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M4 Chemistry Matter I: M4 Chemistry Matter I: Matters Matters

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M4 Chemistry Matter I: M4 Chemistry Matter I: MattersMatters

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Learning ObjectivesLearning Objectives

• Concepts

– Chemistry, matter, substance, element, compound, mixture

– Homogeneous mixture, heterogeneous mixture, solution, colloid, alloy

– Microscopic, macroscopic, sub-microscopic, atom, molecule, ion

• Skills

– Define chemistry as the study of matter and how it changes.

– Define matter and distinguish it from forces and energy.

– Differentiate between pure matter and mixtures.

– Explain that matter that consists of only one type of particle (which includes elements and compounds) is classified as pure and has fixed properties

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Learning ObjectivesLearning Objectives

– Explain that matter that consists of more than one type of particle is classified as a mixture and has properties that vary.

– Be able to distinguish between element, compound and mixture.

– State that most matter exists as mixtures.

– Classify mixtures as homogeneous or heterogeneous.

– Classify homogeneous mixtures as solutions or colloids.

– Explain the difference between a compound and a mixture

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Birth of the earthBirth of the earth

Earth was born approx. 4600 million years Earth was born approx. 4600 million years

ago – a bit before I was born. ago – a bit before I was born.

Earth’s atmosphere would have been made Earth’s atmosphere would have been made

of the of the elementselements hydrogen and helium (just hydrogen and helium (just

like 99% of the universe was). like 99% of the universe was).

The Earth was a very very very hot The Earth was a very very very hot ballball of of

molten (molten (liliqquiduid) rock. ) rock.

It took millions of years for the Earth to gradually cool down.It took millions of years for the Earth to gradually cool down.

As it cooled down a As it cooled down a solidsolid crust formed on the outside surface crust formed on the outside surface

SPACE

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Formation of the atmosphere Formation of the atmosphere

The molten (liquid) rock underneath often burst through the thin crust.

Volcanoes were erupting all over the Earth’s surface giving out gases.

volcanic gases

carbon dioxide gas CO2

methane gas CH4

ammonia gas NH3

Steam (water) H2O

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Oceans and seasOceans and seas

As the Earth slowly cooled down the steam (g) (water vapour) in the atmosphere condensed into liquid water and fell as rain (l).

The water filled up the holes and hollows in the crust to form the first seas and oceans.

seas and oceans formed

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First living organismsFirst living organisms• The first living organisms are “thought” to have developed in the

oceans.

Volcanoes slowly erupting on the ocean floor “spew out” all the elements needed to evolve / develop simple cells.

The first organisms evolved into simple celled plants like algae.

The algae used carbon dioxide gas for photosynthesis and produced a waste gas called OXYGEN (g).

oxygen gas released

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OxygenOxygen

• Some of the waste oxygen, O2, released by the plants formed into ozone, O3.

An ozone layer eventually formed in the atmosphere.

The ozone layer prevented harmful high energy ultra-violet light rays from the sun from reaching the Earth’s surface. The formation of the ozone layer meant that life no longer needed the protection of the sea and could now develop on land.

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AtmosphereAtmosphere

• Some of the oxygen gas reacted with the ammonia gas in the atmosphere to give off nitrogen gas.

Large amounts of nitrogen was being produced by bacteria in the soil.

Methane gas also reacted with oxygen gas forming more nitrogen gas.

Ammonia and methane levels decreased & nitrogen levels increased.

Eventually, about 200 million years ago, the atmosphere we still have today had formed:

78% Nitrogen gas 21% Oxygen gas small amount of CO2 and CH4

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The history of the atmosphereThe history of the atmosphere

Early Volcanic Atmosphere

bacteria in the soil

Our atmosphere now

OXYGEN O2

21%

Photosynthesis

Some carbon trapped as fossil fuels.

Methane carbon dioxide ammonia steam CH4 CO2 NH3 H20reacted with

oxygen to form

plants

some CO2 gas

dissolved in the oceans

dissolved CO2 used by many sea animals to

form calcium carbonate shells, CaCO3

Sedimentary Rocks e.g. limestone or chalk

condense

oceansReacted with

oxygen

NITROGEN N2

78%

Noble gases Remaining 1%

(Argon = 0.09%)

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Matters of ChemistryMatters of Chemistry

• Thus matter was formed.

Chemistry is study of how matter interact, react and can be made to interact and react with each other.

What is matter?

Matter is the “stuff” that makes up all and every thing.

Matter has mass and occupies volume.

How can matter be identified?

