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HYDKOTHEKMAL XNERALIZATION AT SEAFLOOR SPREADING CENTEKS: ATLANTIC OCEAN AKD IHDWN OCEAN Peter A. Zona NationalOceanicandAtmosphericAdministration Atlantic Oceanographic and Meteorological Laboratories 4301 Rickenbacker Causeway Wami, Florida 33149 Hydrothermal mineral deposits including poly- metalLic (Cu, Fe, Pb, Zn; associated Ag, Au) sulfides are formed by precipitation from hot aqueous (hydro- thernal) solutions that convect through seafloor spreading centers driven by volcanogenic heat sources. Approxinately 50 sites of hydrothersal mineral deposits including polymetallic sulfides are presently known along the approximately 54,000 icm length of the globe-encircling system of oceanic ridges and rifts that extend through alL the major ocean basins as seafloor spreading centers. The form of the deposits is closely related to their geologic setting. Strati- form sulfide bodies may form under conditions of rescricced oceanic circulation at an early scage of opening of an ocean basin about a slow-spreading center, exemplified by deposits in basins of the 2ed Sea. Disseminated and stockwork sulfides may form beneath the seafloor where hot (350'), acidic, reducingprimaryhydrothermalsolutions rnix withcold, alkaline, oxidizing normal seawater that penetrates downward through fractures in the oceanic crust, exemplified by deposits beneath the slow-spreading Mid-Atlantic Ridge. Hassive sulfide deposits may form on the seafloor where prisary hydrothermal solutions discharge directly from vents into normal seawater, exemplified by deposits near the axis of the fast- spreading East Pacific Rise. Nearly two-thirds of the 54,000 km length of the globe-encircling system of oceanic ridges and rifts are slow-sprsadigg (half-rate < 2 cm/yr) and are located in the Atlantic Ocean a;;d Indian Ocean (Fig. 1). Systematic investigations for hydrothersal mine- ralization were performed along 1800 km-long portions of the ?Ed-Atlantic Ridge (UR) crest between latitude 10' and 27"N in the central North Atlantic, and the Carlsberg Ridge (CR) crest betveen latitude 5'5 and 10CN in the northwest Indian Ocean. Criteria developed and applied to locate hydrothermal minerali- zation include characteristic seafloor morphology, definitive magnetic signature, composition and mine- ralogy of sediments and rocks, and certain water properties ( 3He ; near-bot tom water temperature). The two slow-spreading oceanic ridges investigated exhibit a segmented structure vith linear sections of rift valley alternating with ridge-ridge transform faults at an average spacing of 75 km . The investigations revealed hydrothermal mineral deposits that were concentrated by high-intensity hydrothermal activity at localized sites of anomalously high thermal gradients and permeabilities within tectonic settings related to the segmented structure of the ridges as follows: (1) The w a l l along linear sections of the rift valley where normal faults act as conduits for deep-seated, long-lived hydrothermal activity, with deposition of disseminated, stockwork, and possibly massive polymetallic sulfides inferred beneath the seafloor as a consequence of subsurface mixing of high-ismperature hydrothermal solutions with normal seawater, deposition of Fe-t4n oxides, hydroxides and silicates as layered bodies at the basalt/seawater interface, and precipitation of ferric hydroxide particles from the discharging solution reduced in temperature and depleted in metals; examples are the TAG Hydrothermal Field and five additional candidate sites identified along the MAR. (2) The intersection of the rift valley with ridge-ridge transform faults where thinning of oceanic crust and faulting has exposed disseminated and stockwork Cu-Fe sulfides; examples occur inthe Vema and Romanche f r a c t u r ez o n e s of the HAR and the Vityaz fracture zone of the CK. (3) Tne axial zone of the rift valley constitutes an inadequately explored province with the possibility for the occurrence of massive sulfides. Evidence presented indicates that extensive hydrothermal mineralizationoccurs on slox-spreading oceanic ridges but, unlike that on intermediate- to fast-spreading ridges in the Pacific Ocean, the bulk of the high- temperature mineralization occurs beneath the seafloor. 60' 40' 20' 0" 20' 40' 60' Fig. 1: World map showing boundaries of lithospheric plates (divergent plate boundaries are seafloor spreading centers), locations of known hydrothermal deposits (dots) at seafloor spreading centers, and belts of oceanic crust exposed on l a n d( o p h i o l i t e s )( f r o mb n a , 1982, MTS Journal, V. 16, No. 3). 817 U.S. Government work not protected by US. copyright.

