Embed Size (px)
DESCRIPTION
balanços massicos
Citation preview
Massa molecular (kg/kmol)Isobutanol (C4H10O) 74.1
Isobutileno (C4H8) 56.1Isobutano (C4H10) 58.1
Hidrogênio (H2) 2.0C12H20 164.3
Isoocteno (C8H16) 112.2Benzeno (C6H6) 78.1Tolueno (C7H8) 92.1Metano (CH4) 16.0
Isooctano (C8H18) 114.2Nonano (C9H20) 128.3O-Xileno (C8H10) 106.2P-Xileno (C8H10) 106.2
Água 18.0
Seletividade Isobutileno/Isobutanol 0.969
Balanço a espécie (kmol/h) CorrenteIsobutanol 0.269905533063428 3Água total 15.6068905294912 5Isobutileno 13.225371120108 4
Correntes de entrada (1) [kg/h]1042.8673493689
Diferença das correntes
Corrente 1 (kg/h) Isobutanol (kg/h) Água (kg/h)1042.8673493689 1000 42.8673493689
Isobutanol (kmol/h) Água (kmol/h)13.4952766531714 2.38151940938
X (Isobutanol) F1total0.98 15.8767960625546
CompostoIsobutanolIsobutileno
Balanco a espécie (kg/h) Água20 Total
280.924029530841741.943319838057
74.1256.1158.122.02
164.29112.2178.1192.1416.04
114.23128.26106.17106.17
18.02
Correntes de saida (2+3+4) [kg/h]1042.8673493689
0
ton/ano 2656412.72kg/ano 2656412720kg/dia 7277843.06849kg/h 303243.461187
Entrada Saída1000 20
0 741.94331983842.8673493688974 280.9240295311042.8673493689 1042.86734937
Massa molecular (kg/kmol)Isobutanol (C4H10O) 74.1
Isobutileno (C4H8) 56.1Isobutano (C4H10) 58.1
Hidrogênio (H2) 2C12H20 164.3
Isoocteno (C8H16) 112.2Benzeno (C6H6) 78.1Tolueno (C7H8) 92.1Metano (CH4) 16
Isooctano (C8H18) 114.2Nonano (C9H20) 128.3O-Xileno (C8H10) 106.2P-Xileno (C8H10) 106.2
Água 18
Seletividade Isoocteno/Isobutileno 0.974Seletividade Isobutano/Isobutileno 0.013
Seletividade C12H20/Isobutileno 0.013
Balanço a espécie (kmol/h) Corrente SaídaIsobutanol 0.269905533063428 3Isobutano 0.0645155774426319 4Isoocteno 4.9627367263563 7
Hidrogênio 0.0645155774426319 6C12H20 0.0645155774426319 5
Isobutileno 3.04183535762483 8
Correntes de entrada (1) [kg/h]761.943319838057
Diferença das correntes
Corrente 1 e 2 (kg/h) Isobutanol (kg/h) Isobutileno (kg/h)761.943319838057 20 741.943319838057
Isobutanol (kmol/h) Isobutileno (kmol/h)0.269905533063428 13.225371120108
X (Isobutileno) X1 X2 X30.77 0.00487816764132554 0.00487816764132554 0.375243664717349
Balanco a espécie (kg/h)20
3.74835504941692556.819060697177
0.12903115488526410.5999093738244170.646963562753
Correntes de saida (2+3+4) [kg/h]761.943319838057
0
Massa molecular (kg/kmol)Isobutanol (C4H10O) 74.1
Isobutileno (C4H8) 56.1Isobutano (C4H10) 58.1
Hidrogênio (H2) 2C12H20 164.3
Isoocteno (C8H16) 112.2Benzeno (C6H6) 78.1Tolueno (C7H8) 92.1Metano (CH4) 16
Isooctano (C8H18) 114.2Nonano (C9H20) 128.3O-Xileno (C8H10) 106.2P-Xileno (C8H10) 106.2
Água 18
Seletividade PX/Isoocteno 0.9Seletividade Isooctano/Isoocteno 0.02Seletividade Benzeno/Isoocteno 0.02Seletividade Tolueno/Isoocteno 0.02