Matter can be identified both macroscopically and sub-microscopically.

Macro- by its properties.

– Properties such as appearance, hardness, color, odor, malleability, ductility, viscosity, electrical conductivity, MP, BP, magnetism, etc.

• Sub-micro- by the particles (atoms and molecules) that make it up

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Macroscopic Properties & Submicroscopic Macroscopic Properties & Submicroscopic CompositionComposition

• Why do different types of matter have different properties?

The properties of matter macroscopically can be explained by the sub-microscopic particles that make them up.

If substances have different properties, then they must be made up of different sub-microscopic particles.

– They must be made up of different building blocks, such as atoms, molecules and ions.

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Creation of New MatterCreation of New Matter

• How many different forms of matter exist?

Millions, Billlions, Trillions

There are approximately 115 elements. Eg. carbon, gold

All of these elements can bond together to form millions of compounds. eg. Carbon dioxide, water, carbon monoxide, sodium chloride.

The elements and compounds can combine physically to create mixtures. Ex. cookies, salt water

How can substances with new properties be created?

By combing substances either chemically to form new compounds or physically to create new mixtures.

Both mixtures and compounds have different properties than the substances that they are made up of.

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Categories of MatterCategories of Matter

• So matter can be divided into two categories: (pure) substances and mixtures.

A substance is matter that is made up of the same sub-microscopic particles, such as atoms or molecules.

If a substance is made up of one kind of atom, then it is classified as an element.

– E.g. helium, sodium, carbon, oxygen, nitrogen, sulfur.

• If a substance is made up of particles that contain two or more kind of atoms bonded together (molecules or ion units), it is classified as a compound.

– E.g. water, carbon monoxide, ammonia, sodium chloride, carbon dioxide, copper sulfate

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Categories of Matter: MixtureCategories of Matter: Mixture

• A mixture on the other hand is matter that is made up of two more kinds of particles or substances put together physically.

A mixture retains the properties of the elements and/or compound it is made of.

– For example sea water is a mixture and it retains the saltiness of salt and fluidity of water.

– Vinegar is a mixture of acetic acid and water.

– Salad dressing is a mixture of a whole variety of spices, oil, and water with the texture and taste of the components.

– Air is a mixture of different gases (nitrogen, oxygen, argon and a few others).

– Alloys are mixtures of two or more metals. Steel is an alloy of iron, chromium and nickel; bronze: copper & tin.

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MixturesMixtures

• Mixture can further be divided into homogeneous and heterogeneous.

Homogeneous mixtures are those that do not have visibly different parts.

– In other words, homogeneous mixtures will be uniform, in appearance, and other physical properties such as taste, melting point, boiling point, density etc.

– Sea water, vinegar, air, alloys, tea and coffee for instance are examples.

– Different parts of a cup of tea do not look different from each other, they won’t taste different either and nor will they boil at different temperature.

• Heterogeneous mixtures are those that have visibly different parts.

– These mixtures you can distinguish the components of by just looking at it.

– What that means is that it is non-uniform in appearance and other physical properties such as taste, melting point, boiling point, density etc.

– Italian salad dressing for instance is heterogeneous—you can see the herbs, oil and vinegar/water components etc. and will also be able to taste the difference.

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Two variety of homogeneous mixtureTwo variety of homogeneous mixture

• Solution: A homogeneous mixture of two or more substances.

A solution can be solid, liquid or gas.

– Examples of solutions are air, sea water, pond and river water, alcohol (ethanol and water), tea, coffee, alloys such as steel (iron and carbon), brass (zinc and copper), and bronze (tin and copper).

• Colloids are a mixture that are kind of in between homogeneous and heterogeneous solutions.

Like solutions, colloids can be solids, liquids, or gases.

– Examples include egg white (both solids), gelatin desserts (both solids), smoke (both gaseous), aerosol sprays (both gaseous), oil and vinegar (both liquid), marshmellow (solid and gas), cotton candy (solid and gas). polystyrene cups (colloid of air and polystyrene).

• The difference between the two is that you can generally see the boundary between the components of colloids.

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Practice QuestionsPractice Questions

• 1. Choose from the list the most suitable method for each of the following separations. [4]

chromatography dissolving

distillation evaporation

filtration fractional distillation

(a) To separate the mixture of liquids in crude oil.

(b) To obtain some solid salt from a solution of salt in water.

(c) To separate a mixture of different colored inks.

(d) To obtain a sample of pure water from some tap water.

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Practice QuestionsPractice Questions

• 2. Distillation has been used in some parts of the world to obtain drinking water from sea water.

