Bakery FLour

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    We start with Wheat flour.

    Wheat flour is the major ingredient used in manufacturing products . It directly affects

    Profitability & performance of the product and the units. The performance of the raw

    material is related to the various constituents in the wheat flour which play a major role

    and go under various chemical, physical and microbiological changes during

    processing. Good quality wheat flour helps to manufacture standard and consistent

    quality product constantly and is directly responsible to the product yield and cost. It is

    because all the constituents of wheat flour are responsible to achieve excellent quality

    product, hence it becomes important for all of us to understand the contribution of

    wheat and wheat flour in general so as be able to implement the same to control the

    product manufacture and production process.

    Wheat grain consists of :

    Bran

    Endosperm

    Germ

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    Chemical Composition of Three Major Constituents of WHEAT

    1. BranProtein 15-18 %

    Fat 4-5%

    Carbohydrate 61-73%

    Fibre 2-13%

    Ash 3-6.3%

    2. Germ

    Moisture 9.2%

    Protein 28.9%

    Crude Fiber 2.1%

    Fat 9.7%

    Mineral Water 4.1%

    Carbohydrate 46.0%

    3. Endosperm

    Moisture 14.0%

    Proteins 9.6%

    Fat 1.4%

    Ash 0.7%

    Carbohydrate 74.3%

    ( Starch - 71.2

    Hemicellulose - 1.8

    Sugar - 1.1

    Cellulose - 0.2

    Total Carbon hydrate - 74.3)

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    The Wheat composition consists of average composition of all these constituents.

    Approximate composition of wheat : Moisture 9-18%Starch 60-68%

    Proteins 815%

    Cellulose 2-2.5%

    Fat 1.52%

    Sugar 2-3%

    Ash 1.52%

    The wheat flour which is used for manufacture of various bakery products mainly

    constitute of the endosperm.

    To understand bakery operation in relation to the constitution of the wheat flour, there

    are too major elements viz starch and Gluten (Protein) which affect the quality and yield

    in bakery operation. It is important to understand the chemical composition and their all

    level effects in the processing.

    The profitability of flour mills is dependant upon the extraction rate. High extraction

    provides better contribution and thereby increases overall profitability. Higher extraction

    produces wheat flour of poor quality and also varies in the composition. It effects the

    gluten quality. Higher extraction rates always damage the starch molecules. The

    variation in composition due to extraction rate is shown below :

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    Wheat Flour

    72% Extraction 80% Extraction

    Moisture 13-15.5 13-15

    Starch 65-70 64-69

    Protein 8-13 914

    Cellulose 0-0.2 0.20.35

    Fat 1.5-2.0 1.5-2.0

    Miral Ash 0.3-0.6 0.6-0.8

    Carbohydrate

    Starch consists of Amylose and amylopectin. Amylose constitutes 23%and consists of

    straight unbranched chain of glucose 1 : 4 gulcosidic linkage. White amylopectin

    consists of highly branched short glucose chains.

    The significant point here is that these compounds react differently to enzymic

    (diastatic) attacks.

    The analysis converts straight chain to maltose but is unable to attack amylopectin

    beyond the branch point.

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    The analyses however can attack linkage at branch point and once this is done

    amylose can act on amylose and produce maltose with residue from amylopectin

    position as dextrin

    When amylose attack starch , dextrin (gummy) are formed from amylopectin and

    these are compounds which are harmful during bread manufacture the formation of

    dextrin makes the product clammy and sticky. During this reaction process , maltose is

    produced. There has always been correlation between the amount of dextrin and

    maltose. If one is able to estimate the percentage of maltose it would be possible to

    derive the extent of starch damage that has taken place and in due course the quantity

    of dextrin produced.

    There are several methods for the estimation of maltose (which is one of the by

    products of anylase reaction. This subjects has always been a very interesting aspect

    of cereal chemistry . Rumsey develop a method of estimation and value was

    represented as maltose figure. The autolysed flour at fixed time at 620C after which a

    separate meter reading was obtained.

    Better physical methods were developed to understand the reaction of amylose

    on wheat starch. Various equipment were developed and one of the most

    important techniques presently used is Amylograph.

