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1 ELECTRO CHEMISTRY MOHD.ILIAS MOHD.ILIAS@5572131 12-D/2015 Write the Applications of Kohlrausch law To calculate Λºm for a weak and strong electrolyte from the λ o of individual ions. a) For strong electrolytes like NaCl, ΛºNaCl = λºNa + + λº Cl b) For weak electrolytes it can be be obtained by the knowledge of limiting molar conductivity of some strong electrolytes Λº CH3COOH = Λº CH3COONa + Λº HCl - Λº NaCl ΛºNH4OH = Λº NH4Cl + Λº NaOH - Λº NaCl Λº H2O = Λº HCl + Λº NaOH - Λº NaCl To calculate the degree of dissociation of weak electrolyte α: To determine the value of the dissociation constant for weak electrolyte (ka) Numerical : 1 .

Batteries 12d

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  • 1

    ELECTRO CHEMISTRY MOHD.ILIAS

    MOHD.ILIAS@5572131 12-D/2015

    Write the Applications of Kohlrausch law

    To calculate m for a weak and strong electrolyte from the o of individual ions. a) For strong electrolytes like NaCl, NaCl = Na+ + Cl b) For weak electrolytes it can be be obtained by the knowledge of limiting molar conductivity of some strong

    electrolytes CH3COOH = CH3COONa + HCl - NaCl

    NH4OH = NH4Cl + NaOH - NaCl

    H2O = HCl + NaOH - NaCl

    To calculate the degree of dissociation of weak electrolyte :

    To determine the value of the dissociation constant for weak electrolyte (ka)

    Numerical :

    1.

  • 2

    ELECTRO CHEMISTRY MOHD.ILIAS

    MOHD.ILIAS@5572131 12-D/2015

    Batteries :

    What is primary batteries ?

    What are secondary cells?

  • 3

    ELECTRO CHEMISTRY MOHD.ILIAS

    MOHD.ILIAS@5572131 12-D/2015

    Ex: Lead storage batteries and nickel cadmium batteries :

    Explain dry cell (leclanchcell)

    Anode Zinc container

    Cathode Carbon rod surrounded by carbon and MnO2

    electrolyte Moist paste of NH4Cl and ZnCl2

    Cell reactions

    anode

    cathode

    Why dry cell cant be recharged and have definite life?

    Explain Mercury cell/ cell used in hearing aids :

    Why mercury cell gives constant voltage?

  • 4

    ELECTRO CHEMISTRY MOHD.ILIAS

    MOHD.ILIAS@5572131 12-D/2015

    Explain lead storage battery

    Anode

    Cathode

    electrolyte

    anode

    cathode

    overall

    Write the cell reactions of lead storage cell when recharging?

    Write the overall reaction of Nickel Cadmium storage cell and explain advantage and disadvantage of it?

    What is fuel cell ?

  • 5

    ELECTRO CHEMISTRY MOHD.ILIAS

    MOHD.ILIAS@5572131 12-D/2015

    Explain hydrogen fuel cell ?

    What are the advantages of fuel cell?

    What is corrosion?

    Explain why Rusting of iron is electrochemical phenomenon ?

  • 6

    ELECTRO CHEMISTRY MOHD.ILIAS

    MOHD.ILIAS@5572131 12-D/2015

    Write the prevention methods of rusting ?

    Explain

    1.

    Rusting inhibits in alkaline medium

    2.

    Rusting becomes faster in saline water

    3.

    4.

  • 7

    ELECTRO CHEMISTRY MOHD.ILIAS

    MOHD.ILIAS@5572131 12-D/2015