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Dispersing Agents Toolbox for hazard- label-free, universal pigment concentrates European Coatings Show 2017

Dispersing Agents Toolbox

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Page 1: Dispersing Agents Toolbox

Dispersing Agents Toolbox for hazard-

label-free, universal pigment

concentratesEuropean Coatings Show 2017

Page 2: Dispersing Agents Toolbox

What matters to pigment concentrate producers right now?

Creation of universal colorant lines for water-borne

and solvent-borne in plant tinting and point of sales

tinting

Optimum formulation for full range of colors

Complexity reduction in production and raw material

basket

Healthier paints fulfilling eco-labels

2

Page 3: Dispersing Agents Toolbox

What can the Dispersing Agents Toolbox do for you?

Our selection of dispersing agents for universal colorants

enables hazard-label-free and eco-label-certified final

paints.

This comes with no compromises on performance, and

applies to all colors and resins: It reduces complexity by

replacing two systems with one.

3

Page 4: Dispersing Agents Toolbox

Our Dispersing Agents Toolbox

4 dispersing agents create the toolbox:

4

Technology Solid

content

(%)

Appearance VOC (%)

ISO 17895

VOC (%)

ISO 11890-2

Product

Label

Eco-label

2014/312/EU

Dispex® Ultra PX

4525

Mixture of

amine- and

acid-functional

polymers

91 Clear yellow

to brownish

liquid

~ 0.3% < 1% H302,

H315,

H319

yes

Dispex® Ultra FA

4484

Anionic

Surfactant

26 Clear to

slightly

yellowish

liquid

< 0.1% < 0.05% H315 yes

Dispex® Ultra PX

4522

Nonionic

Polymer

100 Hazy

colorless

viscous liquid

< 0.1% < 0.01% Label-free yes

Dispex® Ultra FA

4488

Nonionic

Polymer

100 Clear to

slightly

yellowish

liquid

< 0.1% < 0.01% Label-free yes

Page 5: Dispersing Agents Toolbox

The Dispersing Agents Toolbox already has an impact

A key European paint manufacturer is launching a full

range of eco-label-certified colorants based on our

dispersing agents toolbox at the ECS 2017.

We believe that this is an important step towards a future

where a range of a few sustainable dispersants fits all

eco-label-certified tinting systems and paint

technologies. This will be a massive contribution to

earning the trust that consumers put into paint products.

5

Page 6: Dispersing Agents Toolbox

So how does it work?Guiding formulations.