    The process is described below:

    The mixture is mixed at 75 rpm. The material is heated through bath by increasing

    temperature at the rate of 1.5 0C per minute. The shaft operate at the upper end of pen

    that records the changes in viscosity .

    To 50- 80gm flour add 450ml water in smooth suspension.

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    The temperature is allowed to increase to 950C and is held constant and apparatus is

    allowed for an hour. The graph is recorded as a line at which it runs parallel tohorizontal axis but at 700 C starts to rise reaching as peak between 880C to 950C usually

    after 45 to 50 mt. Lower peak shows addition of amylase or excess.

    Baking Viscosity Diastatic activity of maltose Maltose

    Per 10 gm

    Very Poor 150 540 3.5

    Fair 315 395

    Good 442 -547 365 352

    Very Good 763 1000+ 275 85 5.5

    The other method adopted nowadays is Falling No. in milling industry

    The sample of wheat is grounded is allowed to pass through 0.8mm screen. The 7 gm

    of flour is mixed with 25 ml. of water in a tube provided with 20 to 30 shakes. The test

    tube with a stirrer in position is immediately immersed in a lively boiling water bath. The

    contents remain in bath for 60 sec. The stirrer is then raised on top and allowed to drop

    by its own weight to a fixed depth. The time taken for the stirrer to drop is called falling

    No.

    Sprouted wheat would have : Falling No. 150 -300

    This provides indication of amylose activity with liquefaction No.

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    Liquefaction No. 6000

    Falling No. -50 ( Although starch is insoluble in water the granulesswell in hot water and eventually burst. The effect is known a gelatinization of starch.

    During the milling process the starch gets damaged due heat produced from rollers

    during grinding as it is sheared and crushed between roller. A large amount of water

    added which is around 50% or more in the mix is largely consumed by gluten and small

    quantity is utilized by starch, which starts swelling. The top of the bread shows

    preponderances of starch granules that are swollen. This represents first order

    gelatinization. The inside of the loaf has temperature never more that 95 deg Celsius

    and water is limited and the gelatinization is not complete.

    High viscosity of starch is associated with low volume of baked loaf.

    Protein

    An Organic Compound where in amino acids are linked together.

    Amino acetic acid CH2 (NH2)COOH

    Amino group COOH (Carbonlic group).

    Protein Composition of wheat flour

    Carbon 50-55%

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    Hydrogen 6.5-7.5%

    Nitrogen 15- 9%

    Oxygen 22-27%Sulphur 0-3.5%

    Protein in wheat flour is a combination of the following:

    Albumin

    Globulin

    Protease

    Prolamin ( Glidnin)

    Glutelin (glutenin)

    The first three are insignificant because of their quantities in wheat flour are

    approximately 1.7 %. The other two protein are commonly known as gluten and Glidnin

    . Glutenin gives solidity and gliadnin imparts softness. The estimation of

    extensity/strechability and strength is estimated by various techniques as below:

    1) Alveograph

    2.5 % salt solution for making dough at 250C - weigh 250 gm start mixer carefully add

    calculated qty of salt water taking approximately 15 sec. Allow mixing to proceed for 7

    minutes. Stop mixer, raise the shutter A. Extrude the dough cut into four piece . Place

    the dough in tempering compartment . Relax for 20 min. If a bubble is created, the

    recording monometer should watch the bubble as it punctures.

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    Area is measured by Planimeter provides strength of the dough

    P = Height of peak is measured in mm stabilityL = MM gives stretching ability

    Stability 45 90

    Strength 20 75

    Condition Wheat stability 90

    Strength 70 -75

    Sticky body is responsible for binding. The bran and germane richer in protein contact. It

    is quality of gluten rather than quantity that influences baking quality. The quality of

    gluten depends upon chiefly the collidal state of protein.

    P

    L

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    A= Dough Consistency B = Dough Development

    D= Elasticity C = Dough Stability

    B

    ED

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    E= Weakening of dough

    Quality Of flour

    a) There must be sufficient sugar and enough diastatic activity to produce reserve

    sugar during fermentation to ensure continuous sufficiency of gas to distant the

    dough

    b) Protein must be sufficient in quality to hold sufficient gas

    c) The dough must be ripe at the time of baking.

