Aziridine derivativesR 0040 DOI: 10.1002/chin.201109100

Metalated Aziridines for Cross-Coupling with Aryl and Alkenyl Halides via Pal-ladium Catalysis. — The scope concerning the Negishi coupling of stannylated aziri-dine (I) with alkenyl and aryl halides is examined. The products are formed with reten-tion of stereochemistry and the utility of the process is demonstrated by conversion of product (IIId) into furanomycin and analogues. — (NELSON, J. M.; VEDEJS*, E.; Org. Lett. 12 (2010) 22, 5085-5087, http://dx.doi.org/10.1021/ol101904a ; Dep. Chem., Univ. Mich., Ann Arbor, MI 48109, USA; Eng.) — Mais

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ChemInform 2011, 42, issue 09 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim