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© Donald William Reid 2007
CONTENTS
Chlorine gas as a Weapon
Chemical Terrorism Concerns
Homeland Security Authorities Fear Chemical Terrorism in U.S.
Department of Homeland Security National Planning Scenarios
John Negroponte Statement
A Report by the Center for American Progress
Annual FBI Threat Assessment
Lt. Gen. Michael D. Maples
Chlorine Thefts
Tallahassee.com Article
USA TODAY Article
Chlorine Attacks
'Chlorine bomb' hits Iraq village
Deadly Iraq bomb releases chlorine gas
350 poisoned in Iraq chlorine bomb attacks
27 Dead in Iraq Chlorine Bomb
Iraqi Police Foil Chlorine 'Dirty Bomb' Attack in Ramadi
© Donald William Reid 2007
CONTENTS Cont.
Exposure to Chlorine
What chlorine is
Where chlorine is found and how it is used
How people can be exposed to chlorine
How chlorine works
Immediate signs and symptoms of chlorine exposure
What the long-term health effects are
How people can protect themselves, and what they should do if they are exposed to chlorine
How chlorine exposure is treated
How people can get more information about chlorine
Chlorine Suppliers
Resources
© Donald William Reid 2007
"Chlorine gas attacks the eyes and lungs within seconds, causing
difficulty in breathing and skin irritation in low-level exposure. Inhaled
at extremely high levels, it dissolves in the lungs to form hydrochloric
acid that burns lung tissue, essentially drowning a person as liquid
floods the lungs. The chemical has been used a number of times recently in
insurgent attacks in Iraq. Despite fears over the new tactic, some experts
note the insurgents are not yet expert at it, meaning they may be causing
widespread fear but not mass casualties. Chlorine gas causes death by
inhalation but experts say the heat from an explosion can render the gas
nontoxic.
A look at chlorine gas as a weapon
© Donald William Reid 2007
Chlorine is easily accessible. It is used for water purification
plants, bleaches and disinfectants and obtaining large quantities may not
be difficult. Chemical poisons killed tens of thousands of soldiers in
World War I. Their use caused so much international revulsion that the
issue sparked the Geneva Protocol of 1925, which banned the use of
chemical weapons. In general, chlorine is inefficient as a weapon - it
produces a visible greenish cloud and a strong odor, making it easy to
detect. Because it is water-soluble, simply covering the mouth and nose
with a damp cloth can reduce the effect of the gas.„
(Seattle Post Intelligencer; 06Apr07; AP)
© Donald William Reid 2007
Homeland Security Authorities Fear Chemical Terrorism in U.S.
In recent months, federal and state homeland security officials have
become increasingly concerned that terrorists and other groups might
attempt to imitate the insurgents in Iraq and employ chlorine-bombs and
other chemical weapons within the United States. Even before insurgents in
Iraq began detonating trucks carrying bombs combining conventional
explosive with industrial chlorine, U.S. government and0con-government
experts had identified the United States as potentially vulnerable to
terrorist attacks against chemical plants or rail tankers transporting
toxic chemicals such as chlorine.
At the local level, many communities are seeking to reduce their use of chlorine
and instead employ safer chemicals for disinfecting water, manufacturing products,
and other purposes. Although these alternatives are generally more expensive than
chlorine, the attacks in Iraq have appropriately persuaded many localities
of the imperative of reducing U.S. vulnerability to chemical terrorism." (World Politics Watch; 09May07; Richard Weitz)
© Donald William Reid 2007
In their "National Planning Scenarios"
(pdf file), analysts at the Department of
Homeland Security (DHS) identified a dozen
possible homeland security incidents the
department views as most plausible or
devastating. One scenario involved the
hypothetical detonation of a large chlorine
storage tank that killed 17,500 people and
injured more than 100,000.
Department of Homeland Security
National Planning Scenarios
© Donald William Reid 2007
In late February 2007,
then-Director of National
Intelligence John
Negroponte stated (pdf
file) that U.S. "intelligence
reporting indicates that
nearly 40 terrorist
organizations,
insurgencies or cults have
used, possessed, or
expressed an interest in
chemical, biological,
radiological, or nuclear
agents or weapons."
John Negroponte Statement
© Donald William Reid 2007
The most likely target for terrorists seeking
to release large quantities of chlorine are
the railcars that traverse the United States
carrying enormous 90-ton tanks of chlorine.
U.S. railroads annually carry 1.7 million
shipments of hazardous materials, of which
100,000 are toxic chemicals prone to become
airborne in an accident. About 80 percent of
these latter shipments consist of chlorine.
