78
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION III CENTRAL REGIONAL LABORATORY 839 BESTGATE ROAD ANNAPOLIS, MARYLAND 21401 (301)266-9180 ' March 31, 1989 SUBJECT: Organic Data Validation for the Eastern Diversified Site Case 10591 FROM :Theresa A> Region III Acting ESAT DPO (3ES23) TO : Suzanne Billings Regional Project Manager (3HW12) THRU : Patricia J. Chief, QA Section (3ES23) Attached is the organic data review for the Eastern Diversified Site (Case 10591) completed by the Region III Environmental Services Assistance Team (ESAT) contractor under the direction of Region III ESD. If you have any questions regarding this review, please call me. Attachment cc: Mark diFeliciantonio, CDM Virginia Nicholas, GCL Elaine Spiewak (3HW10) (w/o attachments) TID File: 03890225 Task 1514 AR3QI887

REGION III CENTRAL REGIONAL LABORATORY 839 BESTGATE … · REGION III CENTRAL REGIONAL LABORATORY 839 BESTGATE ROAD ... Case 10591 FROM : ... . 2 ° 2 _ z o CO-Bromodlchlofomelhan

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UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION III

CENTRAL REGIONAL LABORATORY839 BESTGATE ROAD

ANNAPOLIS, MARYLAND 21401(301) 266-9180

' March 31, 1989SUBJECT:

Organic Data Validation for the Eastern Diversified SiteCase 10591

FROM : Theresa A>Region III Acting ESAT DPO (3ES23)

TO :Suzanne BillingsRegional Project Manager (3HW12)

THRU : Patricia J.Chief, QA Section (3ES23)

Attached is the organic data review for the Eastern Diversified Site (Case10591) completed by the Region III Environmental Services Assistance Team(ESAT) contractor under the direction of Region III ESD.

If you have any questions regarding this review, please call me.

Attachment

cc: Mark diFeliciantonio, CDMVirginia Nicholas, GCLElaine Spiewak (3HW10) (w/o attachments)

TID File: 03890225 Task 1514

AR3QI887

2568A RIVA ROADSUITE 300ANNAPOLIS, MD 21401PHONE 301-266-9887

MANAGERS X^ DESIGNERS/CONSULTANTS

DATE: March 23, 1989

SUBJECT: Organic Data Validation for Case 10591Site: Eastern Diversified . .

Sfc.*-PROM: Nicholas

Senior Analytical ChemistSudabeh Rowshan-KolarSenior Organic Chemist

TO: Terry SimpsonActing ESAT Deputy Project '.Officer

THROUGH: Charles Matkovichc^ESAT Team Manager

Overview

Case 10591 consisted of three (3) soil samples and two (2) watersamples. Two (2) soil samples were analyzed for full organics and_one (1) soil sample was analyzed for semi-volatile and pesticide"analyses only. One (1) water sample was analyzed for fullorganics and one (1) was analyzed for volatile organics only.Included in this case were one (1) trip blank, one (1) equipmentblank, and one (1) field duplicate pair. The laboratory analyzedall samples as a Contract Laboratory Program (CLP) RoutineAnalytical Service (RAS) .

Summary

samples were successfully analyzed for all target compounds.All instrument and method sensitivities were according to theContract Laboratory Program (CLP) Routine Analytical Services(RAS) protocol.

Minor Problem

o Several volatile and semi-volatile compounds failed precisioncriteria for initial and continuing calibration standards.Quantitation limits are qualified "UJ" for the affected samples,(See Table I and Forms VI and VII in Appendix F) .

AR3Q1888

.Case 10591 Page 2 of 2

Notes

o The maximum concentrations of compounds found in the trip,equipment and method blanks are listed below. All samples withconcentrations of common laboratory contaminants- less than ten(<ldx) the blank level are qualified as "B" in the data summary.(See\ Data Summary forms in Appendix B).

Compound Concentration fucr/L)\methylene chloride* 9acetone* 390

* = common laboratory contaminants

The field duplicate pair (CY755 and CY756) yielded datathat was usable for comparison. The results for precisionestimates are as follows:

Compound Sample Concentrat ion fug/Kg)

CY755 CY756 RPDbis(2-ethylhexyl)phthalate 470J 11000 183

^ RPD = Relative Percent Difference

All data for Case 10591 was reviewed in accordance with theFunctional Guidelines for Evaluating Organic Analyses withModifications for Use Within Region III. This report addressesonly those problems affecting usability.

Attachments

1) Appendix A - Glossary of Data Qualifier Codes2) Appendix B - Data Summary These include:

(a) All positive results for target compounds withqualifier flags where applicable.

(b) All unusable detection limits (qualified "R").3) Appendix C - Results as Reported by the Laboratory for

all Target Compounds4) Appendix D - Reviewed and Corrected Tentatively

Identified Compound Lists5) Appendix E - DPO Report for Contractual Compliance6) Appendix F - Support Documentation

AR301889

Appendix A

Glossary of Data Qualifier Codes

AR30I890

GLOSSARY OF DATA QUALIFIER CODES (ORGANIC)

CODES RELATING TO IDENTIFICATION(confidence concerning presence or absence of compounds):

U - Not detected. The associated number indicatesapproximate sample concentration necessary to bedetected.

(NO CODE) - Confirmed identification.

B - Not detected substantially above the \level reported inlaboratory or field blanks.

- \R - Unreliable result. Analyte may or may not be present

in the sample. Supporting data necessary to confirmresult.

N - Tentative identification. Consider present. Specialmethods may be needed to confirm its presence orabsence in future sampling efforts.

CODES -RELATED TO OUANTITATION(can be used for both positive results and sample quantitationlimits):

J - Analyte present. Reported value may not be accurate orprecise.

«-

K - Analyte present. Reported value may be biased high.Actual value is expected to be lower.

L - Analyte present. Reported value may be biased low.Actual value is expected to be higher.

\~ UJ - Not detected, quantitation limit may be inaccurate or

imprecise. ,

UL - Not detected; quantitation limit is probably higher.

OTHER CODES

Q - No analytical result.

AR30I89I

Appendix B

Data Summary Forms

\

flR30I892

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ae

on-I-

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a

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<-

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Carbon Tetracliloilde

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2-Bulanone •

K

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VI

s>

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m

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-

Total-1. 2 Dlchbtoctliene

-

1.1-DlchlMoellmne

.1,1-D)ch!oroethenc

t

S,1

S"

3

w

2

o

o

ChJofoelhano

0

1O

1

o

Bromomeliiine

o

3a

iP-

Sample No.Dilution Factor

% MoistureLocation

COMPOUNDt |

"1

.

»&

dXi

*

k

o

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5

Pi

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IF

8

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33

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S4£X

(BU

Ul

a

Ul

m

iN

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Chloiobenzene

m

Toluene

i

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1 ,1 ,2,2-Teltachloroelhane

-

Telrachlorodhene

o

2-Hexanona

— »

'A

^

o

1fs»I09ia

c

•H

Ul

uuojomojg

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Trans-1 ,.1-Dlchloropfopene

Ul

Benzene

m

1,1,2-Ttlchtofoethana

Ul

Dlbfomocliloromelliane

Ul

Tilchloroelhene

Ul

9V

1o1a

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1 ,2-Dlchloropropane

I

Sample No.1

Dilution Factor% MoistureLocation

COMPOUND•> ^

$

t f

v

J2»>

5

5-

0

i

^

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O CO9 99

io

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r-mCO

o33

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n

I

c

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oOoI m

2 2& |

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yifs

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4

8

(ou3i|aowmo|a-|,7

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3I35.

[•3a

§B

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3

2.4-Dlmelhvbhenol

§

3

[

-J

r

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§

Nitrobenzene

§

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§

N-Nltroso-dl n oroDvlamtne

sft,

[!2.

S

32ri™

|^

§

f2.

-

^

1 .2-Dlchlorobenzena

1a5

S

S

*-\

8

1 ,4-DIchlorobenzene

»

1 ,3-Dlchlorobenzene

§

ri

i3_

S

bls(2-Ch!oroelhvflel!ier

-3f

i

COMPOUND1*" -V

5 1

1 " !

w 5X&

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Location

•\

t

3

j

% Moisture

c>

^

Dilution Factor

•i»\

M

*

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BO

P

<V3

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33

B*

O _____________________________________ 5w I I I i I————i———' 1 I I I I I I i I I——I g

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2 zTJS >CO

7 -Si

TJm

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O g g 5 5 S 5 8 g g 5 g S 5 5 g 5 g 5 5 6 e e ^a _ —- — — _ _ — — _ — ___ — ________ o cop 8_ _ _ . _ . _ . . _ •

'« z f 6 » > 5s z > 8 z '« 2 f z 5 > > S £ o SO s S s - y O g ^ O a ^ O S » 5 - ' S V ? « » S »±£ ? M s" ~ SM S ~ w iu 3 ^> M *• 2 ST *» *» n ^ 3* noo

aac3aoC • i >c~) 11 jj

ca

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comm

33

1m•no3

SS. m*nS ^

OCO

-*.

4.6-DfnHro-2-methvlDhenol

i

4-Nitroanine

i

Fhiorene

a

ji.

S

3

0

§

2.4-Dlnltrototuena

§

Dibenzoluran

isr

r

i

2,4-Dlnltrophenol - ————

r

B

fasu1

|

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u

2.6 Dlnilrotoluene

S

r>

|f

u

1»_»

1

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1

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ca

2-Chtoronaphthalene

|

2.4.5-Trlchlorophenot

Uw

2.4.6-Trlchlorophenol

w5

f*n

[s?

»

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^

F

^

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u

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8

Hexachlorobutadiene

§

Location

COMPOUNDl_f\ ^v*^ ^

"S*V. N.

U 1

\

0E w

€^ O 3

S 3 "2.g. -n S"

5r

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4)

s£j

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1.§ I2» 5-

TJB

D

1

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O

n _ ._.„._._._._ ._ ._ _ .„ ._ ._ „ ._ ._ ._._.._._ _ _ _ _ _ _ _ _ _ _ _ _ _ _ %o

ao

S-°-fi

m

oo

CO

fI!I•

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DB>enz(a.h)anlhracena • •

•*-\

c

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r9

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Benzo(k)Duoranthena

5

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Benzofblltuoranthene

S

23

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§

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^

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a

53Tr»_S"r

o

;s>a

S

TV

3

1

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gag-

F5r7

3

Anthracene

o

Phenanthrene

i

Penlachlorophenot

3

Hexachlorobenzena

o

k3

[

I

1^?

S

Zi

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»

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Location

COMPOUND

jfX3 X\ «v

• rK

^t< *^^

^ 0\ 'S.U i

"Nt

% Moisture

,^

NV

t>%uO

d°sV>a

Dilution Factor

^A*

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f\•.

^^

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r<:>3\=

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X

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£

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oa.

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S rj<. rn«a Tlo. z?o O5 £

Ul

Blomodlchlorolnclhane

o

Vinyl Acetate

^

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en

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3

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S

^

en

VI

I15"3S.

VI

Chtorofoirn

Ul

* Total- 1,2-Dlchloroolhene

Ul

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en

4 1,1-Dicliloroolhoiio

en

Carbon Dlsuinde

3

Acetone

<O

en

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N&

Cs

-

;>

3

Chlofoelhane

3

•Vinyl Chloride

5

Bromomethane

5

oF?•a

i.

Location

COMPOUND

** t"

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Dilution Factor

a*Q\

*%»

COu•5e

P

£

-J

«•o

R

mco

3|

mTIOaoom ..Rr?a4-ggg

O COS S

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i :m3 r-co >

wm

_ COo - - - - - - - -a?„„„„.„....._._„.-„._._.-.-....

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mivlbenzene

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nlorobenzene

Ul

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a

en

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en

»

[rachloroethene

o

ro

exanone

S

s,

o

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^

5

en

ao

en

Sns-t. 3 Dlchloropropene

en

aeNaa

Ul

ro

13a

en

iromochlofomethane

en

=•

1a

Ul

Q•1,3 Dlchloropropene

«n

To-Dlchloropropatie

o

Location

COMPOUND~ -S

^

||

Dilution Factor

?

>

COu

?

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si

j

i>*

A

o3 1 1 • ' ' • • ' • ' - • " " i———>-" g1 §m

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o

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ft

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o

2.4 Dlchlofophenol

•o

Ws(2-Chloroelhoxy)melhsne

g

C321

1

0

2, . Oimelhytphenol

o

N21

O

uTt1

.

o

Nitrobenzene

^

o

Mexachlo-oelhane

e

N-Nilroso-cN n propylamlne

o

.kS2.i3(

O

bls(2-Chlorolsopropyl)ether

e

fv>

a

fi.

o

t ,2-Dlchlorobenzcne

0

a3•2.£s.

o

• 1 ,4-Dlchlorobenzene

»u6n

1aNae

Mie

5•J5

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3is.

§o

Location

COMPOUND

T.%c^tr^A 2* $-\

i

1 --,

Dilution Factor

&

cn=•aefO*»XJli\X?

1

I 3« •£• m g

•C co s^^ • •

TJ

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|

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1*2- JO&1R301901

o

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o

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mTIoacroamo

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g

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g

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0

•nST

a

e

A•Chlorophenyl phenylelher

e

nlelhylphthalale

0

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o

O

1Jk•Nllrophenol

S

?Ii2.

^

^

o

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g

u•Nltroanina

o

N.0 Dbillrotoluena

o

>cenaphlhytene

o

n

1S£7

M

O

<•

O

ro•ChloronaphthalGne

ro4,5-Trlchlorophenol

e

isa4.6-Trlchloroplieno)

o

_exachbrocyclopentadtena

o

NMelhytnaptillmlene

^H

o

AofJnI

o

^exachlorobutadlene

3.2

Location

COMPOUND^n\ 31 •

" * *•

.;.

Dilution Factor j

e*••

/

COH^e

P

^S^

f•

ICOC

s_ ain' ... —

O CO» sw •

?.

COa>iUs

3 S. 3£ 21 "TJS °CO 2

>CO

rn

co-— m

rn3Oaen

i o£. rnS 2* Bi ien CO

o

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o

0)benz(a.li)»ntliracene

e

|

^

Su|

|

e

3

|

|

e

Benzo(k)fluoranlhene

rS

e

Benzo(b)lluofai.lhene

e

3

^

r

o

STJ

3r•F»*

o

1I

o

Benzo(a)anthracene ~~

1

o

3.3 CHchlorobenzldine

^

0

a1i?r7

o

o

FHioranthene

e

S3ar1rr9

O

Anthracene

o

Phenanthrene

g

•Pentachlorophotiol

e

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o

1Iir

o

Z

5M

T

|

§52

Location

COMPOUND&,£>5- **"*

S>

• •

- ._ ~. .

;

Dilution Factor

!&

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d

COOJ

o.S"

P

r.•iCS3^3

f

-- w« C«_

o co•• ~?

CO

«a

*\

525 Km 33 §

co

03

flaa

I?

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>3 I _ i ' i i i i ' i i iii i i i i i i i i i i i i i t i i •-_ *_ • v% ^ op. ^ M »

3

s

comm

mS3OO3

«s& a-5J aJ

§00)

o

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ii\

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OUl

>0n0

oCT

O

$X01^aa

oen

O

301-Chlordane

oUl

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0o

519-

1

oen

SZ-$n5"

ee

*

&—t

oo

2

S,3

£sTa

e0

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o

oe

m

|

oo

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jk

m

oe

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oZ

m£t

<M=i

og

3gi

f.

o3

ir

eS

XaO7n(T

eUl

0013atDUG

(LIndane)

eUl

a•2o

oS

cr£fao

oen

£Ea0

O

5

ft

Location

.OMPOUND^{> -J» Vr4

• 3f%

\

Dilution Factor i

S)

-

I

COM

T:9~

?P>"s3^>C

i;

3^

O CO• s2 9

% Z«

&COatT5"(Q

Us

H

TJ

m~\ co

-I

1 °•?• m m3

TJSCO

co

TJ

OCO

__ copa. so S7o" a

Appendix C

Form Is

As Reported by the Laboratoryfor all Target Compounds

flR301905

Ub MAM : S - OSfcD I Sanple Nuaber ICase No : CASE 10591 I CY 755 I

ORGANICS ANflLYSIS DATA SHEET *—————————+ &-f(Paqe 2)

Sft«ivolatile Compounds'I .

Concentration: Hojo rtediu* (Circle One ) GPC Cleanup j£Yes _NoDate Extracted: VlPl4-R8 Sepantory Funnel Extraction _ YesDate Analyzed: -10/26/8819:19 Continuous) Liquid-Liquid Extraction _ YesCone/Oil Factor:-"" 1.50Percent Hoisture ( Decanted ) N.A.

