LONGHORN ARMY AMMUNITION PLANT KARNACK, TEXAS ...longhorn-engage.s3.amazonaws.com/static/2010 Volume 6 of 19.pdf · LONGHORN ARMY AMMUNITION PLANT KARNACK, TEXAS ADMINISTRATIVE RECORD

LONGHORN ARMY AMMUNITION PLANT

KARNACK, TEXAS

ADMINISTRATIVE RECORD

CHRONOLOGICAL INDEX

Volume 6 of

2010

Bate Stamp Numbers 00087185 – 00087951

Prepared for

Department of the Army Longhorn Army Ammunition Plant

1976 – 2010

LONGHORN ARMY AMMUNITION PLANT KARNACK, TEXAS

ADMINISTRATIVE RECORD – CHRONOLOGICAL INDEX

VOLUME 6 of 2010 A Title: Report (Continued) - Final Addendum to Final Feasibility Study LHAAP-16, Longhorn Army Ammunition Plant, Karnack, Texas Author(s): Shaw Environmental, Inc., Houston, Texas Recipient: All Stakeholders Date: March 30, 2010 Bate Stamp: 00087185 - 00087951

158 Starlite Drive, Marietta, OH 45750 • T:740-373-4071 • F:740-373-4835 • http://www.microbac.com

Laboratory Report Number: L09030427

Please find enclosed the analytical results for the samples you submitted to Microbac Laboratories.

Review and compilation of your report was completed by Microbac’s Sales and Service Team. If you have questions,comments or require further assistance regarding this report, please contact your team member noted in the reviewedbox below at 800-373-4071. Team member e-mail addresses also appear here for your convenience.

Kathy Albertson Team Chemist/Data Specialist [email protected] Mossburg Team Chemist/Data Specialist [email protected] Long Team Chemist/Data Specialist [email protected] Fickiesen Client Services Specialist [email protected] Brown Client Services Specialist [email protected] Parsons Team Assistant [email protected]

This report was reviewed on March 26, 2009.

Stephanie Mossburg - Team Chemist/Data Specialist

I certify that all test results meet all of the requirements of the accrediting authority listed below. All results for soilsamples are reported on a ’dry-weight’ basis unless specified otherwise. Analytical results for water and wastes arereported on a ’as received’ basis unless specified otherwise. A statement of uncertainty for each analysis is availableupon request. This laboratory report shall not be reproduced, except in full, without the written approval of MicrobacLaboratories.

This report was certified on March 26, 2009.

David Vandenberg - Managing Director

State of origin: TexasAccrediting authority: Texas Commission on Environmental Quality ID:T104704252-07-TXQAPP: Microbac OVDThis report contains a total of 187 pages.

Look closer. Go further. Do more.

1

00087185

Microbac REPORT L09030427PREPARED FOR Shaw E I, Inc.WORK ID: LHAAP-16

1.0 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32.1 Volatiles Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

2.1.1 Volatiles GCMS Data (8260) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202.1.1.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 212.1.1.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31

2.2 Metals Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 842.2.1 Metals ICP-MS Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85

2.2.1.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 862.2.1.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98

2.3 General Chemistry Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1492.3.1 Method 9056 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150

2.3.1.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1512.3.1.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155

3.0 Attachments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179

2

00087186

1.0 Introduction

3

00087187

ID: 91238

Microbac Laboratories Inc.REPORT NARRATIVE

Microbac Login No: L09030427

CHAIN OF CUSTODY: The chain of custody number was 5792.

SHIPMENT CONDITIONS: The chain of custody forms were received sealed in a cooler. The cooler temperaturewas 3 degrees C.

SAMPLE MANAGEMENT: All samples received were intact.

I certify that this data package is in compliance with the terms and conditions agreed to by the client and MicrobacLaboratories Inc., both technically and for completeness, except for the conditions noted above. Release of the datacontained in this hardcopy data package has been authorized by the Laboratory Manager or designated person, asverified by the following signature.

Approved: 20-MAR-09

4

00087188

Laboratory Data Package Cover PageThis data Package consists of:

This signature page, the laboratory review checklists, and the following reportable data:R1 Field chain-of-custody documentation;R2 sample identification cross-reference;R3 Test reports (analytical data sheets) for each enviornmental sample that includes:

a) Items consistant with NELAC 5.13 or ISO/IEC 17025 Section 5.10b) dilution factors,c) preparation methods,d) Cleanup methods, ande) If required for the project, tentatively identified compounds (TICs)

R4 Surrogate recovery data including:a) Calculated recovery (%R) for each analyte, andb) The laboratory’s surrogate QC limits.

XR5 Test reports/summary forms for blank samples;XR6 Test reports/summary forms for laboratory control samples (LCSs) including:

a) LCS spiking amount,b) Calculated %R for each analyte, andc) The laboratory”s LCS QC limits.

R7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:a) Samples associated with the MS/MSD clearly identified,b) MS/MSD spiking amounts,c) Concentration of each MS/MSD analyte measured in the parent and spiked samples,d) Calculated %R and relative percent differences (RPDs), ande) The laboratory’s MS/MSD QC limits

R8 Laboratory analytical duplicate (if applicable) revocery and precision:a) the amount of analyte measured in the duplicate,b) the calculated RPD, andc) the laboratory’s QC limits for anlytical duplicates.

R9 List of method quantitation limits (MQLs) for each analyte for each method and matrix;R10 Other problems or anomalies.The exception Report for every ”No” or ”Not Reviewed (NR)” item in laboratory review checklist.

Release statement: I am responsible for the release of this laboratory data package. This data package has been reviewed by thelaboratory and is complete and technically compliant with the requirements of the methods used, except where noted by the laboratoryin the attached exceptions reports. By my signature below, I affirm to the best of my knowledge, all problems/anomalies, observed bythe laboratory as having the potential to affect the quality of the data, have been identified by the laboratoy in the Laboratory ReviewChecklist, and no information or data have been knowingly withheld that would affect the quality of the data.

Check, If applicable: [] This laboratory is an in-house laboratory controlled by the person repsonding to rule. The official signing thecover page of the rule-required report (for example, the APAR) in which these data are used is responsible for releasing this datapackage and is by signature affirming the above release statement is trus.

MICHAEL D. COCHRAN Semivolatiles Lab Supervisor March 26, 2009

Name (Printed) Signature Official Title (printed) DATE

RG-366/TRRP-13 December 2002 A1

5

00087189

Checklist ID: 37099

Microbac Laboratories Inc.Laboratory Review Checklist

Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L09030427Project Name: 798-LONGHORNMethod: 9056Prep Batch Number(s): WG298057Reviewer Name: MICHAEL D. COCHRANLRC Date: March 23, 2009

Description Yes No NA(1) NR(2) ER(3)

Chain-Of-Custody (C-O-C)Did samples meet the laboratory’s standard conditions of sample acceptability uponreceipt?