Thirty-seven water utilities in the country
still receive chlorine gas by rail, generating
45,000 shipments annually. A March 2007
report by the Center for American Progress
(pdf file) cited the Iraqi insurgent attacks to
justify its assessment that "railcars of
chlorine gas represent a distinct national
security vulnerability." (World Politics Watch; 09May07; Richard Weitz)
A Report by the Center for American Progress
© Donald William Reid 2007
In the annual FBI threat assessment (pdf
file) delivered to the Senate Select
Committee on Intelligence in January
2007, Director Robert Mueller stated that
the acquisition of WMD by terrorist
groups "continues to be a growing
concern." In Mueller's assessment, while
terrorists may not currently possess the
capabilities to produce the complex
biological and chemical agents necessary
to carry out a large-scale attack, "their
capability will improve as they pursue
enhancing their scientific knowledge base,
including recruiting scientists to assist
them."
Annual FBI Threat Assessment
© Donald William Reid 2007
according to Lt. Gen. Michael D.
Maples (pdf file), the U.S. intelligence
community believes that al-Qaida and
other terrorist groups are pursuing the
capability to employ biological and
chemical agents such as ricin,
botulinum toxin, cyanide, anthrax,
sarin, and mustard gases. Suicide
terrorists may prove especially effective
at using CW. Since they are prepared to
die in the attack, they do not wear CW
defensive gear or take other measures
that might alert authorities to the threat.
Lt. Gen. Michael D. Maples
© Donald William Reid 2007
Originally published April 6, 2007
Chlorine taken from pool-supply company
Who would steal 1,600 gallons of chlorine? It's a
question the people at Leslie's Swimming Pool Supplies
are asking after discovering the theft last Friday.
Staffers at the North Monroe Street pool-supply store
"went to fill up a bulk customer (order) and it was
empty, the lock was missing on the inside," assistant
manager John Danner said Thursday of the 2,000-
gallon tank.
Whomever cleaned out Leslie's absconded with an
estimated $3,000 in liquid.
It would take at least an hour to drain 1,600 gallons.
Sodium hypochlorite is used for pressure cleaning and
pool purification. It takes between two and five gallons
to purify a residential pool.
"The cops told us it was pretty much not traceable,"
Danner said. "They did take a bunch of stuff for
fingerprinting. They told us we're not going to hear
from them unless we find something out."
Tallahassee.com Article
© Donald William Reid 2007
Chlorine bombs pose new terror risk. The Department of
Homeland Security (DHS) is warning U.S. chemical plants
and bomb squads to guard against a new form of
terrorism: chlorine truck bombs. The Chlorine Institute, a
trade group that represents more than 200 companies that
make and distribute chlorine, recently alerted the FBI to
several thefts or attempted thefts of 150-pound chlorine
tanks from water treatment plants in California. "This is
now being used as a tactic against us in another part of the
world," says Robert Stephan, DHS' infrastructure
protection chief. "We've got to be prepared for it." The
150-pound chlorine tanks typically used in the bombs are
"ubiquitous across the world," Stephan says. DHS officials
are working with intelligence and Department of Defense
officials to try to prevent similar acts in the U.S., he says.
New federal regulations on chemical plant security are set
to take effect this summer. DHS teams will begin
inspecting hundreds of chemical plants that make and
store chlorine and other potentially deadly chemicals.
April 24, USA TODAY
© Donald William Reid 2007
'Chlorine bomb' hits Iraq village
Wednesday, 16 May 2007
At least 32 people have been killed and
50 injured in a suspected chlorine
bomb in Iraq's Diyala province,
police say.
The attack happened in an open-air
market in the village of Abu Sayda
at about 2000 (1600 GMT) on
Tuesday.
A police spokesman in the provincial
capital Baquba said doctors at a
local hospital believed the nature of
victims' burns suggested poison
gas.
© Donald William Reid 2007
Deadly Iraq bomb releases chlorine gas
Apr 6, 2007
RAMADI, Iraq (Reuters) - A truck bomb exploded in the volatile
Iraqi city of Ramadi on Friday, killing at least 15 people and releasing
chlorine gas into the air, police and security sources said.
Police Colonel Tareq Dulaimi from Ramadi said the bomb, which
targeted a police patrol, wounded at least 30 people. He said several
people were also choking from the gas.
