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CHAIN OF CUSTODY CUEt,;T: Emerge Associates POSTAL ADDRESS: Suite 4, 26 Railway Road, Subiaco WA 6008
~~1}~fQ., •01,,of~iE·d Scic11cr. & Des1q11
PROJ::CT MANAGER: Simon Gregg CONTACT PHONE: 9380 4988
PROJECT ID.: EP15-050(05) PROJECT NAME: SAMR Monitoring - Davis Road
SAMPt.ER(S): Mitchell Ritikis SAMPLERS PHONE: 0449198 721
QUOTE NO.: EP/009116 ORDER NO.:
SAMPI F nFTAII S
Comments/special handli,ig:storage or disposal
Please note short holding time for some analysis.
: ANALYSIS REQUIRED
·1~2 ro o
JE I I "' 2 .,,, ~Jgin I CONTAINER 1NFORMATION ...,, """ ~•• .,.,_..., C: •n Cl)
I ~~i Lab ID Sample ID Matrix
1 P1 Water
"2. P2 Water --------i M1 Water
Date Type & Preser,ative
22/03117 2SP,1VS, 1P,2AP, 1P
21/03117 2SP, 1VS, 1P, 2AP, 1P
22/03117 2SP,1VS, 1P,2AP, 1P
To:al No.
6
6
6
- c:::, ·- a.. z:a:w
X
X
X
Additional information (likely contaminants, dilutions or specific QC analysis)
Environmental Division Perth
Work Order Reference
EP1702765
11111 T elep-!lOne : + 61-8-920H 7656
RELINQUISHED BY: RECEIVED BY CoC emailed to ALS?
/~NAME: Mitchell Ritikis DATE: 23/03/2017 NAME, \~c:_10::>, _Wf?l\r:Ef": DATE: d-,aj0'6 IS] Yes O No ,1 OF: Emerge, Associates TIME: 11:45 OF: f\ lS TIME: \b'.SO NAME: DATE: NAME: DATE: Water Cartainer Codes: P = Unpreserved Plastic: N = Nitric Preserved Plastic; ORC = Nitric Preserved ORC; SH= Sodf.Um Hydroxide/Cd Preserved; S = Sodium Hydroxide Preserved Plastic; AG = Amber Glass Unpreserved; AP= Airfaeight Unpreserved Plastic; V = VOA Vial HCI Preserved; VB= VOA Vial Sodium Bisulphate Preserved; VS= VCA Vial Sulfuric Preserved; AV =Airfreight Unpreserved Vial; SG = Sulfuric Preserved Amber Glass; H = HCI 19reserved Plastic; HS= HCI Preserved Speciation botue; SP= Sulfuric Preserved Plastic; F = Formaldehyde !Dreserved Glass; Z = Zinc Acetate Preserved Bottle; E = EDTA Preserved Bottles; ST= Steriie Bottle; LI = Lugols Iodine Preserved Bottles; STT = Sterile Sodium Thiosulfal!e Preserved Bottles. Soil Container Codes: J = Jar_;_~_SS = Plastic Bag for A_cid Sulfate_Soils; B = Un.e_reser'l'69 3ag;
Environmental
SAMPLE RECEIPT NOTIFICATION (SRN)Work Order : EP1702765
:: LaboratoryClient Environmental Division PerthEMERGE ASSOCIATES
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA
6008
10 Hod Way Malaga WA Australia 6090
:: E-mailE-mail simon.gregg@emergeassociates.co
m.au
LUKE.JONES@alsglobal.com
:: TelephoneTelephone +61 08 9380 4988 08 9209 7631
:: FacsimileFacsimile +61 08 9380 9636 +61-8-9209 7600
::Project EP15-050(05) SAMR Monitoring -
Davis Road
Page 1 of 3
:Order number ---- :Quote number EP2015EMEASS0045 (EP/683/15)
:C-O-C number ---- :QC Level NEPM 2013 B3 & ALS QC Standard
Site : ----
Sampler : MITCHELL RITIKIS
DatesDate Samples Received : Issue Date : 24-Mar-201723-Mar-2017 16:50
Scheduled Reporting Date: 30-Mar-2017:Client Requested Due
Date
30-Mar-2017
Delivery DetailsMode of Delivery : :Carrier Not intact.Security Seal
No. of coolers/boxes : :3 Temperature 10.1 - Ice present
: : 3 / 3Receipt Detail No. of samples received / analysed
General Comments
This report contains the following information:l
- Sample Container(s)/Preservation Non-Compliances
- Summary of Sample(s) and Requested Analysis
- Proactive Holding Time Report
- Requested Deliverables
l Please see scanned COC for sample discrepencies: extra samples , samples not received etc.
l Please direct any queries related to sample condition / numbering / breakages to Sample Receipt (SamplesPerth@alsenviro.com)
l Analytical work for this work order will be conducted at ALS Environmental Perth.
l Please direct any turnaround / technical queries to the laboratory contact designated above.
l Sample Disposal - Aqueous (14 days), Solid (60 days) from date of completion of Work Order.
l COD analysis will be conducted by ALS Environmental, Sydney, NATA accreditation no. 825, Site
No. 10911.l pH analysis should be conducted within 6 hours of sampling.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
:Client EMERGE ASSOCIATES
Work Order : EP1702765 Amendment 02 of 3:Page
24-Mar-2017:Issue Date
Sample Container(s)/Preservation Non-Compliances
All comparisons are made against pretreatment/preservation AS, APHA, USEPA standards.
l No sample container / preservation non-compliance exists.
Summary of Sample(s) and Requested Analysis
Some items described below may be part of a laboratory
process necessary for the execution of client requested
tasks. Packages may contain additional analyses, such
as the determination of moisture content and preparation
tasks, that are included in the package.
If no sampling time is provided, the sampling time will
default 00:00 on the date of sampling. If no sampling date
is provided, the sampling date will be assumed by the
laboratory and displayed in brackets without a time
component
WA
TE
R -
ED
037-P
Alk
alin
ity a
s C
aC
O3 (
PC
T)
WA
TE
R -
ED
045G
Chlo
ride b
y D
iscr
ete
Analy
ser
WA
TE
R -
EG
020F
Dis
solv
ed M
eta
ls b
y IC
PM
S
WA
TE
R -
EP
026S
P
Chem
ical O
xygen D
em
and (
CO
D)
WA
TE
R -
NT
-01
Majo
r C
atio
ns
(Ca, M
g, N
a, K
)
WA
TE
R -
NT
-08
Tota
l Nitr
ogen +
NO
2 +
NO
3 +
NH
3 +
Tota
l P
WA
TE
R -
W-0
2
8 M
eta
ls
EP1702765-001 22-Mar-2017 00:00 P1 ü ü ü ü ü ü ü
EP1702765-002 21-Mar-2017 00:00 P2 ü ü ü ü ü ü ü
EP1702765-003 22-Mar-2017 00:00 M1 ü ü ü ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
WA
TE
R -
EA
01
5H
To
tal D
isso
lve
d S
olid
s -
Hig
h L
eve
l
WA
TE
R -
EG
02
0T
To
tal R
eco
vera
ble
Me
tals
by
ICP
MS
(in
clu
din
g
WA
TE
R -
EP
00
5
To
tal O
rga
nic
Ca
rbo
n (
TO
C)
EP1702765-001 22-Mar-2017 00:00 P1 ü ü ü
EP1702765-002 21-Mar-2017 00:00 P2 ü ü ü
EP1702765-003 22-Mar-2017 00:00 M1 ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
Proactive Holding Time Report
Sample(s) have been received within the recommended holding times for the requested analysis.