Seletividade OX/Isoocteno 0.02Seletividade C9/Isoocteno 0.02
Balanço a espécie (kmol/h) Corrente SaídaIsobutanol (C4H10O) 0.26990553 9
Isobutileno (C4H8) 3.04183536 12Isobutano (C4H10) 0.06451558 8
Hidrogênio (H2) 6.43766208 10C12H20 0.06451558 7
Isoocteno (C8H16) 2.74410855 11Benzeno (C6H6) 0.01342321 14Tolueno (C7H8) 0.00680689 16Metano (CH4) 0.03041761 15
Isooctano (C8H18) 0.03027269 13Nonano (C9H20) 0.03027269 19O-Xileno (C8H10) 0.03027269 17P-Xileno (C8H10) 2.10420037 18
0.00487816764132554
0.375243664717349
0.77
[kg/h]Corrente 1 a 6 (kg/h) Isobutanol 20761.943319838057 Isobutano 3.74835504941692
Isoocteno 556.819060697177Hidrogênio 0.129031154885264
C12H20 10.5999093738244Isobutileno 170.646963562753
X (Isobutileno) X1 X20.47 0.0061 0.0003381
X4 X50.0061 0.424
Balanco a espécie (kg/h)20
170.6469635627533.7483550494169212.875324162858810.5999093738244307.8889791514551.04835272423073
0.6269145408054550.4866816950909293.457141658314333.883986644148233.21496010606814223.466079503753
0.008545454545454550.000949494949494950.00170909090909091
0.00854545454545460.00854545454545454
0.427272727272728
Correntes de entrada (1) [kg/h] Correntes de saida (2+3+4) [kg/h]761.943319838057 761.943648172719
Diferença das correntes 0.000328334661958252
[kmol/h]0.269905533063428
0.06451557744263194.9627367263563
0.06451557744263190.0645155774426319
3.04183535762483
X3 0.470.0003429
X60.0061
Rendimento (PX/Isobutanol)0.223466079503753
Entrada Isobutanol Saída Isobutanol13.4952766531714 0.269905533063428
Conversão Global 0.98
0.008487584650112860.00106094808126411
0.00212189616252822
0.008487584650112930.4243792325056420.00848758465011283
Balanço a espécie (kmol/h) Corrente SaídaIsobutanol (C4H10O) 1.68371120107962 9
Isobutileno (C4H8) 19.0579270850202 12Isobutano (C4H10) 0.247505546558704 8
Hidrogênio (H2) 42.560684177952 10C12H20 8.74519597840756 7
Isoocteno (C8H16) 9.79461949581647 11Benzeno (C6H6) 0.184804141430499 14Tolueno (C7H8) 0.00369608282860999 16Metano (CH4) 0.547205062775709 15
Isooctano (C8H18) 0.0182956100016194 13Nonano (C9H20) 0.0182956100016194 19O-Xileno (C8H10) 0.0182956100016194 17P-Xileno (C8H10) 8.42706884923077 18
28.1950282485876
Balanços de massa [kmol/h]1 2
Isobutanol (C4H10O) 13.4952766531714 0.269905533063428Isobutileno (C4H8) 0 13.225371120108Isobutano (C4H10) 0 0
Hidrogênio (H2) 0 0C12H20 0 0
Isoocteno (C8H16) 0 0Benzeno (C6H6) 0 0Tolueno (C7H8) 0 0Metano (CH4) 0 0
Isooctano (C8H18) 0 0Nonano (C9H20) 0 0O-Xileno (C8H10) 0 0P-Xileno (C8H10) 0 0
Água 2.38151940938319 15.6068905294912
Balanços de massa [kg/h]1 2
Isobutanol (C4H10O) 1000 20Isobutileno (C4H8) 0 741.943319838057Isobutano (C4H10) 0 0
Hidrogênio (H2) 0 0C12H20 0 0
Isoocteno (C8H16) 0 0Benzeno (C6H6) 0 0