    BA

    C

    Tension D Proportional No

    D = B/C

    Time Seconds

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    Fat and lipids

    The whole grain contain 2% rather under 4% fat

    The oil is present in germ contain : Oleic = 30.0

    Linoleic = 44 %

    Linolenic = 10%

    Other saturated = 13 14%

    Germ oil acidity is very important it is responsible for the oxidation of the product. It is

    always necessary to check the germoil acidity on a regular basis. It has been observed

    that more than 20 units is not an acceptable quality for manufacture of biscuits and

    baked varieties.

    The lipids in flour affect both formation of dough as it is influenced by the gluten and

    also a method to understand the gluten quality and water absorption.

    Sugar and Dextrin

    Dextrin are responsible to glaze the side / Top of the bread. Excessive dextrin causes

    heaviness, stickiness in curb which is noticeable with amylose process.

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    Standards of white flour

    Moisture Ash Protein PH fat maltose Gluten %

    min.14 0.65 10.5 6.0 -6.8 1.5 250 8

    Other ingredients

    Other important ingredients used in baking operation is yeast which help in proofing the

    to the required size and volume . It is important to understand the quality of yeast used

    in manufacturing process. The yeast which is commonly used in bakery operation is

    called SACCHAROMYCES CEREVISIAE (YEAST).

    Saccharomyces Cerevisiae

    Dry matter basis - 52% Protein

    2% Fat

    8 9 %mineral matter

    30% glycogen

    Yeast is also used a leavening. Yeast converts fermentable sugars such as maltose,

    glucose, fructose and sucrose into CO2and alcohol. Yeast is a living organism and its

    activity can be influenced by storage practices, dough temperature and PH, availability

    of water and food supply. Out of these control points, the most important is temperature.

    Yeast is available in two forms: Compressed yeast

    Dried yeast

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    The compressed yeast needs to be stored at refrigerated conditions. Active dry yeast

    must be pre hydrated 5-to 15 mins before adding to dough at 95 110oF water. Instant

    Dry yeast can be added directly without pre-hydrating.

    Average quantity requirements : 1.5 lb 280. lb per sack

    4 lb per sack

    Addition Salt

    The fermentation by yeast depends on Quality flour and process parameters used in

    manufacturing. It has been observed that good quality of flour shows an over jump of

    approximately 1.7cm. This is achieved by ability to produce co2while entering the oven

    and gluten able to extend to encompass the gas which qualified as over jump.

    These are various method for manufacture of bread and commonly used are sponge

    and dough and straight dough methods. Sponge and dough process is commonly used

    in Europe, straight dough process has been adopted as common manufacturing

    process. Both these processes have advantages and disadvantage and produce quality

    bread . In American countries sliced bread and soft buns are mostly consumed hence

    the adoption of soft spong process allows them to achieve better texture for soft bread.

    In the European market French bread, Italian bread etc are available from straight

    dough method. Bread obtained by such a method provides quality bread and shows

    better performance.

    The spong dough process is carried out by using half of the flour in formation process

    and half the flour is later added to achieve complete dough. While as in straight dough

    method all ingredients are mixed at one time and dough is straight taken for

    manufacturing process

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    In the spong dough process the flour quality has to be good otherwise during

    fermentation process amylose activity is likely produce more dextrin. So if the quality

    of starch is poor it is always recommended to use straight dough process formanufacture of bread/ bun etc.

    For soft flour some oxidsing and reducing agents have been recommended. Oxidsing

    agents help to achieve good volume and provide strength to the flour while reducing

    agents help gluten to achieve the ability to extend / stretch by breaking down the protein

    structure.

    Oxidizing agents - Ascorbic acid. KBro3

    Reducing agents - Lcystenien Hydrochloride

    SSL Strength

    Ethoxylated monoglyciride

    SH

    SH

    SH Free oxygen by

    O KBro3SH

    S

    S

    Di Sulphide

    bands

    O

    H

    H

    SH

    SH

    SH

    ADA

    H

    ADA

    H

    S

    S

    Di Sulphide

    bands

    OXIDIZING AGENTS

    DehyoAscorbicacid

    KBo3

    SH

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    There are many theories on how oxidizing agents work. We know that oxiding agents

    strengthen the dough. Oxidizing agents have the ability to form disulphide band which

    like protein, chain together. It also allows the dough to recover from mixing faster. This

    may be due to disulphidethiol interchange. Another theory suggests that oxidizing

    agents promote protein aggregation through ionic and hydrogen bonding. When dough

    is under oxidized the dough tends to be over sticky and with poor gas retention

    properties. A dough that is over oxidized will be too tight and stiff and the resulting

    product usually is low in volume( except for over usage of ascorbic acid and KBro3 ) and

    grain is dense with holes.

