Download pdf - HERCULES Hercules Incorporated · 2020. 11. 17. · HERCULES Hercules Incorporated 1010 Marshall Road Jacksonville. AR 72076 (501) 982-9481 July 2, 1987 CERTIFIED MAIL Ms. Diane R

.(J;lHERCULES

Ms. Kate Arthur Environmental Scientist United States Environmental Protection Agency Region VI Superfund Enforcement Section Allied Bank Tower At Fountain Place 1445 Ross Avenue Dallas, Texas 75202

Dear Ms. Arthur:

May 16, 1988

Hercules Incorporated 1010 Marshall Road Jacksonville, AR 72076 (501) 982-9481

As requested, please find enclosed the following information:

• Copies of all available self-monitoring data reports submitted to Jacksonville Wastewater Utility (as required by the Utility issued permit). These reports include daily french drain flow rates, daily discharge rates to the Utility's sewer, and analytical data for the french drains and combined wastewaters (before and after pre-treatment). The point designated "Outfall 002" is the final sampling and metering point (onsite) before pre-treated site waters enter the Utility's sewer system. All of the analyses shown in these reports are performed internally using liquid chromatography.

• A summary ( "Wastewater Pre-treatment Operation Effluent Data") of analytical data, January, 1987 to date, for the Outfall 002 discharge point. These data are our contract laboratory results from composite samples collected by the Utility. The analyses for the phenols were done by gas chromatography.

• A copy of our Industrial Discharge Permit issued by the Utility. Please note that the permit limits for phenols and phenoxyherbicides are in terms of mass flow rate.

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As you may know, the treatment of site wastewaters is done with a twobed activated carbon system (arranged in series). The carbon is changed from the first bed when breakthrough of chlorinated phenols across the first bed reaches the low mg/1 level. Once the carbon is drummed out and replaced with fresh carbon, the previous "first bed" is reconfigured as the second bed in series and the "second bed" becomes the first bed.

80687

Ms. Kate Arthur Environmental Protection Agency May 16, 1988 Page two ...-I

0 0

If you have any questions concerning the enclosed, please contact me at ( 501 l 982-9481. c:,o

MJF:bb

Enclosures

cc D. J. Keilman without attachment

Cl':) Sincerely, <l')

r'-HERCULES INCORPORATED ,-f Jackspnville Facility 0

:1r/l., ;· . ~~ i 1jf///~-vu· · / ( ✓l~'-i

Michael J. Falco Senior Environmental Engineer

{£HERCULES

CERTIFIED MAIL

Ms. Diane R. Martini Industrial Monitoring Supervisor Jacksonville Wastewater Utility Post Office Box 623 Jacksonville, AR 72076

Dear Diane:

July 2, 1987

Hercules Incorporated 1010 Marshall Road Jacksonville. AR 72076 (501) 982-9481

C

Please find attached a report of the analytical and flow data for the period May 21, 1987 through June 20, 1987. These data are submitted pursuant to our compliance with Addendum III, item (4) of our Discharge Pretreatment Permit.

If you have any questions, please contact me.

MJF:bb

Attachment

cc File

Sincerely,

HERCULES INCORPORATED Jacksonville Facility

Michael J .' Falco Senior Environmental Engineer Site Manager

HERCULES INCORPORAT~ Jacksonville Facility Internal Monitoring

All Concentrations in mg/1

DATE REASOR-HILL FR. DRAIN NORTH BURIAL FR. DRAIN SOUTH FR. DRAIN 2,4-D 2, 4-DCP 2,4-D 2,4-DCP 2,4-D 2,4-DCP

05/21/87

05/22/87

05/23/87

05/24/87

05/25/87 64.4 22.6 " -

05/26/87 5.6 2.0

05/27/87 1.5 0.4c

05/28/87

05/29/87

05/30/87

05/31/87

06/01/87 63 22

06/02/87

06/03/87

06/04/87 28 24

06/05/87 0.4 0.6

06/06/87

06/07/87

06/08/87

06/09/87 40 10 6.9 <1.0

06/10/87 <0.5 <0.5 06/11/87

06/12/87

06/13/87

06/14/87

06/15/87 99 47

06/16/87 l.3 0.5

06/17/87 <O.S <0.5

06/18/87

06/19/87

06/20/87

HERCULES INCORPORATED Jae onville Facility Interna '1onitoring Flow Data All Flows in Gal.wns/Day

DATE SANITARY 002 REASOR-HILL NORTH SOO'I DRAIN DRAIN DRAJ

05/21/87 1,100 9,625 2,550 3,930 3::

05/22/87 690 71,751 890 4,750 2E

05/23/87 725 71,373 2,480 5,820 5

05/24/87 1,195 76,051 1,540 5,960 31

05/25/87 1,030 31,668 2,550 6,250 28

05/26/87 1,280 27,283 840 5,570 21

05/27/87 1,030 15,715 2,490 5,990 28

05/28/87 720 12,786 950 5,230 >15

05/29/87 940 8,665 1,820 5,280 ~27 05/30/87 780 28,933 1,450 4,260 21

05/31/87 1,150 34,762 2,580 6,390 15

06/01/87 1,680 38,995 790 6,650 32

06/02/87 1,060 30,497 2,600 5,420 22

06/03/87 2,280 19,418 1,300 4,920 29

06/04/87 16,170 15,977 1,860 5,650 10

06/05/87 520 10,820 990 4,350 24

06/06/87 530 13,790 2,490 4,190 13

06/07/87 390 12,175 840 4,620 21

06/08/87 490 12,973 2,520 2,840 5 06/09/87 2,080 13,866 1,450 3~660 10

06/10/87 2,260 31,233 330 2,860 16 06/11/87 14,840 55,976 2,530 2,790 9 06/12/87 2,010 22,102 1,370 3,010 4

06/13/87 3,460 71,562 1,770 4,430 92 06/14/87 2,020 33,982 1,320 3,870 44 06/15/87 2,510 64,000 2,430 8,594 59 06/16/87 1,940 34,131 1,410 10,136 55 06/17/87 2,940 35,973 1,580 7,720 1,11

06/18/87 2,040 63,322 1,550 8,190 2,00 06/19/87 1,820 29,438 1,370 6,430 1,25 06/20/87 1,620 19,890 1,490 5,400 ~

TOTALS 73,300 1,018,732 53,130 165,160 12,57'

HERCULES INCORPORATED Jackt ,ville Facility Internal .1itoring


DATE WASTE WATER TO WASTE WATER TO OUTFALL 1st Bed 2nd Bed 002

2,4-D 2,4-DCP 2,4-D 2,4-DCP 2,4-D 2,4-DCP

05/21/87 164 87 33.8 18 2.2 0.6

05/22/87 36.9 16.4 11.9 3.2 2.5 0.6

05/23/87

05/24/87

05/25/87 28 8.2 5.6 1.5 1.84 0. 6 -;-

05/26/87 32.9 15.4 1.8 0.6

05/27/87 27.8 16.9 5.1 2.0 2.1 0.6>

05/28/87 42 12 8.1 0.4 1.8 0.6,:::

05/29/87 32 9.3 4.7 3.0 0.8 0.3

05/30/87

05/31/87

06/01/87 34 9.2 4.5 1. 2 1.1 0.6

06/02/87 19.5 14 4.0 1.3 0.6 0.4

06/03/87 38 30.6 4.7 2.8 0.8 0.3

06/04/87 37 15 4.9 1. 4 0.75 0.4

06/05/87 48 11.8 10.2 1.6 0.5 <0.5

06/06/87 48 12 5.8 1.2 1.0 0.4

06/07/87

06/08/98

06/09/87 45 11 6.3 1.0 0.6 0.2

06/10/87 62 40 7.5 0.95 0.8 <1.0

06/11/87 38 12.9 5.8 0.9 <0.5 <0.53

06/12/87

06/13/87

06/14/87

06/15/87 36.5 11.8 7.1 1. 2 0.7 <0.5 06/16/87 28.6 1.2 7.5 <0.5 0.8 1. 2

06/17/87 19 5.8 7.9 1. 3 <0.5 <0.5

06/18/87 23.7 7.3 8.5 1.1 0.7 <0.5

06/19/87 49 12 10.3 1.4 <0.5 <0.5

06/20/87

niHERCULES

CERTIFIED MAIL


Dear Diane:

July 29, 1987


0

Please find attached a report of the analytical and flow data for the period June 21, 1987 through July 20, 1987. These data are submitted pursuant to our compliance with Addendum III, item (4) of our Discharge Pretreatment Permit. The flow data reported for 002, beginning on July 11, 1987, are from the new meter installed at the 002 outfall.


MJF:bb

Attachment

cc File

Sincerely,

HERCULES INCORPORATED

:;i~~t,Y Michael.;(;:;:~-Senior Environmental Engineer Site Manager

(, i. u


Jacksonville Facility Internal Monitoring


DATE REASOR-HILL FR. DRAIN NORTH BURIAL FR. DRAIN SOUTH FR. DRAIN COMBINED LEACHATE 2,4-D 2,4,DCP 2,4-D 2,4-DCP 2,4-D 2,4-DCP 2,4-D 2,4-DCP

06/29/87 216.0 102.0 49.0 47.0 0.7 0.2 40.9 8.9

07/13/87 227.0 67.0 62.0 52.0 0.6 0.2 75.0 22.0

07/20/87 318.0 86.0 68.0 61.0 2.1 0.2 124.0 42.0



All Concentrations in mg/l (06/22/87)

Combined Reasor-Hill N. Burial

Leachate Leachate Leachate

Phenol 0.574 0.205 1. 37

2-Chlorophenol 0.420 0.217 1.22

4-Chlorophenol 5.38 2. 77 7.52

2,4-Dichlorophenol 10.3 20.3 18.6


2,4,5-Trichlorophenol 8.45 34.3 13.3


2,4-Dichlorophenoxyacetic acid 7.16 6.40 2.44


2,4,5-Trichlorophenoxyacetic acid 1. 93 2.04 0.39

(07/06/87)

Phenol 1.45 2.21 1. 53

2-Chlorophenol 1.82 5.63 1.19






2,4-Dichlorophenoxyacetic acid 10.l 37.4 4.21


2,4,5-Trichlorophenoxyacetic acid 2.49 8.01 0.632

2-(2,4,5-Trichlorophenoxy) Propionic 0.0496 acid

S.Fr. Dr,

Leacltc!-b

ND~

ND-·::-~

Ntr:

ND

ND

ND

ND

ND

ND

ND

ND

ND

0,016

0.03E

0.135

0.064

0.084

ND

ND

ND


Jacksonville Facility Internal Monitoring All Concentrations in mg/1

DATE WASTE WATER TO WASTE WATER TO OUTFALL 1st Bed 2nd Bed 002

2,4-D 2,4-DCP 2,4-D 2,4-DCP 2,4-D 2,4-DCP

06/21/87

06/22/87

06/23/87 39 11 .7. 8 1.1 <0.5 <0.5

06/24/87 29 6.5 9.l 4.4 <0.5 <0.5

06/25/87 31.1 9.8 13.7 1.8 1.4 <0.5

06/26/87 29.9 7.6 1.2 1.2 <l.0 <l. o_· __

06/27/87 C

06/28/87

06/29/87 42 8.6 11.4 1. 3 <1.0 <1.0

06/30/87 41.2 8.2 10.4 1.3 <1.0 <1.0

07/01/87 39 7.9 19. 0.6 1.0 0.68

07/02/87 34.9 8.4 14.7 1.8 1.6 0.7

07/03/87 220 23 85.6 1.5 11.8 4.5

07/04/87

07/05/87

07/06/87 35 4.5 3.9 0.6 0.4 0.3

07/07/87 68 12 6.0 0.8 0.96 0.3

07/08/87 60 11 5.0 0.7 0.7 0.3

07/09/87 46 6.2 7.9 2.7 0.7 0.1

07/10/87 39.2 5.9 3.7 0.96 0.6 0.3

07/11/87

07/12/87

07/13/87 51 26 11.6 3.3 21 7.4

07/14/87 44.3 13.5 5.3 2.0 1. 7 0.4

07/15/87 24.5 8.7 10.6 11.2 0.4 0.12

07/16/87 42 12.7 2.9 0.6 l.l 0.35

07/17/87 58 15.2 3.8 0.7 0.68 0.24

07/18/87

07/19/87

07/20/87 58.6 11.5 4.4 0.96 9.57 0.68


Jacksonville Facility Internal Monitoring Flow Data - All Flows in Gallons/Day

DATE SANITARY 002 REASOR-HILL NORTH SOUTH DRAIN DRAIN DRAIN

06/21/87 1,410 17,126 1,460 5,770 830

06/22/87 1,520 19,703 2,030 5,550 730

06/23/87 1,230 15,794 2,030 5,250 710

06/24/87 5,820 56,302 1,850 6,930 7 ,2)0

06/25/87 2,720 62,900 1,490 11,670 6, 9,!)_0

06/26/87 2,150 46,957 1,850 7,720 5,650

06/27/87 1,850 21,997 1,400 6,600 "-3,900

06/28/87 1,490 22,898 2,490 5,960 3,3@:9

06/29/87 1,210 18,593 1,410 5,690 2,410

06/30/87 1,200 16,181 810 5,420 2,050

07/01/87 1,870 47,000 2,440 6,670 2,210

07/02/87 900 30,339 1,450 6,830 2,170

07/03/87 13,560 24,593 2,480 5,120 1,890

07/04/87 6,050 14,578 810 5,670 1,340

07/05/87 11,970 23,397 2,430 5,510 1,350

07/06/87 13,760 17,204 1,390 5,540 1,060

07/07/87 3,110 14,135 780 5,030 850

07/08/87 2,670 12,846 2,460 5,600 920

07/09/87 330 22,674 950 4,070 670

07/10/87 370 24,396 1,760 4,540 630

07/11/87 3,250 *14,460 1,440 5,320 580

07/12/87 6,450 15,910 2,360 4,320 510

07/13/87 9,040 14,520 760 4,310 490

07/14/87 680 29,110 1,430 4,430 440

07/15/87 950 49,170 1,940 3,730 390 07/16/87 360 8,190 880 4,050 410

07/17/87 1,690 8,720 2,430 4,740 220 07/18/87 2,560 29,430 1,340 3,880 280

07/19/87 2,600 11,540 280 3,990 270

07/20/87 1,300 7,600 2,400'· 3,770 160

TOTALS 104,070 718,263 49,030 163,680 50,640

*New meter installed

fEJ HERCULES

CERTIFIED MAIL


Dear Diane:

August 27, 1987


Please find attached a report of the analytical and flow data for the period July 21, 1987 through August 20, 1987. These data are submitted pursuant to our compliance with Addendum III, item (4) of our Pretreatment Discharge Permit.


MJF:bb

Attachment

cc File

Sincerely,


~h/4/;f~,, Michael J. Falco Senior Environmental Engineer Site Manager

C



All Concentrations in mg/l

DATE WASTEWATER TO WASTEWATER TO OUTFALL

lst BED 2nd BED 002 2,4-D 2,4-DCP 2,4-D 2,4-DCP 2,4-D 2,4-DCP

07/21/87 73.0 28.0 6.0 2.0 0.7 0.2

07/22/87 58.0 36.0 5.8 l.0 0.7 0.3-

07/23/87 164.0 29.0 108.0 4.9 2.7 o. 2··

07/24/87 62.5 13. 4 24.3 l.6 0.8 0. 5,_ 07/25/87

07/26/87 C

07/27/87 64.0 2.0 ll.5 l.4 0.7 0.2

07/28/87 57.0 16.7 ll.l l.5 0.9 0.3

07/29/87 l0l. 0 42.0 26.2 2l.0 12.4 8.2

07/30/87 78.0 29.0 10.0 2.5 6.4 0.4

07/31/87 148.0 7.2 115.8 3.4 0.5 0.7

08/0l/87

08/02/87

08/03/87 81. 5 16.4 15.l 1.6 0.8 0.7

08/04/87 434.0 219.0 649.0 81.0 4.6 0.

08/05/87 219.0 68.1 213. 0 2l.9 J.5 0.4

08/06/87 88.8 18.0 90.6 2.3 l. 7 0.3

08/07/87 123.0 38.l 44.8 l.3 l.6 0.3

08/08/87

08/09/87

08/10/87 76.4 18.2 7.3 l. (i 1.5 <0.5

08/11/87 49.0 12.0 5.0 l.5 2.0 2.0

08/12/87 42.9 ll.0 3.4 <0.5 l.2 <0.5

08/13/87 8l.5 34.2 7.8 3.6 0.6 0.3

08/14/87 72.0 17.6 2.8 <0.5 l.0 <0.5

08/15/87

08/16/87

08/17/87 92.0 28.0 5.1 1.3 0.7 0.3

08/18/87 86.2 16.7 4.8 <0.5 <0.5 <0.5

08/19/87 64.0 23.0 6.0 2.3 1.1 0.8

08/20/87 57.9 20.7 4.8 0.5 0.7 0.2

HERCULES INCORPORATEC

Jacksonville Facility Internal monitoring

Flow Data - All Flows in Gallons/Day


07/21/87 100 12,430 1,350 3,840 280

07/22/87 210 10,560 1,270 2,950 150

07/23/87 1,910 29,970 1,380 3,850 70

07/24/87 140 9,690 1,340 3,850 150

07/25/87 160 29,430 1,260 3,720 70

07/26/87 60 9,190 1,350 2,990 0-07/27/87 60 7,440 1,770 3,880 6~ 07/28/87 50 5,240 900 2,750 0 07/29/87 200 11,180 1,390 3,730 70 07/30/87 240 9,130 1,700 2,850 0

07/31/87 30 22,960 920 2,840 0

08/01/87 1,060 6,960 ., 1,700 2,780 0

08/02/87 10 9,980 1,280 3,690 0 08/03/87 30 9,500 910 2,640 0 08/04/87 370 3,370 1,680 2,680 0

08/05/87 720 36,770 4,030 5,840 0

08/06/87 40 27,,450 2,400 4,350 0 08/07/87 70 6,890 800 3,380 0 08/08/87 20 6,120 890 3,290 0 08/09/87 9,190 32,600 1,860 4,390 0

08/10/87 10,760 15,010 1,430 3,580 0 08/11/87 2,740 17,250 3,490 4,260 30

08/12/87 50 14,730 2,200 3,430 0

08/13/87 80 5,810 2,170 3,100 0 08/14/87 1,800 13,670 2,060 4,110 0 08/15/87 4,780 3,570 950 2,910 0

08/16/87 2,980 6,620 2,320 3,000 0

08/17/87 20 13,750 1,370 3,820 0

08/18/87 40 8,670 2,760 2,890 0

08/19/87 510 58,010 4,690 4,000 0

08/20/87 680 62,280 4,190 7,490 0 TOTALS 39,110 516,230 57,810 112,880 880




( 07/27/87)

Combined Reasor-Hill N. Burial Leachate Leachate Leachate

Phenol l. 69 l. 75 0.229


4-Chlorophenol 13.20 12.90 2.32




2,4,6-Trichlorophenol 2.12 11.l 0.220



2,4,5-Trichlorophenoxyacetic acid l. 95 11.1 0.249

(08/10/87)

Phenol 3.17 2.12 1.57

2-Chlorophenol 2.95 1.52 l. 39



2,6-Dichlorophenol 8.60 ND 1.80





2,4,5-Trichlorophenoxyacetic acid 13.l 8.42 3.29

2-(2,4,5-Trichlorophenoxy) propionic acid

S.Fr. Dra Leac;;hat

ND .

ND,"--.,,-

NDc

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

0.070

0.007

0.052

ND

0.024

ND

ND



All Concentrations in rng/1

DATE REASOR-HILL FR. DRAIN NORTH BURIAL FR. DRAIN SOUTH FR. DRAIN COMBINED LEACHATE 2, 4-D 2,4-DCP 2,4-D 2,4-DCP 2,4-D 2,4-DCP 2,4-D 2,4-DCP

08/03/87 240 134 26.7 18.5 0.41 0.37 331 220

08/17/87 849 285 10.0 1.4 <0.5 <0.5 113 38

JR HERCULES

CERTIFIED MAIL


Dear Diane:

September 30, 1987


Please find attached a report of the analytical and flow data for the period August 21, 1987 through September 20, 1987. These data are submitted pursuant to our compliance with Addendum III, item (4) of our Pretreatment Discharge Permit.


MJF:bb

Attachment

cc File

Sincerely,

HERCULES INCORPORATED Jack~onville acility

,:/4?{ff )iz (. Michael J. Falco Senior Environmental Engineer Site Manager




09/14/87 COMBINED REASOR-HILL N. BURIAL LEACHATE LEACHATE LEACHATE

Phenol 2.0 3.5 3.5


4-Chlorophenol 23.9* 25.0* 20.0*



2,3,6-Trichlorophenol ND ND ND


2,4,6-Trichlorophenol 13.1 ND ND

2-Chlorophenoxyacetic acid 16.1 11.1 4.6

4-Chlorophenoxyacetic acid 6.3 5.1 ND


2,6-Dichlorophenoxyacetic acid * * * 2,4,5-Trichlorophenoxyacetic acid 85.3 38.3 7.7

2,4,6-Trichlorophenoxyacetic acid 49.1 23.0 13.l

2-(2,4,5-Trichlorophenoxyacetic) ND ND ND Propionic acid

*Reported as 4-Chlorophenol

S.FR. DRAI LEACHATE

ND

ND i'•-

ND·,--~

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND



Flow Data - All Glows in Gallons/Day

DATE SANITARY 002 REA...;OR-HILL NORTH SOUTH DRAIN DRAIN DRAIN

8/21/87 120 33,620 3,870 4,550 0

8/22/87 90 26,440 1,660 5,470 0

8/23/87 so 12,530 3,090 4,080 0

8/24/87 160 11,280 3,640 4,150 0

B/25/87 150 11,850 2,410 3,230 0

'3/26/87 280 12,360 2,530 4,040 0

J/27/87 90 12,730 1,920 3,700 0 C

3/28/87 520 11,480 1,000 3,080 90

3/29/87 150 11,060 2,180 2,950 30

3/30/87 4,570 15,620 800 3,780 0

3/31/87 1,790 21,320 1,350 2,940 0

J/01/87 260 22,790 1,220 2,800 0

)/02/87 410 30,230 820 2,770 0

J/03/87 870 34,550 720 2,720 0 )/04/87 190 19,640 1,800 2,750 0

)/05/87 2,580 19,740 710 2,550 0

J/06/87 1,060 13,340 840 810 0

J/07/87 220 16,060 1,670 1,090 0

l/08/87 180 16,380 860 2,700 0

l/09/87 5,270 14,890 180 1,400 0

1/10/87 10,840 18,430 2,350 1,080 0

l/11/87 470 13,850 180 2,470 0

J/12/87 190 16,560 1,290 2,240 0

l/13/87 200 37,560 1,230 2,360 0 1/14/87 310 29,850 810 2,500 0

1/15/87 210 19 .• 950 700 2,320 0 1/16/87 2,810 48,920 3,890 10,060 60 1/17/87 1,540 99,310 2,030 8,740 2,620

1/18/87 780 73,420 920 5,300 1,240

1/19/87 2,070 49,340 1,880 7,250 990

1/20/87 1,040 49,890 920 3,050 830

'OTALS 39,470 824,990 49,470 108,930 5,800


Jacksonville Facility Internal monitoring


DATE WASTEWATER TO WASTEWATER TO OUTFALL

1st BED 2nd BED 002 2,4-D 2,4-DCP 2,4-D 2,4-DCP 2,4-D 2,4-DCP

08/21/87 49.6 13.7 8.5 1.2 0.68 0.37

08/22/87

08/23/87

08/24/87 80.0 25.9 6.2 1.0 0.5 0.4 .,-

08/25/87 63.4 16.0 5.6 <0.5 0.56 C

<0.5

08/26/87 60.0 16.0 3.1 <0.5 0.4 0.24

08/27/87 71.0 23.0 9.7 1.0 1.3 0.45

08/28/87 78.0 17.8 9.7 1.3 12.0 7.9

08/29/87

08/30/87

08/31/87 86.0 17.0 8.8 <0.5 3.4 0.6

09/01/87 58.0 6.3 10.1 1.9 2.3 0.17

09/02/87 81.0 39.0 7.0 0.9 7.5 6.l

09/03/87 56.0 34.0 6.7 0.8 l.26 0.3

09/04/87 53.0 10.5 7.2 <0.5

09/05/87

09/06/87

09/07/87 56.7 16.0 0.53 0.36 2.2 0.28

09/08/87 80.0 13.6 0.56 0.69 3.7 0.40

09/09/87 67.7 6.4 0.69 0.36 0.78 0.32

09/10/87 61. 7 9.8 33.0 18.1 8.3 2.6

09/11/87 64.3 7.8 0.49 0.62 0.68 0.23 09/12/87

09/13/87

09/14/87 66.7 12.0 0.57 0.23 0.74 0.93

09/15/87 88.0 l7 .6 <0.5 <0.5 <0.5 <0.5

09/16/87 73.8 15.6 <0.5 <0.5 <0.5 <0.5

09/17/87 64.9 7.7 <0.5 <0.5 <0.5 <0.5

09/18/87 43.4 9.9 <0.5 <0.5 <0.5 <0.5

09/19/87

09/20/87




B/3l/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol

2,4,5-Trichlorophenol


2-Chlorophenoxyacetic Acid


2,4-Dichlorophenoxyacetic Acid


2,4,5-Trichlorophenoxyacetic Acid


2-(2,4,5-Trichlorophenoxy) Propionic Acid

9/07/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol




4-Chlorophenoxyacetic Acid 2,4-Dichlorophenoxyacetic Acid




2-(2,4,5-Trichlorophenoxyacetic) Propionic Acid

*Reported as 2-Chlorophenol *Reported as 4-Chlorophenol

COMBINED REASOR-HILL LEACHATE LEACHATE

2.67 4.9

2.68* 7.3*

28.5** 154. **

4.3 25.2

1.2 4.2

17. 30.7

5.9

17.

4.6

l6.6

4.5

* *

**

ll.8

31.9*

46.8**

92.4

l5.2

87.3

16.4

11.4 267.0

102.3

34.5

22.4

*

**

3.0

88.8

20.

ll. 9

9.9

* *

**

8.5

23.4*

48.l**

46.8

7.3

45.

5.5

8.4 169.5

57.5

23.4

6.9

*

N. BURIAL S.FR. DRAI LEACHATE LEACHATE

4.8 ND

7.5* ND

13.7** ND

40.0 N0-

7. 8 N0-

115. 8 ND-17.7

67.6

10.6

10.5

46.

* **

8.0

10.8

40.8*

48.2

7.0

48.7

6.3

10.3

4.8 64.1

17.6

29.6

ND

**

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

DATE

08/24/87

08/31/87

/_ [. 0



REASOR-HILL FR. DRAIN 2,4-D 2,4-DCP

443 41.6

31 4.3


NORTH BURIAL FR. DRAIN 2,4-D 2,4-DCP

1. 75 .21

67.60 40.

SOUTH FR. DRAIN 2,4-D 2,4-DCP

<.005 .010

ND ND

COMBINED LEACHATE 2,4-D 2,4-DCP

108 12.4

88.8 25.

.tfilHERCULES

CERTIFIED MAIL


Dear Diane:

October 27, 1987


Please find attached a report of the analytical and flow data for the period September 21, 1987 through October 20, 1987. These data are submitted pursuant to our compliance with Addendum III, item (4) of our Pretreatment Discharge Permit.


MJF:bb

Attachment

cc File

Sincerely,

HERCULES INCORPORATED Jacksonvi~cility

/lf:1~#i Michael/2. ;alco Senior Environmental Engineer Site Manager

C


Jacksonville, AR Facility Internal Monitorin~



09/21/87 970 32,890 760 4,610 580

09/22/87 890 57,230 930 4,500 420

09/23/87 780 28,610 2,330 4,860 250

09/24/87 750 24,140 270 4,310 240

09/25/87 4,330 26,220 850 4,160 90 >-

09/26/87 570 21,100 1,760 3,770 80 ,---.,_

09/27/87 9,030 19,510 840 4,080 0 '--

09/28/87 9,680 17,280 270 3,930 0

09/29/87 1,420 38,340 2,370 4,420 80

09/30/87 950 76,520 300 5,040 250

10/01/87 2,250 34,020 1.,380 4,360 90

10/02/87 1,040 24,160 1,200 3,260 80

10/03/87 990 20,170 890 4,080 80

10/04/87 1,200 20,450 720 3,950 0

10/05/87 1,020 18,880 850 3,060 0

10/06/87 1,420 23,500 1,780 4,020 0

10/07/87 1,010 19,070 820 2,870 o. 10/08/87 860 17,680 280 2,710 0

10/09/87 640 23,040 2,320 3,650 0

10/10/87 780 16,170 220 2,810 0

10/11/87 640 18,320 920 2,640 0

10/12/87 1,280 18,680 1,250 2,640 0

10/13/87 960 20,030 1,790 2,600 0

10/14/87 1,690 15,890 270 2,200 0

10/15/87 1,430 6,660 830 2,560 0

10/16/87 1,360 10,950 1,320 2,520 30

10/17/87 1,150 8,590 890 2,590 0

10/18/87 720 5,210 260 2,140 0

10/19/87 600 7,580 830 70 0

10/20/87 2,070 26,040 860 5,310 0

'l'OTAL 52,480 696,930 30,360 103,720 2,270


Jacksonville, AR Facility Internal Monitoring


09/28/87 WASTEWATER TO WASTEWATER 1st Bed 2nd Bed

Phenol 7.3 1.36

2-Chlorophenol 1.3 0.98

4-Chlorophenol 16.2* 0.5*

2,4-Dichlorophenol 15.8 0.00

2,6-Dichlorophenol 2.5 1. 98

2,3,6-Trichlorophenol ND ND


2,4,6-Trichlorophenol ND ND 2-Chlorophenoxyacetic acid 3.9 ND

4-Chlorophenoxyacetic acid 2.3 ND

2,4-Dichlorophenoxyacetic acid 56.8 ND

2,6-Dichlorophenoxyacetic acid * *

2,4,5-Trichlorophenoxyacetic acid 8.1 ND

2,3,6-Trichlorophenoxyacetic acid ND ND

2-(2,4,5-Trichlorophenoxy) Propionic acid ND ND

09/29/87

Phenol 4.1 1.4


4-Chlorophenol 16.3* 2.0

2,4-Dichlorop~enol' 13.4 ND

2,6-Dichlorophenol 1.9 ND




2-Chlorophenoxyacetic acid 3.4 8.7



2,6-Dichlorophenoxyacetic acid * ND




TO OUTFALL 002

ND

ND

ND

ND

'ND >·

ND C

ND

ND ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND



All Concentrations in mq/1


Phenol 1. 9 1.6

2-Chlorophenol 0.6 ND





2,4,5-Trichlorophenol 5.3 ND





2,6-Dichlorophenoxyacetic acid * ND



2-(2,4,5-Trichlorophenoxy) ND ND Propionic acid

10/01/87

Phenol 3.15 1. 9

2-Chlorophenol 0.97 <0.2


2,4-Dichlorophenol 14.3 <0.2


2,3,6-Trichlorophenol <0.2 <0.2


2, 4, 6-Trichlorophenol· <0.2 <0.2


4-Chlorophenoxyacetic acid 1. 9 <0.2

2,4-Dichlorophenoxyacetic acid 44.7 <0.2

2,6-Dichlorophenoxyacetic acid * <0.2

2,4,5-Trichlorophenoxyacetic acid 6.1 <0.2

2,4,6-Trichlorophenoxyacetic acid <0.2 <0.2

2-(2,4,5-Trichlorophenoxy) <0.2 <0.2

Propionic acid

TO OUTFl oo; ND

ND

ND

ND

>ND

·'.No C

ND

ND

ND

ND

ND

ND

ND

ND

ND

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

0.28

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2


Jacksonville, AR Facility Internal monitoring


10/02/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol




2-Chlorophenoxyacetic acid


2,4-Dichlorophenoxyacetic acid


2,4,5-Trichlorophenoxyacetic acid


2-(2,4,5-Trichlorophenoxy) Propionic acid

10/05/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











WASTEWATER 1st Bed

3.7

1.1

7.5*

14.6

2.2

<0.3

3.4

<0.3

3.6

2.1

50.4

*

7.4

<0.3

<0.3

4.9

1.6

9.6*

16.9

2.9

<0.2

<0.2

<0.2 4.4

2.5

63.

*

8.5

8.8

<0.2

TO WASTEWATER 2nd Bed

2.25

0.16

0.43

<0.3

<0.3

<0.3

<0.3

<0.3

0.42

<0.3

<0.3

<0.3

<0.3

<0.3

<0.3

2.0

0.52

0.96*

<0.2

<0.2

<0.2

<0.2

<0.2

0.68

1.1

<0.2

*

<0.2

<0.2

<0.2

TO OUTFJ 7icf;

<O.:

<O •:

<O.:

<o •. :

<O~:

<0.3 >--

<Q_. ~

<tt,3

<0.3

<0.3

<0.3

<0.3

<0.3

<0.3

<0.3

<0.2

<0.2

0. 2:

<0.2

<0.2

<0.2

<0.2

<0.2

6.6

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2




10/06/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











10/07/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











WASTEWATER 1st Bed

4.3

1. 3

8.2*

15.4

2.7

<0.2

<0.2

<0.2

4.2

2.2

60.8

*

9.1

3.5

<0.2

4.4

1.8

8.7*

21.0

3.0

<0.2

<0.2

<0.2

3.9

2.3

56.7

*

8.7

<0.2

<0.2


1. 9

<0.5

0.8*

<0.5

<0.5

<0.2

<0.5

<0.5

<0.5

<0.5

<0.5

*

<0.5

<0.5

<0.5

2.3

0.8

1.14

<0.2

<0.2

<0.2

<0.2

<0.2

17.4

<0.2

<0.2

*

<0.2

<0.2

<0.2

TO OUTFJ' ~

o.;; 0.4

<0.2

<0:-.,2

<0;2

<0.2 i.._

<Q... 2

<lk2

<0.2

<0.2

<0.2

<0.2

<O. ?

<.1...

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2





Phenol 4.5 2.1









4-Chlorophenoxyacetic acid 2.4 <0.2

2,4-Dichlorophenoxyacetic acid 41. 4 <0.2




2-(2,4,5-Trichlorophenoxy) <0.2 <0.2 Propionic acid

10/09/87

Phenol 4.4 2.0








2-Chlorophenoxyacetic acid 1.6 11.1 4-Chlorophenoxyacetic acid 2.5 <0.2






TO OUTFAL 002

<0.2

<0.2

<0.2

<0.2

<O .;2·.

<O.~

<O •.. ~

<0._2

<O.C2

<0.2

<0.2

<0.2

<0.?

<.. <

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2 <0.2

<0.2

<0.2

<0.2

<0.2

<0.2




10/12/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











10/13/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol




2-Chlorophenoxyacetic acid 4-Chlorophenoxyacetic acid






WASTEWATER 1st Bed

3.9

1.3

15.3

11.5

1. 9

<0.2

<0.2

<0.2

4.6

2.5

62.7

2.8

8.2

<0.2

<0.2

4.8

1.2

15.3

16.5

3.0

ND

ND

ND

2.7 <0.5

59.5

*

11.5

90.3

ND


2.2

0.42

2.4*

<0.2

<0.2

<0.2

<0.2

<0.2

0. 77

<0.2

<0.2

*

<0.2

<0.2

<0.2

2.3

0.63

1.45*

ND

ND

ND

ND

ND

8.7 0. 77

ND

*

ND

ND

ND

TO OUTF/ ~

<O.:

<O.:

<0.:

<O.;

<9~:

<'0-.:

~Q.-: <:-{}.:

~-= <O.:

<O.:

<O.:

<O.;

<O.;

<O.:

<O.:

ND

ND

ND

ND

ND

· ND

ND

ND

ND

ND

ND

ND

ND

ND





Phenol 4.5 2.1

2-Chlorophenol 1. 4 0.36

4-Chlorophenol 15.9* 1. 9*













10/09/87

Phenol 4.4 2.0















TO OUTFA, ~

<0.2

<0.2

<0.2

<0.2

<q:_,2

<0~2

<ci':-2

<fb2 <0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2




l0/14/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol







2,6-D"ichlorophenoxyacetic acid




10/15/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











WASTEWATER lst Bed

4.0

1.3

15.86

18.2

3.1

<0.5

<0.5

<0.5

4.5

2.8

63.9

<0.5

12.2

11. 9

<0.5

3.7

1. 4

15.9*

17.3

3.0

<0.5

<0.5

<0.5

4.2

2.8

61. 9

*

10.

13.8

<0.5


1.9

<0.5

1.9

ND

ND

ND

ND

ND

15.4

0.83

ND

ND

ND

ND

ND

4.1

0.87

3.4*

<0.5

<0.5

<0.5

<0.5

<0.5

2.4

<0.5

<0.5

*

<0.5

<0.5

<0.5

TO OUTFl' 00~

ND

ND

ND

ND:

Nii

Np_.

ND-N§::

ND

ND

ND

ND

ND ~,~

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND




10/16/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











10/19/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











WASTEWATER 1st Bed

3.7

1.3

<0.5

18.0

2.8

<0.5

<0.5

<0.5

4.0

2.2

60.5

14.8

10.l

<0.5

<0.5

3.5

1.1

<0.5

12.0

2.0

ND

ND

ND

4.3

2.5

63.8

15.l

11.2

7.6

<0.5


1.5

0.3

1.6*

<0.2

<0.2

<0.2

<0.2

<0.2

8.4

<0.2

<0.2

*

<0.2

<0.2

<0.2

2.3

0.37

2.2*

<0.2

<0.2

<0.2

<0.2

<0.2

1.4

<0.2

<0.2

*

<0.2

<0.2

<0.2

TO OUTFl oo;

ND

ND

ND

NJ:)_

Nil

ND ;----

ND

@

ND

ND

ND

ND

ND

ND

NI

<0.;;

<0.L.

<0.2

<0. 2

<0.2

<0.2

<0.2

<0.2

<0.2 <0.2

<0.2

<0.2

<0.2

<0.2

<0.2





Phenol 1.8 2.4


4-Chlorophenol <0.S 1.9*








2,4-Dichlorophenoxyacetic acid 76. <0.2

2,6-Dichlorophenoxyacetic acid 12.5 *



2-(2,4,5-Trichlorophenoxy) 0.13 <0.2 Propionic acid

TO OUTFAL 002

<0.2

<0.2

<0.2

<0 • .2

<0.2

<o:;-:2 <0~2 r--. <0.2

<0.2

<0.2

<0.2

<0

<0.,.

<0.2

<0.2




DATE WASTEWATER TO WASTEWATER TO OUTFALL 1st Bed 2nd Bed 002

2,4-D 2,4-DCP 2,4-D 2,4-DCP 2,4-D 2,4-DCP

09/21/87 38.9 9.8 <0.5 <0.5 <0.5 <0.5

09/22/87 50.1 24.8 <0.5 <0.5 <0.5 <0.5

09/23/87 50.0 16.8 <0.5 <0.5 <0.5 <0.5

09/24/87 44.0 15.0 <0.5 <0.5 <0.5 <0.5 -

09/25/87 77.9 42.8 <0.5 <0.5 <0.5 <0.5

09/26/87 i"-

09/27/87 C

09/28/87 56.8 15.8 ND ND ND· ND

09/29/87 48.8 13.4 ND ND ND ND

09/30/87 39.4 8.5 ND ND ND ND

10/01/87 44.7 14. 3 <0.2 <0.2 <0.2 <0.2

10/02/87 50.4 14.6 <0.3 <0.3 <0.3 <0.3

10/03/87

10/04/87

10/05/87 63.0 16.9 <0.2 <0.2 <0.2 <0.2

10/06/87 60.8 15.4 <0.5 <0.5 <0.2 <0.2

10/07/87 56.7 21. 0 <0.2 <0.2 <0.2 <0.2

10/08/87 41. 4 17.3 <0.2 <0.2 <0.2 <0.2

10/09/87 49.3 15.5 <0.2 <0.2 <0.2 <0.2

10/10/87

10/11/87

10/12/87 62.7 11.5 <0.2 <0.2 <0.2 <0.2

10/13/87 59.5 16.5 ND ND ND ND

10/14/87 63.9 18.2 ND ND ND ND

l0/l5/87 61.9 17.3 <0.5 <0.5 ND ND

10/16/87 60.5 18.0 <0.2 <0.2 ND ND

10/17/87

10/18/87

10/19/87 63.8 12.0 <0.2 <0.2 <0.2 <0.2

10/20/87 76.0 16.2 <0.2 <0.2 <0.2 <0.2


Jacksonville, Facility Internal Monitoring


)9/21/87 COMBINED REASOR-HILL N. BURIAL LEACHATE LEACHATE LEACHATE

'henol 5.9 1.9 3.1


1-Chlorophenol ND 9.5 7.7*

2,4-Dichlorophenol 16.8 74. 26.7



1,4,5-Trichlorophenol 7.8 49.l 12.8




i,4-Dichlorophenoxyacetic acid 47.2 169. 37.3

!,6-Dichlorophenoxyacetic acid ND * *

i,4,5-Trichlorophenoxyacetic acid 8.5 63. 6.1

',4,6-Trichlorophenoxyacetic acid ND 24.9 ND

'.-(2,4,5-Trichlorophenoxyacetic) Propionic acid ND ND ND

Reported as 4-Chlorophenol

S.FR.DRAIN LEACHATE

ND

ND

ND ,-

ND C

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND




09/28/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol








2,4,5-Trichlorophenoxyacetic

2,4,6-Trichlorophenoxyacetic


acid

acid

COMBINED LEACHATE

3.0

2.49

16.9*

22.3

3.0

ND

3.0

ND

2.2

2.4

66.9

*

15.7

ND

ND

REASOR-HILL N. BURIAL LEACHATE LEACHATE

1.5 5.86

l. 3 1.77

34.7* 27.5

5.1 ND

5.66 ND

ND ND

5.3 ND

ND ND

ND ND

ND ND

48.6 5.0

* 10.5

<0.005 ND

21. 4 ND

ND ND

S.FR.DRAI LEACIU\.TE

ND1

,_

ND·-c-C

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND




10/05/87 COMBINED REASOR-HILL N. BURIAL LEACHATE LEACHATE LEACHATE

Phenol 3.5 3.6 6.5


4-Chlorophenol 9.6 19.5 20.75*

2,4-Dichlorophenol 28.7 101. 5 <0.2

2,6-Dichlorophenol 3.7 13. 9 <0.2

2,3,6-Trichlorophenol ND ND <0.2

2,4,5-Trichlorophenol 13.1 46.6 <0.2

2,4,6-Trichlorophenol ND 11. 7 <0.2

2-Chlorophenoxyacetic acid 7.4 29.4 <0.2

4-Chlorophenoxyacetic acid 3.7 12.3 <0.2

2,4-Dichlorophenoxyacetic acid 101. 215.9 5.6

2,6-Dichlorophenoxyacetic acid * * *

2,4,5-Trichlorophenoxyacetic acid 23. 124. <0.2

2,4,6-Trichlorophenoxyacetic acid 2.9 25.7 1.6

2-(2,4,5-Trichlorophenoxy) Propionic acid ND 20.l

S.FR. DRAJ LEACMTI

ND :---

ND

NOC

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND




10/12/87 COMBINED REASOR-HILL N. BURIAL S.FR.b~IJ LEACHATE LEACHATE LEACHATE LEACHATE

Phenol 3.3 2.0 3.5 ND ;--~

2-Chlorophenol 7.7 l. 7 0.7 ND

4-Chlorophenol 18.9 26.9 12.4 ND

2,4-Dichlorophenol 20.0 58.8 <0.2 ND

2,6-Dichlorophenol 3.0 9.3 <0.2 ND

2,3,6-Trichlorophenol <0.2 <0.2 <0.2 ND

2,4,5-Trichlorophenol 11.2 38.0 <0.2 ND

2,4,6-Trichlorophenol <0.2 10.9 <0.2 ND

2-Chlorophenoxyacetic acid 15.l 10.7 <0.2 ND

4-Chlorophenoxyacetic acid 9.5 4.5 <0.2 ND

2,4-Dichlorophenoxyacetic acid 78.3 147. 6 1.3 ND

2,6-Dichlorophenoxyacetic acid 3.8 4.0 4.9 ND

2,4,5-Trichlorophenoxyacetic acid 18.6 56.2 <0.2 ND

2,4,6-Trichlorophenoxyacetic acid <0.2 47.4 <0.2 ND

2-(2,4,5-Trichlorophenoxyacetic) Propionic acid <0.2 7.8 <0.2 MD




L0/19/87

'henol

!-Chlorophenol

1-Chlorophenol

!,4-Dichlorophenol

1,6-Dichlorophenol


!,4,5-Trichlorophenol


!-Chlorophenoxyacetic acid

t-Chlorophenoxyacetic acid

!,4-Dichlorophenoxyacetic acid


',4,5-Trichlorophenoxyacetic

',4,6-Trichlorophenoxyacetic

~-(2,4,5-Trichlorophenoxy) Propionic acid

acid

acid

COMBINED LEACHATE

4.6

1.8

5.4

29.8

4.1

<0.5

15.2

1.8

7.7

3.7

106.