[IEEE OCEANS '83 - San Francisco, CA, USA (1983.08.29-1983.09.1)] Proceedings OCEANS '83 - Hydrothermal Mineralization At Seafloor Spreading Centers: Atlantic Ocean And Indian Ocean

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Page 1: [IEEE OCEANS '83 - San Francisco, CA, USA (1983.08.29-1983.09.1)] Proceedings OCEANS '83 - Hydrothermal Mineralization At Seafloor Spreading Centers: Atlantic Ocean And Indian Ocean

HYDKOTHEKMAL X N E R A L I Z A T I O N AT SEAFLOOR SPREADING CENTEKS: ATLANTIC OCEAN A K D IHDWN OCEAN

Pe te r A. Zona Nat ional Oceanic and Atmospheric Adminis t ra t ion

Atlant ic Oceanographic and Meteorological Laborator ies 4301 Rickenbacker Causeway

W a m i , F l o r i d a 33149

Hydrothermal mineral deposi ts including poly- metalLic (Cu, Fe, Pb, Zn; a s s o c i a t e d Ag, Au) s u l f i d e s a r e formed by p r e c i p i t a t i o n from hot aqueous (hydro- t h e r n a l ) s o l u t i o n s t h a t c o n v e c t t h r o u g h s e a f l o o r sp read ing cen te r s d r iven by volcanogenic hea t sources . Approxina te ly 50 s i t e s of h y d r o t h e r s a l m i n e r a l d e p o s i t s i n c l u d i n g p o l y m e t a l l i c s u l f i d e s a r e p r e s e n t l y known a long the approximate ly 54,000 icm l e n g t h of t he g lobe-enc i rc l ing sys tem of ocean ic r i dges and r i f t s tha t ex tend th rough alL the major ocean basins as s e a f l o o r s p r e a d i n g c e n t e r s . The form of the deposi ts is c l o s e l y r e l a t e d t o t h e i r g e o l o g i c s e t t i n g . S t ra t i - form su l f ide bodies may form under conditions of r e s c r i c c e d o c e a n i c c i r c u l a t i o n a t an ear ly scage of opening of an ocean basin about a slow-spreading c e n t e r , e x e m p l i f i e d by d e p o s i t s i n b a s i n s of t he 2ed Sea. Disseminated and stockwork sulfides may form benea th t he s ea f loo r where ho t (350 ' ) , a c id i c , reducing pr imary hydro thermal so lu t ions rnix wi th co ld , a lka l ine , ox id i z ing no rma l s eawa te r t ha t pene t r a t e s downward t h r o u g h f r a c t u r e s i n t h e o c e a n i c c r u s t , exempl i f ied by depos i t s benea th the s low-spreading Mid-Atlant ic Ridge. Hassive sulf ide deposi ts may form on the s ea f loo r where p r i s a ry hydro the rma l so lu t ions d i scha rge d i r ec t ly f rom ven t s i n to no rma l seawater, exempl i f ied by depos i t s nea r t he ax i s of t h e f a s t - sp read ing East P a c i f i c Rise.

Nearly two-thirds of t he 54,000 km l eng th of the g lobe-enc i rc l ing sys tem of oceanic r idges and r i f t s a r e s low-sp r sad igg (ha l f - r a t e < 2 cm/yr) and are l o c a t e d i n t h e A t l a n t i c Ocean a;;d Indian Ocean (F ig . 1). S y s t e m a t i c i n v e s t i g a t i o n s f o r h y d r o t h e r s a l mine- r a l i z a t i o n were performed along 1800 km-long p o r t i o n s of the ?Ed-Atlantic Ridge ( U R ) c r e s t b e t w e e n l a t i t u d e 10' and 27"N i n t h e c e n t r a l N o r t h A t l a n t i c , and t h e Carlsberg Ridge (CR) c r e s t b e t v e e n l a t i t u d e 5'5 and 10CN i n t h e n o r t h w e s t I n d i a n Ocean. C r i t e r i a developed and appl ied to locate hydrothermal mineral i - z a t i o n i n c l u d e c h a r a c t e r i s t i c s e a f l o o r m o r p h o l o g y ,