C.A.S. uq/L or([ig/Kq C.A.S.Number (Circle One! Number

uq/L or|(Circle

1(18-95-2 Phenol 560. U 83-32-9 Acenaphthene 560. U111-44-4 bisC-2-ChloroethynEther 560. U 51-28-5 2,4-Oinitrophenol 2800. U95.57-8 2-Chlorophenol 560. U 100-02-7 4-Nitrophenol 2800. U541-73-1 1,3-Dichlorobenzene 560. U 132-64-9 Dibenzofuran 560. U106-46-7 1,4-Dichlorobenzene 560. U 121-14-2 2,4-Dinitrotoluene 560. U100-51-6 Benzyl Alcohol 560. U 6116-20-2 2,6-Oinitrotoluene 560. U95-50-1 1,2-Dichlorobenrene 560. U 84-66-2 Diethylphthalate 560. U

""95-48-7 2-«ethylphenol 560. U 7005-72-3 4-Chlorophenyl-phenylether 560. U39638-32-9 bis(2-chlo.otsopropyl)Ether 560. U 86-73-7 Fluorene 560. U106-44-5 4-ttethylphenol ' 560. U 100-01-6 4-Nitroaniline 560. " U621-64-7 N-Nitroso-Qi-n-Propylaaine 560. U 534-52-1 4,6-Dinitro-2-t1ethylphenol 2800. U67-72-1 .Hexachl.oroethane 560. U 86-30-6 N-Nitrososdiphenylanine (1) 560. U98-95-3 Nitrobenzene 560. U 101-55-3 4-BroMphenyl-phenylether 560. U78-59-1 Isophorone~~ 560. U 118-74-1 Hexachlorobenzene 560. U88-75-5 2-NitropKenol 560. U ' 87-86-5 Pentachlorophenol 2800. U105-67-9 2,4-Oiae-.i$rrphenol 560. U 85-01-8 Phenanthrene 560. U65-85-0 Benzoic-ftctd" 2800. U 120-12-7 Anthracene -560.-U

-Ul-91-1 bis(-2-Ch.oroethoxy)t1ethane 560. U 84-74-2 Di-n-8utylphthalate 560. U120-83-2 2,4-OichUecphenol 560. U 206-44-0 Fluoranthene 560. U120-82-1 1,2,4-Tr.ichlorobenzene 560. U 129-00-0 Pyrene 560. U91-20-3 Naphthalene ' 560. U 85-68-7 Butylbenzylphthalate 560. .U106-47-8 4-ChloroanjJ,ine 560. U . 91-94-1 3,3'-Dichlorobenzidine 1100. U87-68-3 Hexachlorobutadiene 560. U -56-55-3 Benzo(a)Anthracene 560. U59-50-7 4-Chloro-3-ttethylphenol 560. U 117-81-7 bis(2-Ethylhexyl)Phthalate 470. ' J91-57-6 2-Methylnaphthalene 560. U . 218-01-9 Chrysene 560. ' U^77.47-4 Hexachlorocyclopentadiene 560. U 117-84-0 Di-n-Octyl Phthalate .__/ty-W8. J"88-06-2 2,4,6-Trichlorophenol 560. U 205-99-2 Benzo(b)Fluoranthene 560. U95-95-4 2,4,5-Trichlorophenol 2800. U 207-08-9 Benzo(k)Fluoranthene 560. U91-58-7 2-Chloronaphthalene 560. U 50-32-8 Benzo(a)Pyrene 560. U88-74-4 2-Nitroaniline 2800. U 193-39-5 Indeno(l,2,3-cd)Pyrene 560. U131-11-3 Dimethyl Phthalate 560. U 53-70-3 Dibenzo(a,h)Anthracene 560. U208-96-8 Acenaphthylene 560. U 191-24-2 Benzo(g,h,i)Perylene 560. U.99-09-2 3-Nitroaniline 2800. U

(l)-Cannot be separated fro» diphenylamine

Fora 1 . ' . ' • ' 7/85

AR30I906

Laboratory Nan: S-Cubid Saiple MuiberCase Mo.: 10591 CY 755

Concentration:Date Extracted/PreparDate Analyzed:Conc/Dil Factor:

ORSANICS ANALYSIS DATA(Page 3)

Pfsticide/PCBs

LOH ._ 6?C Clianup __Yes JClWd: 10-13-38 Stparatory Funnel Extraction .Yfs

11-01-as . Continuous Liquid-Liquid Extraction _Jfts1.00

CAB I \ __ ug/1Nuiber \ (i319-34-6 ALPHA-3HC319-85-7 , BETA-BHC319-36-8 DELTA-3HC58-89-9 SAMKA-3HC (LINDANEJ76-44-3 HEPTACHLOR309-00-2 flLDRIH1024-57-3 HEPTACHLOR EPOXIDE959-98-8 ENDOSULFAN 1fcO-57-1 DIELORIH72-55-9 4,4'-ODE72-20-3 ENDRIH33213-65-9 ENDOSULFAN II72-54-8 4,4'-DDD7421-93-4 ENDRIH ALDEHYDE1031-07-B EHDOSULFAM SULFftTE50-29-3 4,4'-DDT72-43-5 HETHOIYCHLOR53494-70-5 ENDRIH KETQNE57-74-9 CHLORDAHE8001-35-2 TDIAPHENE12674-11-2 AROCLOR-101&11104-28-2 AROCLOfi-1221 - ' ' --:11141-16-5 ARDCLOR-123253469-21-9 ARQCLOR-1242 ~. '"' .12672-29-6 AROCLDR-124811097-69-1 AROCLQR-1254 .' >11096-82-5 AROCLOR-12iO - - - \\Voluie of Hater extracted Ul): K.AiHeight of suple extracted (g): 30.0Volute of total extract dl): 10.00Voluie of extract injected (ul): . l.OOi

Fun I 7/85 REV. :

« CONFIRMED BY BC DUAL COLUBH COHF1RHATION fl R 3-0 190?

: Sample Nuiber:CRSAHICS ANALYSIS DATA SHEET CY756 :

(Page 1) :................ :

Laboratory Name: S-CUBE5 Case Ho: 10591Lab Sample IS Nc: CY756 (Voa! fiK\&(fi6& gc Report No: N.SSaepls Matrix: SOIL x Contract Ho: 63-01-726!Data Release Authorized By: _JAL___ Datt Saipie Received: 10-12-88 . . ,.

VOLATILE COMPOUNDSConcentration:(Loy (tedium (Circle One)Date Estracted/Tfepartd: 10-14-88

.- ... — — Date Analyzed: 10-14-38 .'....Conc/DU Factor: 1.0 pH: 5.8Percent Koisture (Hot Decanted): 10.3

CAS . . ug/1 orCg/kg) CASNumber .Circle wnrr Nuaber74-87-3 CHLGROMETHAHE 11 U 78-37-5 1,2-OICHLOROPBOPAHE74-33-9 BROMDMETKANE 11 U 10061-02-6 TRAMS-1,3-QICHLQRQPRDPENE75-01-4 VIHYL CHLORIDE 11 U 79-01-6 TRiCHLDRQETHEHE75-00-3 CHLOROETHAHE 11 U 124-48-1 DIBRDHOCHLORDMETHANE75-09-2 HETHYLENE CHLORIDE 6 U 79-00-5 1,1,2-TRICHLORDETHANE67-64-1 ACETONE 11 U. 71-43-2 BENZENE75-15-0 CARBON BISULFIDE 6 U 10061-01-5 CIS-1,3-DICHLORCPRQPENE75-35-4 1,1-aiCHLDRDETHENE 6 U 110-75-3 2-CHLOROETHYLVIHYLETHER 11 U75-34-3 - 1,1-DICHLOROETHANE 6 U 75-25-2 BROHOFORN 6 U156-60-5 TRA«S-1,2-D1CHLQROETHENE 6 U 591-78-6 2-HEXANONE 11 U67-66-3 CHLOROFORM ' 6 U 108-10-1 4-METHYL-2-PENTANONE 11 U107-06-2 1,2-DICHLOROETHANE 6 U 127-13-4 TETRACHLOROETHENE 6 U78-93-3 2-BUTANQNE II U 79-34-5 1,1,2,2-TETRACHLORQETHAHE 6 U71-55-6 1,1,1-TRICHLDROETHANE 6U 108-88-3 TOLUENE 6U56*23-5 CARBON TETRACHLQRIBE 6 U 108-90-7 CHLGROBEHZEHE 6 U103-05-4 VINYL ACETATE 11 U 100-41-4 ETHYL3EN2ENE 6 U75-27-4 BRGHODICKLQROMETHANE 6 U 100-42-5 STYRENE . 6 U

' TOTAL IYLENES ' ' - - 6 UData Reporting Oualifiers •—— —. -

For reporting results to EPft, the following results qualifier are used. Additional flags or footnotesexplaning results are encouraged.However,the definition of each flag lust be explicit. \ •

Value: If the result is a value greater than or equal'to the C This flag applies to pesticide parameters nheredetection limit-report the value. the identification has been confiraed by EC/MS.Single

I) Indicates coipound was analyzed for but not detected.Report component pesticides > or * 10 ng/ul in the finalthe niniaua detection lieit for the saeple with the U (eg.lOU) extract should be confiraed by 6C/HS.based on necessary concentration/dilution action.(this isnot necessarily the instrument detection lititJThe footnotes B This flag is used when analyte is found in the blankshould read:U-Coapound Mas analyzed for but not detected.The as well as saiple. It indicates possible/probablenuaber is the »ini»u» attainable detection liait for the sacple. blank contaiination and warns the data user to take

3 Indicates an estiiated value:This flag is used either when appropriate action. 'estimating a concentration for tentatively identified compoundswhere a 1:1 response is assuaed or when the mass spectral data S Matrix spiked compound. .indicated the presence of a compound that meets the identification • fl D O n icriteria but the result is less than the specified detection limit H 11 O U jbut greater than zero (eg 10.) .If limit of detection is 10 ug/L anda concentration of 3ug/L is calculated,report as 3J.

Lab Nane : S - CUBED I Saxple Nuiber ICase No : CASE 10591 I CY 756 . ' I

ORGANICS ANALYSIS DATA SHEET * ————————— +(Page 2)

Seaivolatile Compounds

Concentration: 0-°ji) Rediun (Circle One ) G?C Cleanup £Yes _ NoDate Extracted: liPl4-88 Separatory Funnel Extraction _ YeDate Analyzed: 11/03/88 0:06 Continuous Liquid-Liquid ExtractionConc/Oil Factor: 3.00Percent Moisture ( Decanted ) N.A.

C.A.S. ug/L or<jjq/K£) C.A.S. uq/L or(uq/KqNunber (Circle One) Nuaber UCircleOne

Yes —— _

108-95-2 Phenol ' 1100. U • 83-32-9 Acenaphthene ' 1100. U111-44-4 bis(-2-Chloroethyl)Ether 1100. U 51-28-5 2,4-Oinitrophenol 5600. U95-57-8 2-DiIorophenol 1100. U 100-02-7 4-Hitrophenol 5600. U541-73-1 1,3-Dichlorobenzene 1100. U 132-64-9 Dibenzofuran 1100. U106-46-7 1,4-Dichlorobenzene 1100. U 121-14-2 2,4-Dinitrotoluene 1100. U100-51-6 Benzyl Alcohol 1100. U 606-20-2 2,6-Oinitrotoluene 1100. U95-50-1 1,2-Dichlorobenzene 1100. U 84-66-2 Diethylphthalate 1100. . U

•• • 95-48-7 2-ttethylphenol 1100. U 7005-72-3 4-Chlorophenyl-phenylether 1100. U39638-32-9 bis(2-chloroisopropyl)Ether 1100. U 86-73-7 Fluorene 1100. U106-44-5 4-Hethylphenol 1100. U 100-01-6 4-Nitroaniline 1100. U

.. 621-64-7 N-Nitroso-Di-n-Propyla»ine 1100. U 534-52-1 4,6-Dinitro-2-Methylphenol 5600. UA. 67-72-1 Hexachloroethane 1100. U 86-30-6 N-Nitrososdiphenylanine (1) 1100. UI • 98-95-3 Nitrobenzene 1100. U 101-55-3 4-Browphenyl-phenyIether 1100. U

•'I 78-59-1 Isophorone 1100. U 118-74-1 Hexachlorobenzene 1100. U• -. 88-75-5 2-Nitrophenol 1100. U 87-86-5 Pentachlorophenol 5600. U• 105-67-9 2,4-Diaethylphenol 1100. U 85-01-8 Phenanthrene 1100. U

.-:. * 65-85-0 Benzoic Acid 5600. U 120-12-7 Anthracene 1100. U'•; 111-91-1 bis(-2-Chloroethoxy)(1ethane 1100. U 84-74-2 Di-n-Butylphthalate 1100.' Ui 120-83-2 2,4-Dichlorophenol * 1100. U 206-44-0 Fluoranthene 1100. U0. - 120-82-1 1,2,4-Trichlorobenzene 1100. U 129-00-0 Pyrene 1100. U_'". . . 91-20-3 Naphthalene ' ' - 1100. U 85-68-7 Butylbenzylphthalate ' 1100. "U '.:. . 106-47-8 4-Chloroaniline 1100. U 91-94-1 3,3'-Dichlorobenzidine 2200. U ~

87-68-3 Hexachlorofautadiene" 1100. U 56-55-3 Benzo(a)Anthracene 1100.~U ;59-50-7 4-Diloro-3-HethyIphenol 1100. U 117-81-7 bi$C2-Ethylhexyl)Phthalate 11000. . ...91-57-6 2-Hethylnaphthalene 1100. U 218-01-9 Chrysene 1100. U77-47-4 Hexachlorocyclopentadiene 1100. U 117-84-0 Di-n-Octyl Phthalate \\06U -MO. J ffi88-06-2 2,4,6-Trichlorophenol 1100. U 205-99-2 Benzo(b)Fluoranthene 1100. U95.95.4 2,4,5-Trichlorophenol 5600. U 207-08-9 Benzo(k)Fluoranthene 1100. U91-58-7 2-Chloronaphthalene 1100. U 50-32-8 Benzo(a)Pyrene 1100. U88-74-4 2-Nitroaniline 5600. U 193-39-5 Indeno(l,2,3-cd)Pyrene 1100. U131-11-3 Diaethyl Phthalate 1100. U 53-70-3 Dibenzo(a,h)Anthracene 1100. U208-96-8 Acenaphthylene 1100. U 191-24-2 Benzo(g,h,i)Perylene 1100. U99-09-2 3-Nitroaniline 560:0. U -

(l)-Cannot be separated fro* diphenylanine

Fortl ' AR30l9tf§

Laboratory Naae: S-Cubed ~ Suple HuiberCase lta.« 10591 CY 756 £irtn a £

<J

ORBANICS ANALYSIS DATA(Page 3)j

PesticidB/PCBs

" ' ''' Concentrations LDH " ~—— "" b»C Cleanup __Yes _£HO " " -" ~ -Date Extracted/Prepared: 10-13-38 jseparatory Funnel Extraction _.YesDate Analyzed: 11-01-38 Continuous Liquid-Liquid Extraction __JfesConc/Bil Factor: 1.00 \

CAS I • ug/1 orn!g/Kg/NuBber \ ICirbUJne)319-84-6 ALPHA-BHC , 8.9 u319-S5-7 BETA-8HC ' 8.9 u319-36-8 DELTA-3HC 8.9 u58-39-9 6AHMA-SHC (LINDAHE) . 8.9 u76-44-3 HEPTACHLOR 8.9 u309-00-2 ALDRIN 8.9 a1024-57-3 HEPTACHLOR EPOXIDE 8.9 u959-98-8 ENDOSULFAN I 8.9 u60-57-1 DIELDRIN " 18 u72-55-9 4,4'-DDE 18 u72-20-3 ENDR1N . 18 u33213-65-9 ENDOSULFAH II 18 u72-54-8 4,4'-DDD 18 u7421-93-4 ENDRIH ALDEHYDE • 18 u1031-07-8 ENDOSULFAH SULFATE 18 u50-29-3 4,4'-DDT 18 u72-43-5 HETHOIYCHLOR 89 u53494-70-5 ENDRIN KETONE 18 u57-74-9 CHLORDANE 89 u8001-35-2" TOIAPHENE 180 u

• --•- - 12674-11-2 AROCLOR-1016 - — • - • . - - - - • ' 89 u ------ -••--- 11104-28-2 AROCLOR-1221 • • . . • - - : . . . - 89 u -_"_..:;_:

11141-16-5 AROCLDR-1232 -•----..: • • • • • 89 u -53469-21-9 AROCLOR-1242 " .••'• B9 u12672-29-6 AROCLOR-1248 ' \ 89 u ': ' .11097-69-1 AROCLOR-1254-—-— \. , 180 u --•11096-32-5 AROCLOR-1260 i 180 u

Volume of Mater extracted (ml):Height of sample extracted (g)tVolume of total extract (ml):Volume of extract injected (ul)i

H.A.30.010.001.00

I

Form I 7/85 REV.