X

Were all departures from standard conditions described in an exception report? XSample and quality control (QC) identificationAre all field sample ID numbers cross-referenced to the laboratory ID numbers? XAre all laboratory ID numbers cross-referenced to the corresponding QC data? XTest reportsWere all samples prepared and analyzed within holding times? XOther than those results


Were MS/MSD RPDs within laboratory QC limits? XAnalytical duplicate dataWere appropriate analytical duplicates analyzed for each matrix? XWere analytical duplicates analyzed at the appropriate frequency? XWere RPDs or relative standard deviations within the laboratory QC limits? XMethod quantitation limits (MQLs):Are the MQLs for each method analyte included in the laboratory data package? XDo the MQLs correspond to the concentration of the lowest non-zero calibration standard? XAre unadjusted MQLs included in the laboratory data package? XOther problems/anomaliesAre all known problems/anomalies/special conditions noted in this LRC and ER? XWere all necessary corrective actions performed for the reported data? XWas applicable and available technology used to lower the SQL minimize the matrixinterference affects on the sample results?

X

Were response factors and/or relative response factors for each analyte within QC limits? XWere percent RSDs or correlation coefficient criteria met? XWas the number of standards recommended in the method used for all analytes? XWere all points generated between the lowest and highest standard used to calculate thecurve?

X

Are ICAL data available for all instruments used? XHas the initial calibration curve been verified using an appropriate second source standard? XInitial and continuing calibration verification (ICV and CCV) and continuingcalibration blank (CCB):Was the CCV analyzed at the method-required frequency? XWere percent differences for each analyte within the method-required QC limits? XWas the ICAL curve verified for each analyte? XWas the absolute value of the analyte concentration in the inorganic CCB


Standards documentationAre all standards used in the analyses NIST-traceable or obtained from other appropriatesources?

X

Compound/analyte identification proceduresAre the procedures for compound/analyte identification documented? XDemonstration of analyst competency (DOC)Was DOC conducted consistent with NELAC Chapter 5C or ISO/IEC 4? XIs documentation of the analyst’s competency up-to-date and on file? XVerification/validation documentation for methods (NELAC Chap 5 or ISO/IEC17025 Section 5)Are all the methods used to generate the data documented, verified, and validated, whereapplicable?

X

Laboratory standard operating procedures (SOPs):Are laboratory SOPs current and on file for each method performed? X

8

00087192

Checklist ID: 37099


Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L09030427Project Name: 798-LONGHORNMethod: 9056Prep Batch Number(s): WG298057Reviewer Name: MICHAEL D. COCHRANLRC Date: March 23, 2009

EXCEPTIONS REPORTER# - Description(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number

9

00087193


This signature page, the laboratory review checklists, and the following reportable data:XR1 Field chain-of-custody documentation;XR2 sample identification cross-reference;R3 Test reports (analytical data sheets) for each enviornmental sample that includes:


XR4 Surrogate recovery data including:a) Calculated recovery (%R) for each analyte, andb) The laboratory’s surrogate QC limits.

XR5 Test reports/summary forms for blank samples;XR6 Test reports/summary forms for laboratory control samples (LCSs) including:


XR7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:a) Samples associated with the MS/MSD clearly identified,b) MS/MSD spiking amounts,c) Concentration of each MS/MSD analyte measured in the parent and spiked samples,d) Calculated %R and relative percent differences (RPDs), ande) The laboratory’s MS/MSD QC limits

XR8 Laboratory analytical duplicate (if applicable) revocery and precision:a) the amount of analyte measured in the duplicate,b) the calculated RPD, andc) the laboratory’s QC limits for anlytical duplicates.

XR9 List of method quantitation limits (MQLs) for each analyte for each method and matrix;XR10 Other problems or anomalies.XThe exception Report for every ”No” or ”Not Reviewed (NR)” item IN laboratory review checklist.


Check, if applicable: [] This laboratory is an in-house laboratory controlled by the person repsonding to rule. The official signing thecover page of the rule-required report (for example, the APAR) in which these data are used is responsible for releasing this datapackage and is by signature affirming the above release statement is true.

MIKE D. ALBERTSON Volatiles Lab Supervisor March 26, 2009



10

00087194

Checklist ID: 37106


Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L09030427Project Name: 798-LONGHORNMethod: 8260BPrep Batch Number(s): WG297819, WG297941Reviewer Name: MIKE D. ALBERTSONLRC Date: March 26, 2009



X




X

ICALWere response factors and/or relative response factors for each analyte within QC limits? XWere percent RSDs or correlation coefficient criteria met? XWas the number of standards recommended in the method used for all analytes? XWere all points generated between the lowest and highest standard used to calculate thecurve?

X




X


X


EXCEPTIONS REPORTER# - Description1) Dibromofluoromethane was below the lower control limit in the 10x analysis of sample 05 and exceeded the upper control limit insamples 03 and 11.2) 2-Butanone exceeded the upper advisory limit in the LCS/LCSD analyzed 03/20/09. 2-Butanone exceeded the upper advisory limitand isopropylbenzene was below the lower control limit in the LCS/LCSD analyzed 03/23/09.3) 2-Hexanone and 1,2-dibromo-3-chloropropane exceeded the upper advisory limits in the LCS/LCSD analyzed 03/23/09.

Footnotes:(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number

13

00087197


This signature page, the laboratory review checklists, and the following reportable data:R1 Field chain-of-custody documentation;R2 sample identification cross-reference;R3 Test reports (analytical data sheets) for each enviornmental sample that includes:


R4 Surrogate recovery data including:a) Calculated recovery (%R) for each analyte, andb) The laboratory’s surrogate QC limits.

R5 Test reports/summary forms for blank samples;R6 Test reports/summary forms FOR laboratory control samples (LCSs) including:


R7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:a) Samples associated with the MS/MSD clearly identified,b) MS/MSD spiking amounts,c) Concentration of each MS/MSD analyte measured in the parent and spiked samples,d) Calculated %R and relative percent differences (RPDs), ande) The laboratory’s MS/MSD QC limits

R8 Laboratory analytical duplicate (if applicable) revocery and precision:a) the amount of analyte measured in the duplicate,b) the calculated RPD, andc) the laboratory’s QC limits for anlytical duplicates.

R9 List of method quantitation limits (MQLs) for each analyte for each method and matrix;R10 Other problems or anomalies.The exception Report for every ”No” or ”Not Reviewed (NR)” item in laboratory review checklist.


Check, If applicable: [] This laboratory is an in-house laboratory controlled by the person repsonding to rule. The official signing thecover page of the rule-required report (for example, the APAR) in which these data are used is responsible for releasing this datapackage and is by signature affirming the above release statement is trus.

MAREN M. BEERY Metals Supervisor March 20, 2009



14

00087198

Checklist ID: 36953


Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L09030427Project Name: 798-LONGHORNMethod: 6020Prep Batch Number(s): WG297722Reviewer Name: MAREN M. BEERYLRC Date: March 20, 2009



X




X ER1

ICALWere response factors and/or relative response factors for each analyte within QC limits? XWere percent RSDs or correlation coefficient criteria met? XWas the number of standards recommended in the method used for all analytes? XWere all points generated between the lowest and highest standard used to calculate thecurve?

