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M/s. Technichem Organics Pvt. Ltd. 0 Pre-Feasibility Report Submitted by M/s. Technichem Organics Pvt. Ltd. Survey No. 347 Village: Lunej, Tal: Khambhat, Dist.: Anand Gujarat

Date : 01/04/2008environmentclearance.nic.in/writereaddata/Online/TOR/22... · 2018. 10. 22. · (C) Pigments 1. Pigment Red 41 21200 0.00 100 100 2. Pigment Orange 05 12075 3. Pigment

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Page 1: Date : 01/04/2008environmentclearance.nic.in/writereaddata/Online/TOR/22... · 2018. 10. 22. · (C) Pigments 1. Pigment Red 41 21200 0.00 100 100 2. Pigment Orange 05 12075 3. Pigment

M/s. Technichem Organics Pvt. Ltd. 0

Pre-Feasibility Report

Submitted by

M/s. Technichem Organics Pvt. Ltd. Survey No. 347

Village: Lunej, Tal: Khambhat, Dist.: Anand

Gujarat

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M/s. Technichem Organics Pvt. Ltd. 1

1. INTRODUCTION

M/s. Technichem Organics Pvt. ltd. is an existing unit engaged in

manufacturing of dyes intermediate at Plot no. 347, Village: Lunej, Tal.:

Khambhat, Dist.: Anand. Now, unit wants expand their dyes intermediated

capacity and also wants to manufacture dyes and pigments. The current

capacity is 35 MTPM and after expansion total capacity will be 600 MTPM.

The expansion will be done in the existing premises. The unit is promoted

by Mr. Bharat Pandya.

2. COST OF PROJECT

Existing cost of the project is 6.0 Crore and cost for proposed expansion

will be 7.75 Crore, hence total investment will be 13.75 crore. Out of which

1.75 crores will be capital cost for EMS and Rs. 75 lakhs recurring cost per

annum.

3. PRODUCTION CAPACITY

Production capacity is prescribe below:

List of Products

Sr. No.

Name of Products CAS No./ CI No.

Quantity (MT/month)

Existing Proposed Total

(A) Dye Intermediates

1. 1-(4 Sulpho Phenyl)-3-

Carboxy-5-Pyrazolone (1,4 SPCP)

118-47-8 20 130 150

2. 3-Amino Crotononitrile (3

AC)

1118-61-2

3. 1-(3-Sulpho Phenyl)-3 Methyl 5-Amino-Pyrazolone)

(1:3 SPMAP)

23646-86-8

4. 1(3-Sulfo Phenyl)-3 Methyl 5-Pyrazolone (1:3 SPMP)

119-17-5

5. 3,5 Dimethyl Pyrazolone

(Dimpa)

67-51-6

6. 1-(4 Sulpho Phenyl)-3-Methyl-5-Pyrazolone (1:4

SPMP)

89-36-1 10 40 50

7. 2-Amino Dimethyl

Terpthalate (ADMT)

5372-81-6

8. 3,4 dichloro-6-sulfo Aniline (3,4 DC 6-SA)

6331-96-0

9. Bisphenol Sulfony / Ester 68015-60-1

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M/s. Technichem Organics Pvt. Ltd. 2

10. 1-(3-sulfomido phenyl)-3

Methyl 5-Pyrazolone (1:3 SAPMP)

89-29-2

11. 1 Phenyl 3 Methyl 5

Pyrazolone (PMP)

89-25-8 5 95 100

12. (1-Pheneyl)-3 Methyl-5 Amino Pyrazole (5 Amio

PMP)

1131-18-6

13. N-Phenyl Ethyl N Cyano Ethyl Aniline (PCN acid)

17601-74-0

14. 3-Amino 5-Methyl Pyrazole

(3 AMP)

31230-17-8

15. 5 Amino 6 Methyl

Benzimidazole (AMBZ)

67014-36-2

16. 1(4-Tolyl) Phenyl-3 Methyl 5 Pyrazole (PTPMP)

86-92-0 0.00

17. 1-2 Chloro Phenyl-3-Methyl-

5-Pyrazolone (OCPMP)

14580-22-4

18. 1-3-Chloro-Phenyl-3-Methyl-5-Pyrazolone

(MCPMP)

20629-90-7

19. 2,5 Dichloro 4 Sulfo Phenyl 3 Methyl 5

Pyrazolone(DCSPMP)

84-57-1

20. 2, 5 Dichloro-Phenyl-3-Methyl-5-Pyrazolone

(DCPMP)

865303-45-3

21. 3-Methyl-5-Pyrazolone 108-26-9

22. 4-Nitro 2 Amino Phenol 5

Sulphonic Acid (4-NAPSA)

96-67-3

23. 2,5 Dichloro-4-Sulpho-Aniline (2,5DC4SA)

88-50-6

24. Vinay-SulfoPhenyl-3-

Methyl-5-Pyrazolone (VS SPMP)

108-26-9

25. 3,5 Di-NItro Benzoic Acid 99-34-3

26. Metanilic Acid 121-47-1 0.00 100 100

27. Meta amino phenol 591-27-5

28. Para amino benzamide 2835-68-9

29. 1-phenyl 3 carbethoxy 5

pyrazolone

89-33-8

30. Bis azo Barbituric Acid 25157-64-6

31. 2,5 Dichloro Phenol 583-78-8

32. 3,5 Di-Amino benzoic acid

33. Di methyl Pyridone (DMP)

34 N-butyl-3-Cyno-6-hydroxy-

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M/s. Technichem Organics Pvt. Ltd. 3

