Polyamide extrusion

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Extrusion guidelines

Polyamide extrusionProcessing guidelinesTed Brink

Page nr.some simple guidelinesfor nylon extrusion

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Moisture POLYAMIDESarehygroscopic

Page nr.How to deal with moisturereliable resin manufacturers supply nylon dry and ready-to-useavoid moisture absorptionuse packaging size according to consumptionshield hopper from atmospheremaximum allowable moisture content 0.1 %

Page nr.Too high moisturetoo high moisture content results in:bubbles/foaming of the meltholes in the filmbubble collapseshydrolytic breakdown

Page nr.Screws for polyamide extrusionGeneral Purpose screws can be used, provided:the barrel is not grooved (unless .....)the heating capacity is sufficientthe compression ratio is < 4.0the L/D ratio is > 24barrier screws suitable

Page nr.Mixing or dispersing elementsmixing sections on standard 3-zone screws may be neededdispersing antiblock agentpigmentsnot needed for standard additives mixing elements:pineapple (distributive mixing)pin(distributive mixing)Maddock (dispersive mixing)

Page nr.Screen packFunction:build-up pressurefiltration

Page nr.Extruder output PA6 extrusionsingle screw3-zoneTcil 250 C

Page nr.Thermal properties of PA6

processing range

crystal growth

melting point

glass transition temperaturetemperature [C]

Page nr.Communicate with the machinelisten to what the machine is telling youwatch energy demand of band heatersshows where energy is neededshows where no energy is neededavoid adiabatic extrusionthe machine is in control, not you!Tpol will show large variations

Page nr.Temperature settingstoo low settings may result in too high polymer temperaturenylons with higher crystallinity require different approach

Page nr.Melt stabilitypolyamide is a condensation polymerconsequence for extrusion:when dry: polymerization occurswhen wet: depolymerization occursreactivity depends on:moisture contentresidence timetemperatureend groups

Page nr.MiscelleneousBlown film:BUR 1:1 1:3lay flat when film is stil warm to prevent wrinklesGeneral:die gap 1 1.2 mmCast film:Chill roll temperature:20 40 C for optimum thermoforming behavior80 130 C for optimum dimensional stabilitychill roll as close to the die to avoid neck-in

Page nr.Film post treatmentCorona treatmentPlasma treatmentFlame surface treatmentPurpose of these treatments:increase surface energy so that inks wet-out improve adhesion during laminationHowever, polyamide has intrinsically good printing and lamination performanceand thus no real need for Corona treatment

untreated filmtreated film

Page nr.Polyamide film propertiesfilms are (near to) isotropicfilms are transparenthigh puncture resistance

Page nr.Influence of moisture on film propertieswhen dry:very high oxygen barrierhigh moduluswhen conditionedhigh oxygen barrierincreased flexibilitypostcrystallization possibledimensional fluctuations

Page nr.Coextrusionpolyamide mostly used in multilayer structurespolyamide function:mechanical protectionbarrier propertiestie resin required for adhesion to nonpolar polymers like PE and PPcoectruded polymers should rheologically match

Page nr.ApplicationsFood packagingcheesemeat fish

Non foodagricultural filmsmedical filmsrelease films for smc

Page nr.Contact

Ted BrinkEmail: [email protected]: www.extrusionist.comTel.: +31 651109899More information

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