Quantum Theory II.ppt

  • Upload
    3334333

  • View
    255

  • Download
    0

Embed Size (px)

Citation preview

  • 7/27/2019 Quantum Theory II.ppt

    1/43

    Quantum Theory II

    Schrdinger's Equation

    Particle in a box or well

    TunnelingHydrogen Atom

    Spin

  • 7/27/2019 Quantum Theory II.ppt

    2/43

    Name That Tune

    He was born on Sept 23, 1949

    in Long Branch NJ

    He is known for his brand of heartland rockinfused with pop hooks, poetic lyrics, and

    Americana sentiments centered around his

    native New Jersey.

    His father was a bus driver

    At the age of 13, he bought his first guitar for $18

    after seeing Elvis Presley on the Ed Sullivan Show

    http://images.google.com/imgres?imgurl=http://members.aol.com/daboss72/bruce/house1.jpg&imgrefurl=http://members.aol.com/daboss72/bruce/bruce.htm&h=400&w=600&sz=36&tbnid=JyjR9anCTLcQqM:&tbnh=88&tbnw=133&hl=en&start=76&prev=/images%3Fq%3DBruce%2BSpringsteen%26start%3D60%26svnum%3D10%26hl%3Den%26lr%3D%26sa%3DNhttp://images.google.com/imgres?imgurl=http://www.brucespringsteen.hu/images/kepek_nagy/2000_Bruce2002a.jpg&imgrefurl=http://www.brucespringsteen.hu/kepek_2000.htm&h=500&w=404&sz=45&tbnid=YIBZnneZ5fmofM:&tbnh=127&tbnw=102&hl=en&start=34&prev=/images%3Fq%3DBruce%2BSpringsteen%26start%3D20%26svnum%3D10%26hl%3Den%26lr%3D%26sa%3DN
  • 7/27/2019 Quantum Theory II.ppt

    3/43

    Name That Tune

    He is known for his brand of heartland rockinfused with pop hooks, poetic lyrics, and

    Americana sentiments centered around his

    native New Jersey.

    At the age of 13, he bought his first guitar for $18

    after seeing Elvis Presley on the Ed Sullivan Show

    He responded to the September 11, 2001

    attacks was his album The Rising.

    Frequently toured and recorded with E Street Band

    He is probably best known for hisalbumBorn in the U.S.A.. (1984),

    which sold 15 million copies.

    http://en.wikipedia.org/wiki/Born_in_the_U.S.A.http://en.wikipedia.org/wiki/1984http://en.wikipedia.org/wiki/Born_in_the_U.S.A.http://en.wikipedia.org/wiki/1984http://en.wikipedia.org/wiki/1984http://en.wikipedia.org/wiki/Born_in_the_U.S.A.http://images.google.com/imgres?imgurl=http://images.art.com/images/-/Bruce-Springsteen--C10102050.jpeg&imgrefurl=http://www.art.com/asp/sp-asp/_/pd--10102050/Bruce_Springsteen.htm&h=477&w=385&sz=26&tbnid=sNiU4kuCVjg6gM:&tbnh=126&tbnw=101&hl=en&start=1&prev=/images%3Fq%3DBruce%2BSpringsteen%26svnum%3D10%26hl%3Den%26lr%3D%26sa%3DGhttp://images.google.com/imgres?imgurl=http://www.brucespringsteen.hu/images/kepek_nagy/2000_Bruce2002a.jpg&imgrefurl=http://www.brucespringsteen.hu/kepek_2000.htm&h=500&w=404&sz=45&tbnid=YIBZnneZ5fmofM:&tbnh=127&tbnw=102&hl=en&start=34&prev=/images%3Fq%3DBruce%2BSpringsteen%26start%3D20%26svnum%3D10%26hl%3Den%26lr%3D%26sa%3DN
  • 7/27/2019 Quantum Theory II.ppt

    4/43

    Quantum Theory II

    Schrdinger's Equation

    Particle in a box or well

    TunnelingHydrogen Atom

    Spin

  • 7/27/2019 Quantum Theory II.ppt

    5/43

    Schedule Change

    Wednesday, April 26 Quantum Theory I

    Read: Chapter 39

    Friday, April 28 Quantum Theory II

    Read: Chapter 40, Sections 1-4, 10Chapter 41, Sections 1-5

    Monday, May 1 Exam #3

    Wednesday, May 3 Nuclear Physics

  • 7/27/2019 Quantum Theory II.ppt

    6/43

    Class Question

    This is the wave function of

    a neutron. At what value ofx

    is the neutron most likely to

    be found?

