 0.0503 101 0.0504 101MercuryMolybdenumNickelPotassiumSeleniumSilverSodiumStrontiumThalliumVanadiumZincTinBoronCyanide***


ILM05.0

Page 284 of 296

U.S. EPA - CLP3-IN

BLANKS



Preparation Blank Matrix (soil/water): SOIL

Preparation Blank Concentration Units: mg/kg

InitialCalibration Continuing Calibration PreparationBlank(mg/L) Blank (mg/L) Blank

Analyte C 1 C 2 C 3 C C MAluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIron 0.020612 U 0.020612 U 0.020612 U 0.020612 U 2.39 JLeadMagnesiumManganese 0.000445 U 0.000445 U 0.000445 U 0.000445 U 0.045 UMercuryMolybdenumNickelPotassiumSeleniumSilverSodiumStrontiumThalliumVanadiumZincTinBoronCyanide***

FORM III - IN ILM05.0

Page 285 of 296

U.S. EPA - CLP3-IN

BLANKS



Preparation Blank Matrix (soil/water): SOIL

Preparation Blank Concentration Units:

InitialCalibration Continuing Calibration PreparationBlank(mg/L) Blank (mg/L) Blank

Analyte C 1 C 2 C 3 C C MAluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIron 0.020612 U 0.020612 U 0.020612 ULeadMagnesiumManganese 0.000445 U 0.000445 U 0.000445 UMercuryMolybdenumNickelPotassiumSeleniumSilverSodiumStrontiumThalliumVanadiumZincTinBoronCyanide***

FORM III - IN ILM05.0

Page 286 of 296

U.S. EPA - CLP4A-IN

ICP-AES INTERFERENCE CHECK SAMPLE



ICP-AES Instrument ID: ICPMS2

Concentration Units: mg/l

True Initial Found Final FoundSol. Sol. Sol. Sol. Sol. Sol.

Analyte A AB A %R AB %R A %R AB %R

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIron 250.0 250.0 248.20771 99 246.84223 99LeadMagnesiumManganese 0.1 0.0035564 0.1048574 105MercuryMolybdenumNickelPotassiumSeleniumSilverSodiumStrontiumThalliumVanadiumZincTinBoron***

FORM IVA - IN ILM05.0

Page 287 of 296

U.S. EPA - CLP5A-IN EPA SAMPLE NO.

MATRIX SPIKE SAMPLE RECOVERY



Matrix (soil/water): SOIL

% Solids for Sample: 28.1


Control Spiked Sample Sample SpikeAnalyte Limit Result (SSR) Result (SR) Added (SA)

%R C C %RAluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIron 75-125 42000 38700 1710 193LeadMagnesiumManganese 75-125 842. 468 342.0 109MercuryMolybdenumNickelPotassiumSeleniumSilverSodiumStrontiumThalliumVanadiumZincTinBoronCyanide

Comments:

FORM VA -IN ILM05.0

NC046SG-000015-20120821S

Page 288 of 296

U.S. EPA - CLP6-IN EPA SAMPLE NO.

DUPLICATES


Lab Code: AAL Case No.:


% Solids for Sample: 28.1 % Solids for Duplicate: 28.1


Control Sample (S) Duplicate (D)Analyte Limit C C RPD

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIron 20 38700 40400 4LeadMagnesiumManganese 20 468 488. 4MercuryMolybdenumNickelPotassiumSeleniumSilverSodiumStrontiumThalliumVanadiumZincTinBoronCyanide

FORM VI - IN ILM05.0

NC046SG-000015-20120821D

Page 289 of 296

U.S. EPA - CLP7-IN

LABORATORY CONTROL SAMPLE


Lab Code: AAL SDG No.: L1215002SOIL

Aqueous (mg/L) Solid (mg/kg)Analyte True Found %R Limits True Found C Limits %R

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIron 1000 1140 75-125 114LeadMagnesiumManganese 200 226. 75-125 113MercuryMolybdenumNickelPotassiumSeleniumSilverSodiumStrontiumThalliumVanadiumZincTinBoronCyanide

FORM VII - IN ILM05.0

Page 290 of 296

U.S. EPA - CLP8-IN EPA SAMPLE NO.

ICP-AES AND ICP-MS SERIAL DILUTIONS

Lab Name: Alpha Analytical SDG No.: L1215002

Lab Code: AAL


Concentration Units: mg/Kg

Serial %Initial Sample Dilution Difference

Analyte Result (I) C Result (S) C Q M

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIron 38700 38900 1LeadMagnesiumManganese 468. 462. 1MercuryMolybdenumNickelPotassiumSeleniumSilverSodiumStrontiumThalliumVanadiumZincTinBoronCyanide

FORM VIII-IN ILM05.0

NC046SG-000015-20120821SER

Page 291 of 296

U.S. EPA - CLP12-IN

PREPARATION LOG



Preparation Method: EPA 3050B

EPASample Preparation Weight VolumeNo. Date (gram) (mL)