• The diagram shows a small scale distillation apparatus that could be used to demonstrate this process in a school laboratory. (a) Explain, as fully as you

can, how the apparatus makes drinking water from salt water. You may use the letters A, B, C and D to help with your answer. [4]

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Practice QuestionsPractice Questions

(b) Why is this method of making drinking water very expensive? [1]

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Practice QuestionsPractice Questions

• 3. There are millions of different substances that make up our world. All these substances are made from chemical elements.

(a) About how many different elements have been discovered?

The Periodic table may help you to answer this question. [1]

(b) What is an element? [1]

(c) Many substances are compounds. What is a compound? [2]

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Practice QuestionsPractice Questions

• 4. (a) The list below gives six substances.

Aluminum beer copper milk pure water sodium chloride

Put each substance in the correct column of the table. [3]

MixturesCompoundsElements

(b) Elements can be divided into two groups, metals and non-metals. The list below gives some properties of elements.

• brittle

• can be hammered into shape

• Dull

• good conductors of electricity

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Practice QuestionsPractice Questions

• poor conductors of electricity

• shiny

Put each property into the correct column. [3]

Properties of Non-metalsProperties of Metals

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Practice Questions: Multiple ChoicePractice Questions: Multiple Choice

• 1. In the following list, only __________ is not an example of matter.

A) planets B) light C) dust D) elemental phosphorus E) table salt

• 2. What is the physical state in which matter has no specific shape but does have a specific volume?

A) gas B) solid C) liquid D) salts E) ice

• 3. Solids have a __________ shape and are not appreciably __________.

A) definite, compressible B) definite, incompressible

C) indefinite, compressible D) indefinite, incompressible

E) sharp, convertible

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Practice Questions: Multiple ChoicePractice Questions: Multiple Choice

• 4. The law of constant composition applies to __________.

A) solutions B) heterogeneous mixtures C) compounds

D) homogeneous mixtures E) solids

• 5. A combination of sand, salt, and water is an example of a __________.

A) homogeneous mixture B) heterogeneous mixture

C) compound D) pure substance E) solid

• 6. Consider a mixture consisting of sand in salt water. This mixture could be separated into its three components (sand, salt, and water) by first __________ the mixture and then __________ the remaining mixture.

A) distilling, distilling B) distilling, filtering

C) filtering, distilling D) filtering, filtering E) evaporating, grinding

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Practice Questions: Multiple ChoicePractice Questions: Multiple Choice

• 7. Which one of the following is a pure substance?

A) concrete B) wood C) salt water D) elemental copper E) milk

• 8. Which one of the following is often easily separated into its components by simple techniques such as filtering or decanting?

A) heterogeneous mixture B) compounds

C) homogeneous mixture D) elements E) solutions

• 9. For which of the following can the composition vary?

A) pure substance

B) element

C) both homogeneous and heterogeneous mixtures

D) homogeneous mixture

E) heterogeneous mixture

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Practice Questions: Multiple ChoicePractice Questions: Multiple Choice

• 10. If matter is uniform throughout, cannot be separated into other substances by physical processes, but can be decomposed into other substances by chemical processes, it is __________.

A) a heterogeneous mixture B) an element

C) a homogeneous mixture D) a compound

E) a mixture of elements

• 11. If matter is uniform throughout, cannot be separated into other substances by physical processes, and cannot be decomposed into other substances by chemical processes, it is __________.

A) an element B) a compound

C) a homogeneous mixture D) a heterogeneous mixture

E) a mixture of compounds

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Practice Questions: Multiple ChoicePractice Questions: Multiple Choice

• 12. If matter is uniform throughout and cannot be separated into other substances by physical means, it is __________.

A) a compound B) either an element or a compound

C) a homogeneous mixture D) a heterogeneous mixture

E) an element

• 13. An element cannot __________.

A) be part of a heterogeneous mixture

B) be part of a homogeneous mixture

C) be separated into other substances by chemical means

D) interact with other elements to form compounds

E) be a pure substance

• 14. Homogeneous mixtures are also known as __________.

A) solids B) compounds C) elements D) substances E) solutions

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Practice Questions: Multiple ChoicePractice Questions: Multiple Choice

• 15. Which one of the following is not a physical property of water?

A) It boils at 100°C at 1 atm pressure.

B) It freezes at 0°C at 1 atm pressure.

C) It is clear and colorless.

D) Water exists in solid, liquid and gaseous forms.

E) It reacts rapidly with potassium metal to form potassium hydroxide.