4-Methyl-2-Pyridone (BMP)

35 N-3-methoxypropyl-3-Cyno-

6-hydroxy-4-Methyl-2-Pyridone (3MMP)

36 N-ethtyl-3-Cyano-6-

hydroxy-4-methyl-2-Pyridone (EMP)

37. Barbituric Acid 67-52-7

(B) Dyes

1. Acid yellow 17 18965 00 100 100

2. Acid yellow 36 13065

3. Acid Yellow 42 22910

4. Acid Yellow 49 18640

5. Acid Yellow 79 12220-70-1

6. Acid yellow 110 12220-74-5

7. Acid yellow 232 134687-50-6

8. Acid Blue 113 26360

9. Acid Red 119 262085

10. Acid Red 183 18800

11. Acid Red 315 12220-47-2

12. Acid Red 357 61951-36-8

13. Acid Red 362 61814-58-2

14. Acid Red 414 172287-09-7

15. Acid Violet 90 18762

16. Acid Brown 282 12219-65-7

17. Acid Brown 355 60181-77-3

18. Acid Orange 142 61901-39-1

19. Acid Orange 74 18745

20. Acid Orange 154 133556-24-8

21. Solvent Orange 58 71775-93-4

22. Disperse Blue CB --

(C) Pigments

1. Pigment Red 41 21200 0.00 100 100

2. Pigment Orange 05 12075

3. Pigment Orange 13 21110

4. Pigment Orange 34 21115

5. Pigment Orange 36 11780

6. Pigment Orange 64 12760

7. Pigment Yellow 83 21108

8. Pigment Yellow 97 11767

9. Pigment Yellow 110 56280

10. Pigment Yellow 114 21092

11. Pigment Yellow 138 56300

12. Pigment Yellow 139 56298

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M/s. Technichem Organics Pvt. Ltd. 4

13. Pigment Yellow 150 12764

14. Pigment Yellow 151 13980

15. Pigment Yellow 152 21111

16. Pigment Yellow 154 11781

17. Pigment Yellow 155 200310

18. Pigment Yellow 168 13960

19. Pigment Yellow 174 21098

20. Pigment Yellow 180 21290

21. Pigment Yellow 181 11777

22. Pigment Yellow 183 18792

23. Pigment Yellow 191:1 18795

24. Pigment Red 146 12485

25. Pigment Red 170 12475

26. Pigment Red 176 12515

27. Pigment Red 177 65300

28. Pigment Red 184 12487

29. Pigment Red 185 12516

30. Pigment Red 187 12486

31. Pigment Red 188 12467

32. Pigment Red 210 12477

33. Pigment Red 254 56110

34. Pigment Red 264 561300

35. Pigment Red 122 73915

Total Production 35 565 600

List of Raw Materials

Sr. No.

Product name Quantity MT/MT

(A) Dyes Intermediates

1

1-(4 Sulpho Phenyl) 3-Carboxy 5-Pyrazolone (1,4 SPCP)

Sulphanilic Acid 0.960

Sulphuric Acid 2.530

Sodium nitrite 0.390

Sodium Bi Sulphite 1.300

Caustic Lye 0.935

Benzene 2.700

Sodium Metal 0.120

Diethyl Oxalate 0.785

Ethyl acetate 0.535

Phenyl hydrazine 0.865

2

3-Amino Crotononitrile (3-AC)

Toluene 4.500

Sodium Metal 0.570

Acetonitrile 1.250

3 1-(3 Sulpho Phenyl)-3-Methyl-5-Amino Pyrazolone (1,3 SPMAP)

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M/s. Technichem Organics Pvt. Ltd. 5

Metanilic Acid 1.000

Sulphuric Acid 0.450

Sodium nitrite 0.410

Sodium Bi Sulphite 1.400

Caustic Lye 0.366

Sulphuric Acid 1.500

3-Amino Crotononitrile 0.413

Hydrochloric Acid 0.650

4

1-(3 Sulfo Phenyl) 3-Methyl 5- Pyrazolone (1:3 SPMP)

Metanilic Acid 1.000

Sulphuric Acid 2.082

Sodium nitrite 0.410

Sodium Bi Sulphite 1.400

Caustic Flakes 0.340

Methyl Aceto Acetic Ester 0.830

Soda Ash 0.550

5

3,5 Dimethyl Pyrazolone (DIMPA)

Acetyl Acetone 1.100

Hydrazine Hydrate 0.750

6

1-(4 Sulpho Phenyl) 3-Methyl 5-Pyrazolone (1:4 SPMP)

Sulphanilic Acid 0.950

Sulphuric Acid 0.780

Sodium nitrite 0.400

Sodium Bi Sulphite 1.300

Caustic Flakes 0.380

H2SO4 0.850

Methyl Aceto acetic ester (MAAE) 0.530

Caustic Lye 0.250

7

2-Amino Dimethyl Terpthalate (ADMT)

Meta chloro benzenamide (MCB) 5.250

Iron powder 2.150

HCl 0.755

2-Nitro Dimethyl Terephalate (NDMT) 0.650

Soda Ash 0.450

8

3,4 Dichloro 6-Sulfo Aniline (3,4 DC 6-SA)