21.4

26.4

<0.5

<0.5

REASOR-HILL N. BURIAL LEACHATE LEACHATE

5.0 4.9

1.9 1.8

4.9 5.6

84.8 16.1

13.0 2.3

<0.5 <0.5

60.5 10.8

15.3 <0.5

37.2 2.9

14.2 <0.5

218.2 25.5

27.l 19.3

87.0 4.9

17.9 <0.5

<4.7 <0.5

S.FR.DRJUN LEACHAII'.E

no samp~ '-'

nnnnnnnnn

unntrHnnnn

"""""""""

nnnnnnnnn

nnn11n11nnn

nnnnn11nnff

nnnnnnt

nnnnn11nnft

nnnnnnnnn

nnnnnnnn"

""""""""" nnnnnnnnn

11nnnn11nnn

j~HERCULES

CERTIFIED MAIL

Ms. Diane R. Martini Industrial Monitoring Supervisor Jacksonville Wastewater Utility Post Office Box 69 Jacksonville, Arkansas 72076

Dear Diane:

November 30, 1987


C

The Hercules' internal monitoring analytical and flow data report for the period October 21, 1987 through November 20, 1987 is enclosed. These data are submitted pursuant to our compliance with Addendum III, item (4) of our Pretreatment Discharge Permit.


MJF:bb

Enclosure

cc File

Sincerely,


~d Michael J. Falco Senior Environmental Engineer Site Manager

HERCULES INCORPORATE

Jacksonville, Arkansas Facility Internal Monitoring


10/21/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











10/22/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











ND= <0.2

WASTEWATER TO 1st Bed

1.8

1.0

<0.2

15.22

2.3

<0.2

5.8

<0.2

1.86

2.7

44.4

9.4

5.9

<0.2

<0.2

2.1

0.86

<0.2

14.8

2.06

<0.2

<0.2

<0.2

2.1

10.3

41. 0

<0.2

4.6

<0.2

<0.2

WASTEWATER TO 2nd Bed

2.5

0.43

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

10.6

<0.2

<0.2

2.1

<0.2

<0.2

<0.2

2.5

0.4

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

13.5

1. 9

<0.2

<0.2

<0.2

<0.2

<0.2

OUTFALL 002

ND

ND

ND

ND

ND -

ND. ,--ND.

NOC

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

HERCULES INCORPORATEL



10/23/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol







2,6-0ichlorophenoxyacetic acid



2-(2,4,5-Trichlorophenoxy} Propionic acid

10/26/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











ND <0.2


4.6

1.27

<0.2

16.1

2.4

<0.2

<0.2

<0.2

6.9

4.4

61.l

14. 4

7.2

9.6

<0.2

2.9

1. 9

*Combined

15.6

1. 95

<0.2

<0.2

<0.2

0.90

2.4

52.4

*13.0

8.3

8.2

<0.2


1.2

0.66

*Combined

<0.2

<0.2

<0.2

<0.2

<0.2

1.5

0.68

<0.2

*1.2

<0.2

<0.2

<0.2

2.5

0.4

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

17.3

<0.2

<0.2

2.3

<0.2

<0.2

<0.2

OUTFALL 002

ND

ND

ND

ND ...

ND

ND i'--

ND ,-..

ND '-'

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

HERCULES INCORPORAT



10/27/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











10/28/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol










2-(2,4,5-Trichlorophenoxy) Propionic acid -


1.7

0.93

<0.2

14.3

1.9

<0.2

2.9

<0.2

6.9

3.9

46.4

10.0

5.5

9.8

<0.2

1.3

0.63

<0.2

9.1

1.18

<0.2

<0.2

<0.2

2.0

1.1

19.0

5.0

<0.2

<0.2

<0.2


2.4

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

8.8

0.68

<0.2

2.2

<0.2

<0.2

<0.2

1.2

1.4

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

2.95

0.69

<0.2

1.2

<0.2

<0.2

<0.2

OUTFALI 002

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.-2

<0.2 ;-~-

<0,.2

<002

<0.2

0.55

<0.2

<O

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2




10/29/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











10/30/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol

2,3,6-Trich~orophenon




4-Chlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid




2-(2,4,5-Trichlorophenoxyl Propionic acid

ND= <0.2


2.8

1.2

<0.5

16.9

2.1

<0.2

1. 4

<0.2

5.0

2.3

54.5

13.7

7.0

2.0

<0.2

3.2

1.6

<0.5

20.0

2.9

<0.5

2.2

<0.5

1.6

1.9

45.9

14.3

7.0

8.6

<0.5


3.9

0.59

<0.5

<0.2

<0.2

<0.2

<0.2

<0.2

9.5

<0.2

<0.2

3.2

<0.2

<0.2

<0.2

4.5

0.7

<0.5

<0.2

<0.2

<0.2

<0.2

<0.2

26.8

<0.2 <0.2

3.8

<0.2

<0.2

<0.2

OUTFALL 002

ND

ND

ND

ND

ND

ND

ND

ND >-

ND,,-

NDC

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND




11/02/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











11/03/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











ND= <0.2


3.4

1.4

<0.5

16.1

2.3

<0.5

<0.5

<0.5

5.7

2.0

52.1

14.9

9.2

<0.5

<0.5

3.4

1.6

<0.5

21.1

2.6

<0.5

3.8

<0.5

3.7

1.9

49.4

15.5

8.9

12.7

<0.5


4.6

0. 72

<0.5

<0.2

<0.2

<0.2

<0.2

<0.2

31.5

<0.2

<0.2

3.4

<0.2

<0.2

<0.2

2.26

0.43

<0.2

0.27

<0.2

<0.2

<0.2

<0.2

16.4

<0.2

0.39

2.3

<0.2

<0.2

<0.2

OUTFALI 002

ND

ND

ND

ND

ND

ND

ND

ND'--

NDC

ND

ND

ND

ND

ND

Nr

ND

ND

ND

ND

ND

ND

ND

ND

ND ND

ND

ND

ND

ND

ND

HERCULES INCORPORATE"



11/04/87 WASTEWATER TO WASTEWATER TO 1st Bed 2nd Bed

Phenol 3.5 2.4


4-Chlorophenol <0.2 <0.2




2,4,5-Trichlorophenol 4.3 <0.2





2,6-Dichlorophenoxyacetic acid 16.1 2.3



2-(2,4,5-Trichlorophenoxy) Propionic acid <0.2 <D.2

11/05/87

Phenol 2.2 2.33








2-Chlorophenoxyacetic acid 6.6 14.5 4-Chlorophenoxyacetic acid 2.6 0.6





2-(2,4,5-Trichlorophenoxy) Propionic acid <0.2 <0.2

OUTFALL 002

<0.2

<0.2

<0.2

<0.2

<0.2

<O. 2.

<0.2

<O.:f'-

<O.~ ,_

<0.2

<0.2

<0.2

<0.2

<0.2

<'

0.53

<0.2

<0.2

3.8

0.14

<0.2

<0.2

<0.2

<0.2 <0.2

4.9

1.5

<0.2

<0.2

<0.2


Jacksonv __ le, Arkansas Facility In~ ,rnal Monitoring



Phenol 7.1 4.8


4-Chlorophenol *Combined <0.2









2,6-Dichlorophenoxyacetic acid *16.8 2.2

2,4,5-Trichlorophenoxyacetic acid 9.3 :<0.2

2,4,6-Trichlorophenoxyacetic acid 19.1 <0.2 2-(2,4,5-Trichlorophenoxy) Propionic acid <0.5 <0.2

11/09/87

Phenol 3.2 1.9




2,6-Dichlorophenol 1. 7 <0.2





4-Chlorophenoxyacetic acid <0.5 <0.2






OUTFALI 002

<0.2

<0.2

<0.2

0.52

<0.2

<O,,? ... -.,

<0.2

<0.2

<o;:2

<De} 0.60

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

HERCULES INCORPORATEr

Jacksonvi1le, Arkansas Facility Internal Monitoring



Phenol 3.8 1.8

2-Chlorophenol <0.2 0.2














11/11/87

Phenol 2.3 1.8


4-Chlorophenol <0.2 *Combined

2,4-0ichlorophenol 11.0 <0.2

2,6-Dichlorophenol <0.2 <0.2

2,3,6-Trichlorophenoxyacetic <0.2 <0.2










OUTFALL 002

<0.2

<0.2

<0.2

<0.2

<O~?

<0.2

<0.2

<O .J <Ot

<0.2

0.95

<0.2

<0.2

dl.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

HERCULES INCORPORA J




Phenol 1.0 2.08















11/13/87

Phenol 3.3 3.9


4-Chlorophenol *6.3 <0.5









2,6-Dichlorophenoxyacetic acid *Combined 2.1




OUTFAJ ~

<O. :-:

<O.;;:

<O.:-:

<0.2

<0.2

<CT. 2

<O. 2

<'0-. 2

<'o.2 C

<0.2

<0.2

<0.2

<0.2

<0.2

<O -

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.5

<0.5





Phenol 2.6 5.0















11/17/87

Phenol <0.2 <0.2



2,4-Dichlorophenol 13. 9 <0.2








2,6-Dichlorophenoxyacetic acid *2.4 <0.2




ND= <0.2

OUTFALL 002

ND

ND

ND

ND

ND

ND

ND ND'-~

NDC

ND

ND

ND

ND

ND

ND

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2





Phenol <0.2 2.5

2-Chlorophenol <0.2 4.3

4-Chlorophenol *Combined *Combined









2,6-Dichlorophenoxyacetic acid *6.1 *3.9


2,4,6-Trichlorophenoxyacetic acid 14. <0.5

2-(2,4,5-Trichlorophenoxy) Propionic acid <0.2 <.05

11/19/87

Phenol 1.1 2.0



2,4-Dichlorophenol 19. <0.2












ND= <0.2

OUTFALL 002

ND

ND

ND

ND

ND

ND

ND

Nti

NQ::

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND





Phenol <0.2 ND

2-Chlorophenol <0.2 ND

4-Chlorophenol ... *4. 4~. ND



2,3,6-Trichlorophenol <0.2 ND

2,4,5-Trichlorophenol 5.7 ND

2,4,6-Trichlorophenol <0.2 ND


4-Chlorophenoxyacetic acid <0.2 ND

2,4-Dichlorophenoxyacetic acid 31. 0 ND

2,6-Dichlorophenoxyacetic acid *Combined ND


2,4,6-Trichlorophenoxyacetic acid <0.2 ND

2-(2,4,5-Trichlorophenoxy) Propionic acid <0.2 ND

OUTFALL 002

ND

ND

ND

ND

ND

ND

ND>

ND~

ND

ND

ND

ND

N"

ND

ND

HERCULES INCORPORATL



10/26/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











11/02/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











REASOR-HILL COMBINED N. BURIAL LEACHATE LEACHATE LEACHATE

6.4

3.0

18.2

9.1

15.4

1.5

64.0

18.4

33.6

13.0

137.3

19.l

116.9

<0.2

20.2

4.5

3.1

<0.5

104.6

12.5

<0.5

61. 3

13.6

32.0

12.4

325.0

36. 0

109.2

65.0

75.0

2.9

1.4

3.3

20.8

13.16

<0.2

12.1

2.2

5.6

2.68

78.1

17.8

18.2

<0.2

<0.2

5.9

1. 4

3.3

23.6

3.0

<0.5

12.8

<0.5

5.2

2.5

71.3

15.6

16.4

18.2

<0.5

3.0

1.4

3.4

25.0

3.2

<0.2

12.6

2.5

5.4

2.7

78.2

17.6

18.8

<0.2

<0.2

5.97

0.7

8.3

<0.5

<0.5

<0.5

<0.5

<0.5

<0.5

<0.5

3.5

21. 8

<0.5

<0.5

<0.5

S.F.DRAIN LEACHATE

no sample rtnnnnn11nn

nwnnnnnnn

nnnn•~nnn

n11n11nn ■ 1111

·--rtnn1111 ■ nnn

nnnnnnnnn C

nnnnnwann

""""""""" nnnnnnnnn

"""""""""

""""""""" n n "" ..

nwnnnnnnn

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

HERCULES INCORPORATE~



11/05/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











11/09/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











REASOR-HILL LEACHATE

6.9

5.3

<0.5

142.9

16.5

<0.5

51. 5

9.3

43.4

19.9

245.1

46.9

135.9

93.2

47.2

3.5

3.7

<0.5

110. 2

13.9

<0.5

54.9

9.5

27.6 13.0

233.3

36.4

97.l

55.7

21.5

COMBINED LEACHATE

3.4

1.7

<0.5

33.6

4.9

<0.5

19.l

2.3

8.5

4.2

120.8

20.4

29.4

19.5

<0.5

3.6

1.7

<0.5

25.3

4.2

<0.2

18.3

<0.2

6.6

3.4

85.8

16.3

21.4

14.9

<0.2

N. BURIAL LEACHATE

4.0

2.3

<0.5

36.3

3.7

<0.5

18.7

2.5

4.5

2.4

44.4

20.1

6.8

21.5

<0.5

7.3

<0.5

8.2

1.4

<0.5

<0.5

<0.5

<0.5

<O.S 1.5

3.5

20.8

<0.5

<0.5

<0.5

S.Fr.DRAI LEACHATE ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

no sample nnnnnnnnn

nnnwnnwnn

ffnnnnnnnn

n11nn11nnnn

nnnttnnnnn

""""""""" n•n••nnnn

""""""""" """"""""" """"""""" """"""""" n ■■ n11nnw ■

n ■ n11nn111111

nnnwnnnnn




11/12/87 REASOR-HILL COMBINED N. BURIAL S.Fr.DRAIN LEACHATE LEACHATE LEACHATE LEACHATE

Phenol 7 .5 1.2 2.8 ND


4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol










2-(2,4,5-Trichlorophenoxy)

<0.5 *Combined <0.2 ND

110.2 7.2 26.4 ND

Propionic acid

11/16/87

10.5

<0.5

40.1

8.3

42.2

19.9

288.7

21. 9

118.0

54.9

11.7

Phenol <0.5

2-Chlorophenol <0.5

4-Chlorophenol *Combined

2,4-Dichlorophenol 43.0


2,3,6-Trichlorophenol <0.5

2,4,5-Trichlorophenol 33.0

2,4,6-Trichlorophenol 7.6 2-Chlorophenoxyacetic acid 9.2

1-Chlorophenoxyacetic acid 3.7

2,4-Dichlorophenoxyacetic acid 140.4

2,6-Dichlorophenoxyacetic acid *7.68

!,4,5-Trichlorophenoxyacetic acid 36.5

1,4,6-Trichlorophenoxyacetic acid <0.5

'-(2,4,5-Trichlorophenoxy) Propionic acid 10.2

ND= <0.2

0.9

<0.5

<0.5

<0.5

1.2

17.1

40.5

*2.3

4.7

<0.5

<0.5

1.3

<0.2

12.6

<0.2

3.8

<0.2

34.3

7.3

29.2

28.2

<0.2

2.9 ND

<0.2 ND

*Combined ND

54.6 ND

3.4 ND

<0.2 ND

15.6 ND

<0.2 ND

6.2 ND

3.5 ND

100.7 ND

*8.6 ND

29.7 ND

<0.2 ND

<0.2 ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND


Jacksonville, Arkansas Facility Internal Monitoring:

All Concentrations in mg:/1

11/19/87 REASOR-HILL COMBINED N. BURIAL S.Fr.DRAIN LEACHATE LEACHATE LEACHATE LEACHATE

Phenol 1.0 0.80 ND ND

2-Chlorophenol 4.1 0.54 ND ND •c-

4-Chlorophenol 19.3* 3.4* ND ND

2,4-Dichlorophenol 147.50 16.8 ND ND 1--

2,6-Dichlorophenol 24.9 2.4 ND ND •:.·

C 2,3,6-Trichlorophenol <0.5 <0.2 ND ND

2,4,5-Trichlorophenol 60.1 13.6 ND ND

2,4,6-Trichlorophenol 14.8 3.0 ND ND

2-Chlorophenoxyacetic acid 20.3 1.5 ND ND

4-Chlorophenoxyacetic acid 9.9 <0.5 ND ND

2,4-Dichlorophenoxyacetic acid 197.6 21.0 ND ND

2,6-Dichlorophenoxyacetic acid *Combined *Combined ND ND

2,4,5-Trichlorophenoxyacetic acid 109.8 8.2 ND ND

2,4,6-Trichlorophenoxyacetic acid 82.7 <0.5 ND ND

2-(2,4,5-Trichlorophenoxy) Propionic acid 10.9 <0.2 ND ND

HERCULES INCORPORATF



DATE SANITARY 002 REASOR-HILL NORTH SOUTH

10/21/87 31,940 1,420 860 5,310 0

10/22/87 17,180 1,700 240 2,700 0

10/23/87 10,810 2,370 230 2,000 0

10/24/87 11,170 710 1,910 2,800 0

10/25/87 8,710 1,030 240 2,060 o·>•

10/26/87 24,550 2,060 2,520 2,870 0

10/27/87 42,370 1,940 1,870 6,340 o---10/28/87 27,780 1,610 930 4,390 10·-···

C 10/29/87 12,950 1,460 190 2,820 30

10/30/87 12,530 5,240 2,520 4,120 80

10/31/87 9,180 10,450 230 3,750 10

11/01/87 8,460 11,550 900 3,700 0

11/02/87 8,320 8,110 840 3,160 0

11/03/87 8,780 4,230 1,880 3,570 0

11/04/87 7,870 4,730 210 2;950 0

11/05/87 8,140 1,440 1,450 3,510 ('

11/06/87 7,480 1,050 240 2,670

11/07/87 8,780 1,160 1,230 2·, 410 0

11/08/87 8,560 710 890 2,660 0

11/09/87 25,770 3,600 1,020 2,950 40

11/10/87 137,710 12,740 4,380 13,890 12,040

11/11/87 127,820 7,580 1,080 8,940 8,150

11/12/87 105,180 7,350 420 5,970 5,600

11/13/87 67,350 4,990 2,580 5,070 4,440 11/14/87 23,790 3,090 990 6,060 3,630 11/15/87 18,330 2,160 930 4,930 2,880 11/16/87 50,080 13,100 3,960 ll,170 11,060

11/17/87 90,030 18,450 2,860 23,700 24,480 11/18/87 66,660 16,500 2,360 8,730 15,460

11/19/87 58,060 1,480 l,010 7,810 1,200

11/2087 33,140 5,860 310 7,020 9,400

1,079,480 159,870 41,280 170,030 98,570

PHERCULES

CERTIFIED MAIL

Ms. Diane R. Martini Industrial Monitoring Supervisor Jacksonville Wastewater Utility Post Office Box 69 Jacksonville, Arkansas 72076

Dear Diane:

December 30, 1987


The Hercules' internal monitoring analytical and flow data report for the period November 21, 1987 through December 20, 1987 is enclosed. These data are submitted pursuant to ouf' compliance with Addendum III, item (4) of our Pretreatment Discharge Permit.