CONFIRMED BY 6C DUAL COLUMN CONFIRMATION

AR30I9IO

s Sample Number:GRSHICS ANALYSIS DATA SHEET CY757 s

Libaratcry Name: s-C'JB£2 , Case Ho: 10591Lab '.Sasple ID He: CY757 (Voa) \MttC*&*) 3C Report No: N.RSaafhc Matrix: HATER >' Contract No: 63-01-7261Data Release Authorized BY; m ,, . Date Sample Received: 10-12-38 _ _ _ _ _ _ _ ... _ _ _ _ _

VQLAm=v COMPOUNDSConcentration )/ Medium (Circle One)Data Extracted/rrepared: 10-H-38Dale Analyzed: 10-H-38

\ Cone/Oil Factor: 2.5 pH: H.RPercent Moisture (Not Decanted): N.R

^ __ ^^^

CAS fug/Hir ug/kg CAS nig/l)br ug/kgHuaber TClfcle One) Number retrcle One)74-S7-3 CHLGROMETHfiNE 25 U 73-B7-5 1,2-DICHLOROPROPANE 13 U74-33-9 BRGHOMETHAHE 25 U 10061-02-6 TRANS-1 ,3-DICHLOROPROPEHE 13 U75-01-4 VINYL CHLORIDE 25 U 79-01-6 TRICHLGROETHEHE 13 U75-00-3 CHLORGE7HANE 25 U 124-48-1 JIBROMOCHLOaOMETKANE 13 U75-09-2 ME7HYLENE CHLORIDE 19 B ' 79-00-5 1,1,2-TRICHLORDETHAHE 13 U67-64-1 ACETONE 390 71-43-2 BENZENE 13 U75-15-0 CARBON DISULFIDE 13 U 10061-01-5 CIS-1, 3-DICHLOMP80FENE 13 U

: • 75-35-4 ' 1,1-DICHLDROETKENE 13 U 110-75-3 2-CHLOROETHYLV1NYLETHER 25 U. 75-34-3 1,1-DICHLOROETHANE 13 U- 75-25-2 BRQMGFORM ..... 13 U

156-60-5 TRAHS-1,2-DICHLDRDETHEHE 13 U 591-78-6 2-HEIAHDKE 25 U* 67-66-3 CHLOROFORM 13 U 108-10-1 4-METHYL-2-PENTANONE ' 25 U• 107-06-2 1,2-DICHLOROETHANE 13 U 127-18-4 TETRfiCHLOROETHENE 13 U

78-93-3 2-BUTANGNE 25 U 79-34-5 1,1,2,2-TETRACHLOROETHANE 13 U.; 71-55-6 1,1,1-TRICHLOROETHAHE 13 U 108-38-3 TOLUENE 13 U: 56-23-5 CAPJON TETRACHLORIDE 13 U 108-90-7 CHLORQBENZENE . 13 U.! 10B-05-4 VINYL ACETATE 25 U 100-41-4 ETHYLBENZENE 13 U

75-27-4 BRQMODICHLORGMETHANE 13 U 100-42-5 STYRENE 13 UTOTAL XYLENES • •-- ' - -13 |f~

Data Reporting flualifiers ' • ' - '—•• For reporting results to ERA, the following results qualifier are used. Additional flags or footnotes' .

'.; explaning results are encouraged. HoMever, the definition of each flag must be explicit. ...'':t \• Value: If the result is a value greater than or equal to the C This flag applies to pesticide parameters where 'j detection limit, report the value. the identification has been confirmed by EC/MS. Single; U Indicates compound Mas analyzed for but not detected. Report component pesticides > or * 10 ng/ul in the final

the miniaum detection limit for the sample with the U (eg.JOU) extract should be confiraed by EC/MS. .. based on necessary concentration/dilution action, (this is I

not necessarily the instrument detection limit. )The footnotes B This flag is used when analyte is found in the blank\ should readiU-Cospound Mas analyzed for but not detected. The as well as sample. It indicates possible/probable.'[ number is the minimum attainable detection limit for the sample. blank contaeination and warns the data nser to take

J Indicates an estimated value: This flag is used either when appropriate action. !, estimating a concentration for tentatively identified compounds: Mhere a 1:1 response is assuaed or when the mass spectral data S Matrix spiked compound;

indicated the presence of a compound that teets the identification ' 'criteria but the result is less than the specified detection limit n n o n I n I Ibut greater than zero (eg 10J) .If limit of detection is 10 ug/L and A K J U I 3 I Ia concentration of 3ug/L is calculated, report as 33. • •

e .Lab Name : S - CUBED ' Sample Nuaber ICase No : CASE 10591 I CY 757 I

IKGANICS ANALYSIS DATA SHEET *—————————*(Paqe 2)

Seii volatile Compounds

Concentration: ofc Mediu« (Circle One ) GPC Cleanup _ Yes j/NoOats Extracted: 15 17-88 Separatory Funnel Extraction _ Yes .Date Analyzed: 10/28/88 12:34 Continuous Liquid-Liquid Extraction j£ YesCone/Oil Factor: l.flflPercent Moisture ( Decanted ) N.A.

C.A.S. <jjq/£)or ug/Kq C.A.S.Nuaber (Circle One) Number " (Circle One)

108-9.-2 Phenol 10. U • 83-32-9 Acenaphthene 10. U111-44-4 bis(-2-Chloroethyl)Ether 10. U 51-28-5 2,4-Oinitrophenol 50. U95-57-8 2-Oilorophenol 10. U 100-02-7 4-Nitrophenol 50. U541-73-1 1,3-Dichlorobenzene ' 10. U 132-64-9 Dibenzofuran 10. U106-46-7 1,4-Dichlorobenzene 10. U 121-14-2 2,4-Dinitrotoluene 10. U100-51-6 Benzyl Alcohol 10. U 606-20-2 2,6-Dinitrotoluene 10. U95-50-1 1,2-Dichlorobenzene 10. U -•" 84-66-2 Diethylphthalate 10. U95-48-7 2-Methylphenol 10. U 7005-72-3 4-Chlorophenyl-phenylether 10. U

39638-32-9 bis(2-chloroisopropyl)Ether 10. U 86-73-7 Fluorene 10. U106-44-5 4-Methylphenol 10. U 100-01-6 4-Nitroaniline 10. U621-64-7 N-Nitroso-Di-n-propylanine 10. U 534-52-1 4,6-Dinitro-2-«thylphenol 50. U67-72-1 Hexachloroethane 10. U 86-30-6 H-Nitrososdiphenylaaine (1) 10. U98-95-3 Nitrobenzene 10. U 101-55-3 4-Bronophenyl-phenylether 10. U.78-59-1 Isophorone 10. U 118-74-1 Hexachlorobenzene 10. U88-75-5 2-Nitrophenol 10. U 87-86-5 Pentachlorophenol 50. U105-67-9 2,4-Dimethylphenol 10. U - . . 85-01-8 Phenanthrene 10. U

* 65-85-0 Benzoic Acid 50. U 120-12-7 Anthracene 10. U111-91-1 bis(-2-ChIoroethoxy).tethane 10. U 84-74-2 Di-n-Butylphthalate -10. U120-83-2 2,4-Dichlorophenol 10. U 206-44-0 Fluoranthene 10. U120-82-1 1,2,4-Trichlorobenzene 10. U 129-00-0 Pyrene .. . 10. U91-20-3 Naphthalene 10. U 85-68-7 Butylbenzylphthalate ' "10." U'106-47-8 4-Chloroaniline 10. U 91-94-1 3,3'-Dichlorobenzidine . 20. U87-68-3 Hexachlorobutadiene 10. U 56-55-3 Benzo(a)Anthracene 10. U59-50-7 4-Diloro-3-aethylphenol 10. U 117-81-7 bis(2-Ethylhexyl)Phthalate 10. U91-57-6 2-Hethylnaphthalene H.-_U_ _ 218-01-9 Chrysene 10. U77-47-4 Hexachlorocyclopentadiene 10." U " " 117-84-0 Di-n-Octyl Phthalate . ' 10. U88-06-2 2,4,6-Trichlorophenol 10. U 205-99-2 Benzo(b)Fluoranthene 10. U95-95-4 2,4,5-Trichlorophenol 50. U 207-08-9 Benzo(k)Fluoranthene 10. U91-58-7 2-Chloronaphthalene 10. U ' 50-32-8 Benzo(a)Pyrene 10. U88-74-4 2-Nitroaniline 50. U ' 193-39-5 Indeno(lf2,3-cd)Pyrene 10. U131-11-3 DiMthyl Phthalate 10. U 53-70-3 DibenzoCa,h)Anthracene 10. U208-96-8 Acenaphthylene * 10. U 191-24-2 6enzo(g,h,i)Perylene 10. U99-09-2 3-Nitroaniline 50. U -

(l)-Cannot be separated from diphenylaaine

For. 1 7/85

Laboratory Hue: S-Cubed - Saaple NumberCase So.: 10591 CY 757

OR6ANICS ANALYSIS DATA(Page 3)

Pesticide/PCBs

Concintration: • LOH - •-•• -•-• GPC Cltanup_Yes >3Datt Extracted/Prepared: 10-13-33 Separatory Funnel itraction _Yi$Date Analyzed: 11-01-38 Continuous Liquid-Liquid ExtractionCone/Oil Factor: HJSf 2-0 fcr.

CAS t /ug/1 or ug/KgNumber \Ocirclt One)319-34-6 ALPHA-BHC 0.10 u319-35-7 BETA-3HC ' 0.10 u319-36-3 DELTA-3HC - 0.10 u53-39-9 6AHHA-3HC (LINDANE) 0.10 u76-44-3 HEPTACHLOR 0.10 u309-00-2 ALDRIH 0.10 u1024-57-3 HEPTACHLOR EPOXJDE 0.10 u

_.——._—— ?5_u93-8 ENDOSULFAN I 0.10 u60-57-1 DIELDRIN 0.20 u72-55-9 4,4'-DDE 0.20 u72-20-3 ENDRIN 0.20 u

. 33213-65-9 ENDOSULFAH II 0.20 u72-54-3 4,4'-DDD 0.20 u7421-93-4 ENDRIH ALDEHYDE 0.20 u1031-07-8 ENDOSULFAH SULFATE 0.20 u50-29-3 4,4'-DDT 0.20 u72-43-5 METHOXYCHLOR 1.0 u53494-70-5 ENDRIN KETONE 0.20 u57-74-9 CHLORDANE 1.0 u8001-35-2 TOXAPHEHE 2.0 u12674-11-2 AROCLDfi-1016 - - . - 1.0 u11104-28-2 AROCLOR-1221 . - .. 1.0 u11141-16-5 AROCLOR-1232 - 1.0 u53469-21-9 AROCLOR-1242 1.0 u12672-29-6 AROCLOR-1248 - . 1.0 u11097-69-1 AROCLDR-I254 . 2.0 u11096-82-5 AROCLOR-1260 2.0 u

iVolume of Mater extracted (ml): 500Height of sample extracted (g): N.A.Volume of total extract (ml): 10.00Volume of extract injected (ul): 1.00

Form I 7/85 REV.

« CONFIRMED BY GC DUAL COLUMN CONFIRMATION AR3019-13

: Sample Number:ORSAHIC3 AHALYSIS DATA SHEET CY758 : . £-3

(Page 1) :................ :

Laboratory ifeae: S-CUBE3 \ Cas. No:Lab Supis la Ho: CY753 <Voa) 3C Report No: H.RSatpl: Matrix: SOIL |\ Contract No: 63-01-7251Data Ssleass Authorized By: |w__ Date Sample Received: 1.-12-3S-JF———

VOLATILE COMPOUNDSConcentration:i(Low/ Medium (Circle One)Date Extracted/fT-ipared: 10-14-38Date Analyzed: \ 10-14-88 - — --Canc/Dil Factor: 0.99 pH: 4.9Percent Moisture (Not Decanted): 9.3

CAS ug/l or(ug/ko) CAS ' ug/1 crfa/kg",Nuaber (Circle .*/ Number (Circle Onei74-87-3 CHLOROMETHANE 11 U 78-S7-5 1,2-DICHLOROPP.OPANE 5 U74-83-9 3ROMMETHANE ' 11 U 10061-02-5 TRANS-1,3-DICHLDROPROFEflE 5 U75-01-4 VINYL CHLORIDE II U 79-01-6 TRICHLQROETHENE 5 U75-00-3 CHLOROETHANE 11 U 124-4B-1 DIBROKOCHLOROMETHANE 5 U75-09-2 METHYLENE CHLORIDE 5 U 79-00-5 1,1,2-TRICHLOROETHANE 5 U67-64-1 ACETONE 11 U 71-43-2 BENZENE 5 U75-15-0 CARBON DISULFIDE 5 U 10061-01-5 CIS-1,3-SICHLOROPROPENE 5 U75-35-4 1,1-DICHLQROETHENE 5 U 110-75-3 2-CHLOROETHYLV1NYLETHER II U75-34-3 1,1-DICHLQROETHANE 5U "75-25-2 BROMOFORM 5U156-60-5 TRANS-1,2-DICHLORQETHENE 5 U 591-78-6 2-HEIANONE 11 U67-66-3 CHLOROFORM 5 U 108-10-1 4-METHYL-2-PENTANONE " . 11 U107-06-2 1,2-DICHLGROETHANE 5U 127-18-4 TETRACHLORDETHENE 5U78-93-3 2-3UTAHGNE 11 U 79-34-5 1,1,2,2-TETRACHLQROETHANE 5U71-55-D 1,1,1-TRICHLOROETHANE 5U 108-88-3 TOLUENE 5U54-23-5 CARBON TETRACHLORIDE 5 U 108-90-7 CH.QROBEHZENE 5 U10B-05-4 VINYL ACETATE 11 U 100-41-4 ETHYLBENZENE 5 U75-27-4 BROMODICHLOROMETHANE 5 U 100-42-5 STYRENE . 5 U

- -' ' ' TOTAL XYLENE5 ".- "- 5 UData Reporting Qualifiers ' ...- ...

For reporting results to EPA, the following results qualifier are used. Additional flags or 'footnotes :explaning results are encouraged.However,the definition of each flag must be explicit.

Value: If the result is a value greater than or equal to the" " " C This flag applies to pesticide parameters wheredetection limit,report the value. the identification has been\confirmed by EC/MS.Single

U Indicates compound Mas analyzed for but not detected.Report component pesticides > or * '10 ng/ul in the finalthe minimum detection limit for the sample with the U (eg.lOU) extract should be confireed by EC/US.based on necessary concentration/dilution action.(this is \not necessarily the instrument detection limit.)The footnotes B This flag is used when analyte is found in the blankshould read:U-Compound mas analyzed for but not detected.The as Nell as saaple. It indicates possible/probablenumber is the minimum attainable detection limit for the sample. blank contamination and warns the data user to take

J Indicates an estimated value:This flag is used either when appropriate action.estimating a concentration for tentatively identified compoundswhere a 1:1 response is assumed or when the mass spectral data S Matrix spiked compound;indicated' the presence of a compound that meets the identificationcriteria but the result is less than the specified detection limit A R 3 0 ! 9 j Ubut greater than zero (eg 10J) .If limit of detection is 10 ug/L and - . . . . . . .a concentration of 3ug/L is calculated,report as 3J.

Lah N«ae : S - DSHDCase Nn : CASE 10591

GRGAN1CS ANALYSIS DATA SHEET(Paqe 2)

Semivolatile Compounds

Concentration: ou) Mediua (Circle One ) 6?C Cleanup j/Yes __ NoDate Extracted: 10-14-88 Separatory Funnel Extraction _YesDate Analyzed: 10/25/8816:12 . - — .._. Continuous Liquid-Liquid Extraction _ YesCone/Oil Factor:' 1.50Percent Moisture ( Decanted ) N.A.

C.A.S. ug/L or q/K C.A.S.Nuaber (Circle One) Number

lflB-95-2 Phenol 550. U - 83-32-9 Acenaphthene 550. U111-44-4 bis(-2-Chloroethyl)Ether 550:. U 51-28-5- 2,4-Dinitrophenol 2700. U95-57-8 2-Oilorophenol 550. U 100-02-7 4-Nitrophenol 2700. U541-73-1 1,3-Dichlorobenzene • 551. U 132-64-9 Dibenzofuran 550. U106-46-7 1,4-Dichlorobenzene 550. U 121-14-2 2,4-Dinitrotoluene 550. U100-51-6 Benzyl Alcohol 550. U 606-20-2 2,6-Dinitrotoluene 550. U95-50-1 1,2-Dichlorobenzene 550. U 84-66-2 Diethylphthalate 550. U95-48-7 2-tlethylphenol 550. U 7005-72-3 4-Chlorophenyl-phenylether 550. U

39638-32-9 bis(2-chloroisopropyl)Ether 550_ U 86-73-7 Fluorene 550. U106-44-5 4-ftethylphenoI 550. U 100-01-6 4-Nit roan i line 550. U

_621-64-7 N-Nitroso-Oi-n-Propylaaine 550. U 534-52-1 4,6-Dinitro-2-t1ethylphenoI 2700. U67-72-1 Hexachloroethane 550. U 86-30-6 N-Nitrososdiphenylaaine (1) 550. -U98-95-3 Nitrobenzene 550. U 101-55-3 4-Browjphenyl-phenylether 550. U78-59-1 Isophorone 550. U" 118-74-1 Hexachlorobenzene 550. U88-75-5 2-N5trophenol . 550. U 87-86-5 Pentachlorophenol 2700. U105-67-9 2,4-Dimethylphenol .. .. 550. U 85-01-8 Phenanthrene 550. U. 65-85-0 Benzoic Acid 2700. U 120-12-7 Anthracene 550. U*111-91-1 bisC-2-D.loroethoxy..lethane 550. U 84-74-2 Di-n-Butylphthalate 550. U120-83-2 2,4-Dichlorophenol 550. U 206-44-0 Fluoranthene • 550.' U120-82-1 1,2,4-Trichlorobenzene .550. U 129-00-0 Pyrene 550. U91-20-3 Naphthalene ' 550. U 85-68-7 Butylbehzylphthalate SSO.'-.'U106-47-8 4-Ch lo roan i line 550. U 91-94-1 3,3'-Dichlorobenzidine 1100. 'U '87-68-3 Hexachlorobutadiene 550. U 56-55-3 Benzo(a)Anthracene 550." 0 .59-50-7 4-Chloro-3-Hethylphenol 550. U 117-81-7 bis(2-EthylhexVnPhthalate 550. U .91-57-6 2-Hethylnaphthalene 550. U 218-01-9 Chrysene 550. U "77-47-4 Hexachlorocyclopentadiene 550. U 117-84-0 Di-n-Octyl Phthalate " ~550.—U *88-06-2 2,4,6-Trichlorophenol 550. U 205-99-2 BenzoCbJFluoranthene ' 550, U95-95-4 2,4,5-Trichlorophenol 2700. U 207-08-9 Benzo(k)Fluoranthene 550. U91-58-7 2-Chloronaphthalene ' 550. U 50-32-8 Benzo(a)Pyrene . 550. U88-74-4 2-Nitroaniline 2700. U 193-39-5 Indeno(l,2,3-ed)Pyrene 550. U .131-11-3 Diaethyl Phthalate 550. U 53-70-3 Dibenzo(a,h)Anthracene 550. U208-96-8 Acenaphthylene 550. U 191-24-2 Benzo(g,h,i)Perylene 550. U99-09-2 3-Nitroaniline 2700. U -

