EFFECT OF UNPROCESSED RICE HUSK ASH AS A CEMENTITIOUS MATERIAL IN CONCRETE.pdf

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    International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 6308

    (Print), ISSN 0976 6316(Online) Volume 4, Issue 2, March - April (2013), IAEME

    240

    EFFECT OF UNPROCESSED RICE HUSK ASH AS A CEMENTITIOUS

    MATERIAL IN CONCRETE

    (A COMPARISON WITH SILICA FUME)

    Mohammad Qamruddin1, Prof.L.G.Kalurkar

    2

    1Master of Civil Structures, Civil Engineering, Faculty of Engineering, Jawaharlal Nehru

    Engineering College Aurangabad2Professor at Jawaharlal Nehru Engineering College Aurangabad Dr.Babasaheb Ambedkar

    Marathwada University, Aurangabad,431001, Maharashtra

    ABSTRACT

    Fast depleting natural resources, huge consumption of energy, and environmental

    hazards involved in the production of cement has inspired for searching the substitution by

    other material with similar material, especially in developing countries. Rice husk ash

    (RHA), an agricultural waste, is classified as a highly active pozzolan because it contains a

    very high amount of amorphous silica and a large surface area. The objective of the study is

    to investigate the mechanical properties of concrete with different replacement levels of

    ordinary Portland cement by rice husk ash and silica fume individually and in combination.

    The cylinders (150mmdia x 300mmheight) were cast. The splitting tensile strength at 7days

    and 28 days have been obtained with normal curing regime. For RHA a maximum increase in

    splitting tensile strength was 10% whereas for silica fume it was 17% compared with nominalmix when used individually. Combination of RHA and silica fume did not show any exciting

    results.

    Keywords: Rice husk ash, Silica fume, cementitious material, concrete.

    INTERNATIONAL JOURNAL OF CIVIL ENGINEERING AND

    TECHNOLOGY (IJCIET)

    ISSN 0976 6308 (Print)

    ISSN 0976 6316(Online)

    Volume 4, Issue 2, March - April (2013), pp. 240-245 IAEME:www.iaeme.com/ijciet.asp

    Journal Impact Factor (2013): 5.3277 (Calculated by GISI)www.jifactor.com

    IJCIET

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    International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 6308

    (Print), ISSN 0976 6316(Online) Volume 4, Issue 2, March - April (2013), IAEME

    241

    1. INTRODUCTION

    With growing environmental consciousness at all levels of society, the pollution and

    health hazards especially associated with the concrete and cements industries, is comingunder intense scrutiny from environmentalists and the governments. The developed countries

    are farther ahead in tackling the problem by using industrial and agricultural wastes in their

    industries. These industrial and agricultural wastes are mostly the by-products of oil and coal

    burning by-products, slag, rice husk ash, bagasse, fly ash, cement dust, stone crusher dust,

    marble dust, brick dust, sewer sludge, glass, tires, etc. Million tons of these waste materials

    are abundantly available and discarded every year in the world. They pose environmental

    problems like air pollution and leaching of hazardous and toxic chemicals (arsenic, beryllium,

    boron, cadmium, chromium, chromium(VI), cobalt, lead, manganese, mercury, molybdenum,

    selenium, strontium, thallium, and vanadium, along with dioxins and polycyclic aromatic

    hydrocarbon compounds, etc.) when dumped in landfills, quarries, rivers and oceans [1,2].

    Consequently air and water pollution have been inextricably linked to environmental

    problems and climate change. The production of cement (key binding component ofconcrete) is costly, consumes high energy, depletes natural resources and emits huge amounts

    0of greenhouse gases (1 ton of cement production emits approximately 1 ton of CO2).

    Consequently, environmental degradation, serious pollution and health hazards associated

    with cement and concrete industries.

    Rice Husk is one of the waste materials in the rice growing regions. This not only

    makes the purposeful utilization of agricultural waste but it will also reduce the consumption

    of energy used in the production of cement. Therefore Rice Husk is an agro based product

    which can be used as a substitute of cement without sacrificing the strength and durability.

    Generally the Rice Husk Ash is used while burning the raw clay bricks in the Brick Kilns.

