SafetyDataSheetVRLARechargeableBattery/
PortableJumpStartersUtilizingSameUpdatedAugust24,2017
SECTION1:PRODUCTANDCOMPANYIDENTIFICATIONProductName: ValveRegulatedLead-AcidRechargeableBattery,MaintenanceFreeBatteryCompany: CloreAutomotiveAddress: 8735RosehillRd.,Suite220,Lenexa,KS66215E-mail: [email protected]: 913.310.1050Emergency: CHEMTEL–888.255.3924;+1.813.248.0573Models: JNC300XL/JNC300XLC/JNC4000/JNC660/JNC660C/JNCAIR/JNC770/ JNC950/JNC1224/JNC065/JNC080/JNC100/JNC105/JNC110Remark: Thisitem(sealedVRLArechargeablebattery)isconsideredanarticleas definedby29CFR1910.1200(OSHAHazardCommunicationStandard). TheinformationcontainedinthisSDSissuppliedatthecustomer’srequest forinformationonly.Chemicalfamily:Thisproductisanon-spillable,wetleadacidstoragebattery.Mayalsoincludegelabsorbedelectrolytetypeleadacidbatterytypes.SECTION2:HAZARDSIDENTIFICATIONGHSLabelElements:
SignalWord:Danger
Category GHSCodes DescriptionHealth
STOTRE2AcuteTox.4Repr.1A
SkinCorr.1AFlam.Gas1
AquaticChronic1AquaticAcute1
H302H314H332H360H373H220H410P260P301/330/331P303/361/353
-Harmfulifswallowed.-Causessevereskinburnsandeyedamage.-Harmfulifinhaled.-Maydamagefertilityortheunbornchild.-Maycausedamagetoorgansthroughprolongedorrepeatedexposure.-Extremelyflammablegas(hydrogen).-Verytoxictoaquaticlifewithlonglastingeffects.-Donotbreathedust/fume/gas/mist/vapors/spray.-IFSWALLOWED:rinsemouth.DoNOTinducevomiting.-IFONSKIN(orhair):Remove/Takeoffimmediatelyallcontaminatedclothing.Rinseskinwithwater/shower.-IFINHALED:Removevictimtofreshairandkeepatrestinapositioncomfortableforbreathing.-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo.Continuerinsing.ImmediatelycallaPOISONCENTERordoctor/physician.
Handling P210P260P264P280P403P405P391P273P501
-Keepawayfromheat/sparks/openflames/hotsurfaces.Nosmoking.-Donotbreathedust/fume/gas/mist/vapors/spray.-Washthoroughlyafterhandling.-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.-Storeinwell-ventilatedarea-Storelockedup.-Collectspillage.-Avoidreleasetotheenvironment.-Disposeofcontents/containerinaccordancewithlocal/regional/national/internationalregulation.
Note:Thebatteryhaspassedthevibrationtest,pressuredifferentialtestandleakagetestat55°CaccordingtorecommendationsontheTRANSPORTOFDANGEROUSGOODSModelRegulation
17thSPECIALPROVISION238.ItisnotrestrictedaccordingtoIATADangerousGoodsRegulation(DGR)56thperspecialprovisionA67andisnotrestrictedaccordingtoIMDGCODEperspecialprovision238.
SECTION3:INFORMATIONONINGREDIENTS
Ingredient CASNo. Concentration(%byWt.) HazardousLabelInorganicLead/LeadCompounds
7439-92-1 ~72% T
SulfuricAcid 7664-93-9 ~20% CFiberglassSeparator 65997-17-3 ~2% /
SiliconDioxide(Gelbatteriesonly) 7631-86-9 ~10%ofacidWt. /
ContainerPlastic(ABSorPP)
9003-56-9(ABS) ~5% /9003-07-0(PP) /
Note:Inorganicleadandelectrolyte(waterandsulfuricacidsolution)aretheprimarycomponentsofallCloreAutomotiveportablejumpstarterbatteries.Otheringredientsmaybepresentdependentuponbatterytype.ABSistheprimarycasematerialofourjumpstarterbatteries.SECTION4:FIRST-AIDMEASURESTakeproperprecautionstoensureyourownhealthandsafetybeforeattemptingtorescueavictimandprovidefirstaid.SkinContact:Electrolyte:Flushwithlargeamountsofwaterforatleast15minutes;removecontaminatedclothingcompletely,includingshoes,anddonotwearagainuntilcleaned.Ifacidissplashedonshoes,removeanddiscardiftheycontainleather.Leadcompounds:Washimmediatelywithsoapandwater.Leadcompoundsarenotreadilyabsorbedthroughtheskin.EyeContact:ElectrolyteandLeadcompounds:Flushimmediatelywithlargeamountsofwaterforatleast15minutes;consultphysicianimmediately.InhalationExposure:Electrolyte:Ifsulfuricacidmistorvaporisinhaled,movetoanareawithfreshairandwarmyourselfusingablanket.Seekmedicaladvice/attentionimmediately.Leadcompounds:Removefromexposure,gargle,washnoseandlips;consultphysician.