6

Page 7: Dispersing Agents Toolbox

Guiding formulations by pigment I

7

TiO2

Kronos®

2310

Irgalite®

Yellow

L 1257

Bayferrox®

yellow

3920

Sicopal®

yellow

L 1100

Irgazin®

Red

L 3670 HD

Bayferrox®

Red

130M

Color Index PY 74 PY 42 PY 184 PR 254 PR 101

Dispex® Ultra FA 4484 2,5 2,5 7,5 3,3

Dispex® Ultra FA 4488 8,4

Dispex® Ultra PX 4522 4,0 7,50 2,5

Dispex® Ultra PX 4525 2,70 5,0 6,7

Dispex Ultra® PA 4501 4,0

Loxanol® PL 5813 12,0 10,00 12,0 10,0 8,0 8,0

Water, demineralized 19,7 38,55 25,0 18,9 52,1 20,7

NaOH 25% 1,1 0,25 0,8 0,6 0,5 0,9

Filler

Pigment 60,0 40,00 54,0 60,0 30,0 56,0

FoamStar® SI 2250 0,3 0,80 0,3 0,2 0,8 0,3

Rheology modifier 0,3 0,3 0,2

Preservative 0,1 0,20 0,1 0,1 0,2 0,1

Total 100,0 100,0 100,0 100,0 100,0 100,0

DoP 8% 25% 10% 7% 28% 19%

Page 8: Dispersing Agents Toolbox

Guiding formulations by pigment II

8

Irgalite®

Red

L 3865

Heliogen®

green

L 8735

Heliogen®

blue

L 7085

Hostaperm®

Rosa E

Hostaperm®

Violet

RL special

Special

Black®

100

Color Index PR 112 PG 7 PB 15:3 PR 122 PV 23 PBk 7

Dispex® Ultra FA 4484 5,0

Dispex® Ultra FA 4488 6,4 6,8 5,3 1,0

Dispex® Ultra PX 4522 4,0

Dispex® Ultra PX 4525 - 2,5 5,7 8,3 6,7

Loxanol® PL 5813 10,0 10,0 10,0 8,0 8,0 8,0

Water, demineralized 42,4 49,7 47,7 45,9 44,7 53,7

NaOH 25% 0,2 0,4 0,7 0,4 1,0 1,1

Filler 25,0 22,5

Pigment 40,0 30,0 30,0 10,0 15,0 30,0

FoamStar® SI 2250 0,8 0,5 0,5 0,3 0,3 0,3

Rheology modifier 0,2

Preservative 0,2 0,2 0,2 0,2 0,2 0,2

Total 100,0 100,0 100,0 100,0 100,0 100,0

DoP 16% 30% 35% 18% 50% 20%

Page 9: Dispersing Agents Toolbox

So how does it work?So how does it work?

9

Page 10: Dispersing Agents Toolbox

Most commonly used pigments were successfully tested in several systems

10

Type of paint Paint

WB paint 1 Facade paint

WB paint 2 Rubbol BL Azura

WB paint 3 Sigma Aqua PU

SB paint 1 Sigma Contour satin

SB paint 2 Rubbol AZ plus

Pigments tested

Irgalite® Yellow L 1257 Heliogen® Green L 8735

Bayferrox® Yellow 3920 Heliogen® Blue L 7085

Irgazin® Red L 3670 Hostaperm® Rosa E

Bayferrox® Red 130 M Hostaperm® Violet RL special

Irgalite® Red L 3865 Special Black® 100

Page 11: Dispersing Agents Toolbox

Results with Irgalite® Yellow L 1257Storage Stability and Color Strength

11

All Color DATA

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100 0,3 97 1 100 2,5 92 3,4Dispex Ultra PX 4522 117 0,9 96 1,1 124 1,5 94 0,8

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100 2,1 90 3,4 100 0,6 92 0,7Dispex Ultra PX 4522 110 0,6 109 0,8 106 0,2 103 1

WB paint 1 WB paint 2

SB paint 1 SB paint 2

Page 12: Dispersing Agents Toolbox

12

Results with Irgalite® Yellow L 1257Compatibility/Rub-out

Water based 1

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

PX 4522

Solvent based 2

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

PX 4522

Page 13: Dispersing Agents Toolbox

Results with Bayferrox® Yellow 3920Storage Stability and Color Strength

All Color DATA

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra

FA 4425100% 0,6 93% 1,4 100% 0,7 94% 0,9

Dispex Ultra FA 4484 & PX 4525 103% 0,8 96% 0,7 103% 1,0 88% 2,0

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra

FA 4425 100% 0,70 97% 0,10 100% 0,70 97% 0,60

Dispex Ultra FA 4484 & PX 4525 107% 0,50 86% 0,70 93% 0,70 105% 0,50

WB paint 1 WB paint 2

SB paint 1 SB paint 2

13

Page 14: Dispersing Agents Toolbox

Results with Bayferrox® Yellow 3920Compatibility/Rub-out

Water based 1

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

FA 4484/PX 4525

Solvent based 1

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

FA 4484/PX 4525

14

Page 15: Dispersing Agents Toolbox

Results with Sicopal® Yellow L 1100Storage Stability and Color Strength

All Color DATA

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra PX 4575 100% 2,5 99% 2,1 100% 0,0 102% 0,2

Dispex Ultra FA 4484 & PX 4522 101% 1,7 100% 0,9 92% 0,7 124% 0,4

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra PX 4575 100% 0,6 104% 0,7 100% 0,8 100% 0,4

Dispex Ultra FA 4484 & PX 4522 297% 0,5 99% 0,2 313% 1,3 105% 0,7

WB paint 1 WB paint 2

SB paint 1 SB paint 2

15

Page 16: Dispersing Agents Toolbox

Results with Sicopal® Yellow L 1100Compatibility/Rub-out

Reference

Dispex® Ultra

PX 4575

New

Dispex® Ultra

FA 4484/PX 4522

Reference

Dispex® Ultra

PX 4575

New

Dispex® Ultra

FA 4484/PX 4522

16

Water based 1 Solvent based 1

Page 17: Dispersing Agents Toolbox

Results with Irgazin® Red L 3670Storage Stability and Color Strength

All Color DATA

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100% 0.2 110% 0.2 100% 0.3 96% 0.2Dispex Ultra FA 4488 101% 0.2 102% 0.1 89% 0.6 96% 0.5

