©Consultnet Limited Safe Use of Cylinder Gases ©Consultnet Limited Presentation Contents Introduction to Gas Cylinder Safety Main causes of Accidents

©Consultnet Limited

Safe Use of Cylinder Gases


Presentation ContentsPresentation Contents Introduction to Gas Cylinder Safety Main causes of Accidents Main Hazards Rules for Safe Working with Gas Cylinders Gas Regulators Flashback Arrestors Hoses, Piping, Blow Pipes and Torches Acetylene –unique properties Handling Gas Cylinders Transporting Gas Cylinders Safe Storage Cylinder Incident Response Gas Cylinders Hazards in Your Workplace Conclusions


IntroductionIntroduction Compressed gases used in a variety of industrial and

laboratory situations Compressed gases present a unique hazard. Depending on

the particular gas, there is a potential for simultaneous exposure to both mechanical and chemical hazards

Gases can be:– Flammable or combustible – Explosive – Corrosive – Poisonous/toxic – Inert – Cryogenic– Pyrophoric(burns on contact with air)– or a combination of hazards


IntroductionIntroduction Common Industrial Gases

Oxidants support combustion e.g. air & oxygen Inerts do not generally react with other materials,

asphyxiants(leak displace air) e.g. nitrogen, argon, helium

Flammables when mixed with oxidant and ignition source will burn e.g. acetylene, hydrogen, propane

Toxics toxic in small concentrations e.g. ammonia, chlorine, carbon dioxide

Corrosives react with materials causing reactions e.g. chlorine, sulfur dioxide

Pyrophorics ignite spontaneously in air e.g. silane, phosphine


Main Causes of AccidentsMain Causes of Accidents

Inadequate training and supervisionPoor installationPoor maintenanceFaulty equipment and/or design(e.g badly

fitting valves or regulators)Poor handlingPoor storage Inadequately ventilated working conditions


Main HazardsMain Hazards Impact from the blast of a gas cylinder

explosion or rapid relase of compressed gas

Impact from parts of gas cylinders that fail or any flying debris

Contact with the released gas or fluid(such as chlorine)

Fire resulting from the escape of flammable gas or fluids such as LPG

Impact from falling cylinder


Safe Working with Gas Cylinders:

Identification and Properties Read the label to see what gas you are dealing with and

double check tha the cylinder/gas is right for th eintended use No compressed gas cylinder should be accepted for use that

does not legibly identify its contents by name If the labeling on a cylinder becomes unclear or an attached

tag is defaced to the point the contents cannot be identified, the cylinder should be marked "contents unknown" and returned directly to the manufacturer

Never rely on the color of the cylinder for identification. Color coding is not reliable because cylinder colors may vary with the supplier. Additionally, labels on caps have little value because caps are interchangeable

If there is a mismatch between the color of a cylinder and the label. Do not use, contact the supplier immediately

Know the properties of the gas (read Material Safety Data Sheets available from your Supervisor)

The cylinder’s contents should be identified at all times as well as the cylinder status (full, empty or in service)


Safe Working with GasSafe Working with Gas Cylinder CylinderssWork Practices

Securely restrain cylinders to prevent them falling over Close the cylinder valve and replace dust caps when cylinder not in use Before connecting a gas cylinder to equipment or pipework make sure regulator and

pipework are suitable for the gas and pressure being used Never drop a gas cylinder Never tamper with cylinders or subject them to abnormal mechanical shocks which

could damage the valve or safety device Never re-paint, change markings or identification or interfere with threads Never disguise damage to a cylinder or valve. Label as faulty and contact the supplier Never attempt to repair a cylinder Never scrap a cylinder Never subject cylinders to abnormally high or low temperatures Never mix gases in a cylinder Never try refill a cylinder Never transport by rolling them on the ground or use them as rollers or supports Never pick them up by magnetic lifting Never subject to abnormal mechanical shocks whuch could damage the valve or

safety device


Safe Working with GasSafe Working with Gas Cylinder CylinderssDaily Inspection

Cylinders should be inspected daily and prior to each use for corrosion, leaks, cracks, etc.

Inspection should include the cylinder, piping, safety relief devices, valves, protection caps and stems.

