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1996 ethers ethers (acyclic compounds) P 0150 33 - 080 Stereoselective Synthesis of Allyl Vinyl Ethers from Silyl Enol Ethers through mixed iodo acetals. The stereochemical outcome of elimination step is found to depend on the used solvent. In DME preferred anti- elimination takes place, while in hexane syn-elimination is favored. — (MAEDA, K.; SHINOKUBO, H.; OSHIMA, K.; UTIMOTO, K.; J. Org. Chem. 61 (1996) 7, 2262-2263; Dep. Mater. Chem., Fac. Eng., Kyoto Univ., Yoshida, Kyoto 606-01, Japan; EN) 1

ChemInform Abstract: Stereoselective Synthesis of Allyl Vinyl Ethers from Silyl Enol Ethers

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Page 1: ChemInform Abstract: Stereoselective Synthesis of Allyl Vinyl Ethers from Silyl Enol Ethers

1996 ethers

ethers (acyclic compounds)P 0150

33 - 080Stereoselective Synthesis of Allyl Vinyl Ethers from Silyl Enol Ethers— through mixed iodo acetals. The stereochemical outcome of eliminationstep is found to depend on the used solvent. In DME preferred anti- eliminationtakes place, while in hexane syn-elimination is favored. — (MAEDA, K.;SHINOKUBO, H.; OSHIMA, K.; UTIMOTO, K.; J. Org. Chem. 61 (1996)7, 2262-2263; Dep. Mater. Chem., Fac. Eng., Kyoto Univ., Yoshida, Kyoto606-01, Japan; EN)

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