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Triazole derivativesR 0280 DOI: 10.1002/chin.201106153
1-Allyl- and 1-Benzyl-3-methyl-1,2,3-triazolium Salts via Tandem Click Transfor-mations. — Triazoles of type (III) are synthesized in a one-pot manner via 1,3-dipolar cycloaddition of terminal alkynes bearing an alkyl chain and organic azides, generated in situ. Methylation yields triazolium iodides which are viscous liquids with stable shelf life. Triazoles resulting from sterically hindered alkynes (R1:-tBu or -Ph) reveal only marginal conversion to the salts. — (FLECHTER*, J. T.; KEENEY, M. E.; WALZ, S. E.; Synthesis 2010, 19, 3339-3345, http://dx.doi.org/10.1055/s-0030-1257909 ; Dep. Chem., Creighton Univ., Omaha, NE 68178, USA; Eng.) — Mais
06- 153
ChemInform 2011, 42, issue 06 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim