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Why some compounds are possible and others impossible? Why is there H2O, but not HO2? Why is there CO2, but not C2O? Why is there H2, but not H?
Why is there NaCl, but not Na2Cl or NaCl2?
At the end of this lesson, you will be able to: Explain why inert gases are stable Explain conditions for the formation of chemical
bonds State the two different types of chemical bonds
Human nature reflects chemical bonding Most people need to make connections with others. But not anyone will do. How do we select people that we can bond with?
What are the criteria that we set? Is it possible to predict the bonds that one person will
make in his/her life?
But atoms are not so complicated How do atoms bond with one another? Why do they form chemical bonds? Why inert gases can live on their own forever without making a single connection in their lives
What happens in a chemical reaction? Old bonds are broken and new ones are made. The result? Products, completely different from the reactants
Activity to discover how atoms bond with one another Two kinds of bonding: I: Between metal and non-metal atoms II: Between non-metal and non-metal atoms Ways that bonds can form: I: By sharing of electrons II: By transfer of electrons #p #e Group task: Using the element cards, periodic table and one cent coins,
combine any two elements to form a compound that fulfills the octet rule for all atoms involved. You need only show the valence electron shell
At the end of this lesson, you will be able to: explain formation of ions write electron arrangements for the ions formed explain formation of ionic bond
illustrate electron arrangement of an ionic bond, illustrate formation of ionic bond.
Stability of atoms What is stability of atoms? How do we know if an atom is stable or not?
Two ways chemical bonds can form Bond forming involves valence electrons on two atoms by Electron transfer One species donates/lose or release all its valence electrons The other species accepts/ gains or receives electrons Electron sharing One or more pairs of electrons will be shared between 2 atoms
Ionic bonding Transfer of electrons So named because this bond is between ions Atoms become ions because by losing/accepting e,
their #p #e Creates one positive ion cation When an atom loses electrons, it becomes positive
One negative ion anion When an atom gains electrons, it becomes negative
Filled shells by gain or loss of electrons
Gain electron outer shell full Lose electron inner shell full
Rules to predict ion charge Metals lose e cations Cation Charge = # of e released
Equation of the process: Na Na+ + e- , Mg Mg2+ + 2e-
Non-metals gain e anions Anion Charge = # of e received Equation of the process: Cl + e- Cl , O + 2e- O2-
Sodium chloride
Na loses electron
Cl gains electron
Composition of ionic compound depends on ionic charge (group number) Charges must balance: ions are charged but compounds are neutral Total cation charges = total anion charges One Ca2+ two F-
Determining formulae Overall charge must be neutral Metal ion first, nonmetal ion second
Ax B y
y+
x-
Coefficient of metal = charge on nonmetal Coefficient of nonmetal = charge on metal x and y are shown with lowest common denominator in most
cases. Calcium oxide is CaO not Ca2O2
Guided Practice Draw electronic structure of atoms write electron
arrangement draw what happens (e transfer) draw what happens after the transfer of e Lithium + fluorine Sodium + oxygen Aluminium and chlorine
2Na + Cl2 2NaCl When metal and non-metal bond, the metal has very low
electronegativity so they will lose their electrons to the nonmetal which has higher electronegativity
Ionic compounds Formed when ions of opposite charges are held by
strong electrostatic forces of attraction Because of this very strong attraction, a lot of energy is needed to separate the ions. Therefore mpt and bpt are very high Arranged in an orderly and compact three-dimensional network Very soluble in water and polar solvents because they can form bonds with water and polar solvents
Physical properties of ionic compounds
Hard, rigid solids at room temperature High melting point Dissolve in polar solvents (if soluble) Solutions conduct electricity (all soluble ionic compounds are electrolytes electricity-conducting soln) Closely packed dense structures
(Compare how metals conduct electricity)
Predicting formula of ionic compounds Na, O Na Na+ + e O + 2e O2-
2Na + O Na2O
A more accurate representation: Na Na+ + e O2 + 4e 2O2-
4Na + O2 2Na2O
Covalent bonds Non-metals have similar electronegativities, neither can take electrons away from the other Hence they are forced to share electrons
Explain why ionic compounds are formed when a metal bonds with a nonmetal but covalent compounds are formed when two nonmetals bond. When a metal bonds with a nonmetal, electrons are
transferred from the metal to the nonmetal because metals have very low electronegativities and nonmetals have high electronegativities. Because nonmetals tend to have similarly high electronegativities, neither atom can take electrons from the other, forcing them to share electrons.