Tolueno (C7H8) 0 0Metano (CH4) 0 0
Isooctano (C8H18) 0 0Nonano (C9H20) 0 0O-Xileno (C8H10) 0 0P-Xileno (C8H10) 0 0
Água 42.8673493688974 280.924029530841TOTAL 1042.8673493689 1042.8673493689
Balanco a espécie (kg/h)124.763
1069.1497094696414.380072255060785.1213683559039 f4,21436.83569925236 Isobutanol (C4H10O) 11098.95630743061 Isobutileno (C4H8) 014.433203445722 Isobutano (C4H10) 0
0.34040922851498 Hidrogênio (H2) 08.75528100441134 C12H20 02.08935866218494 Isoocteno (C8H16) 02.34732676320777 Benzeno (C6H6) 01.94299378217198 Tolueno (C7H8) 0894.954711788308 Metano (CH4) 0
Isooctano (C8H18) 0Nonano (C9H20) 0O-Xileno (C8H10) 0P-Xileno (C8H10) 0
Água 1
Balanços de massa [kmol/h]3 4 5 60 0.2699055 0.00000 0.00000
13.225371120108 0 17.17581 3.95043552938290 0 0.08379 0.08378646421121030 0 0.00000 0.083790 0 0.00000 0.08378646421121030 0 0.00000 6.445110 0 0.00000 0.000000 0 0.00000 0.000000 0 0.00000 0.000000 0 0.00000 0.000000 0 0.00000 0.000000 0 0.00000 0.000000 0 0.00000 0.000000 15.606891 0.00000 0.00000
Balanços de massa [kg/h]3 4 5 60 20 0.00000 0.00000
741.943319838057 0 963.56275 221.6194331983810 0 0.00000 4.867993570671320 0 4.86799 0.1675729284224210 0 0.00000 13.76611606990190 0 0.00000 0.000000 0 0.00000 0.00000
0 0 0.00000 0.000000 0 0.00000 0.000000 0 0.00000 0.000000 0 0.00000 0.000000 0 0.00000 0.000000 0 0.00000 0.000000 280.92403 0.00000 0.00000
741.943319838057 300.92403 968.430746607109 240.421115767376
Entrada (1) Saída (4+11+13+16+19+20)1042.8673493689 1042.86670855144
0.000640817453813725
Rendimento Global0.64916852207978
Conversão Isobutanol0.98
*****A correntes de saída estão mal numeradas, referem-se ao diagrama manual. São as correntes de saída do R3***
f9,8 f11,9 f13,10 f15,14 f17,15 f19,180 0 0 0 0 01 0 0 0 0 01 0 0 0 0 01 1 0 0 0 00 0 0 0 0 00 0 0 1 1 00 0 1 0 0 00 0 1 0 0 01 1 0 0 0 00 0 0 0 1 00 0 0 0 0 00 0 0 1 0 00 0 0 1 0 10 0 0 0 0 0
Balanços de massa [kmol/h]7 8 9 10 11 12
0.00000 0.00000 0.00000 0.00000 0.00000 0.000003.95044 3.95044 3.95044 0.00000 0.00000 3.950440.08379 0.08379 0.08379 0.00000 0.00000 0.083790.08379 18.59776 18.59776 0.00000 18.59776 0.000000.08379 0.08379 0.00000 0.08379 0.00000 0.00000
14.41674 7.97163 0.00000 7.97163 0.00000 0.000000.00000 0.03899 0.00000 0.03899 0.00000 0.000000.00000 0.01977 0.00000 0.01977 0.00000 0.000000.00000 0.08836 0.08836 0.00000 0.08836 0.000000.00000 0.08794 0.00000 0.08794 0.00000 0.000000.00000 0.08794 0.00000 0.08794 0.00000 0.000000.00000 0.08794 0.00000 0.08794 0.00000 0.000000.00000 6.11270 0.00000 6.11270 0.00000 0.000000.00000 0.00000 0.00000 0.00000 0.00000 0.00000
Balanços de massa [kg/h]7 8 9 10 11 12
0.00000 0.00000 0.00000 0.00000 0.00000 0.00000221.61943 221.61943 221.61943 0.00000 0.00000 221.61943