    Our strategy is to give longer fermentation time. As the fermentationt time increases, the

    oxidation requirements are reduced. Another strategy is to reduce proofing temperature.

    The only problem in reducing the proofing temperature is , it extends the proofing time.

    This can be overcome by adding additional quantities of yeast.

    The oxidizing agents: Strengthens dough structure by creating bond between

    proteinsImproves dough handling

    Increases product volume

    Produces tigular grain

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    S

    S

    HS-X

    REDUCING AGENTS

    Free L-cystine

    S

    S

    SH

    S-S-X

    Disulphide

    bands

    Break band between protein chain

    Reducing Agents :

    Wakens dough structure by breaking

    bonds between proteins

    Allows shorter mixing time

    Improves machine reliability

    HS X

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    Mai Lard reaction/ broconing 121/350

    Alpha Amylose

    Starch Gelitinization

    Slow

    Begins starch geletinization

    Protien

    Thermal death point of yeast

    CO2liberated expanding cell

    Mixing Makeup Proofing baking Cooling

    200

    180

    160

    140

    120

    100

    80

    93oC

    79-80o

    60

    49o

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    Some of the reducing agents and emulsifiers performance in bakery operations

    Strength Soft

    SSL (0.5%) +++ +++ Sodium stearoyl Lactate

    CSL(0.5) +++ ++ Calcium stearoyl lactate

    DATEM ++ + Diacetlge Tartrate ESTER of

    EMG (0.5) +++ - Ethoxylated Monoglycicle

    SE +++ 0 Sucrose Ester

    Poly60 (0.5) +++ 0 Prysorbate 60

    SMG + ++ succinylated Mono glyoxide

    Hardamono - +++ Hard monoglycode

    Soft Mono - +++ Soft Monoglyonde.

    The reducing agents reacts during the mixing cycle and has infinite and limited reaction.

    It should always be balanced with oxidizing agents. It helps to achieve proper mixing

    and flour time.

    Usage in rays for same important Ascobric acid 100200 ppm

    Cystaine 10-90 ppm

    Sodium bisulphate (bakery) 20- 100 mm

    (Pie, crackers)

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    Dough strengtheners/ Crumb softenersare also called emulsifiers or surface active

    agents or surfacetants. They help to change surface tension. These emulsifiers haveboth strengthening and softening effect upon the product. The most common softeners

    are mono and triglycerides. They also help to increase shelf life. For breads, we need

    hard monoglycerides and for cakes we need soft monoglycerides are used. The

    percentage of alpha alpha monoglycerides is important as it has better dispersibility.

    Softeners flows down starch retrogradation thereby inhibiting the staling process. It also

    slows moisture migration and improves moistures retention.

    In manufacturing process several bread softness have been used. This help to develop

    the linkage with starch molecules and also provide help in retaining better moisture

    which in togetherness give rise to very soft brand.

    The Common Softners - Monoglycerides, starch glycerids

    During baking process the flour and other constituents go under various changes. It is

    important to understand these changes so as to be able take appropriate steps to

    achieve better quality products.

    The flour will affect the handling qualities of dough and all the quality factors that will be

    evaluated in the product.

    Water : The second largest ingredient in bakery operation is water. The main function is

    hyderation. Gluten must be hydrated and for gelatinization of starch water is essential .

    It also serves as dispersing agent and a medium for fermentation. Water is used to

    control dough temperature. The total level of water in a bread dough is normally in the

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    range of 55 to 65%. Water is the best cereal softener. Higher quantity of water can

    dilute an otherwise good product.

    Salt : The main function of salt is to bring out the flavor of the baked product. Its usage

    levels range from 1.75to2.25%. Bread made out of 1.75% of salt, tastes bland and

    bread made out of 2.25% of salt tastes very brackish. Salt also inhibits fermentation due

    to osmatic pressure effect and it also toughens gluten . Salt lengthens mixing time.