Ortho dichloro benzene (ODCB) 4.500

H2SO4 1.450

3,4 Dichloro Aniline 0.680

Caustic Lye 0.450

9

Bisphenol Sulfony/ Ester

Meta Chloro Benzamide(MCB) 0.850

Catalyst 0.015

Bisphenol 1.150

NaSH 30% 1.150

10

1-(3 Sulfomido Phenyl) 3-Methyl 5-Pyrazolone (1:3 SAPMP)

MABSA 0.909

HCl 2.800

Sodium nitrite 0.372

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M/s. Technichem Organics Pvt. Ltd. 6

Sodium Bi Sulphite 1.316

Caustic Flakes 1.200

Sulphuric Acid 1.500

Methyl Aceto acetic ester 0.505

11

1 Phenyl 3 Methyl 5 Pyrazolone (PMP)

Aniline 0.850

HCl 1.500

Sodium nitrite 0.650

Sodium Bi Sulphite 1.500

Caustic Lye 0.565

HCl 1.500

Methyl Aceto acetic ester 0.550

12

1-Phenyl 3 Methyl 5 Amino Pyrazolone (5 Amino PMP)

Aniline 0.500

HCl 2.320

Sodium nitrite 0.600

Sodium Bi Sulphite 1.200

Caustic Lyes 0.705

Sulphuric Acid 1.200

3 Amino Cratononitrile 0.540

Soda Ash 0.350

13

N-Phenyl Ethyl N Cyno Ethyl Aniline (PCN Acid)

Aniline 1.150

Sodium Metal 0.068

Styrene Monomer 0.995

Acrylonitrite 0.420

ZnCl2 0.240

Acetic Acid 0.120

14

3-Amino 5-Methyl Pyrazolone (3 AMP)

Hydrazine hydrate 0.650

Liq. NH3 1.100

3 Aceto Crotonitrile (AC) 1.100

Toluene 4.000

15

5 Amino 6 Methyl Benzimidazole (AMBZ)

Rani nickle 0.040

Ortho dichloro benzene (ODCB) 2.200

MNPT (Meta nitro Totuidnet) 1.200

Hydrazine Hydrate 1.300

Urea 0.500

Methanol 4.500

Nitric Acid 1.200

16

1-(4-Tolyl) Phenyl 3-Methyl 5 Pyrazole (PTPMP)

Para Toluidine 0.820

HCl 2.050

Sodium nitrite 0.550

Sodium Bi Sulphite 1.200

Caustic Lye 0.930

Sulphuric Acid 0.900

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M/s. Technichem Organics Pvt. Ltd. 7

Methyl Acetoacetic Ester 0.800

Caustic Flakes 0.275

17

1-2 Chloro Phenyl 3-Methyl 5-Pyrazolone (OCPMP)

Ortho Chloro Aniline 0.700

HCl 2.400

Sodium nitrite 0.400

Sodium Bi Sulphite 1.200

Caustic Lye 0.800

Methyl Acetoacetic Ester 0.500

Sulphuric Acid 0.150

18

1-3 Chloro Phenyl 3-Methyl 5-Pyrazolone (MCPMP)

Mono Chloro Aniline 0.650

HCl 2.000

Sodium nitrite 0.350

Sodium Bi Sulphite 1.200

Caustic Lye 0.465

Sulphuric Aicd 0.700

Methyl Acetoacetic Ester 0.450

19

2,5 Dichloro 4 Sulfo Phenyl 3 Methyl 5 Pyrazolone (DCSPMP)

2,5 Dichloro Aniline 4 Sulphonic Acid (2,5DC4SA) 0.800

Sulphuric Acid 2.350

Sodium nitrite 0.250

Sodium Bi Sulphite 1.000

Caustic Lye 0.900

Methyl Ester 0.400

20

2,5 Dichloro Phenyl 3 Methyl 5 Pyrazolone (DCPMP)

2,5 Dichloro Aniline (2,5 DCA) 0.700

HCl 3.300

Sodium nitrite 0.300

Sodium Bi Sulphite 1.100

Caustic Lye 0.465

Methyl Ester 0.440

21

3-Methyl 5-Pyrazolone

Methyl Ester 1.200

Hydrazine Hydrate 0.470

22

4-Nitro 2 Amino Phenol 5 Sulphonic Acid (4-NAPSA)

Oleum 2.500

Para Nitro Chloro benzene (PNCB) 0.950

Nitric Acid 0.700

HCl 0.300

Caustic Flakes 0.500

NaSH 1.500

Ammonium Sulfate 1.500

23

2,5 Dichloro 4-Sulfo Aniline (2,5 DC 4-SA)

Oleum 3.300

H2SO4 0.130

2,5 Dichloro Aniline 0.800

24 Vinyl-Sulfo Phenyl 3-Methyl 5-Pyrazolone (VS SPMP)

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M/s. Technichem Organics Pvt. Ltd. 8