:Client EMERGE ASSOCIATES
Work Order : EP1702765 Amendment 03 of 3:Page
24-Mar-2017:Issue Date
Requested Deliverables
ACCOUNTS (INVOICES)
- A4 - AU Tax Invoice (INV) Email accounts@emergeassociates.com.
au
JEREMY PAYET
- *AU Certificate of Analysis - NATA (COA) Email jeremy.payet@emergeassociates.co
m.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email jeremy.payet@emergeassociates.co
m.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email jeremy.payet@emergeassociates.co
m.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email jeremy.payet@emergeassociates.co
m.au
- Chain of Custody (CoC) (COC) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - ENMRG (ENMRG) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - ESDAT (ESDAT) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - XTab (XTAB) Email jeremy.payet@emergeassociates.co
m.au
MITCHELL RITIKIS
- *AU Certificate of Analysis - NATA (COA) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email mitchell.ritikis@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email mitchell.ritikis@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - ENMRG (ENMRG) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email mitchell.ritikis@emergeassociates.c
om.au
SIMON GREGG
- *AU Certificate of Analysis - NATA (COA) Email simon.gregg@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email simon.gregg@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email simon.gregg@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email simon.gregg@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - ENMRG (ENMRG) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email simon.gregg@emergeassociates.c
om.au
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 4EP1702765
:: LaboratoryClient EMERGE ASSOCIATES Environmental Division Perth
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
10 Hod Way Malaga WA Australia 6090
:Telephone +61 08 9380 4988 :Telephone 08 9209 7631
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 23-Mar-2017 16:50
:Order number ---- Date Analysis Commenced : 24-Mar-2017
:C-O-C number ---- Issue Date : 30-Mar-2017 15:19
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EP/683/15
3:No. of samples received
3:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:
l General Comments
l Analytical Results
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with
Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Efua Wilson Metals Chemist Perth Inorganics, Malaga, WA
Indra Astuty Instrument Chemist Perth Inorganics, Malaga, WA
Jeremy Truong Laboratory Manager Perth Inorganics, Malaga, WA
Tyrone Cole Inorganics Preparation Supervisor Perth Inorganics, Malaga, WA
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with 1S0/IEC 17025 - Testing
2 of 4:Page
Work Order :
:Client
EP1702765
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When no sampling time is provided, the sampling time will default 00:00 on the date of sampling. If no sampling date is provided, the sampling date will be assumed by the laboratory and displayed in brackets without a
time component.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
^ = This result is computed from individual analyte detections at or above the level of reporting
ø = ALS is not NATA accredited for these tests.
~ = Indicates an estimated value.
Key :
COD conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.l
It is recognised that Chemical Oxygen Demand (EP026SP) is less than Total Organic Carbon (EP005) for various samples . However, the difference is within experimental variation of the methods.l
A
3 of 4:Page
Work Order :
:Client
EP1702765
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
--------M1P2P1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
--------22-Mar-2017 00:0021-Mar-2017 00:0022-Mar-2017 00:00Client sampling date / time
----------------EP1702765-003EP1702765-002EP1702765-001UnitLORCAS NumberCompound
Result Result Result ---- ----
EA015: Total Dissolved Solids dried at 180 ± 5 °C
749 341 1560 ---- ----mg/L10----Total Dissolved Solids @180°C
ED037P: Alkalinity by PC Titrator
<1Hydroxide Alkalinity as CaCO3 <1 <1 ---- ----mg/L1DMO-210-001
<1Carbonate Alkalinity as CaCO3 <1 <1 ---- ----mg/L13812-32-6
190Bicarbonate Alkalinity as CaCO3 21 <1 ---- ----mg/L171-52-3
190 21 <1 ---- ----mg/L1----Total Alkalinity as CaCO3
ED045G: Chloride by Discrete Analyser
292Chloride 201 664 ---- ----mg/L116887-00-6
ED093F: Dissolved Major Cations
59Calcium 14 13 ---- ----mg/L17440-70-2
21Magnesium 12 39 ---- ----mg/L17439-95-4
148Sodium 95 334 ---- ----mg/L17440-23-5
29Potassium 5 8 ---- ----mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS
0.01Aluminium 0.06 13.6 ---- ----mg/L0.017429-90-5
<0.001Arsenic <0.001 0.007 ---- ----mg/L0.0017440-38-2
<0.0001Cadmium <0.0001 <0.0001 ---- ----mg/L0.00017440-43-9
<0.001Chromium <0.001 <0.001 ---- ----mg/L0.0017440-47-3
0.001Copper 0.050 <0.001 ---- ----mg/L0.0017440-50-8
<0.001Nickel <0.001 <0.001 ---- ----mg/L0.0017440-02-0
<0.001Lead <0.001 0.002 ---- ----mg/L0.0017439-92-1
0.090Zinc 0.065 0.057 ---- ----mg/L0.0057440-66-6
0.131Manganese 0.034 0.106 ---- ----mg/L0.0017439-96-5
<0.01Selenium <0.01 0.04 ---- ----mg/L0.017782-49-2
EG020T: Total Metals by ICP-MS
12.4Iron 3.31 25.5 ---- ----mg/L0.057439-89-6
EG035F: Dissolved Mercury by FIMS
<0.0001Mercury <0.0001 <0.0001 ---- ----mg/L0.00017439-97-6
EK055G: Ammonia as N by Discrete Analyser
4.18Ammonia as N 0.08 4.15 ---- ----mg/L0.017664-41-7
EK057G: Nitrite as N by Discrete Analyser
0.04Nitrite as N <0.01 <0.01 ---- ----mg/L0.0114797-65-0
EK058G: Nitrate as N by Discrete Analyser
0.95Nitrate as N 0.01 <0.01 ---- ----mg/L0.0114797-55-8
A
---------------
4 of 4:Page
Work Order :
:Client
EP1702765
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
--------M1P2P1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
--------22-Mar-2017 00:0021-Mar-2017 00:0022-Mar-2017 00:00Client sampling date / time
----------------EP1702765-003EP1702765-002EP1702765-001UnitLORCAS NumberCompound
Result Result Result ---- ----
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
0.99 0.01 <0.01 ---- ----mg/L0.01----Nitrite + Nitrate as N
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser
4.4 0.1 4.7 ---- ----mg/L0.1----Total Kjeldahl Nitrogen as N
EK062G: Total Nitrogen as N (TKN + NOx) by Discrete Analyser
5.4^ 0.1 4.7 ---- ----mg/L0.1----Total Nitrogen as N
EK067G: Total Phosphorus as P by Discrete Analyser
0.08 <0.01 0.04 ---- ----mg/L0.01----Total Phosphorus as P
EP005: Total Organic Carbon (TOC)
18 10 <1 ---- ----mg/L1----Total Organic Carbon
EP026SP: Chemical Oxygen Demand (Spectrophotometric)
21 <10 76 ---- ----mg/L10----Chemical Oxygen Demand
A
False
5 5.00True
Environmental
QUALITY CONTROL REPORTWork Order : EP1702765 Page : 1 of 6
:: LaboratoryClient Environmental Division PerthEMERGE ASSOCIATES
:Contact MR SIMON GREGG :Contact Luke Jones
:Address SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
Address : 10 Hod Way Malaga WA Australia 6090
::Telephone +61 08 9380 4988 08 9209 7631:Telephone
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 23-Mar-2017
:Order number ---- Date Analysis Commenced : 24-Mar-2017
:C-O-C number ---- Issue Date : 30-Mar-2017
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EP/683/15
No. of samples received 3:
No. of samples analysed 3:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limits
l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits
l Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Efua Wilson Metals Chemist Perth Inorganics, Malaga, WA
Indra Astuty Instrument Chemist Perth Inorganics, Malaga, WA
Jeremy Truong Laboratory Manager Perth Inorganics, Malaga, WA
Tyrone Cole Inorganics Preparation Supervisor Perth Inorganics, Malaga, WA
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with 150/IEC 17025 - Testing
2 of 6:Page
Work Order :
:Client
EP1702765
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
RPD = Relative Percentage Difference
# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) Report
The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges
for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:
No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QC Lot: 812145)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 341 320 6.20 0% - 20%P2 EP1702765-002
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 2160 2470 13.6 0% - 20%Anonymous EP1702815-008
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QC Lot: 812879)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 196 185 6.03 0% - 50%Anonymous EP1702726-001
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 240 240 0.417 0% - 20%Anonymous EP1702726-009
ED037P: Alkalinity by PC Titrator (QC Lot: 811224)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EP1702748-003
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 284 310 8.70 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 284 310 8.70 0% - 20%
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EP1702748-001
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 377 349 7.77 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 377 349 7.77 0% - 20%
ED045G: Chloride by Discrete Analyser (QC Lot: 808854)
ED045G: Chloride 16887-00-6 1 mg/L 313 312 0.00 0% - 20%Anonymous EP1702764-002
ED045G: Chloride 16887-00-6 1 mg/L 12800 12900 0.930 0% - 20%Anonymous EP1702767-003
ED093F: Dissolved Major Cations (QC Lot: 812103)
ED093F: Calcium 7440-70-2 1 mg/L 1080 1090 0.917 0% - 20%Anonymous EP1702760-008
ED093F: Magnesium 7439-95-4 1 mg/L 6280 6410 2.00 0% - 20%
ED093F: Sodium 7440-23-5 1 mg/L 56700 57500 1.31 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 964 1000 4.00 0% - 20%
ED093F: Calcium 7440-70-2 1 mg/L 2 2 0.00 No LimitAnonymous EP1702764-004
ED093F: Magnesium 7439-95-4 1 mg/L 21 21 0.00 0% - 20%
A
3 of 6:Page
Work Order :
:Client
EP1702765
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
ED093F: Dissolved Major Cations (QC Lot: 812103) - continued
ED093F: Sodium 7440-23-5 1 mg/L 224 226 0.932 0% - 20%Anonymous EP1702764-004
ED093F: Potassium 7440-09-7 1 mg/L 10 11 0.00 0% - 50%
EG020F: Dissolved Metals by ICP-MS (QC Lot: 812104)
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EP1702764-002
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L 0.001 0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.007 0.007 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.891 0.895 0.398 0% - 20%
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.031 0.031 0.00 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L 1.63 1.66 1.78 0% - 20%
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020T: Total Metals by ICP-MS (QC Lot: 812071)
EG020A-T: Iron 7439-89-6 0.05 mg/L 12.4 12.5 0.525 0% - 20%P1 EP1702765-001
EG035F: Dissolved Mercury by FIMS (QC Lot: 812102)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EP1702739-006
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitP2 EP1702765-002
EK055G: Ammonia as N by Discrete Analyser (QC Lot: 808861)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.10 0.12 18.4 0% - 50%Anonymous EP1702764-002
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.75 0.77 1.59 0% - 20%Anonymous EP1702767-003
EK057G: Nitrite as N by Discrete Analyser (QC Lot: 808853)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EP1702764-002
EK057G: Nitrite as N 14797-65-0 0.01 mg/L 0.03 0.03 0.00 No LimitAnonymous EP1702767-003
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QC Lot: 808862)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 0.01 0.00 No LimitAnonymous EP1702764-002
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 0.14 0.14 0.00 0% - 50%Anonymous EP1702767-003
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QC Lot: 810527)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 4.4 4.3 3.96 0% - 20%P1 EP1702765-001
EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 810526)
EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.08 0.06 17.3 No LimitP1 EP1702765-001
EP005: Total Organic Carbon (TOC) (QC Lot: 808199)
EP005: Total Organic Carbon ---- 1 mg/L 3 2 0.00 No LimitAnonymous EP1702732-001
EP005: Total Organic Carbon ---- 1 mg/L <1 <1 0.00 No LimitAnonymous EP1702764-004
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QC Lot: 813574)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L 17 17 0.00 No LimitAnonymous EP1702727-001
EP026SP: Chemical Oxygen Demand ---- 10 mg/L <10 <10 0.00 No LimitAnonymous EP1702747-003
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Method Blank (MB) and Laboratory Control Spike (LCS) Report
The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC
parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target
analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QCLot: 812145)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 95.52000 mg/L 11183
<10 1021000 mg/L 13070
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QCLot: 812879)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 1052000 mg/L 11183
<10 1101000 mg/L 13070
ED037P: Alkalinity by PC Titrator (QCLot: 811224)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-00
1
1 mg/L <1 -------- --------
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 -------- --------
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L <1 -------- --------
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L <1 10520 mg/L 12676
<1 96.3200 mg/L 10690
ED045G: Chloride by Discrete Analyser (QCLot: 808854)
ED045G: Chloride 16887-00-6 1 mg/L <1 98.910 mg/L 12084
<1 1011000 mg/L 11084
ED093F: Dissolved Major Cations (QCLot: 812103)
ED093F: Calcium 7440-70-2 1 mg/L <1 10250 mg/L 10991
ED093F: Magnesium 7439-95-4 1 mg/L <1 95.650 mg/L 10890
ED093F: Sodium 7440-23-5 1 mg/L <1 97.450 mg/L 11187
ED093F: Potassium 7440-09-7 1 mg/L <1 99.650 mg/L 11090
EG020F: Dissolved Metals by ICP-MS (QCLot: 812104)
EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 91.70.5 mg/L 11684
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 1010.1 mg/L 10884
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 93.00.1 mg/L 10886
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 91.20.1 mg/L 10985
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 92.50.1 mg/L 11084
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 93.40.1 mg/L 10785
EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 92.20.1 mg/L 10985
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 94.40.1 mg/L 11284
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 1040.1 mg/L 11288
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 94.80.1 mg/L 11589
EG020T: Total Metals by ICP-MS (QCLot: 812071)
EG020A-T: Iron 7439-89-6 0.05 mg/L <0.05 97.00.5 mg/L 12077
EG035F: Dissolved Mercury by FIMS (QCLot: 812102)
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EG035F: Dissolved Mercury by FIMS (QCLot: 812102) - continued
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 1140.01 mg/L 11692
EK055G: Ammonia as N by Discrete Analyser (QCLot: 808861)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 98.61 mg/L 11587
EK057G: Nitrite as N by Discrete Analyser (QCLot: 808853)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 98.80.5 mg/L 11286
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 808862)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 1060.5 mg/L 11292
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 810527)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 85.510 mg/L 11082
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 810526)
EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 89.94.42 mg/L 13070
EP005: Total Organic Carbon (TOC) (QCLot: 808199)
EP005: Total Organic Carbon ---- 1 mg/L <1 98.610 mg/L 11179
<1 106100 mg/L 11179
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 813574)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L <10 10650 mg/L 11282
<10 94.8500 mg/L 11383
Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on
analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
ED045G: Chloride by Discrete Analyser (QCLot: 808854)
Anonymous EP1702764-001 16887-00-6ED045G: Chloride 1031000 mg/L 13070
EG020F: Dissolved Metals by ICP-MS (QCLot: 812104)
Anonymous EP1702764-003 7440-38-2EG020A-F: Arsenic 1030.2 mg/L 13070
7440-43-9EG020A-F: Cadmium 99.00.05 mg/L 13070
7440-47-3EG020A-F: Chromium 98.00.2 mg/L 13070
7440-50-8EG020A-F: Copper 98.40.2 mg/L 13070
7439-92-1EG020A-F: Lead 99.00.2 mg/L 13070
7439-96-5EG020A-F: Manganese 98.90.2 mg/L 13070
7440-02-0EG020A-F: Nickel 1020.2 mg/L 13070
7440-66-6EG020A-F: Zinc 1060.2 mg/L 13070
EG035F: Dissolved Mercury by FIMS (QCLot: 812102)
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EG035F: Dissolved Mercury by FIMS (QCLot: 812102) - continued
Anonymous EP1702739-007 7439-97-6EG035F: Mercury 1000.01 mg/L 13070
EK055G: Ammonia as N by Discrete Analyser (QCLot: 808861)
Anonymous EP1702764-001 7664-41-7EK055G: Ammonia as N 79.41 mg/L 13070
EK057G: Nitrite as N by Discrete Analyser (QCLot: 808853)
Anonymous EP1702764-001 14797-65-0EK057G: Nitrite as N 79.80.5 mg/L 13070
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 808862)
Anonymous EP1702764-001 ----EK059G: Nitrite + Nitrate as N 1040.5 mg/L 13070
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 810527)
P2 EP1702765-002 ----EK061G: Total Kjeldahl Nitrogen as N 87.65 mg/L 13070
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 810526)
P2 EP1702765-002 ----EK067G: Total Phosphorus as P 86.21 mg/L 13070
EP005: Total Organic Carbon (TOC) (QCLot: 808199)
Anonymous EP1702732-002 ----EP005: Total Organic Carbon 119100 mg/L 13070
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 813574)
Anonymous EP1702727-001 ----EP026SP: Chemical Oxygen Demand 90.747.6 mg/L 13070
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True
Environmental
QA/QC Compliance Assessment to assist with Quality ReviewWork Order : EP1702765 Page : 1 of 8
:: LaboratoryClient Environmental Division PerthEMERGE ASSOCIATES
:Contact MR SIMON GREGG Telephone : 08 9209 7631
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 23-Mar-2017
Site : ---- Issue Date : 30-Mar-2017
MITCHELL RITIKIS:Sampler No. of samples received : 3
:Order number ---- No. of samples analysed : 3
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated
reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this
report contribute to the overall DQO assessment and reporting for guideline compliance.
Brief method summaries and references are also provided to assist in traceability.
Summary of Outliers
Outliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.
l NO Duplicate outliers occur.
l NO Laboratory Control outliers occur.
l NO Matrix Spike outliers occur.
l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliance
l Analysis Holding Time Outliers exist - please see following pages for full details.
Outliers : Frequency of Quality Control Samples
l Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Outliers : Analysis Holding Time Compliance
Matrix: WATER
AnalysisExtraction / Preparation
Date analysedDate extractedContainer / Client Sample ID(s) Days
overdue
Days
overdue
Due for extraction Due for analysis
Method
EK057G: Nitrite as N by Discrete Analyser
Clear Plastic Bottle - Natural
23-Mar-2017----P2 24-Mar-2017---- ---- 1
Outliers : Frequency of Quality Control Samples
Matrix: WATER
Quality Control SpecificationQuality Control Sample Type
Method ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC StandardTotal Metals by ICP-MS - Suite A 0.00 5.000 4
Analysis Holding Time Compliance
Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and
should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.
Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics
14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.
If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.
This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container
provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EA015: Total Dissolved Solids dried at 180 ± 5 °C
Clear Plastic Bottle - Natural (EA015H)
P2 28-Mar-2017---- 28-Mar-2017----21-Mar-2017 ---- üClear Plastic Bottle - Natural (EA015H)
P1, M1 29-Mar-2017---- 28-Mar-2017----22-Mar-2017 ---- üED037P: Alkalinity by PC Titrator
Clear Plastic Bottle - Natural (ED037-P)
P2 04-Apr-2017---- 27-Mar-2017----21-Mar-2017 ---- üClear Plastic Bottle - Natural (ED037-P)
P1, M1 05-Apr-2017---- 27-Mar-2017----22-Mar-2017 ---- üED045G: Chloride by Discrete Analyser
Clear Plastic Bottle - Natural (ED045G)
P2 18-Apr-2017---- 24-Mar-2017----21-Mar-2017 ---- üClear Plastic Bottle - Natural (ED045G)
P1, M1 19-Apr-2017---- 24-Mar-2017----22-Mar-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
ED093F: Dissolved Major Cations
Clear Plastic Bottle - Filtered; Lab-acidified (ED093F)
P2 18-Apr-2017---- 29-Mar-2017----21-Mar-2017 ---- üClear Plastic Bottle - Filtered; Lab-acidified (ED093F)
P1, M1 19-Apr-2017---- 29-Mar-2017----22-Mar-2017 ---- üEG020F: Dissolved Metals by ICP-MS
Clear Plastic Bottle - Filtered; Lab-acidified (EG020A-F)
P2 17-Sep-2017---- 29-Mar-2017----21-Mar-2017 ---- üClear Plastic Bottle - Filtered; Lab-acidified (EG020A-F)
P1, M1 18-Sep-2017---- 29-Mar-2017----22-Mar-2017 ---- üEG020T: Total Metals by ICP-MS
Clear Plastic Bottle - Unfiltered; Lab-acidified (EG020A-T)
P2 17-Sep-201717-Sep-2017 28-Mar-201728-Mar-201721-Mar-2017 ü üClear Plastic Bottle - Unfiltered; Lab-acidified (EG020A-T)
P1, M1 18-Sep-201718-Sep-2017 28-Mar-201728-Mar-201722-Mar-2017 ü üEG035F: Dissolved Mercury by FIMS
Clear Plastic Bottle - Filtered; Lab-acidified (EG035F)
P2 18-Apr-2017---- 29-Mar-2017----21-Mar-2017 ---- üClear Plastic Bottle - Filtered; Lab-acidified (EG035F)
P1, M1 19-Apr-2017---- 29-Mar-2017----22-Mar-2017 ---- üEK055G: Ammonia as N by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK055G)
P2 18-Apr-2017---- 24-Mar-2017----21-Mar-2017 ---- üClear Plastic Bottle - Sulfuric Acid (EK055G)
P1, M1 19-Apr-2017---- 24-Mar-2017----22-Mar-2017 ---- üEK057G: Nitrite as N by Discrete Analyser
Clear Plastic Bottle - Natural (EK057G)
P2 23-Mar-2017---- 24-Mar-2017----21-Mar-2017 ---- ûClear Plastic Bottle - Natural (EK057G)
P1, M1 24-Mar-2017---- 24-Mar-2017----22-Mar-2017 ---- üEK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK059G)
P2 18-Apr-2017---- 24-Mar-2017----21-Mar-2017 ---- üClear Plastic Bottle - Sulfuric Acid (EK059G)
P1, M1 19-Apr-2017---- 24-Mar-2017----22-Mar-2017 ---- üEK061G: Total Kjeldahl Nitrogen By Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK061G)
P2 18-Apr-201718-Apr-2017 28-Mar-201728-Mar-201721-Mar-2017 ü üClear Plastic Bottle - Sulfuric Acid (EK061G)
P1, M1 19-Apr-201719-Apr-2017 28-Mar-201728-Mar-201722-Mar-2017 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EK067G: Total Phosphorus as P by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK067G)
P2 18-Apr-201718-Apr-2017 28-Mar-201728-Mar-201721-Mar-2017 ü üClear Plastic Bottle - Sulfuric Acid (EK067G)
P1, M1 19-Apr-201719-Apr-2017 28-Mar-201728-Mar-201722-Mar-2017 ü üEP005: Total Organic Carbon (TOC)
Amber TOC Vial - Sulfuric Acid (EP005)
P2 18-Apr-2017---- 24-Mar-2017----21-Mar-2017 ---- üAmber TOC Vial - Sulfuric Acid (EP005)
P1, M1 19-Apr-2017---- 24-Mar-2017----22-Mar-2017 ---- üEP026SP: Chemical Oxygen Demand (Spectrophotometric)
Clear Plastic Bottle - Sulfuric Acid (EP026SP)
P2 18-Apr-2017---- 29-Mar-2017----21-Mar-2017 ---- üClear Plastic Bottle - Sulfuric Acid (EP026SP)
P1, M1 19-Apr-2017---- 29-Mar-2017----22-Mar-2017 ---- ü
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Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to
the expected rate. A listing of breaches is provided in the Summary of Outliers.
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 13.33 10.002 15 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 14.29 10.002 14 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 10.00 10.001 10 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 12.50 10.002 16 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 11.76 10.004 34 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 33.33 10.001 3 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 25.00 10.001 4 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 13.33 10.002 15 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 20.00 10.001 5 üTotal Phosphorus as P By Discrete Analyser EK067G
Laboratory Control Samples (LCS)
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 11.76 10.004 34 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 33.33 5.001 3 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 13.33 10.002 15 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üTotal Phosphorus as P By Discrete Analyser EK067G
Method Blanks (MB)
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üDissolved Metals by ICP-MS - Suite A EG020A-F
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Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Method Blanks (MB) - Continued
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 5.88 5.002 34 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 33.33 5.001 3 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üTotal Phosphorus as P By Discrete Analyser EK067G
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 33.33 5.001 3 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 4 ûTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üTotal Phosphorus as P By Discrete Analyser EK067G
7 of 8:Page
Work Order :
:Client
EP1702765
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the
Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 2540C. A gravimetric procedure that determines the amount of `filterable` residue
in an aqueous sample. A well-mixed sample is filtered through a glass fibre filter (1.2um). The filtrate is
evaporated to dryness and dried to constant weight at 180+/-5C. This method is compliant with NEPM (2013)
Schedule B(3)
Total Dissolved Solids (High Level) EA015H WATER
In house: Referenced to APHA 2320 B This procedure determines alkalinity by automated measurement (e.g. PC
Titrate) using pH 4.5 for indicating the total alkalinity end-point. This method is compliant with NEPM (2013)
Schedule B(3)
Alkalinity by PC Titrator ED037-P WATER
In house: Referenced to APHA 4500 Cl - G.The thiocyanate ion is liberated from mercuric thiocyanate through
sequestration of mercury by the chloride ion to form non-ionised mercuric chloride.in the presence of ferric ions
the librated thiocynate forms highly-coloured ferric thiocynate which is measured at 480 nm APHA 21st edition
seal method 2 017-1-L april 2003
Chloride by Discrete Analyser ED045G WATER
In house: Referenced to APHA 3120 and 3125; USEPA SW 846 - 6010 and 6020; Cations are determined by
either ICP-AES or ICP-MS techniques. This method is compliant with NEPM (2013) Schedule B(3)
Sodium Adsorption Ratio is calculated from Ca, Mg and Na which determined by ALS in house method
QWI-EN/ED093F. This method is compliant with NEPM (2013) Schedule B(3)
Hardness parameters are calculated based on APHA 2340 B. This method is compliant with NEPM (2013)
Schedule B(3)
Major Cations - Dissolved ED093F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. Samples are 0.45µm filtered
prior to analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions
are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct
mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Dissolved Metals by ICP-MS - Suite A EG020A-F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. The ICPMS technique utilizes
a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass
spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their
measurement by a discrete dynode ion detector.
Total Metals by ICP-MS - Suite A EG020A-T WATER
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS)
Samples are 0.45µm filtered prior to analysis. FIM-AAS is an automated flameless atomic absorption technique.
A bromate/bromide reagent is used to oxidise any organic mercury compounds in the filtered sample. The ionic
mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell.
Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM
(2013) Schedule B(3)
Dissolved Mercury by FIMS EG035F WATER
In house: Referenced to APHA 4500-NH3 G Ammonia is determined by direct colorimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Ammonia as N by Discrete analyser EK055G WATER
In house: Referenced to APHA 4500-NO2- B. Nitrite is determined by direct colourimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Nitrite as N by Discrete Analyser EK057G WATER
A
8 of 8:Page
Work Order :
:Client
EP1702765
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500-NO3- F. Nitrate is reduced to nitrite by way of a chemical reduction followed
by quantification by Discrete Analyser. Nitrite is determined seperately by direct colourimetry and result for Nitrate
calculated as the difference between the two results. This method is compliant with NEPM (2013) Schedule B(3)
Nitrate as N by Discrete Analyser EK058G WATER
In house: Referenced to APHA 4500-NO3- F. Combined oxidised Nitrogen (NO2+NO3) is determined by
Chemical Reduction and direct colourimetry by Discrete Analyser. This method is compliant with NEPM (2013)
Schedule B(3)
Nitrite and Nitrate as N (NOx) by Discrete
Analyser
EK059G WATER
In house: Referenced to APHA 4500-Norg D (In house). An aliquot of sample is digested using a high
temperature Kjeldahl digestion to convert nitrogenous compounds to ammonia. Ammonia is determined
colorimetrically by discrete analyser. This method is compliant with NEPM (2013) Schedule B(3)
Total Kjeldahl Nitrogen as N By Discrete
Analyser
EK061G WATER
In house: Referenced to APHA 4500-Norg / 4500-NO3-. This method is compliant with NEPM (2013) Schedule
B(3)
Total Nitrogen as N (TKN + Nox) By
Discrete Analyser
EK062G WATER
In house: Referenced to APHA 4500-P H, Jirka et al (1976), Zhang et al (2006). This procedure involves
sulphuric acid digestion of a sample aliquot to break phosphorus down to orthophosphate. The orthophosphate
reacts with ammonium molybdate and antimony potassium tartrate to form a complex which is then reduced and
its concentration measured at 880nm using discrete analyser. This method is compliant with NEPM (2013)
Schedule B(3)
Total Phosphorus as P By Discrete
Analyser
EK067G WATER
In house: Referenced to APHA 5310 B, The automated TOC analyzer determines Total and Inorganic Carbon by
IR cell. TOC is calculated as the difference. This method is compliant with NEPM (2013) Schedule B(3)
Total Organic Carbon EP005 WATER
In house: Referenced to APHA 5220 D. Samples are digested with a known excess of an acidic potassium
dichromate solution using silver sulfate as a catalyst. The chromium is reduced from the Cr (VI) oxidation state
to the Cr (III) state by the oxygen present in the organic material. Both of these chromium species are coloued
and absorb in the visible region of (400nm & 600nm) the spectrum. The oxidisable organic matter can be
calculated in terms of oxygen equivalents.
Chemical Oxygen Demand (COD)
(Spectrophotometric)
EP026SP WATER
Preparation Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 Norg - D; APHA 4500 P - H. This method is compliant with NEPM (2013)
Schedule B(3)
TKN/TP Digestion EK061/EK067 WATER
In house: Referenced to USEPA SW846-3005. Method 3005 is a Nitric/Hydrochloric acid digestion procedure
used to prepare surface and ground water samples for analysis by ICPAES or ICPMS. This method is compliant
with NEPM (2013) Schedule B(3)
Digestion for Total Recoverable Metals EN25 WATER
A
CHAIN OF CUSTODY CLIEI\-: Emerge Associates POSTAL ADDRESS: Suite 4, 26 Railway c'{oad, Subiaco WA 6008
~m~rg#J ~'.rqrJl::'d Sciirte & lk;Hp
PROJ=CT MAl\;AGER: Simon Gregg
PROJ=CT ID.: EP15-050(05)
SAMPLER(S): Mitchell Ritikis
QUOTE NO.: EP/009/16 ORDER NO.:
CONTACT PHONE: 9380 4988
PROJECT NAME: SAMR Monitoring - Davis Road
SAMPLERS PHONE: 0449198 721
Comments/special handling,'storage or disposal
Please note short holding time for some analysis.
Email invoice to: accounts@emergeassociates.com.au
ANALYSIS REQUIRED
w I
~ I
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i =1-----r~~~~~~~~~--------J~~m ~z~ _,;:;xo -~~w
SAMPLE DETAILS CONTAINER !NFORMATION --
ro a "ii,:, :;;~ "O $ C Olctl~ll)
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Lab ID I Sample ID Matrix Date Type & Preser,ative
MW2 '
Water 22/03/17 2SP,3VS, 1P,2AP,1AG '2. I MW3 Water 21/03/17 2SP, 3VS, 1P, 21'1P, 1AG
MW4 Water 22/03/17 2SP, 3VS, 1P, 21'1P, 1AG
~ I MW5 Water 21/03117 2SP, 3VS, 1P, 21'1P, 1AG
) I GWQA13 Water 21/03117 2 SP, 3VS, 1P, 2AP, 1AG
-o--'
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9 X
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Work Order Reference
EP1702764
11111 f elel)h0lle : • 61-8-9209 76'55
Additional information (likely contaminants, dilutions or specific QC analysis)
Mislabelled "DUP1"
Please log as per COC
RECEIVED BY I Coe emailed to ALS?
I NAME · Mitchell Ritikis DATE: 23/03/2017 NAME : . \r.\Cl \~ DATE: ~103117r: [gj Yes O No II
RELINQUISHED BY:
OF: Ener eAssociates TIME: 11:45 OF: L'.::, TIME: lb'.SQ_ NAME DATE: NAME: DATE: Water Ccwrrainer Codes: P = Unpreserved Plastic; N = Nitric Preserved Plastic; ORC = Nitric Preserved ORC; SH = S,Jctium Hydroxide/Cd Preserved; S = Sodium Hydroxide Preserved Plastic; AG = Amber Glass Unpreserved; AP = Airf-eiight Unpreserved Plastic; V = VOA Vial HCI Preserved; VB= VOA Vial Sodium Bisulphate Preserved; VS= VOA Vial Sulfuric Preserved; AV =-Airfreight Unpreserved Vial; SG = Sulfuric Preserved Amber Glass; H = HCI .Jfaserved Plastic; HS= HCI Preserved Speciation bottle; SP= Sulfuric Preserved Plastic; F = Formaldehyde ?rsserved Glass; z = Zinc Acetate Preserved Bottle; E = EDTA Preserved Bottles; ST= Steriie Bottle; LI= Lugols Iodine Preserved Botues; STT = Sterile Sodium Thiosulfa::i Preserved Bottles. Soil Container Codes: J = Jar; J\SS = Plastic Bag for Acid Sulfate Soils; B = Unpreserved _B_ag~; __ _
Environmental
SAMPLE RECEIPT NOTIFICATION (SRN)Work Order : EP1702764
:: LaboratoryClient Environmental Division PerthEMERGE ASSOCIATES
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA
6008
10 Hod Way Malaga WA Australia 6090
:: E-mailE-mail simon.gregg@emergeassociates.co
m.au
LUKE.JONES@alsglobal.com
:: TelephoneTelephone +61 08 9380 4988 08 9209 7631
:: FacsimileFacsimile +61 08 9380 9636 +61-8-9209 7600
::Project EP15-050(05) SAMR Monitoring -
Davis Road
Page 1 of 3
:Order number ---- :Quote number EP2015EMEASS0045 (EP/683/15)
:C-O-C number ---- :QC Level NEPM 2013 B3 & ALS QC Standard
Site : ----
Sampler : MITCHELL RITIKIS
DatesDate Samples Received : Issue Date : 24-Mar-201723-Mar-2017 16:50
Scheduled Reporting Date: 30-Mar-2017:Client Requested Due
Date
30-Mar-2017
Delivery DetailsMode of Delivery : :Carrier Not intact.Security Seal
No. of coolers/boxes : :3 Temperature 10.1 - Ice present
: : 5 / 5Receipt Detail No. of samples received / analysed
General Comments
This report contains the following information:l
- Sample Container(s)/Preservation Non-Compliances
- Summary of Sample(s) and Requested Analysis
- Proactive Holding Time Report
- Requested Deliverables
l Please see scanned COC for sample discrepencies: extra samples , samples not received etc.
l Please direct any queries related to sample condition / numbering / breakages to Sample Receipt (SamplesPerth@alsenviro.com)
l Analytical work for this work order will be conducted at ALS Environmental Perth.
l Please direct any turnaround / technical queries to the laboratory contact designated above.
l Sample Disposal - Aqueous (14 days), Solid (60 days) from date of completion of Work Order.
l COD analysis will be conducted by ALS Environmental, Sydney, NATA accreditation no. 825, Site
No. 10911.l pH analysis should be conducted within 6 hours of sampling.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
:Client EMERGE ASSOCIATES
Work Order : EP1702764 Amendment 02 of 3:Page
24-Mar-2017:Issue Date
Sample Container(s)/Preservation Non-Compliances
All comparisons are made against pretreatment/preservation AS, APHA, USEPA standards.
l No sample container / preservation non-compliance exists.
Summary of Sample(s) and Requested Analysis
Some items described below may be part of a laboratory
process necessary for the execution of client requested
tasks. Packages may contain additional analyses, such
as the determination of moisture content and preparation
tasks, that are included in the package.
If no sampling time is provided, the sampling time will
default 00:00 on the date of sampling. If no sampling date
is provided, the sampling date will be assumed by the
laboratory and displayed in brackets without a time
component
WA
TE
R -
ED
037-P
Alk
alin
ity a
s C
aC
O3 (
PC
T)
WA
TE
R -
ED
045G
Chlo
ride b
y D
iscr
ete
Analy
ser
WA
TE
R -
EG
020F
Dis
solv
ed M
eta
ls b
y IC
PM
S
WA
TE
R -
EP
026S
P
Chem
ical O
xygen D
em
and (
CO
D)
WA
TE
R -
NT
-01
Majo
r C
atio
ns
(Ca, M
g, N
a, K
)
WA
TE
R -
NT
-08
Tota
l Nitr
ogen +
NO
2 +
NO
3 +
NH
3 +
Tota
l P
WA
TE
R -
W-0
2
8 M
eta
ls
EP1702764-001 22-Mar-2017 00:00 MW2 ü ü ü ü ü ü ü
EP1702764-002 21-Mar-2017 00:00 MW3 ü ü ü ü ü ü ü
EP1702764-003 22-Mar-2017 00:00 MW4 ü ü ü ü ü ü ü
EP1702764-004 21-Mar-2017 00:00 MW5 ü ü ü ü ü ü ü
EP1702764-005 21-Mar-2017 00:00 GWQA13 ü ü ü ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
WA
TE
R -
EA
01
5H
To
tal D
isso
lve
d S
olid
s -
Hig
h L
eve
l
WA
TE
R -
EG
02
0T
To
tal R
eco
vera
ble
Me
tals
by
ICP
MS
(in
clu
din
g
WA
TE
R -
EP
00
5
To
tal O
rga
nic
Ca
rbo
n (
TO
C)
WA
TE
R -
W-1
7
TR
H/B
TE
XN
/PA
H/P
he
no
ls/O
C/P
CB
EP1702764-001 22-Mar-2017 00:00 MW2 ü ü ü ü
EP1702764-002 21-Mar-2017 00:00 MW3 ü ü ü ü
EP1702764-003 22-Mar-2017 00:00 MW4 ü ü ü ü
EP1702764-004 21-Mar-2017 00:00 MW5 ü ü ü ü
EP1702764-005 21-Mar-2017 00:00 GWQA13 ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
Proactive Holding Time Report
Sample(s) have been received within the recommended holding times for the requested analysis.
:Client EMERGE ASSOCIATES
Work Order : EP1702764 Amendment 03 of 3:Page
24-Mar-2017:Issue Date
Requested Deliverables
ACCOUNTS (INVOICES)
- A4 - AU Tax Invoice (INV) Email accounts@emergeassociates.com.
au
JEREMY PAYET
- *AU Certificate of Analysis - NATA (COA) Email jeremy.payet@emergeassociates.co
m.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email jeremy.payet@emergeassociates.co
m.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email jeremy.payet@emergeassociates.co
m.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email jeremy.payet@emergeassociates.co
m.au
- Chain of Custody (CoC) (COC) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - ENMRG (ENMRG) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - ESDAT (ESDAT) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - XTab (XTAB) Email jeremy.payet@emergeassociates.co
m.au
MITCHELL RITIKIS
- *AU Certificate of Analysis - NATA (COA) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email mitchell.ritikis@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email mitchell.ritikis@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - ENMRG (ENMRG) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email mitchell.ritikis@emergeassociates.c
om.au
SIMON GREGG
- *AU Certificate of Analysis - NATA (COA) Email simon.gregg@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email simon.gregg@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email simon.gregg@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email simon.gregg@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - ENMRG (ENMRG) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email simon.gregg@emergeassociates.c
om.au
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 8EP1702764
:: LaboratoryClient EMERGE ASSOCIATES Environmental Division Perth
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
10 Hod Way Malaga WA Australia 6090
:Telephone +61 08 9380 4988 :Telephone 08 9209 7631
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 23-Mar-2017 16:50
:Order number ---- Date Analysis Commenced : 24-Mar-2017
:C-O-C number ---- Issue Date : 31-Mar-2017 19:57
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EP/683/15
5:No. of samples received
5:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:
l General Comments
l Analytical Results
l Surrogate Control Limits
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with
Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Canhuang Ke Metals Instrument Chemist Perth Inorganics, Malaga, WA
Efua Wilson Metals Chemist Perth Inorganics, Malaga, WA
Huynh Huynh Organic Chemist Perth Organics, Malaga, WA
Indra Astuty Instrument Chemist Perth Inorganics, Malaga, WA
Jeremy Truong Laboratory Manager Perth Inorganics, Malaga, WA
Tyrone Cole Inorganics Preparation Supervisor Perth Inorganics, Malaga, WA
Vanessa Nguyen Organic Chemist Perth Organics, Malaga, WA
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with 1S0/IEC 17025 - Testing
2 of 8:Page
Work Order :
:Client
EP1702764
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When no sampling time is provided, the sampling time will default 00:00 on the date of sampling. If no sampling date is provided, the sampling date will be assumed by the laboratory and displayed in brackets without a
time component.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
^ = This result is computed from individual analyte detections at or above the level of reporting
ø = ALS is not NATA accredited for these tests.
~ = Indicates an estimated value.
Key :
COD conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.l
Benzo(a)pyrene Toxicity Equivalent Quotient (TEQ) is the sum total of the concentration of the eight carcinogenic PAHs multiplied by their Toxicity Equivalence Factor (TEF) relative to Benzo(a)pyrene. TEF values
are provided in brackets as follows: Benz(a)anthracene (0.1), Chrysene (0.01), Benzo(b+j) & Benzo(k)fluoranthene (0.1), Benzo(a)pyrene (1.0), Indeno(1.2.3.cd)pyrene (0.1), Dibenz(a.h)anthracene (1.0),
Benzo(g.h.i)perylene (0.01). Less than LOR results for 'TEQ Zero' are treated as zero.