There has been a spate of chlorine truck bomb attacks in recent
months, mainly in western Anbar province. Ramadi is the capital of
Anbar, stronghold of the Sunni Arab insurgency and a haven for al
Qaeda.
© Donald William Reid 2007
U.S. commanders and Iraqi police have
blamed al Qaeda militants for several of the
chlorine attacks.
Chlorine gas was widely used in World War
One but its use in insurgent attacks in Iraq
has particular resonance there. Saddam
Hussein attacked Kurdish areas with
chemical weapons in the 1980s during the
Iran-Iraq war.
Reuters News Service.
© Donald William Reid 2007
At least 350 Iraqi civilians needed hospital treatment after insurgents detonated three
trucks filled with toxic chlorine gas, killing two policemen, the US military said
yesterday.
Friday‟s gas attack was the seventh this year in which insurgents have used chemical
gas bombs on civilians and security forces, in what appears to be a new tactic for Al
Qaeda militants.
The attacks were carried out between 4.11pm (1311 GMT) and 7.13pm on Friday, two
of them just south of the town of Fallujah and one northeast of the nearby city of
Ramadi, both hotbeds of Al Qaeda militants in the Anbar province.
350 poisoned in Iraq chlorine bomb attacks Published: Sunday, 18 March, 2007
© Donald William Reid 2007
“Approximately 350 Iraqi civilians and six
coalition force members were treated for
chlorine gas exposure,” said Lieutenant Roger
Hollenbeck of the US-led Multinational
Division West, based in Ramadi.
Iraqi state television reported that at least six
people were killed in the blasts, but the US
military could initially only confirm the deaths
of two Iraqi policemen in the second
explosion, in Ameriyah, outside Fallujah.
“Coalition forces confirmed that the Ameriyah
citizens exposed to the chlorine were treated
locally for symptoms ranging from minor skin
and lung irritation to vomiting,” Hollenbeck
said in a statement.
In each attack a suicide bomber detonated a
vehicle packed with explosives and gas
canisters near police and civilian targets.
© Donald William Reid 2007
Police in the Anbar provincial capital said that a suicide bomber driving a truck
loaded with TNT and toxic chlorine gas crashed into a police checkpoint in
western Ramadi on Friday, killing at least 27 people ;two of them policemen
and wounding dozens. The Basra police commander said the type of roadside
bomb used in an attack that killed four British soldiers on Thursday had not
been seen in the region previously. Two more of the bombs were discovered
planted along routes heavily travelled by U.S. and British diplomats in Basra. It
was the sixth chlorine bomb detonated in the Anbar province in the last two
months and the most lethal, though it is unclear if the victims were killed by
the explosion or the chlorine.
27 Dead in Iraq Chlorine Bomb
© Donald William Reid 2007
"The U.S. military says Iraqi authorities have foiled a suicide chemical
bomb attack in the western city of Ramadi. A statement issued Sunday says
Iraqi police detained a suicide bomber Friday, before he could detonate
two tons of explosives aboard his truck that was also loaded with nearly
20,000 liters of chlorine. U.S. officials say the truck was stopped near
a police station about 150 meters from a water treatment plant in the
predominantly Sunni city." (Voice of America News; 25Mar07)
Iraqi Police Foil Chlorine 'Dirty Bomb' Attack in Ramadi
© Donald William Reid 2007
Chlorine is an element used in industry and found in some household products.
Chlorine is sometimes in the form of a poisonous gas. Chlorine gas can be
pressurized and cooled to change it into a liquid so that it can be shipped and
stored. When liquid chlorine is released, it quickly turns into a gas that stays close
to the ground and spreads rapidly.
Chlorine gas can be recognized by its pungent, irritating odor, which is like the
odor of bleach. The strong smell may provide an adequate warning to people that
they have been exposed.
Chlorine gas appears to be yellow-green in color.
Chlorine itself is not flammable, but it can react explosively or form explosive
compounds with other chemicals such as turpentine and ammonia.
What chlorine is
© Donald William Reid 2007
Chlorine was used during World War I as a choking (pulmonary)
agent.
Chlorine is one of the most commonly manufactured chemicals in the
United States. Its most important use is as a bleach in the manufacture
of paper and cloth, but it is also used to make pesticides (insect
killers), rubber, and solvents.
Chlorine is used in drinking water and swimming pool water to kill
harmful bacteria. It is also as used as part of the sanitation process for
industrial waste and sewage.
Household chlorine bleach can release chlorine gas if it is mixed with
other cleaning agents.