MJF:bb

Enclosures

cc File

Sincerely,


,~/~ti~ Michael J. Falco Senior Environmental Engineer Site Manager

c-




DATE SANITARY 002 REASOR-HILL NORTH SOUTH

11/21/87 4,980 36,630 1,710 6,560 8,120

11/22/87 4,630 28,950 910 6,920 7,330

11/23/87 3,470 30,010 1,310 6,870 6,500

11/24/87 10,710 72,830 3,280 13,140 13,050

11/25/87 11,760 68,930 2,700 16,440 19,050

11/26/87 15,140 76,970 3,620 15,200 24,580

11/27/87 11,570 57,680 2,340 10,650 23,970

11/28/87 10,110 55,370 3,120 10,290 19,820 ;--

11/29/87 7,730 45,330 2,500 9,580 16,370 ,..._

11/30/87 6,350 45,060 1,080 8,000 14,100 '---

12/01/87 5,920 37,910 2,810 8,720 12,460

12/02/87 5,820 91,320 1,710 7,350 8,870

12/03/87 4,780 75,600 3,690 8,020 7,430

12/04/87 3,530 45,160 3,400 6,980 6,570

12/05/87 3,530 29,510 1,970 6,660 6,270

12/06/87 3,070 27,860 4,260 6,830 5,630

12/07/87 5,230 48,460 2,810 6,970 5,770

12/08/87 5,810 46,130 3,650 5,110 5,980

12/09/87 4,640 50,830 3,280 5,930 5,960

12/10/87 5,160 39,090 3,430 7,240 5,720

12/11/87 4,430 31,690 2,700 7,280 5,560

12/12/87 3,380 25,900 2,380 6,680 5,290

12/13/87 3,680 22,030 3,130 6,700 4,920

12/14/87 16,140 69,090 6,350 18,150 10,340

12/15/87 16,880 78,820 9,480 13,180 14,310

12/16/87 11,760 96,330 3,280 9,460 18,990

12/17/87 8,720 92,070 1,360 7,770 16,570

12/18/87 7,590 76,270 1,560 8,820 15,670

12/19/87 8,920 83,500 31390 9,690 14,690

12/20/87 10,850 97,950 3,830 12,180 17,730

TOTALS 226,290 1,683,280 91,040 273,370 347,620




Ll/23/87 REASOR-HILL COMBINED N. BURIAL S.F. DRAIN LEACHATE LEACHATE LEACHATE LEACHATE

c>henol l.7 <0.5 ND ND

2-Chlorophenol 1.5 <0.5 ND ND

1-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol


~,4,5-Trichlorophenol

Z,4,6-Trichlorophenol

Z-Chlorophenoxyacetic acid


~,4-Dichlorophenoxyacetic acid

Z,6-Dichlorophenoxyacetic acid

Z,4,5-Trichlorophenoxyacetic acid

Z,4,6-Trichlorophenoxyacetic acid

1-(2,4,5-Trichlorophenoxy)

20.8* 5.4* 0.89* ND

69.5 6.0 ND ND

lO.l 0.67 ND ND

Propionic acid

'l/26/87

<0.5

52.0

15.3

10.9

4.3

145.

*Combined

56.5

41.4

9.2

'ienol ND

!-Chlorophenol ND

1-Chlorophenol 18.5*

~,4-Dichlorophenol 77.7

!,6-Dichlorophenol 5.2

!,3,6-Trichlorophenol ND

!,4,5-Trichlorophenol 60.0

!,4,6-Trichlorophenol l5.2

'-Chlorophenoxyacetic acid 5.8 -Chlorophenoxyacetic acid 3.1

',4-Dichlorophenoxyacetic acid 123.8

'.,6-Dichlorophenoxyacetic acid *Combined

'.,4,5-Trichlorophenoxyacetic acid 39.4

:,4,6-Trichlorophenoxyacetic acid

'-(2,4,5-Trichlorophenoxy) Propionic acid

ND

ND

ND

<0.5

ND

ND

ND ND

<0.5 ND

<0.5 ND

14.2 5.5

*Combined *Combined

3.8 ND . ND

ND

ND

ND

25.4 ND

ND ND

7.1* 10.0*

6.8 13.0

1.0 1.4

ND ND

5.0 7.0 ND ND

9.6 ND ND ND

20.2 18.7

*Combined *Combined

5.0 ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND ND

ND

ND

ND

ND

ND




11/30/87 REASOR-HILL COMBINED N. BURIAL S.F. DRAIN LEACHATE LEACHATE LEACHATE LEACHATE

Phenol ND ND ND ND

2-Chlorophenol ND ND ND ND

4-Chlorophenol ND ND 9.5* ND

2,4-Dichlorophenol 8.6 5.3 73.7 ND

2,6-Dichlorophenol ND ND ND ND

2,3,6-Trichlorophenol ND ND ND ND i'-2,4,5-Trichlorophenol 14.6 ND 74.9 ND

2,4,6-Trichlorophenol ND ND ND ND C

2-Chlorophenoxyacetic acid ND ND ND ND 4-Chlorophenoxyacetic acid ND ND ND ND

2,4-Dichlorophenoxyacetic acid ND 8.7 51. 9 ND

2,6-Dichlorophenoxyacetic acid ND ND *Combined ND

2,4,5-Trichlorophenoxyacetic acid ND ND ND ND

2,4,6-Trichlorophenoxyacetic acid NE ND ND ND

2-(2,4,5-Trichlorophenoxy) ND ND ND ND Propionic acid

12/03/87


2-Chlorophenol *Combined 0.50 ND ND

4-Chlorophenol 32.8** 7.5* ND ND

2,4-Dichiorophenol 82.7 8.7 0.41 ND

2,6-Dichlorophenol 9.7 1.0 ND ND

2,3,6-Trichlorophenol ND ND ND ND

2,4,5-Trichlorophenol 57.l 5.1 ND ND 2,4,6-Trichlorophenol 12.7 1.1 ND ND

2-Chlorophenoxyacetic acid 25.9* 1.7 ND ND 4-Chlorophenoxyacetic acid 11.6 l. 4 ND ND


2,6-Dichlorophenoxyacetic acid **Combined *Combined ND ND


2,4,6-Trichlorophenoxyacetic acid 67. 7.4 ND ND

2-(2,4,5-Trichlorophenoxy) 15.1 ND ND ND Propionic acid





Phenol ND 0.99 7.81 ND

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol




0.21 0.55 ND ND

1.43* 7.6* 18.9* ND

14.4 13.8 26.7 ND

1.40 1.5 ND ND

ND

23.2

11. 9


4-Chlorophenoxyacetic acid ND


2,6-Dichlorophenoxyacetic acid *Combined

2,4,5-Trichlorophenoxyacetic acid 2.23



12/10/87

Phenol

2-Chlorophenol

·1 -Chloropheno l

2,4-Dichlorophenol

2,6-Dichlorophenol



!,4,6-Trichlorophenol

Z-Chlorophenoxyacetic acid

l-Chlorophenoxyacetic acid

~,4-Dichlorophenoxyacetic acid

!,6-Dichlorophenoxyacetic acid

!,4,5-Trichlorophenoxyacetic acid


'-(2,4,5-Trichlorophenoxy) Propionic acid

ND

ND

5.4

2.8

20.2*

48.6

<0.5

ND

27.4

16.7

8.8

<0.5

170.

*Combined

48.

<0.5

2.1

ND

9.1

4.1

ND

14.8

ND

2.0 1.69

1.3 7.8

34.6 38.2

*Combined *Combined

8.1 7.7

8.9

0.74

2.9

0.53

10.6*

14.5

ND

ND

7.3

1.3

1.6

2.1

42.9

*Combined

12.2

<0.5

ND

ND

ND

7.0

ND

6.7*

0.8

0.8

ND

ND

ND

ND

ND

3.3

*Combined

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

C




12/14/87 REASOR-HILL COMBINED N. BURIAL S.F. DRAI~ LEACHATE LEACHATE LEACHATE LEACHATE

Phenol 2.0 ND ND ND

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol






<0.5 ND ND ND

19.7* ND 5.3* ND

26.2 33.4 9.4 ND

5.5 ND ND ND

ND

34.0

12.9

11.2

7.3






12/17/87

<0.5

ND

Phenol 3.2

2-Chlorophenol 6.3

4-Chlorophenol 33.*



2,3,6-Trichlorophenol ND




4-Chlorophenoxyacetic acid <0.5






<0.5

10.9

ND

6.4

ND

ND

ND

58.3

ND

20.9

ND

ND

ND

ND

ND

13. 2

0.9

ND

6.9

ND

2.8

ND

39.4

5.2

9.9

ND

ND

ND

ND

ND

0.5

ND

11.2

*Combined

ND

ND

ND

3.5

1.1

14.9*

12.9

1.2

ND

8.1

ND

1.6

ND

22.1

*Combined

5.2

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

C




11/23/87 WASTEWATER TO WASTEWATER TO OUTFALL 1st Bed 2nd Bed 002

Phenol ND ND ND

2-Chlorophenol 2.7 ND ND

4-Chlorophenol 12.1* ND ND

2,4-Dichlorophenol 16.7 ND ND


2,3,6-Trichlorophenol ND ND ND .-. 2,4,5-Trichlorophenol ND ND ND

2,4,6-Trichlorophenol ND ND ND C·

2-Chlorophenoxyacetic acid ND ND ND 4-Chlorophenoxyacetic acid ND ND ND

2,4-Dichlorophenoxyacetic acid 31.4 ND ND

2,6-Dichlorophenoxyacetic acid *Combined ND ND 2,4,5-Trichlorophenoxyacetic acid ND ND ND 2,4,6-Trichlorophenoxyacetic acid ND ND ND

2-(2,4,5-Trichlorophenoxy) ND ND ND Propionic acid

11/24/87

Phenol <0.5 <0.5 ND

2-Chlorophenol <O.S <0.5 ND 4-Chlorophenol <O.S <0.5 ND 2,4-Dichlorophenol 18.0 <0.5 ND 2,6-Dichlorophenol <0.5 <O.S ND

2,3,6-Trichlorophenol <0.5 ND ND 2,4,5-Trichlorophenol <0.5 ND ND 2,4,6-Trichlorophenol <0.5 ND ND

2-Chlorophenoxyacetic acid 4.1 <0.5 ND 4-Chlorophenoxyacetic acid <0.5 <0.5 ND 2,4-Dichlorophenoxyacetic acid 35.9 ND ND 2,6-Dichlorophenoxyacetic acid 9.3 ND ND

2,4,5-Trichlorophenoxyacetic acid <0.5 ND ND


2-(2,4,5-Trichlorophenoxy) <0.5 ND ND Propionic acid




11/25/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











11/26/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol










WASTEWATER 1st Bed

ND

ND

9.6*

20.9

ND

ND

ND

ND

ND

ND

39.3

*Combined

ND

ND

ND

<0.5

<0.5

6.8*

16.3

<0.5

ND

5.8

<0.5

2.8

<0.5

46.7

*Combined

5.0

<0.5

ND


1. 7

ND

3.3*

ND

ND

ND

ND

ND

0.44

ND

ND

*Combined

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

6.2

ND

ND

ND

ND

ND

ND

TO OUTFALL 002

ND

ND

ND

ND

ND

ND

ND i'-

ND ·,-

ND C

ND

ND

ND

ND

ND

ND

ND

ND

ND

<0;5

ND

ND

ND

ND

ND

ND

1. 9

ND

ND

ND

ND




11/27/87 WASTEWATER TO WASTEWATER TO OUTFALL 1st Bed 2nd Bed 002

Phenol <0.5 2.8 ND

2-Chlorophenol <0.5 ND ND

4-Chlorophenol 5.2* 5.1* ND

2,4-Dichlorophenol 10.4 ND <0.5



2,4,5-Trichlorophenol <0.5 ND ND r---

2,4,6-Trichlorophenol <0.5 ND ND C


4-Chlorophenoxyacetic acid 1.1 ND ND

2,4-Dichlorophenoxyacetic acid 35.9 ND 5.5 2,6-Dichlorophenoxyacetic acid *Combined *Combined ND

2,4,5-Trichlorophenoxyacetic acid 5.0 ND ND



11/30/87

Phenol 1.2 4.6 ND

2-Chlorophenol 0.89 2.0 ND


2,4-Dichlorophenol 12.0 ND <0.5 2,6-Dichlorophenol 1. 4 ND ND

2,3,6-Trichlorophenol ND ND ND 2,4,5-Trichlorophenol 3.3 ND ND 2,4,6-Trichlorophenol <0.5 ND ND


4-Chlorophenoxyacetic acid <0.5 ND ND

2,4-Dichlorophenoxyacetic acid 27.5 ND 1.5

2,6-Dichlorophenoxyacetic acid *Combined *Combined ND

2,4,5-Trichlorophenoxyacetic acid 3.6 NO NO

2,4,6-Trichlorophenoxyacetic acid <0.5 NO ND





12/01/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol










12/02/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











WASTEWATER 1st Bed

2.8

ND

9.1*

12.3

0.57

ND

1.2

ND

1.3

ND

27.9

*Combined

2.4

ND

ND

ND

10.3*

14.5

ND

ND

ND

ND

2.0

ND

22.2

*Combined

ND

ND

ND


ND

5.5

16.8*

ND

ND

ND

ND

ND

ND

ND

1.8

*Combined

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

TO OUTFALL 002

ND

ND

ND ,...,,,

ND:·

ND·

ND:--

ND~

ND

ND

ND

0.48

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND




12/03/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











12/04/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











WASTEWATER 1st Bed

1.2

0.54

5.6*

7.4

0.7

ND

ND

ND

2.7

1.0

20.0

*Combined

2.7

4.1

ND

ND

ND

9.5*

12_5

ND

ND

0.2

ND

1.9

ND

28.5

*Combined

4.3

ND

ND

TO WASTEWATER TO 2nd Bed

1.8

ND

5.6*

0.65

ND

ND

ND

ND

10.6

ND

1.4

*Combined

ND

ND

ND

ND

ND

ND

0.5

ND

ND

ND

ND

ND

ND

2.5

ND

ND

ND

ND

OUTFALL 002

ND

ND

ND

<0.5 ,

ND

ND ;-

ND C

ND

ND

ND

<0.5

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND




12/07/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











12/08/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











WASTEWATER 1st Bed

9.2

1.9

24.4*

41. 9

<0.2

ND

16.5

10.0

4.2

5.5

95.8

*Combined

16.2

ND

1. 9

2.9

2.0

8.28*

13.3

1.8

ND

ND

ND

ND

ND

19.0

*Combined

1.2

ND

ND


6.9

1.6

9.0*

0.2

0.23

ND

ND

ND

7.0

ND

1.4

*Combined

ND

ND

ND

1.5

1.6

6.5*

ND

0.30

ND

ND

ND

0.66

2.2

1.2

*Combined

ND

ND

ND

TO OUTFALL 002

ND

ND

ND

0.2

ND

ND 1---

ND C ND

ND

ND

1.0

ND

ND

ND

ND

ND

2.0

2.0*

ND

0.90

ND

ND

ND

ND

ND

1. 3

*Combined

ND

ND

ND

HERCULES INCORPORATEI



12/09/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











12/10/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











WASTEWATER 1st Bed

1.8

0.9

9.6*

7.9

0.7

ND

ND

ND

2.8

1.7

22.6

*Combined

3.4

5.8

ND

2.0

ND

6.1*

16.9

ND

ND

5.0

0.9

ND

2.6

41. 9

*Combined

7.0

ND

0.2


ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

2.1

ND

6.8*

ND

ND

ND

ND

ND

4.6

ND

1.5

*Combined

ND

ND

ND

OUTFALL 002

ND

ND

ND

NO-

ND NI:f-·

ND~

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

0.11

ND

ND

ND

ND

ND

ND

0.65

ND

ND

ND

ND



All Concentrations in mg/I

12/11/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











12/14,1/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol



2,4,6-Trichlorophenol 2-Chlorophenoxyacetic acid







WASTEWATER 1st Bed

19.9

0.7

9.3*

11.0

1.0

ND

ND

ND

2.1

ND

26.6

*Combined

5.6

ND

ND

1.4

0.73

7.3*

8.5

1.3

ND

6.5

ND

2.2

ND

34.7

*Combined

ND

ND

ND


13.7

8.5

15.6*

ND

ND

ND

ND

ND

24.6

ND

ND

*Combined

ND

ND

ND

17.0

ND

7.3*

ND

ND

ND

ND

ND

6.0

ND

4.2

*Combined

ND

ND

ND

TO OUTFALL 002

ND

ND

ND

ND

ND

ND :-

ND C

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND




12/15/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol


2,4,5-TRichlorophenol









12/16/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol







4-Dichlorophenoxyacetic acid




WASTEWATER 1st Bed

ND

ND

24.5*

6.2

ND

ND

ND

ND

29.l

ND

25.9

*Combined

ND

ND

ND

ND

ND

6.2*

7.3

ND

ND

ND

ND

ND

ND

23.7

*Combined

ND

ND

ND


16.0

ND

8.1*

ND

ND

ND

ND

ND

6.0

ND

6.0

*Combined

ND

ND

ND

ND

ND

9.8*

ND

ND

ND

ND

ND

8.5

ND

5.8

*Combined

ND

ND

ND

TO OUTFALL 002

ND

ND

NI?---ND::.

ND :-.

ND .,~--

Nic,

ND

ND

ND

1. 7

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1.1

ND

ND

ND

ND




12/17/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











12/18/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











WASTEWATER 1st Bed

ND

ND

6.5*

4.8

0.69

ND

ND

ND

4.8

ND

14.1

*Combined

ND

ND

ND

0.87

ND

6.8*

7.2

0.85

ND

ND

ND

1.9

1.1

20.6

*Combined

3.3

ND

ND


10.0

ND

14.2*

ND

ND

ND

ND

ND

7.3

ND

8.1

*Combined

ND

ND

ND

ND

ND

5.5*

ND

ND

ND

ND

ND

4.6

ND

4.2

*Combined

ND

ND

ND

OUTFALL 002

ND

ND

ND

ND

ND

ND "--.w•

ND C

ND

ND

ND

ND

ND

ND

ND

Nr

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1.7

ND

ND

ND

ND

_{@HERCULES Hercules Incorporated 1010 Marshall Road Jacksonville, AR 72076 (501) 982-9481

CERTIFIED MAIL

Ms. Diane R. Martini Industrial Monitoring Supervisor Jacksonville Wastewater Utility Post Office Box 69 Jacksonville, Arkansas

Dear Diane:

72076

January 22, 1988

The Hercules' internal monitoring analytical and flow data report for the period December 21, 1987 through January 20, 1988 is enclosed. These data are submitted pursuant to our compliance with Addendum III, item (4) of our Pretreatment Discharge Permit.