    Therefore addition of salt should be delayed to have proper mixing.

    Bacterial analyses (180)0F Temperature at which these enzymes get

    destroyed in baking operation

    Fungal at (150)0F

    (Cereal amylose) 1700F

    In baking operation other than mixing other parameters like proof time, weight loss, P,

    are responsible for loaf volume. Tables are provided to explain the correlation o these

    parameter which is self-explanatory.

    Effect of proofing Temperature on proof time loaf volume

    Temp OC Time (min) Volume Lb

    Ml

    21.1 120 2200

    30.0 60 2280

    35.0 50 2270

    40.0 47 2290

    46.1 41 2260

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    Effect of proofing time on loaf volume PH of bread and loss of weight in baking.

    Proof line Volume lb PH of Bread Loss in baking (g)

    of bread

    (ml)

    0 1270 5.49 46

    15 1610 5.46 52

    30 1980 5.41 61

    60 2640 5.34 72

    75 2780 5.31 73

    90 3030 5.26 80

    120 3550 5.16 88

    150 4090 5.13 89

    Effect of humidity during proofing on proof time , loaf volume and yield.

    RH Proof Loss in Volume / lb

    % Time Proofing + of bread

    (min) Baking

    35 57 74 2230

    50 52 72 2320

    60 54 71 2230

    80 49 64 2150

    90 46 64 2270

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    Average Proof condition

    Straight dough dry bulbs wet bulb RH

    F C

    100 - 110 37.8-43.3 5-8 2.8-4.5 75 -80

    Continuous Process 115 -120 46.1 48.9 3-5 1.7 -2.8 80 -90

    Correlation between time and Temperature is shown to help bakers to achieve better

    product quality.

    !

    " ! 0 5 10 15 20

    210

    170

    150

    Rigid roll

    225oF

    200 oF

    275 oF

    280oF

    250 oF

    1 23

    4

    5

    # $

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    Some of the bread rolls characteristics are presented below to draw our attention to

    their uniqueness..

    Hard Rolls : American Hard

    Jewish

    Kaiser or crown rolls

    Italian or French

    All are made almost from same type of dough . the dough is left until is light enough to

    be flattened by Shimmy Machine

    Flour Water Yeast KBro3 Diastatic moulten

    60 33 36 2 -3 -0.0375 0-2

    Italian Bread : Lean Formula

    (Normal Composition Flour, Water, yeast, salt, V. less sugar)

    Incorporate Old Dough. Proof bread is provided with smell certs. To appear shell like

    bread different shapes, twist S, must have hard, thick crust with dry crumb. Sometimes

    the bread is proofed in oven so that it will be crusted when it goes to oven thus

    producing heavier crust on the baked loaf.

    French Bread : Made from old fermented dough, it is thick, hard crust

    and characteristic taste. Fermentation line 3/4 to 1 1/2hrs. Molding should be tight with

    tight skin without tearing. Gain character is open. Proofing should be just to the point

    where it will receive cut and open slightly not over proofed should be baked with low

    pressure steam. Steam should be left in the oven for sometime (5mt.) No definite temp

    and time of baking is recommended. slow baking produces better results.

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    Bread Faults

    Deviations from the normal bread quality standards, whether perceived subjectively or

    determined by objective measurements, are designed by the collective terms bread

    faults. They arise from two principal sources : inferior ingredients and improper

    processing. in many instances bread faults result from a combination of various factors

    so that it is more convenient to classify them into broad categories and indicate the

    possible causes that may be involved in each.

    Pelshenke has made the very succinct observation that every bakery encounters as

    many bread faults as it deserves. This implies that bread faults can be held to a

    minimum by paying close attention to the quality of the ingredients and by accurate

    control of the production process. It is often quite difficult to the correct diagnose the

    immediate cause of a given bread fault and to apply the appropriate remedial action.

