Transcript
Page 1: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

APICAL : Polyimide FilmCONTENTS

DescriptionAPICAL AV

GradePhysical PropertiesTensile Stress Strain CurvesStress Relaxation and CreepIsotropy of Tensile ModulusThermal PropertiesThermal AgingDimensional StabilityElectrical PropertiesChemical PropertiesAlkaline ResistanceAdhesion PropertiesAPICAL AF

GradePhysical PropertiesThermal PropertiesElectrical PropertiesChemical PropertiesAPICAL NP

GradePhysical PropertiesIsotropy of Tensile ModulusThermal PropertiesDimensional Stability - 1 -Dimensional Stability - 2 -Electrical PropertiesChemical PropertiesAlkaline ResistanceCOMPARISON DATA

APICAL DIVISION KANEKA TEXAS CORPORATION

6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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United States

APICAL DIVISION

KANEKA TEXAS CORPORATION

6161 Underwood Rd.Pasadena, TX 77507U.S.A.800-222-8128FAX: 281-291-2110

Europe

KANEKA BELGIUM N.V.

Boulevard Du Triomphe 1731160 Brussels Belgium32-2-672-0190FAX: 32-2-675 22 68

Japan

KANEKA CORPORATION

1-12-32, Akasaka, Minato-kuTokyo 107 Japan81-3-5574-8101FAX: 81-3-5574-8401

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Page 2: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

APICAL : Polyimide FilmDESCRIPTIONAPICAL polyimide film possesses an excellent balance of physical, thermal, electrical and chemi-cal properties over a wide range of temperature (-269°C [-452°F] to 400°C [752°F]). More precise thickness control, superior web flatness, plus improved adhesion and excellent dimen-sional stability are standard features with Apical polyimide films. Applications for APICAL poly-imide film include flexible printed circuits (FPC),tape automated bonding (TAB), motor generator insulation, wire and cable insulation, bar code label and pressure sensitive tape. APICAL is produced by the polycondensation reaction between an aromatic dianhydride and an aromatic diamine.APICAL DIVISION KANEKA TEXAS CORPORATION PRODUCES THREE TYPES OF APICAL FILM.

APICAL AVAPICAL AV has been sucessfully used in appli-cations where a wide operating temperature (-269°C to 400°C) combined with excellent physical, electrical and chemical properties is

-ture is as follows.

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APICAL AFAPICAL AF is a FEP fluoropolymer resin coated/laminated polyimide film developed for high temperature applications where heat sealabil-ity or improved moisture and chemical resistance is required. APICAL AF is available in a variety of constructions. (see Table 7)

APICAL NPAPICAL NP is developed by using state of the art technology designed specifically for applications where superior dimensional stability is essential. The superior dimensional stability characteristics of Apical NP make it particularly well suited for use in FPC and TAB applications.

=

O

C

N

=

O

C

=

C

O

=

C

O

N O

n

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APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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Page 3: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

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®APICAL : Polyimide FilmTABLE 1 APICAL AV GRADES

PRODUCT NOMINAL THICKNESS APPROXIMATE AREA FACTOR

50AV 0.5 12.5 56 27575AV 0.75 19.0 36 175100AV 1.0 25.0 28 138200AV 2.0 50.0 14 69300AV 3.0 75.0 9 46500AV 5.0 125.0 6 27100AVY* 1.0 25.0 28 138

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APICAL DIVISION KANEKA TEXAS CORPORATION 800-222-8128

DISCLAIMER:

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APICAL : Polyimide FilmTable 2 PHYSICAL PROPERTIES OF APICAL AV(APICAL 100AV 1MIL)

PROPERTY UNIT TYPICAL VALUE TEST METHOD -195°C 23°C 200°CUltimate Tensile Strength (MD) psi 48,000 35,000 20,000 ASTM D-882 Mpa 330 241 138Yield Point at 3% Elongation (MD) psi 10,000 6,000 ASTM D-882 Mpa 69 41Stress at 5% Elongation (MD) psi 13,000 8,000 ASTM D-882 Mpa 90 55Ultimate Elongation % 20 95 103 ASTM D-882Tensile Modulus psi 610,000 460,000 260,000 ASTM D-882 Gpa 4.2 3.2 1.8Folding Endurance cycles >100,000 ASTM D-2176 Tear Strength Propagating g 7 ASTM-1938(Single tear) lbs 0.02Tear Strength Initial g 520 ASTM D-1004(Graves) lbs 1.15Density g/cm 1.42 ASTM D-1505Coefficient of Friction [Kinetic] - 0.40 ASTM D-1894(Film to Film)Coefficient of Friction [Static] - 0.50 ASTM D-1894(Film to Film)

APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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®APICAL : Polyimide Film

TENSILE STRESS STRAIN CURVES OF

APICAL AV

The usual values of tensile strength, tensile

modulus, and ultimate elongation at various

temperatures appear in the typical stress strain

curves shown in Figure 1. Such properties as

tensile strength and modulus decrease at higher

temperature, while elongation reaches a maxi-

mum value at about 200°C (392°F).

Other factors, such as humidity and film thickness

have only a negligible effect on the shape of the

stress strain curves.

120100806040

Strain (%)

200

0

50

100

150

Stress

(MPa)

200

250

300

FIGURE 1

TENSILE STRESS STRAIN CURVES

(APICAL 100AV 1MIL)

APICAL DIVISION KANEKA TEXAS CORPORATION

6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110

www.kanekatexas.com

DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or

warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion

described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or

warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume

that toxicity data or safety measures are fully indicated or that other measures may not be required.

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Stress relaxation is shown in Figure 2 and Creep is shown in Figure 3. Stress relaxation and Creep can happen during film processing or in application.

Ratio of Stress(%)

105

100

95

90

850 10 20 30 40 50 60 70

Time (Minutes)

Stress relaxation is observed as the film is strained by elongation.

0.05

0.04

0.03

0.01

0

0.02

0 10 20 30 40 50 60 70

Figure 3 CREEP

(APICAL 100AV 1MIL) INITIAL STRESS 5688psi

Time (Minutes)

Creep is observed as the film is strained by stress.

Strain(%)

Figure 2 STRESS RELAXATION

(APICAL 100AV 1MIL) INITIAL STRAIN 0.3%

APICAL : Polyimide FilmSTRESS RELAXATION AND CREEP OF

APICAL AV

APICAL DIVISION KANEKA TEXAS CORPORATION

6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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Page 7: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

APICAL : Polyimide FilmISOTROPY OF TENSILE MODULUS OF

APICAL AV

2.0

0

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Figure 4 ISOTROPY OF TENSILE MODULUS

(APICAL 100AV 1MIL) (UNIT: GPa)

2.0

0

2.0

0

E C W

MD

DD (Left) 4.0 DD (Right)MD

DD (Left) 4.0 DD (Right)MD

DD (Left) 4.0 DD (Right)

TDTDTD

E (East), C (Center), W (West) describe the location on the web.Measurement was done in four directions across the web (Machine direction [MD],Transverse direction [TD] and 2 Diagonal directions [DD]), shown as dots.

®Tensile Modulus of Apical AV is isotropicFigure 4 describes the isotropy of tensile modulus at positions across the web.

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APICAL DIVISION KANEKA TEXAS CORPORATION

6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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Page 8: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

ASTM E 794

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®Table 3 THERMAL PROPERTIES OF APICAL AV(APICAL 100AV 1MIL)

PROPERTY UNIT TYPICAL VALUE TEST METHOD

APICAL DIVISION KANEKA TEXAS CORPORATION

DISCLAIMER:

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Page 9: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

APICAL : Polyimide Film

THERMAL AGING OF APICAL AVThe life of APICAL polyimide film at high

temperature significantly depends on the environ-

ment. APICAL is degraded by oxygen. Its useful

life in nitrogen is at least an order of magnitude

greater than in air. The weight loss characteristics

of APICAL in air and nitrogen at elevated

temperatures are shown in Figure 5 and the

isothermal weight loss in air at several tempera-

tures is shown in Figure 6.

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Figure 5 WEIGHT LOSS BY USING THERMOGRAVIMETRIC ANALYSIS(APICAL 100AV 1MIL)

Rate of temperature rise in °C was 10 °C/min. (18° F/min.)

Weight loss

%

Nitrogen

Air

-100

-80

-60

-40

-20

-0

200

(392)

0 400

(752)

600

(1112)

800

(1472)

1000

(1832)

Temperature °C (°F)

Figure 6 ISOTHERMAL WEIGHT LOSS AT SEVERAL TEMPERATURES(APICAL 100AV 1MIL)

2 4 6 8 10 12 14 16 18 200-70

-60

-40

-20

-0

-10

-30

-50

Time (Hours)

Weight loss

%

APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110

www.kanekatexas.com

DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or

warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion

described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or

warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume

that toxicity data or safety measures are fully indicated or that other measures may not be required.

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Page 10: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

MDDD (Left) 4.0 DD (Right)

MDDD (Left) 4.0 DD (Right)

MDDD (Left) 4.0 DD (Right)

temperatures as indicated in Figure 7, Coefficient

of Thermal Expansion (CTE) is also one of the

important factors for dimensional stability. CTE

of Apical is isotropic. The isotropy of CTE on

APICAL AV is shown in Figure 8.

APICAL : Polyimide Film

DIMENSIONAL STABILITY OF APICAL AVShrinkage is one of the important factors for

dimensional stability. APICAL shows residual

shrinkage after its first exposure to elevated

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Figure 7 RESIDUAL SHRINKAGE VS EXPOSURE TIMEAT SEVERAL TEMPERATURES(APICAL 100AV 1MIL)

0.20

0.18

0.16

0.14

0.12

0.10

0.08

0.06

0.04

0.02

020 40 60 80 100 120 140 160 180 2000

Time (Minutes)

Shrinkage %

2

0

E

TD

2

0

2

0

C W

TDTD

Figure 8 ISOTROPY OF CTE (APICAL 100AV 1MIL)

(UNIT: X10 / °C,TEMPERATURE 100-200°C)

E (East),C (Center),W (West) describes the location on the web.

Measurements were done in four directions across the web (Machine direction [MD],

Transverse direction [TO] and 2 Diagonal directions [DO]), shown as dots.

APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110

www.kanekatexas.com

DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or

warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion

described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or

warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume

that toxicity data or safety measures are fully indicated or that other measures may not be required.

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Page 11: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

Dielectric Strength V/mil ASTM D-149 METHOD A 100AV (1mil) 7,800 Type 3 electrodes, 60Hz 200AV (2mil) 5,600 300AV (3mil) 4,600 500AV (5mil) 3,600

Dielectric Constant IPC TM-650 Method 2.5.5.3 100AV (1mil) 3.3 1KHz 3.3 1MHz

Dissipation Factor IPC TM-650 Method 2.5.5.3 100AV (1mil) 0.001 1 KHz 0.005 1MHz

Volume Resistivity ohm-cm ASTM D-257, 500V 100AV (1mil) > 10

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®APICAL : Polyimide FilmTable 4 ELECTRICAL PROPERTIES OF APICAL AV

PROPERTY UNIT TYPICAL VALUE TEST METHOD

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APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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Hygroscopic Coefficient cm/cm/%RH 1.95X10 35°C, 20-80%RHof Expansion

Moisture Absorption % 1.3 23°C, 50%RH 2.9 23°C, immersion 24hrs.

Resistance to Chemicals Tensile properties retained (%) Condition

Chemicals Tensile Elongation Modulus StrengthBenzene 100 85 130 20°C immersion 14daysToluene 100 90 110 20°C immersion 14daysMethanol 100 85 120 20°C immersion 14daysAcetone 95 85 115 20°C immersion 14daysMEK 100 85 115 20°C immersion 14days10% HCI 95 90 115 20°C immersion 14days10% H SO 95 90 120 20°C immersion 14days10% NaOH Degraded Degraded Degraded 20°C immersion 4days5% NaOH 80 75 115 50°C immersion 3min.FeCI 90 70 120 20°C immersion 14daysCuCI 60 55 115 20°C immersion 14daysH OPH = 1 60 20 125 100°C immersion 14daysPH =4 60 30 130 100°C immersion 14daysPH = 7 75 60 120 100°C immersion 14daysPH = 10 20 15 100 100°C immersion 4days

2 4

3

2

2

APICAL : Polyimide FilmTable 5 CHEMICAL PROPERTIES OF APICAL AV(APICAL 100AV 1MIL)

PROPERTY UNIT TYPICAL VALUE TEST METHOD

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APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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APICAL : Polyimide FilmALKALINE RESISTANCE OF APICAL AVAPICAL AV can be etched by caustic solution as shown in Figure 9 and 10. Figure 9 shows the weight loss of APICAL AV in caustic solution.

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Figure 10 shows the etching rate in caustic solution. (Solvent is a mixture of water and ethanol)weight lossof APICAL AV in caustic solution. Figure 10 shows the etching rate in caustic solution. (Solvent is a mixture of water and ethanol)

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Figure 9 WEIGHT LOSS IN CAUSTIC SOLUTION VS EXPOSURE TIME (APICAL 100AV 1MIL.)

Figure 10 ETCHING RATE IN CAUSTIC SOLUTION (APICAL 100AV 1MIL.)

0 1.0 2.0 3.00

5

10

15

Weight Loss%

Time in caustic solution (Minutes)

0 20 40 60 80 100

1.0

2.0

3.0

Etching rate(%/Min.)

Weight of Ethanol to Water (wt%)

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APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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APICAL : Polyimide Film

Table 6 ADHESION PROPERTIES OF APICAL AV(APICAL 100AV 1MIL)

PROPERTY UNIT TYPICAL VALUE TEST METHOD

APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110

www.kanekatexas.com

DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or

warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion

described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or

warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume

that toxicity data or safety measures are fully indicated or that other measures may not be required.

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Contact angle ° 40 Water, 20°C, 50%RH,1atm

Surface tension dyne/cm 60 ASTM D2578

Peel strength p/i 6.2 Kaneka Method using Kaneka

kg/cm 1.1 proprietary Epoxy adhesive

Page 15: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

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®Table 7 GRADE OF APICAL AF

PRODUCT NOMINAL THICKNESS CONSTRUCTION (MIL) APPROXIMATE AREA FACTOR

APICAL DIVISION KANEKA TEXAS CORPORATION

DISCLAIMER:

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Page 16: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

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®APICAL : Polyimide FilmTable 7 GRADE OF APICAL AF

PRODUCT NOMINAL THICKNESS CONSTRUCTION (MIL) APPROXIMATE AREA FACTOR

2 2

APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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J11A7 0.95 24.1 0.1 0.75 0.1 28 135

P50A10 1.5 38.1 0.0 1.0 0.5 16 81

P77A10 2.4 61.0 0.7 1.0 0.7 15 77

T10A10 1.1 28.1 0.1 1.0 0.0 24 116

T10N10 1.1 27.4 0.1 1.0 0.0 24 117

T11A7 0.95 24 0.1 0.75 0.1 26 128

T11N7 0.9 22.9 0.1 0.7 0.1 27 133

T11N10 1.2 30.0 0.1 1.0 0.1 21 103

T55N10 2.0 50.3 0.5 1.0 0.5 11 56

T55N20 3.0 75.4 0.5 2.0 0.5 8 39

130EF616B 1.3 33.0 0.15 1.0 0.15 21 101

150AF019B 1.5 38.1 0.0 1.0 0.5 16 79

Page 17: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

120AF616 150AF019 200AF919Ultimate Tensile Strength [23°C] psi 28,000 23,000 20,000 ASTM D-882(MD) Mpa 193 159 138 [200°C] psi 14,500 13,500 10,700 Mpa 100 93 74

