2008

KetonesQ 0350 Tandem Oxidation/Halogenation of Aryl Allylic Alcohols under Moffatt—Swern

Conditions. — A number of aryl allylic alcohols follows the title reaction to give α-ha-loketones like (II) and (III). However, substrates bearing electron-donating substituents in ortho or para position such as (IV) afford allylic halides like (IV). — (YIN, J.; GALLIS, C. E.; CHISHOLM*, J. D.; J. Org. Chem. 72 (2007) 18, 7054-7057; Dep. Chem., Syracuse Univ., Syracuse, NY 13244, USA; Eng.) — Jannicke

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