X




X


X


17

00087201

Checklist ID: 36953


Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L09030427Project Name: 798-LONGHORNMethod: 6020Prep Batch Number(s): WG297722Reviewer Name: MAREN M. BEERYLRC Date: March 20, 2009

EXCEPTIONS REPORTER#1- Due to high levels of nontarget analytes, client samples 01 through 10 were analyzed at dilutions for all analytes.ER2 - Client sample 02 required further dilution analysis in order to obtain a result for chromium within the linear range.Client sample 04 required further dilution analysis in order to obtain a result for manganese within the linear range. Clientsample 10 required further dilution analysis in order to obtain a result for nickel within the linear range.Footnotes:(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number

18

00087202

2.1 Volatiles Data

19

00087203

2.1.1 Volatiles GCMS Data(8260)

20

00087204

2.1.1.1 Summary Data

21

00087205

LABORATORY REPORT

03/26/09 16:12

L09030427

1 OFL1_A_PROD - Modified 03/06/2008

03/26/2009 16:12Report generated:1351447PDF File ID:

1

L09030427-03

L09030427-05

L09030427-05

L09030427-11

16WW32-031709

16WW16-031709

16WW16-031709

TRIP BLANK

Client ID Lab ID Dilution

1

250

10

1

Sample Analysis Summary

Date Received

19-MAR-09

19-MAR-09

19-MAR-09

19-MAR-09

Attention: Jennifer Hoang

Account Name: Shaw E & I, Inc.ABB Lummus Biulding3010 Briarpark Drive Suite 4NHouston, TX 77042

Project Number:

Site:

2773.025Longhorn AAP

P.O. Number: 389869/ 390836(GWTP)

Submitted By

For

Microbac Laboratories Inc.

158 Starlite Drive

Marietta OH 45750,740 373 4071)( -

Method

8260B

8260B

8260B

8260B

LHAAP-16Project:

22

00087206

L09030427

March 26, 2009

Report Number:

Report Date :

1 of


8

L09030427-03Sample Number: HPMS10Instrument:

10M71271File ID:03/23/2009Run Date:Analyst:03/18/2009 15:23Cal Date:

14:15Workgroup Number:Matrix: Analytical Method:Water

16WW32-031709Client ID:

Sample Tag:01Dilution:

Units:

WG2979418260BTMB1ug/L

Collect Date:03/17/2009 12:05

Prep Method:5030B 03/23/2009 14:15Prep Date:

Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene 1,1-Dichloropropene Ethylbenzene 2-Hexanone Hexachlorobutadiene Isopropylbenzene p-Isopropyltoluene 4-Methyl-2-pentanone Methylene chloride Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane

UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU

2.500.1250.1250.2000.2500.5000.5002.500.2500.2500.2500.5000.2500.1250.2500.5002.000.1250.2500.1250.2501.000.2500.2500.1250.2500.1250.2500.1250.2500.5000.2500.2500.2000.2000.2500.2500.5000.2500.2502.500.2500.2500.2502.500.2500.2000.1250.1250.2500.1250.2500.2500.1500.2000.2500.2500.2500.250

10.01.001.001.001.001.001.0010.01.001.001.001.001.001.001.001.0010.01.001.001.001.005.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.0010.01.001.001.0010.05.001.001.001.001.001.001.001.001.001.001.001.001.001.00

67-64-171-43-2108-86-174-97-575-27-475-25-274-83-978-93-3104-51-8135-98-898-06-675-15-056-23-5108-90-7124-48-175-00-3110-75-867-66-374-87-395-49-8106-43-496-12-8106-93-474-95-395-50-1541-73-1106-46-775-71-875-34-3107-06-275-35-4156-59-2156-60-578-87-5142-28-9594-20-710061-01-510061-02-6563-58-6100-41-4591-78-687-68-398-82-899-87-6108-10-175-09-291-20-3103-65-1100-42-5630-20-679-34-5127-18-4108-88-387-61-6120-82-171-55-679-00-579-01-675-69-4

Analyte QualResultCAS. Number PQL SDL

NONEPrePrep Method:

23

00087207

L09030427

March 26, 2009

Report Number:

Report Date :

2 of


8






Units:


Collect Date:03/17/2009 12:05


U Not detected at or above adjusted sample detection limit* Surrogate or spike compound out of range

86808886

118120110115

12110299.490.4

* Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene

Surrogate Lower Upper% Recovery Qual

1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride o-Xylene m-,p-Xylene

UUUUUUU

0.5000.2500.2502.500.2500.2500.500

1.001.001.0010.01.001.001.00

96-18-495-63-6108-67-8108-05-475-01-495-47-6

136777-61-2


NONEPrePrep Method:

24

00087208

L09030427

March 26, 2009

Report Number:

Report Date :

3 of


8





Sample Tag:DL02Dilution:

Units:

WG2979418260BTMB250ug/L

Collect Date:03/17/2009 14:35



UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU

UUUUUUUUUUUUUUUUUUUUUUUUU

U

62531.331.350.062.512512562562.562.562.512562.531.362.512550031.362.531.362.525062.562.531.362.531.362.531.362.512562.562.550.050.062.562.512562.562.562562.562.562.562562.550.031.331.362.531.362.562.537.550.062.562.562.562.5

2500250250250250250250250025025025025025025025025025002502502502501250250250250250250250250250250250250250250250250250250250250025025025025001250250250250250250250250250250250250250250

11800

18900

67-64-171-43-2108-86-174-97-575-27-475-25-274-83-978-93-3104-51-8135-98-898-06-675-15-056-23-5108-90-7124-48-175-00-3110-75-867-66-374-87-395-49-8106-43-496-12-8106-93-474-95-395-50-1541-73-1106-46-775-71-875-34-3107-06-275-35-4156-59-2156-60-578-87-5142-28-9594-20-710061-01-510061-02-6563-58-6100-41-4591-78-687-68-398-82-899-87-6108-10-175-09-291-20-3103-65-1100-42-5630-20-679-34-5127-18-4108-88-387-61-6120-82-171-55-679-00-579-01-675-69-4


NONEPrePrep Method:

25

00087209

L09030427

March 26, 2009

Report Number:

Report Date :

4 of


8






Units:

WG2979418260BTMB250ug/L

Collect Date:03/17/2009 14:35


U Not detected at or above adjusted sample detection limit

86808886

118120110115

11810499.788.9

Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene



UUUU

UU

12562.562.562562.562.5125

2502502502500250250250

772

96-18-495-63-6108-67-8108-05-475-01-495-47-6

136777-61-2


NONEPrePrep Method:

26

00087210

L09030427

March 26, 2009

Report Number:

Report Date :

5 of


8






Units:


Collect Date:03/17/2009 14:35



UUUUUUUUUUUUUUUUUUUUUUUUUUUUU

I

UUUUUUUUUUUUUUUUUUUUUUUUIU

25.01.251.252.002.505.005.0025.02.502.502.505.002.501.252.505.0020.01.252.501.252.5010.02.502.501.252.501.252.501.252.505.002.502.502.002.002.502.505.002.502.5025.02.502.502.5025.02.502.001.251.252.501.252.502.501.502.002.502.502.502.50

10010.010.010.010.010.010.010010.010.010.010.010.010.010.010.010010.010.010.010.050.010.010.010.010.010.010.010.010.010.010.010.010.010.010.010.010.010.010.010010.010.010.010050.010.010.010.010.010.010.010.010.010.010.010.010.010.0

