1998 amino alcohols

amino alcohols (acyclic compounds)P 0130

05 - 066Diastereoselective Addition of Allyl Reagents to N-Tosyl- and N-Benzyl-N-tosyl-L-alaninal. — The stereochemical outcome of thetitle reaction is found to depend on the protection of the amino group.The monoprotected derivative (I) mainly gives the syn-product, while thediprotected one predominantly yields the anti-product. — (GRYKO, D.;URBANCZYK-LIPKOWSKA, Z.; JURCZAK, J.; Tetrahedron 53 (1997) 39,13373-13382; Inst. Org. Chem., Pol. Acad. Sci., PL-01-224 Warszawa, Pol.; EN)

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