(D-Cannot be separated froa diphenylaaine

Form 1 . ' 7/85A R 3 0 I 9 1 5

Laboratory Naae: S-Cubed Sample Number Bow*Case Ho.: 10591 CY 758 ^

ORSANICS ANALYSIS DATA(Page 3)

Pesticide/PCBs

'Concentration: . LW 6PC Cleanup _Yes j HQ -•• — ••—-.- — .Date Extracted/Prepared: 10-13-38 Separatory Funnil Extraction _YtsDate Analyzed: 11-01-88 ' Continuous Liquid-Liquid Extraction _YtfConc/Dil Factor: 1.00

CAS I ug/1 orfug/KgNumber (Cirtftr'Onel319-34-6 ALPHA-SKC 8.3 u319-35-7 BETA-BHC . ' 8.8 u319-36-8 DELTA-SHE 8.8 u58-39-9 6AHHA-BKC (LINDANE) 8.8 u76-44-8 HEPTACHLOR 8.8 u309-00-2 ALDRIH 8.8 u1024-57-3 HEPTACHLOR EPOXIDE 8.8 u959-98-8 ENDOSULFAH I 8.8 u50-57-1 DIELDRIN 18 u72-55-9 4,4'-DDE 18 u72-20-8 ENDRIN IB u33213-65-9 ENDOSULFAN U 18 u72-54-8 4,4'-DDD 18 u7421-93-4 ENDRIN ALDEHYDE 18 U1031-07-3 ENDOSULFAN SULFATE 18 u50-29-3 4,4'-DDT 18 u72-43-5 METHOXYCHLDR 88 u53494-70-5 EHDRIH KETOHE 18 u57-74-9 CHLORDAKE 88 u8001-35-2 TOXAPHENE 180 u12574-11-2 AROCLOR-1015 88 u11104-23-2 AROCLOR-1221 .." . 88 u11141-16-5 AROCLOR-1232 _ ' 88 u53469-21-9 AROCLOR-1242 . 88 u12672-29-6 AROCLOR-1248 88 u11097-69-1 AROCLOR-1254 180 u11096-82-5 AROCLOR-1260 180 u

Volume of water extracted (ml): N.A.Height of sample extracted (g): 30.0Volume of total extract (ill: 10.00Volume of extract injected (ul): 1.00

Form I 7/85 REV.

H CONFIRMED BY 6C DUAL COLUKN CONFIRMATION

: Sample NumbersunSANICS ANALYSIS DATA SHEET CY759 s

(Page 15 :................ :

Laboratory Nane: S-CU3ED ' , Case No: W591Las Saspie ID Ho: CY7S9 (Voa) I 50 Report No: N.3Saaple Matrix: KATESData Relsise Authorized By: _,

Contract No: 68-01-7261Date sample Received: 10-12-33

VOLATILE COMPOUNDSConcentration: (op Medium (Circle One)Date Extracted/Prepared: 10-14-381Date Analyzed: 10-14-33 \Canc/DiI Factor: 1.0 pH: Jf.R -.—.--.Percent Moisture (Not Decanted): N.R

CAS (ug/) or ug/kg ' CAS (ug/Mir ug/kgNumber (Circle One) Number N5rfcle One)74-37-3 CiLORCMETHANE 10 U 78-37-5 1,2-DICHLGF.OPROPfiNE 5 U74-33-9 BRDHOHETKANE 10 U , 10061-02-6 TRANS-1,3-DICHLORQPSGPEHE 5 U75-01-4 VINYL CHLORIDE 10 U 79-01-6 TRICHLGRGETKENE 5 U75-00-3 CKLGRGETHANE 10 U 124-48-1 DIBROMOCHLORCMETHANE 5 U75-09-2 HETHYLENE CHLORIDE 9 3 79-30-5 1,1,2-TRICHLOROETHANE 5 U67-64-1 ACETONE 10 U 71-43-2 BENZENE 5 U75-15-0 CARBON DISULFIDE 5 U 10061-01-5 CIS-1,3-DICHLOROPRGPENE 5 U75-35-4 1,1-DICHLOROETHENE 5 U 110-75-3 2-CHLDRCETHYLVINYLETHER 10 U75-34-3 1,1-DICHLGRQETHANE 5 U 75-25-2 BROMOFORH 5 U156-60-5 TRANS-1,2-DICHLOROETHENE 5 U 591-7B-6 2-HEXANONE 10 U67-66-3 CHLOROFORM 5 U 108-10-1 4-METHYL-2-PENTANONE 10 U107-06-2 1,2-DICHLOROETHANE ' • 5 U 127-18-4 TETRACHLOROETHENE 5 U78-93-3 2-3UTAHONE 10 U 79-34-5 1,1,2,2-TETRACHLOROETHANE 5 U71-55-6 1,1,1-TRICHLOROETHANE 5 U 108-38-3 TOLUENE 5 U56*23-5 CARBON TETRACHLORIDE 5 U 108-90-7 CHLOROBENZEHE 5 U103-05-4 VINYL ACETATE 10 U 100-41-4 ETHYLBENZENE 5 U75-27-4 BRQMODICHLORQMETHAHE 5 U 100-42-5 STYRENE 5 U

... ... _•„ ..." - TOTAL XYLEHE3 , . 5 U •Data Reporting Qualifiers . " • •

For reporting results to EPA, the following results qualifier are used. Additional flags or footnotes -. .. •explaning results are encouraged.However,the definition of each flag must be explicit. -;••••

\Value: If the result is a value greater_than or equal to the C This flag applies to pesticide parameters where _ _

detection limit,report the value. the identification has been confirmed by BC/HS.SingleU Indicates compound was analyzed for but not detected.Report component pesticides > or « 10 ng/ul in the final

the minimum detection limit for the sample with the U (eg.lOU) extract should be confirmed by 6C/HS.based on necessary concentration/dilution action, (this is \not necessarily the instrument detection limit.)The footnotes B This flag is used when analyte is found in the blankshould read:U-Compound Mas analyzed for but not detected.The as well as sample. It indicates possible/probablenumber is the minimum attainable detection limit for the sample. blank contamination and warns the data user to take

J Indicates an estimated value:This flag is used either when appropriate action.estimating a concentration for tentatively identified compoundswhere a 1:1 response is assumed or when the mass spectral data S Matrix spiked compound.indicated the presence of a compound that meets the identificationcriteria but the result is less than the specified detection limit ' • fl R Q H J Q I "7but greater than zero (eg 10J) .If limit of detection is 10 ug/L and Hfl ° u I J I /a concentration of 3ug/L is calculated,report as 3J.

Appendix D

Reviewed and CorrectedTentatively Identified Compound Lists

-o., N.-, _i-CW<9irt

C«M No ______

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1.

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13

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20

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is.

18

20212223242S2627.2129.30 .

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(2.V75?

CASCompound N«m«

n VO-

S-CUICD . - u v .NvmbtrCa.t No

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TtnUtlvtry ld«ntifi*d Compounds

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AB30I922

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Organics Analysis Data Shttt(Paflt 4)

Tentatively Identified Compounds

CAS

, .*

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110 '

1112

14

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17

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AR30I923

rc"-.Vr»«nl * 7 85. ' ""*"'" "•"* '" "~ '" * ' ' * • - _-.--—,.- .-.,-.. —..»- ^__-, ,_

Appendix E

DPO Report for Contractual Compliance

BR30I921*

'page 1 of 2

ORGANIC DATA VALIDATION SUMMARY

Date Review Completed: 3/20/89 Contract Lab.: S CubedCase No.: 10591 Contract No.: 68-01-7261Site Name: Eastern Diversified Lab DPO: Kent KitchingmanSample Nos.: CY755-CY759 Reviewer: Nicholas J. Kurlick

From: Region III/ESATPhone: (301) 266-9887

CONCENTRA1MATRIXsoil/solidaqueousother

"low32

medPIONhicrh MATRIX RELATED COMMENTS

7OLATILESGC/MS tunina — BFBInitial CalibrationContinuing CalibrationSurrocrate RecoveryMatrix SpikesReaaent BlanksHoldina Times

OKXX

XX,X

FYI

X

X

Action COMMENT

See note 1

See note 2

5EMI-VOLATILESGC/MS tunina — DFTPPInitial CalibrationContinuincr CalibrationSurrogate Recovery'Matrix SpikesReaaent BlanksHoldincr Times

OKXX

X

XX

FYI

X

X

Action COMMENT 1"1

See note 1

See note 3

PESTICIDESInstrument PerformanceInitial CalibrationContinuina CalibrationSurroaate RecoveryMatrix SpikesReacrent BlanksHoldina Times

OKXXX

XX

FYI

XX

Action COMMENT

See note 4See note 5 & 6

DVERALL CASECompound IdentificationData Completeness

OKXX

FYI Action

REVIEWER'S COMMENTS;

DOCUMENTATION ATTACHED (see following pages) * n o n i Q 9c

Case 10591 Page 2 of 2

Organic Data Validation Summary

Note 1 - The %D values for several compounds exceeded precisioncriteria in the continuing calibration standards. (SeeTable I in Appendix F).

Note 2 - The maximum concentration of the following commonlaboratory contaminant was found in the laboratorymethod blanks.

Compound Concentration fug/L)

methylene chloride 6

Note 3 - Semi-volatile MS/MSD analyses of water sample CY757 hadtwo (2) out of ten (10) spike recoveries of the acidextractables outside quality control limits. (See FormIII in Appendix F).

Note 4 - Pesticide surrogate recoveries for samples CY756 andCY758MSD were outside quality control limits.(See Form II in Appendix F).

Note 5 - Pesticide MS/MSD analyses of soil sample CY758 had oneout of twelve (12) spike recoveries and two (2) out ofsix (6) relative percent differences (RPD's) outsidequality control limits. (See Form III in Appendix F).

Note 6 - The matrix recovery calculation for pesticide analyses ofsamples CY757 MS/MSD and CY758 MS/MSD were performed basedon the analysis of the actual matrix spiking solution.This percent recovery was then used to calculate the amountin the matrix samples using the matrix solution as acalibration standard. (See Support Documentation inAppendix F).

. Appendix F

Support Documentation

AR30I927

Page 1 of 1Case 10591

Table ICompounds and Associated Samples Affected by Calibration

Uncertainty

Volatiles CY755 CY756 CY757 CY758 CY759

2-butanone C C C Cvinyl acetate C C C C2-hexanone C C C C4-methyl-2-pentanone C C C C

Semi-Volatiles

benzyl alcohol C C Cnitrobenzene Cbenzoic acid C C2-methylnaphthalene C C C C3-S'-dichlorobenzidine C- C C Cbenzo(k)fluoranthene C C C Cdibenzo(a,h)anthracene C C2-4-dinitrophenol C C

C = The %D exceeded 25% in the continuing calibration. Quantitation* limits are qualified "UJ".

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Initial Calibration Data\Jdtthld HSL Compounds

Case No! /OS'4/ Instruaent ID' HP 12

Contractors S-CUBEO Calibration Date' 10/04/88i ......................

Contract Nos 6801-7261

fliniaua RF for SPCC is 0.300 flaxinua Z RSD for CCC is 30::

laboratory ID* >CB401 >OCOC4 >CB403 >CB404 >CB405RF RF RF RF RF __

\ Conpound "20.00' 50.00 100.00 150.00 200.00 RF I RSO CCC SPCC \_„„_„„_..._____..... ...._ __._ .._.. __... ...._. ___ _.._ _. _._ \Chloroaethane .56595 ,64674 .54311 .56103 .550.3 .57355/7.299 »«Bronowthane 1.02711 1.00150 .99176 1.01639 .94867 .99709 3.034Vinyl Chloride .68593 .79509 .70865 .76163 .75265 .74479 6.269^iChloroethane .47311 .56651 .45206 .53631 .53115 .51184 9.283tlethylene Chloride 1.28168 i.14164 1.09249 1.14370 1.01285 1.13447 8.632flcstone .63756 .30290 .23030 .20439 .20018 .31507 (|8_i2.DCarbon Disulfide 2.27141 2.55310 2.67614 2.82414 2.71252 2.60748 8.1031,1-Dichloroethene .75210 .76792 .79526 .79981 .80735 .78449 2.987/» - - - - - '1,1-Diehloroethane 1.79364 1.72548 1.75085 1.72484 1.61606 1.72218/3.809 •»Trans-1,2-Dichloroethene 1.09422 1.08701 1.06944 1.05757 1.01012 1.06367 3.124.Chlorofora 2.54237 2.43763 2.47375 2.46685 2.266B3 2.43749 4.219'•U-DiGhloroethane-d4 1.58616 1.52386 1.60298 1.55178 1.61428 1.57581 2.375 (Cone-50.0,50.0,50.0,50.0,50.0)1,2-Dichloroethane 1.95373 1.73233 1.76692 1.75144 1.59090 1.75906 TJiS2-Butanone .20.58 .05085 .07445 .06629 .06494 .09322 (70J6 >1,1,1-Trichloroethane 2.27392 2.19235 2.14575 2.26892 2.09560 2.19531 T.529Carbon Tetrachloride 2.30954 2.27723 2.30909 2.33514 2.21868 2.28994 1.957Vinyl acetate 2.06546 1.72791 1.64484 1.62312 1.49220 1.71071 12.602Broaodichloroaethane 2.40777 2.34498 2.41985 2.40936 2.21870 2.36013 3.5761,2-Dichloropropane .3146! .29679 .29660 .29459 .28648 .29783 3.466-/«Trans-l,3-D5chloropropene .46939 .47012 .46402 .48280 .45840 .46893 1.934 (Conc-14.4,34.0,72.0,108.0,144.0)Trichloroethene .50431 .47459 .46254 .45655 .44459 .46852OibroiochloroMthane .50903 .50993 .51384 .53162 .50890 .514661,1,2-Trichloroethane .36423 .32574 .31314 .30912 .29345 .32113Benzene .79574 .74579 .73681 .73366 .70704 .74381cis-l,3-Diehloropropene .50637 .50705 .50244 .50833 .49331 .50360 1.233 (Conc*25.U4.0,128.0,1?2.0,256.02-Chloroethyluinylether .20122 .16795 .16302 .16543 .15654 .17123BroM.on .57128 .54734 .53750 .56294 .56290 .55638«/ 2.450 •»2-Hexanone .4642! .26853 .25913 .24994 .24276 .29693l4-Methyl-2-Pentanone ' .30903 .18095 .17614 .17417 .16874 .20181Tetrachloroethene .61012 .58581 .57317 .55260 .53342 .571021,1,2,2-Tetrachloroethane" " .84644 .61779 .60440 .60332 .56920Toluene .67237 .64865 .63531 .63976 .60803

RF .- Response Factor (Subscript is aaount in ug/L)

RF - Average Response Factor

XRSD - Percent Relative Standard Deviation A R O U I 9 «3 L,

CCC * Calibration Check Coapounds (') SPCC • Systea Performance Check Coapounds (")

Fora VI Page 1 of 2

Initial Caliiration DataHSL Compounds

Case Ho' /Q<r-a / Instruwnt ID« HP 12

Contractor: S-CUBED Calibration Date: 10/04/88

Contract Ho: 6801-7261

Hiniaua RF for SPCC is 0.300 'Haxiaua : RSD for CCC is 30Z2

Laboratory ID: >CB401 >DCOC4 >C8403 >CB404 >CB405 IRF RF RF RF RF I _

Coapour.d 20.M 50.00 100.00 150.00 200.00 \ RF X RSD CCC SPCC _ _ .

Toluene d-8 1.06827 1.06727 1.07157 .99209 1.02735 1.04531 3.332 (Conc-50.0,50.0,50.0,50.0,50.0)Chlorobenzene 1.03347 .95328 .94978 .94017 .89558 .95446 5.222 •«Ethylbenzene .437« .43349 .42860 .43746 .40765 .42898 2.910*'*Styrene .97950 .92871 .93616 .94816 .90197 .93890 3.017•-XYLEHE .55513 .54607 .54604 .55023 .51696 .54289 2.757o-/p-Xylenes .57634 .53310 .53019 .53329 .49816 .53422 5.205 (Conc«40.0,100.0,200.0,300.0,400.Broaofluorobenzene .85752 .85653 .84300 .80155 .82967 .83765 2.765 (Cone-50.0,50.0,50.0,50.0,50.0)

RF - Response Factor (Subscript is aaount in ug/L)

RF - Average Response Factor

XRSO • Percent Relative Standard legation . A R 3 0 I 9 3 3

CCC - Calibration Check Coapounds _•) SPCC - Systea Performance Check Coapounfe ("}

Fora 01 Paje 2 of 2

.

Continuing Calibration Check•" \jbW-\lfl- HSL Coapounds

Case Ho» (OS'4/ Calibration Date* 10/14/88

Contractors S-CUBED Tiae» 10 = 25 **~

Contract No: 6801-7261 Laboratory ID: >QC014 P- !