    1. x =xA

    2. x =xB

    3. x =xC

    4. x = 0

  • 7/27/2019 Quantum Theory II.ppt

    7/43

    Class Question

    This is the wave function of

    a neutron. At what value ofx

    is the neutron most likely to

    be found?

    1. x =xA

    2. x =xB

    3. x =xC

    4. x = 0

  • 7/27/2019 Quantum Theory II.ppt

    8/43

    Reading Question

    The quantity is called the

    1. wave function.

    2. probability.

    3. probability density.4. amplitude density.

    5. Schrdinger function.

  • 7/27/2019 Quantum Theory II.ppt

    9/43

    Reading Question

    The quantity is called the

    1. wave function.

    2. probability.

    3. probability density.4. amplitude density.

    5. Schrdinger function.

  • 7/27/2019 Quantum Theory II.ppt

    10/43

    Quantum Theory

    Matter Waves

    hfE

    khp

  • 7/27/2019 Quantum Theory II.ppt

    11/43

    Quantum Theory

    This is one of the most important

    equations in physics

    ),,(),,(),,(),,(2

    2

    2

    zyxEzyxzyxVzyxm

    ),,(),,(),,( zyxEzyxVzyxK opop

    EVK

    ),,(),,(),,( zyxzyxdVzyxP

    ?4 i 212

    imaginary numbers

    imaginary function

  • 7/27/2019 Quantum Theory II.ppt

    12/43

    Quantum Theory

    Schrdinger's Equation in

    One-dimension

    )()()()(2 2

    22xExxVx

    dxd

    m

    )()()()(2

    xxxdxxP

    )(isequationthistosolutionThe x

  • 7/27/2019 Quantum Theory II.ppt

    13/43

    Quantum Theory

    Below are the wave functions for two different particles.

    Which particle has the largest momentum? Explain.

    particle 1

    particle 2

    )(2

    )(22

    2

    xmE

    xdx

    d

    In one-dimension

    and no potentialenergy

    Kp2

    2m

    So matter wave with the largest curvature (smallest

    wavelength) has the largest momentum.

  • 7/27/2019 Quantum Theory II.ppt

    14/43

    Quantum Theory

    The wave function has no physical meaning, but dx

    does. What is the physical meaning ofdx? Discuss

    this in your group.

    Below is a plot of for an electron in a electrical

    potential. Where is the electron most likely to be found?

    Explain.

    (x)(x)dxThe largest probability iswhere the function is a

    maximum.

    Probability of finding the particle in dx

  • 7/27/2019 Quantum Theory II.ppt

    15/43

  • 7/27/2019 Quantum Theory II.ppt

    16/43

    Student Workbook

  • 7/27/2019 Quantum Theory II.ppt

    17/43

  • 7/27/2019 Quantum Theory II.ppt

    18/43

    Student Workbook

  • 7/27/2019 Quantum Theory II.ppt

    19/43

  • 7/27/2019 Quantum Theory II.ppt

    20/43

    Quantum Theory

    )()(2 2

    22

    xExdx

    d

    m

    )()(2)(22

    2

    xaxmExdxd

    kxAx sin)(

    kxBx cos)(

    kxBkxAx cossin)(

    Boundary conditions 00)0( Bx

    Particle in a one-dimensional box

    kxAx sin)(

    x = 0 x = L

  • 7/27/2019 Quantum Theory II.ppt

    21/43

    Quantum Theory

    kxAx sin)(

    2

    2

    2

    8n

    mL

    hE

    n

    )()(2 2

    22

    xExdx

    d

    m

    nLk 22

    0)(

    Lx

    Boundary condition

    Particle in a one-dimensional box

    x = 0 x = L

  • 7/27/2019 Quantum Theory II.ppt

    22/43

    Quantum Theory

    dxxxdxxP )()()(

    xkAx nsin)(

    xkA

    xxxP

    n

    22 sin

    )()()(

  • 7/27/2019 Quantum Theory II.ppt

    23/43

    Quantum Theory

    The Infinite Square Well or Particle in a Box What is the equation that describes the energy for a particle

    in a box?

