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Cycloalkylphenyl derivativesQ 0760 DOI: 10.1002/chin.201240110
Tandem Decarboxylative Allylation and Fragmentation of Allyl Benzocyclobute-nyl Carbonates: Access to ortho-Functionalized Aryls from Aryl Bromides. — Benzocyclobutenols (IV) and (VI) undergo Pd-catalyzed decarboxylative allylation and selective β-elimination leading to ortho-substituted arenes (V) and (VII), generally in good yields. — (ROSA, D.; CHTCHEMELININE, A.; ORELLANA*, A.; Synthesis 2012, 12, 1885-1891, http://dx.doi.org/10.1055/s-0031-1290943 ; Dep. Chem., York Univ., North York, Toronto, Ont. M3J 1P3, Can.; Eng.) — Mais
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ChemInform 2012, 43, issue 40 © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim