SFUND RECORDS CTR 88015257 SFUND RECORDS CTR AR0556 … · 2018-01-23 · a\ analyticaltechnologies, sfund records ctr 88015257 inc sfund records ctr 0222-00704 ar0556 quality control

A \ AnalyticalTechnologies,

SFUND RECORDS CTR

88015257

Inc SFUND RECORDS CTR

0222-00704 AR0556

QUALITY CONTROL DATA

TEST : VOLATILE ORGANICS (EPA 624)

CLIENT PROJECT # PROJECT NAME

MONTGOMERY & ASSOCIATES 661D HASSAYAMPA

ATI I.D.

REF. I.D. DATE ANALYZED SAMPLE MATRIX UNITS

806130

80799902 06/28/88

UG/L

COMPOUNDS

DUP. DUP. SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC. RPD

1,1-DICHLOROETHENE TRICHLOROETHENE CHLOROBENZENE TOLUENE BENZENE

ND 45 ND ND ND

50 50 50 50 50

55 92 56 51 53

110 94 112 102 106

57 91 54 55 53

114 92 108 110 106

2 ^ Chrn-io:+o^(-

J^2^ T^i^-^uA

RIC eib/23/88_ 15; 13: DLI SAMPLE: JOB 856111-1 tl5D COMDS.: J X I RH.NGE: G 1.1200 LABEL: N e.. 4 .0

DrtTrt: 80£l l l l t1bCi «1 C H L I : SGbl l l lHSD #2

bCAMi 1 TO 12D6

QUHN: H y.. 1.0 J U BH5E: U

180.0-1

RIC

Cl

-̂ o u. o ^

Q l:J - T -

01 •—* z

o n T o -0 T - i

CD GC V

CD CC " V

O

1 -< a u

3b

1 ^ 1̂

J 1 J

4."SO

J

b03

L .^ ' -

637

760 i

I

Jl

S24

J

94;

yy?

^02 (

Jlj — \

\ \.

bOU 300 26:40

1000 33:20

1200 SCAÎ I 40:08 TIME

PROCEDURE DATA FILE REFERENCE NAME LIST

REPORT

DIAGNOSTIC F^EPOFrr TCA 8061111MSD 8061111MSD VQN INITIALIZATION GPTION: VQSTDS

6/28/88 15: 5G: 4!

PROCESSING GPTION: 3

STANDARDS >< PLUS UNKNOWNS — - LIST NAMES -PROC USED POSS RMS PROC USED POSS

4

/-* 0

NG 1 2 3 4 5 6 7 8 9 10 11 12 13 ' A .5 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 10 41 42

6 6 6

6 6 6

2 COMPOUNDS

OMPGUND >< LIB VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ

ENTRY 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

1 1 1

36 36 36

; PROCESSED,

— — — REF

-300 -608 -75Q -382 -721 -902 -54 -85

-107 -137 -203 -222 -252 -286 -326 -346 -363 -385 -382 -424 -436 -438 -450 -686 -491 -499 -515 -534 -537 -531 -537 -570 -616 -631 -678 -687 -727 -762 -824 -947 -987 -956

PRED 300 608 758 382 721 902 54 85 107 137 203 222 252 286 326 346 363 385 382 424 436 438 450 686 491 499 515 534 537 531 537 570 616 631 678 687 727 762 824 946 986 955

18 18 18

17 1 17 6 18 60

40 FOUND

_ CC" A — btA SEL 300 608 758 382 721 901

86 107 138 204 222 252 286 325 346 363 384 383 424 436 438 450 686 491

515 534 537 531 537 570 616 631 679 687 727 761 824 946 986 956

RCH -DELTA PEAKS

-1 1 , , 1 1

1 1 1 1

-1 1

-1 1 1 1

-

2

"̂

1 1

1 1 5 3 2

1 2

54 VQSTDS/VQl 30 VQSTDS/VQ2 46 VGSTDS/VQ3

"•..'• O A T *•••'" .y

Qu.antitation Report File: 806n,llMSb

Data: 8061111MSD. TI 06/28/88 15:18:00

pie: JOB 806111-1 MSD L̂ .ids, : GC4 Formula: Instrument: 1050 Weight: 0,003 Submitted by: Analyst: MGB Acct. No. :

AMOUNT=AREA * REF AMNT/(REF AREA * RESP FACT) Resp fac. from Library Entry

BROMOCHLOROMETHANE 1,4-DIFLUGRGBENZENE CHLGRaBENZENE-D5 DICHL0R0ETNANE-D4 T0LUENE-D8 BROMOFLUGRGBENZENE CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE ^ CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1.l-DICHLOROETHENE 1, l-DICHLORGETHANE TRANS-li 2-DICHLORaETHENE CHLOROFORM 1,2-DICHLOROETHANE 2-BUTAANONE 1,1/1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1, 1,2, 2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLGROPRGPANE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1.3-DICHLOROPRaPENE 2-CHLOROETHYL VINYL ETHER BROMOFORM 4-METHYL-2-PENTANaNE , 2-HEXANONE TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

42 XYLENES

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 * 1 3

19 20 21 22 23 24 25 26 . 27 2S 29 30 31 32 33 34 35 36 '37 38 39 40 41

Name ISl IS2 ISS SSI SS2 SSS 45V 46V 88V 16V 44V 13H 15H 29V 13V 30V 23V IOV 14H U V 6V 19H 48V 15V 32V 33VT 87V 51V 14V 4V

33VC 19V 47V 17H 16H 85V 86V 7V

38V 18H 20H

No 1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 IB 19 20 21 22 23 24 25 26 27 -̂ 8

7

30 31 32 33 34 35 36 37 38 39 40 41 42

m/ z 128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75

130 129 97 78 75 63 173 43 43

164 92 112 106 104 106 106

Scan 300 608 758 382 721 902 53 86 107 138 204 222 252 286 325 345 363 385 383 424 435 438 450 686 492 499 515 534 537 531 537 570 616 631 679 687 726 762 824 947 986 955

Time 10: 20: 25: 12: 24; 30: 1: 2; 3: 4: 6: 7; 8: 9:

10: 11; 12: 12: 12; 14; 14: 14: 15: 22: 16 16 17-17 17 17 17 19 20 21 22 22 24 25 27 31 32 31

00 16 16 44 02 04 46 52 34 36 48 24 24 32 50 30 06 50 46 08 30 36 00 52 24 38 10 4G 54 42 54 00 32 02 38 54 12 24 28 34 • 52 50

Ref 1 2 3 1 3 3 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3

1, 1. 1. 1. 0. 1, 0. 0, 0. 0 0. 0. 0. 0. 1, 1, 1, 1, 0. 0. 0. 0, 0, 1. 0. 0. 0, 0 0. 0. 0 0 1 0 0 0 0

RRT 000 000 000 273 951 190 177 287 357 460 680 740 840 953 083 150 210 283 630 697 715 720 740 128 809 821 847 878 883 873 883 937 013 832 896 906 950 005 0Q7 249 301 260

Me A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A

th DB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BD BB VB BB BB BB BB BB BB BB VB BB BB BB BB BB BB BB BB BB BB BB BB BB

AreaiHght) 52150.

321257. 238703 117865 327601 192412

5160. 75546. 14U78, 37602. 76959. 17862.

129712. 78352.

153866. 797S6.

189744. 128806

6251. 111671, 95985. 145392, 166102. 156424.. 123318. 165177. 187943. 106735. 103224. 284624. 57002. 14434, 534 58,

101648. 66066.

105451. 212G85, 24612.7, 108158. 461776. 241124, 115898.

Amount 50. 000 50. 000 50, 000

104, 903 100. 984 102 753 13. 381 51. 643 IB. 887 52. 459 50. 384 52. 576 46. 672 56. 786 57. 412 54. 084

55. aoo 57. 557 74. 678 60. 949 52. 703 62. 163 57. 008 56, 708 58. 112 56 510 90. 633 55. 855 58. 170 53. 472 58. 400 23. 491 55 238 67. 318 72. 645 58. 804 55, 4Q3 53. 516 49. 916

124. 841 100, 968 47. 219

UG/L UG/L UG/L 7. 7. 7. UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UQ/L UG/L UG/L UG/L UG/L UG/L

7.Tot 1. 98 1. 98 1. 98 4. 14 3. 99 4 06 0, 53 2. 04 0. 75 2. 07 1. 99 2. 08 1. 84 2. 24 -^ 2. 27 2. 14 2. 20 2, 27 2, 95 2, 41 2. 08 2. 46 2. 25 2. 24 2 30 2. 23 3. 58 • 2. 21 2. 30 2. 11 y 2. 31 0. 93 2. 18 2, bb 2. 87 2. 3 2 , / 2. 19',/ 2. 11 ̂ 1, 97 4. 93 3, 99 1. 87

I J 7 7 ->nuJ-'7LLAl

30611111'13 ttl 06111 IMS S2

RIC UHTH:

0b/2S/£S 14:27:00 CALI: SAMPLE: JOB 306111-1 MS W STDMIX 250!

PRUCEDURE DATA FILE REFERENCE NAME LIST

REPORT

2 —

TCA 806111 IMS 806111 IMS VQN

DIAONLI.'STIL

INITIALIZATION VQSTDS

— STANDARDS PROC USI

4

r KJ

NO 1

3 4 5 6 7 8 9

10 1 1 12 13 ^4

}

16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 0

-+1 42

6 6 6

ED POSS 1 6 6 6

2 COMPOUNDS

GMPOU ND >< LIB ENTRY VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

5 1 1

— ~7 ^Z ^MS 56 56 56

i PROCESSED,

REF -300 -608 -758 -382 -721 -902 -54 -85

-107 -137 -203 -222 -252 -286 -326 -346 -363 -385 -382 -424 -436 -438 -450 -686 -491 -499 -515 -534 -537 -531 -537 -570 -616 -631 -678 -687 -727 -762 -824 -947 -987 -956

PRED 300 608 758 382 721 902 54 85

107 137 203 222 252 286 326 346 363 385, 382' 424 436 438 450 686 491 499 515 534 537 531 537 570 616 631 678 687 727 762 824 947 987 956

OPTION

RLPOKT

: 2

PLUS UNKNOWNS PROC

18 IB 18

USED 17 17 IB

40 FOUND

C C A — — O t H

SEL 300 609 759 3B2 721 902

86 107 13B 204 221 252 287 325 346 363 385 383 4 24 436 439 451 686 492

515 534 V)37 t731

537 570 616 632 679 6B7 727 761 825 948 987 956

RCH -DELTA

1 1

1

1 1

-1

1 -.1

1

1 1

1

1 1

-1 1 1

POSS 1 B c

PEAKS

5

2

PROCESSING OPTION:

' y y

RMS 69 51 59

-.—. — __— ""̂

FIT 971 946 995 997 995 936

998 914 970 999 905 954 99B 995 993 953 996 956 992 936 993 999 996 92 5

996 999 ?9(j 994 1000 991 997 939 949 999 909 986 935 999 908 908

6/;.'8/B8

3

- LIST NAMES - z-STAND.ARD /'UNKNOWN VQSTDS/VQl VQSTDS/VG2 VQSTDS/VQ3

y~ C A T "••.̂•" -. o M 1 .'*•_ PEAKS M/Z

128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 63 173 43 43

164 92

112 106 104 106 106

ri.j D n ĵ r 1K U

15:

TOP DELTA 300 60S 759 382 722 903 53 86 107 138 204 221 252 286 325 346 363 385 383 424 436 439 451 686 492 499 515 534 538 531 538 570 616 632 679 688 727 762 825 948 988 957

-1

1 1

-1

1

1

1

1

1 1

08: 07

PEAKS

•Quantitation Report File, 8061illM8

Data: 8061111MS, TI 0^/28/88 14:27:00

.pie: JOB 806111-1 MS W/ STDMIX 250NG 5ML Conds. ; GC4 Formula: Instrument; 1050 Weight: 0,003 Submitted by; Analyst: MGB Acct. No

AM0UNT=AREA « REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry

BROMOCHLOROMETHANE 1,4-DIFLUGRGBENZENE CHL0R0BENZENE-D5 DICHL0R0ETNANE-D4 TOLUENE-DS BROMOFLUOROBENZENE CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE TRANS-1,2-DICHLOROETHENE CHLOROFORM 1,2-DICHLOROETHANE 2-BUTAANONE 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BRGMGDICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLGRaPROPANE TRANG-1,3-DICHLGROPRaPANE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLGROETHYL VINVL ETHER BROMOFORM 4-METHYL-2-PENTANONE 2-HEXANONE TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

42 XYLENES

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 '7 .8 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41

Name ISl IS2 I S3 SSI SS2 SS3 45V 46V BBV 16V 44V 13H 15H 29V 13V 30V 23V IOV 14H U V 6V 19H 48V 15V 32V 33VT 87V 51V 14V 4V

33VC 19V 47V 17H 16H 85V 86V 7V

38V 18H 20H

No 1 2 1 4 5 6 -r / 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 '̂ 8

7

LIO 31 32 33 34 35 36 37 38 39 40 41 42

t\\ / I

128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 63 173 43 43 164 92 112 106 104 106 106

Scan 300 608 759 382 722 903 53 86 107 138 204 221 252 286 325 346 363 385 383 424 436 439 451 686 492 499 515 534 538 531 538 570 616 632 679 688 727 762 825 948 988 957

Time 10: 20: 25: 12: 24: 30: 1; 2; 3: 4: 6: 7: 8: 9;

10: 11: 12: 12: 12: 14: 14; 14: 15-22-16-16 17 17 17 17 17 19 20 21 22 22 24 25 27 31 32 31

00 16 18 44 04 06 46 52 34 36 48 22 24 32 50 32 06 50 46 08 32 38 02 52 24 38 10 48 56 42 56 00 32 04 38 56 14 24 30 : 36 : 56 ; 54

Ref 1 2 3 1 3 3 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3

1. 1. 1, 1. 0. 1. 0, 0, 0 0. 0. 0. 0. 0. 1. 1, 1, 1, 0, 0, 0, 0, 0. 1. 0. 0. 0 0 0 0 0 0 1 0 0 0 0

RRT 000 000 000 273 951 190 177 287 357 460 680 737 840 953 083 153 210 283 630 697 717 722 742 128 809 821 847 878 885 873 885 937 013 833 895 906 958 004 087 249 302 261

Me A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A

th BB BB BB DB BB BB BB BB BB BE BB BU BB BB BB BB BB BB BB BB VB BB BB BB BB BB BV BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB

Area(Hght) ?i2369.

317384. 2325B0. 123851. 324467 185541.

5648. 75492. 16B90. 37Q57. 79000 1B705.

123600. 76015. 151897 78202. 190183. 132959.

5814. 106672. 90455. 122483, 164732, 182996 122231. 159518. 187779 101236. 95152.

281164. 56992. 39982. 47220, 99946, 64154, 110228 1904B3. 251810, 120505, 491722, 258224. 134627,

Amount 50. 000 50. 000 50. 000

109. 770 102 651 101.692 14. 595 51.390 21 35:1 52. 593 51. 504 55. 062 44. 287 54. 862 56. 441 52. 808 55. 695 59. 165 70, 305 58, 931 50, 273 53, 007 57. 227 67 151 58. 303 55. 240 91. 659 53. 624 54 276 53, 467 59. 102 65. 865 51. 479 67. 933 72, 400 63. 086 50, 951 56. 193 57 07B 136. 436 110. 974 56, 29:3

UG/L UG/L UG/L 7. 7. 7. UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L

y.Tot 1. 92 1 92 1 92 4 21 3. 94 3. 90 0 56 1. 97 0. 82 2. 02 1 98 2. 11 1. 70 2. 1 1 ' y 2 17 2. 03 2. 14 2. 27 2. 70 2. 26 1. 93 2. 03 2. 20 2, 58 2. 24 2. 12 3 , 5 2 y 2. Ob 2. 08 . 2. 05K 2, 27 2. 53 1, 98 2, 61 2. 78 2. 42 1. 96"^ 2. 16^^ 2. 19 5. 24 4. 26 2, 16

ACCESSION: 806130 yr/Ty) - '7U.A

/ \ AnalyticalTechnologies, Inc.

QUALITY CONTROL DATA: 188 METHOD 624 & 8240

CLIENT: MONTGOMERY & ASSOCIATES UNITS: ug/l ANALYSIS DATE: 6/29/88

DICHLOROMETHANE 1,1-DICHLOROETHENE CHLOROFORM 1,1,1-TRICHLOROETHANE BROMODICHLOROMETHANE TRICHLOROETHENE TETRACHLOROETHENE CHLOROBENZENE BENZENE TOLUENE

FOUND

54.4 55.4 59.5 59.2 60.4 55.1 61, 58, 53, 56,

4 3 6 3

ACTUAL

5 2 . 7 5 0 . 8 5 4 . 5 5 0 . 9 5 9 . 2 5 2 . 3 5 4 . 3 5 0 . 2 4 9 . 8 5 1 . 6

7.7i^^

/n /^9 /c7 ///, 7^1 / o S

/ / 3 )f/.

J i g

/ f 9

SURROGATE RECOVERY 102% l,2-DICHLOROETHANE-D4 113% BROMOFLUOROBENZENE (BFB) 102% TOLUENE - D8

PROJECT MANAGER: ./Tk. DATE: 8/16/88

07^7 - Trz/u-'h'u^

RIC 06/23/38 11:27:00 SAMPLE; %

Gl

DATA: QCG29 ttl CALI: QC623 «2

138 12,51 CONDS. RANGE: 1.1200 LABEL: N 0., 4.0 QUAH: A 0.. 1.0 J

; U U . U -

:.CAr6 1 TO 1200

0 BASE: U 20.• 760 234496.

J

RIC

D CC • CD LL V

0-•z> C i

'Sl

— a

L- En

204

153 " 1 200 6:40

'2iiPl

".63

iJ

451

u u

ilb

11

. i^L

bU'd

637 I !l

u 1140 400

13:20 6'00

28:00 SOO

26:40 1000 1200 SCAN

48:00 TIME


REPORT

TCA DIAGNOSTIC REPORT QC629 QC629 VQN INITIALIZATION OPTION: 2 VQSTDS

6/29/Be i"c!

PROCESSING OPTION: 3

STANDARDS >< PROC USED POSS RMS

PLUS UNKNOWNS -PROC USED POSS

1 1 1

6 6 6

6 6 6

42 COMPOUNDS

COMPOUND y< NO 1 2 3 4 5 6 7 8 9 10 11 12 13 M 5

16 17 IB 19 20 21 22 23 24 25 26 27 2B 29 30 31 32 33 34 35 36 37 38 39 0

41 42

LIB VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ

ENTRY 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

1 1 1

36 36 36

> PROCESSED,

1 REF

-300 -608 -758 -382 -721 -902 -54 -85

-107 -137 -203 -222 -252 -286 -326 -346 -363 -385 -382 -424 -436 -438 -450 -686 -491 -499 -515 -534 -537 -531 -537 -570 -616 -631 -678 -687 -727 -762 -824 -947 -987 -956

PRED 300 608 758 382 721 902 54 85 107 137 203 222 252 286 326 346 363 385 381 423 435 437 449 686 490 498 514 533 536 530 537 570 616 631 678 687 727 762 824 947 987 956

18 IB 18

9 12 10

19 FOUND

— SEARCH --SEL 300 608 758 382 721 901

203

2B6

363

424 424

451 687

516

531

687 727 761

948

DELTA

-1

1 -11

2 1

2

1

-1

1

PEAKS

>;: - LIST NAMES - !: RMS STANDARD/UNKNOWN 28 VGSTDS/VQl

369 VQSTDS/VQ2 60 VQSTDS/VQ3

FIT 975 922 994 1000 995 972

-'.: SAT PEAKS

997

994

993 934

993 909

1 1000

909

976 908 995

942

M/Z 12B 114 117 65 98 95 50 94 . 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 63 173 173 43 164 92 112 106 104 106 106

— CHRO — TOP DELTA 300 608 750 382 721 902

?03

IQb

363

424 424

451 687

516

531

679 687 727 762

948 987

PEAKS 1' 1 1 1 1 1

Ouantitation Report File: GC629

Dr3ta: QC629. TI 06/29/88 11:27:00 • ->ple: QC 188 12. 5UL ^ .ids. : GC4 Formula: Instrument; 1050 Weight: 0. 004 Submitted by: Analyst: MGB Acct. No, :

AM0UNT=AREA * REF AMNT/(REF AREA * RESP FACT) Resp fac. from Library Entry

No Name 1 ISl . BROMOCHLOROMETHANE 2 IS2 1, 4~DIFLU0R0BENZENE 3 133 CHLaRaBENZENE-D5 4 SSI DICHL0R0ETNANE-D4 5 SS2 TOLUENE-DS 6 SS3 BROMOFLUOROBENZENE 7 45V CHLOROMETHANE 8 46V BROMOMETHANE 9 88V VINYL CHLORIDE 10 16V CHLOROETHANE 11 44V METHYLENE CHLORIDE 12 13H ACETONE 13 15H CARBON DISULFIDE 14 29V 1,1-DICHLOROETHENE 15 13V 1,1-DICHLGRGETHANE 16 30V TRANS-1,2-DICHLORGETHENE ^7 23V CHLOROFORM i IOV 1,2-DICHLORGETHANE

19 14H 2-BUTAANGNE 20 IIV 1, 1, 1-TRICHLOROETHANE 21 6V CARBON TETRACHLORIDE 22 19H VINYL ACETATE 23 48V BROMODICHLOROMETHANE 24 15V 1. 1, 2, 2-TETRACHLGROETHANE 25 32V 1. 2-DICHLaRaPRaPANE 26 33VT TRANS-1, 3-DICHLOROPROPANE 27 87V TRICHLOROETHENE 28 51V DIBROMOCHLOROMETHANE 29 14V 1, 1.2-TRICHLOROETHANE 30 4V BENZENE 31 33VC CIS-1,3-DICHLOROPROPENE 32 19V 2-CHLOROETHYL VINYL ETHER 33 47V BROMOFORM 34 4-METHYL-2-PENTAN0NE 35 16H 2-HEXANONE 36 85V TETRACHLOROETHENE 37 86V TOLUENE 38 7V CHLOROBENZENE 39 3BV ETHYLBENZENE 40 IBH STYRENE 41 20H TOTAL XYLENES 42 XYLENES

No 1 2 1

A

5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 '21 22 23 24 25 26 27 "'8 9

30 31 32 33 34 35 36 37 38 39 40 41 42

m/ I 128 114 117 65 98 95

NGT NGT NOT NGT 84 43

NGT 96

NGT NGT 83

NOT NOT 97 117 NOT 83 83

NOT NGT 130 NOT NQT 78

NGT NGT NOT NGT 43 164 92 112 NOT 104 106 NOT

Scan 300 608 758 382 721 902

FOUND FOUND FOUND FOUND

203 222

FOUND 286

FOUND FOUND

363 FOUND FOUND

424 424

FOUND 451 687

FOUND FOUND

516 FOUND FOUND

531 FOUND FOUND FOUND FOUND

679 687 727 762

FOUND 948 987

FOUND

Time Ref RRI' Meth Area(Hqht) Amount 7. Tnt 10: 20; 25: 12: 24; 30:

00 16 16 44 02 04

6; 46 7; 24

9; 32

12: 06

14; 08 14; 08

15: 02 22: 54

17: 12

17: 42

22: 38 22: 54 24: 14 25; 24

31: 36 32: 54

1 2 3 1 3 3

000 000 000 273 951 190

2 0. 742 2 1. 130

A A A A A A

BB BB BB BB BB BB

1 0. 677 A BB 1 0. 740 A BB

1 0. 953 A BB

1. 210 A BB

2 0. 697 A BB 2 0. 697 A BB

A BB A BB

0. 049 A BB

0. 873 A BB

3 0, 896 A BB 3 O. 906 A BB 3 0, 959 A BB 3 1. 005 A BB

3 1 251 A BB 3 1. 302 A BB

5947B. 377655. 289785. 115121. 403679. 245005.

104157, 4159.

92761.

239197.

133902. 20315,

216223. 6447.

137408.

357938.

50. 000 UG/L 50, 000 UG/L 50, 000 UG/L 101 745 7. 101. 974 7. 113 134 7.

54 394 UG/L 8 478 UG/L

55. 372 L'G/L

4. 4. 4 9. 9.

70 70 70 57 60

10, 65

5. 12 0, 80

s o-̂ y

59, 457 UG/L 5, 59 "'

59, 9,

60, 1,

227 995

382 697

UG/L UG/L

UG/L UG/L

5, 0,

5, 0.

57-^ 94

68 y 16

55, 146 UG/L 5. 19 ^

53. 567 UG/L 5. 04'

320 128799, 247076. 332095.

5812. 1856.

0. 61, 56. 58.

1. 0.

230 445 269 283

308 638

UG/L UG/L UG/L UG/L

UG/L UG/L

0. 5. w/ .

5.

0, 0.

02 7G 29 48

12 06

( ^ 7 i yn7J'^9U


REPORT

ROC

IB 18 18

USED 18 17 18

41 FOUND

— SEA SEL 300 608 758 382 721 902 54 85 107 138 204 222 252 286 326 346 363 385 383 424 436 439 450 685 491

515 534 537 531 537 570 616 631 678 687 727 761 824 947 986 956

n/-»LJ n^^ri DELTA

-1 1

2 -3 2 1

-1 -1 -1

-1 1

-1

1 -1

I 1 1 2 3 2 1

-2 -5 -2

POSS 1 2 2

PEAKS

C

•

PROCESSING GPTION:

RMS 131 108 236

^ — ŝ

FIT 972 925 991 997 995 990 935 997 949 995 998 907 953 999 1000 1000 951 1000 918 975 940 991 1000 998 923

1000 997 997 994 1000 984 998 993 9G7 1000 910 997 935 997 910

I 910

6/28/88 9:

3

- LIST NAMES - > STANDARD/UNKNOWN VQSTDS/VQl VQSTDS/VQ2 VQSTDS/VQ3

< SAT - %x' '̂'•._ —. — — -PEAKS M/Z

128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 63 173 43 43 164 92 112 106 104 106 106

ruc3n L-rlKU

TOP DELTA 300 608 758 382 721 902 54 85 107 137 -1 203 -1 222 252 286 326 346 363 385 382 -1 424 436 438 -1 450 686 1 491 499 515 534 537 531 537 570 616 631 678 687 727 762 1 824 947 987 1 956

37 ; 07

—

PEAKS

Ouantitation Report File: STD628

Data: STD628 TI 06/28/88 8:56:00

No 1 2 ) 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27

^a .9 30 31 32 33 34 35 36 37 38 39 40 41 42

m/z 128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 63 173 43 43 164 92 112 106 104 106 106

Scan 300 608 758 382 721 902 54 85 107 137 203 222 252 286 326 346 363 385 382 424 436 438 450 686 491 499 515 534 537 531 537 570 616 631 678 687 727 762 824 947 987 956

Time 10: 20: 25: 12: 24: 30: 1: 2: 3: 4: 6: 7: 8: 9; 10: 11: 12: 12: 12: 14; 14: 14: 15; 22; 16: 16: 17: 17: 17; 17: 17: 19: 20; 21: 22 22: 24 25 27 31 32 31

00 16 16 44 02 04 48 50 34 34 46 24 24 32 52 32 06 50 44 08 32 36 00 52 22 38 10 48 54 42 54 : 00 : 32 : 02 : 36 : 54 : 14 ; 24 ; 28 : 34 ; 54 : 52

Ref 1 2 3 1 3 3 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3

1. 1. 1. 1, 0. 1. 0. 0. 0. 0, 0. 0. 0. 0. 1. 1. 1. 1. 0. 0. 0, 0 0, 1. 0. 0. 0. 0, 0. 0. 0. 0. 1, 0, 0, 0, 0,

RRT 000 000 000 273 951 190 180 283 357 457 677 740 840 953 087 153 210 283 628 697 717 720 740 12B 008 821 847 878 883 873 883 937 013 832 894 906 959 005 087 249 . 302 261

Meth A BB A BB A BB A BB A BB A BB A BB A BB A BB A DB A BB A DD A BB A BB A DD A BB A BB A DD A BD A DB A VB A BB A BD A DD A DB A DB A BB A BB A DD A BB A BD A DD A DD A DD A DB A BD A DD A DD A BD A DD A DD A BD

Area(Hght) 53428,

336587, 267372. 115110. 363373. 209747. 19754. 74935. 40353. 36718. 7B244. 17403,

142365, 70679. 137285. 75541. 1741B8. 114636,

4385. 95981, 95407, 122525. 152636. 144502. 111167. 153122, 108631. 100105, 92960,

27BB41, 51132. 32188, 50698, 84566, 50933

100432, 214838, 257574. 121353. 517896, 267496 137464,

Amount 50. 50. 50.