Stress at 5% Elongation [23°C] psi 10,500 8,500 7,100 ASTM D-882(MD) Mpa 72 59 49 [200°C] psi 7,000 5,700 4,300 Mpa 48 39 30

Ultimate Elongation [23°C] % 90 95 100 ASTM D-882 [200°C] psi 100 105 105

Tensile Modulus [23°C] psi 405,000 343,000 310,000 ASTM D-2176 Gpa 2.8 2.4 2.1 [200C] psi 205,000 185,000 130,000 Gpa 1.4 1.3 0.9

Tear Strength Propagating g 12 25 34 ASTM D-1938(Single tear) Ibs 0.03 0.06 0.08

Tear Strength Initial g 590 700 800 ASTM D-1004(Graves) Ibs 1.32 1.55 1.77

Density g/cm 1.53 1.67 1.79 ASTM D-1505

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®APICAL : Polyimide FilmTable 8 PHYSICAL PROPERTIES OF APICAL AF

PROPERTY UNIT TYPICAL VALUE METHOD

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APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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120AF616 150AF019 200AF919Shrinkage MD % 0.08 0.09 0.12 IPC TM-650 2.2.4 TD 0.03 0.02 0.03 Method AHeat seal Strength MIL P-461128Coated side to coated side g/in 1,000 1,200 1,100Coated side to uncoated side - 900 -

Table 10 ELECTRICAL PROPERTIES OF APICAL AF

PROPERTY UNIT TYPICAL VALUE TEST METHOD

120AF616 150AF019 200AF919Dielectric Strength V/mil 6,900 5,000 4,800 ASTM D-149 METHOD A Type 3 electrodes, 60Hz

Dielectric Constant - 3.1 2.7 2.5 ASTM D-150 AC 1KHz

Dissipation Factor - 0.0014 0.0012 0.0008 ASTM D-150 AC 1KHz Volume Resistivity ohm-cm >10 >10 >10 ASTM D-257 DC 500V 1minute

Table 11 CHEMICAL PROPERTIES OF APICAL AF

PROPERTY UNIT TYPICAL VALUE TEST METHOD

120AF616 150AF019 200AF919Moisture Absorption % 0.8 0.8 0.4 23°C, 50%RH 1.7 1.7 1.2 23°C, immersion 24hrs.

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APICAL : Polyimide FilmTable 9 THERMAL PROPERTIES OF APICAL AF

PROPERTY UNIT TYPICAL VALUE TEST METHOD

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APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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Page 19: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

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®APICAL : Polyimide FilmTable 12 GRADE OF APICAL NP

PROPERTY NOMINAL THICKNESS APPROXIMATE AREA FACTOR

50NP 0.5 12.5 55 269100NP 1.0 25.0 28 135200NP 2.0 50.0 14 67300NP 3.0 75.0 9 45500NP 5.0 125.0 6 27

2 2

APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110

DISCLAIMER:

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Page 20: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

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Ultimate Tensile Strength (MD) psi 44,000 ASTM D-882

Mpa 303

Ultimate Elongation % 90 ASTM D-882

Tensile Modulus psi 600,000 ASTM D-2176

Gpa 4.1

Folding Endurance cycles >100,000 ASTM D-2176

Tear Strength Propagating g 7 ASTM-1938

(Single tear) lbs 0.02

Tear Strength Initial g 600 ASTM D-1004

(Graves) Ibs 1.33

Density g/Cm 1.45 ASTM D-1505

Coefficient of Friction Kinetic 0.50 ASTM D-1894

Contact Angle ° 40 Water, 20°C, 50%RH, 1atm

Surface Tension dyne/cm 60 ASTM D2578

Peel Strength p/i 6.2 Kaneka Method using

kg/cm 1.1 Kaneka propietary

Epoxy adhesive

APICAL : Polyimide Film

Table 13 PHYSICAL PROPERTIES OF APICAL NP(APICAL 100NP 1MIL)

PROPERTY UNIT TYPICAL VALUE TEST METHOD

3

APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110

www.kanekatexas.com

DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or

warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion

described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or

warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume

that toxicity data or safety measures are fully indicated or that other measures may not be required.