Leaking regulators, cylinder valves or other equipment should be taken out of service.


Safe Working with GasSafe Working with Gas Cylinder Cylinderss

Maintenance of cylinders and their valves or relief devices shall be performed only by trained personnel.

An emergency response plan shall be developed and implemented wherever compressed gas cylinders are used, handled or stored.

Never smoke around compressed gas cylinders. Valve protection caps must remain in place at all times except

when cylinders are secured and connected to dispensing equipment

Only wrenches or tools provided by the cylinder supplier should be used to open or close a valve. At no time should pliers be used to open a cylinder valve.

Never apply PTFE tape, jointing compounds or any other sealing material to the valve in an attempt to achieve a tight seal, if a gas tight seal cannot be achieved metal to metal, replace the regulator or change the cylinder


After the regulator is attached, the cylinder valve should be opened just enough to indicate pressure on the

regulator gauge (no more than one full turn) and all the connections checked

with a soap solution for leaks.

Never use oil or grease on the regulator of a cylinder valve.

Before a regulator is removed from a cylinder, the cylinder valve shall be closed and the regulator relieved of gas pressure.The valve

cap shall be replaced, the cylinder clearly marked as "empty," and returned to a storage area for pickup by the supplier

Regulators, gauges, hoses and other apparatus shall not be used on gas cylinders having different chemical properties

Valve outlet thread size is different for different products but the same products from different gas suppliers will have the same thread

Gas Cylinder UseGas Cylinder Use


Gas Cylinder RegulatorsGas Cylinder RegulatorsA regulator is a device that receives gas at a high

pressure and reduces it to a much lower working pressure

Precision instruments and MUST be handled with care to avoid damage to their sensitive springs, diaphragms, valve seals etc.

Equipment should display the relevant European/British Standard number and the pressures up to which it can operate

Leave the pressure adjustment knob/screw fully out when the regulator is not in use (this ensures a minimum of tension on the springs and diaphragms)

Cylinders should be placed with the valve accessible at all times. The main cylinder valve should be closed as soon as it is no longer necessary that it be open, it should never be left open when the equipment is unattended or not operating

This is necessary not only for safety when the cylinder is under pressure, but also to prevent the corrosion and contamination resulting from diffusion of air and moisture into the cylinder after it has been emptied.


Flashback ArrestorsFlashback Arrestors

Flashback is the result of mixture of fuel gas and oxygen burning within the hose, flame travels and burns its way towards the gas source at great speed, can result in force of explosion in either cylinder

Flashback arrestors must be fitted on both oxygen and fuel gas regulators

If flashback arrestor is dropped/damaged replace immediately

Flashback arrestors should oinly be used with the gas they are labelled for and the presuure thay are designed for

Coomon reasons for flashback: incorrect purging of hose/torch prior to use, incorrect gas pressure, incorrect nozzle, damaged torch valves, gas passages blocked within the torch, kinked or trapped hose


HosesHoses Correct hose bore size, pressure rating, length and color coding are essential

for safety BS EN 559 Blue – oxygen, Red - acetylene and other fuel gases(except LPG) Black – inert and non combustible gases Orange – Liquified Petroleum Gas Never use hoses that are longer than necessary Never use equipment while hoses are wrapped around the cylinders or trolley Length of hose should be suitable for the task Keep hoses in good condition Examine the hose for cracks, deterioration, damage and test the hose for

leaks before use Do not repair hoses unless you have the skill and means to test hem in

accordance with BS En 1256 Purge hose thoroughly before lighting torch Do not put wrapping tape around hosing as this contains combustible

hydrocarbons Do not use copper piping with acetylene hoses as it is potentially explosive Protect hosing from heat, oil, grease or mechanical damage


PipingPiping Distribution lines and their outlets should be

clearly labeled as to the type of gas contained

Piping systems should be inspected for leaks on a regular basis

Special attention should be given to fittings as well as possible cracks that may have developed