V.S. Condenses 0.770

HCl 2.160

Sodium Nitrite 0.215

Sodium bi sulfite 0.850

Caustic Lye 0.350

Hydrazine 0.550

Ester 0.300

25

3,5 Dinitro Benzoic Acid

Oleum 2.500

Benzoic Acid 0.800

Sulfuric Acid 1.000

Nitric Acid 1.200

26

Metanilic Acid

Nitro benzene 0.840

Oleum (25%) 1.680

Calcium hydroxide 1.200

HCl (30%) 0.300

Iron Powder 0.840

Soda Ash 0.450

H2SO4 (98%) 0.700

27

Meta Amino Phenol

Metanilic Acid 1.590

Potassium Hydroxide 1.600

Sulfuric Acid 0.380

28

Para amino benzamide

Ortho dichloro benzene (ODCB) 1.012

PNBA 0.500

Urea 0.595

PNBAM 0.445

Iron 0.445

Soda 0.140

HCl 0.405

29

1-Phenyl 3 Carbethoxy 5 Pyrazolone (PCEP)

Aniline 0.650

HCl 1.950

Sodium Nitrite 0.520

Sodium Bi Sulphite 1.800

Caustic Lyes 0.850

Sulfuric Acid 0.750

Hydrazine Sulfate 0.925

Oxal Ester 0.925

30

Bis Azo Barbaturic Acid (BABA)

3 Amino Guanidine 1.150

HCl 1.800

Sodium Nitrite 0.600

Barbituric Acid 1.000

Caustic Soda 0.850

31 2,5 Dichloro Phenol (2,5 DCP)

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M/s. Technichem Organics Pvt. Ltd. 9

Sulphuric Acid 2.200

2,5 Dichloro aniline 1.150

Urea 0.100

NaNO2 0.580

Sulphuric Acid 1.250

32

3,5 Di Amino Benzoic Acid

3,5 Di nitro benzoic Acid 1.800

Soda ash 0.500

HCl 1.525

Iron 1.150

33

Di methyl Pyridone (DMP)

Mono methyl amine 40% 1.030

Ethyl Aceto Acetate 0.850

Ethyl Cyno Acetate 0.750

Water 2.500

HCl (30%) 0.650

34

N-butyl-3-Cyno-6-hydroxy-4-Methyl-2-Pyridone (BMP)

NBA 0.750

Ethyl Aceto Acetate 0.650

Ethyl Cyno Acetate 0.600

35

N-3-methoxypropyl-3-Cyno-6-hydroxy-4-Methyl-2-Pyridone (MMP)

3-AMP 0.275

Ethyl Aceto Acetate 0.235

Ethyl Cyno Acetate 0.210

36

N-ethtyl-3-Cyano-6-hydroxy-4-methyl-2-Pyridone (EMP)

MEA 70% 0.800

Ethyl Aceto Acetate 0.800

Ethyl Cyno Acetate 0.700

37

Barbituric Acid

Methanol 2.500

Malonic Acid 0.625

Urea 0.402

Phosphoryl Chloride 0.020

HCl (30%) 0.080

(B) ACID DYES

1

Acid Yellow 17

Salfanilic Acid 0.280

HCl 0.550

NaNO2 0.150

DCSPMP 0.550

Na2CO3 0.200

KCl 0.300

2

Acid Yellow 36

Metanilic Acid 0.400

Sodium Nitrite 0.100

HCl 0.250

Diphenyl Amine 0.425

Caustic Flakes 0.150

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Soda Ash 0.200

3

Acid Yellow 42

BDSA 0.425

Soda Ash 0.150

Nitrite 0.180

HCl 0.750

PMP 0.400

Caustic Flakes 0.150

Soda Ash 0.200

4

Acid Yellow 49

2, 5 Dichloro Sulfanilic Acid 0.550

HCl 0.210

Sodium Nitrite 0.150

5-Amino PMP 0.390

HCl 0.100

Soda Ash 0.210

5

Acid Yellow 79

1,1 Dimethyl 4.4 Dihydroxy diphenyl Methane 0.370

4 Amino phenol 0.220

1:3 SPMP 0.680

HCl 0.450

Sodium Nitrite 0.125

Soda Ash 0.450

Diazo Ester 0.015

Sodium Chloride 0.270

6

Acid Yellow 110

Salphanilic Acid 0.400

NaNO2 0.115

HCl 0.370

2,5 DCSPMP 0.450

Soda Ash 0.075

7

Acid Yellow 232

1-Phenyl 3 Methyl 5 Pyrozozine 0.250

Salicylic Acid 0.075

Sodium Nitrite 0.160

Anthranilic Acid 0.150

Hydrochloric Acid 0.250

Soda Ash 0.270

Basic Chromium Sulfate 0.410

Sulphuric Acid 0.220

8

Acid Blue 113

Metanilic Acid 0.320

HCl 0.285

Sodium Nitrite 0.125

Alpha Napthyl Amine 0.250

Nitrite 0.150

H2SO4 0.270

Caustic Flakes 0.225

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M/s. Technichem Organics Pvt. Ltd. 11

Phenyl Peri Acid 0.450

Soda Ash 0.225

Sodium Acetate 0.320

9

Acid Red 119

Metanilic Acid 0.310

HCl 0.275

Sodium Nitrite 0.115

Alpha Napthyl Amine 0.220

Nitrite 0.100

H2SO4 0.230

Caustic Flakes 0.200

EBAMASA 0.450

Soda Ash 0.110

Sodium Acetate 0.330

10

Acid Red 183

4-CAPSA 0.350

HCl 0.100

Sodium Nitrite 0.095

3 SPMP 0.450

Soda Ash 0.425

Salicylic Acid 0.065

Basic Chromium Sulfate 0.450

Sulfuric Acid 0.215

11

Acid Red 315

4-CAPSA 0.350

HCl 0.105

Sodium Nitrite 0.100

3 SPMP 0.400

Soda Ash 0.425

Salicylic Acid 0.065

Basic Chromium Sulfate 0.450

Sulfuric Acid 0.250

12

Acid Red 357

6 NAPASA 0.450

HCl 0.075

Nitrite 0.120

PMP 0.300

Caustic Flakes 0.160

Salicylic Acid 0.050

B.C.S. 0.300

13

Acid Red 362

PMP 0.350

CFC 0.100

4-CAPSA 0.500

Sodium Nitrite 0.150

HCl 0.125

Salicylic Acid 0.065

BCS 0.350

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M/s. Technichem Organics Pvt. Ltd. 12

