ChemInform Abstract: Allyl and Benzyl Dance under Basic Conditions.

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  • ChemInform 2011, 42, issue 51

    AminesQ 0120 DOI: 10.1002/chin.201151050

    Allyl and Benzyl Dance under Basic Conditions. A new reversible rearrange-ment is observed when UgiSmiles adducts are treated with NaH in MeCN. Allyl, pro-pargyl and benzyl groups migrate between two nitrogen atoms what is explained by formation of a highly stabilized aniline anion. (EL KAIM*, L.; GRIMAUD, L.; PURUMANDLA, S. R.; Synlett 2011, 13, 1816-1820, ; Lab. Chim. Procedes, Ec. Natl. Super. Tech. Avancees, F-75739 Paris, Fr.; Eng.) Mais

    51- 050 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim


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