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100% 0.3 114% 0.1 100% 0.3 96% 0.1

Dispex Ultra FA 4488 101% 0.3 109% 0.2 109% 0.5 99% 0.3

WB paint 2 WB paint 3

SB paint 1 SB paint 2

17

Page 18: Dispersing Agents Toolbox

Results with Irgazin® Red L 3670Compatibility/Rub-out

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

FA 4488

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

FA 4488

18

Water based 1 Solvent based 1

Page 19: Dispersing Agents Toolbox

Results with Bayferrox® Red 130 MStorage Stability and Color Strength

All Color DATA

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100% 0.1 97% 0.5 100% 0.2 96% 0.5Dispex Ultra PX 4525/ FA 4484/ PA 4501 90% 0.4 104% 0.5 95% 0.7 102% 0.4

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100% 0.1 111% 0.2 100% 0.2 95% 0.4

Dispex Ultra PX 4525/ FA 4484/ PA 4501 77% 1.7 116% 1.7 60% 4,2 122% 1.7

WB paint 2 WB paint 3

SB paint 1 SB paint 2

19

Page 20: Dispersing Agents Toolbox

Results with Bayferrox® Red 130 MCompatibility/Rub-out

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

PX 4525/FA 4488/PA4501

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

PX 4525/FA 4488/PA4501

20

Water based 1 Solvent based 1

Page 21: Dispersing Agents Toolbox

Results with Irgalite® Red L 3865Storage Stability and Color Strength

All Color DATA

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100 1,9 105 2,2 100 2 94 1,8Dispex Ultra FA 4488 100 0,6 110 0,4 102 1,25 94 1,9

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100 1,2 106 2,3 100 1,2 95 1,1Dispex Ultra FA 4488 116 0,5 97 1 102 0,5 93 1,2

WB paint 1 WB paint 2

SB paint 1 SB paint 2

21

Page 22: Dispersing Agents Toolbox

Results with Irgalite® Red L 3865Compatibility/Rub-out

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

FA 4488

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

FA 4488

22

Water based 1 Solvent based 1

Page 23: Dispersing Agents Toolbox

Results with Heliogen® Green L 8735Storage Stability and Color Strength

All Color DATA

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100 1 103 1 100 1,8 100 0,6Dispex Ultra FA 4488/

Dispex Ultra PX 4525103 0,1 98 0,5 110 1,8 93 0,4

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100 1 94 1,3 100 0,6 84 0,6Dispex Ultra PX 4525 /

Dispex Ultra FA 4488 97 0,1 101 0,1 93 0,4 92 0,3

WB paint 1 WB paint 2

SB paint 1 SB paint 2

23

Page 24: Dispersing Agents Toolbox

24

Results with Heliogen® Green L 8735Compatibility/Rub-out

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

FA 4488/PX 4525

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

FA 4488/PX 4525

Water based 1 Solvent based 1

Page 25: Dispersing Agents Toolbox

Results with Heliogen® Blue L 7085Storage Stability and Color Strength

All Color DATA

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100 1,8 101 1,4 100 1,5 95 1,5Dispex Ultra PX 4525 /

Dispex Ultra FA 448888 0,3 113 0,1 104 1,4 83 1,1

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100 0,5 100 0,4 100 0,3 87 0,4Dispex Ultra PX 4525 /

Dispex Ultra FA 4488 103 0,5 100 0,8 97 0,3 95 0,2

WB paint 1 WB paint 2

SB paint 1 SB paint 2

25

Page 26: Dispersing Agents Toolbox

Results with Heliogen® Blue L 7085Compatibility/Rub-out

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

PX 4525/FA 4488

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

PX 4525/FA 4488

26

Water based 1 Solvent based 1

Page 27: Dispersing Agents Toolbox

Results with Hostaperm® Rosa EStorage Stability and Color Strength

All Color DATA

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°CDispex Ultra

FA 4425100% 2,0 110% 2,1 100% 0,9 100% 0,3

Dispex Ultra

FA 4484 FA 4488 PX 4522 98% 0,8 94% 1,6 102% 0,4 95% 0,8

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°CDispex Ultra

FA 4425 100% 0,2 90% 0,5 100% 0,4 92% 0,3Dispex Ultra

FA 4484 FA 4488 PX 4522 77% 0,3 100% 0,4 86% 1,4 105% 1,8

WB paint 1 WB paint 3

SB paint 1 SB paint 2

27

Page 28: Dispersing Agents Toolbox

Results with Hostaperm® Rosa ECompatibility/Rub-out

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra FA 4484

/FA 4488/PX 4522

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra FA 4484/FA

4488/PX 4522

28

Water based 1 Solvent based 1

Page 29: Dispersing Agents Toolbox

Results with Hostaperm® Violet RL specialStorage Stability and Color Strength

All Color DATA

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100% 0.1 91% 0.6 100% 0.2 98% 0.3Dispex Ultra PX 4525 127% 0.2 96% 0.1 127% 0.4 96% 0.4