Caustic Flakes 0.075

14

Acid Red 414

6-NAPSA 0.350

P-tolyl-3-methyl-5-pyrazolone 0.280

5 NAP 0.200

Sodium nitrite 0.185

Sulphuric Acid 0.180

Sodium hydroxide 0.200

Salicylic Acid 0.045

Basic Chromium Sulfate 0.415

15

Acid Violet 90

1 Diazo 0.390

PMP 0.290

Caustic Flakes 0.175

Salicylic Acid 0.085

B.C.S. 0.315

16

Acid Brown 282

6-Nitro 0.250

Beta Napthol 0.100

Caustic Flakes 0.100

Salicylic Acid 0.065

B.C.S. 0.180

4NAP 0.200

HCl 0.035

Nitrite 0.100

PMP 0.200

17

Acid Brown 355

6-Nitro 0.210

Beta Napthol 0.120

Caustic Flakes 0.045

Salicylic Acid 0.060

B.C.S. 0.140

4NAPASA 0.165

HCl 0.055

Nitrite 0.050

PMP 0.150

Caustic Flakes 0.075

18

Acid Orange 142

4 NADASA 0.420

HCl 0.075

Nitrite 0.110

PMP 0.350

Caustic Flakes 0.100

Salicylic Acid 0.080

B.C.S. 0.300

Caustic Flakes 0.150

19

Acid Orange 74

PMP 0.380

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M/s. Technichem Organics Pvt. Ltd. 13

Caustic Soda 0.110

4 NAPSA 0.480

HCl 0.200

Sodium Nitrite 0.180

Salicylic Acid 0.085

BCS 0.670

Sulphuric Acid 0.315

20

Acid Orange 154

PMP 0.400

Caustic Soda 0.110

4 NAPSA 0.450

HCl 0.210

Sodium Nitrite 0.180

Salicylic Acid 0.110

BCS 0.700

Sulphuric Acid 0.320

21

Solvent Orange 58

2 amino phenol 4 N-Methyl sulfone 0.400

Sodium Nitrite 0.150

HCl 0.450

M-Chloro DMP 0.520

Chrominating Agent 0.075

Caustic Soda 0.250

22 Disperse Blue CB

Acetic Acid 1.050

C15H20N4O 0.550

HCl 2.100

Sodium Nitrite 0.175

Methanol 1.800

C17H24N25 0.565

Caustic Flakes 0.850

(C) PIGMENTS

1

Pigment Red 41

Sodium Hydroxide (50%) 0.410

1-phenyl 3-methyl, 5-pyrazoline 0.550

HCl (35%) 0.055

Acetic Acid 0.030

3,3 dimethoxy benzidine 0.400

Sodium nitrite 0.225

2

Pigment Orange 5

HCl 1.150

Sodium Nitrite 0.220

2,4-Dinitrobenzenamine 0.570

Napthalan 2 Ol 0.475

Sodium Hydroxide 0.310

Sodium Acetate 0.030

Rosin Solution 0.002

3 Pigment Orange 13

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M/s. Technichem Organics Pvt. Ltd. 14

1-phenyl-3-methyl-5-pyrazoline 0.610

Sodium Hydroxide (50%) 0.275

Acetic acid 0.045

Hydrochloric acid (35%) 0.060

3,3-dichlorobenzidine 0.435

Hydrochloric acid (31%) 1.000

sodium nitrite 0.250

Sodium Hydroxide (15%) 0.110

4

Pigment Orange 34

1-p-tolyl-3-methyl pyrazol-5-one 0.650

Sodium Hydroxide (50%) 0.325

Acetic acid 0.035

Hydrochloric acid (35%) 0.060

3,3-dichlorobenzidine 0.445

Hydrochloric acid (35%) 1.200

sodium nitrite 0.250

Sodium hydroxide (15%) 0.110

5

Pigment Orange 36

HCl (31%) 0.850

4 Chloro-2-Nitroaniline 0.375

Sodium nitrite (40%) 0.365

Sodium Hydroxide 0.200

5-Acetoacetyle amino benzimidazolone 0.500

Sodium acetate 0.185

6

Pigment Orange 64

HCl (31%) 0.750

5-amino-6-methyl-1,3-dihydro-2H benzimidazol-2-one 0.700

Sodium nitrite (40%) 0.345

Sodium acetate 0.035

Barbituric acid 0.285

7

Pigment Yellow 83

Acetoacet-2:5-dimethoxy-4-chloroanilide 1.000

Sodium hydroxide (50%) 0.320

Acetic Acid 0.025

Hydrochloric Acid (35%) 1.410

3,3-dichlorobenzidine 0.450

Sodium nitrite 0.250

Sodium hydroxide (15%) 0.115

8

Pigment Yellow 97

HCl 0.850

Sodium Nitrite 0.750

Amine 0.650

Coupler 0.350

Sodium hydroxide 0.085

Sodium Acetate 0.075

9

Pigment Yellow 110

O-Dichlorobenzene 4.000

1,4-Diaminobenzene 0.250

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M/s. Technichem Organics Pvt. Ltd. 15