OralExposure:Electrolyte:Ifthisliquidisswallowed,washyourmouthwithplentyofwaterimmediately,thendrinkplentyofwater.Obtainmedicaladviceorattention.Donotinducevomitingwhenswallowed.Inaddition,donotperformanyaction,suchasaneutralizationprocess.Leadcompounds:Consultphysicianimmediately.
SECTION5:FIREFIGHTINGMEASURES
FlashPoint:NotApplicableFlammableLimits:LEL=4.1%(hydrogengasinair);UEL=74.1%ExtinguishingMedia:Smallfire–Foamhalogenand/ornon-flammablegasfireextinguisherLargefire:Largequantitiesofsprinkledand/oratomizedwater.(Inthiscase,topreventenvironmentaldamage,flushwatermustbetreatedappropriately.)Particularhazards:Irritant,corrosiveand/ortoxicgasesmayescapefromaburningbattery.Properfirefighting:Ifpossible,disconnectfrompowerfirstifbatteriesareonchargeorremoveignitionsourceandremovebatteriesfromthefiresource.Wherepossible,extinguishthefirefromwellventilatedareaupwindfromfire.Waterusedtoextinguishfiremustbetreatedappropriatelytopreventenvironmentaldamage.Cooldownburntbatteriesusingplentyofwater.FireFightingProcedures:Usepositivepressure,self-containedbreathingapparatus.Bewareofacidsplatterduringwaterapplicationandwearacid-resistantclothing,gloves,faceandeyeprotection.Ifbatteriesareoncharge,shutoffpowertothechargingequipment,but,notethatstringsofseriesconnectedbatteriesmaystillposeriskofelectricshockevenwhenchargingequipmentisshutdown.
SECTION6:ACCIDENTALRELEASEMEASURES
Humanbody:Donottouchthespilledelectrolyteandwalkaroundthespillagesite.Keepoutsidersfromthespillagesite.Environment:Spilledelectrolytemustbetreatedappropriatelytopreventenvironmentaldamage,suchasdirectoutflowingofthespilledelectrolyteintoriver,drain,etc..Neutralization:Neutralizespilledelectrolytewithsodiumbicarbonate,lime,etc.andflushwithlargequantitiesofwater.
SECTION7:HANDLINGANDSTORAGE
Handling:Keepawayfromignitionsources,heatandflame.Batteriesmustbepackedinsuchamannerastoeffectivelypreventshortcircuitsandtopreventmovementwhichcouldleadtoshortcircuits.Avoidmechanicalorelectricalabuseandovercharge.Morethanamomentary
shortcircuitwillgenerallyreducethebatteryservicelife.Avoidreversingbatterypolaritywithinthebatteryassembly.Storage:Storeinacool,well-ventilatedarea.Keepawayfromignitionsources,heatandflame.Batteriesmustbepackedinsuchamannerastoeffectivelypreventshortcircuitsandtopreventmovementwhichcouldleadtoshortcircuits.MaterialstoAvoid:Strongoxidant,combustiblematerialsandcorrosives.Charging:Thereisapossibleriskofelectricshockfromchargingequipmentandfromstringsofseriesconnectedbatteries,whetherornottheyarebeingcharged.Shutoffpowertochargerswhenevernotinuseandbeforedetachmentofanycircuitconnections.Batteriesbeingchargedwillgenerateandreleaseflammablehydrogengas.Charginglocationshouldbewellventilated.Keepbatteryventcapsinposition.Prohibitsmokingandavoidcreationofflamesandsparksnearby.Wearfaceandeyeprotectionwhennearbatteries.
SECTION8:EXPOSURECONTROLANDPERSONALPROTECTION NotapplicableforValveRegulatedLeadAcidbattery.
SECTION9:PHYSICAL/CHEMICALPROPERTIESNotapplicableforValveRegulatedLeadAcidbattery.
Reference(component)
Electrolyte(SulfuricAcid) LeadAppearance Clear Silverysolid
SpecificGravity 1.280–1.380(38–48%) 11.3BoilingPoint 112deg.C(38%) 1740deg.CMeltingPoint -40deg.Corbelow 327deg.C
SolidifyingPoint -56.4deg.C(34.6%) -VaporPressure 3.17kPa(30%) 0.1Paorless(25deg.C)
SECTION10:STABILITYANDREACTIVITY
Stability:Stableundernormaltemperaturesandpressures.MaterialstoAvoid:Strongoxidant,corrosives.ConditionstoAvoid:Avoidexposuretoheatandopenflame.Avoidmechanicalorelectricalabuseandovercharge.Preventshortcircuits.Preventmovementwhichcouldleadtoshortcircuits.HazardousPolymerization:Willnotoccur.HazardousDecompositionProducts:Sulfuroxides,Sulfuricacidmist,Metaloxides.