    However , bread faults will manifest themselves less frequently and their effect will

    generally be less serve if an adequate quality control program is adopted and effectively

    implemented .Adequate

    Quality assurance implies that proper steps are taken at all times to ensure that only

    ingredients of satisfactory quality are used, that errors in formulation are avoided, that

    proper environmental conditions are consistently maintained. That proper time

    temperature and humidity requirements are satisfied without fail at all stages of dough

    processing and baking , and that the equipment us maintained in optional operating

    condition at all times.

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    The table below is a list broad classes of common bread faults, together with their

    probable causes.

    Bread Faults

    External Faults

    Lack of Loaf Volume

    Immature or green Flour

    Wrong type of flour.

    Insufficient absorption

    Insufficient Yeast

    Poor quality or mishandled yeast.

    Excess salt

    Excessive diastatic activity

    Lack of shortening

    Improper mixing over or under termented dough

    Over mentioned or under fermented dough

    Dough temperature too low.Insufficient pan proof.

    Insufficient dough weigh for size

    Hot Oven

    Excessive Loaf Volume

    Overaged Dough

    Insufficient salt

    Over proofing

    Overscaling for pan size

    Cool oven

    Pale crust colour

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    Insufficient residual sugar

    Deficiency in diastatics activity

    Excessive mineral yeast food.Fermentation temperature too high

    Old dough

    Insufficient humidity in final proof

    Cool oven

    Low top heat in oven

    Under baking

    Dark Crush Colour

    Excessive sugar in formula

    Immature milk Products in formula

    Excessive milk products in formula

    Hot oven

    High top heat in oven

    Over baking

    Blisters Under Crust

    Undermixing

    Young dough

    Careless moulding

    Excessive steam in final proof

    Over proofing

    Rough handling at oven

    Excessive oven steam ( condensation)

    Excessive vacuum at depanner (separation)

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    Thick Crust

    Insufficient sugar and shortening in formulaInsufficient milk in formula

    Deficient diastatic activity

    Old Dough

    Insufficient humidity in final proof

    Low oven temperature

    Over baking

    Shell Tops

    Immature Flour

    Deficient diastatics activity

    Inadequate oxidation

    Young dough

    Insufficient humidity in final proof

    Too tight moulding (low pressure board)

    Excessive to heat in oven

    Insufficient Oven

    Wild Break and Shred

    Slightly overaged dough

    Overmixing

    Inadequate oxidation

    Insufficient STEAM IN OVEN

    Improper moulding (low Pressure Board)

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    Absences of break and ShredWeak Flour

    Undermixing

    Excessively diastatic activity

    Over oxidation

    Excessive final proof

    Excessively hot Oven

    Internal Faults

    Gray Dull Crumb Color

    Excessive diastatics

    Overmixing or undermixing

    Young Dough (round , thick, cells)

    Old dough (open Cell structure)

    Improper sheeting and moulding

    Underweight dough for pan size.

    Excessive proof

    Low oven temperature

    Streaked Crumb

    Improper dough mixing

    Excessive dusting flour.

    Too much trough grease or divider oil.

    Insufficient shortening

    Dough crushing during termination and final proof

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    Improper use of rework doughExcessive pan grease

    Poor Gain

    Weak flour

    Overly stiff dough

    Overly slack dough

    Overmixing

    Young dough

    Improper moulding

    Insufficient dough weight for pan size

    Low oven temperatures

    Poor Texture :

    Overly stiff dough

    Improper mixing

    Excessive diastatic activity

    Insufficient Shortening

    Old Dough

    Crushing of sponge or dough fermentation

    Crushing of sponge or dough during fermentation

    Over Proofing

    Insufficient dough weigh for pan size

    Low over heat.

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    Holes in breads

    Immature or weak flour

    Unbalanced formulaImproper mixing either over or under mixed

    Old dough, young dough

    Crusting of sponge or dough during fermentation

    Excessive dusting four or divider oil.

    Improper moulding

    High final proof temperature

    Insufficient Oven steam

    Poor Flavor

    Poor quality ingredients

    Improper storage of ingredients

    Unbalanced formula

    Insufficient salt

    Old dough , young dough

    Insanitary plant conditions

    Old trough and pan grease

    Over or underbaking

    Poor Keeping Quality

    Unbalanced formula

    Lean formula

    Poor quality ingredients

    Improper mixing

    Overfermentation

    Under proofing

    Low oven temperature

    Excessive cooling before wrapping.