3,3,4,5,6,7-Hexachloro-2,3-dihydro-1H-isoindol-1-one 1.000

Methanol wash 1.800

10

Pigment Yellow 114

N-Acetoacetyl-4-methylaniline 0.450

Acetoacetanilide 0.500

Sodium Hydroxide 0.325

Acetic Acid 1.400

HCl 0.350

Sodium Hydroxide 0.110

3,3-dichlorobenzidine 0.450

Sodium Nitrite 0.250

HCl 1.100

Sodium Acetate 0.075

11

Pigment Yellow 138

ODCB 3.200

8-aminoquinaldine 0.250

Tetrachlorophthalic anhydride 0.850

Methanol washing 1.800

12

Pigment Yellow 139

Sodium Methoxide (30%) 1.000

1,2 Dicynobenzene 0.450

Barbituric acid 0.340

Acetic Acid 0.030

MCB 1.450

Surfactants 0.005

13

Pigment Yellow 150

Aminoguanidine bicarbonate 0.075

Hydrochloric acid (30%) 0.500

Potassium nitrite (37%) 0.075

Barbituric acid 0.800

Potassium hydroxide 0.025

Melamine 0.025

Nickel chloride (6.5%) 1.450

14

Pigment Yellow 151

2-aminobenzoic acid 0.400

Hydrochloric acid (31%) 0.750

Sodium nitrite (40%) 0.450

Sodium hydroxide (25%) 0.150

5-Acetoacetylamino-benzimidazolone 0.650

Acetic acid 0.035

Sodium Hydroxide (10%) 0.150

Xylene 0.150

Caustic 0.010

15

Pigment Yellow 152

N-(4-ethoxyphenyl)-3-oxo butanamide 1.000

Sodium Hydroxide 0.410

Acetic Acid 0.035

HCl 0.300

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M/s. Technichem Organics Pvt. Ltd. 16

3,3 Dichlorobenzidine 0.450

Sodium nitrite 0.250

HCl 1.100

16

Pigment Yellow 154

2-(trifluoromethyl)aniline 0.400

Hydrochloric acid (31%) 0.700

Sodium nitrite (40%) 0.400

Sodium hydroxide (25%) 0.100

5-Acetoacetylamino-benzimidazolone 0.600

Acetic acid 0.030

Sodium Hydroxide (10%) 0.150

Xylene 0.150

Caustic 0.010

17

Pigment Yellow 155

HCl (31%) 1.250

Dimethyl-2-amino-terephthalate 0.750

Sodium nitrite (40%) 0.700

Sodium hydroxide 0.100

1,4-bis (Aceto Acetylamino) benzene 0.300

Sodium acetate 0.035

18

Pigment Yellow 168

Sodium Nitrite 0.350

4-Amino-3-nitro Benzene sulfonic acid 0.610

Acetic acid 0.030

N-(2-chloro phenyl)-3-oxo Butanamide 0.520

Sodium Hydroxide 0.350

Calcium Chloride 0.550

19

Pigment Yellow 174

HCl (31%) 0.900

3,3-dichlorobenzidine 0.600

Sodium nitrite (40%) 0.750

Sodium hydroxide 0.075

Acetoacet-2-methylanilide 0.250

Acetoacet-2:4-dimethylanilide 0.450

Sodium acetate 0.040

20

Pigment Yellow 180

2-(Ethylene dioxy) Dianiline acid 0.550

Sodium Nitrite 0.350

HCl 0.600

Acetic Acid 0.030

5- Aceto acetyl amino Benzimidazolone 0.500

Sodium Hydroxide 0.225

Caustic 0.010

Xylene 0.115

21

Pigment Yellow 181

4-(4-Aminobenz Amido) Benzamide 0.550

Sodium Nitrite 0.350

HCl 0.600

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M/s. Technichem Organics Pvt. Ltd. 17