MJF:bb

Enclosures

cc File

Sincerely,

HERCULES INCORPORATED Jacksonvtl+e Facility

./::-l,I / ·;(I//L,/t2//{)

Michail J. Falco Senior Environmental Engineer Site Manager

C





12/21/87 9,880 75,260 3,000 9,380 17,240

12/22/87 8,520 54,420 1,210 9,290 16,910

12/23/87 6,510 60,260 2,840 7,840 14,790

12/24/87 7,190 57,920 2,050 10,220 15,210

12/25/87 28,800 129,670 8,160 30,480 19,410

12/26/87 32,120 165,740 11,740 18,040 44,550

12/27/87 31,500 170,320 5,770 45,040 42,960

12/28/87 20,490 162,650 4,210 16,250 32,860 -12/29/87 14,970 171,130 3,210 11,270 26,580 ·--

C 12/30/87 11,870 92,300 3,070 10,710 21,770

12/31/87 10,050 158,170 2,610 10,440 19,880

01/01/88 12,930 117,670 2,810 10,300 19, sio 01/02/88 10,290 56,560 2,920 9,480 17,800

01/03/88 9,300 51,830 2,860 9,150 16,260

01/04/88 8,960 78,120 3,320 7,990 15,330

01/05/88 8,210 55,340 990 8,900 13,720 01/06/88 8,170 73,510 2,750 8,380 11,870

01/07/88 10,740 71,660 2,800 7,350 11,940 01/08/88 11,760 79,830 1,940 8,120 10,810 01/09/88 13,710 129,240 3,370 8,240 10,300 01/10/88 13,430 138,480 1,780 7,080 9,870 01/11/88 13,880 131,850 2,000 -7;950 9,450 01/12/88 11,400 117,530 2,810 7,200 9,310 01/13/88 14,500 122,830 3,640 11,340 10,610 01/14/88 14,050 69,710 1,150 :?9-;'.JSO 12,340 01/15/88 12,710 76,130 2,850 8,730 12,930 01/16/88 10,470 88,960 3,130 8,760 12,650 01/17/88 22,470 143,710 4,810 26,600 21,710 01/18/88 16,060 159,520 3,350 11,650 25,140 01/19/88 15,670 88,510 4,200 17,220 22,300 01/20/88 16,300 57,420 3,820 12,580 25,880

TOTAL 436,910 3,206,250 105,170 385,730 571,890


Jacksonv le, Arkansas Facility In' ~nal Monitoring


12/21/87 OUTFALL WASTEWATER TO WASTEWATER 002 1st Bed 2nd Bed

Phenol ND 1.6 ND

2-Chlorophenol ND ND ND

4-Chlorophenol ND 6.5* 9.7*

2,4-Dichlorophenol ND 7.2 ND





2-Chlorophenoxyacetic acid ND 2.0 7.5 4-Chlorophenoxyacetic acid ND ND ND

2,4-Dichlorophenoxyacetic acid 1. 4 21.4 8.9 2,6-Dichlorophenoxyacetic acid ND *Combined *Combined

2,4,5-Trichlorophenoxyacetic acid ND 3.8 ND

2,4,6-Trichlorophenoxyacetic acid ND ND ND

2-(2,4,5-Trichlorophenoxy} Propionic acid ND ND ND

12/22/87

Phenol ND 0.64 ND

2-Chlorophenol ND ND ND 4-Chlorophenol ND 7.7* 7.7* 2,4-Dichlorophenol ND 8.9 ND

2,6-Dichlorophenol ND l.l ND 2,3,6-Trichlorophenol ND ND ND

2,4,5-Trichlorophenol ND ND ND 2,4,6-Trichlorophenol ND ND ND 2-Chlorophenoxyacetic acid ND 2.99 3.9 4-Chlorophenoxyacetic acid ND 2.3 ND

2,4-Dichlorophenoxyacetic acid 1.2 28.6 ND 2,6-Dichlorophenoxyacetic acid ND *Combined *Combined ~,4,5-Trichlorophenoxyacetic acid ND 4.2 ND 2,4,6-Tr~chlorophenoxyacetic acid ND ND ND

2-(2,4,5-Trichlorophenoxy) Propionic acid ND ND ND

TO

:---

C


Jacksonviile, Arkansas Facility Int~rnal Monitoring


12/23/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











12/24/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Di~hlorophenol

2,6-Dichlorophenol










OUTFALL 002

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1. 9

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND ND

ND

ND

ND

ND

WASTEWATER TO WASTEWATER 1st Bed 2nd Bed

1.1 ND

ND ND

7.1* 8.5*

7.8 ND

1.1 ND

ND ND

ND ND

ND ND

1. 94 5.2

ND ND

23.4 3.5

*Combined *Combined

3.5 ND

ND ND

ND ND

ND ND

1.45 ND

7.33* 6.00*

8.06 ND

0.853 ND

ND ND

ND ND

ND ND

ND 5.64

ND ND 26.9 9.45

*Combined *Combined

3.73 ND

ND ND

ND ND

TO

(';

--C


Jacksonv le, Arkansas Facility Int :nal Moni taring


12/25/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol


2,4,5-Trichloropher.ol









12/28/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











OUTFALL 002

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1. 60

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

4.10

ND

ND

ND

ND


ND ND

ND 5.22*

4.78* 11. 5**

11.2 ND

1.49 ND

ND ND

6.85 ND

ND ND

2.3 *Combined

ND *Combined

37.1 16.0

*Combined **Combined

5.77 ND

ND ND

ND ND

ND ND

ND ND

ND 7.84*

2.66 ND

ND ND

ND ND

5.07 ND

ND ND

ND 3.90

ND ND

22·.2 13.5

ND *Combined

ND ND

ND ND

ND ND

TO

C


Jacksonv. .e, Arkansas Facility Int nal Monitoring


12/29/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol










12/30/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











OUTFALL 002

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND 4.43

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

4.33

ND

ND

ND

ND


ND ND

1.46* ND

3.32** 9.49*

7.27 ND

ND 1.19

ND ND

18.1 ND

ND ND

*Combined 4.39

*Combined ND 26.9 13.5

**Combined *Combined

ND ND

ND ND

ND ND

1.09 ND

0.575 ND

7.66* 7.11*

9.20 ND

1.15 ND

ND ND

ND ND

ND ND

2.06 1.17 ND ND

29.4 18.7

*Combined *Combined

4.75 ND

ND ND

ND ND

TO

r---

C-


Jackson, _le, Arkansas Facility In rnal Monitoring


12/31/87 OUTFALL WASTEWATER TO WASTEWATER TO 002 1st Bed 2nd Bed

Phenol ND ND ND

2-Chlorophenol ND ND 0.555

4-Chlorophenol ND 8.02* 5. 77*




2,4,5-Trichlorophenol ND ND ND i'-

2,4,6-Trichlorophenol ND ND ND C

2-Chlorophenoxyacetic ND ND ND

4-Chlorophenoxyacetic acid ND ND ND


2,6-Dichlorophenoxyacetic acid ND *Combined *Combined



2-(2,4,5-Trichlorophenoxy} Propionic acid ND ND ND

01/01/88

Phenol ND 0. 72 0.82

2-Chlorophenol ND 0.48 0.53







2-Chlorophenoxyacetic acid ND 2.89 2.5







HERCUT,ES INCORPORATED

Jackson Ile, Arkansas Facility I1 !rnal Monitoring


01/04/88 OUTFALL WASTEWATER TO WASTEWATER TO

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











01/05/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











002 1st Bed 2nd Bed

ND 4.4 ND

ND ND ND

ND 8.8* 6.4*

ND 10.l ND

1.2 1. 4 8.3

ND ND ND

ND ND ND :--.

ND ND ND C ND 1.47 2.3

ND ND ND

ND 33.3 ND

ND *Combined *Combined

ND 5.9 ND

ND ND ND

ND ND ND

ND 10.0 ND

ND ND ND

ND 12.0* 13.5*

ND 7.68 ND

ND 1.2 ND

ND ND ND

ND ND ND

ND ND ND

ND 13.4** ND

ND **Combined 1.6

1. 47 23.2 15.5


ND 3.6 ND

ND ND ND

ND ND ND

HERCULES INCORPORATED Jacksonvi e, Arkansas Facility Int nal Monitoring

All Concentrations in m~/1

0l/06/88 OUTFALL WASTEWATER TO WASTEWATER TO

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











01/07/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











002 1st Bed 2nd Bed

ND ND 0.65

ND ND ND

ND 2.89* 3.9*

ND 3.6 ND

ND ND ND

ND ND ND !"'--·

ND ND ND

ND ND ND

ND 0.88 1.85 r-

ND ND ND 0

ND 11.69 ND


ND 0.76 ND

ND ND ND

ND ND ND

ND ND ND

ND ND ND

ND 2.99* 3.89*

ND 3.7 ND

ND 0.8 ND

ND ND ND

ND ND ND

ND ND ND

ND 1.44 2.07

ND ND 1.28

0.79 13.4 12.2


ND ND ND

ND ND ND

ND ND ND


JacksonvL ~e, Arkansas Facility Int nal Monitoring


01/08/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











01/11/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











OUTFALL 002

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND


ND ND

ND 1.05

2.26* 5.89*

3,06 ND

ND ND

ND ND

ND ND

ND ND

1.16 3.5

ND ND

16.6 20.0

*Combined *Combined

ND ND

ND ND

ND ND

ND ND

ND ND

3.0* 3,2*

3.2 ND

ND ND

ND ND

ND ND

ND ND 0,92 1.26

ND ND

14.3 8.2

*Combined *Combined

2.9 ND

ND ND

ND ND

TO

,"'-..

C)


Jacksonv _ le, Arkansas Facility Int. _·na 1 Moni taring

All Concentrations in mg.1


Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2~6-Dichlorophenol











01/13/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











002 1st Bed 2nd Bed

ND 0.43 ND

ND ND ND

ND 3.6* 5.6*

ND 4.9 ND

ND 0.62 ND

ND ND ND

ND ND ND

ND ND ND r--ND 1.63 1.53

C ND ND 1.92

1.01 22.l 18.0


ND ND ND

ND ND ND

ND ND ND

ND 1.98 ND

ND ND 0.44

ND 4.35* 5.13*

ND 3.95 ND

ND 0.87 ND

ND ND ND

ND ND ND

ND ND ND

ND 11.l 1.6

ND ND l.28

l. 7 18.74 l0.l


ND 2.97 ND

ND ND ND

ND ND ND


Jacksonvi _e, Arkansas Facility Int nal Monitoring



Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











01/15/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











002 1st Bed 2nd Bed

ND 0.78 ND

ND 0.41 ND

ND 5.58* 3.6*

ND 7.03 ND

ND 1.03 ND

ND ND ND ,..,,

ND ND ND

ND ND ND

ND 2.11 l. 38 ,-, '--'

ND 1.24 0.96

2.02 30.86 10.42


ND 6.61 ND

ND ND ND

ND ND ND

ND 0.71 ND

ND 0.39 ND

ND 5.40* 5.64 1.33 6.24 ND

ND 0.98 ND

ND ND ND ND ND ND

NE ND ND ND 1. 98 3.38

ND 1.11 1.97 2.69 25.99 18.l


ND 6.83 ND

ND ND ND

ND ND ND

HERCULES INCORPORATF-

Jacksonville, Arkansas Facility Internal monitoring



Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











01/19/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol










002 1st Bed 2nd Bed

ND 0.69 0.58

ND 0.39 0.37

ND 4.69* 6.4*

0.53 6.40 1.00

ND 1.01 0.62 ::\,!

ND ND ND

ND ND ND

ND ND ND C

ND 0.22 1.61

ND 1. 31 1.23

2.23 21. 9 14.22


ND 4.04 ND

ND ND ND

ND ND ND

ND 0.59 ND

ND ND ND

ND 5.17* 5.8*

1.26 6.20 ND

ND 0.96 0.79

ND ND ND

ND ND ND

ND ND ND

ND 1. 72 1.58 ND ND 1.0

6.46 27.1 11.52


ND 5.25 ND

ND ND ND

ND ND ND


Jacksonville, Arkansas Internal Monitoring



Phenol ND ND 0.61



2,4-Dichlorophenol ND 5.0 ND '- '~!

2,6-Dichlorophenol ND 0.77 0.83





4-Chlorophenoxyacetic acid ND ND 1.81







Jacksonvi e, Arkansas Facility Intl 1al Monitoring


12/21/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol








ND

3.1

21. 3*

93.1

13. 7

ND

48.3

13.4

19.1

10.5

150.



2,4,6-Trichlorophenoxyacetic acid ND

2-(2,4,5-Trichlorophenoxy) ND Propionic acid

12/24/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











2.63

3.81

31. 7*

98.2

12.9

ND

41. 4

5.98

26.7

12.2

342.

*Combined

91.6

56.4

23.3

COMBINED LEACHATE

ND

ND

3.8*

2.2

ND

ND

ND

ND

ND

ND

' 6. 5

N. BURIAL LEACHATE

1.8

1.3

10.1*

17.8

1.9

ND

11.1

ND

2.0

ND

16.1

*Combined *Combined

ND

ND

ND

o. 971

0.900

8.51*

18.8

2.60

ND

10.2

ND

4.14

2.38

67.5

4.6

ND

ND

3.64

1.35

9.44*

17.4

1. 95

ND

9.22

ND

3.22

ND

21.2

*Combined *Combined

15.3

ND

ND

3.50

ND

ND

S.F. DRAI LEACHATE

ND

ND

ND

ND

NO

NO>: ND

;·-ND

NDC

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND


Jackson~ ~le, Arkansas Facility In ornal Monitoring


12/28/87 REASOR-HILL COMBINED N. BURIAL

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol









2,4,6Trichlorophenoxyacetic acid


12/31/87

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol






LEACHATE

4.12

1. 89

16.8*

54.1

7.52

ND

34.8

ND

10.9

5.22

170.

*Combined

41.7

ND

ND

ND

11.5*

32.4**

98.7

7.54

ND

62.7

10.3

*Combined

NO

2,4-0ichlorophenoxyacetic acid 273.7

2,6-0ichlorophenoxyacetic acid **Combined


2,4,6-Trichlorophenoxyacetic acid ND

2-(2,4,5-Trichlorophenoxy) Propionic acid 21. 2

LEACHATE LEACHATE

ND

0.189

3.08*

10.0

1.21

ND

6.30

ND

NO

ND

27.3

*Combined

7.17

ND

ND

13.1

ND

5.37*

4.25

0.724

ND

ND

ND

ND

NO

10.0

*Combined

ND

ND

ND

ND

ND

ND

NO

ND

ND

ND

ND

ND

ND

NO

ND

NO

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

S.F. DRA LEACHATE

ND

NO

ND

ND

ND

ND, ....

ND .........

NO

ND C

ND

ND

ND

ND

NO

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

HERCULES INCORPORA~-~



01/04/88 REASOR-HILL COMBINED N. BURIAL LEACHATE LEACHATE LEACHATE

Phenol ND ND ND


4-Chlorophenol ND '7.8* ND

2, 4-Dichlorophenol ND 9 .1 ND


2, 3, 6-Trichlorophenol ND ND ND

2,4,5-Trichlorophenol ND 7.0 ND

2, 4, 6-Trichlorophenol ND ND ND


4-Chlorophenoxyacetic acid ND 1.2 ND

2,4-Dichlorophenoxyacetic acid ND 35.8 ND

2,6-Dichlorophenoxyacetic acid ND *Combined ND




01/11/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol







ND

ND

1.8

2.5

27.6*

68.9

10.1

ND

49.5

11.3

19.8

8.3

165.0





50.5

9.1

ND

ND

1.2

0.56

6.4*

8.0

1.0

ND

4.6

ND

1.7

ND

28.8

ND

ND

8.4

1.6

40.7*

3.5

ND

ND

ND

ND

1.9

ND

37.2

*Combined *Combined

6.9 14.5

ND 22.6

ND ND

S.F. DRA: LEACHATE

ND

ND

ND

ND

ND ND C<

ND _

ND

ND C

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND




01/18/88 REASOR-HILL COMBINED N. BURIAL S.F.DRAIN LEACHATE LEACHATE LEACHATE LEACHATE

Phenol 2.77 0.60 1.56 ND


4-Chlorophenol 21.9* 5.30* 9.31* ND

2,4-Dichlorophenol 59.97 6.93 '' 14.4 ND

2,6-Dichlorophenol 7.74 1.02 2.27 ND

2,3,6-Trichlorophenol ND ND ND ND ··=--

2,4,5-Trichlorophenol 3.5 C

36.5 ND ND

2,4,6-Trichlorophenol 5.7 ND ND ND

2-Chlorophenoxyacetic acid 17.02 2.07 2.03 ND

4-Chlorophenoxyacetic acid 7.61 0.97 1.32 ND


2,6-Dichlorophenoxyacetic acid *Combined *Combined *Combined ND

2,4,5-Trichlorophenoxyacetic acid 52.96 5.93 3.67 ND

2,4,6-Trichlorophenoxyacetic acid 27.7 ND ND ND

2-(2,4,5-Trichlorophenoxy) Propionic acid 0.87 ND ND ND

@HERCULES Hercules Incorporated 1 01 O Marshall Road Jacksonville, AR 72076 (501) 982-9481

CERTIFIED MAIL

Mr. Frank Stephens Assistant Manager Jacksonville Wastewater Utility Post Office Box 69 Jacksonville, AR 72076

Dear Mr. Stephens:

March 1, 1988

The Hercules' internal monitoring analytical and flow data report for the period January 21, 1988 through February 20, 1988 is enclosed. These data are submitted pursuant to our compliance with Addendum III, item (4) of our Pretreatment Discharge Permit.


MJF:bb

Enclosures

Sincerely,


#:1&~ Michael J;,: F:l;~~-Senior Environmental Engineer Site Manager

C

HERCULES INCORPORATl




01/21/88 12,570 8,840 2,840 3,300 21,110

01/22/88 11,050 8,670 2,480 15,890 18,400

01/23/88 9,120 6,050 2,440 8,660 16,330

01/24/88 7,680 5,030 3,220 8,720 15,210

01/25/88 7,330 3,660 2,600 8,990 13, 4.fo·

01/26/88 7,810 44,960 1,760 5,410 11, 78;tl ..

01/27/88 7,190 53,110 1,850 4,560 10,306-

01/28/88 5,850 42,870 2,570 4,530 9, ostr-01/29/88 5,580 60,800 2,680 5,840 9,620

01/30/88 4,310 74,660 1,820 5,640 8,900

01/31/88 4,480 60,660 2,650 4,870 8,460

02/01/88 4,420 63,950 1,710 5,630 8,090

02/02/88 11,940 134,980 4,200 13,510 10,390

02/03/88 19,020 168,020 8,080 7,740 19,270

02/04/88 13,510 164,350 5,900 7,700 18,570

02/05/88 12,520 131,500 6,860 6,860 18,080

02/06/88 11,370 52,660 5,870 6,500 16,700

02/07/88 10,100 72,790 4,380 6,620 15,170

02/08/88 8,180 17,460 5,000 6,480 13,050

02/09/88 7,360 48,910 3,030 24,400 12,510

02/10/88 6,780 27,820 2,650 8,330 11,280

02/11/88 6,670 46,490 2,810 8,900 10,730 02/12/88 8,270 51,160 1,890 7,700 8,870 02/13/88 7,830 80,570 2,840 7,970 8,500 02/14/88 6,320 30,290 1,970 7,550 8,390 02/15/88 5,840 36,280 3,260 7,280 7,990

02/16/88 6,460 6,780 2,780 7,720 8,050

02/17/88 5,130 16,630 1,920 6,590 7,030 02/18/88 8,650 45,750 2,990 9,990 8,100 02/19/88 14,910 41,590 3,950 12,980 12,730

02/20/88 13,080 26,260 2,540 9,910 15,620

TOTALS 271,330 1,633,550 101,540 256,770 381,720

HERCULES INCORPORATF.



01/25/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











02/01/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol












3.82

1.40

17.44*

40.28

5.6

ND

18.21

8.69

8.51

4.15

128.22

*Combined

1.99

ND

ND

2.2

3.53

38.6*

94.0

3.8

ND

39.0

8.06

31.9

14.25

46.5

*Combined

105.9

53.9

0.38

COMBINED LEACHATE

0.90

ND

6.74*

6.78

0.68

ND

0.58

ND

1.97

0.65

25.78

N. BURIAL S.F. DRAil LEACHATE LEACHATE

1.92 ND

1.3 ND

10.85* ND

16.01 ND

1. 88 ND

ND

7.75

ND

2.68

ND

22.03

*Combined *Combined

ND

ND

ND

ND

ND

ND

ND

ND

ND

6.15

ND

ND

1.0

ND

7.6*

8. 77

1.03

ND

ND

ND

2.94

ND

40.89

*Combined

10.9

ND

ND

3.90

ND

ND

5.3

2.88

14.0

2.3

ND

ND

ND

ND

1.39

ND

29.57

20.4

21.6

18.52

ND

Nf

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

HERCULES INCORPORATF~

Jacksonvi.1le, Arkansas Facility Internal Monitoring




2-Chlorophenol 1.55 ND ND ND

4-Chlorophenol 13.0* 6.19* ND ND




2,4,5-Trichlorophenol 29.03 2.08 ND ND i"··-

2,4,6-Trichlorophenol 0.40 ND ND ND

2-Chlorophenoxyacetic acid 4.54 2.13 ND ND

4-Chlorophenoxyacetic acid ND ND ND ND

2,4-Dichlorophenoxyacetic acid 39.62 37.8 ND ND

2,6-Dichlorophenoxyacetic acid *Combined *Combined ND ND


2,4,6-Trichlorophenoxyacetic acid ND ND ND ND

2-(2,4,5-Trichlorophenoxy) Propionic acid ND ND ND ND

02/15/88

Phenol 1.6 ND 1.05 ND

2-Chlorophenol 2.07 ND ND ND

4-Chlorophenol 30.37* ND 7.96* ND

2,4-Dichlorophenol 67.80 ND 7.72 ND

2,6-Dichlorophenol ND ND 0.26 ND


2,4,5-Trichlorophenol 35.67 ND 0.56 ND 2,4,6-Trichlorophenol 8.58 ND ND ND 2-Chlorophenoxyacetic acid 23.1 ND 2.46 ND

4-Chlorophenoxyacetic acid 10.12 ND ND ND

2,4-Dichlorophenoxyacetic acid 265.8 ND 27.63 ND

2,6-Dichlorophenoxyacetic acid *Combined ND *Combined ND 2,4,5-Trichlorophenoxyacetic acid 74.8 ND 8.18 ND

2,4,6-Trichlorophenoxyacetic acid 48.0 ND ND ND

2-(2,4,5-Trichlorophenoxy) Propionic acid 7.1 ND ND ND

HERCULES INCORPORATEP

Jacksonviile, Arkansas Facility Int~rnal Monitoring


01/21/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











01/22/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol










OUTFALL 002

ND

ND

ND

2.63

ND

ND

ND

ND

ND

ND

5.07

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

2.88

ND

ND

ND


0.51 0.69

ND ND

4.62* 7.88*

5.57 0.95

0.87 0.81

ND ND

ND ND

ND ND ,· 1.85 3.58 C

ND 2.24

21.07 27.8

*Combined *Combined

4.1 ND

ND ND

ND ND

0.89 ND

ND ND

4.08* 7.88*

5.11 ND

0.63 1.13

ND ND

ND ND

ND ND

0.99 3.36

ND 2.65

20.96 2.75

*Combined *Combined

ND ND

ND ND

TC





Phenol ND 0.80 0.68

2-Chlorophenol ND 0.52 0.48


2,4-Dichlorophenol 0.55 6.09 ND

2,~~bichlorophenol ND 1.00 0.50


2, 4 ,,-5-Trichlorophenol NO ND ND

2, 4·,-6-Trichlorophenol ND ND ND








01/26/88

Phenol ND 0.6 ND




2,6-Dichlorophenol ND o. 77 ND





4-Chlorophenoxyacetic acid ND ND 2.5 2,4-Dichlorophenoxyacetic acid 0.74 22.46 29.9





TO

C\"2 M O".l ~ .,-.j

0


Jacksonv le, Arkansas Facility In rnal Monitoring


01/29/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











02/01/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











OUTFALL WASTEWAER TO 002 1st Bed

ND 1.08

ND ND

ND ND

ND 6.8

ND 1.03

ND ND

ND

ND

ND

ND

1.2

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

0.87

ND

ND

ND

ND

ND

ND

1. 72

ND

27.29

8.42

4.69

ND

ND

1.08

ND

9.25*

7.46

o. 72

ND

ND

ND

2.67

ND

31. 7

*Combined

4.16

ND

ND

WASTEWATER TC 2nd Bed

ND

ND

3.50*

0.60

0.78

ND

ND

ND

1.34

ND

9.05

*Combined

ND

ND

ND

0.69

ND

5.4*

ND

ND

ND

ND

ND

1. 47

ND

9.17 *Combined

ND . ND

ND

C




01/27/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











01/28/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











OUTFALL WASTEWATER TO 002 1st Bed

ND ND

ND ND

ND 3.99*

ND 4.~9

ND ND

ND ND

ND ND

ND ND

ND 1.48

ND ND

1.62 22.1

ND *Combined

ND 2.3

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

2.08

ND

ND

ND

ND

ND

ND

0.67

ND

5.89*

6.36

0.89

ND

ND

ND

2.2

ND

29.4

*Combined

6.15

ND

ND


0.56

ND

9.56*

ND .,...j 0

0.480

ND

ND

ND

('I':,

"" e, r ...