Instrument ID: HP |2, Initial Calibration Date' 10/14/00

diniaua RF for SPCC is 0.300 flaxiaua I Biff for CCC is Z

Coapound , RF RF ZDiff CCC SPCC

Chloroaethane .57355 .58191 •" 1.46 »Broaoaethane .99709 1.03422 3.72Vinyl Chloride .74479 .82476 10.74 /•Chloroethane .51184 .54414 6.31Oethylene Chloride 1.134471.07613 5.14Acetone .31811 .33237 4.41 • (__. '\t <-) *Z &Carbon Disulfide 2.60748 2.36700 9.22 .-1,1-DSchloroethene .78449 .91180 16.23«'» *) 3 71,1-DSchloroethane 1.722181.55365*' 9.79 »Trans-l,2-Dichloroethene 1.06367 .96462 9.31 C U 7 gy fi _5Chlorofora 2.43749 2.24037 8.09/tl,2-Dichloroethane-d4 1.575811.41528 10.If Cy 751,2-Dichloroethane 1.75906 1.61647 8.11 '2-Butanone .09322 .06646 (28.7Q As bj- _jcljmc, fifa k [1,1,1-Trichloroethane 2.19531 2.17085 1.11 ' /Carbon Tetrachloride 2.289942.18871 4.42 C\JVinyl Acetate 1.71071 1.26467 CzTjDBroaodichloroaethane 2.36013 2.15408 8.731,2-Dichloropropane .29783 .28024 5.91'*Trans-1,3-Oichloropropene .46893 .44260 5.62 (Cone-36.00)Trichloroethene . .46852 .45012 3.93OibroaochloroBCthane .51466 .48744 5.291,1,2-Trichloroethane .32113 .29712 7.41Benzene .74381 .71998 3.2tcis-l,3-0ichloropropene .50360 .48361 3.97 (Conc«64.00)2-Chloroethylvinylether ' .17123 .14002 18.23Broaofon .55638 .47380'2-Hexanone .29693 .215814-Methyl-2-Pentanone .20702 .13618Tetrachloroethene .57102 .56901 .3$1,1,2,2-Tetrachloroethane .64823 .53454f 17.54 ••Toluene ,64082 .63304 1.2IM

RF - Response Factor froa daily standard file at 50.00 ug/L

RF - Average Response Factor froa Initial Calibration Fora VI

tOiff - t Difference froa original average or curve . ^ . "

CCC - Calibration Check Coapounds (*] SPCC - Systea Perforaance Cheek Coapounds (*•_

Fora VII Page 1 of 2

Continuing Calibration CheckISL Coapounds

Case Ho» . _^ Calibration Date« 10/14/88

Contractor! S-CUBED - Tiae> 10:25

Contract No' 6801-7261 Laboratory ID: >DC014

Instruaent ID: HP 12 Initial Calibration Date» 10/U/OO

Hini.ua RF for SPCC is 0.301 Maxiaua Z Diff for CCC is Z

Coapound\ RF RF ZDiff CCC SPCC 5> r»~»

Toluene d-8 \ 1.045311.04002 .51Chlorobenzene '• .95446 .91498 + 4.14 »» ' A<£ bEthylbenzene .42898 .40555 5.46 /• 'Styrene .93890 .90104 4.03 £ \la-XYLENE . .54289 .53667 1.14 /o-/p-Xylenes , .53422 .51474 3.65 (Cone-100.00)Broaofluorobenzene .83765 .84200 .52

ccv

RF - Response.Factor froa daily standard file at 50.00 ng/L

RF - Average Response Factor froa Initial Calibration Fora VI

ZDiff - t Difference froa original average or curve • "''30/935

CCC - Calibration Check Coapounfc (*} SPCC - Systea Perforaance Cheek Coapomds (••)

Fora .II Page 2 of 2

Trf&fContinuing Calibration Check

HSL Coapounds

Case Ho: (QT1? / Calibration Date' 10/17/88

Contractor: S-CUBED - Ti«*« 10:32 •"

Contract No: 6801-7261 Laboratory ID« >OC017 v^-

Instrument ID! HP 12 Initial Calibration Date' 10/14/00

niniaua RF for SPCC is 0.300 Haxiaua Z Diff for CCC is Z<

Coapound RF RF ZOiff CCC SPCC .

Chloronethane .57355 .54057 5.75 » t^- 2Broaoaethane .99709 .93189 6.54Vinyl Chloride .74479 .72316 2.90fi .Chloroethane .51184 .49584 3.13Hethylene Chloride 1.134471.12699 .66Acetone .31811 .31797 .04Carbon Oisulfide 2.60748 2.20252 15.531,1-Dichloroethene .78449 .84094 7.20/*1,1-Dichloroethane 1.72218 1.40638' 18.34 «•Trans-l,2-0ichloroethene 1.06367 .88252 17.03Chlorofora 2.43749 2.07425 14.90 •l,2-0ichloroethane-d4 1.57581 1.32726 15.771,2-Dichloroethane 1.75906 1.45J20 17.062-Butanone .09322 CM24>QOP1,1,1-Trichloroethane 2.19531 1.92163 12.47Carbon Tetrach lor ide 2.289941.98022 13.53Vinyl Acetate 1.71071 1.12684 (347jpBroaodichloroaethane 2.36013 1.92957 18.241,2-Oichloropropane .29783 .26980 9.41"iTrans-l,3-Dichloropropene .46893 .40559 13.51 (Cone-36. 00)Trichloroethene .46852 .45258 3.40Dibroaochloroaethane ' .51466 .46823 9.02 .1,1,2-Trichloroethane .32113 .28417 11.51 'Benzene .74381 .69198 6.97cis-l,3-Dich1oropropene .50360 .45851 8.95 (Conc-64.00)2-Chloroethylvinylether ' .17123 .13711 19.93 .Broaofora .55638 .45471" 18.27 ' ' ••2-Hexanone .2969! .205714-ltethyl-2-Pentanone .20702 .12166Tetrachloroethene ' . .57102 .560381,1,2,2-Tetrachloroethane .64823 .50149/22.64 *•Toluene - - .64082 .60285 5.93v*

RF - Response Factor froa daily standard file at 50.00 ug/L

RF - Average Response Factor froa Initial Calibration Fora VI

ZOiff - Z Difference froa original average or curve8R3QI936CCC - Calibration Check Coapounds (•) SPCC - System Performance Check Coapounds (»») - • -_

5 . .

. Fora VII Page 1 of 2

Continuing Calibration CheckHSL Coapounds

Case No« /0S*7/ ' Calibration Date« 10/17/88... J.«............*...... •••....•....•••••••.I

Contractor: S-CUBED - Tiae: 10:32

Contract Not 6801-7261 j Laboratory ID: >DC017

Instrucent IDt HP 12 j Initial Calibration Date' -10/14/00—

tliniaua RF for SPCC is 0,300 flaxiaua Z Diff for CCC is Z 2-tT

Coapound \ RF RF ZOiff CCC SPCC

Toluene d-8 \ 1.04531 1.04316 .21Chlorobenzene \ .95446 ..1997/ 3.61 •»Ethylbenzene \ .42898 .39595 7.70 '• -Styrene '•.93890 .88450 5.79 /& A n I&_* ka-XYLENE .54289 .51725 4.72o-/p-Xylenes .53422 .50856 4.80 (Conc-100.00)Broaofluorobenzene .83765 .84734 1.16

RF - Response Factor froa daily standard file at 50.00 ug/L

RF - Average Response Factor froa Initial Calibration Fora VI

ZDiff - t Difference froa or.jinal average or carve

CCC - Calibration Check Coaaounds (*) SPCC - Systea Performance Check Caapounds (•*)flR301937Fora VII fage 2 if 2

I N I T I A L C A L I B R A T I O N D A T ASeaivolatile KSL Compounds

(Page 1)* -—Case No.: 901?. .6?.Y»* Region : / TT£- Instrument 10

Cantrattar : S - CLSED Calibration Date : 881071 Ki2.Contractor No.: 68~01-7261

tlimrauB RF for SPCC is, 0.050 foxiaua SR3) for CCC is 30*I

Laboratory ID : >CF901 >CF902 >CF903 >CF?04 >C?9_5- | ccc

Compound RF20 RF50 RF80 RF128 RF160 RF XRSO SPCC •Phenol 2.5113 2.0709 2.0485 1.9004 1.8747 2.0412 8.54 •" *bis(-2-Chloroethyl.Ether 1.5J599 1.6622 1.7371 1.6428 1.6355 1.7275 7.872-ChlorophenoI 1.4852 1.3932 1.4243 1.3684 1.3689 1.4080 3.47

——1,3-Oichlorobenzene 1.5159 1.4599 1.4011 1.3332 1.3714 1.4163 5.111,4-Dichlorobenzene 1.5998 1.4781 1.4043 1.3352 1.3814 1.4398 7.17 •Benzyl Alcohol .4375 .6471 .7769 .9928 .9679 .7643 (TOT)1,2-Oichlorobenzene 1.5734 1.5077 1.4258 1.3810 1.3433 1.4463 6.492-fle thy I phenol 1.7393 1.5902 1.5552 1.4829 1.5141 1.5762 6.34bis(2-chloroisopropyl)Ether 3.7455 3.6326 3.5446 3.4641 3.5560 3.5886 2.964-rtethylphenoI '1.7527 1.6190 1.6335, 1.5469 1.5403 1.6185 5.30 'N-Nitroso-Oi-n-Propylaatne 1.830i 1.5992 1.5776 1.5602 1.6020 1.6338 < 6.80 « *Hexachloroethane .6544 .6298 .6027 .5936 .5854 .6132 4.64 'Nitrobenzene .4792 .4535 .4711 .4329 .4039 .4481 6.79Isophorcne .9754 .9209 .9047 .8909 .9153 .9214 3.502-Nitrophenol .2212 .2206 .2233 .2159 .2238 .2210 1.43 • •2,4-Dinethylphenol .3061 .2922 .2900 .2719 .2837 .2888 4.32

.- Benzoic Acid * .1297 .1596 .1841 .1324 .1515 16.92bis(-2-Chloroethoxy)ttethane .5674 .5183 .5296 .5025 .5055 .5247 5.UO2,4-Dichlorophenol .2988 .2788 .2822 .2635 .2726 .2792 4.68 • »1,2.4-Trichlorobenzene .2903 .2745 ..2709 .2553 .2605 .2703 5.03Naphthalene 1.0680 .9544 .9452 .8488 .8599 .9351 . 9.474-Chioroaniline .3840 .4581 .4667 .4292 .4427 .4362 7.45Hexachlorobutadiene .1361 .1254 .1245 .1145 .1191 .1239 6.53" »4-Chloro-3-Hethylphenol .3804 .3499 .3680 .3376 .J375 .3546 5.36 " •2-tlathylnaphthalene .6845 .6160 .5537 .4599 .3863 .5401 '22.18Hexaehlorocyelcpentadiene'- .1600 .2053 .1931 .1769 .1742 .1819 9.67 •»2,4,6-Trichlorophenol .3263 .3199 .3176 .3033 .3130 .3160 2.72 r •2,4,5-Trichlorophenol » .3778 .3820 .3620 .3643 .3715 2.662-Q.loronaphthaler* . 1.1106 1.0810 1.0483 .9479 .9611 1.0280 7.822-NJtroaniline » .5993 .6130 .5797 .6016 .5984 2.31OiMthyl Phthalate 1.4096 1.3144 1.2763 1.2088 1.2342 1.2885 6.12AcenapMhylene 1.7897 1.6291 1.5487 1.4324 1.3908 1.5581 18.28.-Nit roan Hint . * .4418 .4185 .3916 .4125 .4159 4.89Acenaphthene 1.1538 1.8780 1.0145 .9157 .9280 1.B164 18.09 " *2.4-Dinitrophenol « .1418 .1858 .2035 .2199 .1874" 18.17 ••4-Nitrophenol * .3337 .3381 .3420 .3469 .3402" 1.65 ••Dibenzofuran 1.6558 1.5645 1.4948 1.3787 1.3997 1.4987 7.78

RF - Response Factor (subscript is the aaotmt of nanograas) SPCC > System Performance Check Coapounds ( * • )

RF - Average Response Factor ' » - Not detectable at 28 ngJSRSO - Percent Relative Standard DeviationCCC - Calibration Check Coapounds (•). A R 3 Q f Q *3 8

Fora VI - " " 7/85

I N I T I A L C A L I B R A T I O N D A T ASemi volatile HSL Compounds

(Page 2)'° "IN Jtf- TCase NO.: .027/JA..Y1** Region : fl T\L. Instrument ID '. *1(HP)

Contractor : S - CUBED Calibration Date : BO'.DJlContractor No.: 6801-7261 ' JO -| b

Minimum RF for SPCC is 0.050 Maximum XRSO for CCC is 30*

Laboratory ID : >CF901 >CF902 >CF9D3 >CF?04 >CF905

Compound RF20 RF50 RF80 RF120 RF160 RF JlRSO SPCC • *2,4-Dmitrotoluene .5259 .5253 .5176 .5013 .49792.6-Dinitrotoluene .3744 .3688 .3688 .3619 .3498Diethylphthalate 1.7190 1.4364 1.3428 1.2*81 1.2666

\ 4-Chlorophenyl-phenylether .5621 .4992 .4612 .4266 .4329,' Fluorene 1.2684 1.1825 1.1241 1.0536 1.0438

4-Nitrosniline * .4597 .4788 .4646 .4268.4,6-Dinitro-2-Methylphenol - * .1402 .1468 .1278 .1139

i N-Nitrosodiphenylaaine (1) .4996 .4587 .4471 .3669 .35924-Broaophenyl-phenylether- .1628 .1629 .1635 .1478 .1572Hexachlorobenzene .1853 .1744 .1752 .1657 .1702 '

•. Pentachlorophenol + .0784 .0915 ,1024 .1114Phenanthrene 1.0182 .9457 .9313 .8836 .9171Anthracene 1.0466 .9809 .9347 .8417 .8157

. Di-n-Butylphthslate 1.6433 1.5173 1.5157 1.3977 1.3909Fluoranthene 1.0898 1.0332 1.0104 .9466 .9507

, Pyrene 1.3266 1.2804 1.3194 1.5306 1.6422! Butylbenzylphthalate .8985 .8783 .8979 1.0351 1.1504: 3,3'-Dichlorobenzidine .3962 .3717 .4126 .4906 .5190

Banzo(a.Anthracane 1.2542 1.2249 1.2728 1.5303 1.7658bis(2-Ethylhexyl)Phthelate 1.4442 1.2926 1.3553 1.5208 1.6439Chrysene 1.1091 1.0576 1.0303 1.1554 1.0857Di-n-Octyl Phthalate 1.9946 1.8259 1.8812 ' 1.8412 1.8556Benzo(b)Fluoranthene 1.1524 1.8989 1.0561 1.2412 1.1887Benzo(k)Fluoranthene .8502 .7731 .8068 .3546 .4438Banzo(a)Pyrene .9600 .9389 .9091 .8620 .8736Indeno(l,2,3-cd)Pyrene . 1.1506 1.8405 .9868 .8969 • .9219Dibenzo(a,h)._ithracene .8854 .8889 .7621 .7068 .1283Benzo(g,h,i.Perylene .9497 .8457 .7892 . .7478 .7786

RF - Response Factor (subscript is the aaount of nanograas) SPCC - System Performance Check Coapounds ( * • )

RF - Average Response Factor * - Not detectabli at 28 ngXRSO - Percent Relative Standard Deviation (1) - Cannot be separated froa diphenylaaineCCC - Calibration Check Coapounds ( * )

Fora Ul 7/85

AR30I939

C O N T I N U I N G C A L I B R A T I O N C H E C KSeaivolatile HSL Compounds

(Paqe 1)

Case No.: CASE ICXT^V Reqion : / TjP Calibration Date**

0818.6Contractor : S - CUBED n Time : 881826 88:57 <

Contractor No.: 6801-7261 • Laboratory ID : >OC026::02 *Instrument ID : .UHP) Initial Calib Date : XT 16 1988 '

Minimua RF for SPCC is fl.050 flaxiaua *0 for CCC is 25*

Compound ! RF RF5D . SO CCC SPCCPhenol 1 2.8412 1.9922 2.40 » - - - - - -bis(-2-Chloroethyl)Ether, 1.7275 1.7995 4.172-Chlorophenol 1 1.4880 1.3622 3.251,3-Oichlorobenzene I 1.4163 1.4650 3.441,4-Dichlorobenzene ' 1.4398 1.5096 JJl. *Benzyl Alcohol \ .7643 1.8448 (JOp £&. m»f &1,2-Dichlorobenzene » 1.4463 1.4984 3.60 ^ \2-Hethylphenol 1.5762 1.4189 9.98bis(2-chloroisopropyl)Ether 3.5886 3.4253 4.554-Methylphenol 1.6185 1.5236 5.86N-Nitroso-Di-n-Propylamine 1.6338 1.5222 6.83 »Hexachloroethane .6132 .6675 8.86Nitrobenzene .4481 .4618 3.06Isophorone .9214 .9121 1.012-Nitrophenol .2218 .2172 1.71 «2,4-Dimethylphenol .2888 .2765 4.24Benzoic Acid * .1515 .1748 14.88bis(-2-Oiloroethoxy)Hethane .5247 .5157 1.722,4-Dichlorophenol .2792 .2810 .64 *1,2,4-Trichlorobenzene .2783 .2837 4.96Naphthalene .. .9351 .9342 .094-Chloroani!ine .4362 .4114 5.68Hexachlorobutadiene .1239 .1271 2.54 »4-Chloro-3-«ethylphenol .3546 .3163 10.88 •2-ftethylnaphthalene .5481 .7484 <387!pHexachlorocyclopentadiene .1819 .1931 6.18 » *2,4,6-TrichlorophenoI .3168 .3440 8.87 *2,4,5-TrichIorophenoI * .3715 .3592 3.322-Chloronaphthalene 1.8280 1.0994 6.952-Nitroanitine * .5984 .5932 .88 . - - -Dimethyl Phthalati 1.2805 1.2894 .87Acenaphthylene 1.5581 1.6617 6.653-Nitroaniline * .41.9 .4833 3.83Acenaphthene - 1.8164 1.8378 2.11 *2,4-Oinitrophenol » .1874 .1522 18.79 « •4-Nitrophenol * .3402 .3358 1.52 **Dibenzofuran 1.4987 1.5458 3.14