Acetic Acid 0.025

5- Aceto acetyl amino benzimidazolone 0.500

Sodium Hydroxide 0.220

Caustic 0.010

Xylene 0.110

22

Pigment Yellow 183

Sodium hydroxide (33%) 0.575

2-Amino-4,5-dichloro-benzenesulfonic acid 0.525

Hydrochloric acid (31%) 0.650

Sodium nitrite (38%) 0.300

1-(3'-Sulfophenyl)-3-methyl-5- Pyrazolone 0.575

Calcium Chloride 0.255

23

Pigment Yellow 191:1

Sodium hydroxide (33%) 0.600

2-amino-4chloro-5-methyl-benzenesulfonic acid 0.480

Hydrochloric acid (31%) 0.650

Sodium nitrite (38%) 0.300

1-(3'-sulfophenyl)-3-methyl-5-pyrazolone 0.500

Ammonium Chloride 0.275

24

Pigment Red 146

HCl (31%) 0.900

3-amino-4-methoxybenzanilide 0.550

Sodium nitrite (40%) 0.350

Sodium hydroxide 0.100

4'-chloro-3-hydroxy-2-5'dimethoxy-2-Naphthanilide 0.750

sodium acetate 0.025

25

Pigment Red 170

HCl (31%) 1.000

4-aminobenzamide 0.320

Sodium nitrite (40%) 0.370

Sodium hydroxide 0.100

N-(2-ethoxyphenyl)-3-hydroxynaphthalene-2-carboxamide 0.650

Sodium acetate 0.110

26

Pigment Red 176

HCl (31%) 0.750

Amine 0.500

Sodium nitrite (40%) 0.360

Sodium hydroxide 0.085

Coupler 0.670

Sodium acetate 0.025

27

Pigment Red 177

Polyethylene glycol 1.150

Potassium hydroxide 0.350

Sodium chlorate 0.035

1-amino-4-bromo anthracene-9,10-Dione 1.250

28

Pigment Red 184

N-(3-amino-4-methoxyphenyl) benzamide 0.500

Sodium Nitrite 0.370

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M/s. Technichem Organics Pvt. Ltd. 18

HCl 0.750

Sodium hydroxide 0.095

5-Chloro-2-methylphenyl ) methanone 0.750

Sodium acetate 0.025

29

Pigment Red 185

2-Methyl-4-amino-5-methoxy-N-methyl benzene sulfonamide 0.450

Sodium Nitrite 0.385

HCl 0.850

Sodium hydroxide 0.110

3-Hydroxy-N-2-naphthamide 0.550

Sodium acetate 0.035

30

Pigment Red 187

3-Amino-4-methoxy-4-carbamoyl Benzanilide 0.450

Sodium Nitrite 0.400

HCl 0.800

Sodium hydroxide 0.080

3-Hydroxy-5-chloro-2,4-dimethoxy-2-Naphthanilide 0.735

Sodium acetate 0.020

31

Pigment Red 188

2′,5′-Dichloro-3-amino-4-methoxy carbonyl Benzanilide 0.550

Sodium Nitrite 0.365

HCl 0.850

Sodium hydroxide (50%) 0.095

2′-Methoxy-3-hydroxy-2-naphthanilide 0.465

Sodium acetate 0.025

32

Pigment Red 210

HCl (31%) 1.000

4-aminobenzamide 0.350

Sodium nitrite (40%) 0.380

Sodium hydroxide(50%) 0.120

3-hydroxy-N-(2-methoxy phenyl) naphthalene-2-carboxamide 0.580

Sodium acetate 0.035

3

Pigment Red 254

Tert-amyl alcohol 3.800

p-chlorobenzonitrile 1.000

Potassium tert-butoxide 0.100

Di-isopropylsuccinate 0.550

Methanol 3.000

34

Pigment Red 264

Tert-amyl alcohol 3.800

4-phenylbenzylnitrile 1.100

Potassium tert-butoxide 0.055

Di-isopropylsuccinate 0.650

Methanol 3.100

35

Pigment Red 122

HCl (31%) 0.850

2,4,5-trichloroaniline 0.400

Sodium nitrite (40%) 0.375

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M/s. Technichem Organics Pvt. Ltd. 19

Sodium hydroxide 0.090

3-hydroxy-2'methyl-2-naphthanilide 0.570

Sodium Acetate 0.045

4. MANUFACTURING PROCESS

Pl. refers Annexure-II of Form No. 1 for process description, chemical

reaction & mass balance of all products.

5. DETAILS OF MANPOWER

At present, 50 no of employees are employed. After expansion it will be

125 nos.

WATER CONSUMPTION & WASTE WATER GENERATION

Break up of Water consumption & waste water generation

Water Consumption

Sr. No.

Source Water Consumption

Existing (KL/day)

Water consumption after expansion

(KL/day)

1. Domestic 3.7 10.0

2. Green Belt 2.0 25

3. Industrial

A Water treatment 00 10.0

B Process 10 140

C Scrubber 00 10.5

D Boiler 3.0 30

F Cooling 2.0 45

G Washing 2.0 50

Total Industrial 17.0 285.5

Total (1 +2 + 3) 22.7 320.5

Less recycle -- 260

Actual fresh water consumption

22.7 60.5

Waste Water Generation

Sr. No.

Source Waste Water generation

Existing

(KL/day)

Waste Water generation

After expansion

(KL/day)

1. Domestic 2.7 8.0

2. Green Belt -- --

3. Industrial

A Water treatment -- 10.0

B Process 10 201

C Scrubber 00 3.0

D Boiler 2.0 3.0

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M/s. Technichem Organics Pvt. Ltd. 20

F Cooling 00 15.0

g Washing 2.0 50.0

Total Industrial 14.0 282.0

Total (1 +2 + 3) 16.7 300.0

6. SOURCE Of POLLUTION

Details of Air Pollution

The main source of emission will be of flue gas emission. Proper Stack

height and APCM will be provided in order to achieve norms prescribed by

statutory authority. Details of stacks are given below.

Sr.

No.

Stack

attached to

Fuel Type Stack

Height,

in m

APC

measures

Probable emission

Flue Gas Stacks

Existing

1. Boiler

(2.0 TPH)

Coal/

Biofuel -8.0

Mt/Day

15 Cyclone PM ≤ 150 mg/Nm3

SO2 ≤ 100 ppm

NOx ≤ 50 ppm

2. Thermic Fluid Heater

(5 lakhs kcal/hr.)