5.0 .,...j

3.85 O

41. 9

*Combined

ND

ND

ND

0.73

0.52

7.95*

ND

0.61

ND

ND

ND

4.73

3.05 31.0

*Combined

ND

ND

ND


Jacksonvi~ e, Arkansas Facility Inte_.1al Monitoring



Phenol ND 0.99 0.97









4-Chlorophenoxyacetic acid ND I. 47 0.82

2,4-Dichlorophenoxyacetic acid 1.16 27.89 10. 30


2,4,5-Trichlorophenoxyacetic acid ND 0.91 ND 2,4,6-Trichlorophenoxyacetic acid ND ND ND


02/03/88

Phenol ND 0.86 3.1 2-Chlorophenol ND ND ND 4-Chlorophenol ND 9.6* 5.5* 2,4-Dichlorophenol ND 12.6 ND 2,6-Dichlorophenol ND 2.19 ND 2,3,6-Trichlorophenol ND ND ND 2,4,5-Trichlorophenol ND ND ND 2,4,6-Trichlorophenol ND ND ND 2-Chlorophenoxyacetic acid ND 4.6 1.90 4-Chlorophenoxyacetic acid ND 2.94 ND 2,4-Dichlorophenoxyacetic acid 1.4 56.22 14. 49

2,6-Dichlorophenoxyacetic acid ND *Combined *Combined 2,4,5-Trichlorophenoxyacetic acid ND 8.99 ND 2,4,6-Trichlorophenoxyacetic acid ND ND ND


TO

,,_

C


Jacksonv~~le, Arkansas Facility In~_rnal Monitoring

All Concentrations in mg/

02/04/88 OUTFALL WASTEWATER TO WASTEWATER TC 002 1st Bed 2nd Bed

Phenol ND 0.64 0.65


4-Chlorophenol ND 5.39* ND


2,6-Dichlorophenol ND ND 0.64'


2,4,5-Trichlorophenol ND ND ND ..__





2,6-Dichlorophenoxyacetic acid ND *Combined 6.57




02/05/88

Phenol ND 0.81 0.79






2,4,5-Trichlorophenol ND 3.78 ND













Phenol ND 4.22 0.50

2-Chlorophenol ND 0.51 ND

4-Chlorophenol ND ND 5.19*




2,4,5-Trichlorophenol ND 2.35 ....---

ND





2,6-Dichlorophenoxyacetic acid ND 5.47 *Combined




02/09/88

Phenol ND 0.87 ND











2,6-Dichlorophenoxyacetic acid ND *Combined ND





Jacksonv~ le, Arkansas Facility Int. .·nal Monitoring


02/10/88 OUTFALL WASTEWATER TO WASTEWATER

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











02/11/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











002

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

0.96

ND

ND

ND

ND

1st Bed 2nd Bed

0.84 ND

0.73 ND

7.8* ND

6.67 ND

0.98 ND -ND ND

ND ND ·-ND ND ·,-

2.04 ND C

1.41 ND

26.75 ND

*Combined ND

3.77 ND

ND ND

ND ND

0.71 ND

0.31 ND

3.5* ND

3.59 ND

0.53 ND

ND ND

ND ND

ND ND

0.99 ND

ND ND

11.28 ND

*Combined ND

ND ND

ND ND

ND ND

TC





Phenol ND ND ND




2,6-Dichlorophenol ND ND ND


2,4,5-Trichlorophenol ND ND ND ',"-·"




2,4-Dichlorophenoxyacetic acid 0.73 6.69 ND





02/15/88

Phenol ND 1.69 ND

2-Chlorophenol ND 0.18 ND


2,4-Dichlorophenol ND 8.1 ND 2,6-Dichlorophenol ND ND ND

2,3,6-Trichlorophenol ND ND ND 2,4,5-Trichlorophenol ND ND ND

2,4,6-Trichlorophenol ND ND ND 2-Chlorophenoxyacetic acid ND 1.81 ND 4-Chlorophenoxyacetic acid ND ND ND 2,4-Dichlorophenoxyacetic acid 0.84 25.44 ND

2,6-Dichlorophenoxyacetic acid ND *Combined ND 2,4,5-Trichlorophenoxyacetic acid ND 3.47 ND



TO





Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











02/17/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol








2,4,S-Trichlorophenoxyacetic acid



002

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1.3

ND

ND

ND

ND

1st Bed 2nd Bed

1.88 ND

0.52 ND

ND ND

5.15 ND ,·

6.66 ND

ND ND r---ND ND ,-.

'--ND ND

1.533 ND

ND ND

24.l ND

ND ND

2.76 ND

ND ND

ND ND

1.41 ND

0.22 ND

8.0* ND

8.13 ND

ND ND

ND ND

ND ND

ND ND

1.76 ND

ND ND

28.66 ND

*Combined ND

5.12 ND

ND ND

ND ND

HERCULES INCORPORATE.



02/18/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











02/19/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol







2,6-Dichlorophenoxyace~ic acid




OUTFALL 002

ND

0.37

ND

ND

ND

ND

ND

ND

ND

ND

1.1

ND

ND

ND

ND

ND

0.68*

ND

1.69

ND

ND

ND

ND

ND

ND

2.20

*Combined

ND

ND

ND


1.78

3.4*

5.4

10.l

1.38

ND

ND

ND

2.2

1.2

24.0

*Combined

5.2

ND

ND

0.36

2.5*

1.73

9.76

0.91

ND

ND

ND

2.88

1.64

30.2

*Combined

5.6

4.3

ND


ND

0.37

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

0.41*

ND

ND

ND

ND

ND

ND

ND

ND ND

*Combined

ND

ND

ND

C

.(fol HERCULES Hercules Incorporated 101 0 Marshall Road Jacksonville, AR 72076 (501) 982-9481

CERTIFIED MAIL

Mr. Frank Stephens Assistant Manager Jacksonville Wastewater Utility Post Office Box 69 Jacksonville, Arkansas 72076

Dear Mr. Stephens:

March 24, 1988

The Hercules' internal monitoring analytical and flow data report for the period February 21, 1988 through March 20, 1988 is enclosed. These data are submitted pursuant to our compliance with Addendum III, item (4) of our Pretreatment Discharge Permit.

We are experiencing problems with our effluent flow meter. The meter is not indicating accurately and has been removed from service for repair. In the interim until the meter is repaired, we will report flows based on the in-plant totalizing meter.


MJF:bb

Enclosures

Sincerely,


~ft:: Senior Environmental Engineer Site Manager

0

HERCULES INCORPORATED JACKSONVILLE~ ARKANSAS FACILITY INTERNAL MoINTORING

FLOW DAre- ALL FLOWS IN GALLONS/DAY

DATE SANITARY 002 REASOR-HILL DRAIN

NORTH DRAIN

SOUTH DRAIR

02/21/88 10,llO 31,860 2,490 9.,570 14.,650

02/22/88 7,650 26., 810 2,280 8.,120 12,850 Cc

02/23/88 6,740 38,630 2,820 9.,170 12.,200

02/24/88 8.,050 22,980 3.,230 8.,180 11,590 --~ 02/25/88 6.,860 9.,310 2.,040 8.,100 10.,630 ,-·

02/26/88 6.,450 16.,710 2.,780 8.,740 9.,900 C

02/27/88 4.,580 23.,890 1,800 7.,930 9.,440

02/28/88 4A40 19.,380 1.,940 7.,880 8.,820

02/29/88 4,530 11,790 2,800 7.,460 8.,320

03/01/88 4.,550 40,210 2.,780 6.,800 7.,580

03/02/88 19.,350 69.,860 2.,540 7.,590 7.,380

03/03/88 30.,160 70.,180 2.,900 8.,140 7.,180

03/04/88 30.,080 51,990 2.,890 8.,030 7.,270

03/05/88 28.,300 18.,960 1.,130 7.,610 6.,80

03/06/88 26,160 11.,700 2.,780 7.,070 6.,170

03/07/88 23.,790 15.,910 2.,820 7.,530 6,080

03/08/88 5.,140 24.,410 2.,530 6.,810 6,200

03/09/88 9.,240 40.,500 3.,070 11.,330 9,040

03/10/88 7.,820 40,120 1.,930 9,900 9.,330

03/11/88 5.,960 28.,804* 2.,540 8.,530 8.,950

03/12/88 6.,250 45.,174* 2.,980 7.,940 9.,100

03/13/88 8.,230 66,424* 3.,000 9,560 10.,310

03/14/88 7.,090 50.,017* 3.,370 8.,880 9,750

03/15/88 7,050 38.,02?* . ,a 2,100 8,280 9.,290

03/16/88 5.,800 50., 820*3-" ,~' I 2.,080 7.,610 8.,llO 03/17/88 4,800 46 050*•' 51 l\:J- 2.,380 7,520 7.,770

.1 1 :,..Si

03/18/88 5,490 62 470* 1-t "l, 0

3 2.,830 6.,940 7,920 .I O I

03/19/88 8.,300 73 750* .,s ,~" 2,140 7.,830 7.,690 ., ~'.l l,

03/20/88 3,160 60., 530* 3 (,, . 3,310 7.,650 7.,340

TOTAL 306.,130 L 107., 264 ~ Da.7, l~t 74.,280 236.,700 257.,660

•FLOW TOTALIZER NOT WORKING - NUMBERS FROM BACKUP METER,

HERCULES INCORPORATED JACKSONVILLE, ARKANSAS FACILITY INTERNAL MONITORING

ALL CONCENTRATIONS IN MG/L

02/22/88

PHENOL 2-CHLOROPHENOL LJ-CHLOROPHENOL 2,lJ-DJCHLOROPHENOL 2,6-DICHLOROPHENOL 2,3,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2,LJ,6-TRICHLOROPHENOL 2-CHLOROPHENOXYACETIC ACID 11-(HLOROPHENOXYACET IC ACID

2,4-DICHLOROPHENOXYACETIC ACID 2, 6-DICHLOROPHENOXYACETilC ACID 2,LJ,5-TRICHLOROPHENOXYACETIC ACID ~,4,6-TRICHLOROPHENOXYACETIC ACID ~-(2,4,5-TRICHLOROPHENDXY)

PRDPIONIC ACID

)2/29/88 1HENOL 1-CHLOROPHENOL !-(HLOROPHENOL ',4-DICHLOROPHENOL ',6-DICHLOROPHENOL ', 3,6-TRI CHLOROPHENOL ', 4, 5-TR I CHLOROPHENOL ,4,6-TRICHLOROPHENOL

-[HLOROPHENOXYACETIC ACID -(HLOROPHENOXYACETIC ACID

,4-DICHLOROPHENOXYACETIC ACID ,6-DICHLOROPHENOXYACETIC ACID ,LJ,5-TRICHLOROPHENOXYACETIC ACID ,4,6-TRICHLOROPHENOXYACETIC ACID -(2,4,5-TRICHLOROPHENOXY)

PROP IONIC AC ID

REASOR-HILL LEACRAIE

2.74 15.25*

5.81 83.7 7.61

ND 53.1 8.0

19.27 9.6

138.5 *COMBINED

37.11 17,3

ND

3.49 15.50* 12.34 64.77 10.79 ND 12.22 0.92

20.76 8,119

134.77 *COMBINED

84.93 22.3

61.0

COMBINED N. BURIAL [EACRAIE LEACHAIE

0.79 3.2 1.11* 2.7 11.2

ND ND 3,116

ND ND ND 13.29

5,8* 7.1

12.57 1.78

ND ND ND ND 2.85

24.06 *COMBINED *CoMBIEND

0.38 6.2 ND ND

ND ND

1.1 9.2* 6.68 6.48 1.03

ND 0.5

ND 17.5 1.2

28.0 *COMBINED

6.85 ND

ND

ND 0,90

ND 2,3

ND ND ND ND ND ND 2.49

ND ND ND

ND

S.F. DRAIN LEACHAIE

ND ND ND ND ND :ND DN C

ND · ND ND ND ND ND ND

ND

ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND


ALL CONCENTRATIONS IN MGIL

03/07/88 REASOR-HILL COMBINED N. BURIAL S. BURIAL CEACRAIE CEACAAIE CEACRAIE [EACRAIE

PHENOL 14.9 2.35 0,35 ND

2-(HLOROPHENOL 31.17* 5.93* 0.56* ND

4-CHLOROPHENOL 9.78 4.40 1.26 ND

2J4-DICHLOROPHENOL 87.29 19,99 1.31 ND

2J6-DICHLOROPHENOL · 14.12 3.12 ND ND

2J3J6-TRICHLOROPHENOL ND ND ND ND

2J4J5-TRICHLOROPHENOL 56.38** ND ND ND

2J4J6-TRICHLOROPHENOL 6,5 ND ND ND C

2-CHLOROPHENOXYACETIC ACID 33.97 6.14 ND ND

4-CHLOROPHENOXYACETIC ACID 15.60 2.76 ND ND

2J4-DICHLOROPHENOXYACETIC ACID 38.76 88.97 3.05 ND

2J6-0ICHLOROPHENOXYACETIC ACID *COMBINED *COMBINED *COMBINED ND

2J4J5-TRICHLOROPHENOXYACETIC ACID 119.4 26.56 ND ND

2J5J6-TRICHLOROPHENOXYACETIC ACID 27.0 4.76 ND ND

2-(2J4J5-TRICHLOROPHENOXY) PROP IONIC AC ID **COMBINED 10,65 ND ND

03/14/88

PHENOL 2.8 1.03 2.6 ND

2-CHLOROPHENOL 14.05* 2.27* 3.09* ND

4-CHLOROPHENOL 1.05 3.21 7.46 ND

2J4-DICHLOROPHENOL 72.26 9.34 10.48 ND

2J6-DICHLOROPHENOL 11.41 1.06 1.18 ND

2J3J6-TRICHLOROPHENOL ND ND ND ND

2J4J5-TRICHLOROPHENOL 66.6** ND 0.98 ND

2,4,6-lRICHLOROPHENOL 10,07 ND 0,97 ND

2-CHLOROPHENOXYACETIC ACID 17,47 1.73 1.66 ND

4-CHLOROPHENOXYACETIC ACID 7,81 0.91 0.82 ND

2J4-DICHLOROPHENOXYACETIC ACID 236.5 25.50 19.33 ND

2J6-DICHLOROPHENOXYACETIC ACID *COMBINED *COMBINED *COMBINED ND

2J4J5-TRICHLOROPHENOXYACETIC ACID 81.3 8.26 5.8 ND

2J4J6-TRICHLOROPHENOXYACETIC ACID 12.37 ND 1.35 ND

2-(2J4J5-TRICHLOROPHENOXY) PROPIONIC ACID **COMBINED ND ND ND

HERCULcS 1NCURPORATtD JACKSONVT E1 ARKANSAS FACILITY lNT NAL MONITORING


02122/88

PHENOL 2-CHLOROPHENOL 4-(HLOROPHENOL 2,4-DICHLOROPHENOL 2,6-DICHLOROPHENOL 2,3,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2,4,6-TRICHLOROPHENOL 2-(HLOROPHENOXYACETIC ACID 4-(HLOROPHENOXYACETIC ACID 2,4-DICHLOROPHENOXYACETIC ACID 2,6-DICHLOROPHENOXYACETIC ACID 2,4,5-TRICHLOROPHENOXYACETIC ACID 2,4,6-TRICHLOROPHENOXYACETIC ACID 2-(2,4,5-TRICHLOROPHENOXY)

PROPIONIC ACID

02/23/88

PHENOL 2-CHLOROPHENOL 4-CHLOROPHENOL 2,4-DICHLOROPHENOL 2,6-DICHLOROPHENOL 2,3,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2,4,6-TRICHLOROPHENOL 2-(HLOROPHENOXYACETIC ACID

4-(HLOROPHENOXYACETIC ACID

2,4-DICHLOROPHENOXYACETIC ACID 2,6-DICHLOROPHENOXYACETIC ACID 2, lJ, 5-TR ICHLOROPHENOXYACETIC ACID 2,4,6-TRICHLOROPHENOXYACETIC ACID 2-(2,4,5-TRICHLOROPHENOXY)

PROPIONIC ACID

OUTFALL WASTEWATER TO 002 lsT BED

ND 0.59 0.38*

ND 0.36


1.78* 2.56 7.3 0,44

ND ND ND 1.66 0.87

19.07 *COMBINED *COMBINED

ND 4.18 ND 4.46

ND

ND ND ND ND ND ND ND ND ND ND 2.2

ND ND ND

ND

ND

1.0 0.21*

3.4 6.86 0.51

ND ND ND 1.78 0,92

22,06 *COMBINED

1.01 5.62

ND

WASTEWATER . 2ND BED

ND ND ND ND ND ND ND r•-. ND ND C

ND ND ND ND ND

ND


ND

HERCULES INCORPORATFQ JACKSON\,LLE, ARKANSAS FACILITY I~,cRNAL MONITORING


02/24/88

PHENOL 2-(HLOROPHENOL 4-(HLOROPHENOL 2,4-DICHLOROPHENOL 2,6-DICHLOROPHENOL 2,3,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2,4,6-TRICHLOROPHENOL 2-(HLOROPHENOXYACETIC ACID 4-(HLOROPHENOXYACETIC ACID 2,4-DICHLOROPHENOXYACETIC ACID 2,6-DICHLOROPHENOXYACETIC ACID 2,4,5-TRICHLOROPHENOXYACETIC ACID 2,4,6-TRICHLOROPHENOXYACETIC ACID 2-(2,4,5-TRICHLOROPHENOXY)

PROPIONIC ACID

02/25/88

PHENOL 2-(HLOROPHENOL 4-CHLOROPHENOL 2,4-DICHLOROPHENOL 2,6-DICHLOROPHENOL 2,3,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2,4,6-TRICHLOROPHENOL 2-CHLOROPHENOXYACETIC ACID 4-CHLOROPHENOXYACETIC ACID 2,4-DICHLOROPHENOXYACETIC ACID 2,6-DICHLOROPHENOXYACETIC ACID 2,4,5-TRICHLOROPHENOXYACETIC ACID 2,4,6-TRICHLOROPHENOXYACETIC ACID 2-(2,4,5-TRICHLOROPHENOXY)

PROP IONIC AC ID

OUTFALL 002

0.31 ND ND ND ND ND ND ND ND ND 3,65

ND ND ND

ND

ND ND ND ND ND ND ND ND ND ND 2,25

ND ND ND

ND

WASTEWATER TO 1ST BED

1.1 1,32* 3.16 6.76 1.42

ND ND ND 2.96 1.21

20,5 *COMBINED

3.69 ND

ND

1.08 1.47 3.2 9,63 2,2

ND ND ND 2.5 1.70

30.7 1.2 4.46

ND

ND

WASTEWATER 2ND BED

ND ND· 0.39

ND_ND -ND ND:~ND ~ ND ND ND ND ND rm

ND

ND ND ND ND ND ND ND ND ND ND 0,50

ND ND ND

ND

HERCULES INCORPORATED JACKSONVL E, ARKANSAS FACILITY INT ..... NAL MONITORING


02/26/88

PHENOL 2-CHLOROPHENOL 4-(HLOROPHENOL 2,4-DICHLOROPHENOL 2,6-DICHLOROPHENOL 2,3,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2,4,6-TRICHLOROPHENOL 2-CHLOROPHENOXYACETIC ACID

4-CHLOROPHENOXYACETIC ACID

2,4-DICHLOROPHENOXYACETIC ACID 2,6-DICHLOROPHENOXYACETIC ACID 2,4,5-TRICHLOROPHENOXYACETIC ACID 2,4,6-TRICHLOROPHENOXYACETIC ACID 2-(2,4,5-TRICHLOROPHENOXY)

PROPIONIC ACID

02/29/88

PHENOL 2-CHLOROPHENOL 4-CHLOROPHENOL 2,4-DICHLOROPHENOL 2,6-DICHLOROPHENOL 2,3,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2,4,6-TRICHLOROPHENOL 2-CHLOROPHENOXYACETIC ACID 4-CHLOROPHENOXYACETIC ACID 2,4-DICHLOROPHENOXYACETIC ACID 2,6-DICHLOROPHENOXYACETIC ACID 2,4,5-TRICHLOROPHENOXYACETIC ACID 2,4,6-TRICHLOROPHENOXYACETIC ACID 2-(2,4,5-TRICHLOROPHENOXY)

PROPIONIC ACID

OUTFALL WASTEWATER TO 002 lsr BED

ND 0.43 ND 0.93* ND 1.70 ND 7.8 ND ND ND ND ND ND ND ND ND 1.67 ND 0.87 1.56 20.75

ND *COMBINED ND 4,4 ND 1,36

ND

ND ND ND ND 0.33

ND ND ND ND ND 1.3

ND ND ND

ND

2.45

ND 2,5* 3.5 8.52 1.08

ND 3.48

ND 2.25 1.3

35.51 *COMBINED

6.27 ND

ND

WASTEWATER ZND BED

0.3 ND 1.0

ND ND ND ND ND 1'-

ND ~ '---'

ND 0.42

ND ND ND

ND


ND ND ND

ND

HERCULES INCORPORATET

JACKSONVILLE., ARKANSAS FACILITY INTERNAL MONITORING ALL CONCENTRATIONS IN MGIL

03/01/88 OUTFALL WASTEWATER TO WASTEWATER 002 IsT BED 2ND BED

PHENOL ND 1.17 ND

2-(HLOROPHENOL ND ND ND

4-(HLOROPHENOL ND 3.12 ND

2,4-DICHLOROPHENOL ND 10.48 ND


2,3,6-TRICHLOROPHENOL ND ND ND



2-CHLOROPHENOXYACETIC ACID ND 1.83 ND c,

4-(HLOROPHENOXYACETIC ACID ND 2,6 ND

2,4-DICHLOROPHENOXYACETIC ACID 1.61 23,9 0.55

2,6-DICHLOROPHENOXYACETIC ACID ND ND ND

2,4,5-TRICHLOROPHENOXYACETIC ACID ND 5.51 ND.