Blow Pipes and TorchesBlow Pipes and Torches

Leaks are a serious hazard as they are closest to the operator Always check condition before use, ensure tip is free of obstruction Signs of heat damage around the blow pipe or torch may indicate the equipemnt

has sufferd interal damage and is leaking and should be replaced immeidately No sign of sideways movement of the cutting leaver as this could cause gas

leaks within the body of the torch that are difficult to detect Always fit the correct size nozzle for the job( hole size and pressure set at

regulator determine gas flow and gas velocity exiting the nozzle, manufacturer gives a pressure rating for the nozzle being use, if the gas exit velocity is slower than the combustion velocity backfire and flashback may occur

Replace blow pipe or torch if Broken bent or loose gas control valve Bent mixer, misshapen cutter head Bent cutter tube Broken of bent cutting oxygen lever

Leak test all connections and valves prior to use If replacing O ring seals always use the correct materials


AcetyleneAcetyleneUnique properties

Acetylene gas under excess pressure becomes unstable

Cylinders should never be subject to intense heat or physical impact as the rise in temperature and pressure may cause the acetylene to thermally decompose

Prior to moving a cylinder that has been subject to heat or severe impact contact trained emergency personnel who can check for temperature rise and apply correct procedures

The cylinder may appear normal but if it is moved it may detonate with fatal consequences


Handling Gas CylindersHandling Gas Cylinders Wear PPE: gloves, protective footwear, eye protection Correct way to move cylinders is to: keep upright, secure and with

valves uppermost Use mechanical aids such as a trolley where reasonably

practicable( do a risk assessment) Use suitable cradles, slings, clamps or other effective means when

lifting with a hoist or crane For short distances on even ground the practice of ‘milk-churning’

(manually moving cylindres) can be used only by trained personnel and never for longer distances, in uneven ground, wet or icy conditions, poor lighting, or at speed a trolley should be used

All personnel involved should have completed manual handling training

Never roll cylinders along the ground Never transport cylinder with valve and pressure regulator

attached or with the valve open Never attempt to catch a falling cylinder just get out of the way Never lift a cylinder by its cap, valve or guard/shroud

RRemember that a cylinder is never emptyemember that a cylinder is never empty


TransportingTransporting Cylinders CylindersCarriage of Dangerous Goods Regulations apply

If possible carry in open vehicles or trailers If they must be carried in closed vans/cars ensure good

ventilation at all times If the load compartment is not separated from the driver

do not carry toxic gas cylinders (those with a toxic gas label and having yellow as a colour on the cylinder)

Secure cylinders properly so they cannot move or fall in transit or do not project beyond the edges of the vehicle, normally in the upright position unless instructions for transport state otherwise

Ensure gas cylinders are clearly labelled to show contents and associated hazards

Fit suitable protective valve caps and covers to cylinders


TransportingTransporting Cylinders CylindersCarriage of Dangerous Goods Regulations apply

Disconnect hoses and regulators from cylinders Carry propane cylinders upright and do not carry

flammable gas cylinders in the same compartment as toxic gas cylinders

Do not smoke while carrying cylinders inside vans/cars

Unload the cylinders as soon as possible and move to a well ventilated storage area

If you suspect it is leaking, park the vehicle, investigate the fault and contact the supplier

If you are involved in an accident advise, any emergency services involved what gas cylinders are being carried


Safe StorageSafe StorageEach Storage area should be subject to unique risk

assessment It is best to store gas cylinders in the open and on concrete in a

fenced compound with some weather protection In storage areas oxygen cylinders must be stored at least 3 metres

away/separated by a fire wall from fuel gases such as acetylene, propane, methane etc.

Full cylinders should be stored separately from empties and empty oxygen cylinders should be segregated from empty fuel gas cylinders

Other products should not be stored in the gas storage areas especially not oil or corrosive liquids, sources of ignition or flammable materials

Ease of access into and around storage area, such as provision of aisle >0.6m to prevent domino effect

LPG cylinders have special requirements including storage 3m away from other gases

Pyrophoric and toxic gases should be stored seperately in locked, suitable ventilated storage areas with restricted access

Protect gas cylinders from external heat sources which may adversely affect their mechanical integrity

Cylinders should be secured and properly restrained, secure with straps or chains connected to a wall bracket or other fixed surface, or by use of a cylinder stand

Cylinders should be clearly labelled to show contents and associated hazards


Safe Safe SStoragetorage

Store all cylinders upright and secure on a level surface to prevent them from falling