L1215002-01 08/27/12 2.080 50L1215002-03 08/27/12 2.050 50L1215002-05 08/27/12 2.030 50L1215002-07 08/27/12 2.010 50L1215002-09 08/27/12 2.070 50L1215002-11 08/27/12 2.070 50L1215002-13 08/27/12 2.120 50L1215002-15 08/27/12 2.130 50L1215002-17 08/27/12 2.060 50L1215002-19 08/27/12 2.130 50L1215002-21 08/27/12 2.040 50L1215002-23 08/27/12 2.120 50L1215002-25 08/27/12 2.160 50WG557278-1 08/27/12 1.000 50WG557278-2 08/27/12 1.000 50WG557278-3 08/27/12 2.020 50WG557278-4 08/27/12 2.080 50WG557278-5 08/27/12 2.130 50

FORM XII-IN ILM05.0

Page 292 of 296

U.S. EPA - CLP13-IN

Analysis Run Log



Instrument ID: ICPMS2 Analysis Method: 6020A

Start Date: 08/29/12 End Date: 08/29/12

AnalytesLab

Sample D/F Time A S A B B C C C C C F P M M H M N K S A N S T V Z SID L B S A E D A R O U E B G N G O I E G A R L N N

A1-ICV 1 9:31 X XA1-ICB 1 9:32 X XA1-ICSA 1 9:34 X XA1-ICSAB 1 9:35 X XA1-CCV 1 9:41 X XA1-CCB 1 9:42 X XA1-CCV 1 9:52 X XA1-CCB 1 9:53 X XWG557278-1 2 9:57 X XWG557278-2 2 9:58 X XL1215002-01 20 9:59 X XL1215002-03 20 10:00 X XL1215002-05 20 10:01 X XL1215002-07 20 10:02 X XA1-CCV 1 10:03 X XA1-CCB 1 10:03 X XL1215002-09 20 10:05 X XL1215002-11 20 10:06 X XL1215002-13 20 10:07 X XL1215002-15 20 10:08 X XWG557278-3 20 10:09 X XWG557278-5 100 10:09 X XWG557278-4 20 10:10 X XL1215002-17 20 10:11 X XL1215002-19 20 10:12 X XL1215002-21 20 10:13 X XA1-CCV 1 10:14 X XL1215002-23 20 10:15 X XA1-CCB 1 10:15 X XL1215002-25 20 10:16 X XA1-CCV 1 10:24 X XA1-CCB 1 10:25 X X

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U.S. EPA - CLP13-IN

Analysis Run Log



Instrument ID: ICPMS2 Analysis Method: 6020A

Start Date: 08/29/12 End Date: 08/29/12

AnalytesLab

Sample D/F Time A S A B B C C C C C F P M M H M N K S A N S T V Z SID L B S A E D A R O U E B G N G O I E G A R L N N

A1-CCV 1 10:31 X XA1-CCB 1 10:32 X X

FORM XIII-IN ILM02.0

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U.S. EPA - CLP14-IN

ICP-MS TUNE



ICP-MS Instrument ICPMS Date: 08/29/12

Element - MassAvg. Measured Mass (amu) Avg. Peak Width at10% Peak Height (amu)

%RSD

9Be 8.975 0.724 0.87259Co 58.975 0.697 0.907115In 114.875 0.676 0.845205Tl 205.025 0.733 0.719238U 238.125 0.717 0.565

Comments:

FORM XIV-IN ILM05.0

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U.S. EPA - CLP15-IN

ICP-MS Internal Standards Relative Intensity Summary

Lab Name: Alpha Analytical SDG No.: L1215002

Lab Code: AAL

ICP Instrument ID: ICPMS2 Start Date: 8/29/2012 End Date: 8/29/2012

EPA Sample Time Internal Standards %RI For:

No. Lithium Q Scandium Q Germanium Q Indium Q Bismuth Q Q

ICV 9:31 101

ICB 9:32 101

ICSA 9:34 77

ICSAB 9:35 76

CCV 9:41 101

CCB 9:42 101

CCV 9:52 102

CCB 9:53 103

WG557278-1 9:57 104

WG557278-2 9:58 99

L1215002-01 9:59 102

L1215002-03 10:00 103

L1215002-05 10:01 102

L1215002-07 10:02 102

CCV 10:03 102

CCB 10:03 102

L1215002-09 10:05 101

L1215002-11 10:06 102

L1215002-13 10:07 101

L1215002-15 10:08 101

WG557278-3 10:09 101

WG557278-5 10:09 103

WG557278-4 10:10 102

L1215002-17 10:11 104

L1215002-19 10:12 102

L1215002-21 10:13 103

CCV 10:14 102

L1215002-23 10:15 104

CCB 10:15 102

L1215002-25 10:16 104

CCV 10:24 105

CCB 10:25 105

CCV 10:31 102

CCB 10:32 102

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Documents

Alpha Analytical Deliverable Packagenewtowncreek.info/docs2/2 Remedial Investigation/Phase 1...Alpha Analytical Deliverable Package Alpha SDG: L1215002 Client: Anchor QEA, LLC Site: