Multi-Layer Tubing Solutions for Fuel Lines

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This presentation addresses innovative solutions for creating multi-layer tubing systems for automotive fuel lines. It also describes the construction and performance of the SUNBESTA-ZV 3-layer tube system. For more information, go to www.agcchem.com or call 800-424-7833. You can also follow AGC on Twitter @AGCChem_Amer. Thanks for viewing!

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NEWLY INNOVATIVE MLT SOLUTIONS: SUNBESTA-ZV Double Barrier Material Created by:

AGC CHEMICALS AMERICAS, INC.

Requirements for Fuel Lines

�  Mechanical properties (Burst pressure, cold impact resistance, tensile elongation, etc.)

�  Long term durability (Lifetime) •  15 years, 150,000 miles

�  Fuel and chemical resistance •  CE5, CE10, CM15, CE22, CM30, CE85, E100 •  Bio fuels (Bio alcohol, Bio diesel; RME, SME, etc.) •  Auto oxidized fuels (aggressive fuels with high peroxide number)

�  Low permeation •  Euro4, Euro5, Euro6 •  LEV II, PZEV, LEV III

�  Conductive (USA , Japan)

�  Processability, thermoforming (Straight, corrugate)

�  Cost reduction

Trend of MLT System

•  Wide variety of fuels are being used •  Lower emission requirements •  Cost efficiency •  Oligomer free and conductive material for inner layer •  Wide range of MLT systems for fuel lines:

•  PA11/PA12 and PBT, PBN, PVDF, ETFE, EFEP, EVOH, PPS MLT systems

•  Layer construction of MLT has grown more complicated

Advanced Multi-Layer Tube System

AGC, KURARAY and UBE jointly developed 3-layer tube system in order to offer: •  High level of low permeation system against variety of fuels •  Low oligomer wash out system •  Reasonable cost performance system Outer layer •  Modified-PA12 with excellent cold impact resistance and

long term heat resistance Middle layer •  Modified-PA9T with excellent hydro-carbon barrier properties and

good chemical and hydrolysis resistance Inner layer •  Modified-ETFE with excellent alcohol barrier properties •  Fuel, chemical and hydrolysis resistance (including aggressive oxidized fuels and

high alcohol-based fuel) •  Adhesive properties

SUNBESTA-ZV Tube Construction

OD/ID = 8.0 mm/6.0mm Thickness: Inner/Middle/Outer = 150/150/700 µm

�  Standard Material: •  Outer layer: PA12 UBESTA 3030JI series •  Middle layer: PA9T Genestar N1001D-U series •  Inner layer: ETFE Fluon AH series

Fuel Permeation Rate

Barrier layer thickness 300 µm 250 µm 250 µm

Temp: 60 oC Method : Weight Loss

Combination Benefits of PA9T and ETFE

Temp: 60 oC Method: Weight Loss

Permeation Rate in Comparison with Various MLTs

SHED Method (Fuel: CARB DBL Indolene+ETOH10%) 

Tube dimensions = OD/ID: 8.0 mm/6.0 mm Length: 1m

Typical Tube Properties

*Tensile Speed: 50mm/min. Distance between Marks/Grips: 50mm/100mm

Burst Properties: SAE J2260

Cold Impact Properties: SAE J2260

Layer Adhesion: SAE J2260

Electrical Resistance: SAE J2260

Layer Adhesion Performance

Peeling strength measured after filling with CE10 at 60 oC Test specimens prepared by spiral strip, peeling speed: 50mm/min

Adhesion between PA12 layer and PA9T layer

Adhesion between PA12 layer and Mod. PO layer

Typical Processing Conditions: Conductive Straight Tube

Line speed: 20 m/min

UBESTA 3030JI26L Properties

Genestar N1001D – U83/02 Properties

Fluon AH2000 and AH3000L Properties

For Your Consideration

* These contents are prepared under the actual information and they can be revised at anytime.

* The described numerical values are average values obtained by measurement under prescribed conditions; not guaranteed values.

* Asahi Glass, KURARAY and UBE don’t guarantee the quality and safety of your company’s finished product even if Asahi Glass, KURARAY and UBE’s materials and the data described here or data prepared by other companies are used to manufacture the finished product.

* Determination of the suitability of the finished product shall be the responsibility of your company.

* Specific application may be Subject to standards, regulations and commercial property right, fully researched by your company.

* Ask for “Product Safety Data Sheet” before using Asahi Glass, KURARAY and UBE’s products.

AGC Chemicals Americas, Inc.

   For  More  Informa,on  

www.agcchem.com    

800-­‐424-­‐7833    

Intelligent Resins Custom Compounds Smart Chemistry Solutions

AGC CHEMICALS AMERICAS, INC.

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