def in i t ive magnet ic s igna ture , composi t ion and mine- ra logy of sed iments and rocks , and cer ta in water p r o p e r t i e s ( 3He ; near-bot tom water tempera ture) . The two s low-sp read ing ocean ic r i dges i nves t iga t ed exh ib i t a s e g m e n t e d s t r u c t u r e v i t h l i n e a r s e c t i o n s of r i f t v a l l e y a l t e r n a t i n g w i t h r i d g e - r i d g e t r a n s f o r m f a u l t s a t an average spacing of 75 km. The i n v e s t i g a t i o n s r e v e a l e d h y d r o t h e r m a l m i n e r a l d e p o s i t s t h a t were concen t r a t ed by h i g h - i n t e n s i t y h y d r o t h e r m a l a c t i v i t y a t l o c a l i z e d s i tes of anomalously high thermal g r a d i e n t s and p e r m e a b i l i t i e s w i t h i n t e c t o n i c s e t t i n g s r e l a t e d t o t h e s e g m e n t e d s t r u c t u r e o f t h e r i d g e s as fo l lows: (1) The w a l l a l o n g l i n e a r s e c t i o n s of t h e r i f t v a l l e y where normal f a u l t s a c t as c o n d u i t s f o r deep- sea t ed , l ong- l ived hydro the rma l ac t iv i ty , w i th depos i t i on o f d i s semina ted , s tockwork , and poss ib ly m a s s i v e p o l y m e t a l l i c s u l f i d e s i n f e r r e d b e n e a t h t h e s e a f l o o r a s a consequence of subsurface mixing of high-ismperature hydrothermal solut ions with normal seawater, d e p o s i t i o n of Fe-t4n oxides , hydroxides and s i l i c a t e s as l aye red bod ie s a t t h e b a s a l t / s e a w a t e r i n t e r f a c e , and p r e c i p i t a t i o n of f e r r i c h y d r o x i d e pa r t i c l e s f rom the d i scha rg ing so lu t ion r educed i n tempera ture and d e p l e t e d i n m e t a l s ; e x a m p l e s a r e t h e TAG Hydrothermal F ie ld and f ive addi t iona l candida te si tes i d e n t i f i e d a l o n g t h e MAR. ( 2 ) The i n t e r s e c t i o n o f t h e r i f t v a l l e y w i t h r i d g e - r i d g e t r a n s f o r m f a u l t s where th inning of oceanic c rus t and fau l t ing has exposed disseminated and stockwork Cu-Fe s u l f i d e s ; examples occur i n t h e Vema and Romanche f r a c t u r e z o n e s of the HAR and t h e V i t y a z f r a c t u r e z o n e of t he CK. ( 3 ) Tne a x i a l zone of t h e r i f t v a l l e y c o n s t i t u t e s a n i n a d e q u a t e l y e x p l o r e d p r o v i n c e w i t h t h e p o s s i b i l i t y for the occur rence o f mass ive su l f ides . Evidence p r e s e n t e d i n d i c a t e s t h a t e x t e n s i v e h y d r o t h e r m a l m i n e r a l i z a t i o n o c c u r s on s lox - sp read ing ocean ic r i dges b u t , u n l i k e t h a t on i n t e r m e d i a t e - t o f a s t - s p r e a d i n g r i d g e s i n t h e P a c i f i c Ocean, the bulk of the h igh- t e m p e r a t u r e m i n e r a l i z a t i o n o c c u r s b e n e a t h t h e s e a f l o o r .

60'

40'

20'

0"

20'

40'

60'

Fig. 1: World map showing boundar i e s o f l i t hosphe r i c p l a t e s (d ive rgen t p l a t e boundar i e s are s e a f l o o r s p r e a d i n g c e n t e r s ) , l o c a t i o n s o f known hydro the rma l depos i t s (do t s ) a t s e a f l o o r s p r e a d i n g c e n t e r s , a n d b e l t s o f oceanic c rus t exposed on l a n d ( o p h i o l i t e s ) ( f r o m b n a , 1982, MTS Journa l , V. 16, No. 3).

817 U.S. Government work not protected by US. copyright.