Acetylene and propane must never be stacked horizontally either in storage or in use

Storage arrangements should ensure turnaround of stock in adequate time

Storage areas with gas cylinders must have more than one exit

Cylinders should be located away from any heat/source of ignition and if possible away from the fire exits, elevators, walkways, building egresses, unprotected platform edges, or in locations where heavy moving objects may strike or fall on them

Storage arrangements should be clearly described in the emergency plan

Storage area must have good housekeeping and adequate warning signs with fire fighting equipment as necessary


CylinderCylinder Incident Response Incident ResponseReport any damaged/leaking cylinder to supplierReport any damaged/leaking cylinder to supplier

If a cylinder is leaking but the leak has not ignited and it is safe to do so having considered the gases specific properties: Eliminate all sources of ignition Ensure the valve is closed but do not over-tighten it Put the cylinder in a safe place that is well-ventilated

– keep it upright Mark the cylinder as faulty and not to be used Warn everyone in the area of the gas leak Inform the supplier Ensure the work area is thoroughly ventilated before

continuing with any work If a hydrogen cylinder is involved be aware that

hydrogen burns with an invisible flame so seek expert assistance


CylinderCylinder Incident Response Incident ResponseReport any damaged/leaking cylinder to supplierReport any damaged/leaking cylinder to supplier

If a cylinder is leaking and it has ignited it could explodeCall the emergency services and evacuate

the area to a minimum distance of 100 metres

Where a cylinder has been damaged If it has been dropped or physically damaged check

it for leakage and deal with as for a leaking cylinder For handling acetylene cylinders should not be

moved unless it is clearly established that there is no thermal disassociation

Clearly mark any cylinder that has been exposed to excessive heat or physical impact and contact the supplier


CylinderCylinder Incident Response Incident ResponseIf a flashback has occurred: Close both blowpipe valves oxygen first Close both cylinder valves Check the temperature of the acetylene cylinder

for thermal decomposition Check the blowpipe has not overheated Check the nozzle is not damaged Open both blowpipe valves oxygen first to vent

the system Unwind the pressure adjustment screw on each

pressure regulator Before starting up again, check the integrity of

the whole system


Cylinder Incident ResponseGas Cylinders on Fire

Depends on the gas, whether the gas is alight at the cylinder valve or if the cylinder has been subject to severe pressure as a result of the heat from the fire. Nature of hazard will

determine procedure to be applied

If cylinder has been involved in fire do not approach, evacuate the area to 100m minimium to 300m

Call fire brigade Use large quantities of water to cool the cylinders if safe to do

so (do not aim high pressure water direct at the cylinders) from a safe location and await the arrival of trained emergency personnel (Emergency plan training should address)

Remove any cylinders not involved in fire to safe place, ensure valves are closed if safe to do so

Inform gas supplier, If cylinder contents are unknown, treat as acetylene


In Your Workplace Look Out for Gas Cylinders:Look Out for Gas Cylinders:

In horizontol position/on the ground In contact with electrical cords Not protected from falling – chain not secure Damaged In an area where could be subject to impact such

as near operating forklift Stored near combustibles Oxygen and acetylene stored together Without valve caps

Deal with these Hazards IMMEDIATELY


Conclusions Compressed gases present a unique hazard. Depending on

the particular gas, there is a potential for simultaneous exposure to both mechanical and chemical hazards

Inadequate training and supervision, poor installation, poor maintenance, faulty equipment and/or design(e.g badly fitting valves or regulators), poor handling, poor storage, inadequately ventilated working conditions

When working with compressed gases you need to know the properties of the gas, safe use procedures and what to do when things go wrong

For detailed use of individual gases you should now review the relevant Material Safety data Sheet (MSDS) for each gas used on your site

Always Treat Gas Cylinders with RespectFor additional information which could be used as presentation handouts visit UK

HSE information on Gas Safety for a whole series of leaflets on the topic

http://www.hse.gov.uk/pubns/gasindex.htm

Documents

©Consultnet Limited Safe Use of Cylinder Gases ©Consultnet Limited Presentation Contents Introduction to Gas Cylinder Safety Main causes of Accidents