RF58 • Response Factor froa daily standard file at *0 - Percent Difference__ concentration indicated (58 total nanoqraas) CCC - Calibration Check Coapounds ( • )RF - Averaqe Response Factor froa initial Calibration Fora UI SPCC - System Performance Cheek Compounds ( • * )+ - Due to low response, analyze at 88 total nanograas

C O N T I H U I N B C A L I B R A T I O N C H E C KSeai volatile HSL Coapounds

(Paqe 2)

Case No.: CASE1O<^\ Reqion : V Calibration Date ; 881826 BH.lContractor : S - CUBED ** Ti«t : 881026 08:57

Contractor No.: 6801-7261 . Laboratory ID : >DC026::D2Instrument ID : __CHP) Initial Calib Date : OCT 16 1988

Minimum RF for SPCC is 0.050 Maximum H) for CCC is 25*

Compound RF2,4-Oinitrotoluene .51362,6-Oinitrotoluene .3647Diethylphthalate 1.40264-Chlorophenyl-phenylether .4764

RF5Q SO CCC SPCC.5030 2.07 - - ....3716 1.901.3430 4.25 . SA"V.4919 3.261.1497 1.34 CFluorene . 1.1345

————4-Nitroaniline * .4575 '.39084,6-Oinitro-2-«ethylphenol * .1322 \.1563N-Nitrosodiphenylaaine (1) .4263 .4618 8.14 *4-Bromophenyl-phenyIether .1587 .1647 3.76Kexachlorobenzene .1742 .1688 3.12Pentachlorophenol * .0959 .1039 8.29 «Phenanthrene .9392 .9545 1.62Anthracene .9239 .9813 ' 6.21Di-n-Butylphthalate 1.4938 1.4648 1.89Fluoranthene 1.0061 1.8069 .08 *Pyrene 1.4198 1.2490 12.03Butylbenzylphthalate .9704 .8332 14.143,3'-Dichlorobenzidine ' .4388 .2188 (jO.Oj)Benzo(a)Anthracene 1.4096 1.2044 14.56bis(2-Ethylhexyl)Phthalate 1.4513 1.2681 12.62Chrysene 1.0876 1.8638 2.26Di-n-Octyl Phthalate 1.8797 1.8026 4.18 «Benzo(b)FIuoranthene 1.1458 .9936 13.28Benzo(k)Fluoranthene .6457 .8962 uQiD8enzo(a)Pyrene .9071 .9217 1.61 •Indeno(l,2,3-cd-Pyrene .9992 1.1559 15.68Dibenzo(a,h)Anthracene .6567 .8748 (33.2p8enzo(q,h,i)Perylene - .8222 .9681 16.77 ... . . .

RF58 - Response Factor froa daily standard file at SO - Percent Difference - '__ concentration indicated (50 total nanoqraas) CCC - Calibration Check Compounds ( • )RF - Average Response Factor froa initial Calibration Fora UI SPCC - Systea Performance Check Compounds ( • • )+ - Due to low response, analyze at 86 total nanoqraas (1) - Cannot be separated from diphenylaai.it

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C O N T I N U I N G C f t L l S R A T I O N C H E C KSemivolatile MSl. Conpounds

(Page U

Case No.: CflSE \0 \ Region '•jf'fc. Calibration Date :-88WiS MUTr^Contractor :.£ - C'JfctD Time : 881025 11:89.*-

Contractor No.: 68U1-7261 Laboratory ID : >DC025::D3 **••Ir.strucent 10 : tltk?) Initial CsliH Date : OCT 16 1989 r

RF for SPCC is 8.850 ttaximuw S3 for CCC is ,25X

Compound -' RF RF58 SO CCC SPCCPhenol 2.0412 2.0602 .93 »bisjl-2-ChloroethyUEther 1.7275 1.8438 6.732-Chlorophenol 1.4.80 1.3662 2.971,3-Dichlorobenzene 1.4163 1.4541 2.67l,4JDienlorebenzene •""1.4398 1.4340 3.07 *

.?«, "

Benryl Alcohol .7643 1.0421 Q6j C V 71,2-Dicftlorobensene 1.4*63 1.5117 4.52 72-ttethylphenol 1.5762 1.4824 5.95b.sl2-chloroisopropyl)£ther 3.5886 3.5699 .524-Kethylphenol 1.6185 -1.5698 3.01N-Nitroso-Oi-n-Propylaame 1.6338 1.6619 1.72 * »Hexachloroethane .6122 .6647 -8.39 . / , , /,Nitrobenzsne .4481 .4745 5.88 ** *> ft/*-*,Isophorone .9214 .8920 3.19 ._ . _2-Nitrophenol .2210 .2204 .28 *2, 4-Dimethyl phenol .2888 .2824 2.23Benzoic Acid » .1515 .2014 (&$£>bist-2-Chloroethoxy)Methane .5247 ,5279 .612,4-Dichlorophenol .2792 .2799 .27 •1,2,4-Trschlorobenzene .2703 .2667 1.34Naphthalene .9351 .9619 2.874-Diloroaniline .4362 .4023 7.78Hexachlofobutadiene .1239 .1252 1.03 »4-Chloro-3-Hethylphenol .3546 .3275 7.64 »2-ftethylnaphthalene .5401 .7740 M3.IDHexachlorocyclopentadiene ' .1819 .1696 6.78 • *2,4,6-Trichloropnenol <316° "4°4 ' 7'74 * . . . .2,4,5-Trichlorophenol * .3715 .3549 4.482-Chloronaphthalene 1.0280 1.0832 5.372-Nitroaniline » .5984 .6104 2.88 - . . . " ' "Diaethyl Phthalate -1.2885 1.3098 1.59Acenaphthylene 1.5581 1.7848 9.423-Nitrowiiline * .4159 .3977 4.38Acenaphthene " 1.8164 1.0682 4.M •2,4-Ihnu.opheno! » .1874 .1224 Q4.69J « »4-Mitrophenol » .3432 .3476 2.18 • *Dibentofuran 1.4987 1.5480 3.29

RF.8 - Response Factor froa daily standard file at • *D - Percent Drfierence_ concentration tndicated 150 total nanograas) . CCC - Calibration Check Compounds (•)SF - Average Response Factor froa initial Calibration Fora VI SPCC - Systea Performance Check Coapounds ( • • )* - Out to low response, analyze at 88 total nanograas

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Case No.: CASE 10$3 / Region ijPTjT Calibration Date i-001fl!Z!? 1014: 'Contractor : S - CLBED Time : 881025 11:09

Contractor No.: 6801-7261 Laboratory ID : >DC025::03Instrument 10 : tl(KP) Initial Calib Date : OCT 16 1988

Minimum 8F fop SPCC is 0.050 Maximum JiO for CCC is 25*

Compound • RF RF50 XD CCC SPCC2,4-Dinitrotoluene .5136 .5063 1.422,6-OinitrotolueneDiethylphthalate4-Chlorophenyl-phenyletherFluorene4-Nttroaniline

.3647 .3789 3.881.4026 1.3791 1.68.4764 .4951 3.931.1345 1.1770 3.75

> .4575 .3750 18.034,6-0_nitro-2-nethylphenol ' * .1322 .1383 . __.4.62N-Nitrosodiphenylaaine (1) \ .4263 .4605 8.834-Bronophenyl-phenylether .1587 .1539 3.01Hexach'.orobenzene . .1742 .1608 7.69Pentachlorophenol * .0959 .0981 6.08 _

. Phenanthrene .9392 .9500 1.15 C/ </5Anthracene .9239 .9796 6.03Di-n-Butylphtha!ate 1.4930 1.5146 1.45Fluoranthene 1.0061 1.8132 .71Pyrene 1.4198 1.2650 10.98Sutylbenzylphthalate .9704 • .8786 9.453,3'-Dicnlorobenzidine • .4388 .2558 (41.60;Benzo(a}Anthracene 1.4096 ' 1.1988 14.95

i bis<2-£tnylhexyl)Phtnalate 1,4513 1.3845 10.12Chrysene 1.0876 1.8703 1.59Di-n-Octyl Phthalate 1.8797 1.9017 1.17

1 Benzolb.Fluoranthene 1.1458 1.0716 _i-48• ' 8enzoU)Fluoranthene .6457 .8494

i Benzo(a)Pyrene .9071 .9222; Indeno(l,2,3-cd)Pyrene .9992 1.1231

Dibenzo(a,h.Anthracene .6567 .8594i . • Benzo(g,h,i)Perylene .8222 .9514 15.71

RF50 - Response Factor froa daily standard file at . *0 - Percent Difference .. ~__ concentration ineicated 158 total ninograes) CCC - Calibration Check Compounds ( * )RF - Average Response Factor froa initial Calibration Fora UI SPCC - Systea Performance Check -Compounds ( * • )* - Due to low response, analyze at 80 total nanograas (1) - Cannot be separated froa diphenylaaine

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C O N T I N U I N G C A L I B R A T I O N C H E C KSeai volatile HSL Compounds

(Paqe 1)

Case No.: CASE JC\ Region : f "^P Calibration Date : SS10SO .9i;?Contractor : S - CUBED >nJ Time : 881028 08:19

Contractor No.: 6801-7261 Laboratory ID : >OC028::02 iInstrument ID : tl(HP) Initial Calib Date : XT 16 1988

Mini nun RF for SPCC is 0.050 Maxiaua SO for CCC is 25*

Coqiound RF RF50 SO CCC SPCCPhenol - 2.0412 2.1888bis(-2-Chloroethyl. Ether 1.7275 1.82452-Chlorophenol 1.4088 1.43131,3-Oichlorobenzene 1.4163 1.50031,4-Dichlorobenzene 1.4398 1.4916 3.60 • \ C I/ 7/7Benzyl Alcohol .7643 .9484 24.09 \ r ,, s 7 fitf1,2-Dichlorobenzene 1.4463 1.5006 3.75 \ /2-Hethylphenol 1.5762 1.4237 9.68 ^ y 'bis(2-chIoroisopropyl)Ether 3.5886 3.3878 5.68 74-Nethylphenol 1.6185 1.5425 4.78 / / ,,/ L, r,N-Nitroso-Di-n-Propylamine " 1.6338 1.6184 .94 •• M b '*""•* C kHexachloroethane .6132 .6264Nitrobenzene .4481 .5752Isophorone .9214 .88542-Nitrophenol .2210 .21732,4-Dinethylphenol .2888 .2739Benzoic Acid * .1515 .1777bis(-2-Chloroethoxy).fethane .5247 .51332,4-Dichlorophenol .2792 .28471,2,4-Trichlorobenzene .2783 .2808Naphthalene .9351 .95294-Chloroaniline .4362 .4818Hexachlorobutadiene .1239 .13554-O»loro-3-l1ethylphenol .3546 .34952-Methylnephthalene .5401 .8282Hexachlorocyclopentadiene .1819 .18942,4,6-Trichlorophenol .3168 .35422,4,5-TrichIorophenoI ' + .3715 .36652-OiloronaphthaIene 1.8280 1.10822-NitroanUin8 » .5984 .5562

. Dimethyl Phthalate 1.2885 1.3611Acenaphthylene 1.5581 1.68323-Nitroaniline * .4159 .4015Aeenaphthene 1.8164 1.86982,4-Dinitrophenol * .1874 .1480 <75.2£) • •4-Nitr.phenol * .3402 .3148 7.48 * «Dibenzofuran 1.49S7 1.5646 4.48

RF50 - Response Factor froa daily standard file at *0 - Percent Difference__ concentration indicated (50 total nanoqrams) CCC - Calibration Check Compounds ( • )RF - Average Response Factor froa initial Calibration Fora UI SPCC • Systea Performance Check Coapounds ( • • )* - Due to low response, analyze at 80 total nanogrsas

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(Page 2)

Case No.: CASE JOS^l Region t-y |"*'*'

Calibration Date : 8B1QMContractor : S - CUBED "% "*' Time : 881028 08:19

Contractor No.: iSOl-7261 Laboratory ID : >DC028::D2Instrument ID : *1(HP) Initial Calib Date : OCT 16 1988

Minimum RF for SPCC is 0.050 Maximum SO for CCC is 25*

Coapound RF RF50 SO CCC SPCC2,4-Dinitrotoluene .5136 .5170 .67

.3647 .3748 2.772,6-OinitrotolueneDiethylphthalate 1.4026 1.36364-Chlorophenyl-phenylether .4764 .5868 6.22Fluorene \ 1.1345 1.1690 3.044-Nitroaniline ', +-...4575 .3449 24.62 Ct/9.f74,6-Dinitro-2-Methylphenol\ + .1322 .1494 13.03 '\N-Nitrosodiphenylaaine (1) .4263 .4528 6.20 » C V4-Broaophenyl-phenylether .1587 .1711 7.78Hexachlorobenzene ' .1742 .1821 ' 4.55 C *Pentachlorophenol + .8959 .1055 10.81 *Phenanthrene .9392 .9424 .34 L±4> #/#*/_ (t& Z'tJAnthracene .9239 .9602 3.93 • 'Oi-n-Butylphthalate 1.4930 1.4649 1.88Fluoranthene 1.0061 1.0311 2.48 *Pyrene 1.4198 1.2527 11.77Butylbenzylphthalate .9704 .7880 18.883,3'-Dichlorobenzidine .4388 .2025 .53.71)Benzo(a)Anthracene 1.4896 1.1876 15.75bis(2-Ethylhexyl)Phthalate 1.4513 1.1605 28.84Chrysene 1.8876 1.8418 4.21Di-n-Octyl Phthalate 1.8797 1.7250 8.23 »Benzo(b)Fluoranthene 1.1458 1.0648 7.14Benzo(k)Fluoranthene .6457 .8557 £32.51;Benzo(a)Pyrene .9671 .9278 2.28 •Indeno(l,2,3-cd.Pyrene .9992 1.0195 2.83Dibenzo(a,h)Anthracene .6567 .7459 13.58Benzo(g,hJi)Perylene .8222 .8598 4.48 - • • - - • - • - -,' • "

RF58 - Response Factor froa daily standard file at 50 - Percent Difference . • • • • • • '_ concentration indicated (56 total nanograas) CCC - Calibration Check Coapotmds ( • )RF - Average Response Factor froa initial Calibration Fora VI SPCC - Systea Performance Check Coapounds ( • • )+ - Due to IOM response, analyze at 86 total nanograas (1) - Cannot be separated froa diphenylaaine

Fora UII 7/85

C O N T I N U I N G C A L I B R A T I O N C H E C KSeaivolatile HSL Compounds

CPaqe 1)

Case No.: CASE \0£Q\ Region : J/- If. Calibration DateContractor : S - CUBED ""* Time

Contractor No.: 6801-7261 Laboratory IDInstrument ID : *KHP) Initial Calib Date

00110S881102 13:47>OCN02::02OCT 16 1988

MiniiauB RF for SPCC is 0.050 j Maxiaua SO for CCC is 25*

Compound Rl^ RF50 SO " CCC " SPCC "Phenol 2.0412 1.8392 9.90 / »bis(-2-0»loroethynEther 1.7275 1.6088 6.872-Chlorophenol 1.4080 1.3586 3.511,3-Dichlorobenzene 1.4163 1.4262 .781,4-Oichlorobenzene 1.4398 1.4584 1.29 / »~ .Benzyl Alcohol .7643 .9668 ' (2675JD1,2-Dichlorobenzene 1.4463 1.4431 .222-«ethylphenol 1.5762 1.3685 13.18•bis.2-chloroisopropyl)Ether 3.5886 3.6799 2.544-Methylphenol 1.6185 1.4409 10.97N-Nitroso-Di-n-Propylamine 1.6338 1.4890/ 8.86 » «Hexachloroethane .6132 .6004 2.09Nitrobenzene .4481 .4225 5.72Isophorone .9214 .8599 6.682-Nitrophenol .2218 .2114 4.35 »2,4-DiBethylphenol .2888 .2761 4.40Benzoic Acid + .1515 .1896 (J5.12>bis(-2-Chloroethoxy)Methane .5247 .4881 8.492,4-Dichlorophenol .2792 .2788 .15 \S »1,2,4-Trichlorobenzene .2703 .2827 4.59Naphthalene .931>l .9257 1.004-Chloroaniline .4362 .3890 10.82Hexachlorobutadiene .1239 .1346 8.60 •' •4-Chloro-3-«ethylphenol .3546 .3228 8J8 - »2-Hethylnaphthalene .5401 .7776 (ffLJjbHexachlorocyclopentadiene .1819 .1789'' 1.66 * •2,4,6-Trichlorophenol . . .3160 .3457 9.41" » . - • - • •

:. 2,4,5-Trichlorophenol * .3715 .3629 2.312-Chloronaphthalene . - 1.8280 1.0809 5.15 — ,. '2-Nitroaniline * .5984 .5724 4.35Dimethyl Phthalate ' 1.2885 1.3079 1.51Acenaphthylene 1.5581 1.6398 5.243-Nitroaniline + .4159 .3885 6.59Acenaphthene 1.8164 1.0265 .99 V •2,4-Dimtrophenol + .1874 .1682' 14.49 « •4-Nitrophenol » .3482 .3138 -" 7.77 • »Dibenzofuran -- 1.4987 1.5379 2.62