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Page 21: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

MD

DD (Left) 4.0 DD (Right)MD

DD (Left) 4.0 DD (Right)MD

DD (Left) 4.0 DD (Right)

APICAL : Polyimide FilmISOTROPY OF TENSILE MODULUS OF

APICAL NP

Tensile Modulus of APICAL NP is isotropic.

Figure 9 describes the isotropy of tensile modulus at positions across the web. APICAL NP is designed specifically for applications where superior dimensional stability is essential.

2.0

0

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Figure 9 ISOTROPY OF TENSILE MODULUS

(APICAL 100NP 1MIL) (UNIT: GPa)

2.0

0

2.0

0

E C W

TDTDTD

E (East), C (Center), W (West) describe the location on the web.Measurement was done in four directions across the web (Machine direction [MD],Transverse direction [TD] and 2 Diagonal directions [DD]), shown as dots.

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APICAL DIVISION KANEKA TEXAS CORPORATION

6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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Page 22: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

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®APICAL : Polyimide FilmTable 14 THERMAL PROPERTIES OF APICAL NP(APICAL 100NP 1MIL)

PROPERTY UNIT TYPICAL VALUE TEST METHOD

0.8X101.6X101.8X10

-5

-5

-5

APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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50-150°C Thermal Mechanical 100-200°C Analyzer 150-250°C

Mechanical 200 UL 7468

Flammability 94V-0 UL94Shrinkage % IPC TM-650 2.2.4 Method A 150°C 30min. 0.04 200°C 2hrs. 0.08 400°C 2hrs. 0.65

Page 23: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

MDDD (Left) 4 DD (Right)

MDDD (Left) 4 DD (Right)

MDDD (Left) 4 DD (Right)

for dimensional stability. CTE at several tempera-ture is shown in Figure 10. CTE of APICAL is isotropic. The isotropy of CTE on APICAL NP is shown in Figure 11.

APICAL : Polyimide FilmDIMENSIONAL STABILITY OF APICAL NP -1- Coefficient of thermal expansion (CTE), Tensile modulus and Shrinkage are the important factors

2

0

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Figure 11 ISOTROPY OF CTE (APICAL 100NP 1MIL) (UNIT: X 10 /°C, TEMPERATURE

2

TDTD

E (East), C (Center), W (West) describe the location on the web.Measurement was done in four directions across the web (Machine direction [MD],Transverse direction [TD] and 2 Diagonal directions [DD]), shown as dots.

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0

Figure 10 THERMAL EXPANSION PER 1DCVS TEMPERATURE (APICAL 100NP 1MIL)

0 50 (122) 100 (212) 150 (302) 200 (392)0

1

2

3

4

5

CTE-5

2

TD0

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APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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Page 24: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

the degree of shrinkage in Transverse direction (TD) when the film is elongated in Machine direction (MD) as shown in Figure 13. Shrinkage of NP is the same as AV shown in Figure 7.

APICAL : Polyimide FilmDIMENSIONAL STABILITY OF APICAL NP - 2 -

Tensile modulus changes according to the tempera-ture as shown in Figure 12. Poisson's ratio indicates

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Figure 12 MODULUS VS TEMPERATURE

(APICAL 100NP 1MIL)

0 50 (122)

100 (212)

150 (302)

200 (392)

0

1

2

3

4

5

TensileModulus

(GPa)

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0 50 (122)

100 (212)

150 (302)

200 (392)

0

0.2

0.4

PoissonsRatio

0.6

0.8

10

Figure 13 Poisson’s Ratio

(APICAL 100NP 1MIL)

APICAL DIVISION KANEKA TEXAS CORPORATION

6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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APICAL : Polyimide FilmTable 15 ELECTRICAL PROPERTIES OF APICAL NP(APICAL 100NP 1MIL)