Where chlorine is found and how it is used
© Donald William Reid 2007
People‟s risk for exposure depends on how close they are to the place
where the chlorine was released.
If chlorine gas is released into the air, people may be exposed
through skin contact or eye contact. They may also be exposed by
breathing air that contains chlorine.
If chlorine liquid is released into water, people may be exposed by
touching or drinking water that contains chlorine.
If chlorine liquid comes into contact with food, people may be
exposed by eating the contaminated food.
Chlorine gas is heavier than air, so it would settle in low-lying areas
How people can be exposed to chlorine
© Donald William Reid 2007
The extent of poisoning caused by chlorine depends on the amount of
chlorine a person is exposed to, how the person was exposed, and the length
of time of the exposure.
When chlorine gas comes into contact with moist tissues such as the eyes,
throat, and lungs, an acid is produced that can damage these tissues.
How chlorine works
© Donald William Reid 2007
During or immediately after exposure to dangerous concentrations of chlorine, the following
signs and symptoms may develop:
•Coughing
•Chest tightness
•Burning sensation in the nose, throat, and eyes
•Watery eyes
•Blurred vision
•Nausea and vomiting
•Burning pain, redness, and blisters on the skin if exposed to gas, skin injury similar to
frostbite if exposed to liquid chlorine
•Difficulty breathing or shortness of breath (may appear immediately if high
concentrations of chlorine gas are inhaled, or may be delayed if low concentrations of
chlorine gas are inhaled)
•Fluid in the lungs (pulmonary edema) within 2 to 4 hours
Showing these signs or symptoms does not necessarily mean that a person has been exposed
to chlorine.
Immediate signs and symptoms of chlorine exposure
© Donald William Reid 2007
Long-term complications from chlorine exposure are not found in people
who survive a sudden exposure unless they suffer complications such as
pneumonia during therapy. Chronic bronchitis may develop in people
who develop pneumonia during therapy
What the long-term health effects are
© Donald William Reid 2007
Leave the area where the chlorine was released and get to fresh air. Quickly moving
to an area where fresh air is available is highly effective in reducing exposure to
chlorine.
If the chlorine release was outdoors, move away from the area where the
chlorine was released. Go to the highest ground possible, because chlorine is
heavier than air and will sink to low-lying areas.
If the chlorine release was indoors, get out of the building.
If you think you may have been exposed, remove your clothing, rapidly wash your
entire body with soap and water, and get medical care as quickly as possible.
How people can protect themselves, and what they
should do if they are exposed to chlorine
© Donald William Reid 2007
Removing and disposing of clothing: Quickly take off clothing that has liquid chlorine on it. Any
clothing that has to be pulled over the head should be cut
off the body instead of pulled over the head. If possible,
seal the clothing in a plastic bag. Then seal the first plastic
bag in a second plastic bag. Removing and sealing the
clothing in this way will help protect you and other people
from any chemicals that might be on your clothes.
If you placed your clothes in plastic bags, inform either the
local or state health department or emergency personnel
upon their arrival. Do not handle the plastic bags.
If you are helping other people remove their clothing, try to
avoid touching any contaminated areas, and remove the
clothing as quickly as possible.
© Donald William Reid 2007
Washing the body: As quickly as possible, wash your entire body with large amounts of
soap and water. Washing with soap and water will help protect people
from any chemicals on their bodies.
If your eyes are burning or your vision is blurred, rinse your eyes with
plain water for 10 to 15 minutes. If you wear contacts, remove them
before rinsing your eyes, and place them in the bags with the
contaminated clothing. Do not put the contacts back in your eyes. You
should dispose of them even if you do not wear disposable contacts. If
you wear eyeglasses, wash them with soap and water. You can put the
eyeglasses back on after you wash them.
If you have ingested (swallowed) chlorine, do not induce vomiting or
drink fluids.
Seek medical attention right away. Dial 911 and explain what has
happened
© Donald William Reid 2007
No antidote exists for chlorine exposure. Treatment
consists of removing the chlorine from the body as soon
as possible and providing supportive medical care in a
hospital setting.
How chlorine exposure is treated
© Donald William Reid 2007
People can contact one of the following:
Regional poison control center: 1-800-222-1222
Centers for Disease Control and Prevention
Public Response Hotline (CDC)
800-CDC-INFO
888-232-6348 (TTY)
E-mail inquiries: [email protected]
Centers for Disease Control and Prevention
(CDC), National Institute for Occupational
Safety and Health (NIOSH), Pocket Guide to
Chemical Hazards
How people can get more information about chlorine