29.643.2950024.0

14200

67-64-171-43-2108-86-174-97-575-27-475-25-274-83-978-93-3104-51-8135-98-898-06-675-15-056-23-5108-90-7124-48-175-00-3110-75-867-66-374-87-395-49-8106-43-496-12-8106-93-474-95-395-50-1541-73-1106-46-775-71-875-34-3107-06-275-35-4156-59-2156-60-578-87-5142-28-9594-20-710061-01-510061-02-6563-58-6100-41-4591-78-687-68-398-82-899-87-6108-10-175-09-291-20-3103-65-1100-42-5630-20-679-34-5127-18-4108-88-387-61-6120-82-171-55-679-00-579-01-675-69-4


NONEPrePrep Method:

27

00087211

L09030427

March 26, 2009

Report Number:

Report Date :

6 of


8






Units:


Collect Date:03/17/2009 14:35


U Not detected at or above adjusted sample detection limit* Surrogate or spike compound out of rangeI Semiquantitative result (out of instrument calibration range)

86808886

118120110115

70.099.811087.2




UUUU

UU

5.002.502.5025.02.502.505.00

10.010.010.010010.010.010.0

564

96-18-495-63-6108-67-8108-05-475-01-495-47-6

136777-61-2


NONEPrePrep Method:

28

00087212

L09030427

March 26, 2009

Report Number:

Report Date :

7 of


8




TRIP BLANKClient ID:


Units:


Collect Date:03/18/2009 00:01



UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU

2.500.1250.1250.2000.2500.5000.5002.500.2500.2500.2500.5000.2500.1250.2500.5002.000.1250.2500.1250.2501.000.2500.2500.1250.2500.1250.2500.1250.2500.5000.2500.2500.2000.2000.2500.2500.5000.2500.2502.500.2500.2500.2502.500.2500.2000.1250.1250.2500.1250.2500.2500.1500.2000.2500.2500.2500.250

10.01.001.001.001.001.001.0010.01.001.001.001.001.001.001.001.0010.01.001.001.001.005.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.0010.01.001.001.0010.05.001.001.001.001.001.001.001.001.001.001.001.001.001.00

67-64-171-43-2108-86-174-97-575-27-475-25-274-83-978-93-3104-51-8135-98-898-06-675-15-056-23-5108-90-7124-48-175-00-3110-75-867-66-374-87-395-49-8106-43-496-12-8106-93-474-95-395-50-1541-73-1106-46-775-71-875-34-3107-06-275-35-4156-59-2156-60-578-87-5142-28-9594-20-710061-01-510061-02-6563-58-6100-41-4591-78-687-68-398-82-899-87-6108-10-175-09-291-20-3103-65-1100-42-5630-20-679-34-5127-18-4108-88-387-61-6120-82-171-55-679-00-579-01-675-69-4


NONEPrePrep Method:

29

00087213

L09030427

March 26, 2009

Report Number:

Report Date :

8 of


8




TRIP BLANKClient ID:


Units:


Collect Date:03/18/2009 00:01


U Not detected at or above adjusted sample detection limit* Surrogate or spike compound out of range

86808886

118120110115

11910399.589.1




UUUUUUU

0.5000.2500.2502.500.2500.2500.500

1.001.001.0010.01.001.001.00

96-18-495-63-6108-67-8108-05-475-01-495-47-6

136777-61-2


NONEPrePrep Method:

30

00087214

2.1.1.2 QC Summary Data

31

00087215

Example 8260 Calculations

1.0 Calculating the Response Factor (RF) from the initial calibration (ICAL) data:

RF = [ (Ax) (Cis) ] / [ (Ais) (Cx) ]Example

where:Ax = Area of the characteristic ion for the compound being measured: 3399156Cis = Concentration of the specific internal standard (ug/mL) 25Ais = Area of the characteristic ion of the specific internal standard 846471Cx = Concentration of the compound in the standard being measured (ug/mL) 100

RF = Calculated Response Factor 1.0039

2.0 Calculating the concentration ( C ) of a compound in water using the average RF: *

Cx = [ (Ax) (Cis) (Vn)(D)] / [ (Ais) (RF) (Vs) ]Example

where:Ax = Area of the characteristic ion for the compound being measured 3122498Cis = Concentration of the specific internal standard (ug/L) 25D = Dilution factor for sample as a multiplier ( 10x = 10) 1Ais = Area of the characteristic ion of the specific internal standard 611048RF = Average RF from the ICAL 1.004Vs = Purge volume of sample (mL) 10Vn = Nominal purge volume of sample (mL) ( 10.0 mL ) 10Cx = Concentration of the compound in the sample being measured (ug/L) 127.2428

3.0 Calculating the concentration ( C ) of a compound in soil using the average RF: *

Cx = [ (Ax) (Cis) (Wn)(D)] / [ (Ais) (RF) (Ws) ]Example

where:Ax = Area of the characteristic ion for the compound being measured 3122498Cis = Concentration of the specific internal standard (ug/L) 25D = Dilution factor for sample as a multiplier ( 10x = 10) 1Ais = Area of the characteristic ion of the specific internal standard 611048RF = Average RF from the ICAL 1.004Ws = Weight of sample purged (g) 5Wn = Nominal purge weight (g) ( 5.0 g) 5Cx = Concentration of the compound in the sample being measured (ug/L) 127.2428

Dry weight correction:Percent solids (PCT_S) 50Cd = (Cx) (100)/PCT_S 254.4856

* Concentrations appearing on the instrument quantitation reports are on-column results and do not take into accountinitial volume, final volume, and the dilution factor.

4.0 Concentration from Linear Regression

Step 1: Retrieve Curve Data From Plot, y = mx + b

y = response ratio = response of analyte / response of IS = Ax/Ais

x = amount ratio = concentration analyte/concentration internal standard = Cx / Cis

m = slope from curve = 0.213

b = intercept from curve = - 0.00642

32

00087216

Step 2: Calculate y from Quantitation Report

y = 86550/593147 = 0.1459

Step 3: Solve for x

x = (y - b)/m = [( 0.1459 -( - 0.00642)]/ 0.213 = 0.7152

Step 4: Solve for analyte concentration Cx

Cx = Cis ( x ) = (25.0)(0.7152) = 17.88

Example Spreadsheet Calculation:

Slope from curve, m: 0.213Intercept from curve, b: -0.00642

Area of analyte, Ax: 86550Area of Internal Standard , Ais: 593147

Concentration of IS, Cis 25.00Response Ratio: 0.145917

Amount Ratio: 0.715195Concentration: 17.87988

Units of Internal Standard: ug/L

5.0 Concentration from Quadratic Regression

Step 1 - Retrieve Curve Data from Plot, y = Ax^2 + Bx + CWhere:Ax^2 + Bx + (C - y) = 0A, B, C = constants from the ICAL quadratic regressiony = Response ratio = Area of analyte/Area of internal standard (IS)x = Amount ratio = Concentration of analyte/concentration of IS

Step 2: Calculate y from Quantitation Report

y = Ax/Ais

Step 3: Solve for x using the quadratic formulaAx^2 + Bx + C - y = 0

(Two possible solutions)

Step 4: Solve for analyte concentration Cx

Cx = ( Cis )( Amount ratio)

Example Spreadsheet Calculation:

Value of A from plot: -0.00629Value of B from plot: 0.511Value of C from plot: -0.0276

Area of unknown from quantitation report: 293821Area of IS from quantiation report: 784848

Response ratio, y: 0.374367C - y: -0.40197

Root 1 - Computed amount ratio , X1: 80.44567Root 2 - Computed amount ratio , X2: 0.794396 use this solution