PROPERTY UNIT TYPICAL VALUE TEST METHOD

16

APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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Dielectric Strength V/mil 8,000 ASTM D-149 METHOD A Type 3 electrodes, 60HzDielectric Constant IPC-TM 650 Method2.5.5.3 3.3 1KHz 3.3 1 MHzDissipation Factor IPC-TM 650 Method2.5.5.3 0.001 1 KHz 0.004 1MHzVolume Resistivity ohm-cm > 10 ASTM D-257, 500V

Page 26: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

Hygroscopic Coefficient cm/cm/%RH 0.9X10 35°C, 20-80%RHof Expansion

Moisture Absorption % 1.3 23°C, 50%RH 2.1 23°C, immersion 24hrs.

Resistance to Chemicals Tensile Properties retained (%) ConditionChemicals Tensile Strength Elongation ModulusBenzene 100 100 100 20°C immersion 14daysToluene 100 100 100 20°C immersion 14daysMethanol 100 100 100 20°C immersion 14daysAcetone 95 100 100 20°C immersion 14daysMEK 100 100 100 20°C immersion 14days10% HCI 95 90 100 20°C immersion 14days10% H SO 95 90 100 20°C immersion 14days10% NaOH Degraded Degraded Degraded 20°C immersion 4days5% NaOH 80 75 100 50°C immersion 3min.FeCI 90 100 100 20°C immersion 14daysCuCI 60 55 100 20°C immersion 14days

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2 4

3

2

APICAL : Polyimide FilmTable 16 CHEMICAL PROPERTIES OF APICAL NP(APICAL 100NP 1MIL)

PROPERTY UNIT TYPICAL VALUE TEST METHOD

APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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Page 27: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

weight loss of APICAL NP in caustic solution. Figure 15 shows the etching rate in caustic solution (Solvent is a mixture of water and ethanol).

APICAL : Polyimide FilmALKALINE RESISTANCE OF APICAL NPAPICAL NP can be etched by caustic solution as shown in Figure 14 and 15. Figure 14 shows the

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Figure 14 WEIGHT LOSS IN CAUSTIC SOLUTION VS EXPOSURE TIME (APICAL 100NP 1MIL)

Figure 15 ETCHING RATE IN CAUSTIC SOLUTION (APICAL 100NP 1MIL)

0 100

810

16

Weight Loss%

Time in caustic solution (Minutes)

0 20 40 60 80 100

1.0

2.0

3.0

Etching rate(%/Min.)

Weight of Ethanol to Water (wt%)

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0

1412

642

5 15 20 25 30

APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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Page 28: APICAL : Polyimide Film CONTENTS United States APICAL ...APICAL: Polyimide Film DESCRIPTION APICAL polyimide film possesses an excellent balance of physical, thermal, electrical and

APICAL : Polyimide FilmTABLE 17 COMPARISON DATA

PROPERTY UNIT APICAL APICAL COMPETlTOR* TEST METHOD Ultimate Tensile Strength psi 35,000 44,000 33,500 ASTM D-882(MD) Mpa 241 303 231Ultimate Elongation % 95 90 72 ASTM D-882Tensile Modulus psi 460,000 600,000 370,000 ASTM D-2176 Gpa 3.2 4.1 2.5Density g/cm 1.42 1.45 1.42 ASTM D-1505Coefficient of Friction Kinetic 0.40 0.50 0.48 ASTM D-1894Flammability 94 V-O 94 V-O 94 V-O UL94Coefficient of 3.2X10 1.6X10 3.2X10 Thermal MechanicalThermal Expansion Analyzer(100°C - 200°C)Shrinkage % IPC TM 650, 2.2.4150 - 30min 0.04 0.04 0.03 Method ADielectric Strength V/mil 7,800 8,000 7,700 ASTM D-149Moisture Absorption % ASTM D-57050%RH at 23°C 1.3 1.3 1.8Immersion for 24hrs. at 23°C 2.9 2.1 2.8'These data are derived from OU PONT catalog. (Kapton Type VN film)

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100AV 100NP

-5

-3

APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.

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