117. 109. 110 57. 46. 171. 42. 42. 41. 50. 41. 46, 41 48, 51, 29. 50, 51, 43, 48. 40. 42. 41, 42, 44. 41 41 42. 48, 40. 50. 46. 45, 45, 47, 48

143. 119 56

000 000 000 669 602 027 392 136 315 884 343 568 179 538 392 070 975 418 761 109 102 577 212 680 255 515 871 377 241 812 070 601 116 377 552 486 059 795 366 630 . 321 . 343

UG/L UG/L UG/L y. 7. 7. UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L

7.T 2, 2, 2, 4. 4. 4. 2. 1. 7. 1, I, 1 2. 1. 1. 1. 2. 2. 1. 2. 2, 1, 1. 1, 1. 1. 1. 1 1. 1, 1. 2, 1, 2, 1 1 1 1 2 5 4 2

ot 07 07 07 86 53 55 37 91 08 77 75 72 07 72 92 70 02 12 23 07 11 80 99 68 75 72 77 83 70 73 74 01 , 66 08 , 92 , 88 . 86 . 98 . 00 94 . 93 , 33

Quantitation Report File; STD62B

Data: STD628. TI 06/28/88 8:56:00

mple: STD MIX 250NG (6/27/88) ^onds. : GC4 Formula; Instrument; 1050 Weight: 0,003 Submitted by: Analyst: MGB Acct. No :

AM0UNT=AREA » REF AMNT/(REF AREA » RESP FACT) Resp. fac. from Library Entry

BROMOCHLOROMETHANE 1,4-DIFLUOROBENZENE CHL0R0DENZENE-D5 DICHL0R0ETNANE-D4 TOLUENE-DB BROMOFLUGRGBENZENE CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLGROETHANE TRANS-1.2-DICHLOROETHENE CHLOROFORM 1,2-DICHLORGETHANE 2-BUTAANONE 1,1,l-TRICHLGRGETHANE CARBON TETRACHLORIDE VINYL ACETATE BRGMODICHLGRGMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLORGPROPANE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYL VINYL ETHER BROMOFORM 4-METHYL-2-PENTAN0NE 2-HEXANaNE TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

42 XYLENES

No 1 2 3 4 5 6 7 B 9 10 11 12 13 14 15 16 ^7

) 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41

Name ISl 152 153 SSI SS2 553 45V 46V 88V 16V 44V 13H 15H 29V 13V 30V 23V IOV 14H U V 6V 19H 48V 15V 32V 33VT 87V 51V 14V 4V

33VC 19V 47V 17H 16H 85V 86V 7V

38V 18H 20H

No m/z Scan Time Ref RRT Meth Area(Hght) Amount 1 2 3 4 5 6 7

e 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 -n ?

30 31 32 33 34 35 36 37 38 39 40 41 42

128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 63 173 43 43

164 92 112 106 104 106 106

300 608 758 382 721 902 54 85 107 137 203 222 252 286 326 346 363 385 382 424 436 438 450 686 491 499 515 534 537 531 537 570 616 631 678 687 727 762 824 947 987 956

10; 20: 25; 12: 24: 30; 1; 2: 3: 4: 6: 7: 8; 9:

10; 11: 12; 12: 12: 14: 14: 14: 15-22 16 16 17 17 17 17 17 19 20 21 22 22 24 25 27 31 32 31

00 16 16 44 02 04 48 50 34 34 46 24 24 32 52 32 06 50 44 08 32 36 00 52 22 38 10 48 54 42 54 00 32 02 36 54 14

: 24 : 28 : 34 ; 54 ; 52

3 4 5 6 7 B

1 1, 000 A BB 2 1, 000 A BB 3 1. 000 A BB 1 1, 273 A BB 3 0, 951 A BB 3 1 190 A BB 1 0, 180 A BB 1 0. 283 A BD 1 0. 357 A BB 1 0. 457 A BB 1 0. 677 A BB 1 0. 740 A BB 1 0.840 A DB 1 0. 953 A BB 1 1. 087 A BB 1 1. 153 A BB 1 1. 210 A BB 1 1. 283 A BB 2 0. 628 A BB 2 0.697 A BB 2 0. 717 A VB 2 0. 720 A BB 2 0.740 A BB 2 1. 128 A BB 2 0. 808 A BB 2 0. 821 A BB 2 0, 847 A BB 2 0. 878 A BB 2 0. 883 A BB 2 0. 873 A BB 2 0. 883 A BB 2 0. 937 A BB 2 1, 013 A BB 3 0.832 A BB 3 0. 894 A BB 3 0. 906 A BD 3 0, 959 A BB 3 1. 005 A BB 3 1, 087 A BB

1. 24'

No Ret(L) Ratio RRT(L) Ratio 1 10; 00 1. 00 1. 000 1, 00

20: 16 25: 16 12: 44 24; 02 30; 04

1. 00 1, 00 1. 00 1, 00 1, 00

1. 000 1. 000 1. 273 0, 951 1, 190

1, 00 1. 00 1. 00 1. 00 1. 00

A BB 3 1 302 A BB 3 1. 261 A BB

1: 40 1. 00 O. 180 1. 00 2: 50 1. 00 0, 283 1. 00

9 3:34 1. 00 0 357 1. 00 0 4: 34 1. 00 0. 457 1. 00

U 6:46 1.00 0.677 1,00 12 7:24 1. 00 0. 740 1, 00

Amnt 50, 00 50, 00 50. 00 100,00 100. 00 100.00 50. 00 50, 00 50 00 50. 00 50. 00 50. 00

53428. 336587, 267372, 115110. 363373. 209747, 19754. 74935. 40353. 36718. 78244. 17403.

142365. 70679. 137285, 75541, 1741BB, 114636.

4385. 95981. 95407. 122525. 152636, 144502. 111167, 153122. 108631. 100105. 92960.

27B041. 51132. 32188, 50698, 84566. 50933.

100432, 214888. 257574, 121353. 517B96, 267496. 137464,

Amnt(L) 50. 00 50, 00 50, 00

100, 00 100.00 100, 00 50, 00 50, 00 50, 00 50. 00 50. 00 50. 00

50.000 UG/L 50. 000 UG/L 50 000 UG/L

100. 000 7. 100. 000 7. 100. 000 7. 50 000 UG/L 50. 000 UG/L 50. 000 UG/L 50. 000 UG/L 50.000 UG/L 50, 000 UG/L 50.000 UG/L 50, 000 UG/L 50, 000 UG/L 50. 000 UG/L 50, 000 UG/L 50.000 UG/L 50. 000 UG/L 50,000 UG/L 50, 000 UG/L 50, 000 UG/L 50, 000 UG/L 50.000 UG/L 50. 000 UG/L 50, 000 UG/L 50.000 UG/L 50. 000 UG/L 50. 000 UG/L 50, 000 UG/L 50. 000 UG/L 50. 000 UG/L 50. 000 UG/L 50.000 UG/L 50. 000 UG/L 50.000 UG/L 50.000 UG/L 50. 000 UG/L 50.OOO UG/L

125. 000 UG/L 100.000 UG/L 50, 000 UG/L

7. Tot 2, U 2, 2. 4, 4, 4.

2. 2, 2. 2, 2. 2. 2. 2. 2. 2. 2. 2. 2.

2. 2. '~i C .

2.

11 11 21 21 21 11 11 1 1 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 26 21 11

R, Fac R. Fac (L) Ratio 1. 000 1. 000 1, 00 1, 000 1. 000 1, 00 1, 000 1. 000 1. 00 1, 077 1. 077 1, 00 0. 6S0 0. 6B0 1. 00 0, 392 0. 392 1. 00 0. 370 0, 370 1, 00 1,403 1.403 1,00 O. 755 0. 755 1, 00 0. 687 0, 687 1, 00 1. 464 1. 464 1. 00 0, 326 0. 326 1, 00

No 13 14 5

l b

17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 1

42

Ret(L) 8: 9: 10: 11; 12: 12; 12; 14: 14: 14: 15: 22: 16: 16: 17; 17: 17; 17: 17: 19: 20: 21: 22; 22; 24; 25: 27: 31: 32: 31:

24 32 52 32 06 50 44 08 32 36 00 52 22 38 10 48 54 42 54 00 32 02 36 54 14 24 : 28 34 : 54 52

Rati 0 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 00 , 00 , 00 , 00 . 00 00 . 00

RRT(L) 0, 840 0. 953 1. 087 1, 153 1, 210 1, 283 0, 628 0. 697 0. 717 0 720 0. 740 1 128 0. 808 0. 821 0 847 0. 878 0. 883 0. 873 0. 883 0. 937 1. 013 0. 832 0, 894 0. 906 0. 959 1. 005 1. 087 1, 249 1, 302 1, 261

Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 . 00 , 00 . 00 . 00 . 00

Amnt 50. 00 50, 00 50. 00 50. 00 50. 00 50. 00 50, 00 50. 00 50. 00 50. 00 50, 00 50, 00 50, 00 50, 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 ' 50. 00

125. 00 100, 00 50. 00

Amnt(L) 50, 00 50, 00 50, 00 50. 00 50 00 50. 00 50. 00 50. 00 50. 00 50, 00 50. 00 50, 00 50. 00 50. 00 50. 00 50, 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50, 00 50. 00

125, 00 100. 00 50, 00

R. 2. 1, 2. 1. 3. 2, 0. 0. 0, 0. 0, 0, 0, 0. 0, 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0, 0. 0, 0. 0.

Fac R. 665 323 570 414 260 146 013 285 283 364 453 429 330 455 323 297 276 828 152 096 151 316 190 376 804 963 4 54. 775 500 514

Fac(L) 2. 665 1. 323 2. 570 1 414 3. 260 2 146 0. 013 0 285 0. 283 0. 364 0. 453 0. 429 0. 330 0. 455 0. 323 0. 297 0. 276 0. 82B 0. 152 0. 096 0. 151 0. 316 0. 190 0. 376 0. 804 0. 963 0 454 0. 775 0. 500 0. 514

Rat : i 0 00 00 00 00 00 00 00 00 00 GO 00 00 00 00 00 00 00 00 00 00 00 00 00 00 . 00 . 00 . 00 . 00 . 00 . 00

/j>ZH- '>7)(y/-'7u7\

DATA: STD623 ̂ 1 CALI: STDb23 #2

SCANS

100.0-1

RIC 0S/29/S3 10:13:00 SAMPLE: STD MIX250HG < 6/27/S8) CONDS.: _GCT ' • RANGE: G 1.1200 LABEL: N O.. 4 .0 QUAH: A O.. 1.0 J O BASE: U 20, 3

760

637

1 TO 1'2O0 fe&'^^

RIC

o

Q - t Z D 00 O OD U. -v

Cf o nj

o Q • UJ I -X < OJ » - Q Z UJ ^ X u. cn

PROCEDURE DATA FILE REFERENCE MAME LIST

REPORT

TCA DIAGNOSTIC REPORT STD629 STD629 VQN INITIALIZATION OPTION; 2 VQSTDS

6/29/85 10: ̂ ."f : 1 1


: STANDARDS -PROC USED POSS

6 6 1 6 6 1 6 6 1

-— X PLUS UNKNOWNS X - LIST NAMES - : RMS PROC USED POSS RMS STANDARD/UNKNOWN 46 IS 18 1 49 VQSTDS/VQl 46 18 17 2 48 VQSTDS/VQ2 46 18 17 1 3B0 VQ5TDS/VQ3

42 COMPOUNDS PROCESSED, 40 FOUND

COMPOUND >< NO LIB ENTRY REF 1 2 3 4 5 6 7 8 9 10 11 12 13 4 .5 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39

) 41 42

VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VG VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

-300 -608 -758 -382 -721 -902 -54 -85

-107 -137 -203 -222 -252 -2B6 -326 -346 -363 -385 -3G2 -424 -436 -438 -450 -686 -491 -499 -515 -534 -537 -531 -537 -570 -616 -631 -678 -687 -727 -762 -824 -947 -987 -956

PRED 300 608 758 382 721 902 54 85 107 137 203 222 252 286 326 346 363 385 382 424 436 438 450 686 491 499 515 534 537 531 536 569 615 630 677 686 726 761 824 947 987 956

— SEARCH SEL DELTA PEAKS 300 609 758 382 721 902 53 85 107 137 204 222 252 286 325 346 363 385 383 424 436 439 450 685 491

515 534 537 531 537

616 616 67B 687 727 761 825 948 988 956

1 1

-1 1

1 1

-1 )

1

1

-1

1

1 •14 1 1 1

1 1 1

;>< SAT >o FIT PEAKS M/Z 970 949 993 999 949 973 934 994 950 993 995 909 953

L 997 L 997 I 955 L 953 L 999 i 920 L 990 t 937 I 9BB L 997 L 997 1 924

1 996 I 998 1 976 1 772 1 1000

1 1000 1 1000 1 990 1 999 1 910 1 993 1 932 1 993 1 908 1 908

128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 77 117 43 83 83 63 75 130 129 97 78 75 63 173 173 43 164 92 112 106 104 106 106

— CHRO : TOP DELTA PEAKS 300 608 -1 758 382 721 902 53 85 107 137 204 222 252 2B6 325 346 363 385 383 424 436 439 450 606 492 499 515 534 537 531 538 570 616 616 678 687 727 762 824 946 987 956

I

1 1 1 1

1 1

1 1 1 1 2 1 1 1

Quantitation Report File: STD629

Data: STD629. TI 06/29/88 10: 18: 00

pie; STD MIX 250NG (6/27/88) L^nds. ; GC4 Formula: Instrument: 1050 Weight; 0.004 Submitted by; Analyst: MGD Acct No ;

AMGUNT=AREA * REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry

BROMOCHLOROMETHANE 1,4-DIFLUORGDENZENE CHL0RaDENZENE-D5 DICHL0R0ETNANE-D4 T0LUENE-D8 BROMOFLUaRGBENZENE CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLGRGETHENE 1,1-DICHLGRGETHANE TRANS-1,2-DICHL0RaETH£NE CHLOROFORM 1,2-DICHLOROETHANE 2-BUTAANONE 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BRGMODICHLGRGMETHANE 1, 1,2, 2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLORGPRGPANE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1.3-DICHLOROPROPENE 2-CHLORGETHYL VINYL ETHER BROMOFORM BROMOFORM 2-HEXANONE TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

42 XYLENES

No 1 2 3 4 5 6 7 a 9 10 11 12 13 14 15 16 '7 J

19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41

Name ISl 152 153 551 552 553 45V 46V 88V 16V 44V 13H 15H 29V 13V 30V 23V IOV 14H U V 6V 19H 48V 15V 32V 33VT 87V 51V 14V 4V

33VC 19V 47V 47V 16H 85V 86V 7V

38V 18H 20H

No m/z Scan Time Ref RRT Meth Area(Hght) Amount 7.Tot 1 2

'\ 5 6 7 8 9 10 11 •42 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 -q

1

30 31 32 33 34 35 36 37 38 39 40 41 42

128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 63 173 173 43 164 92 112 106 104 106 106

300 608 758 382 721 902 53 85 107 137 204 222 252 286 325 346 363 385 383 424 436 439 450 686 492 499 515 534 537 531 538 570 616 616 678 687 727 762 824 946 987 956

10: 20: 25: 12: 24: 30: 1: 2: 3: 4: 6: 7: 8: 9:

10: 11: 12: 12: 12: 14: 14: 14; 15 22 16 16 17 17 17 17 17 19 20 20 22 22 24 25 27 31 32 31

00 16 16 44 02 04 46 50 34 34 48 24 24 32 50 32 06 50 46 08 32 38 00 52 24 38 10 48 54 42 56 00 32 32 36 54 14 24 28 32 54 52

1 2 3 1 3 3 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3

1. 000 1. 000 1. 000 1, 273 0, 951 1. 190 0, 177 0, 283 0, 357 0. 457 0, 680 0. 740 0. 840 0, 953 1. 083 1, 153 1, 210 1, 283 0. 630 0, 697 0. 717 0. 722 0. 740 1. 128 0. 809 0. 821 0. 847 0. 878 0. 883 0. 873 0. 8G5 0. 937 1. 013 1. 013 0. 894 0. 906 0. 959 1, 005 1. 087 1. 248 1. 302 1. 261

A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A

BB BB BB BB BB BB DB BB BB BD DD BB BB BB BB BB BB BB BB BB VB BD DB BB BB BB BE BB BB BB BB BD BB BB DB BB BB BB BB EB BE BB

61052. 388218. 303265. 116141. 414278. 226635. 13766. 76383. 38412. 43888. 98277. 25177.

202311. 85978 181328, 9S883.

206474. 122921.

7383. 116202. 104468. 185914. 184053. 195237. 152026. 214935. 128070. 118819. 11361G, 343448. 70653. 3809.

59173. 59173. 72710. 1096S3. 229763. 298151, 142075. 5B1272. 304374, 160413,

50. 50, 50 88 100, 95, 30. 44. 41 52. 54 63. 62, 53. 57, 57, 51, 46. 72, 52, 47. 65, 52. 58. 59. 60 51 51 52 53 57 5

50 50 62 48 47 51 51

123 100 51

000 UG/L 000 UG/L 000 UG/L 296 7. 516 7. 263 7. 492 UG/L 602 UG/L 651 UG/L 300 UG/L 959 UG/L 302 UG/L 181 UG/L 228 UG/L 794 UG/L 277 UG/L 866 UG/L 919 UG/L 989 UG/L 483 UG/L 467 UG/L 778 UG/L 273 UG/L 571 UG/L 283 UG/L 850 UG/L 108 UG/L 454 UG/L 984 UG/L 394 UG/L 900 UG/L 130 UG/L 597 UG/L 597 UG/L 930 UG/L 143 UG/L 134 UG/L 027 UG/L 610 UG/L 696 UG/L 326 UG/L 442 UG/L

2, 06 2. 06 2 06 3. 63 4. 13 3. 92 1, 25 1. 83 1 71 2. 15 2. 26 2 60 2, 56 2. 19 2, 38 2, 36 2, 13 1, 93 3, 00 2, 16 1. 95 2, 70 2, 15 2. 41 2, 44 2. 50 2. 10 2. 12 2. 18 2, 20 2. 46 0, 21 2, 08 2, 08 2, 59 1, 98 1. 94 2, 10 2. 12 5, 09 4. 13 2, 12

Quantitation Report File: 5TD629

Data: STD629, TI 06/29/88 10: 18; 00

tple: STD MIX 250NG (6/27/88) Lunds, : GC4 Formula: Instrument: 1050 Weight: 0.004 Submitted by; Analyst; MGB Acct. No,:

AMOUNT=AREA » REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 ' 1 3 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40

No 1 2 3

Name ISl 152 153 551 552 553 45V 46V BBV 16V 44V 13H 15H 29V 13V 30V 23V IOV 14H U V 6V 19H 48V 15V 32V 33VT 87V 51V 14V 4V

33VC 47V 16H a5V B6V 7V 38V 18H 20H

BROMOCHLOROMETHANE 1,4-DIFLUGRaBENZENE CHLGR0BENZENE-D5 DICHL0R0ETNANE-D4 TOLUENE-DB BROMOFLUGRGBENZENE CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLORGETHENE 1,1-DICHLGROETHANE TRANS-1,2-DICHLORaETHENE CHLOROFORM 1,2-DICHLOROETHANE 2-BUTAANGNE 1,1, 1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BRGMODICHLGRGMETHANE 1, 1,2, 2-TETRACHLGRGETHANE 1,2-DICHLGROPROPANE TRANS-1, 3-DICHLGRGPRGPANE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPRaPENE BROMOFORM 2-HEXANGNE TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

XYLENES

m/z 128 114 117

Scan Time Ref RRT Meth 300 10:00 11,000 A BB 608 20: 16 2 1. 000 A BB 758 25: 16 3 1. 000 A BB

Area(Hght) 61052, 388218, 303265.

Amount 7.Tot 50. 000 UG/L 2. 20 50. 000 UG/L 2, 20 50. 000 UG/L 2. 20

No 4 5

7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 -̂1

33 34 35 36 37 38 39 40

No 1 -1

3 4 5 6 7 0 9 10 11 12 13 14 5 16 17

ni/ z

65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 173 43 164 92 112 106 104 106 106

5 can 382 721 902 53 85 107 137 204 222 252 286 325 346 363 385 383 424 436 439 4 50 686 492 499 515 534 537 531 538 616 678 687 727 762 824 946 987 956

Ret(L) Ra 10: 20; 25: 12; 24: 30: 1: 2; 3: 4; 6; 7: 8; 9: 10: 11: 12;

00 16 16 44 02 04 46 50 34 34 48 24 24 32 50 32 06

Time R 12; 44 24: 02 30: 04 1; 46 2: 50 3: 34 4: 34 6: 48 7: 24 B: 24 9: 32 10; 50 11; 32 12; 06 12: 50 12: 46 14: 08 14: 32 14: 38 15: 00 22: 52 16: 24 16; 38 17; 10 17: 48 17:54 17: 42 17; 56 20: 32 22: 36 22: 54 24: 14 25: 24 27: 28 31: 32 32: 54 31: 52

ef 1 3 3

2 2 2 2 2 2 2 2 2 2 2 2 2 n

3 3 3 3 3 3 3 3

tio RRT(L) R 00 1. 000 00 1. 000 00 1. 000 00 1.273 00 0. 951 00 1. 190 00 0. 177 00 0. 283 00 0, 357 00 0, 457 00 0, 680 00 0, 740 00 0. 840 00 0, 953 00 1. 083 00 1, 153 00 1. 210

RRT 1. 273 0, 951 1, 190 0, 177 0, 283 0. 357 0 457 0. 680 0. 740 0. 840 0. 953 1. 083 1. 153 1. 210 1. 283 0. 630 0, 697 0, 717 O, 722 0, 740 1. 128 0. 809 0. 821 0. 847 0. 878 0. 883 0. 873 0. 885 1. 013 0, 894 0. 906 0, 959 1. 005 1. 087 1, 248 1. 302 1. 261

atio . 00 , 00 , 00 . 00 .00 . 00 . 00 . 00 . 00 , 00 , 00 . 00 , 00 , 00 , 00 , 00 , 00

Meth A BB A DB A BB A DD A DB A BB A BD A BB A BD A BB A BB A BB A BD A BB A DD A DD A DB A VD A DD A DD A DD A BB A BB A DD A BB A BB A DD A BB A BB A DB A BB A BD A DD A DB A DD A BB A DB

Amnt 50, 00 50. 00 50. 00

100. 00 100, 00 100. 00 50. 00 50, 00 50, 00 50, 00 50. 00 50, 00 50. 00 50. 00 50. 00 50. 00 50. 00

Area(Hght) 116141. 414278. 226635. 13766. 76383. 3B412. 43888. 98277. 25177.

202311. 8597B. 181328. 988B3,

206474 122921

7383, 116202. 104468. 185914, 184053. 195237. 152026. 214935. 12B070. 118319. 113618 343448. 70653 59173. 72710. 109683. 229763. 29B151. 142075. 5B1292. 304394. 160413

Amn t(L) 50, 00 50. 00 50 00

100. 00 100, 00 100, 00 50. 00 50, 00 50, 00 50. 00 50. 00 50, 00 50. 00 50. 00 50. 00 50. 00 50. 00

Amount 100, 000 100, 000 100. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50, 000 50. 000 50. 000 50. 000 50. 000 50.000 50, 000 50, 000 50. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50, 000 50, 000 50. 000 50. 000 50 000 50. 000 50. 000 50. 000 50, 000 50. 000 50. 000 125. 000 100 000 50. 000

r̂ Fac R. 1. 000 1. 000 1. 000 0. 951 0. 683 0. 374 0. 225 1. 251 0, 629 0, 719 1, 610 0, 412 3, 314 1, 408 2. 970 1. 620 3. 382

7. 7. 7. UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L

F a c ( L ) 1. 000 1 000 1. 000 0. 951 0. 683 0. 374 0. 225 1. 251 0. 629 0. 717 1, 610 0. 412 3, 314 1. 408 2. 970 1, 620 3, 382

7.Tot 4. 40 4. 40 4. 40 2 20 2. 20 2. 20 2. 20 2. 20 2, 20 2 20 2. 20 2. 20 2. 20 2. 20 2 20 2. 20 2 20 2. 20 2, 20 2, 20 2, 20 2, 20 2. 20 2, 20 2. 20 2. 20 2. 20 2 20 2 2.0 2. 20 2. 20 2. 20 2. 20 2, 20 5. 49 .4. 40 2, 20

Ratio 1 . 00 1. 00 1. 00 1, 00 1 00 1. 00 1 00 1. 00 1. 00 1. 00 1 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

No IB 1.9 3

21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40

Ret(L) 12: 50 12:46 14; 08 14: 32 14: 38 15: 00 22: 52 16: 24 16; 38 17: 10 17: 48 17: 54 17: 42 17: 56 20: 32 22: 36 22; 54 24; 14 25: 24 27: 28 31:32 32; 54 31; 52

Ra t io 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 , 00 . 00 , 00 , 00 00

RRT(L) 1, 283 0. 630 0. 697 0. 717 0, 722 0. 740 1. 128 0. 809 0, 821 0, 847 0, 878 0, 883 0, 073 0, 885 1. 013 0., 894 0. 906 0, 959 1. 005 1. 087 1, 248 1. 302 1. 261

Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 00 , 00 . 00 . 00 00

Amnt 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50, 00 50. 00 50, 00 50, 00 50, 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

. 125. 00 100, 00 50. 00

Amnt(L) 50 00 50, 00 50, 00 50, 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50 00 50. 00 50, 00 50, 00 50. 00 50, 00 50, 00 50. 00 50 00 50, 00 125. 00 100. 00 50, 00

R. 2. 0. 0. 0, 0, 0, 0, 0 0 0, 0 0, 0. 0. 0. 0, 0. 0. 0. 0. 0. 0. 0.

Fac F 013 019 299 269 479 474 503 392 554 330 306 293 885 182 152 240 362 758 983 468 767 502 529

L Far(L) 2. 013 0. 019 0. 299 0 269 0. 479 0 474 0. 503 0. 392 0 554 0. 330 0. 306 0, 293 0. 885 0. 182 0. 152 0. 240 0. 362 0. 758 0 983 0. 46B 0. 767 0 502 0 527

Rat ;io 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 . 00 00 . 00 00 . 00

/ ^ AnalyticalTechnologies, Inc

TvU-HiiA

QUALITY CONTROL DATA

TEST : SEMI-VOLATILE ORGANICS (EPA 625)



ATI I.D.