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100% 0.1 98% 0.2 100% 0.1 102% 0.1

Dispex Ultra PX 4525 130% 0.4 104% 0.0 121% 0.5 100% 0.3

WB paint 2 WB paint 3

SB paint 1 SB paint 2

29

Page 30: Dispersing Agents Toolbox

Results with Hostaperm® Violet RL specialCompatibility/Rub-out

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

PX 4525

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

PX 4525

30

Water based 2 Solvent based 1

Page 31: Dispersing Agents Toolbox

Results with Special Black® 100Storage Stability and Color Strength

All Color DATA

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100% 0.1 104% 0.1 100% 0.1 89% 0.1Dispex Ultra PX 4525 100% 0.1 97% 0.2 97% 0.0 103% 0.2

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Relative

color

strength Rubout

Dispersant fresh fresh 2w 50°C 2w 50°C fresh fresh 2w 50°C 2w 50°C

Dispex Ultra FA 4425 100% 0.1 104% 0.1 100% 0.3 93% 0.1

Dispex Ultra PX 4525 104% 0.1 96% 0.1 93% 0.8 99% 0.0

WB paint 2 WB paint 3

SB paint 1 SB paint 2

31

Page 32: Dispersing Agents Toolbox

Results with Special Black® 100Compatibility/Rub-out

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

PX 4525

Reference

Dispex® Ultra

FA 4425

New

Dispex® Ultra

PX 4525

32

Water based 2 Solvent based 1

Page 33: Dispersing Agents Toolbox

formulate hazard-label-free, universal pigment

concentrates?

So would you like to…

Dispex® Ultra PX 4525

Dispex® Ultra FA 4484

Dispex® Ultra PX 4522

Dispex® Ultra FA 4488

... test our system with our new technology now!

33

Page 34: Dispersing Agents Toolbox

[email protected]

+41 8888 8888

[email protected]

www.basf.com

... test our system with our

new technology now!

Page 35: Dispersing Agents Toolbox

This tool provides you the best additive solution for your

challenging formulation task :

• From dispersing agents, wetting agents and surface

modifiers, to defoamers, rheology modifiers and film-forming

agents

Explore the BASF formulation additives portfolio for the

paints and coatings industry, by :

• Receiving recommendations for your formulation challenges

• Understanding the main benefits of our products by

application and get technical information

• Ordering samples or contacting us for more detailed

consultations

Check out our Solution Finder Tool on www.basf.com/formulation-additives

BASF Solution Finder Tool

for Formulation Additives

Page 36: Dispersing Agents Toolbox

Toolbox benefits

Performance benefits:

Allows for formulation of universal

colorants

Has a broad pigment application

latitude

Offers the possibility to create

optimum pigment concentrates for

full range of colorants

Excellent compatibility in water- and

solvent-based systems

Excellent storage stability

Sustainability benefits:

Low VOC according to DIN EN ISO

17895 (TÜV) and ISO 11890-211

APEO-free2

Allows formulation of label–free

universal colorants

Complies with the 2014 revision of

the Eco-flower label

36

1 VOC content <1% 2 APEO not intentionally added. Product may comprise minor traces as ubiquitiously occuringimpurities cannot be excluded

Page 37: Dispersing Agents Toolbox

Country registration

37

REACH TSCA DSL CHEMINV ECLISHL &

ENCSIECSC Taiwan AICS NZIoC PICCS

Dispex® Ultra

PX 4525Compliant

In

progress

In

progressListed Listed Listed Listed

In

progress

In

progress

In

progressExempt

Dispex® Ultra

FA 4484Compliant

In

progress

quantity

exceptionListed

In

progressListed

In

progress

In

progress

In

progress

In

progressListed

Dispex® Ultra

PX 4522Compliant Listed Listed Exempt Listed Listed Listed Listed Listed Listed Listed

Dispex® Ultra

FA 4488Compliant Listed Listed Exempt Listed Listed Listed Listed Listed Listed Listed