Concentration of IS, Cis: 25.00Concentration of analyte, Cx: 19.86 ug/L

( )( )x

b b a c ya

=± − −2 4

2

33

00087217

Instrument Run Log

Run Log ID:27121

Page: 1

Approved:


Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS10

TMB

8260B

031809

NA

MSV01 12

Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD31494

STD31848

STD31691

STD31819 NA

WG297559

3

6

9

X

X

X

Comments

Seq. Rerun Dil. AnalytesReason

Column 1 ID: Column 2 ID:RTX502.2 NA

Method: SOP: Rev:5030B/5035 PAT01 11

1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

10M71171

10M71172

10M71173

10M71174

10M71175

10M71176

10M71177

10M71178

10M71179

10M71180

10M71181

10M71182

10M71183

10M71184

10M71185

10M71186

10M71187

10M71188

10M71189

10M71190

SYSTEM BLANK

SYSTEM BLANK

WG297559-01 50ng BFB STD 8260

WG297559-01 50ng BFB STD 8260

WG297559-02 0.3ug/L STD 8260

WG297559-03 0.4ug/L STD 8260

WG297559-04 1ug/L STD 8260

WG297559-03 0.4ug/L STD 8260

WG297559-04 1ug/L STD 8260

WG297559-05 2ug/L STD 8260

WG297559-06 5ug/L STD 8260

WG297559-07 20ug/L STD 8260

WG297559-08 50ug/L STD 8260

WG297559-09 100ug/L STD 8260

WG297559-10 200ug/L STD 8260

WG297559-11 300ug/L STD 8260

SYSTEM BLANK

SYSTEM BLANK

WG297559-12 20ug/L ALT SRC STD 8260

SYSTEM BLANK

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

STD31709

STD31709

STD31848

STD31848

STD31848

STD31848

STD31848

STD31848

STD31848

STD31848

STD31848

STD31848

STD31848

STD31848

STD31819

03/18/09 07:43

03/18/09 08:17

03/18/09 08:47

03/18/09 09:00

03/18/09 09:26

03/18/09 09:58

03/18/09 10:31

03/18/09 11:03

03/18/09 11:36

03/18/09 12:08

03/18/09 12:40

03/18/09 13:13

03/18/09 13:45

03/18/09 14:17

03/18/09 14:50

03/18/09 15:23

03/18/09 15:55

03/18/09 16:27

03/18/09 16:58

03/18/09 17:30

Seq. File ID Sample Information Dil Reference Date/TimeMat

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

pH

Tune failed. DNR.

No secondary for 123-TCB. DNR.

Idomethane didn't show up at all. DNR.

Comments:

10M71173

10M71176

10M71179

File ID:

File ID:

File ID:

Maintenance Log ID: 28031

34

00087218

Instrument Run Log

Run Log ID:27161

Page: 1

Approved: March 23, 2009


Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS10

TMB

8260B

031909

NA

MSV01 12

Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD31494

STD31848

STD31691

STD31819 STD31819

WG297551

Comments



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

10M71192

10M71193

10M71194

10M71195

10M71196

10M71197

10M71198

10M71199

10M71200

10M71201

10M71202

10M71203

10M71204

10M71205

10M71206

10M71207

10M71208

10M71209

10M71210

10M71211

10M71212

10M71213

10M71214

10M71215

10M71216

10M71217

10M71218

10M71219

10M71220

10M71221

10M71222

WG297549-01 50ng BFB STD 8260

WG297549-02 50ug/L CCV STD 8260

WG297549-02 50ug/L CCV STD 8260

WG297551-01 VBLK0319 BLANK STD 826

WG297549-01 50ng BFB STD 8260

WG297549-02 50ug/L CCV STD 8260

WG297549-01 50ng BFB STD 8260

WG297549-02 50ug/L CCV STD 8260



WG297559-12 20ug/L ALT SRC STD 8260

WG297551-02 20ug/L LCS STD 8260

L09030379-13 A 826-SPE

L09030379-01 A 826-SPE

L09030379-02 A 826-SPE

L09030379-03 A 826-SPE

L09030379-04 A 826-SPE

L09030379-05 A 826-SPE

L09030379-06 A 826-SPE

L09030379-07 A 826-SPE

L09030379-08 A 826-SPE

L09030379-09 A MS 826-SPE

L09030379-10 A MSD 826-SPE

L09030379-11 A 826-SPE

L09030379-12 A 2X 826-SPE

L09030379-14 A 826-SPE

L09030379-15 A 826-SPE

L09030379-16 A 826-SPE

L09030379-17 A 826-SPE

SYSTEM BLANK

SYSTEM BLANK

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

2

1

1

1

1

1

1

STD31709

STD31848

STD31848

STD31709

STD31848

STD31709

STD31848

STD31819

STD31819

STD31819

STD31819

03/19/09 12:01

03/19/09 12:27

03/19/09 13:04

03/19/09 13:36

03/19/09 14:04

03/19/09 14:28

03/19/09 15:01

03/19/09 15:25

03/19/09 15:57

03/19/09 16:33

03/19/09 17:05

03/19/09 17:38

03/19/09 18:10

03/19/09 18:42

03/19/09 19:15

03/19/09 19:47

03/19/09 20:19

03/19/09 20:52

03/19/09 21:24

03/19/09 21:56

03/19/09 22:29

03/19/09 23:01

03/19/09 23:33

03/20/09 00:05

03/20/09 00:38

03/20/09 01:10

03/20/09 01:43

03/20/09 02:15

03/20/09 02:48

03/20/09 03:21

03/20/09 03:53


1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

Instrument Run Log

Run Log ID:27161

Page: 2



Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS10

TMB

8260B

031909

NA

MSV01 12

Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD31494

STD31848

STD31691

STD31819 STD31819

WG297551

2

3

4

6

9

14

15

16

17

18

19

20

X

X

X

X

X

X

X

X

X

X

X

X

1

1

5

10

10

50

1

10

10

VC

2-BUT

2-BUT

2-BUT

2-BUT

2-BUT

2-BUT

Comments

Seq. Rerun Dil. Analytes

Over Linear Range

Over Linear Range

Carry-over contamination

Over Linear Range


Over Calibration Range







Reason



VC was low. DNR.

VC was low. DNR.

DNR.

VC was low. DNR.

DNR.

DNR.

Comments:

10M71193

10M71194

10M71195

10M71197

10M71200

10M71205

10M71206

10M71207

10M71208

10M71209

10M71210

10M71211

File ID:

File ID:

File ID:

File ID:

File ID:

File ID:

File ID:

File ID:

File ID:

File ID:

File ID:

File ID:


36

00087220

Instrument Run Log

Run Log ID:27161

Page: 3



Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS10

TMB

8260B

031909

NA

MSV01 12

Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD31494

STD31848

STD31691

STD31819 STD31819

WG297551

21

24

25

26

27

28

29

X

X

X

X

X

X

X

10

5

10

10

1

1

10

2-BUT

2-BUT

2-BUT

2-BUT

2-BUT

Comments







Surrogate standard failure


Reason



DNR.

DNR.