    Till recently it is also used in Hotels for cooking but now it is replaced by LPG Gas. Since

    Rice Husk has negligible protein content, it is not useful for animal feeding. Rice Husk Ash is

    obtained from burning of Rice Husk, which is the by-product of rice milling. It is estimatedthat 1,000 kg of rice grain produce 200 kg of Rice Husk; after Rice Husk is burnt, about 20

    percent of the Rice Husk or 40 kg would become RHA. Rice Husk Ash contains as much as

    80-85% silica which is highly reactive, depending upon the temperature of incineration. Due

    to relative high water demand, the lime Rice Husk Ash cement developed lower compressive

    strengths. However, the strength characteristics are considered adequate for general masonry

    work. The water demand for normal consistency tends to increase with increasing Ash

    content of the blended cements. However, this can be corrected by application of certain

    water reducing admixtures. The investigations as outlined above point towards encouraging

    trend. Normally fly Ash may be used for partially replacing cement to the extent of about

    25% of cement. Reactions that take place in the preparation of Rice Husk Ash concrete are;

    Silicon burnt in the presence of Oxygen gives Silica.

    Si + O2 SiO2

    C3S (Cement) + H2O CSH + Ca (OH) 2

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    International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 6308

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    242

    The highly reactive silica reacts with Calcium hydroxide released during the hydration of

    cement, resulting in the formation of Calcium Silicates responsible for strength.

    SiO2 + Ca (OH)2 CSH + SiO2

    Mehta, P.K., (1) has conducted investigations on Portland Rice Husk Ash cements up to

    50% of Ash showed higher compressive strength than the control Portland cement even at as

    early as 3 days. Mehta, and Pirtz (2) in a concrete mixture, when 30% Rice Husk Ash by

    weight of the total cementing material was present, the 7 days and the 28 days compressive

    strengths were higher. Subba Rao.et.al (3) studied the reaction product of lime and silicate

    from Rice Husk Ash and showed that it is Calcium Silicate Hydrate (C-S-H) which accounts

    for the strength of lime Rice Husk Ash cements.

    2. MATERIAL PROPERTIES INVESTIGATED FOR THIS RESEARCH

    Table 1:- Material Properties

    1 Nominal Max.Size of coarse aggregate 20 mm

    2 Slump range (Medium) 50-75 mm IS 10262-2009

    (Pg.02)

    3 Finness Modulus Of Fine Aggregate 2.88 Confirming to zone II (IS 383-1970)

    4 Finness Modulus Of Steel Slag

    aggregate

    2.86 Confirming to zone II (IS 383-1970)

    5 Finness Modulus Of Coarse Aggregate 5.12 Confirming to zone II (IS 383-1970)

    6 Specific Gravity Of Fine Aggregate 2.65

    7 Specific Gravity Of Steel Slag aggregate 2.67

    8 Specific Gravity Of Coarse Aggregate 2.75

    9 Specific Gravity Of Cement 3.15

    10 Water Absorption of fine aggregates 4.7 %

    11 Water Absorption of coarse aggregates 1.65 %

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    International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 6308

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    3. CHEMICAL COMPOSITION AND PHYSICAL PROPERTIES OF RICE HUSK

    ASH USED IN THE STUDY

    Table 2:- Chemical Composition of rice husk ash:

    Constituent SiO2 Al2O3 Fe2O3 CaO MgO SO3 Na2O K2O

    Percentage ( % ) 94.84 0.39 0.54 1.32 0.40 0.01 0.11 1.45

    Table 3:- Physical Properties of rice husk ash

    Physical Properties Steel Slag

    Colour Grey

    Appearance Amorphous

    specific gravity 2.17

    3.1 RHA characteristics

    A residual RHA obtained from open filed burning from local resource was used. Thematerial was carefully homogenised packed to enhance the transport to the laboratory.

    Grinded RHA (GRHA): after drying and homogenization process the RHA was ground in a

    laboratory ball mill by one hour for optimization. The size and shape of the natural rice husk

    ash particles make difficult the development of pozzolanic reactions and the water demand

    strongly increases. The GRHA was passed through IS 90 micron sieve and this was used for

    the research. Adopting an adequate sequence for concrete mixing process, where the RHA

    and the coarse aggregates are mixed during a certain time and after that the rest of component

    materials are incorporated, the RHA characteristics can be improved. Table 2 and 3 presents

    some chemical composition of the ash and the physical characteristics.

    4. EXPERIMENTAL PROGRAM

    Materials used in this study were OPC 53 grade cement confirming to IS 8112 and

    fine aggregate and coarse aggregate confirming to IS 383-1970.The cement and aggregate

    were tested to fulfill the IS requirements.

