1
2008 Polyphenyl derivatives Q 0700 Palladium-Catalyzed Suzuki—Miyaura Cross-Couplings of Aryl Tosylates with Potassium Aryltrifluoroborates. — The procedure offers a practical and efficient approach to a wide range of biaryls. However, with highly hindered and heteroaryl to- sylates only low yields are obtained. Aryl chlorides are found to be more active than tosylates. — (ZHANG, L.; MENG, T.; WU*, J.; J. Org. Chem. 72 (2007) 24, 9346-9349; Dep. Chem., Fudan Univ., Shanghai 200433, Peop. Rep. China; Eng.) — Jannicke 14- 098

ChemInform Abstract: Palladium-Catalyzed Suzuki—Miyaura Cross-Couplings of Aryl Tosylates with Potassium Aryltrifluoroborates

Embed Size (px)

Citation preview

Page 1: ChemInform Abstract: Palladium-Catalyzed Suzuki—Miyaura Cross-Couplings of Aryl Tosylates with Potassium Aryltrifluoroborates

2008

Polyphenyl derivativesQ 0700 Palladium-Catalyzed Suzuki—Miyaura Cross-Couplings of Aryl Tosylates with

Potassium Aryltrifluoroborates. — The procedure offers a practical and efficient approach to a wide range of biaryls. However, with highly hindered and heteroaryl to-sylates only low yields are obtained. Aryl chlorides are found to be more active than tosylates. — (ZHANG, L.; MENG, T.; WU*, J.; J. Org. Chem. 72 (2007) 24, 9346-9349; Dep. Chem., Fudan Univ., Shanghai 200433, Peop. Rep. China; Eng.) — Jannicke

14- 098