2001 sulfuration, sulfonation, S-alkylation sulfuration, sulfonation, S-alkylation O 0245 13 - 056 Remarkably Fast Direct Synthesis of Thiols from Alcohols under Mild Conditions. — A rapid and efficient method for the direct synthesis of thiols from corresponding alcohols under mild conditions via treatment of trifluoroacetates with polymer-supported hydrosulfide is developed (19 examples). The methodology is compatible with a variety of other functional groups such as carbonyl, methylenedioxy, ester, ether, N-protecting groups (Fmoc, Boc) and C=C double bonds. — (BANDGAR, B. P.; SADAVARTE, V. S.; UPPALLA, L. S.; Chem. Lett. (2000) 11, 1304-1305; Sch. Chem. Sci., Swami Ramanand Teerth Marathwada Univ., Nanded 431 606, India; EN) 1

ChemInform Abstract: Remarkably Fast Direct Synthesis of Thiols from Alcohols under Mild Conditions

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Page 1: ChemInform Abstract: Remarkably Fast Direct Synthesis of Thiols from Alcohols under Mild Conditions

2001 sulfuration, sulfonation, S-alkylation

sulfuration, sulfonation, S-alkylationO 0245

13 - 056Remarkably Fast Direct Synthesis of Thiols from Alcohols underMild Conditions. — A rapid and efficient method for the direct synthesisof thiols from corresponding alcohols under mild conditions via treatmentof trifluoroacetates with polymer-supported hydrosulfide is developed (19examples). The methodology is compatible with a variety of other functionalgroups such as carbonyl, methylenedioxy, ester, ether, N-protecting groups(Fmoc, Boc) and C=C double bonds. — (BANDGAR, B. P.; SADAVARTE,V. S.; UPPALLA, L. S.; Chem. Lett. (2000) 11, 1304-1305; Sch. Chem. Sci.,Swami Ramanand Teerth Marathwada Univ., Nanded 431 606, India; EN)