SECTION11:TOXICOLOGICALINFORMATION
RoutesofEntry:Electrolyte:Harmfulbyallroutesofentry.Undernormalconditionsofuse,sulfuricacidvaporsandmistarenotgenerated.Sulfuricacidvaporsandmistmaybegeneratedwhenproductisoverheated,oxidized,orotherwiseprocessedordamaged.Leadcompounds:Undernormalconditionsofuse,leaddust,vapors,andfumesarenotgenerated.Hazardousexposurecanoccuronlywhenproductisheatedabovethemeltingpoint,oxidizedorotherwiseprocessedordamagedtocreatedust,vapor,orfume.AcuteToxicity:InhalationLD50:Electrolyte:LC50rat:375mg/m3;LC50:guineapig:510mg/m3ElementalLead:AcuteToxicityPointEstimate=4500ppmV(basedonleadbullion)OralLD50:Electrolyte:rat:2140mg/kgElementallead:AcuteToxicityEstimate(ATE)=500mg/kgbodyweight(basedonleadbullion)Correspondtosection3
SECTION12:ECOLOGICALINFORMATION
EnvironmentalFate:Leadisverypersistentinsoilandsediments.Nodataonenvironmentaldegradation.Mobilityofmetallicleadbetweenecologicalcompartmentsisslow.Bioaccumulationofleadoccursinaquaticandterrestrialanimalsandplantsbutlittlebioaccumulationoccursthroughthefoodchain.Moststudiesincludeleadcompoundsandnotelementallead.EnvironmentalToxicity:AquaticToxicity:Sulfuricacid:24-hrLC50,freshwaterfish(Brachydaniorerio):82mg/L96hr-LOEC,freshwaterfish(Cyprinuscarpio):22mg/LLead:48hrLC50(modeledforaquaticinvertebrates):<1mg/L,basedonleadbullion
SECTION13:DISPOSALCONSIDERATIONS
AppropriateMethodofDisposalofSubstance:Lead-acidbatteriesarecompletelyrecyclable.Returnwholescrapbatteriestodistributor,manufacturerorleadsmelterforrecycling.Forneutralizedspills,placeresidueinacid-resistantcontainerswithsorbentmaterial,sandorearthanddisposeofinaccordancewithlocal,stateandfederalregulationsforacidandleadcompounds.Contactlocaland/orstateenvironmentalofficialsregardingdisposalinformation.
SECTION14:TRANSPORTINFORMATION
WeherebycertifythatalllistedCloreAutomotiveportablejumpstarterbatteriesconformtotheUN2800classificationas“Batteries,Wet,Non-Spillable”asaresultofpassingtheVibrationandPressureDifferentialTestdescribedinD.O.T.,49CFR173.159(f),andIMO/IMDG,andICAO/IATApackinginstruction872andnoteA48,A67,A164andA183.ThebatteriesarenotrestrictedaccordingtoIMO/IMDGcodeperspecialprovision238.CloreAutomotiveportablejumpstarterbatteries,havingmettherelatedconditions,areEXEMPTfromhazardousgoodsregulationsforthepurposeoftransportationbyDOTandIATA/ICAO,andthereforeareunrestrictedfortransportationbyanymeans.Forallmodesoftransportation,eachbatteryouterpackagemustbelabeled"NON-SPILLABLE."ProductsreturnedtoCloreAutomotive,orsubsequentlytransported,thatcontainabatteryorjumpstarter,mustbereturnedintheoriginalpackageorinastrongouterbox,certifiedfortheweightoftheunit,withadequatepackingmaterialtopreventtheunitfrommovementinsidethecarton.Forshipmentsofbatteries,batterypostsmustbeprotectedtopreventanypossibleshortcircuit.Forjumpstarters,thegripsmustbeproperlywrappedaroundtheunitandclampssecuredtopreventashortcircuitintransit.Ifaunitisbeingtransportedwithmetalclamps,gripsmustbeprotectedusingtheoriginallysuppliedgripguards,orthegripswrappedsoastopreventashortcircuit.Inadditionthecartonmustbemarkedwithphrase'Non-spillablebattery'soastocomplywiththerequirementsfortransportingthisasanon-dangerousshipment.
SECTION15:REGULATORYINFORMATION
EURegulation:InaccordancewithEU2006/66/ECBatteryDirective,VRLAbatteriesshouldpresentcrossed-outwheeledbinsymbolofleadtogetherwiththeISOrecyclingsymbol.Doesnotcontainanymercury,Hg,(<0.0005%)orcadmium,Cd,(<0.002%).
SECTION16:OTHERINFORMATION
ProductssuchasBatteriesarenotinthescopeofregulationwhichrequiresthepublicationofanEUSafetyDataSheet(91/155/EEC).
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