806130

80613001 08/01/88 AQUEOUS UG/L

COMPOUNDS

DUP. DUP, SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC. RPD

1,2,4-TRICHLOROBENZENE ACENAPHTHENE 2,4-DINITROTOLUENE PYRENE N-NITROSO-DI-N-PROPYLAMINE 1,4-DICHLOROBENZENE PENTACHLOROPHENOL PHENOL 2-CHLOROPHENOL 4-CHLORO-3-METHYLPHENOL 4-NITROPHENOL

^PA- U Z ^

2p(,î cz__

uAVAi 88.''.3325ol Vr22l5 C A L I ! 88ri3325di ir2

SCAî S 2hZ Vo 2otfi6

lee.e-

RkKf

tf8/tfi/88 b! i6! i5d SAiVi.£: 8*?i58=i5 J2CL^ CONDS.: IUL 1L->2X1ML RANGE: G 1,2608 LA8EL: N 0, 4.3 QUAN: A 8, 1.8 J 8 SASE: U 28, 3

2618&3.

RIC _

-ik }\k. T 588 8:28

I 1888 16:48

\

1588 25:88

I!- 1 r 2888 33:28

— I 2588 41:48

SCAH TIME

ROCEDURE ATA FILE EFERENCE AME LIST

REPORT

T

45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

SV SV SV SV SV SV SV SV SV SV SV SV SV SV sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

10 ir 51 52 53 54 55 56 57 58 5

59 60 61 62 63 64 65 66 67 6 12 68 69 70 71 72 73 74 75 76 77 78 79 80 81

-1073 -1337 -1235 -1225 -1241 -1171 -1299 -1298 -1289 -1310 -1962 -1315 -1323 -1387 -1407 -1444 -1465 -1474 -1609 -1689 -2211 -1776 -1776 -1728 -1887 -1967 -1959 -2010 -1967 -2121 -2151 -2155 -2202 -2393 -2401 -2443

1072 1338 1235 1225 1241 1171 1300 1299 1290 1311 1962 1315 1323 1387 1407 1444 1465 1474 1609 1688 2215 1775 1775 1727 1887 1967 1959 2010 1967 2121 2151 2155 2202 2393 2401 2443

1072 1341

, ,

1244 , , . , .

1962 ,

1325

, , , ,

1606 ,

2215 1774 1775 1729

, . ,

2007 , , , , , , . ,

,

3

3

2

-3

-1

2

-3

1 1

1

1

1

1

1 1 1 1

1

991 973

, .

992

, , , , ,

929 ,

748 , , , , ,

993 ,

976 983 702 987

,

.

988 , , , , , , , ,

172 330 139 168 89 165 149 204 166 138 240 198 169 248 284 266 178 178

1 149 202 264 244 184 202 149 252 228 149 228 149 252 252 252 276 278 276

1072 1341

1245

1962

1325

1606 ,

2215 1774 1774 1729

, . ,

2007 . , , .

• , , ,

1 1

L 1

1

1

1 ,

1 1

1 1 1

1

Quantitation Report File: 88M3B2501

Data: 88M3B2501. TI 08/01/88 6:10:00 ,. ^ Sampl*: 807158-15 C / * ^ ) Conds.: IUL IL->2X1ML standard ID: 2-BNA-7-1A Sffnsitivity ID: 2491

Instrunisnt: 5100 Analyst: RJT Inst Cali:

AMOUNT=AHEA • R E F AMNT/(HEP AREA • RESP FACT) Resp. fac. from Library Entry NO 1 2 3 4 3 6 7 8 9 10 11 12 13 14 13 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19

NAME ISl IS2 I S3 IS4 ISS IS6 SS2 SSI SS3 SS4 SS3 SS6 26B 27B 25B 63B 8B 22A IB

35B 62B 68B 5B

84B 66B

1.4-DICHLOROBENZENE-04 NAPHTHALENE-D8 ACENAPHTHENE-D8 PHENANTHRENE-DIO CHRYSENE-D12 PERYLENE-D12 PHENOL-D5 2-FLUOROPHENOL

NITR08ENZENE-D5

1 '

2-FLUOROBIPHENYL 2.4. 6-TRIBROMOPHENOL TERPHENYL-D14 1.3-1,4-1,2-

DICHLOROBENZENE DICHLOROBENZENE DICHLOROBENZENE

N-NITROSO-DI-N-PRCPYLAMINE 1.2. 4-TRICHLOROBENZENE 4-CHL0R0-3-METHYLPHEN0L ACENAPHTHENE 2.4-DINITROTOLUENE N-NITROSODIPHENYLAMIN6 DI-N l-BUTYLPHTHALATE BENZIDINE PYRENE BIS( 2-tTHYLHEXYL)PHTHALATE

CYCLOHEXENE UNKNOWN D4-1, ,4-DICHLOROBENZENE (INI.i D8-NAPHTHALENE (INT. STD.) D10-( ACENAPTHENE (INT. STD. > DIO-PHENANTHRENE (INT. PERYLENE-D12

m/z 152 136 164 188 240 264. 99 112 82 172 330 244 146 146 146 70 180 107 133

Scan 639 862 1186 1461 1962 2213 619 444 743 1072 1341 1774 642 642 642 729 839 1015 1192

Time Ref 10:39 1 14:22 2 19: 46 3 24:21 4 32:42 3 36:33 6 10:19 1 7:24 1 12:23 2 17:52 3 22:21 3 29:34 3 10:42 1 10: 42 1 10:42 1 12:09 1 14: 19 2 16:55 2 19:52 -3

STD. )

RRT 1. 000 1, 000 1.000 1.000 1. 000 1. 000 0. 969 0. 695 0.862 0. 904 1. 131 0. 904 1. 003 1. 005 1. 005 1. 141 0. 997 1. 177 1. 005

STD. )

Meth A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A 3B A BB A BB A BV A BB A BV A BB

Area(Hght> 85333.

309920. 208261, 331545. 176313. 114204. 72132. 37120. 122769. 301217. 39313.

218651. 124326. 124326. 124326. 33184. 105382. 6034.

23663'?:

Afflount 40. 40. 40. 40. 40. 40. 33. 59. 55. 64. 59. 64. 43. 42. 43. 38. 47. 2.

—45.

000 000 000 000 000 000 357 606 617 875 421 896 591 480 204 099 774 584 380

NC/UL NG/UL NC/UL NC/UL NC/UL NC/UL NC/UL NO/UL NG/UL NC/UL NC/UL NC/UL NC/UL NC/UL NC/UL NC/UL NC/UL NC/UL NC/UL

X^ 3. 3. 3. 3. 3. 3. 2. 4. 4. 5. 4. 5. 3. 3. 3. 2. 3. 0. 3.

ot 13 13 13 13 13 13 63 67 3^

oa 65 0C« 57 32 30 90 74 20 OJr

k • «« « • ta

20 21 22 23 24 25 26 27 28 29 30 31 32

89 169 149 184 202 149 RIC RIC RIC RIC RIC RIC KIC

1245 1325 1606 1774 1729 2007 174 396 641 862 1186 1461 2215

20: 22: 26: 29: 26: 33: 2: 6: 10: 14: 19: 24: 36:

45 05 46 34 49 27 54 36 41 22 46 21 55

3 4 4 5 5 5

29 29 28 29 30 31 32

1. 0. 1. 0. 0. 1. 0. 0. 1. 1. 1. 1. 1.

050 907 099 904 881 023 202 459 000 000 000 000 000

A A A A A A A A A A A A A

BB BB BB BB BB BB BB BB BB BB BV BB BQ

56606. 1435.

413785. 5695.

315031. 6335.

530488. 76512.

1079420, 1204110. 773452. 879979. 326001.

36. 0.

43. 64. 52. 1.

44. 6.

40. 40. 40. 40. 40.

700 61S 754 785 764 529 056 354 000 000 000 000 000

NG/UL NG/UL NG/UL NC/UL NG/UL MG/UL

UG/L UG/L UC/L UC/L UG/L

2. 0. 3. 5. A. 0. 3. 0. 3. 3. 3. 3. 3.

37 Ob 4;' 07 13 IV Ab 50 13 K^ KH 13 13

^0 7 y

z ^

•5 ;

^ 7 / 7 P ^ ^

Rii J^

%0(^) 3 O ^ ' •

7r}u}-*7/^y7 OAVA: 88/i332552 w22l

'ROCEDURE )ATA F I L E lEFERENCE lAME L I S T

REPORT

DIAGNOSTIC REPORT TCA 88M3B2502 , ._o 88M3B2502 '^ ' Kl INITIALIZATION OPTION: XI

8/01/88 7:52:05


: STANDARDS PROC USED POSS

2 2 2 2 2 2 2 2 2 1

2 2 2 2 2 2 2 6

>< PLUS UNKNOWNS >< - LIST NAMES - > RMS PROC USED POSS RMS STANDARD/UNKNOWN

0 11 7 2 498 Xl/Zl 0 9 3 2 300 Xl/ZA 0 9 2 1 0 X2/Z2 0 9 5 1 367 X2/ZB

106 12 3 1 73 X3/Z3 0 12 3 1 283 X3/ZC 0 11 3 1 238 X4/Z4 0 10 6 1 237 X5/Z5 0 7 0 1 0 X6/Z6

80 COMPOUNDS PROCESSED. 28 FOUND

COMPOUND >< NO LIB ENTRY REF 1 2-3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 32 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40

SV SV SV SV SV SV SV SV SV SV SV SV SV SV sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

1 2 14 15 16 17 18 19 20 21 22 7 8

23 24 25 26 27 3

28 29 30 31 32 33 34 9

35 36 37 38 39 40 4

41 42 43 44 45 46

-644 -866 -239 -613 -600 -617 -615 -637 -647 -680 -677 -611 -449 -710 -710 -737 -734 -729

-1189 -748 -793 -805 -828 -867 -843 -849 -745 -861 -869 -902 -910 -988 -996 -1461 -1041 -1057 -1063 -1083 -1114 -1164

PRED 638 862 239 610 597 614 612 633 643 676 673 607 444 706 706 733 730 725 1186 744 789 801 824 863 839 845 743 860 868 901 909 987 996 1458 1037 1053 1059 1079 1110 1160

— SEARCH — SEL DELTA 638 862

,

613 , ,

612 640 640

,

666 611 443

, , ,

728 ,

1186 , , , , , , ,

743 858

, , ,

996 ,

1459 ,

, .

, ,

3

, ,

7 -3 ,

-7 4

-1

-2

-2

9

1

PEAKS 1 1

1

,

1 1 2 .

1 1 1 . . .

2 ,

1

, .

^ ,

.

1 1

, ,

1 ,

2

X SAT X FIT PEAKS M/Z 989 909

999 .

983 989 991

.

927 969 988

.

.

.

995

998 ', . . . . ^ .

981 996

, , ,

973 ,

965 , , , . . ,

152 136 42 94 93 93 128 146 146 108 146 99 112 108 45 108 70 117 164 77 82 139 122 122 93 162 82

. 180 128 127 225 107 142 188 237 196 196 162 65 163

CHRO TOP DELTA PEAKS 637 862

.

613 , , ,

612 640 640

, .

611 443

.

.

.

728 ,

1186 . , .

- •

. , ,

742 838

, , .

995 ,

1459 , . . . ,'

I 1 1

1 . ,

I 1 1

,

1 1

, ,

1 ,

1 , , . . . , ,

1 1 1

,

1 1 .

1

.

44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

SV SV SV SV SV SV SV SV SV SV SV SV SV SV

sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

50 10 11 51 52 53 54 55 56 57 58 5

59 60 61 62 63 64 65 66 67 6 12 68 69 70 71 72 73 74 75 76 77 78 79 80 81

-1210 -1073 -1337 -1235 -1225 -1241 -1171 -1299 -1298 -1289 -1310 -1962 -1315 -1323 -1387 -1407 -1444 -1465 -1474 -1609 -1689 -2211 -1776 -1776 -1728 -1887 -1967 -1959 -2010 -1967 -2121 -2151 -2155 -2202 -2393 -2401 -2443

1207 1071 1337 1234 1224 1240 1170 1298 1297 1288 1309 1962 1314 1322 1386 1406 1443 1464 1473 1608 1688 2214 1774 1774 1726 1886 1967 1958 2010 1967 2121 2151 2155 2202 2393 2401 2443

1070 1339

, ,

1243^ , ,

.

1962

1322 , ,

1446

,

1605 ,

2214 1774 1774 1728

. , ,

2006 , , , , . , , .

-1 2

3

3

-3

2

-4

1 1

1

1

1

1

1 ,

1 1 1 1

1

997 981

.

996 ,

, , , , ,

935 ,

746 ,

993 ,

994 ,

970 983 727 993

, . ,

994 , , ^ , , .

.

184 172 330 139 168 89 165 149 204 166 138 240 198 169 248 284 266 178 178

1 149 202 264 244 184 202 149 252 228 149 228 149 252 252 252 276 278 276

1070 1339

. .

1244 . , , ,

,

1962 ,

1323 , ,

1447 , ,

1605 ,

2214 1774 1774 1727

, . ,

2006 , , , , , , , .

