1999 reactions of organo-metal compounds

reactions of organo-metal compoundsO 0350

26 - 077Synthesis of Alcohols via Mild Oxidation of Perfluoroethylstannanes.— Perfluoroethyl substituted stannanes (I) are directly converted into thecorresponding alcohols (II) by oxidation with alkaline hydrogen peroxide. Thechiral version of the reaction proceeds with complete retention of configura-tion. — (FALCK, J. R.; LAI, JING-YU; VENKATA RAMANA, D.; LEE,SANG-GYEONG; Tetrahedron Lett. 40 (1999) 14, 2715-2718; Dep. Biochem.Pharmacol., Univ. Tex. Southwest. Med. Cent., Dallas, TX 75235, USA; EN)

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