2,4,6-TRICHLOROPHENOXYACETIC ACID ND 0,68 ND

2-(2,4,5-TRICHLOROPHENOXY) PROP IONIC AC ID ND ND ND

03/02/88

PHENOL ND 1.55 ND

2-CHLOROPHENOL ND 1.57 ND

4-(HLOROPHENOL ND 3,90 ND




2,4,5-TRICHLOROPHENOL ND 2.4 ND


2-CHLOROPHENOXYACETIC ACID ND 4,99 ND

4-(HLOROPHENOXVACETIC ACID ND 2.83 ND 2,4-DICHLOROPHENOXYACETIC ACID 1.36 36.15 ND

2,6-DICHLOROPHENOXYACETIC ACID ND 1.18 ND

2,4,5-TRICHLOROPHENOXYACETIC ACID ND 6.3 ND

2,4,6-TRICHLOROPHENOXYACETIC ACID ND ND ND


HERCULES INCORPORATED JACKSONV, _E1 ARKANSAS FACILITY fNl .NAL MONITORING


03/03/88

PHENOL 2-(HLOROPHENOL 4-CHLOROPHENOL 2,4-DICHLOROPHENOL 2,6-DICHLOROPHENOL 2,3,6-TRICHLOROPHENOL 2, lJ, 5-T RI CHLOROPHENOL 2,4,6-TRICHLOROPHENOL 2-CHLOROPHENOXYACETIC ACID 4-CHLOROPHENOXYACETIC ACID 2,4-DICHLOROPHENOXYACETIC ACID 2,6-DICHLOROPHENOXYACETIC ACID 2,4,5-TRICHLOROPHENOXYACETIC ACID 2,4,6-TRICHLOROPHENOXYACETIC ACID 2-(2,4~5-TRICHLOROPHENOXY)

PROPIONIC ACID

03/04/88

PHENOL 2-CHLOROPHENOL 4-CHLOROPHENOL 2,4-DICHLOROPHENOL 2,6-DICHLOROPHENOL 2,3,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2,4,6-TRICHLOROPHENOL 2-CHLOROPHENOXYACETIC ACID 4-(HLOROPHENOXYACETIC ACID 2,4-DICHLOROPHENOXYACETIC ACID 2,6-DICHLOROPHENOXYACETIC ACID 2,4,5-TRICHLOROPHENOXYACETIC ACID 2,4,6-TRICHLOROPHENOXYACETIC ACID 2-(2,4,5-TRICHLOROPHENOXY)

PROPIONIC ACID

OUTFALL 002

ND ND ND 0,36


ND ND ND

ND

ND ND ND 0.42


ND ND ND

ND

WASTEWATER TO lsT BED

0,995 2.53* 0.322 7.84 1.03

ND 5.95

ND 2. lJ 1.37

29.37 *COMBINED

ND ND

ND

1.1 2,58* 3.10 7.25 1.19

ND 2,88

ND 2.32

ND 22.06

*COMBINED 4.35

ND

ND

WASTEWATER 2ND BED ND ND ND ND ND ND 1.09

ND ND

1·-.

ND 0

0.61 ND. ND ND

ND


ND

HERCULES INCORPORAJtD JACKSONV ·-El ARKANSAS FACILITY JN- !NAL MONITORING


03/07/88 OUTFALL WASTEWATER TO WASTEWATER 002 Isr BED 2ND BED

PHENOL ND 1.58 ND

2-(HLOROPHENOL ND 2,65* ND


2,4-DICHLOROPHENOL 0.77 9.19 ND





2-(HLOROPHENOXYACETIC ACID ND 2.28 ND

4-CHLOROPHENOXYACETIC ACID ND 1.54 ND .-.__

2,4-DICHLOROPHENOXYACETIC ACID 2.66 29.13 ND

2,6-DICHLOROPHENOXYACETIC ACID ND *COMBINED ND

2,4,5-TRICHLOROPHENOXYACETJC ACID ND 5.64 ND

2,4,6-TRJCHLOROPHENOXYACETIC ACID ND ND ND

2-(2,4,5-TRICHLOROPHENOXY) PROPIONIC ACID ND ND ND

03/08/88

PHENOL ND 1. 6l/ ND

2-(HLOROPHENOL 0.31* 6,13* ND

4-(HLOROPHENOL 0,30 0.96 ND






2-(HLOROPHENOXYACETIC ACID 0,26 2.30 ND

4-CHLOROPHENOXYACETIC ACID ND 3,55 ND 214-DICHLOROPHENOXYACETIC ACID 1.79 30.53 ND

2,6-DICHLOROPHENOXYACETIC ACID *COMBINED *COMBINED ND




HERCULES INCORPORATF-,IACKSONVILLE, ARKANSAS FACILITY INTERNAL MONITORING


03/09/88 OUTFALL WASTEWATER TO WASTEWATER 002 1ST BED ZND BED

PHENOL 2-CHLOROPHENOL 4-(HLOROPHENOL 2,4-DICHLOROPHENOL 2,6-DICHLOROPHENOL 2,3,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2,4,6-TRICHLOROPHENOL 2-(HLOROPHENOXYACETIC ACID

4-CHLOROPHENOXYACETIC ACID 2,4-DICHLOROPHENOXYACETIC ACID 2,6-DICHLOROPHENOXYACETIC ACID 2,4,5-TRICHLOROPHENOXYACETIC ACID 2,4,6-TRICHLOROPHENOXYACETIC ACID 2-(2,4,5-TRICHLOROPHENOXY)

PROP I ON IC AC ID

03/10/88

PHENOL 2-CHLOROPHENOL 4-(HLOROPHENOL 2,4-DICHLOROPHENOL 2,6-DICHLOROPHENOL 2,3,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2,4,6-TRICHLOROPHENOL 2-CHLOROPHENOXYACETIC ACID 4-(HLOROPHENOXYACETIC ACID 2,4-DICHLOROPHENOXYACETIC ACID 2,6-DICHLOROPHENOXYACETIC ACID 2,4,5-TRICHLOROPHENOXYACETIC ACID 2,4,6-TRICHLOROPHENOXYACETIC ACID 2-(2,4,5-TRICHLOROPHENOXY)

PROPIONIC ACID


ND ND ND

ND


ND ND ND

ND

0.87 2.54* 2,99 9.06 1.2

ND 1.54

ND 2.87 1.43

34.77 *COMBINED

8.24 2.84

ND_ -

1.21 2,19* 3.31 7.92 1.34

ND 3.29

ND 3.64 1.34

24.89 *COMBINED

4,92 2.0

ND

ND ND ND ND ND ND ND ND C

ND ND ND ND ND ND


ND



03/11/88 OUTFALL WASTEWATER TO WASTEWATER 002 Isr Brn 2ND BED

NO SAMPLES TAKEN

03/14/88 \

PHENOL ND 0,93 ND .. 2-CHLOROPHENOL ND 1.89* ND ·.·· 4-CHLOROPHENOL ND 3.0 ND C

2,4-DICHLOROPHENOL ND 5.856 ND 2,6-DICHLOROPHENOL ND 0.71 ND 2,3,6-TRICHLOROPHENOL ND ND ND 2,4,5-TRICHLOROPHENOL ND 3.01 ND 2,4,6-TRICHLOROPHENOL ND ND ND 2-(HLOROPHENOXYACETIC ACID ND 1.45 ND 4-CHLOROPHENOXYACETIC ACID ND 0.80 ND 2,4-DICHLOROPHENOXYACETIC ACID ND 21.3 ND 2,6-DICHLOROPHENOXYACETIC ACID ND *COMBINED ND 2,4,5-TRICHLOROPHENOXYACETIC ACID ND 2.87 ND 2,4,6-TRICHLOROPHENOXYACETIC ACID ND ND ND 2-(2,4,5-TRICHLOROPHENOXY)

PROPIONIC ACID ND ND ND


JACKSONVILLE, ARKANSAS FACILITY INTERNAL MONITORING ALL CONCENTRATIONS IN MGIL

03/15/88 OUTFALL WASTEWATER TO WASTEWATEF 002 IsT BED 2ND BEi

PHENOL ND 1.6 ND

2-CHLOROPHENOL ND 2.24* ND


2,4-DICHLOROPHENOL ND 7.23 ND,.


2,3,6-TRICHLOROPHENOL ND ND ND:--

2,4,5-TRICHLOROPHENOL ND .07 ND·~ '-


2-CHLOROPHENOXYACETIC ACID ND 0.15 ND

4-CHLOROPHENOXYACETIC ACID ND ND ND

2,4-DICHLOROPHENOXYACETIC ACID ND 24.36 ND

2,6-DICHLOROPHENOXYACETIC ACID MD *COMBINED ND




03/16/88

PHENOL ND 2.52 0,56

2-CHLOROPHENOL ND 3.68* ND

4-(HLOROPHENOL ND 4.56 ND



2,3,6-TRICHLOROPHENOL ND ND -ND



2-[HLOROPHENOXYACETIC ACID ND 1.83 ND

4-CHLOROPHENOXYACETIC ACID ND 1.47 ND

2,4-DICHLOROPHENOXYACETIC ACID 0.73 28,51 ND

2,6-DICHLOROPHENOXYACETIC ACID ND *COMBINED ND



2-(2,4,5-TRICHLOROPHENOXY) PROPIONIC ACID ND ND ND

HERCULES INCORPORATL_ JACKSONVILLEl ARKANSAS FACILITY INTERNAL MONITORING


03/17/88 OUTFALL WASTEWATER TO WASTEWATE 002 IsT Brn ZND BE

PHENOL ND 0.87 0.19

2-(HLOROPHENOL ND 1.9* 0.69*




2,3,6-TRICHLOROPHENOL ND ND ND ;---

2,4,5-TRICHLOROPHENOL ND ND ND C


2-CHLOROPHENOXYACETIC ACID ND ND ND


2,4-DICHLOROPHENOXYACETIC ACID 0.9 20.97 ND

2,6-DICHLOROPHENOXYACETIC ACID ND *COMBINED *COMBINED



2-(2,4,5-TRICHLOROPHENOXY) PROPIONIC ACID ND ND Nr

03/18/88

PHENOL ND 2.48 0.78

2-(HLOROPHENOL 0.31* 1.75 ND

4-(HLOROPHENOL 0.30 3.96 0.31

2,4-DICHLOROPHENOL ND 9,86 ND





2-(HLOROPHENOXYACETIC ACID 0.35 2.55 0.36


2,4-DICHLOR0PHEN0XYACETIC ACID 0.82 30.71 ND 2,6-DrcHLOROPHENOXYACETIC ACID *COMBINED 2.2 ND




J'.RHERCULES

CERTIFIED MAIL

Mr. Dick Morris, Manager Jacksonville Wastewater Utility Post Office Box 69 Jacksonville, Arkansas 72076

Dear Mr. Morris:

April 22, 1988

Hercules Incorporated 101 O Marshall Road Jacksonville, AR 72076 (501) 982-9481

The Hercules' internal monitoring analytical and flow data report for the period March 21, 1988 through April 20, 1988 is enclosed. These data are submitted pursuant to our compliance with Addendum III, item (4) of our Pretreatment Discharge Permit.

Also enclosed is a corrected copy of the flow data for the period February 21, 1988 through March 20, 1988. The only figures changed are - 002 - March 16 - 20.

The effluent flow meter removed from service during the last reporting period has now been repaired and is in service again.


MJF:bb

Enclosures

Sincerely,


J~ff){:;t~~~cility

///,::UJ·,/, 7c:: l-U

Michael J. Falco Senior Environmental Engineer Site Manager

0

CORRECTED COPY UERCULES INCORPORATED

JACKSONVILLE, ARKANSAS FACILITY INTERNAL MoINTORING FLOW DATA - ALL FLOWS IN GALLONS/DAY

DATE SANITARY 002 i REASOR-HILL NORTH SDUTII -ummr--= 7JR7Titr uRJTTN-

]2/21/88 10.,110 31., 860 2.,490 9.,570 14.,650

)2/22/88 7.,650 26.,810 2.,280 8.,120 12.,850 _

)2/23/88 6.,740 38.,630 2.,820 9.,170 12.,200_::

)2/24/88 8.,050 22.,980 3.,230 8.,180 11.,590

)2/25/88 6.,860 9.,310 2.,040 8.,100 10., 630:~~

]2/26/88 6.,450 16.,710 2.,780 8,,740 9.,900~

)2/27 /88 4.,580 23.,890 1.,800 7.,930 9.,440

12/28/88 4., 440 19.,380 1., 940 7.,880 8.,820

12/29/88 lf.,530 11.,790 2.,800 7".,IJ60 8.,320

)3/01/88 4.,550 40.,210 2.,780 6.,800 7.,580

)3/02/88 19.,350 69.,860 2.,540 7.,590 7.,380

13/03/88 30.,160 70.,180 2.,900 8.,140 7.,18:

13/04/88 30.,080 51.,990 2.,890 8.,030 7.,270

13/05/88 28.,300 18.,960 1.,130 7,610 6.,800

13/06/88 26.,160 11.,700 2.,780 7,070 6.,170

3/07/88 23.,790 15.,910 2.,820 7.,530 6.,080

3/08/88 5,140 24.,410 2.,530 6,810 6.,200

3/09/88 9.,240 40,500 3,070 11.,330 9., OLIO

3/10/88 7,820 40.120 1., 930 9.,900 9.,330

3/11/88 5.,960 28.,804* 2,540 8.,530 8,950

3/12/88 6.,250 45,174* 2.,980 7.,9lf0 9,100

3/13/88 8.,230 66,424* 3,000 . 9.,560 10.,310

3/14/88 7,090 50.,017* 3.,370 8.,880 9,750

3/15/88 7,050 38.,025* 2,100 8,280 · 1~,290

3/16/88 5.,800 32,139* 2.,080 7,610 8.,110

3/17/88 4,800 28.,421* 2,380 7,520 7,770

5/18/88 5.,490 43.,328* 2.,830 6., 9lfD 7.,920

5/19/88 8.,300 48,263* 2,ll!O 7.,830 7,690

'i/20/88 3.,160 36.,426* 3.,310 7,650 7.,340

TOTAL 306.,130 1.,002.,221 71.J,280 236,700 257.,660

LOW TOTALIZER NOT WORKING - NUMBERS FROM BACKUP METER.





B/21/88 3,670 28,233* 2,810 7,560 6,850 03/22/88 3,530 23,820* 1,050 7,500 6,360

03/23/88 3,160 24,140* 2,800 6,620 5,880

B/24/88 3,280 28,522* 2,810 6,670 5,500

13/25/88 6,020 36,596* 2,810 10,820 7,070

::>3/26/88 7,070 56,560* 3,060 8,980 10,490 :----

)3/27/88 5,250 43,157* 850 8,240 9,420 C

J3/28/88 4,320 30,953* 2,600 8,230 8,490

)3/29/88 3,410 38,799* 2,540 8,460 8,400

)3/30/88 7,050 52,655* 3,160 8,750 7,920

13/31/88 5,130 56,075* 1,810 8,390 7,960

14/01/88 5,140 35,004* 2,620 8,330 7,540

)4/02/88 6,270 43,485* 3,170 10,880 14,000

14/03/88 5,580 53,897* 1,050 9,120 4,410

14/04/88 5,310 41,244* 2,690 8,640 9,970

)4/05/88 4,280 39,131* 2,570 7,630 8,710

14/06/88 24,870 51,810* 3,240 9,650 9,020

14/07/88 5,830 53,075* 1,910 8,620 9,820

14/08/88 5,020 35,862* 2,640 8,230 9,120

)4/09/88 5,060 30,261* 3,240 7,680 8,130

14/10/88 3,310 24,702* 950 7,520 7,550

)4/11/88 4,500 26,533* 2,630 7,440 6,800

14/12/88 6,250 66,867* 3,370 10,770 8,180

14/13/88 6,140 45,835* 2,000 9,020 8,180

14/14/88 6,640 34,485 2,720 8,570 7,450

14/15/88 3,560 37,276 3,240 8,450 6,640 4/16/88 4,450 37,627 1,890 6,920 6,380

4/17/88 6,270 29,591 1,690 8,370 6,060

4/18/88 10,500 55,716 4,710 18,750 11,640

4/19/88 13,170 68,169 2,230 10,970 18,150

,4/20/88 7,860 73,812 3,280 9,680 19,280

TOTAL 191,900 1,303,892 78,140 275,460 271,370

Flow totalizer not working - numbers from backup meter

HERCULES INCORPORATF



03/21/88 REASOR-HILL COMBINED N. BURIAL LEACHATE LEACHATE LEACHATE

Phenol 1.79 7.1 ND


4-Chlorophenol 10.70 11.68 ND




2,4,5-Trichlorophenol 19.86 9.44 ND

2,4,6-Trichlorophenol 7.48 ND ND

2-Chlorophenoxyacetic acid l.98 5.75 ND



2,6-Dichlorophenoxyacetic acid *Combined *Combined ND

2,4,5-Trichlorophenoxyacetic acid 15.60 15.05 ND

2,4,6-Trichlorophenoxyacetic acid 3.18 ND ND


03/28 & 04/04/88 - NO SAMPLES

S.F. DRAIN LEACHATE

ND

ND

ND

ND

ND ,,-,

ND

ND j'-

ND 0

ND

ND

ND

ND

ND

ND

ND




04/11/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol






REASOR-HILL COMBINED N. BURIAL S.F. DRAIN LEACHATE LEACHATE LEACHATE LEACHATE

3.48 1.41 4.62 ND

12.87* 1.58 6.2* ND

7.72 3.65 13.98 ND

55.58 7.62 45.53 ND

19.58 2.81 6.54 ND

ND ND ND ND

29.11 0.80 ND ND

2.06 ND 0.80 ND

17.50 2.79 5.76 ND

10.25 1.38 4.62 ND


3.57

9.24

ND

55.94

*Combined

11.67

13.3

ND

ND 2,6-Dichlorophenoxyacetic acid *Combined



2-(2,4,5-Trichlorophenoxy) Propionic acid ND

04/18/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol







2.0

7.6*

5.49

51.22

15.6

ND

53.4

7.7

11.41

5.5

139.l

*Combined



2-(2,4,5-Trichlorophenoxy) Propionic acid 12. 60

ND

0.88

2.35*

2.44

18.23

4.31

ND

14.46

2.30

2.66

1.22

41.02

11.61

2.10

2.7*

6.3

17.97

2.72

ND

10.53

ND

2.69

2.22

24.4

*Combined *Combined

14.13

3.98

NO

6.44

2.88

ND

ND C:

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

HERCULES INCORPORATE_



03/21/88 OUTFALL WASTEWATER TO 002 1st Bed

Phenol ND 2.68

2-Chlorophenol ND 2.46*

4-Chlorophenol ND 5.45 2,4-Dichlorophenol ND 11.36

2,6-Dichlorophenol ND 2.47


2,4,5-Trichlorophenol ND 1. 71


2-Chlorophenoxyacetic acid ND 1. 98

4-Chlorophenoxyacetic acid ND 1.51

2,4-Dichlorophenoxyacetic acid 1. 36 31. 91

2,6-Dichlorophenoxyacetic acid ND *Combined

2,4,5-Trichlorophenoxyacetic acid ND 1.37



03/22/88

Phenol ND 1.80

2-Chlorophenol ND 2.20









2,4,-Dichlorophenoxyacetic acid 0.56 44.78

WASTEWATER r

2nd Bed

0.96

1.52*

ND ND

ND

ND

ND

ND --ND

ND c;

ND

*Combined

ND

ND

ND

1.27

3.60*

ND

ND

ND

ND

ND

ND

ND

ND

ND

2,6-Dichlorophenoxyacetic acid ND 2.90 *Combined

2,4,5-Trichlorophenoxyacetic acid ND 7. 72 ND

2,4,6-Trichlorophenoxyacetic acid ND ND ND 2-(2,4,5-Trichlorophenoxy)

Propionic acid ND ND ND

HERCULES INCORPORATEu




Phenol ND 1.74






2,4,5-Trichlorophenol ND 4.18




2,4-Dichlorophenoxyacetic acid ND 35.32





03/24/88

Phenol ND 1. 78


4-Chlorophenol ND 4. 71





2,4,6-Trichlorophenol ND ND 2-Chlorophenoxyacetic acid ND 2.96

4-Chlorophenoxyacetic acid ND 1.05 2,4-Dichlorophenoxyacetic acid ND 34.95




WASTEWATER ' 2nd Bed

ND

ND

ND

ND

ND

ND

ND

ND C

ND

ND

0.87

ND

ND

ND

ND

0.87

ND

ND

ND

ND

ND

ND

ND

ND

ND ND

ND

ND

ND

HERCULES INCORPORATE[


All Concentrations in mg/I


Phenol ND 1.10



2,4-Dichlorophenol ND 11. 58






4-Chlorophenoxyacetic acid ND 1. 79






03/28/88

Phenol ND 1.52


4-Chlorophenol ND 3.80 2,4-Dichlorophenol ND 9.18



2,4,5-Trichlorophenol ND ND 2,4,6-Trichlorophenol ND ND

2-Chlorophenoxyacetic acid ND 2.25 4-Chloropheno:xyacetic acid ND 1.42

2,4-Dichlorophenoxyacetic acid ND 31.22 2,6-Dichlorophenoxyacetic acid ND *Combined


2,4,6-Trichlorophenoxyacetic acid ND ND 2-(2,4,5-Trichlorophenoxy)

Propionic acid ND ND

WASTEWATER T 2nd Bed

0.94

ND

ND

ND

ND

ND

ND C

ND

ND

ND

ND

ND

ND

ND

ND

0.63

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

HERCULES INCORPORATE.