LDO – 1.25

Kl/Day

15 --

Proposed after expansion

1. Boiler

(5.0 TPH)

Coal/

Biofuel -20.0

Mt/Day

21 Cyclone &

bag filter

PM ≤ 150 mg/Nm3

SO2 ≤ 100 ppm

NOx ≤ 50 ppm

2. Thermic Fluid Heater

(5 lakhs kcal/hr.)

LDO – 1.25

Kl/Day

21 --

3. Hot Air Generator

(15 lakhs kcal/hr.)

Products Spray Dryer

Coal/

Biofuel -8.0

Mt/Day

21 --

2. D G Set

(250 kVA)

HSD-30 lit/hr. 11 --

Process Gas Stacks

Existing

1. Hydrolysis vessel

(2 Nos.)

-- 15 Water and

Alkali

Scrubber

NH3 ≤175 mg/nm3

SO2 ≤40 mg/Nm3

Proposed after expansion

1 Process vent of dyes

intermediates

-- 15 Water

Scrubber

NH3≤ 175 mg/nm3

2. Reaction vessel of

Multipurpose Plant-2

Sets

-- 21 Alkali

Scrubber

SO2 ≤ 40 mg/Nm3

3. Spray Dryer-1

(1500 Lit/Hr)

(For Product

Recovery)

-- 21 Cyclone +

scrubber +

submerged

type gas

PM ≤ 45 mg/Nm3

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M/s. Technichem Organics Pvt. Ltd. 21

4. Spray Dryer-2

(1200 Lit/Hr)

(For Effluent)

Coal/

Biofuel - 6.0

Mt/Day

15 bubbling

tank

PM ≤ 150 mg/Nm3

SO2 ≤ 100 ppm

NOx ≤ 50 ppm

5. Spray Dryer-3

(1200 Lit/Hr)

(For effluent)

Coal/

Biofuel - 6.0

Mt/Day

15

Source of wastewater

Generated industrial effluent will be treated in ETP followed to RO. RO

permeate will be reused and reject will be evaporated in in-house MEE and

spray dryer to achieve “Zero Liquid Discharge”. Domestic wastewater

will be disposed through soak pit.

Source and disposal of Hazardous wastes

There will be eight types of hazardous waste generation i.e. ETP sludge,

process iron sludge, process gypsum sludge, spent acid, spent alkali, SBS,

used oil and discarded containers/liners. ETP sludge will be disposed off at

TSDF site, Iron sludge and gypsum sludge will be disposed to cement

manufacturer or Disposal at TSDF site, spent acid and NaOH will be sold to

end user, SBS will be reused within premises, used will be disposed by

selling to registered re-processors and Discarded containers/liners will be

disposed by selling to registered recyclers. Detail of hazardous waste is

given below:

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Sr.

No.

Type of

Waste

Category

No. as per

HWM

rules,

2016

Quantity Method of

Disposal

Existing Proposed Total

1. ETP sludge

Spray Dryer

Salt

35.3 3.33

MT/Month

Nil

96.67

MT/month

155.0

MT/month

100

MT/month

155.0

MT/month

Collection, Storage,

Transportation,

Disposal at TSDF

site.

2. Process Iron

Sludge

26.1 2

MT/month

288

MT/Month

290

MT/Month

Collection, Storage,

Transportation and

sold to cement

manufacturer or

Disposal at TSDF

site.

3. Process

Gypsum

Sludge

26.1 Nil 240

MT/Month

240

MT/Month

Collection, Storage,

Transportation and

sold to cement

manufacturer or

Disposal at TSDF

site.

4. Discarded

Containers/Li

near/

Bags

33.1 2520

Nos./Year

2480

Nos./Month

1.0

Mt/month

5000

Nos./Month

Collection, Storage,

Decontamination,

Transportation,

Disposal by selling

to Authorized

Recycler.

5. Used Oil 5.1 Nil 0.5

KL/Year

0.5

KL/Year

Collection, Storage,

Transportation,

Disposal by selling

to Registered

Reprocess

6. Spent H2SO4

(70-75%)

26.3 Nil 675

KL/Month

675

KL/Month

Collection, storage

and sold to actual

users under Rule-9

of Haz. rules, 2016

7. SBS

(40-45%)

B(15) Nil 145

KL/Month

145

KL/Month

Collection, storage

and reuse within

premises or sold to

actual users under

Rule-9 of Haz.

rules, 2016.

8. Liq. Ammonia

(12-15%)

-- Nil 50

KL/month

50

KL/month

Collection, storage

and reuse within

premises or sold to

actual users under

Rule-9 of Haz.

rules, 2016.

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M/s. Technichem Organics Pvt. Ltd. 23

7. FUNDS FOR POLLUTION CONTROL MEASURES

The management is quite conscious of its responsibility for maintaining

clear environment adequate funds can be provided for the pollution control

measures as financing part of overall project. Necessary provision for

Environmental management system is in practice.

8. MONITORING FACILITIES

Air sampling will be done by outside agency and will be part of practice in

future projects.

9. CONCLUSION

On the basis of information presented in the pre-feasibility report on

pollution control measures and after its implementation, there will be no

discharge of effluent and air emission from the plant beyond the norms

specified by the Board as per the provisions of Air (Prevention and Control

of Pollution) Act, 1981 and Water (Prevention and Control of Pollution).