Comments:

10M71212

10M71215

10M71216

10M71217

10M71218

10M71219

10M71220

File ID:

File ID:

File ID:

File ID:

File ID:

File ID:

File ID:


37

00087221

Instrument Run Log

Run Log ID:27181

Page: 1



Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS10

TMB

8260B

032009

NA

MSV01 12

Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD31494

STD31848

STD31691

STD31819 NA

WG297819



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

10M71224

10M71225

10M71226

10M71227

10M71228

10M71229

10M71230

10M71231

10M71232

10M71233

10M71234

10M71235

10M71236

10M71237

10M71238

10M71239

10M71240

10M71241

10M71242

10M71243

10M71244

10M71245

10M71246

10M71247

10M71248

10M71249

10M71250

10M71251

10M71252

10M71253

10M71254

10M71255

10M71256

SYSTEM BLANK

WG297818-01 50ng BFB STD 8260

WG297818-02 50ug/L CCV STD 8260



WG297819-02 20ug/L LCS STD 8260

WG297819-03 20ug/L LCSDUP STD 8260

L09030341-15 A 826-SPE

L09030343-09 A 8260

L09030393-01 A 826-SPE

L09030393-04 A 826-SPE

L09030341-05 A 826-SPE

L09030341-06 A 826-SPE

L09030343-01 A 8260

L09030343-03 A 8260

L09030343-05 A 8260

L09030343-06 A 8260

L09030343-07 A 8260

L09030313-21 10X 826-TC

L09030313-23 10X 826-TC

L09030313-24 10X 826-TC

L09030427-03 100X 826-LOW

L09030427-05 10X 826-LOW

L09030406-05 10000X 8260

SYSTEM BLANK

SYSTEM BLANK

SYSTEM BLANK

SYSTEM BLANK

L09030120-01 A 826-REF-BLK

L09030120-02 A 826-REF-BLK

L09030120-03 A 826-REF-BLK

L09030120-04 A 826-REF-BLK

L09030120-05 A 826-REF-BLK

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

10

10

10

100

10

10000

1

1

1

1

1

1

1

1

1

STD31709

STD31848

STD31819

STD31819

03/20/09 07:39

03/20/09 08:11

03/20/09 08:35

03/20/09 09:08

03/20/09 09:40

03/20/09 10:12

03/20/09 10:44

03/20/09 11:17

03/20/09 11:49

03/20/09 12:21

03/20/09 12:54

03/20/09 13:26

03/20/09 13:59

03/20/09 14:31

03/20/09 15:03

03/20/09 15:36

03/20/09 16:08

03/20/09 16:40

03/20/09 17:13

03/20/09 17:45

03/20/09 18:17

03/20/09 18:49

03/20/09 19:22

03/20/09 19:54

03/20/09 20:26

03/20/09 20:58

03/20/09 21:31

03/20/09 22:03

03/20/09 22:35

03/20/09 23:07

03/20/09 23:40

03/21/09 00:12

03/21/09 00:44


1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

17

17

17

1

1

12

1

1

1

1

1

1

1

1

1

NA

NA

NA

NA

NA

NA

NA

Instrument Run Log

Run Log ID:27181

Page: 2



Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS10

TMB

8260B

032009

NA

MSV01 12

Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD31494

STD31848

STD31691

STD31819 NA

WG297819

4

22

23

X

X

X

1

250

1

CIS12DCE, TCE

Comments




Analyzed too dilute

Reason



DNR.

DNR.

Comments:

10M71227

10M71245

10M71246

File ID:

File ID:

File ID:


39

00087223

Instrument Run Log

Run Log ID:27210

Page: 1



Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS10

TMB

8260B

032309

NA

MSV01 12

Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD31494

STD31848

STD31691

STD31819 NA

WG297941

5

20

X

X

1

10

Comments



Surrogate standard failure

Reason



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

10M71258

10M71259

10M71260

10M71261

10M71262

10M71263

10M71264

10M71265

10M71266

10M71267

10M71268

10M71269

10M71270

10M71271

10M71272

10M71273

10M71274

10M71275

10M71276

10M71278

10M71279

10M71280

10M71281

10M71282

10M71283

10M71284

SYSTEM BLANK

SYSTEM BLANK

WG297940-01 50ng BFB STD 8260

WG297940-02 50ug/L CCV STD 8260



WG297941-02 20ug/L LCS STD 8260

WG297941-03 20ug/L LCSDUP STD 8260

WG297941-04 FBLK STD 8260

L09030428-02 A 826-SPE

L09030438-08 A 826-SPE

L09030427-11 A 826-LOW

L09030468-20 A 826-LOW

L09030427-03 B 826-LOW

L09030427-05 B 250X 826-LOW

L09030468-08 A 826-LOW

L09030468-09 A 826-LOW

L09030468-10 A 826-LOW

L09030386-01 10X 826-TC

L09030421-01 10X 826-TC

L09030452-02 A 250X 826-LOW

L09030468-17 A 100X 826-LOW

L09030468-18 A 100X 826-LOW

L09030468-19 A 2000X 826-LOW

L09030428-01 A 826-SPE

SYSTEM BLANK

1

1

1

1

1

1

1

1

1

1

1

1

1

1

250

1

1

1

10

10

250

100

100

2000

1

1

STD31709

STD31848

STD31819

STD31819

03/23/09 07:27

03/23/09 08:00

03/23/09 08:26

03/23/09 08:51

03/23/09 09:23

03/23/09 09:56

03/23/09 10:28

03/23/09 11:01

03/23/09 11:33

03/23/09 12:05

03/23/09 12:37

03/23/09 13:10

03/23/09 13:42

03/23/09 14:15

03/23/09 14:47

03/23/09 15:19

03/23/09 15:52

03/23/09 16:24

03/23/09 16:56

03/23/09 17:29

03/23/09 18:01

03/23/09 18:34

03/23/09 19:06

03/23/09 19:39

03/24/09 07:13

03/24/09 07:46


1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

17

17

1

1

1

1

1

1

NA

NA

NA

NA

NA

NA

NA

NA

NA

Instrument Run Log

Run Log ID:27210

Page: 2



Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS10

TMB

8260B

032309

NA

MSV01 12

Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD31494

STD31848

STD31691

STD31819 NA

WG297941

22

23

25

X

X

X

10

10

1

Comments


Analyzed too dilute

Analyzed too dilute

Missed Tune

Reason



DNR.

DNR.

DNR.

DNR.