1 1

I 1

1

1 1

1 1

1 ,

1 1 1

1 1

1

Quantitation Keport File: a8M3B230S

^̂ ̂I>

4)ata: .88M3B2502. TI 08/01/88 7:08:00 Sample; 807138-16 Conds.: IUL 1L->2X1ML Standard ID: 2-BNA-7-1A Sensitivity ID: 2491

Instrument: 5100 Analyst: RJT Inst Cali:

AMOUNT=AREA • REF AMNT/(REK AREA • RESP FACT) Resp. fac. from Library Entry NO 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34

No 1 2 3 4 3 6 7 8 9 10 11 12 13 14 15 16 17

NAME ISl IS2 I S3 IS4 IS3 IS6 SS2 SSI SS3 SS4 SSS SS6 65A 24A 26B 27B 63B SB

22A IB

35B 62B 64A 68B 3B

84B 66B

1.4-DICHL0R0BENZENE-D4 NAPHTHALENE-DS ACENAPHTHENE-PHENANTHRENE-CHRYSENE-D12 PEHYLENE-D12 PHEN0L-D5

•D8 -DIO

2 FLUOROPHENOL NITROBENZENE--D5

t

2-FLUCROBIPHENYL 2.4.6-TRIBROMOPHENOL TEHPHENYL-D14 PHENOL 2-CHLOROPHENOL 1.3-DICHLOROBENZENE 1,4-DICHLOROBENZENE N-NITROSO-DI--N-PROPYLAMINE 1. 2. 4-TRICHLOROBENZENE 4-CHL0R0-3-METHYLPHEN0L ACENAPHTHENE 2.4-DINITROTOLUENE N-NITROSODIPHENYLAMINE PENTACHLOROPHENOL DI N-BUTYLPHTHALATE BENZIDINE PYRENE BIS(2-eTHYLHEXYL)PHTHALATE

CYCLOHEXENE UNKNOWN D4-1 .4-DICHLaROBENZENE

IS 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34

180 107 153 89 169 266 149 184 202 149 RIC RIC RIC RIC RIC RIC RIC

858 . 995 1191 1244 1323 1447 1605 1774 1727 2006 174

1254 640 862 1186 1459 2214

14: 16: 19: 20: 2 ^ : 24: 26: 29: 28: 33: 2:

20: 10: 14: 19: 24: 36:

18 35 51 44 03 07 45 34 47 26 54 54 40 22 46 19 54

c

2 3 3 4 4 4 5 5 5

31 31 30 31 32 33 34

0. 1. 1. 1. 0. 0. 1. 0. 0. 1. 0. 1. 1. 1. 1. 1. 1.

995 154 004 049 907 992 100 904 880 022 202 455 000 000 000 000 000

A A A A A A A A A A A A A A A A A

EB BB BB BB BB BB BB BB BB BB BB VB BB BB BV VB BB

91812. 189585. 252585. 63691. 1750.

49157. 369778.

4978. 291919.

4288. 505319. 249864. 1067060. 1208050. 79798S. 860048. 309873.

41. 80. 44. 40. 0.

78. 40. 58. 50. 1.

41 20. 40. 40. 40. 40. 40.

235 311 254 910 7/4 056 155 930 880 077 827 633 000 000 000 000 000

NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NC/UL NG/UL NG/UL NG/UL

UG/L UG/L UG/L UG/L UC/L

2. 5. 2 2. 0. 5. 2. 3. 3. 0. 2. 1. 2. 2. 2. 2. 2.

61-16 34 63 05 01 53 77 27 OV 67 33 57 57 57 57 57

73 f Ub-y ^373 y

7^T0-7UA

/7ys.̂ AnalyticalTechnologies, Inc

ACCESSION: 806130

QUALITY CONTROL DATA: 482-4 & 881-2 METHOD 625

CLIENT: MONTGOMERY & ASSOCIATES UNITS: ug/l ANALYSIS DATE: 7/31/88

TRUE VALUE .SAMPLE RESULTS ^ '7i>7^t

£P7̂ bZ^ 'U>L>l 3 0

T^KJ'^UAI DATA: 88M3B2493 #1 CALI: 88M3B2493 «2

RIC 87/31/88 22:23:88 SRrrCE: EP0_QC_^D CONDS.: riL RANGE: G 1,2688 LABEL: N 8, 4.8 QUAN: A 8, 1.8 J 8 BASE: U 28,

SCANS 388 TO 2688

188.8-1

RIC

I

483456.

LUU 588 1888

16:48 1588 25:88

\>^.4>V«

2888 33:28

JULLw — \ 2588 41:48

SCAN TIME

7\ c.-"M gL L^tLA ;ai/̂ iiUAKu:s Kt::iUL; ::a GĈS 3/N/A

AHALTSIi :ATA:

ANALYST:

- g " ^ / 97ad2^ f3

^JT ^/5

.OARAWETc.̂ "^286

Bis (2-c,Tionjetiiyl) ether

1,3-Oi CTl orobenzene

1,2-Oi c l l orobenzene

Mi trosodi -n-propyl aaine

Isopiiorone

Sis (2-CJi]oroet.*ioxy)aiethane

1,2,4-Tri CTl orobenzene

Hexacnl orobutadi ene

2-Ch1oronaontftalene

2,6-Oinitrotoluene

2,4-Oinitrotoluene

Oietftyl Pht.*ialate

Hexac.ll orobenzene

Phenantiirene

Oi-n-butyl Phthalate

Pyrene

Benzo (a) anthracene

Oi-n-octyl Phthalate

Benzo (k) f luoran thene

PARAMETER WP881

Phenol

2-Chlorophenol

2-Nitrophenol

2,4-OimeWyl phenol

2,4-Oic.Tloropnenol

4-Chloro-3-iTiethyl phenol

2,4,o-Tri cnl orophenol

4-Ni troone.no 1

2-Mec.nyl-4,5-dim" t rophenol

Pencacnioroonenol

OETEv RESULTS MUST 8£ GREATER

TRUE VALUE

50

50

50

50

50

50

50

50

50

50

50

50

50

50

50

50

50

50

50

125

150

125

75

125

112.5

125

125

375

137.5

THA/I ZERO

SAMPIE RESULT

97 HI-yr yz Vf y r HI y? n HI-r? HI iu 5-h V 2

S'L.

5 - / ro

7 ^ / ^ '

//s-u ^ /

1 0 1

1 Z \ / I O

Z'iO

/ f J

UARNINe LIMITS

21.5 -

8.4 -

24.3 -

6.3 -

23.3 -

24.5 -

28.7 -

18.9 -

32.3 -

34.1 -

23.3 -0 -

3.9 -

32.6 -

4.2 -

34.3 -

20.9 -

9.3 -

12.6 -

20.3 -

54.3 -

56.3 -

31.4 -

65.3 -

45.9 -

65.5 -

16.3 -

198.3 -

71.3 -

63.0

76.9

56.0

99.0

90.1

82.4

64.5

51.1

56.3

68.4

63.5

50.0

70.3

54.4

55.5

50.0

66.5

65.9

72.9

125.0

180.6

208.5

31.3

152.3

144.0

161.5

133.3

375.3 184.5

http://Hexac.llhttp://troone.no

'.OCEDURE T̂A FILE :FERENCE ^ME LIST REPORT

DIAGNOSTIC REPORT TCA 88M3B2493 88M3B2493 Kl INITIALIZATION OPTION XI

7/31/88 23:07:31


STANDARDS -»ROC USED POSS

2 2 2 2 2 2 2 2 1

2 2 2 2 2

2 8

>< PLUS UNKNOWNS >< - LIST NAMES - > RMS PROC USED POSS RMS STANDARD/UNKNOWN

2 119 11 7 4 621 Xl/Zl 1 0 9 3 1 178 Xl/ZA 1 0 9 7 1 284 X2/Z2 1 0 9 6 1 616 X2/ZB 2 170 12 5 2 257 X3/Z3 1 0 12 6 2 804 X3/ZC 1 0 11 9 1 432 X4/Z4 1 0 10 8 3 372 X5/Z5 0 0 7 3 1 352 X6/Z6


COMPOUND X NO LIB ENTRY REF 1 SV 2 SV 3 SV 4 SV 5 SV 6 SV 7 SV 8 SV 9 SV 10 SV 11 SV 12 SV 13 SV 14 SV 15 SV 16 SV 17 SV 18 SV 19 SV 20 SV 21 SV 22 SV 23 SV 24 SV 25 SV 26 SV 27 SV 28 SV 29 SV 30 SV 31 SV 32 SV 33 SV 34 SV 35 SV 36 SV 37 SV 38 SV 39 SV 40 SV 41 SV

1 2 14 15 16 17 18 19 20 21 22 7 8 23 24 25 26 27 3

28 29 30 31 32 33 34 9

35 36 37 38 39 40 4

41 42 43 44 45 46 47

-644 -866 -239 -613 -600 -617 -615 -637 -647 -680 -677 -611 -449 -710 -710 -737 -734 -729

-1189 -748 -793 -803 -828 -867 -843 -849 -745 -861 -869 -902 -910 -988 -996

-1461 -1041 -1057 -1063 -1083 -1114 -1164 -1158

PRED 643 865 246 614 601 617 616 637 647 679 676 610 450 709 709 735 732 727 1186 748 793 803 828 867 843 849 741 858 866 899 907 986 994 1459 1038 1054 1060 1081 1112 1162 1156

— SEARCH — SEL DELTA 644 864

.

621 , ,

619 636 636

,

676 , , . , .

731 ,

1186 ,

791 804 829

,

841 854

.

860 ,

892 905 993

,

1460

1058 1058 1080

, ,

1 -1

•

7

^

3 -1

-11

-1

-2 -1 1 .

-2 5 .

2 ,

-7 -2 9 ,

1 .

4 -2 -1 , ,

PEAKS 2 1

1

^

1 1 2 ,

2 ,

, , ,

,

\ • ,

2

2

,

>< SAT >< FIT PEAKS M/Z 990 985

979

, ,

974 994 995

, .

994 , , . . , ,

995

995

995 985 997

,

994 997

,

989 ,

973 996 977

.

946

1000 989 999

152 136 42 94 93 93 128 146 146 108 146 99 112 108 45 108 70 117 164 77 82 139 122 122 93 162 82 180 128 127 225 107 142 188 237 196 196 162 65 163 152

CHRO : TOP DELTA PEAKS 643 863

,

622 , ^

619 636 636

,

676 , . , , ,

731 ,

1186 ,

791 804 829

,

840 854

,

859 ,

892 905 996

.

1460 ,

1056 1058 1080

, , ,

--

-

-

L 1 I 1

,

I 1 , ,

1 1 1 ,

1 . . . . .

I 1

1 1

1 1

.

.

.

43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80


sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

49 50 10. 11 51 52 53 54 55 56 57 58 5

59 60 61 62 63 64 65 66 67 6 12 68 69 70 71 72 73 74 75 76 77 78 79 80 81

-1195 -1210 -1073 -1337 -1235 -1225 -1241 -1171 -1299 -1298 -1289 -1310 -1962 -1315 -1323 -1387 -1407 -1444 -1465 -1474 -1609 -1689 -2211 -1776 -1776 -1728 -1887 -1967 -1959 -2010 -1967 -2121 -2151 -2155 -2202 -2393 -2401 -2443

1193 1208 1076 1338 1237 1227 1243 1174 1300 1299 1290 1311 1962 1314 1322 1386 1406 1443 1464 1473 1607 1687 2214 1774 1774 1726 1886 1966 1958 2009 1966 2117 2154 2159 2217 2454 2463 2515

,

1251 ,

1243 1170 1296

, , ,

1962 1319 1322

, 1405 1447 1464 1464 1605

, 2214

, 1774 1728

, 1969 1959 2006 1959 2117 2157 2157

, , , .

, ,

14 .

-4 -4

,

5 . .

-1 4 ,

-9 -2 , , ,

2 , 3 1

-3 -7 , 3

-2 , .

,

. ,

1

1 2 1

,

1 1 1 . 1 1 1 1 1

1 , 3 1

1 1 1 1 1 1 1

, ,

977

997 994 998

, , ,

932 992 973

, 994 993 986 986 996

, 977

, 748 989

, 571 986 946 983 988 928 986

, , , ,

133 184 172 330 139 168 89 165 149

• 204 166 138 240 198 169 248 284 266 178 178

1 149 202 264 244 184 202 149 232 228 149 228

1 149 252 252 252 276 278 276

.

1251

1243 1171 1296

, . ,

1962 1319 1322

, 1405 1447 1464 1464 1605

, 2214

, ,

1728 ,

1969 1959 2006 1959 2117 2157 2157

.

. , ,

1

1 I 1

1

.

1 1 1 . 1 1 1 1 1 , 1

. •

1 ,

1 1 1 1 1 1 1

.

.

.

.

Data: 88M3B2493.TI 07/31/ds 22;23:00 Sample: EPA QC STD Conds. : IUL Standard ID: 2-BNA-5-1 Sensitivity ID: 2491

Instrument: 5100 Analyst: RJT I m t Cali:

AMOUNT»AREA » RE- AMNT/(REF Resp. NO 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

fac. NAME ISl IS2 I S3 184 ISS 186 18B 26B 25B 63B S4B 43B SB 52B 20B 35B 36B 70B 9B

81B 68B 84B 720 69B 74B

m/z 152 136 164 188 240 264 93 146 146 70 82 93 180 223 162 89 163 149 284 178 149 202 228 149 252

from

1,4-

Library En • AREA • RESP itry

DICHL0R0BENZENE-D4 NAPHTHALENE-D8 ACENAPHTHENE-PHENANTHRENE CHHYSFNE-D12 PEHYLENE-D12 BIS 1.3-1,2-

-D8 -Die •

(2-CHLOROETHYL) ETHER DICHLOROBENZENE DICHLOROBENZENE

N-NITROSO-DI-ISOPHORONE BIS 1,2.

