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Organic Macromolecules
Chemical ReactionsThe rearrangement of atoms
6 CO2 + 6 H2O C6H12O6 + 6 O2
(Reactants) (Products)
En
erg
yTime
Chemical ReactionsEndergonic Reaction
Energy is required
Exergonic Reaction Energy is released
Activation Energy Energy req’d to start rxn
Catalyst Decreases AE Speeds up rxns
ProductsReactants
Chemical Reactions Review
2 Mg + O2 2 MgO Was energy mostly released or absorbed? Is this reaction exergonic or endergonic? Why doesn’t this reaction occur on its
own?
6 CO2 + 6 H2O C6H12O6 + 6 O2
Is energy mostly released or absorbed? Is this reaction exergonic or endergonic? Where does the absorbed energy go?
Condensation (dehydration) Monomers join to form polymers
Hydrolysis Polymers can be split into monomers
Macromolecular Structure
Macromolecular Structure
C O H
H
H
H C O H
H
H
H
Dehydration/Condensation
1. H and OH are removed
2. Monomers bond
Macromolecular Structure
C
O H
H
H
H C O H
H
H
H
Hydrolysis
1. Molecules separate
2. Water lyses and occupies open bonds
CarbohydratesC, H, & O in 1:2:1 ratio
Often in rings
or linked rings
Monosaccharide (simple sugar) Carbohydrate monomer Glucose - Photosynthesis Fructose - Fruit Galactose - Milk
CarbohydratesPolysaccharide (sugars linked together) Cellulose - Plant cell walls, wood, cotton Starch - Plant energy storage
Lots of C, twice as much H, very little O
Hydrocarbon chains
Fatty acid (monomer)
Triglyceride (polymer) 3 fatty acids linked together Oil (liquid) - E storage Fat (solid) - E storage,
insulation,
padding
Lipids
Nonpolar- Won’t dissolve in H2O
Polar- Will dissolve in H2O
=
LipidsSteroids (four carbon rings) Cholesterol, venoms, hormones
ProteinsC, H, O, N and sometimes S
Peptide = Amino Acid = Protein Monomer
Over twenty varieties
(Differ only in “radical” group)
R
Radical Group
C
H
NH
HC
O
O H
Proteins
ProteinsPolymers made of amino acids
Structural examples Muscle fibers, hair, cytoskeleton Cell membrane proteins
ProteinsEnzymes Protein catalysts Help convert substrates to products
C C
H H
H H
H C C
H H
H H
HO
H
H
Rate of RxnsTemperature As temp ↑, collisions are more frequent (rate ↑) At high temps, enzyme changes shape (rate ↓)
Temperature
Rat
e
Denaturation
Rate of RxnspH Different enzymes have different optimal
ranges
Rate of RxnsAs [substrate] ↑,
Rate ↑
[substrate]
Rat
e
Nucleic Acids
Nucleotide (monomer) Phosphate group 5-C monosaccharide
Ribose
Deoxyribose Nitrogen base
A, C, G, T, or U
Nucleic AcidsNucleic Acid Polymers RNA
Protein synthesis DNA
Primary genetic info