Covalent bonds and compounds Covalent bonds can be formed between Atoms of the same element elements Atoms of different elements compound Three types of covalent bonds Single bond one pair of e shared between 2 atoms Double bond two pairs of electrons shared between 2 atoms Triple bond - three pairs of electrons shared between 2 atoms
How many valence electrons will atoms share? It depends on how many they need (valency) Alone each has seven, each need one more In order to get one more, Cl needs to share one
Number of bonds = 8 (no of valence electrons) Each covalent bond is a pair of electrons shared
Covalent bonds between unlike elements Oxygen and hydrogen Oxygen: No of bonds formed = 8 6 = 2 Hydrogen: No of bonds formed = 2 1 = 1 Predict Lewis structure of water
Try drawing the Lewis structure for these Use this equation to predict the # of bonds formed and
the molecular formula of the compound: No of bonds formed//valency = 8 (or 2) - #valence e Carbon and oxygen Nitrogen and nitrogen Carbon and chlorine Nitrogen and hydrogen
Bond order increases as valence electron total decreasesMolecule
# valence e
Total number of electrons in molecule
Bond order
F-F O=O NN
7 6 5
14 12 10
1 2 3
Practice P and Q are two elements with proton numbers 6 and 9 respectively. Draw the Lewis diagram for the formation of compounds between Q and H Q and P
Diatomic molecules
Predicting formula of covalent compounds M (Gp 14) and N (Gp 16) M: valency 4 N: valency 2
M2N4 Therefore, compound formed: MN2
element
No of valence e Valency
Gp 14 Gp 15 Gp 16 Gp 17
4 5 6 7
4 3 2 1
M (Gp 15) and N (Gp 17)/ (Gp 1) M: valency 3 N: valency 1
MN3 Therefore, compound formed: MN3
Draw/ illustrate Compare between ionic bonding and covalent bonding in terms of Aim or final result of bonding
What happened to valence electrons Types of particles formed as a result of bonding Type of attractive forces between particles after bonding
Properties of simple moleculesWeak interparticle forces of attraction (van der Waals) low m.pt, b.ptInterparticle forces of attraction -Formed between particles (in this case, molecules) -Temporary, forms only when particles are close to each other -Disappears when particles move further apart Covalent bond (a chemical bond) -Formed between atoms Weak interparticle in a molecule
forces of attraction ~ -Broken only only very little energy during a chemical reaction required to overcome -Formed these forces only during achemical reaction
Simple covalent and giant covalent
Giant covalent structure - diamond
Summary A+BC+D Reactants : one or all not stable Hence undergo reaction (form chemical bonds, sometimes
break existing bonds) to become more stable Products: More stable than reactants, after formation of ionic/ covalent bonds Ionic bonding// ions are formed Covalent bonding // molecules are formed
Explaining formation of ionic bond Na + O2 // sodium unstable but oxygen stable
A sodium atom (2.8.1) achieves the stable octet electron arrangement after it loses its valence e to form a sodium ion, Na+ // Na Na+ + e An oxygen atom with an e arrangement of 2.6 achieves the stable octet electron arrangement after it accepts 2 valence e from 2 sodium atoms to form an oxide ion, O2//O
+ 2e O2-
The electrostatic force of attraction between the
oppositely-charged sodium and oxide ions forms the ionic bond.
Explaining formation of covalent bond Formation of ammonia molecule (NH3 ) Nitrogen has an electron arrangement of 2.5 It needs to share 3 valence electrons in order to achieve a stable octet
electron arrangement. Hydrogen has an electron arrangement of 1 It needs to share 1 valence e to achieve a stable duplet electron arrangement One nitrogen atom contributes three of its valence electrons to be shared with three hydrogen atoms, each sharing its only electron to form three single covalent bonds. By sharing three valence e, N atom achieves the stable octet e arrangement. Each H atom achieves the stable duplet e arrangement by sharing its only electron.
Practice (ex from pink book)
Chemical reactions that you will encounter Synthesis reaction
Bird eats worm fat bird Two or more simple substances combine to form a complex
product Eg, Eg, 2Mg + O2 2MgO
Chemical reactions that you will encounter Decomposition reaction
Egg hatches egg shell + organism A complex substances breaks down to form 2 or more
simpler substances Eg,
Chemical reactions that you will encounter Single replacement reaction
John attends a party, meets Anna and Brad, steals Anna
from Brad, leaving Brad alone When one reactant has greater affinity for an ion, it will steal the ion from its partner Eg,
Chemical reactions that you will encounter Double displacement/replacement reaction
Exchange hats/ partners Eg,