Comments:

10M71278

10M71280

10M71281

10M71283

File ID:

File ID:

File ID:

File ID:


41

00087225

Data Checklist

Checklist ID: 36896

Generated: MAR-19-2009 14:16:58

CHECKLIST1 - Modified 03/05/2008


Date:

Analyst:

Analyst:

Method:

Instrument:

Analytical Workgroups:

18-MAR-2009

TMB

NA

8260

HPMS10

WG297559

System Performance Check BFBInitial Calibration Average RF Linear Reg or Higher Order CurveSecond Source standard % DifferenceContinuing Calibration /Check StandardsProject/Client Specific RequirementsSpecial StandardsBlanks TCL's SurrogatesLCS (Laboratory Control Sample) Recoveries SurrogatesMS/MSD/DuplicatesSamples TCL Hits Spectra of TCL Hits Surrogates Internal Standards Criteria Library Searches Calculations & Correct Factors Dilutions Run RerunsManual IntegrationsCase NarrativeResults Reporting/Data QualifiersKOBRA Workgroup DataCheck for CompletenessPrimary ReviewerSecondary Reviewer

Check for compliance with method and project specific requirementsCheck the completeness of reported informationCheck the information for the report narrativeCheck the reasonableness of the results

NAXXXXXXXXXXXXXX

NAXXXXX

NAXXX

NAXXXX

TMB

Primary Reviewer:19-MAR-2009

Secondary Reviewer:

Curve Workgroup: NA

Runlog ID: 27121

42

00087226

Data Checklist

Checklist ID: 36964

Generated: MAR-23-2009 13:54:54



Date:

Analyst:

Analyst:

Method:

Instrument:


19-MAR-2009

TMB

NA

8260

HPMS10

WG297551



NAXXXXXXX

NAXXXXXXXXXXXX

NAXXX

NAXXXX

TMBMDA

XXXX


Secondary Reviewer:23-MAR-2009

Curve Workgroup: NA

Runlog ID: 27161

43

00087227

Data Checklist

Checklist ID: 36984

Generated: MAR-24-2009 10:06:20



Date:

Analyst:

Analyst:

Method:

Instrument:


20-MAR-2009

TMB

NA

8260

HPMS10

WG297819



NAXXXXXXX

NAXXXXXX

NAXXXXX

NAXXX

NAXXXX

TMBMDA

XXXX



Curve Workgroup: NA

Runlog ID: 27181

44

00087228

Data Checklist

Checklist ID: 37039

Generated: MAR-25-2009 16:33:40



Date:

Analyst:

Analyst:

Method:

Instrument:


23-MAR-2009

TMB

NA

8260

HPMS10

WG297941



NAXXXXXXX

NAXXXXXX

NAXXXXX

NAXXX

NAXXXX

TMBMDA

XXXX



Curve Workgroup: NA

Runlog ID: 27210

45

00087229

HOLD_TIMES - Modified 03/06/2008

03/26/2009 14:56Report generated1351337PDF File ID:

HOLDING TIMESEQUIVALENT TO AFCEE FORM 9


WG2978198260BAnalytical Method:

16WW16-031709

Client ID Date

CollectedDate

Extracted QDate

ReceivedDate

AnalyzedMax HoldTime Ext.

Max HoldTime Anal

Time HeldAnal.

Time HeldExt.

03/17/09 03/19/09 03/20/09 14 3.18 03/20/09 14 3.18

* EXT = SEE PROJECT QAPP REQUIREMENTS *ANAL = SEE PROJECT QAPP REQUIREMENTS

AAB#:

Login Number:L09030427

46

00087230

HOLD_TIMES - Modified 03/06/2008


HOLDING TIMESEQUIVALENT TO AFCEE FORM 9


WG2979418260BAnalytical Method:

16WW32-031709

16WW16-031709

TRIP BLANK

Client ID Date

CollectedDate

Extracted QDate

ReceivedDate

AnalyzedMax HoldTime Ext.

Max HoldTime Anal

Time HeldAnal.

Time HeldExt.

03/17/09

03/17/09

03/18/09

03/19/09

03/19/09

03/19/09

03/23/09

03/23/09

03/23/09

14

14

14

6.09

6.01

5.55

03/23/09

03/23/09

03/23/09

14

14

14

6.09

6.01

5.55

* EXT = SEE PROJECT QAPP REQUIREMENTS *ANAL = SEE PROJECT QAPP REQUIREMENTS

AAB#:

Login Number:L09030427

47

00087231

SURROGATES - Modified 03/06/2008


SURROGATE STANDARDS


L09030427-05

WG297819-01

WG297819-02

WG297819-03

DL01

01

01

01

1 2 3 4Sample Number Dilution Tag

10.0

1.00

1.00

1.00

1

2

3

4

-

-

-

-

1,2-Dichloroethane-d4

Dibromofluoromethane

4-Bromofluorobenzene

Toluene-d8

8260Method:

HPMS10Instrument Id:

L09030427Login Number:

WaterMatrix:WG297819Workgroup (AAB#):

Underline = Result out of surrogate limits

99.8 70.0 87.2 110

100 116 89.7 99.6

92.7 96.2 100 95.5

94.9 99.7 100 94.9

80

86

86

88

-

-

-

-

120

118

115

110

Surrogates Surrogate Limits

DL = surrogate diluted out

HPMS10CAL ID: -18-MAR-09

ND = surrogate not detected

48

00087232

SURROGATES - Modified 03/06/2008


SURROGATE STANDARDS


L09030427-03

L09030427-05

L09030427-11

WG297941-01

WG297941-02

WG297941-03

WG297941-04

01

DL02

01

01

01

01

01

1 2 3 4Sample Number Dilution Tag

1.00

250

1.00

1.00

1.00

1.00

1.00

1

2

3

4

-

-

-

-




Toluene-d8

8260Method:

HPMS10Instrument Id:


WaterMatrix:WG297941Workgroup (AAB#):

Underline = Result out of surrogate limits

102 121 90.4 99.4

104 118 88.9 99.7

103 119 89.1 99.5

99.6 117 88.8 100

96.7 96.5 104 94.4

94.2 98.4 96.4 96.1

104 119 90.4 102

80

86

86

88

-

-

-

-

120

118

115

110

Surrogates Surrogate Limits

DL = surrogate diluted out

HPMS10CAL ID: -18-MAR-09

ND = surrogate not detected

49

00087233



METHOD BLANK SUMMARY

Report Name: BLANK_SUMMARY

10M71228

03/20/09 09:40

03/20/09 09:40

WG297819

WG297819-01

HPMS10

Blank File ID:

Prep Date:

Analyzed Date:

Work Group:

Blank Sample ID:

Instrument ID:

8260BMethod:

TMBAnalyst:


LCS

LCS2

16WW16-031709

WG297819-02

WG297819-03

L09030427-05

10M71229

10M71230

10M71245

03/20/09 10:12

03/20/09 10:44

03/20/09 18:49

This Method Blank Applies To The Following Samples:

Client ID Lab Sample ID Lab File ID Time Analyzed TAG

01

01

DL01

50

00087234



METHOD BLANK SUMMARY

Report Name: BLANK_SUMMARY

10M71263

03/23/09 09:56

03/23/09 09:56

WG297941

WG297941-01

HPMS10

Blank File ID:

Prep Date:

Analyzed Date:

Work Group:

Blank Sample ID:

Instrument ID:

8260BMethod:

TMBAnalyst:


LCS

LCS2

FBLK

TRIP BLANK

16WW32-031709

16WW16-031709

WG297941-02

WG297941-03

WG297941-04

L09030427-11

L09030427-03

L09030427-05

10M71264

10M71265

10M71266

10M71269

10M71271

10M71272

03/23/09 10:28

03/23/09 11:01

03/23/09 11:33

03/23/09 13:10

03/23/09 14:15

03/23/09 14:47

This Method Blank Applies To The Following Samples:

Client ID Lab Sample ID Lab File ID Time Analyzed TAG

01

01

01

01

01

DL02

51

00087235


METHOD BLANK REPORT

Report Name:BLANK

PDF ID: 1351339

26-MAR-2009 14:56

Analytes Concentration Dilution Qualifier

Acetone

Benzene

Bromobenzene

Bromochloromethane

Bromodichloromethane

Bromoform

Bromomethane

2-Butanone

n-Butylbenzene

sec-Butylbenzene

tert-Butylbenzene

Carbon disulfide

Carbon tetrachloride

Chlorobenzene

Chlorodibromomethane

Chloroethane

2-Chloroethyl vinyl ether

Chloroform

Chloromethane

2-Chlorotoluene

4-Chlorotoluene

1,2-Dibromo-3-chloropropane

1,2-Dibromoethane

Dibromomethane

1,2-Dichlorobenzene

1,3-Dichlorobenzene

1,4-Dichlorobenzene

Dichlorodifluoromethane

1,1-Dichloroethane

1,2-Dichloroethane

1,1-Dichloroethene

cis-1,2-Dichloroethene

trans-1,2-Dichloroethene

1,2-Dichloropropane

1,3-Dichloropropane

2,2-Dichloropropane

cis-1,3-Dichloropropene

trans-1,3-Dichloropropene

1,1-Dichloropropene

Ethylbenzene

2-Hexanone

Hexachlorobutadiene

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

2.50

0.125

0.125

0.200

0.250

0.500

0.500

2.50

0.250

0.250

0.250

0.500

0.250

0.125

0.250

0.500

2.00

0.125

0.250

0.125

0.250

1.00

0.250

0.250

0.125

0.250

0.125

0.250

0.125

0.250

0.500

0.250

0.250

0.200

0.200

0.250

0.250

0.500

0.250

0.250

2.50

0.250

10.0

1.00

1.00

1.00

1.00

1.00

1.00

10.0

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

10.0

1.00

1.00

1.00

1.00

5.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

10.0

1.00

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

2.50

0.125

0.125

0.200

0.250

0.500

0.500

2.50

0.250

0.250

0.250

0.500

0.250

0.125

0.250

0.500

2.00

0.125

0.250

0.125

0.250

1.00

0.250

0.250

0.125

0.250

0.125

0.250

0.125

0.250

0.500

0.250

0.250

0.200

0.200

0.250

0.250

0.500

0.250

0.250

2.50

0.250

10M71228

WG297819

Instrument ID:HPMS10

File ID:

Prep Date:03/20/09 09:40

Run Date:03/20/09 09:40

Analyst:TMB

Workgroup (AAB#): ug/LUnits:

8260BMethod:

WaterMatrix:

L09030427Login Number: WG297819-01Sample ID:

18-MAR-09Cal ID:HPMS10-DACA56-94-D-0020Contract #:

5030BPrep Method:

SDL PQL

52

00087236


METHOD BLANK REPORT

Report Name:BLANK

PDF ID: 1351339

26-MAR-2009 14:56



Toluene-d8


116

100

99.6

89.7

Surrogates % Recovery Surrogate Limits

86

80

88

86

-

-

-

-

118

120

110

115

Qualifier

PASS

PASS

PASS

PASS


Isopropylbenzene

p-Isopropyltoluene

4-Methyl-2-pentanone

Methylene chloride

Naphthalene

n-Propylbenzene

Styrene

1,1,1,2-Tetrachloroethane

1,1,2,2-Tetrachloroethane

Tetrachloroethene

Toluene

1,2,3-Trichlorobenzene

1,2,4-Trichlorobenzene

1,1,1-Trichloroethane

1,1,2-Trichloroethane

Trichloroethene

Trichlorofluoromethane

1,2,3-Trichloropropane

1,2,4-Trimethylbenzene

1,3,5-Trimethylbenzene

Vinyl acetate

Vinyl chloride

o-Xylene

m-,p-Xylene

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

0.250

0.250

2.50

0.250

0.200

0.125

0.125

0.250

0.125

0.250

0.250

0.150

0.200

0.250

0.250

0.250

0.250

0.500

0.250

0.250

2.50

0.250

0.250

0.500

1.00

1.00

10.0

5.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

10.0

1.00

1.00

1.00

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

0.250

0.250

2.50

0.250

0.200

0.125

0.125

0.250

0.125

0.250

0.250

0.150

0.200

0.250

0.250

0.250

0.250

0.500

0.250

0.250

2.50

0.250

0.250

0.500

ND Analyte Not detected at or above reporting limit

* |Analyte concentration| > RL

10M71228

WG297819


File ID:

Prep Date:03/20/09 09:40

Run Date:03/20/09 09:40

Analyst:TMB


8260BMethod:

WaterMatrix:



5030BPrep Method:

SDL PQL

SDL

PQL

Method Detection Limit

Reporting/Practical Quantitation Limit

53

00087237


METHOD BLANK REPORT

Report Name:BLANK

PDF ID: 1351339

26-MAR-2009 14:56


Acetone

Benzene

Bromobenzene

Bromochloromethane

Bromodichloromethane

Bromoform

Bromomethane

2-Butanone

n-Butylbenzene

sec-Butylbenzene

tert-Butylbenzene

Carbon disulfide

Carbon tetrachloride

Chlorobenzene

Chlorodibromomethane

Chloroethane

2-Chloroethyl vinyl ether

Chloroform

Chloromethane

2-Chlorotoluene

4-Chlorotoluene

1,2-Dibromo-3-chloropropane

1,2-Dibromoethane

Dibromomethane

1,2-Dichlorobenzene

1,3-Dichlorobenzene

1,4-Dichlorobenzene

Dichlorodifluoromethane

1,1-Dichloroethane

1,2-Dichloroethane

1,1-Dichloroethene

cis-1,2-Dichloroethene

trans-1,2-Dichloroethene

1,2-Dichloropropane

1,3-Dichloropropane

2,2-Dichloropropane

cis-1,3-Dichloropropene

trans-1,3-Dichloropropene

1,1-Dichloropropene

Ethylbenzene

2-Hexanone

Hexachlorobutadiene

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

2.50

0.125

0.125

0.200

0.250

0.500

0.500

2.50

0.250

0.250

0.250

0.500

0.250

0.125

0.250

0.500

2.00

0.125

0.250

0.125

0.250

1.00

0.250

0.250

0.125

0.250

0.125

0.250

0.125

0.250

0.500

0.250

0.250

0.200

0.200

0.250

0.250

0.500

0.250

0.250

2.50

0.250

10.0

1.00

1.00

1.00

1.00

1.00

1.00

10.0

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

10.0

1.00

1.00

1.00

1.00

5.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

10.0

1.00

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

2.50

0.125

0.125

0.200

0.250

0.500

0.500

2.50

0.250

0.250

0.250

0.500

0.250

0.125

0.250

0.500

2.00

0.125

0.250

0.125

0.250

1.00

0.250

0.250

0.125

0.250

0.125

0.250

0.125

0.250

0.500

0.250

0.250

0.200

0.200

0.250

0.250

0.500

0.250

0.250

2.50

0.250

10M71263

WG297941


File ID:

Prep Date:03/23/09 09:56

Run Date:03/23/09 09:56

Analyst:TMB


8260BMethod:

WaterMatrix:



5030BPrep Method:

SDL PQL

54

00087238


METHOD BLANK REPORT

Report Name:BLA

Documents

LONGHORN ARMY AMMUNITION PLANT KARNACK, TEXAS ...longhorn-engage.s3.amazonaws.com/static/2010 Volume 6 of 19.pdf · LONGHORN ARMY AMMUNITION PLANT KARNACK, TEXAS ADMINISTRATIVE RECORD