4.86799 4.86799 4.86799 0.00000 0.00000 4.867990.16757 37.19552 37.19552 0.00000 37.19552 0.00000
13.76612 13.76612 0.00000 13.76612 0.00000 0.000001617.55828 894.41688 0.00000 894.41688 0.00000 0.00000
0.00000 3.04546 0.00000 3.04546 0.00000 0.00000
0.00000 1.82119 0.00000 1.82119 0.00000 0.000000.00000 1.41381 1.41381 0.00000 1.41381 0.000000.00000 10.04299 0.00000 10.04299 0.00000 0.000000.00000 11.28297 0.00000 11.28297 0.00000 0.000000.00000 9.33945 0.00000 9.33945 0.00000 0.000000.00000 649.16852 0.00000 649.16852 0.00000 0.000000.00000 0.00000 0.00000 0.00000 0.00000 0.00000
1857.979393522 1857.9803374 265.09675531539 1592.88358211 38.6093285463 226.48742676905
*****A correntes de saída estão mal numeradas, referem-se ao diagrama manual. São as correntes de saída do R3***
Massa molecular (kg/kmol)Isobutanol (C4H10O) 74.1
Isobutileno (C4H8) 56.1Isobutano (C4H10) 58.1
Hidrogênio (H2) 2.0C12H20 164.3
Isoocteno (C8H16) 112.2Benzeno (C6H6) 78.1Tolueno (C7H8) 92.1Metano (CH4) 16.0
Isooctano (C8H18) 114.2Nonano (C9H20) 128.3O-Xileno (C8H10) 106.2P-Xileno (C8H10) 106.2
Água 18.0
Balanços de massa [kmol/h]13 14 15 16
0.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.08379 0.00000 0.083790.00000 7.97163 7.97163 0.000000.03899 0.03899 0.00000 0.038990.01977 0.01977 0.00000 0.019770.00000 0.00000 0.00000 0.000000.00000 0.08794 0.00000 0.087940.00000 0.08794 0.00000 0.087940.00000 0.08794 0.08794 0.000000.00000 6.11270 6.11270 0.000000.00000 0.00000 0.00000 0.00000
Balanços de massa [kg/h]13 14 15 16
0.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 13.76612 0.00000 13.766120.00000 894.41688 894.41688 0.000003.04546 3.04546 0.00000 3.04546
1.82119 1.82119 0.00000 1.821190.00000 0.00000 0.00000 0.000000.00000 10.04299 0.00000 10.042990.00000 11.28297 0.00000 11.282970.00000 9.33945 9.33945 0.000000.00000 649.16852 649.16852 0.000000.00000 0.00000 0.00000 0.00000
4.86664811477 1592.88358211258 1552.92485462694 39.9587274856
Reator 2 X X1 X2 X30.77 0.0048781676 0.00487817 0.37524366
Reator 3 X X1 X2 X3 X4 X5 X60.47 6.10E-03 3.38E-04 3.43E-04 6.10E-03 4.24E-01 6.10E-03
Balanços de massa [kmol/h]17 18 19 20
0.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000007.97163 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.08794 0.00000 0.087940.00000 6.11270 6.11270 0.000000.00000 0.00000 0.00000 0.00000
Balanços de massa [kg/h]17 18 19 20
0.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.00000
894.41688 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.00000
0.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 0.00000 0.00000 0.000000.00000 9.33945 0.00000 9.339450.00000 649.16852 649.16852 0.000000.00000 0.00000 0.00000 0.00000
894.41687975309 658.50797487 649.16852208 9.33945279