RF50 - Response Factor froa daily standard file at SO - Percent Difference_ concentration indicated (50 total nanograms) . CCC- Calibration Check Compounds ( * )RF - Averaqe Response Factor from initial Calibration Fora UI SPCC - Systea Performance Check Coapounds ( » * )* - Due to low response, analyze at 80 total nanograas

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C O N T I N U I N G C A L I B R A T I O N C H E C KSemivolatile HSL Compounds

(Paqe 2)

Case No.: CASE [C£cl\ Reqion : !/** TlT Calibration Date-_*.___«.__ . «mf*n ' *^ T i •*

001102 H.flContractor : S - CUBED ' ""~" Time : 881102 13:47

Contractor No.: 680. -7261 Laboratory ID : >DCN02::02Instrument ID : .1CKP) Initial Calib Date : OCT 16 1988

Minimum RF for SPCC is 0.050 Maximum SO for CCC is 25* j

Compound RF RF58 • SO CCC SPCC2,4-Oinitrotoluene .5136 .4940 3.812,6-Oinitrotoluene .3647 .3691 1.21Oiethylphthalate 1.4026 1.2944 7.714-Chloropheny]-phenylether .4764 .4862 2.06Fluorene 1.1345 1.1558 1.88 .4-Nitroaniline + .4575 .3868 15.454,6-Dinitro-2-Methylphenol » .1322 .1489 12.66N-Nitrosodiphenylamine (1) .4263 .4600 7.90'/ «4-8romophenvl-phenyIether .1587 .1671 5.31Hexachlorobenzene .1742 .1753 .64Pentachlorophenol * .0959 .1070 11.60 • »Phenanthrene .9392 .9525 1.42Anthracene .9239 .9686 4.83Di-n-Butylphthalate 1.4930 1.4457 3.17Fluoranthene 1.0061 .9883 1.77 1/ *Pyrene 1.4198 1.3158 7.32Butylbenzylphthalate .9704 .8486 12.553,3'-Dichlorobenzidine .4380 .2767 (.36.84)Benzo(a)Anthracene 1.4096 1.2278 12.98bis(2-Ethylhexyl)Phthalate 1.4513 • 1.2794 . 11.84Chrysene . 1.0876 1.0818 .53Di-n-Octyl Phthalate 1.8797 1.8266 2.82" «Benzo(b)Fluoranthene 1.1458 1.0778 _ 1Benzo(k)Fluoranthene .6457 .8260 (27 95)Benzo(a)Pyrene .9071 .9274 2.23 • ...Indeno(l,2,3-cd)Pyrene .9992 .9982 .10Oibenzo(a,h)Anthracene .6567. .7447 13.39 . • . -.Benzo(g,h,i)Perylene - .8222 .8137 . 1.03 .

RF50 - Response Factor froa daily standard file at SO - Percent Difference_ concentration indicated (50 total nanograas) CCC - Calibration Cheek Coapounds ( > )RF - Average Response Factor from initial Calibration Fora UI SPCC - System Performance Check Compounds ( * * )+ - Due to low response, analyze at 88 total nanoqraas (1) - Cannot be separated from diphenylaaine

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AR30I91.7

0

i Satple Kuaber:CRS.iJ.IC3 ANALYSIS. DATA SHEET JWfeS.83 BLANK :

.rags 15 :....££.>........ :

Laboratory Na*e: S-CUSE3 £A(3 gcAru*. t- f/***'• • ) Case Ho: 10591Lata Saeple 1$ Kc: L3Y14 Woa) }L6MOCfi& 3C Report Ko: H.SSaapis Hatris: SATE?, fer So.lsftfCA fiOil 6j?£e) Contract Hoi eo-Ol-7261Data Release Authorized By: __W__ . . ' Date Satple Received: NR

VOLATILE COMPOUNDS •Concentration:(LOK) Medina (Circle One)Data Extracted/Trtpared: 10-14-93Date Analyzed: 10-14-38Conc/Sil Factor: J.O pH: H.RPercent Koisture (Not Decanted): H.R

CAS \ug/l/jr ug/kg CASNuiber .Circle One) Nuiber74-87-3 CHLQRGHE7KANE 10 U 7S-87-5 1,2-DICHlQRQPRQPANE74-93-9 BRDHO.JETHANE 10 U 1D061-02-6 TRANS-1,3-SICHLCRDP80P5NE75-01-4 VINYL CHLORIDE 10 U 79-01-6 TRICHLQRDETHEHE75-00-3 CHLOSDETHANE • 10 U 124-4B-1 D!BROKDCHLDRC«£THA!i£75-09-2 METHYLENE CHLORIDE 5 U 75-00-5 1,1.2-TRICHLQROETHAHEo7-64-l ' ACETONE 10 U 71-43-2 BENZENE75-15-0 • CARBON DISULFIDE 5U 10061-01-5 CIS-1,3-DICHLOROPRGPENE75-35-4 i.l-DICHLOROETHENE 5 U 110-75-8 2-CHLOROETHYLV1NYLE7HER75-34-3 1,1-DICHLORQETHANE 5 U 75-25-2 BROHOFORM156-60-5 TRANS-1,2-DICHLOROETHENE 5 U 591-78-6 2-HEXANONE«-6e-3 CHLOROFORM . 5 U 108-10-1 4-HETHYL-2-PENTANONE107-06-2 1,2-DICHLOROETHANE 5 U 127-18-4 - TETRACHLOROETHEKE78-93-3 2-BUTANONE 10 U 79-34-5 1,1,2,2-TETRACHLDRGETHAHE71-55-6 l.l.i-TRlCHLOROETHANE 5 U 10B-B8-3 TOLUENE56-23-5 CARBON TETRACHLORIDE 5 U 108-90-7 CHLOROBENZENE108-05-4 VINYL ACETATE 10 U 100-41-4 ETHYLBENZENE75-27-4 BROKODICHLOROMETHANE 5 U 100-42-5 STYRENE _ 5 U

" '. TOTAL XYLEKES ' '." : . ". 5 U ' .D»t» Reporting Bualifiers " "— " .

For reporting results to EPA, the following results qualifier are used. Additional flags or footnotesexplaning results are encouraged.However,the definition of each flag oust be explicit. •

Value: If the result is a value greater than or equal'to" the ' C This flag applies to pesticide parameters wheredetection liiit.report the value. the identification has been confined by BC/HS.Single

U Indicates coipound Nat analyzed for but not detected.Report coiponent pesticides > or * 10 ng/ul in the finalthe linitua detection liiit for the suple with the U (eg.lOU) extract should be confiraed by SC/MS.based on necessary concentration/dilution action, (this isnot necessarily the instnment detection liiit.)The footnotes B This flag is used when analyte is found in the blankshould read:U-Cospound was analyzed for but not detected.The as well as steple. It indicates possible/probablenuaber is the ainiiue attainable detection liiit for the sacple. blank contamination and warns the data user to take

J Indicates an estimated value:This flag is used either when appropriate action.estimating a concentration for tentatively identified cupoundswhere a 1:1 response is assueed or when the aass spectral data S Matrix spiked coapound.indicated the presence of a coipound that aeets the identificationcriteria taut the result is less than the specified detection litit a n O n j Q i obut greater than zero (eg 10J) .If limit of detection is 10 ug/L and H n O U I- 3 H <J .a concentration of 3ug/L is calculated.report as 33.

ol

Lab Name : S - CUBED I Sample Number 1Case No : CASE 10591 I LPB BLANK 10-141

ORGANICS ANALYSIS DATA SHEET *—————————*(Page 2)

Senivolatile Compoundsj

Concentration: Qou) tlediua (Circle One ) GPC Cleanup j__res _NoDate Extracted: UM4-83 Separatory Funnel Extraction _ YesDate Analyzed: . 10/26/88 18:21 -Cone/Oil factor: 1.50Percent Moisture ( Decanted ) N.A.

Continuous Liquid-Liquid Extraction __Yes.-~-

C.A.S. • uq/L or Jo/Kq '. C.A.S. uq/L or(uq/KiNumber : (Circle One) \ Number (Circle One."

108-95-2 Phenol ' 500. U • ' 83-32-9 ftcenaphthene 500. UUl-44-4 bis(-2-Chloroethyl)Ether 500. U 51-28-5 2,4-DinitrophenoI 2500. U95-57-8 2-Chlorophenol 500. U 100-02-7 4-Nitrophenol 2500. U541-73-1 1,3-Dichlorobenzene 50B. U 132-64-9 Dibenzofuran 500. U106-46-7 1,4-Dichlorobenzene 500. U ' 121-14-2 2,4-Dinitrotoluene 500. U100-51-6 Benzyl Alcohol 500. U 606-20-2 2,6-Oinitrotoluene 500. U95-50-1 1,2-Dichlorobenzene 500. U ' 84-66-2 Diethylphthalate 500. B95-48-7 2-HethyIphenol 500. U 7005-72-3 4-Chlorophenyl-phenylether 500. U

39638-32-9 bisC2-chloroisopropyl)Ether 500. U 86-73-7 Fluorene 500. U106-44-5 4-flethyiphenol 500. U 100-01-6 4-Nitroaniline 500. U621-64-7 N-N5troso-Di-n-Propylamine 500. U 534-52-1 4,6-Dinitro-2-Methylphenol 2500. U67-72-1 Hexachloroethane 500,. U 86-30-6 N-Nitrososdiphenylaaine (1)' ™ 500. U98-95-3 Nitrobenzene 500. U 101-55-3 4-Bromophenyl-phenylether 500. . U78-59-1 Isophorone 500. U 118r74-l Hexachlorobenzene 500. U88-75-5 2-Nitrophenol 500. U 87-86-5 Pentachlorophenol 2500. U105-67-9 2,4-Dimethylphenol 500. U 85-01-8 Phenanthrene • 500. U65-85-0 Benzoic Acid 2500. U 120-12-7 Anthracene 500. U111-91-1 bis(-2-Chloroethoxy)«ethane 500. U 84-74-2 Di-n-Butylphthalate 500. U120-83-2 2,4-Dichlorophenol 500. U 206-44-0 Fluoranthene 500. U120-82-1 1,2,4-Trichlorobenzene 500. U 129-00-0 Pyrene 500. U91-20-3 Naphthalene ' 500. U .85-68-7 Butylbenzylphthalate ' 500/ U106-47-8 4-Diloroaniline 500. U 91-94-1 .,3'-Dichlorobenzidine ' 1000." U87-68-3 Hexachlorobutadiene 500. U 56-55-3 Benzo(a)Anthracene • 500. • U59-50-7 4-Chloro-3-Hethylphenol 500. U 117-81-7 bis(2-Ethylhexyl)Phthalate 500. U91-57-6 2-Hethylnaphthalene 500. U 218-01-9 Chrysene _____ 500. U77.47-4 Hexachlorocyclopentadient 500. U • 117-84-0 Di-n-Octyl Phthelate 500.' U88-06-2 2,4,6-Trichlorophenol 500. U 205-99-2 Benzo(b)Fluoranthene 500. U95-95-4 2.4,5-Tr.chlorophenol 2500. U 207-08-9 BenzoddFluoranthene 500. U91-58-7 2-ChIoronaphthaIene 500. U 50-32-8 BenzoCaJPyrene 500. U88-74-4 2-NitroaniIine 2500. U 193-39-5 Indeno(l,2,3-cd)Pyrene 500. U131-11-3 Dimethyl Phthalate 500. U 53-70-3 Dibenzo(a,h)Anthracene 500. U208-96-8 Acenaphthylene 500. U 191-24-2 Benzo(g,h,i)PeryIene .00. U99-09-2 3-Nitroaniline 2500. U -

(l)-Cannot be separated froa diphenylamine

Fora 1 . 7/85

Laboratory Naae: S-Cubed Sacple NuaberCase Ho.: 10591 LAB BLANK L

ORSANICS ANALYSIS DATA(Page 3)

Pasticide.PCBs

Concentration: LOH SPC Cleanup _Yes ^NQ —---—---.Date Extracted/Prepared: 10-18-88 Separatary Funnel Extraction _YesDate Analyzed: 11-01-B8 Continuous Liquid-Liquid Extraction _YesConc/Dii Factor: 1.00

CAS tNuiber319-84-4 ALPHA-3HC319-B5-7 BETA-BHC319-36-8 DELTA-BHC58-89-9 SAMA-8HC (LINDANE)76-44-B HEPTACHLDR309-00-2 ALDRIN1024-57-3 HEPTACHLOR EPOXIDE959-98-B ENDOSULFAN 160-57-1 DIELDRIN72-55-9 4,4'-DDE72-20-B ENDRIN33213-65-9 ENDOSULFAN II72-54-B 4.4'-DDD7421-93-4 ENDRIN ALDEHYDE1031-07-8 ENDDSULFAN SULFATE50-29-3 4,4'-DDT72-43-5 HETHOXYCHLD'R53494-70-5 ENDRIN KETONE57-74-9 CHLDRDANE8001-35-2 TOXAPHENE12674-11-2 AROCLDR-101611104-28-2 AROCLOR-122111141-16-5 AROCLOR-123253469-21-9 AROCLOR-124212672-29-6 AROCLOR-124B11097-69-1 AROCLOR-125411096-82-5 AROCLOR-1260

Voluai of water extracted (•!): K.A.Height of saiple extracted (g): 30.0Voluit of total extract (•!): 10,00Voluie of extract injected (ul)t 1.00

Fori I 7/85 REV.

« COMFIRMEB BY GC DUAL COLUIW CONFIRMATION « *» 3 0 I 9 5 0

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AR30I95I

: Sample Number:ORGANICS ANALYSIS DATA SHEET LAB BLANK :

(Page 1) :................ :

Laboratory Name: S-CUBED . Case No: 10591Lab Sample ID No: LB017 (Voa) _! fiC Report No: N.RSample Matrix: HATER -Vf **£** (VOfr) Contract No: 68-01-7261Data Release Authorized By: Kj Date Sample Received: NR

VOLATILE COMPOUNDSConcentration:/Lo7\ Medium (Circle One)Date ExtractedVf^ared: 10-17-38Date Analyzed: 10-17-88Conc/Dil Factor: 1.0 pH: N.RPercent Moisture (Hot Decanted)': N.It

CAS (jjg/j)or ug/kg CASNumber (Circle One) Number74-87-3 CHLOROMETHAHE 10 U 78-87-5 1,2-DICHLOROPROPANE74-83-9 BROHGMETHANE 10 U 10061-02-6 TRANS-1,3-DICHLOROPROPEJiE75-01-4 VINYL CHLORIDE 10 U 79-01-6 TRICHLOROETHENE75-00-3 CHLOROETHANE 10 U 124-48-1 DIBROMOCHLORDHETHANE75-09-2 METHYLENE CHLORIDE 4 J 79-00-5 1.1,2-TRICHLOROETHANE67-64-1 ACETONE 10 U 71-43-2 BENZEHE75-15-0 CARBON DISULFIDE 5 U . 10061-01-5 CIS-1,3-DICHLOROPROPE)IE75-35-4 1.1-DICHLOROETHEJE 5U 110-75-B 2-CHLOROETHYLV1JIYLETHER75-34-3 1,1-DICHLOROETHAHE 5 0 75-25-2 BROMOFORM156-60-5 TRANS-1,2-DICHLORflETHEie 5 U 591-78-6 2-HEXAHOHE67-66-3 CHLOROFORM 5 U 108-10-1 4-«£THYL-2-PENTflNOHE107-06-2 1,2-DICHLORDETHANE 5 U 127-13-4 TETRACHLOROETHENE78-93-3 2-BUTANOHE ' ..... 10 U 79-34-5 1,1,2,2-TETRACHLOROETHANE71-55-6 1,1,1-TRICHLORDETHANE 5 U 108-88-3 TOLUENE56-23-5 CARBON TETRACHLORIDE 3 U 108-90-7 CHLQROBENZENE10B-05-4 VINYL ACETATE 10 U 100-41-4 ETHYLBENZENE75-27-4 BRDHODICHLORQMETHAHE 5 U 100-42-5 STYRENE

TOTAL IYLENES "Data Reporting Qualifiers

For reporting results to EPA, tbc following results qualifier are used. Additiosal flags or footnotes —-"•explaning results are encouraged.Ho«ever,the definition of each flag lust be explicit. . V f. *•

Value: If the result is > value greater than or equal to the C This flag applies to pesticide parameters"wheredetection limit,report the value. the identification has been confirmed by GC/MS.Single

U Indicates compound was analyzed for fait not detected.Report component pesticides > or * 10 ng/ul ia the finalthe minimum detection limit for the sample with the U (eg.1011) extract should be confirmed by 6C/MS. - •based on necessary concentration/dilution actiom.Uhis isnot necessarily the instrument detection limit.)The footnotes B This flag is used when analyte is found in the blankshould reid:lKoipound MS analyzed for but not detected,The as Nell as sample. It indicates possible/probablenumber is the minimum attainable detection limit for the sample. blank contamination and darns the data nstr to takt

i Indicates an estimated valoe:This flag is used either when appropriate action.estimating a concentratiom for tentatively identified compoundswhere a hi response is assumed or when the mass spectral data S Matrix spiked compound.indicated the presence of a compound that meets the identificationcriteria but the result is less than the specified detection limit A D Q n t n r- obut greater than zero (eg 10J) .If limit of detection is 10 ug/L ind H ft 0 U I :? J £a concentration of 3ug/L is calculated.report as 34.