    What is the ground state energy for an electron in a box 5.0nm in length?

    What is the energy of the first excited state for an electronin a box 1.0 nm in length?

    En 2h2

    mL2n

    2

    eV

    nmkgX

    JsX

    mL

    hE ??

    0.51011.9

    106.621

    2229

    34

    2

    2

    2

    1

    E2

    E1

    n2

  • 7/27/2019 Quantum Theory II.ppt

    24/43

    Quantum Theory

    Growth via Chemical Beam Epitaxy (CBE) A contacted InAs/InP nanowire

    50nm

    0.6 eV

    InA

    s

    InA

    s

    InA

    s

    In

    P

    In

    P

    Ec

    TEM photo of InAs/InP nanowire Energy landscape

    TMInP2(As2)

  • 7/27/2019 Quantum Theory II.ppt

    25/43

  • 7/27/2019 Quantum Theory II.ppt

    26/43

    Student Workbook

  • 7/27/2019 Quantum Theory II.ppt

    27/43

    Student Workbook

  • 7/27/2019 Quantum Theory II.ppt

    28/43

    Student Workbook

  • 7/27/2019 Quantum Theory II.ppt

    29/43

    Student Workbook

  • 7/27/2019 Quantum Theory II.ppt

    30/43

    Student Workbook

  • 7/27/2019 Quantum Theory II.ppt

    31/43

    Class Question

    A particle in the ground state of a potential energy well

    1. is at rest.

    2. has a zero-point motion.

    3. is equally probable to be found at any pointinside the well.

    4. has a wave function that is zero at all points.

    5. has zero energy.

  • 7/27/2019 Quantum Theory II.ppt

    32/43

    Class Question

    A particle in the ground state of a potential energy well

    1. is at rest.

    2. has a zero-point motion.

    3. is equally probable to be found at any pointinside the well.

    4. has a wave function that is zero at all points.

    5. has zero energy.

  • 7/27/2019 Quantum Theory II.ppt

    33/43

    Class Question

    A particle in a rigid box in the n = 2 stationary state is most

    likely to be found

    1. One-quarter of the way from either end.

    2. One-third of the way from either end.3. In the center of the box.

    4. It is equally likely to be found at any point

    in the box.

  • 7/27/2019 Quantum Theory II.ppt

    34/43

    Class Question

    A particle in a rigid box in the n = 2 stationary state is most

    likely to be found

    1. One-quarter of the way from either end.

    2. One-third of the way from either end.3. In the center of the box.

    4. It is equally likely to be found at any point

    in the box.

  • 7/27/2019 Quantum Theory II.ppt

    35/43

    Class Question

    For which potential energy is this an appropriate n = 4

    wave function?

    (1) (2) (3) (4)

  • 7/27/2019 Quantum Theory II.ppt

    36/43

  • 7/27/2019 Quantum Theory II.ppt

    37/43

    Quantum Theory

    Plot the energy levels for a particle in a box (n = 1 to 5) andthe energy levels we found for the hydrogen atom (n = 1 to 4).

    E = 0

    E = -10 eV

    E = -5 eV

    E = 5 eV

    E = 10 eV

    E = 15 eV

    E = -15 eV

    n = 1

    n = 2n = 3

    n = infinityn = 1

    n = 2

    n = 3

  • 7/27/2019 Quantum Theory II.ppt

    38/43

  • 7/27/2019 Quantum Theory II.ppt

    39/43

    Quantum Theory

    Tunneling Microscope

  • 7/27/2019 Quantum Theory II.ppt

    40/43

    Student Workbook

  • 7/27/2019 Quantum Theory II.ppt

    41/43

    Class Question

    A quantum particle can pass through a region of space that

    would be forbidden to a classical particle. What is the name of

    this process?1. Teleportation

    2. Vacuum decay3. Lasing

    4. Trapping

    5. Tunneling

  • 7/27/2019 Quantum Theory II.ppt

    42/43

    Class Question

    1. Decreases.

    2. Increases.

    3. Does not change.

    A particle with energyEapproaches an energy barrier with

    height U0 >E. IfU0 is slowly decreased, the probability that

    the particle reflects from the barrier

  • 7/27/2019 Quantum Theory II.ppt

    43/43