Phenol ND 1.35









4-Chlorophenoxyacetic acid ND l. 77






03/30/88

Phenol ND 0.94















WASTEWATER 2nd Bed

1.13

ND

ND

ND

ND

ND --

ND ~-

ND

ND

ND

ND

ND

ND

ND

ND

0.85

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

HERCULES INCORPORAT.



03/31/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











04/01/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND ND

ND

ND

ND

ND

ND

1.14

1. 82*

3.51

9.61

1.40

ND

2.06

ND

2.66

1.57

26.54

*Combined

3.08

2.43

ND

1.58

0.15*

3.64

6.70

1. 46

ND

ND

ND

1.95

1.22

24.20

•Combined

ND

ND

ND

0.98

ND

ND

ND

ND

ND

ND

ND

ND

2.37

ND

ND

ND

ND

ND

0.48

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

HERCULES INCORPORA'- v Jacksonville, Arkansas Facility Internal Monitoring


04/01/8~ OUTFALL WASTEWATER TO 002 1st Bed

Phenol ND 1.00















04/05/88

Phenol ND 1.93








2-Chlorophenoxyacetic acid ND 4.2 4-Chlorophenoxyacetic acid ND 2.46






WAS TEWA TE! 2nd Be,

1.4

ND

ND

ND:

ND.

ND:--

ND~

NDC

ND

0.78

ND

ND.

Nl'

NL

ND

ND

ND

ND

ND

ND

ND

ND

ND

2.38 ND

ND

ND

ND

ND

ND




04/06/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











04/07/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











OUTFALL 002

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND


1.21

0.83

3. 77

7.56

2.85

ND

ND

ND

3.87

2.26

33.13

1.74

7.78

1.66

ND

1.5

1. 78

6.3

9.45

2.33

ND

1.67

ND

3.66

2.64

32.26

4.15

6.6

3.3

ND

WASTEWATER 2nd Bed

1.06

ND

ND

ND

ND

ND

ND C ND

ND

ND

2.94

ND

ND

ND

ND

1. 72

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

HERCULES INCORPORA~-J



04/08/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











04/11/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











OUTFALL 002

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND


1.28

2. 77*

4.3

11. 94

2.82

ND

1.21

ND

1.83

1.25

38.98

*Combined

7.44

2.53

ND

1.97

3.34*

ND

10.1

3.26

ND

0.42

ND

2.97

1.33

34.91

*Combined

9.46

3.28

ND

WASTEWATER 2nd Bed

1.02

ND

ND

ND

ND ,~ ND

ND C

ND

ND

ND

ND

ND

ND

ND

ND

1.4

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND





Phenol ND 0.80

2-Chlorophenol ND 1. 89*














04/13/88

Phenol ND 0.65















WASTEWATER ~

2nd Bed

0.35

ND

ND

ND

ND

ND

ND C

ND

ND

ND

ND

ND

ND

ND

ND

o. 72

ND

ND

ND

ND

ND

ND

ND

ND ND

ND

ND

ND

ND

ND

HERCULES INCORPORATb~



04/14/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











04/15/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol



2,4,6-Trichlorophenol 2-Chlorophenoxyacetic acid







OUTFALL 002

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND ND

ND

ND

ND

ND

ND

ND


1.65

0.69*

3.57

8.66

2.08

ND

ND

ND

1.93

0.31

28.69

*Combined

6.11

ND

ND

0.73

1.35*

2.26

3.38

0.66

ND

1.58

ND 1.20

0.47

13.17

*Combined

2.85

1.49

ND

WASTEWATER 2nd Bed

0.96

ND

ND

ND

ND r--ND

ND ,---~ ND

ND

ND

ND

ND

ND

ND

ND

0.80

ND

ND

ND

ND

ND

ND

ND ND

ND

ND

ND

ND

ND

ND

HERCULES INCORPORA~-J



04/18/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol











04/19/88

Phenol

2-Chlorophenol

4-Chlorophenol

2,4-Dichlorophenol

2,6-Dichlorophenol





4-Chlorophen~xyacetic acid






OUTFALL 002

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND


1. 45

2.05*

3. 31

7.93

1.37

ND

3.16

ND

1.88

0.95

24.50

*Combined

5.87

2.57

ND

0.65

2.20*

2.61

11.97

2.56

ND

ND

ND

2.09

3.89

23.16

*Combined

6.15

ND

ND

WASTEWATER 2nd Bed

0.73

ND

ND

ND

ND

ND r--

ND ·~,

ND

ND

ND

ND

ND

ND

ND

NC

1.27

ND

ND

ND

ND

ND

ND

ND

14.26

ND

ND

ND

ND

ND

ND





Phenol ND 0.55

2-Chlorophenol ND ND










2,6-Dichlorophenoxyacetic acid ND ND


2,4,6-Trichlorophenoxyacetic acid NE ND


WASTEWATER 2nd Bed

0.87

ND

ND

ND -~-

ND c-

ND C

ND

ND

ND

ND

ND

ND

ND

ND

ND

( L)

VERHIC sm JRCKSONVILLE,A~ ,-

WASTEWH£R PRETRH1TIIENT OPERATIO~ EFFLUENT OAT.\

2,J,6- 2,4,5- 2,4,6- 214-D 2,4,5-T 2,4,6-T 2,l,7,8-LOCllllaN FLOW pH ISS TDC 016 CHLORIOE JDS TOLIJHIE PHENOL 2-IICP 4-~CP 2,4-0CP 2,6-DCP TCP TCP TCP ACID ACID ACID SILVEJ TCDD (STRE"411J IIIHE !9pdl IS/UJ (1g/l) (■gill !,g/1) hg/ll (1g/l) hg/1) l1g/ll f1qlll (1g/ll ! ■ git) l1g/l! (■g/11 (1g/ll l ■ g/ll (lg/ll (■gill (1g1ll ! ■ g/11 (nq!IJ

001 OI/0~-07187 SOOH 6.00 "' " 29'1.7 b070 2b!I.OO 0,J'r:i 0.1m 0,M4 ,a " 001 01115-lb/87 38925 "' o.os~ " "' .. .. " 0.2l5 0,032 0.035 0.001>

002 0t/22/87 55269 379.00

001 02/02-03187 60056 6.46 3) 315.00 0.043 0.125 0,044 0,064 0.022 0.02~ 0.011 o.no 0,043 0.045 0,024 " 002 02111/87 31091 &.23 II " 002 02/IB-19/87 li7297 6.58 " " .. 493.00 0.044 0.02'i' 0.036 0.083 " 0.005 0.00b 0,163 0.010 0.007 .. 002 02/22/87 H189 6.82 0,(11

002 C212M4/87 35063 0.044 0,053 0.033 0.0711 NO 0.014 0.008 1.fllO ~.IH C

0.071 0.0JO

001 02/24·25/87 468111 0,188 0.267 0.081 o.m " 0,046 0.023 uoo 0.123 0,127 0.031 (_ CO2 03105-06187 Hrn 6.!3 57 NO 1780,00 0.0B8 o.m 0,125 0.114 NO O.C67 0.034 2.600 0.287 0.!50 0.0~6 ND

002 03/13107 46183 6,!4 .. 002 03/19-20/87 62417 418,00 0,124 o.m 0.074 0.146 NO 0.055 0.023 0,730 0,131 0.075 0.023

002 03126/87 40518 6,05 IS " 002 04101/87 30241 6.20 JB NO

002 0(109/87 23910 6.09 NO

002 0~/1511!7 22oqq 6.37 14 NO

001 01/17181 36035 6.20 !JO NO

001 04122-23187 373:''i' 6.55 IS 12 NO 372.00 0,023 0.199 o.ooq o.,m NO o.ooa 0.006 0.239 0,021 0.032 0.007

002 oms-mer lbW ,.n 200 NO

'" 002 05/0M87 l'i'7% 6.33 17 NO

002 05/13/87 12194 6.32 NO

002 05/19-20187 130~~ 6.40 14 !14.00 NO 0.0!6 NO 0.072 NO NO NO Q.385 0.019 O.Oi9 NO NO

001 051n/BI 71751 6.t8 4[G!)

10

VERTACSITE JACKSONYILLE,AR

VitiSlEllf!TU PREHIH1l'1mn OPER11110N EFFLUENT DATA

2,3,ii- 2,4,5- 2,4,&· 2,4-D 2,4 15-T 2,4,6-T 2,3,7,B-LocmoN FLDW pH rss roe "" CHLORIDE m TOlUENE PHENOL 2-NCP ◄ -NCP 214-IICP 2,0-DCP TCP TCP TCP mo ACIB ACID SILVEX TC.DD !STREA~) DATE lgpdl 15/UJ ltglll [1g/ll {1g/ll (1gfl) !•gill (19/l) (1g/tl 119/ll (1q/l) (1gtll 119/ll hg/1! C1g/ll (ag/11 (1g/1l hgfll 119(1) ! ■ gill (ng/lJ

002 05/28/67 12786 6.33 ,. IO

002 06/05/87 10820 6.Jb JIO " 002 06/09-10/87 31233 i,,92 31 " 150,00 0.025 0.161 '" 0.045 " " ND 0.21,I 0.011 0.019 " '° 002 06117187 35973 6,'1

'°' %1?5187 629QO S.76 IJ JI

"' Ob/29-)0rn? lbl81 h,90 II " 001 07102/Sl J0339 0.020 0.033 0,037 0.0211 0.055 0,038 0.045 4.770 0,1118 0.325 0.06B

( 002 07!0/i-07187 14135 6.71 0.054 o.ua 0.127 o.m " 0.017 ND o.m 0.015 0.024 '" 002 07/!b/ei am 6,98 17 ND l 001 01!21/87 12430 7.31 48 " 002 07129/87 11180 b.71 180 IJ

002 08/04-05187 36770 9.65 0.185 o.m 0.122 0.111 NP 0.028 ND 1.140 0.014 0.115 0.009

002 08/ll-14/87 13670 !3.30 0,239 o.m 0.064 0.305 NO 0.021 ND 0.197 " 0.022 NO

002 08124-2518] !1850 '" 002 0%)2-1)~/87 ~4550 b.\f, 100 ND Sb.Ii) o.rn \,21,1) 0. 10~ o.srs '" ND 0.0lS o.1ai " 0.MS NO

"' 09/11/B? 13850 6.65 13 17,60

002 09/lb-!7/Bl q1mo 5.% " 12 NO '" ND 0.011! '" '" ND o.m 0.011 o.on 0.005 '" 002 O'i/13/87 28610 us 760

001 10102/B1 24160 6.38 12

001 !0107/87 19070 s.n JO '" CO2 10112-ll/87 20030 b.40 1, " ND '" ND " ND ND

"" ND 0.100 NO 0.007 '" NC

002 I0/20/81 2&,m U7 2J

00:' !0127187 4;1;0 6,41, JO

/_ I ()

\JERTAC SITE JACXSONV!LLE,RR

WASTEWr1TERPRETREAil1ENTOPERATION EFFLUENTDMA

2,l,6- 2,4,5-2 I·~~- 21--n ?,~,S-1 l,~,t.-T 213,1.B-l{lCM"Hlll fl!) .. ,, TSS lOC O&a CHLORIDE TDS TOlUENE PHENOL 2-IICP 4-NCP 21 HCP 2,6-DCP lCP lCP lCP ACIO ACIO ACID Sflm rm !STREMI! DATE (gpcl) (5/Ul (1g/l) l1g/ll l1g/tl f1g/ll ciw.itll bg/l) laglll l1g/ll lagll) (1g!ll (1g!I) 119/IJ lag/II l ■glll t1g/ll l ■ g/ll (1g/IJ l ■g/11 (ngllJ

002 l!/06/87 H80 5.% " ND

002 ll/13/87 67350 NO ND ND ND ND ND ND 0.040 ND ND ND

002 II/IHB7 23790 0,0b ND

001 ll118/B7 li6b60 6.52 " 001 11124187 72B30 5.1:.1 ND ND ND " " " " 0,033 0.007 ND ND

002 12/0lrel :m10 5.85

002 121[19/87 '50830 S.BB " ND 1.72 ND ,n ND ND " " " 0, JOO 0.033 0,020 0.007 " '°' 12110/87 96330 &.07 4.80 NO (

002 12/2[-22/87 SH20 5.03 ' ND

001 12/31/87 158170 U9 40 ND

" ND 0.087 0.017 ND 0.067 0.00 2.JJO O.JbB 0.174 o.m 002 01/06/89 51B4 70 ND 119 503 20.80 " ND " 0.015 0.025 " 0.010 0.007 0,570 0.110 0,045 0,028 ND

002 01112-tlrBB 437B0 5.87 ND 171 2.49 ND " 0,010 0,105 0.021 " 0,053 0.030 1.700 0.260 0.110 0,041 ND

002 01129/89 5W7 5.95 lD " 001 02102-0HBB b20~3 5.96 '° 10.50 0.008 0.008 O.OII 0.110 0,022 " 0.046 o.rn l.BlO o.m 0.124 0,040 " 001 02111-12/8B S5b68

001 03101-02/BB: W:i?c 2.7b " " ND ND NO NO ND NO 0.640 0,2H 0.08B 0.025 NO

002 03/17-18188 43l2B lb 452 ,1, 4.82 ND " ND ND " ND ND " 0.44[ o.on 0.044 0,013

002 03/23-24188 28522 0.1'i 0.076 ND ND 0.01:i: " NO O.OOB " O.OBS 0,011 0.0011, ND

002 omo-311aa 56075 0.91 ND " ND ND " ND ND " 0.037 0.009 " ND

002 OH0~-01188 53075 0.94 ND NO ND " NO NO ND ., 0.027 ND NO NO ND

002 orno-21/68 mso 405 0.87 NO " ND NO ND ND ND NO 0.044 0.010 ND NO

JACKSONVILLE WASTEWATER UTILITY INDUSTRIAL WASTEWATER DISCHARGE PERMIT

Perr.tit No. 87-02-21-I

In accordance with all terms and conditions of Jacksonville

City Ordinance No. 620, and also with any applicable pro

visions of Federal or state law or regulation;

Permission Is Hereby Granted To Hercules Incorporated

Classified by SIC No. Non-manufacturing (2879)

For the contribution of industrial wastewater into the

Jacksonville Wastewater Utility sewer lines at

1010 Marshall Road

This permit is granted in accordance with the application filed

on _____ M_a_y'-_1 ____ , 19_8_7 ___ in the office of the Jacksonville

11astewa ter Utility and in conformity with plans, specifications

and other data submitted to the Jacksonville Wastewater Utility

in support of the above application, all of which are filed with

and considered as part of this permit, together with the following

named conditions and requirew.ents.

Effective this Sthday of June

To Expire __ l_s_t __ day of April

c:~· Manager, Jacksonville Wastewater Utility

1'or upon sixty (60) days written notice by the Jacksonville Sewer Commission.

ADDENDUM I

The undersigned hereby attest that they are authorized to conduct

business on behalf of Hercules Incorporated, and that any agreement

which they shall sign on behalf of that company shall be binding

upon the organization known as Hercules Incorporated, as relates

to the disposition of the Jacksonville site known as Vertac.

The undersigned further state their awareness that any permit issued

to the Vertac site by the Jacksonville Sewer Commission will expireC

on April 1, 1989, or sixty (60) calendar days after written notice

by the Jacksonville Sewer Commission. In no case shall wastewater

generated at the vertac site be discharged to any Jacksonville Waste

water Utility treatment works other than the present West Treatment

Facility.

e Authorized Representative les Incorporated

Name and Title of Authorized Representative (please type)

4~//;' 'o,t✓~ Signature at, oc 1 Representative of Hercules Incorporated

Michael j. Falco, Senior Environmental Engineer Name and Title of Local Representative

(please type)

4/?,o/:n Date

Ii_- .:2?-S) Date

Penni t No • __ 8_7_-_0_2_-_2_1_-_r __ _

ADDENDUM Il

Monitoring Schedule

1. Surveillance, Enforcement and Surcharge Monitoring shall be performed at a frequency subject to the discretion of the Utility.

2. The Utility reserves the right to increase monitoring frequency on any and all parameters without notice.

3. Self-monitoring for 2,4-D and 2,4 Dichlorophenol shall be performed not less than weekly on all contributory waste streams as well as on the guard bed and the carbon columns.

C

Permit No. 87-02-21-1

ADDENDUM III

Special Requirements

1) In case of an accidental discharge the Jacksonville Wastewater Utility must be notified immediately by telephone. Notification shall include location of discharge, type of waste, concentration and volume, and corrective actions to be taken.

2) A notice shall be permanently posted on the User's bulletin board or other prominent place advising employees of the notification procedure in the event of a dangerous discharge. Employer shall ensure that all employees who may cause or witness such & dangerous discharge are advised of the emergency notification procedure.

3) Within five days of an accidental discharge the User shall submit to the Manager of the Jacksonville Wastewater Utility a detailed written report describing the cause of the discharge and the measures to be taken by the User to prevent similar future incidents.

4) By the 1st of each month, the User shall report the results .of all selfmonitoring conducted during the previous month, as measured from the 21st day to the 20th day. These data shall be submitted in chart form to include all monitored flow volumes and parameters.

5) The Utility shall be notified at least twenty-four (24) hours prior to carbon regeneration.

6) The Utility shall be notified thirty (30) days prior to any proposed change in operations at the site.

C

Parameters (mg/1)

Biochemical Oxygen Demand

Chemical Oxygen Demand

Total Suspended Solids pH-maximum pH-minimum

Oil & Grease

Flow (MGD)

Arsenic (As) Cadmium (Cd)

Chromium (Cr) Copper (Cu) Cvanide (CN) Lead (Pb)

Mercurv <H<>\ Nickel (Nl) Silver (A<,,)

Zinc (Zn\

Chloride Tolvene

Parameters (LBS/DAY)

Phenol 2-or-4 Chlorophenol

2,4 - Dichlorophenol 2,6 - Dichloroohenol 2,4,5 - Trichloroohenol 2,4,6 - Trichlorophenol 2,4 D 2,4,5 T Silvex 2 3 7 8 TCDD

E- Enforcement Monitoring sv- Surveillance l'.oni taring SC- Surcharge !1onitoring

Perr.tit ,lo. 87-02-21-1

Limitations on Wastewater Strength

250 10 10

5 5 100

0.4 0.4 0.45 0.45 2.2 2.2 0.7 0.7 1. 2 1.2 0.7 0.7 0.012 0.012 1.0 1.0 0.8 fl R

1.5 250 250 14.3 14.3

12. 4 0.004

0.021 0.006

0.031 0.077

11. 90 14.90 0.60 0

Monitoring Requirements

(E, SV, SC)

SC

E,SV

E SV E sv

E SV E,SV E,SV

E SV

E SV

" '"'

E SV E,SV

E <:11

E,SV

E,SV

E SV E,SV

E,SV E SV E,SV

E SV