    Rice husk ash was replaced with cement as 10%, 15%, 20% and 25%, similarly silica

    fume was also replaced with cement in different batches with percentage replacements

    as10%, 15%, 20% and 25%. In the third step rice husk ash and silica fume were replaced in

    combination as

    Rice husk ash and silica fume were replaced according to following table

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    International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 6308

    (Print), ISSN 0976 6316(Online) Volume 4, Issue 2, March - April (2013), IAEME

    244

    Table 4:-

    Batch Cement(%) RHA(%) Silica fume(%)

    1 100 0 0

    2 90 10 03 85 15 0

    4 80 20 0

    5 75 25 0

    6 90 0 10

    7 85 0 15

    8 80 0 20

    9 75 0 25

    10 90 5 5

    11 85 7.5 7.5

    12 80 10 10

    13 75 12.5 12.5

    14 75 15 10

    15 70 20 10

    16 65 25 10

    Designed concrete mix of M-20 grade having mix proportion 1:1.90:2.96 with w/c ratio 0.5

    same for different percentages of rice husk ash and silica fume were used.

    The concrete ingredients namely, cement and coarse aggregates and rice husk ash and silica

    fume according to batches were first mixed in the dry state and water was added last.

    Cylinders of size 150mm diameter x 300mm length for split tensile strength, Cubes of size

    150x150x150 mm for compressive strength were cast replacing rice husk ash and silica fume

    by weight of cement.All the samples were watered cured for 7 days and 28 days. For each batch of RHA and silica

    fume percentage replacement 6 specimens were cast. Details of the experimental

    investigation of effect of different percentages replacement of fine aggregate by steel slag are

    given elsewhere.

    4.1 Testing Programme

    4.1.1 Compressive Strength

    The cube specimen was placed in the machine, of 1000kN capacity. The load was

    applied at a rate of approximately 140 kg/sq.cm/min until the resistance of the specimen to

    the increasing load can be sustained. Results are presented in Tables 5 and 6.

    4.1.2 Splitting Tensile Strength

    The cylinder specimen was placed horizontally in the centering with packing skip or

    loading pieces carefully positioned along the top and bottom of the plane of loading of the

    specimen. The load was applied without shock and increased continuously at a nominal rate

    within the range 1.2 N/mm2/min to 2.4 N/mm2/min until failure the specimen. The maximum

    load applied was recorded at failure.

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    International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 6308

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    TEST RESULTS FOR SPLITTING TENSILE STRENGTH

    4. DISCUSSIONS ON TEST RESULTS

    4.1 Splitting tensile Strength of Concrete

    As the replacement level increases there is increase in splitting tensile strength at 28

    days age of strength. The maximum splitting tensile strength for the replacement with RHA

    and silica fume individually was 4.54 and 4.78 respectively. An increase of 14% and 20%

    was observed for RHA and silica fume individually. RHA and silica fume in combination

    showed a decreasing trend of strength.

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    International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 6308

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    246

    5. CONCLUSIONS

    1. Replacement of cement with Rice Husk Ash leads to increase in the compressive strength

    at 14% at 15% replacement.2. Optimum replacement level for silica fume was found to be 20% where 17% increase in

    splitting tensile strength is observed.

    3. The strength achieved for the replacement of combination of RHA and SF was even less

    than the nominal mix but cannot be authenticated due to less number of tests.

    REFERENCES

    [1] P.K.Mehta, Properties of Blended Cements Made from Rice Husk Ash, ACI

    Journal/September 1977 pp. 440-442.

    [2] P.K.Mehta and D.Pritz, Use of Rice Husk Ash to Reduce Temp in HSC,

    Journal/February 1978 pp. 60-63.

    [3] James, J., Subba rao .M., Reactive of Rice Husk Ash, Cement and Concrete Research,Vol.16, 1986.

    [4] Rahman M.N., Curing of RHA Mix sand concrete blocks, International Journal of

    Structures, Vol. 8, No.1, 1988.

    [5] Seshagiri Rao M.V., Chankravarthi R.K., Narasimha Murthy, Rice Husk Ash Blend

    Cement National Seminar on Recent Advances in Civil Engg. With Special. Reference to

    Building Industry, JNTU College of Engg. & Tech., Hyderabad1992.

    [6] K. Sasiekalaa and R. Malathy, Flexural Performance of Ferrocement Laminates

    Containing Silicafume and Fly Ash Reinforced With Chicken Mesh, International Journal of

    Civil Engineering & Technology (IJCIET), Volume 3, Issue 2, 2012, pp. 130 - 143,

    ISSN Print: 0976 6308, ISSN Online: 0976 6316.

    [7] Raju Sathish Kumar, Janardhana Maganti and Darga Kumar Nandyala, Rice Husk Ash

    Stabilized Compressed Earth Block-A Sustainable Construction Building Material AReview, International Journal of Civil Engineering & Technology (IJCIET), Volume 3,

    Issue 1, 2012, pp. 1 - 14, ISSN Print: 0976 6308, ISSN Online: 0976 6316.