•

-N-PROPYLAMINE

(2-CHLOROETHOXY) METHANE 4-TRICHLOROBENZENE

HEXACHLOROBUTADIENE 2-CHLORONAPHTHALENE 2, 4-2,6-

DINITROTOLUENE DINITROTOLUENE

DIETHYLPHTHALATE HEXACHLOROBENZENE PHENANTHRENE DI N l-BUTYLPHTHALATE PYRENE BENZO(A)ANTHRACENE DI-N l-OCTYLPHTHALATE (BENZO(K)FLUORANTHENE

Scan 643 863 1186 1460 1962 2214 617 636 676 731 791 840 859 905 1080 1243 1171 1296 1405 1464 1605 1728 1959 2117 2157

lime 1 10: 43 14:23 19: 46 24: 20 32:42 36: 54 10: 17 10:36 11: 16 12: 11 13: 11 14:00 14: 19 15:05 13:00 20: 43 19:31 21: 36 23:25 24:24 26: 45 23: 48 32: 39 35: 17 35: 57

•

\J W ^ I I W A V I W .1 U I I r\ t;̂ p • u. I n V \rf

Data: 88M3B2493.TI 07/31/88 22:^23:00 Sample: EPA QC STD Cond*. : IUL Standard ID: 2-BNA-5-1 Sensitivity ID: 2491

Instrument: 5100 Analyst: RJT Inst Cali

AMOUNT-AREA • REF AMNT/(REF AREA • Resp, NO 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16

. fac. NAME ISl IS2 I S3 IS4 ISS IS6 65A 24A 57A 34A 31A 22A 21A S8A 60A 64A

m/z 152 136 164 188 240 264 94 128 139 122 162 107 196 139 198 266

from

1,4-

L ibrari L| EntT 'y

DICHL0R0BENZENE-D4 NAPHTHALENE-1 ACENAPHTHENE PHENANT HRENE CHRYSENE-D12 PEHYLF.NE-D12 PHENOL

D8 -D8 -DIO

2-CHLOROPHENOL 2-NITROPHENOL 2.4-2.4-

•DIMETHYLPHENOL •DICHLOROPHENOL

» RESP

4-CHL0R0-3-METHYLPHEN0L 2,4. 6-TRICHLOROPHENOL 4-NITHOPHENOL 4,6-•DINITRO-: S-METHYLPHENOL PENTACHLOROPHENQL

Scan 643 863 1186 1460 1962 2214 622 619 804 829 854 996 1058 1231 1319 1447

1 ime 1 10:43 14:23 19: 46 24:20 32: 42 36: 54 10:22 10: 19 13:24 13:49 14: 14 16:36 17: 38 20: 51 21: 59 24:07

Ref 1 2 3 4 5 6 1 1 2 2 2 2 3 3 4 4

0. 0. 0. 0. 0. 1. 0. 1. 0. 0.

RRT 000 000 000 000 000 000 967 963 932 961 990 154 892 055 903 991

Meth A BV A BB A BB A BV A BB A B3 A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB

FACT)

Area(Hght) 61200.

246380. 153877. 25J358. 199537. 154081. 171584. 214306. 126240. 104089. 138371. 187838. 127840. 77987.

206129. 95310.

Amount 40. 40. 40. 40. 40. 40. 96.

131. US. 62. 81. 100. 121. 110. 390. 192.

000 000 000 000 000 000 329 376 430 579 247 841 473 275 112 842

NG/UL NC/UL NG/UL NG/Ui. NG/UL NG/UL NG/Ul NG/UL NG/UL NG/UL NG/UL NG/UL NO/UL NG/UL NG/UL NG/UL

7.1 2. 2. 2. 2. 2. 2. 5. 7. 6. 3. 4. 5. 7. 6.

23. 11.

foi 31 31 31 31 31 31 57 60 3f. 6ii 70 33 OS* 33 56 15

^/A Ozs-

RIC 87/31/88 21:11:88 SArPLET 58/88NG BNA STD CONDS.: IUL RANGE: G 1,2688 LABEL: N 8, 4.8

DATA: CALI :

QUAN

te/3o y77U7 -A77yi

88n362492 ftl 88I13B2492 ft2

: A 8 , 1.8 J 8

SCANS 388 TO 2688

BASE: U 28, 3 188.8-1

rv

lhi o

Q (M z . D 00 o ta u. V,

r-t

Cf n t v -X

IV

Q .. UJ I -

=.JC < Ul >-• a Z UJ •- X U. Ul

t - t < z O t-t H U.

RIC

488768.

588 f̂ ^ s r \

1888 1588 2888 2588 41'4fl

SCAN TTME

{OCEDURE STA F ILE iFERENCE >»ME L IST

REPORT

DIAGNOSTIC REPORT 'TCA 88M3B2492 . , 88M3B2492 ' ' ^ Kl INITIALIZATION OPTION XI

7/31/88 21: SS:05


STANDARDS 'ROC USED POSS

2 2 2 2 2 2 2 2 2 1

2 2 2 2 2 2 2 10

>< PLUS UNKNOWNS — >< - LIST NAMES - > RMS PROC USED POSS RMS STANDARD/UNKNOWN 0 11 11 96 472 Xl/Zl 0 9 9 48 330 Xl/ZA 0 9 9 3 788 X2/Z2 O 7 9 4 463 X2/ZB

184 12 12 6 436 X3/Z3 0 12 11 2 187 X3/ZC 0 11 11 4 237 X4/Z4 0 10 10 4 167 XS/ZS 0 7 7 8 214 X6/Z6


COMPOUND >< NO LIB ENTRY REF 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 2S 26 27 28 29 30 31 32 33 34 33 36 37 38 39 40


sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

1 2 14 15 16 17 18 19 20 21 22 7 8

23 24 25 26 27 3

28 29 30 31 32 33 34 9

35 36 37 38 39 40 4

41 42 43 44 45 46

-644 -866 -239 -613 -600 -617 -615 -637 -647 -680 -677 -611 -449 -710 -710 -737 -734 -729 -1189 -748 -793 -SOS -828 -867 -843 -849 -745 -861 -869 -902 -910 -988 -996

-1461 -1041 -10S7 -1063 -1083 -1114 -1164

PRED 642 863 253 616 604 620 618 639 649 681 678 616 459 712 712 738 733 730 1183 732 796 808 831 869 846 8S2 744 860 868 901 909 987 993 14S8 1040 10S6 1062 1082 1113 1163

— SEARCH — SEL DELTA 642 863 2S4 621 605 617 619 635 643 691 67S 619 459 717 707 747 732 723 1183 747 791 804 834 879 841 866 744 859 866 906 906 997 993 1439 1037 1039 1039 1080 1118 1160

, ,

1 5 1

-3 1

-4 -4 10 -3 3 ,

5 -5 9

-3 -5 .

-5 -5 -4 3 10 -3 14 ,

-1 -2 5

-3

10 ,

1 -3 3 -3 -2 5

-3

PEAKS 1 1 2 1 1 1 1 2 4 2 3 1 4 3 1 2 2 1 1 3 1 1 1 1 1 I 1 1 1 2 I 1 2 2 1 1 1 3 1 1

>< SAT >< FIT PEAKS M/Z 990 979 894 963 996 949 919 993 993 997 992 983 984 994 974 983 994 989 993 993 997 978 997 989 996 917 984 990 994 929 991 831 998 947 993 997 987 998 982 996

152 136 42 94 93 93 128 146 146 108 146 99 112 108 45

• 108 70 117 164 77 82 139 122 122 93 162 82 180 128 127 223 107 142 186 237 196 196 162 63 163

CHRO : TOP DELTA PEAKS 642 863

, ,

621 606 1 616 -1 620 ] 635 643 691 673 619 439 717 707 747 732 723 118S 747 791 804 834 878 841

.

744 839 866 908 90S 998 995 1439 1037 1039 1039 1080 1118 1160

L 1 L 1 L 1

1 1

2 1 1 1 1 1

44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80


sv sv sv sv sv sv . sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

50 -1210 , 10 -1073 11 -1337 51 -1235 52 -1225 53 -1241 54 -1171 53 -1299 56 -1298 57 -1289 58 -1310 5 -1962

59 -1315 60 -1323 61 -1387 62 -1407 63 -1444 64 -1465 63 -1474 66 -1609 67 -1689 6 -2211 12-1776 68 -1776 69 -1728 70 -1887 71 -1967 72 -1939 73 -2010 74 -1967 75 -2121 76 -2131 77 -2155 78 -2202 79 -2393 80 -2401 81 -2443

1209 1070 1335 1233 1223 1239 1169 1297 1296 1287 1308 1962 1314 1322 1386 1406 1443 1464 1473 1608 1688 2214 1774 1774 1726 1886 1967 1959 2010 1967 2121 2151 2156 2204 2400 2408 2431

1218 1070 1338

,

1222 1242 1169 1293 1295 1286 1310 1962 1318 1321 1384 1403 1447 1463 1472 1605 1688 2214 1774 1774 1728 1884 1968 1959 2007 1967 2118 2153 2157 2204 2401 2405 2452

9 ,

3 .

-1 3 ,

-2 -1 -1 2 ,

4 -1 -2 -1 4 -1 -1 -3 , , , ,

2 -2 1 ,

-3 ,

-3 2 1 ,

I -3 1

2

2

2

2

2

2 2 2 1 1 1

977 995 986

951 996 996 985 985 892 821 917 994 921 988 990 996 986 986 993 916 965 985 729 985 995 713 982 990 982 994 930 982 983 995 975 988

184 172 330 139 168 89 165 149 204 166 138 240 198 169 248 284 266 178 178

1 149 202 264 244 184 202 149 252 228 149 228

1 149 252 252 252 276 278 276

1218 1070 1338

1222 1242 1169 1293 1293 1286

,

1962 1318 1321 1384 1404 1447 1463 1472 1603 1688 2214 1774 1774 1728 1884 1969 1939 2007 1967 2117 2133 2137 2204 2401 2403 2432

1 1

1 1

1 1

luantitation Report File: 88M3B2492

•ata: 88M3B2492. TI 17/31/88 21: 11: 00 lample: 30/80NG BNA ;onds. : IUL itandard ID: >ensitivity ID: 2491

STD

Instrument: 5100 Analyst: RJT Inst Cali:

\MOUNT=AREA • REF AMNT/(REF AREA « RESP FACT) f rom L i b r a r y E n t r y

1,4-DICHL0R0BENZENE-D4 (SV#1) NAPHTHALENE-DS (SV«2) ACENAPHTHENE-DIO (SV#3) PHENANTHRENE-DIO (SV#4) CHRYSENE-D12 (SV#5) PERYLENE-D12 (SV#6) PHEN0L-D5 (SV»7) 2-FLUOROPHENOL (SV#8) NITROBENZENE-DS (SV*9) 2-FLUOROBIPHENYL (SV»10) 2,4.6-TRIBROMOPHENOL (SV«11) TERPHENYL-D14 (SV«12) N-NITROSODIMETHYLAMINE (SV#14) PHENOL (SVttl5) ANILINE (SV#16) BIS(2-CHLOROETHYL)ETHER (SV#17) 2-CHLOROPHENOL (SV#18) 1,3-DICHLOROBENZENE (SV#19) 1,4-DICHLOROBENZENE (SV#20) BENZYL ALCOHOL (SV4»21) 1,2-DICHLOROBENZENE (SV»22) 2-METHYLPHENOL (SV«23) BIS(2-CHLOROISOPROPYL)ETHER (SV#24) 4-METHYLPHENOL (SV«25) N-NITROSO-DI-N-PROPYLAMINE (SV#26) HEXACHLOROETHANE (SV#27) NITROBENZENE (SV*28) ISOPHORONE (SV#29) 2-NITROPHENOL (SV»30) 2,4-DIMeTHYLPHENOL (SV#31) BENZOIC ACID (SV»32) BIS(2-CHLOROETHOXY)METHANE (SV#33 > 2.4-DICHLOROPHENOL (SV«34) 1,2. 4-TR I CHLOROBENZENE (SV#3S) NAPHTHALENE (SV«36) 4-CHLOROANILINE (SV#37) HEXACHLOROBUTADIENE (SV#38) 4-CHL0R0-3-METHYLPHEN0L (SV#39) 2-METHYLNAPHTHALENE (SV#40) HEXACHLOROCYCLOPENTADIENE (SV#41) 2.4,6-TRICHLOROPHENOL (SV#42) 2.4,5-TRICHLOROPHENOL (SV*43) 2-CHLORONAPHTHALENE (SV«44) 2-NITROANILINE (SV»45) DIMETHYL PHTHALATE (SV»46) ACENAPHTHYLENE (SV#47) 3-NITROANILINE (SV»4a) ACENAPHTHENE (SV#49) 2.4-DINITROPHENOL (SV#50) 4-NITROPHENOL (SV#51)

esp NO 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

. fac NAME ISl IS2 I S3 IS4 ISS IS6 SS2 SSI SS3 SS4 SSS SS6 61B 65A 5H 18B 24A 26B 27B 6H 2SB 2H 42B 4H 63B 12B 56B S4B S7A 34A IH 43B 31A 8B SSB 7H 52B 22A 9H 53B 21A 4H 20B lOH 71B 77B U H IB 59A SSA

No 1 2 . 3 4 5 6 7 3 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 43 46 47 48 49 50

m/z 152 136 164 188 240 264 99 112 82 172 330 244 42 94 93 93 128 146 146 108 146 108 45 108 70 117 77 82 139 122 122 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 153 184 139

Scan 642 863 1185 1459 1962 2214 619 459 744 1070 1338 1774 244 621 606 616 620 635 645 691 675 717 707 747 732 725 747 791 804 834 878 841 869 859 866 908 905 998 993 1037 1059 1059 1080 1118 1160 1156 1118 1191 1218 1257

Time 10:42 14:23 19:45 24: 19 32:42 36: 54 10: 19 7:39 12:24 17: 50 22: 18 29:34 4:04 10:21 10:06 10: 16 10:20 10: 35 10:43 11:31 11: 15 11:57 11:47 12:27 12: 12 12:05 12:27 13: 11 13:24 13: 54 14:38 14:01 14:29 14: 19 14:26 15:08 15:05 16:38 16:35 17: 17 17:39 17:39 18:00 18:38 19:20 19: 16 18:38 19:51 20: 18 20:57

Ref 1 2 3 4 5 6 I 1 2 3 3 5

2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3

RRT 1, 000 1.000 1. 000 1.000 1. 000 1. 000 0. 964 0. 715 0. 862 0. 903 1. 129 0. 904 0. 380 0. 967 0. 944 0. 960 0. 966 0. 989 1. 005 1. 076 1. 051 1. 117 1. 101 1. 164 1. 140 1. 129 0. 866 0. 917 0. 932 0. 966 1. 017 0. 975 1. 007 0. 995 1. 003 1. 052 1.049 1. 156 1. 153 0. 875 0. 894 0. 894 0. 911 0. 943 0. 979 0. 976 0. 943 1. 005 1.028 1.061

Meth A BB A BB A BB A BV A BB A BV A BB A BB A BB A BB A BB A BB M XX A BB A BV A VB A BB A BV A VB A BB A BB A BB A BB A BB A BV A BB A BB A BB A BB A BB A BB A BB M XX A BB A BB A BB A BB A BB A BV A BB A BB A BB A VB A BB A BB A BB A BB A BB A BV ,M XX

Area(Hght) 70316,

281432. 170316. 281680. 204781. 142438. 88558. S94eir.(»lf^^ 100225. 189855. 27053. 195664. 26143. 102328. 26350. 116365. 93711. 112528. 120769. 34034. 118746. 85704. 67821. 85114. 59673. 60468. 151489. 203337. 60880. 94997. 67877. 140706. 97269. 100343. 345240. 34793. 61147. 106386. 319452. 29841. 58242. 58242.