. J.t • >

•si•1• *,;•i.ji * ?• i

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AR30I953

85

: Sample Nuabsr:DRSANICS ANALYSIS DATA SHEET ' LAB BLANK : ',

(Page 1) :................ :

Laboratory Name: S-C'JEED Case No: 10591Lab Eaapie ID Ho: L2104 (Voa) ;LBn00WW) QC Report Not N.RSample Matrix: HATER a0 *'0~'?<'r'':>VContract No: sB-01-7261Data Release Authorized By: Jhr.L___ . Date Saaple Rscsived: NR

VGLAnj= COMPOUNDSConcentration/Loy Medium (Circle One)Date Estr3ctfid/.Taparid: 10-14-33Date Analyzed: 10-14-38Conc/Dil Factor: 1.0 pH: N.R \Percent Moisture (Not Decanted): N.R '

CAS (Wpor ug/kg CAS (ug/l)or ug/kgNumber (Circle One) Number TCTrcle One)74-87-3 CHLORGMETHANE 10 U 73-37-5 1,2-DICHLOROPROPANE 5 U74-33-9 BfiOMOMETHANE 10 U 10061-02-5 TRANS-1,3-DICHL38GPROPEKE 5 U75-01-4 VINYL CHLORIDE 10 U 79-01-6 THICHLOROETHEHE 5 U75-00-3 CKLOROETHANE 10 U 124-43-1 DIBRQMQCHLORDKETHANE 5 U75-.9-2 METKYLENE CHLORIDE 6 79-00-5 1,1,2-TRICHLOP.OETHANE 5 U67-64-1 ACETONE 10 U 71-43-2 BENZENE 5 U75-15-0 CARBON BISULFIDE 5 U 10061-01-5 CIS-1,3-DICHLORGPROFENE 5 U75-35-4 1,1-DICHLORGETHENE 5 U 110-75-8 2-CHLGROETHYLV1NYLETHER 10 U75-34-3 1,1-DICHLOROETHANE 5U 75-25-2 BROMGFORM ._; 5 U156-60-5 TRANS-1,2-DICHLGRDETHENE 5 U 591-73-6 2-HEXANONE 10 U57-66-3 CHLOROFORM 5 U 108-10-1 4-METHYL-2-PENTANQNE 10 U107-06-2 1,2-DICHLOROETHANE 5 U 127-18-4 TETRACHLOROETKENE 5 U78-93-3 2-BUTAHONE 10 U 79-34-5 1,1,2,2-TETRACHLORGETHANE 5 U71-55-6 1,1,1-TRICHLGROETHANE 5 U 108-88-3 TOLUENE 5 U56-23-5 CARBON TETRACHLORIDE 5 U 109-90-7 CHLORQBENZENE 5 U108-05-4 VINYL ACETATE 10 U 100-41-4 ETHYLBEHZENE 5 U75-27-4 BROMQD1CHLOROHETHANE 5 U 100-42-5 STYRENE 5 U .

TOTAL XYLENES —'• - 5 U ™- - -~.---"Data Reporting flualifiers - - -:- . •_•• .— ••

For reporting results to EPft. the following results qualifier are used. Additional flags or footnotes"": . ..,.•;'explaning results are encouraged.However,the definition of each flag must be explicit. . .;... ...

Value: If the result is a value greater than or equal to the C This flag applies to pesticide parameters wheredetection limit,report the value. the identification has been confirmed by SC/HS.Single

U Indicates compound MS analyzed for but not detected.Report component pesticides > or * 10 ng/ul in the finalthe minimum detection limit for the sample with the U (eg.iOU) extract should be confirmed by EC/MS.based on necessary concentration/dilution action.(this isnot necessarily the instrument detection limit.JThe footnotes B This flag is used when analyte is found in the blankshould read:U-Compound was analyzed for but not detected.The as well as sample. It indicates possible/probablenumber is the minimum attainable detection limit for the sample. blank contamination and warns the data user to take

J Indicates an estimated value:This flag is used either when appropriate action.estimating a concentration for tentatively identified compoundswhere a 1:1 response is assumed or when the mass spectral data S Matrix spiked compound.indicated the presence of a compound that meets the identificationcriteria but the result is less than the specified detection limitbut greater than zero (eg 10J) .If limit of detection is 10 ug/L and anona concentration of 3ug/L is calculated,report as 33. H R 3 0 I 9 5 fy

+——•_•.•_ ••»•*••« +

Lab Name : S - CUBED I Sample Number ICase No : CASE 10591 I LAB BLANK 10-/71

ORSANICS ANALYSIS DATA SHEET +—————————+(Paqe 2)

Semivolatile Compoundsj /

Concentration: ^o^ Hediun (Circle One ) GPC Cleanup _ Yes l_ NoDate Extracted: 10-17-88 Separat'ory Funnel Extraction _ Yes sDate Analyzed: 10/28/88 11:36 Continuous Liquid-Liquid Extraction i YeCone/Oil Factor: 1.00

' Percent Moisture ( Decanted ) N.A.

C.A.S. ^ug/Uor ug/Kq. C. ..S. uq/Ls _Nuaber CCTfrcle One) Nuinber \ CStfcle (Sie

108-95-2 Phenol 10. U 83-32-9 Acenaphthene 10. UHl-44-4 bis(-2-ChloroethyI)Ether 10. U 51-28-5 2,4-Dinitrophenol 50. U95-57-8 2-Chlorophenol 10. U 100-02-7 4-Nitrophenol 50. U541-73-1 1,3-Oichlorpbenrene 10. U 132-64-9 Dibenzofuran 10. U106-46-7 1,4-Dichlorobenzene 10. U 121-14-2 2,4-Dinitrotoluene 10. U100-51-6 Benzyl Alcohol 10. U 606-20-2 2,6-Dinitrotoluene 10. U95-50-1 1,2-Dichlorobenzene 10. U 84-66-2 Diethylphthalate 10. tl95-48-7 2-Methylphenol 10. U 7005-72-3 4-Chlorophenyl-phenylether 10. U

39638-32-9 bis(2-chloroisopropyl)Ether 10. U 86-73-7 Fluorene 10. U106-44-5 4-Methylphenol 10. U 100-01-6 4-Nitroaniline 10. U621-64-7 N-Nitroso-Di-n-propylamine 10. U 534-52-1 4,6-Dinitro-2-«iethylphenol 50. U67-72-1 Hsxachloroethane 10. U 86-30-6 N-Nitrososdiphenylaaine (1)' 10. U98-95-3 Nitrobenzene 10. U 101-55-3 4-Broaophenyl-phenylether 10. U

• 78-59-1 Isophorone 10. U 118-74-1 Hexachlorofaenzene 10. U88-75-5 2-Nitrophenol 10. U -87-86-5 Pentachlorophenol 50. U105-67-9 2,4-Diaethylphenol 10. U 85-01-8 Phenanthrene 10. U65-85-0 Benzoic Acid 50. U 120-12-7 Anthracene 10. U111-91-1 bis(-2-Chloroethoxv)ttethane 10. U 84-74-2 Di-n-Butylphthalate 10. U120-83-2 2,4-Oichlorophenol 10. I) 206-44-0 Fluoranthene 10. U120-82-1 1,2,4-Trichlorobenzene 10. . U 129-00-0 Pyrene 10. U91-20-3 Naphthalene - 10. U 85-68-7 Butylbenzylphthalate 10. U106-47-8 4-Chloroaniline 10. U . 91-94-1 3,3'-Dichlorobenzidine 20. U87-68-3 Hexachlorobutadiene II. U 56-55-3 Benzo(a)Anthracene 10. U59-50-7 4-Chloro-3-aethylphenoI ' 10. U 117-81-7 bistt-EthylhexyDPhthalate IB. U'91-57-6 2-Hethylnaphthalene 10. U 218-01-9 Chrysene 10. U77-47-4 Hexaehlorocyclopentadiene U. U 117-84-0 Di-n-Octyl Phthalate 10. U88-06-2 2,4,6-Trichlorophenol 10. U 205-99-2 Benzo(b)Fluoranthene 10. U95-95-4 2,4,5-Trichlorophenol 50:. U 207-08-9 Benzo(k)Fluoranthene 18. U91-58-7 2-Chloronaphthalene 10. U 50-32-8 Benzo<a)Pyrene 10. U88-74-4 2-Nitroaniline 5&. U 193-39-5 Indeno(l,2,3-cd)Pyrene 10. U131-11-3 Diwsthyl Phthalate 10. U 53-70-3 Dibenzo(a,h)Anthracene 10. U208-96-8 Acenaphthylene 10. U 191-24-2 Benzo(g,h,i)Perylene 10. U99-09-2 3-Nitroaniline 50. U -

(D-Cannot be separated from diphenylaaine

Fort 1 . 7/85

AR30I955'

Laboratory Name: S-Cubed Sample NumberCase No.: 10591 LAB BLANK 10-17

ORBANICE ANALYSIS DATA(Page 3)

; Pesticide/PCBsi

Concentration: M LOW . . . - - . . . . BPC Cleanup _Yes jfato - •• -.Date Extracted/Prepared: 10-18-38 Separalory Funnel Extraction_Yes ,Date Analyzed: \ 1 11-01-88 ' Continuous Liquid-Liquid Extraction J_YesConc/Dil Factor: i i 1.00

CAS I • , — fug/l^r ug/KgNuaberl \ VJxICircle One)319-84-6 ALPHA-BHC 0.050 u319-85-7 BETA-BHC • 0.050 u319-85-8 DELTA-BHC 0.050 u58-89-9 6AMHA-BHC (LINDANE) 0.050 u76-44-8 HEPTACHLOR 0.050 u309-00-2 ALDRIN 0.050 u1024-57-3 HEPTACHLOR EPDX1DE 0.050 u959-98-8 ENDOSULFAK I 0.050 u60-57-1 DIELDRIN ' 0.10 u72-55-9 4,4'-DDE 0.10 u72-20-8 ENDRIN 0.10 u33213-65-9 ENDQSULFAN II 0.10 u72-54-8 4,4'-ODD 0.10 u7421-93-4 EHDRIK ALDEHYDE - ' 0.10 u1031-07-8 ENDOSULFAH SULFATi 0.10 u50-29-3 4,4'-DOT 0.10 u72-43-5 HETHOIYCHLQR 0.50 u53494-70-5 ENDRIH KETOHE 0.10 u57-74-9 CHLDROAHE - 0.50 u8001-35-2 TOXAPHENE 1.0 u12674-11-2 AROCLDR-1015 • . • __ .- 0.50 u11104-28-2 AROCLOR-1221 " - •• - 0_50 u11141-16-5 AROCLOR-1232 -". " ". ' 0.50 u53469-21-9 AROCLOR-1242 ' 0.50 B12572-29-6 AROCLOR-1248 • ' 0.50 u11097-69-1 ARQCLOR-1254 _ 1.0 u11096-82-5 AROCLOR-1260 " ' 1.0 u

Volume of Mater extracted (ml): 1000'Height of sample extracted ig): N.A.VoluH of total extract Ul): 10.00Volume of extract injected (ul): 1.00

Form I 7/85 REV."•.

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AR30I957

85

_J) U v& -

Ar-i-i33.v^3.s. = 3 SXXO31r14ylReported on 31-Oct-88 at 22:02

P336VQ TRASH

Analyst Name :FT Analysis ID: HP 5890IIIInformation :CLP STANDARDS RUN

CLP PESTICIDES" ANALYSIS HP58.0III SP2250/2401 ,1 UL INJi

Channel:3 Title: CHANNEL 3 Date 31-Qct-S8 Time 21:23Analysis:ST1031 Sample Name:MATRIX Sample ID: 14 Bottle:!Sample 14 Injection 1 i

Peak R/I m. Fight uV Area uVs ng/sl Identity RF slope RF intercept1 0.471 253983 923876 0.0000 \2 0.836 1619 6102 0.00003 0.951 1391 6817 0.0000 \4 1.253 463 25SO 0.0000 \5 1.502 1057 5391 0.00006 1.751 770 6960 0.00007 2.018 1732 11990 0.00008 2.676 36799 250702 10.7643 2 G-BHC 2.329023E+04 O.OOOOOOE+009 3.271 35910 306009 10.7063 4 HEPMCHLOR 2.858200E+04 O.OOOOOOE+0010 3.929 25476 253476 10.4617 6 ALDRIN 2.422886E+04 O.OOOOOOE-W11 8.791 29913 627362 26.7061 10 DIELDRIH 2.349132E+04 O.OOOOOOE+0012 10.622 17198 434341 23.1165 11 ENDRIN 1.878922E+04 O.OOOOOOE-KW13 14.889 9818 343052 25.5578 14 DDI 1.342260E+04 O.OOOOOOE+00

Residual 0 0 0.0000Total 416127 3178629 107.3128

Sample Type: SA Scale Factor: 1.000 Amount: 1.000Method: CLP Calibration: PEST Type: ES Usins:AreaUC type: UC factor (= 0.0000)

AR30I958

Reported on 31-Oct-SS at 21:25

VG TRASH

Analyst Name : FT Analysis ID: HP 5890IIIInformation :CLP STANDARDS RUN

CLP PESTICIDE ANALYSIS HP33.0 III SP2100, luL INJi

Channel:2 Title: CHANNEL 2, Date 31-Oct-88 Time 20:4&Analysis:ST1031 | Sample, Name:MAIRIX Sample ID: 14 Bottle:!Sample 14 Injection 1

Identity RF slope RF interceptPeak R/I m. Hsht u. Area uVs no/ml1 0.738 201398 945493 0.00002 1.760 2211 16273 0.00003 2.151 394 2899 0.0000 \4 2.489 263 2038 0.0000 \5 2.773 425 2892 0.00006 3.547 33239 219972 7.4052 4 G-BHC ' 2.970495E+04 O.OOOOOOE+007 4.231 453 4547 0.00008 5.533 30199 341482 11.5228 5 HEPTACHLOR 2.963523E+04 O.OOOOOOE+009 6.782 18579 244513 10.2048 6 ALDSIN 2.396066E+04 O.OOOOOOE+0010 11.653 29798 672456 26.9638 10 DIELDRIH 2.493925E+04 O.OOOOOOE+0011 12.969 17400 449377 24.4578 11 ENDRIH 1.837355E+04 O.OOOOOOE+0012 14.427 3513 155726 6.1608 14 ENDRIN ALD. 2.527706E+04 O.OOOOOOE+0013 18.498 10137 354643 28.3622 16 DDT 1.250409E+04 O.OOOOOOE+0014 21.404 1205 49904 0.0000

Residual 0 0 0.0000Total 349214 3462220 ' 115.0773

Sample Type: SA Scale Factor: 1.000 Amount: 1.000Method: CLP Calibration: PEST Type: ES Usiri3:AreaUC type: UC factor <= 0.0000) *

AR30I959

S~CUBEDA Division of Maxwell Laboratories, Inc.

March 16,1989

Mr. Nicholis KourlickRoyF. Weston,Inc.ESAT Team, Suite 3002568 Riva RoadAnnapolis, MD 21401

Mr. Kourlick:

In reference to your phone call of 03/13/89,1 have rechecked pesticide calculations for Case 10591. Thecalculations for the EVAL A,B, and C checked out correct as originally submitted. The concentrations inthe EVAL mixtures are as follows:

A (ppb) B (ppb) C(ppb)Aldrin 5 25 50Endrin 15 75 150DOT 18 90 180DEC 25 125 250

Calibration factors are calculated by dividing the area response of the appropriate compound by theamount injected on column (i.e., 5 ng for aldrin in EVAL A, since 1 mL was injected).

I have checked how the matrix calculations were performed and found that the recoveries were calculatedbased on the analysis of the actual matrix spiking solution. This percent recovery was then used tocalculate the amount in the sample suing the matrix solution as a calibration standard. For example, thecalculation of lindane in water sample CY757MS and soil sample CY758MSD is as follows:

Area Lindane Sample: 208639 cts. ___ _— * - = 95% RecoveryArea Lindane Matrix Solution: 219972 cts

The sample was spiked with 1 mL of a 0.1-mg/mL solution. Since the spike level was 0.2 mg/L thiscalculates to be 0.19 mg/L in CY757MS. (500 mL was extracted not 1 liter.)

For soil sample CY758MSDP:

_____Area Lindane Sample: 171868 cts.Area Lindane Matrix Solution: 219972 cts = 78% Recovery

The 30-g aliquot was spiked with 2 mL of a 0.1-mg/mL solution. Since the spike level was 7.4 ing/Kg(corrected for percent moisture) this calculates to be 5.8 mg/Kg dry weight in the sample.

AR301960P.O. Box 1620. La Jolla. California 92038-1620 3398 Camel Mountain Road, San Diego. CaUfomia 92121-1095

Tel: (619) 453-0060 TWX: 910-337-1253 Telecopier: (619) 755-0474

Mr. Nicholis KourlickMarch 16,1989Page Two

•' . ' i • • •I have emphasized to the GC analysts that the analytical protocol is that the amount of the spikedcompounds found in the matrix samples will be calculated from the standards in the 72-hour run sequence.The amount spiked can be calculated from analysis of the spiking solution in order to assure trial anaccurate 100% recovery value is known for Form III. It is not appropriate'to e.ssume that the amountspiked is actually 0.2 Mg/L in this specific instance and then back calculate the amount from the recoveryvalue. .. . . . ' . . " ^ . ' A.. _

\ iIf you have more questions, please feel free to call me and I will attempt to further clarify this response.

Sincerely, .

MrvnJoAnn WilkinsonProject Manager

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cc: D. ArmstrongF. Tsang

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