215373. 62109. 262278. 32080S. 72204.

231222. 22513. 62620.

Amount 40,000 NG/UL 40. 000 NG/UL 40.000 NO/UL 40. 000 NG/UL 40.000 NG/UL 40.000 NO/UL 50. 000 NO/UL 50. 000 NO/UL 50.000 NG/UL 50. 000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50.000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NO/UL 80. 000 NG/UL 30. 000 NG/UL 30. 000 NG/UL 30. 000 NG/UL 30.000 NG/UL 50.000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50.000 NG/UL 30.000 NG/UL 50.000 NG/UL 80.000 NG/UL 50. 000 NG/UL 80. 000 NG/UL 50.000 NG/UL 50. 000 NG/UL 80,000 NG/UL 50,000 NG/UL 80.000 NG/UL 80. 000 NG/UL

•/.Tot

0.88 0.88 0. 88 0. 88 0. 88 0. 88 1. 10 1. 10 ^^. 1. 10 1. 10 1. 10 1, 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1.73 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1.7S 1. 10 1.73 1. 10 1. 10 1.75 1. 10 1.75 1.73

^/27yy

No 1 2 3 4 5 6 7 3 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 43 46 47 48 49 50

Ret(L) 10: 42 14:23 19: 45 24: 19 32:42 36: 54 10; 19 7:39 12:24 17: 50 22: 18 29: 34 4:04 10:21 10: 06 10: 16 10:20 10:33 10: 45 11:31 11: 15 11: 57 11:47 12: 27 12: 12 12:03 12:27 13: 11 13:24 13: 54 14:38 14:01 14:29 14: 19 14:26 15:08 15:05 16:38 16:35 17: 17 17:39 17:39 18:00 18:38 19:20 19: 16 18:38 19: 51 20: 18 20: 57

Ratio 00 00

1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

RRT(L) 1. 000 1. 000 1. 000 1. 000

00 00 00 00 00 00 00

1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

1 1 0 0 0 0 1 0 0

0. 0. 0. 1. 1.

000 000 964 715 862 903 129 904 380

0. 967 0. 944

960 966 989 003 076

1. 031 1. 117 1. 101 1. 164 1. 140 1. 129 0. 866 0. 917 0. 932 0. 966 1. 017 0. 973 1. 007 0. 995 1. 003 1. 032 1. 049 1. 136 1. 133 0. 873 0. 894 0. 894 0. 911 0. 943 0. 979 0. 976 0. 943 1. OOS 1. 028 1. 061

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 00 00 00 00 00 00

1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 00 00 00 00 00

1. 00 1. 00 1. 00 1, 00 1. 00 1. 00 1. 00

Amnt 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 80. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 80. 00 50. 00 80. 00 50. 00 50. 00 80. 00 50. 00 80. 00 80. 00

Amnt(L) 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 80. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50, 00 50. 00 50. 00 50. 00 80. 00 50. 00 80. 00 50. 00 30. 00 80. 00 50. 00 80. 00 80. 00

R. Fac R, 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 1. 008 0 7 - 4 4 ^ 0. 285 0. 892 0. 127 0.764 0.297 1. 164 0. 300 1. 324 1. 066 1. 280 1.374 0. 387 1. 331 0. 975 0. 772 0. 968 0. 679 0. 688 0. 431 0. 378 0. 173 0.270 0. 121 0. 400 0.276 0. 283 0. 981 0. 099 0. 174 0. 302 0.908 0. 140 0. 274 0. 171 1.012 0. 182 1. 232 1. 307 0. 212 1. 086 0. 066 0. 184

Fac(L) 000 000 000 000 000 000 008

0. 449 0. 283 0. 892 0. 127 0. 764 0. 297 1, 164 0. 300 1. 324 1. 066 1. 280 1. 374 0. 387 1. 3S1 0. 975 0. 772 0. 968 0. 679 0. 688 0. 431 0. 578 0. 173 0. 270 0. 121 0. 400 0. 276 0. 283 0. 981 0. 099 0. 174 0. 302

908 140 274 171

1. 012 0. 182 232 307 212 086

0. 066 0. 184

Ratio 00

0. 0. 0. 0.

1. 1. 0. 1.

. 00

. 00

. 00

. 00

. 00

.00

. 00 c-T-co

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 0 0

. 00 , 00 . 00 . 00

u d i i b 1 V d I. X u n n ep I O O n J D c i t - T e S

'ata: 88M3B2492. '7/31/88 J lamp: ondl

TI 21: 11:00

le: 50/80NG 3. : IUL

itandard : lensitivi'

ID: by ID:

BNA STD

2491

>MOUNT=AREA « REF AMNT/(REF !esp. NG 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 63 66 67 68 69 70

fac. NAME 8H 3 SB 36B 70B 40B BOB 12H 60A 62B 41B 9B 64A 81B 78B 68B 39B SB 84B 67B 28B 72B 66B 76B 69B 74B 74B 73B 83B 82B 79B

m/z 168 89 165 149 204 166 138 198 169 248 284 266 178 178 149 202 184 202 149 252

from

Instrument An

AREA ̂• Library Entry

DIBENZOFURAN (SV#52) 2,4-1 2, 6-1

:: 3100 lalyst: RJT Inst

' RESP FACT)

DINITROTOLUENE (SVttSO) DINITROTOLUENE (SVtt54)

DIETHYL PHTHALATE (SV#5S) 4-CHLOROPHENYLPHENYL ETHER (SV*56) FLUORENE (SV#57) 4-NlTROANILINE (SVttSB) 2-METHYL-4. 6-DINITROPHENOL (SVtt59> N-NITROSODIPHENYLAMINE (SVtt60) 4-BROMOPHENYLPHENYL ETHER (SVtt61) HEXACHLOROBENZENE (SVtt62) PENTA(:HL0R0PHEN0L (SVtt63) PHENANTHRENE (SVtt64) ANTHRACENE (SVtt65) DI-N' -BUTYL PHTHALATE (SVtt66) FLUORANTHENE (SV»67) BENZIDINE (SVtt68) PYRENE (SVtt69) BUTYL BENZYL PHTHALATE 3,3' -DICHLOROBENZIDINE

(SVtt70) (SVtt71)

BENZO(A)ANTHRACENE (SVtt72) BIS(2-ETHYLHEXYL)PHTHALATE (SV#73) CHRYSENE (SVtt74) DI-N

1

-OCTYL PHTHALATE (SVtt7S> BENZO(B)FLUORANTHENE (SVtt76) BENZO(K)FLUORANTHENE (SVtt77) BENZO(A)PYRENE < :SVtt78) INDENO(1, 2, 3-CD)PYRENE DIBENZO(A. H)ANTHRACENE

(SVtt79) (SVttSO)

BENZO(O.H. DPERYLENE (SVttSl)

Scan 1222 1242 1169 1295 1295 1286 1321, 1318 1321 1384 1404 1447 1463 1472 1603 1688 1774 1728 1884 1969

Time Ref 20:22 3 20:42 3 19:29 3 21:35 3 21:35 3 21:26 3 22:01 3 21:58 4 22:01 4 23:04 4 23:24 4 24: 07 4 24: 23 4 24:32 4 26:43 4 28:08 4 29:34 3 28: 48 3 31:24 5 32: 49 5

RRT 1. 031 1. 048 0. 986 1.093 1. 093 1. 085 1. 115 0. 903 0. 905 0. 949 0.962 0. 992 1. 003 1. 009 1. 100 1. 157 0. 904 0. 881 0. 960 1. 004

Meth A BB A BB A BV A BB A BB A BB M XX A.BV A BB A BB A BB M XX A BV A VB A BV A BV A BB A BB A BB A BV

Area(Hght) 330839. 63070. 35447.

255848. 102796. 242167. 35369. 46996. 98690. 63001. 73992. 439S9.

330927. 348342. 401740. 349432.

3105. 346727. 168398. 37487.

Cali

Afflc SO. 50. 50. 50. 50. 50. 80. 80. 50. 50. SO. 80. SO. SO. 30. 30. 30. 30. 50. 50.

•

lunt 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000

NG/UL NO/UL NO/UL NO/UL NG/UL NG/UL NO/UL NO/UL NO/UL NO/UL NO/UL NG/UL NG/UL NG/UL NO/UL NG/UL NG/UL NO/UL NG/UL NG/UL

7.Tot 10 10 10 10 10 10 7S 73 10 10 10 73 10 10 10 10 10 10 10 10

/ t i .

73 74 75 76 77 78 79 SO

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

l t 7 ^ \ J \ J / J w

228 1967 3S 149 '2117 35 252 2153 35 252 2157 35 252 2204 36 276 2401 4C 278 2405 4C

. c /

!: 47 : 17 »: 53 >: 57 »:44 >:01 ):05

276 2452 40:52

Ret(L) 20:22 20:42 19:29 21:35 21:35 21:26 22:01 21:58 22:01 23:04 23:24 24:07 24:23 24:32 26:45 28:08 29:34 28:48 31:24 32:49 32:39 33:27 32:47 35: 17 35: 53 35: 57 36:44 40:01 40:05 40: 52

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

RRT(L) 1. 031 1. 048 0. 986 1. 093 1. 093 1.085 1. 115 0. 903 0. 905 0. 949 0. 962 0. 992 1. 003 1. 009 1. 100 1. 157 0. 904 0. 881 0. 960 1. 004 0. 998 1.023 1. 003 0. 956 0. 972 0. 974 0. 995 1. 084 1. 086 1. 107

. J

5 6 6 6 6 6 6 6

X , wci%j

1. 003 0. 956 0. 972 0. 974 0. 995 1. 084 1. 086 1. 107

Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00

« B V

A VB A BV A BV A VB A BB A BB A BB A BB

Amnt 50. 00 50. 00 SO. 00 50. 00 50. 00 50. 00 80. 00 80. 00 SO. 00 50. 00 50. 00 80. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. ,00 50. 00 50. 00 50.00 50. 00 50. 00 50. 00 50. 00 50. 00 SO. 00 SO. 00

^ • ^ \ J . J ^ € L .

243297. 377501. 251538. 239378. 228766. 236444. 183364. 182706.

Amnt(L) 50. 00 50. 00 50. 00 50. 00 50. 00 50.00 80. 00 80. 00 50. 00 50. 00 50. 00 80. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50.00 50. 00 50. 00 50. 00 50.00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

>^U. \ J \ J \ J

50. 000 SO. OOO 50. OOC 50. OOC 30, OOC 30. OOC 50. OOC

ii«r/ \/i_

NG/UL NG/UL NG/UL

) NG/UL » NO/UL > NG/UL > NG/UL

50. 000 NG/UL

R.Fac R. 1. 554 0. 296 0. 260 1. 202 0. 483 I. 137 0. 104 0. 083 0.280 0. 179 0. 210 0. 078 0. 997 0. 989 1. 141 0. 992 0.020 1. 355 0. 658 0. 146 1. 021 0.940 0. 950 2. 120 1.413 1. 344 1. 285 1. 328 1. 030 1. 026

Fac(L) 1. 554 0. 296 0. 260 1. 202 0. 483 1. 137 0. 104 0. 083 0. 280 0. 179 0.210 0. 078 0. 997 0. 989 1. 141 0. 992 0. 020 1. 355 0. 658 0. 146 1. 021 0. 940 0. 950 2. 120 1. 413 1. 344 1. 285 1. 328 1. 030 1. 026

X

Ra

X \ J

10 10 10 10 10 10 10 10

tio 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 .00 .00 .00 . 00 . 00 . 00 . 00 .00 . 00

file:///J/J/J

/ tbs AnalyticolTechnologies, Inc

7>7/J.7llA

QUALITY CONTROL DATA ATI I.D.

TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 608) 806130




80613802 07/13/88 AQUEOUS UG/L

COMPOUNDS

DUP. DUP. SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC, RPD

GAMMA BHC HEPTACHLOR ALDRIN DIELDRIN ENDRIN DDT

ND ND ND ND ND ND

2.00 2.00 2.00 2.00 2.00 2.00

2.13 2.00 1.95 1.74 2.59 2.42

107 100 98 87 130 121

1.92 1.87 2.19 1.69 2.98 2.47

96 94 110 85 149 124

10 7 12 3 14 2

% Recovery = (Spike Sample Result - Sample Result)

Spike Concentration 100

RPD (Relative % Difference) (Spiked Sample - Duplicate Spike) Result S

Documents

SFUND RECORDS CTR 88015257 SFUND RECORDS CTR AR0556 … · 2018-01-23 · a\ analyticaltechnologies, sfund records ctr 88015257 inc sfund records ctr 0222-00704 ar0556 quality control