l
A
3 of 8:Page
Work Order :
:Client
EP1702764
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
GWQA13MW5MW4MW3MW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)
21-Mar-2017 00:0021-Mar-2017 00:0022-Mar-2017 00:0021-Mar-2017 00:0022-Mar-2017 00:00Client sampling date / time
EP1702764-005EP1702764-004EP1702764-003EP1702764-002EP1702764-001UnitLORCAS NumberCompound
Result Result Result Result Result
EA015: Total Dissolved Solids dried at 180 ± 5 °C
444 684 236 825 651mg/L10----Total Dissolved Solids @180°C
ED037P: Alkalinity by PC Titrator
<1Hydroxide Alkalinity as CaCO3 <1 <1 <1 <1mg/L1DMO-210-001
<1Carbonate Alkalinity as CaCO3 <1 <1 <1 <1mg/L13812-32-6
12Bicarbonate Alkalinity as CaCO3 <1 <1 45 <1mg/L171-52-3
12 <1 <1 45 <1mg/L1----Total Alkalinity as CaCO3
ED045G: Chloride by Discrete Analyser
198Chloride 313 77 452 313mg/L116887-00-6
ED093F: Dissolved Major Cations
<1Calcium 1 <1 2 1mg/L17440-70-2
4Magnesium 14 5 21 14mg/L17439-95-4
92Sodium 165 47 224 168mg/L17440-23-5
<1Potassium 2 2 10 2mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS
0.05Aluminium 0.05 0.36 1.91 0.04mg/L0.017429-90-5
<0.001Arsenic <0.001 <0.001 <0.001 <0.001mg/L0.0017440-38-2
<0.0001Cadmium <0.0001 <0.0001 0.0001 <0.0001mg/L0.00017440-43-9
<0.001Chromium <0.001 <0.001 <0.001 <0.001mg/L0.0017440-47-3
0.001Copper <0.001 0.004 0.014 <0.001mg/L0.0017440-50-8
<0.001Nickel 0.001 0.003 0.009 0.001mg/L0.0017440-02-0
<0.001Lead <0.001 <0.001 <0.001 <0.001mg/L0.0017439-92-1
0.020Zinc 0.017 0.015 0.120 0.019mg/L0.0057440-66-6
0.004Manganese 0.864 0.014 1.50 0.861mg/L0.0017439-96-5
<0.01Selenium <0.01 <0.01 <0.01 <0.01mg/L0.017782-49-2
EG020T: Total Metals by ICP-MS
34.9Iron 46.6 1.36 39.5 45.0mg/L0.057439-89-6
EG035F: Dissolved Mercury by FIMS
<0.0001Mercury <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017439-97-6
EK055G: Ammonia as N by Discrete Analyser
0.59Ammonia as N 0.10 0.03 <0.01 0.15mg/L0.017664-41-7
EK057G: Nitrite as N by Discrete Analyser
<0.01Nitrite as N <0.01 <0.01 <0.01 <0.01mg/L0.0114797-65-0
EK058G: Nitrate as N by Discrete Analyser
0.02Nitrate as N <0.01 0.12 0.02 0.01mg/L0.0114797-55-8
A
---------------
4 of 8:Page
Work Order :
:Client
EP1702764
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
GWQA13MW5MW4MW3MW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)
21-Mar-2017 00:0021-Mar-2017 00:0022-Mar-2017 00:0021-Mar-2017 00:0022-Mar-2017 00:00Client sampling date / time
EP1702764-005EP1702764-004EP1702764-003EP1702764-002EP1702764-001UnitLORCAS NumberCompound
Result Result Result Result Result
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
0.02 <0.01 0.12 0.02 0.01mg/L0.01----Nitrite + Nitrate as N
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser
0.8 0.4 <0.1 <0.1 0.4mg/L0.1----Total Kjeldahl Nitrogen as N
EK062G: Total Nitrogen as N (TKN + NOx) by Discrete Analyser
0.8^ 0.4 0.1 <0.1 0.4mg/L0.1----Total Nitrogen as N
EK067G: Total Phosphorus as P by Discrete Analyser
0.12 0.13 0.02 0.04 0.15mg/L0.01----Total Phosphorus as P
EP005: Total Organic Carbon (TOC)
8 9 8 <1 7mg/L1----Total Organic Carbon
EP026SP: Chemical Oxygen Demand (Spectrophotometric)
<10 18 <10 16 13mg/L10----Chemical Oxygen Demand
EP066: Polychlorinated Biphenyls (PCB)
<1 <1 <1 <1 <1µg/L1----Total Polychlorinated biphenyls
EP068A: Organochlorine Pesticides (OC)
<0.5alpha-BHC <0.5 <0.5 <0.5 <0.5µg/L0.5319-84-6
<0.5Hexachlorobenzene (HCB) <0.5 <0.5 <0.5 <0.5µg/L0.5118-74-1
<0.5beta-BHC <0.5 <0.5 <0.5 <0.5µg/L0.5319-85-7
<0.5gamma-BHC <0.5 <0.5 <0.5 <0.5µg/L0.558-89-9
<0.5delta-BHC <0.5 <0.5 <0.5 <0.5µg/L0.5319-86-8
<0.5Heptachlor <0.5 <0.5 <0.5 <0.5µg/L0.576-44-8
<0.5Aldrin <0.5 <0.5 <0.5 <0.5µg/L0.5309-00-2
<0.5Heptachlor epoxide <0.5 <0.5 <0.5 <0.5µg/L0.51024-57-3
<0.5trans-Chlordane <0.5 <0.5 <0.5 <0.5µg/L0.55103-74-2
<0.5alpha-Endosulfan <0.5 <0.5 <0.5 <0.5µg/L0.5959-98-8
<0.5cis-Chlordane <0.5 <0.5 <0.5 <0.5µg/L0.55103-71-9
<0.5Dieldrin <0.5 <0.5 <0.5 <0.5µg/L0.560-57-1
<0.54.4`-DDE <0.5 <0.5 <0.5 <0.5µg/L0.572-55-9
<0.5Endrin <0.5 <0.5 <0.5 <0.5µg/L0.572-20-8
<0.5beta-Endosulfan <0.5 <0.5 <0.5 <0.5µg/L0.533213-65-9
<0.54.4`-DDD <0.5 <0.5 <0.5 <0.5µg/L0.572-54-8
<0.5Endrin aldehyde <0.5 <0.5 <0.5 <0.5µg/L0.57421-93-4
<0.5Endosulfan sulfate <0.5 <0.5 <0.5 <0.5µg/L0.51031-07-8
<2.04.4`-DDT <2.0 <2.0 <2.0 <2.0µg/L250-29-3
<0.5Endrin ketone <0.5 <0.5 <0.5 <0.5µg/L0.553494-70-5
A
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EP1702764
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EMERGE ASSOCIATES
Analytical Results
GWQA13MW5MW4MW3MW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)
21-Mar-2017 00:0021-Mar-2017 00:0022-Mar-2017 00:0021-Mar-2017 00:0022-Mar-2017 00:00Client sampling date / time
EP1702764-005EP1702764-004EP1702764-003EP1702764-002EP1702764-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP068A: Organochlorine Pesticides (OC) - Continued
<2.0Methoxychlor <2.0 <2.0 <2.0 <2.0µg/L272-43-5
<0.5^ <0.5 <0.5 <0.5 <0.5µg/L0.5----Total Chlordane (sum)
<0.5^ Sum of DDD + DDE + DDT <0.5 <0.5 <0.5 <0.5µg/L0.572-54-8/72-55-9/5
0-2
<0.5^ Sum of Aldrin + Dieldrin <0.5 <0.5 <0.5 <0.5µg/L0.5309-00-2/60-57-1
EP075(SIM)A: Phenolic Compounds
<1.0Phenol <1.0 <1.0 <1.0 <1.0µg/L1108-95-2
<1.02-Chlorophenol <1.0 <1.0 <1.0 <1.0µg/L195-57-8
<1.02-Methylphenol <1.0 <1.0 <1.0 <1.0µg/L195-48-7
<2.03- & 4-Methylphenol <2.0 <2.0 <2.0 <2.0µg/L21319-77-3
<1.02-Nitrophenol <1.0 <1.0 <1.0 <1.0µg/L188-75-5
<1.02.4-Dimethylphenol <1.0 <1.0 <1.0 <1.0µg/L1105-67-9
<1.02.4-Dichlorophenol <1.0 <1.0 <1.0 <1.0µg/L1120-83-2
<1.02.6-Dichlorophenol <1.0 <1.0 <1.0 <1.0µg/L187-65-0
<1.04-Chloro-3-methylphenol <1.0 <1.0 <1.0 <1.0µg/L159-50-7
<1.02.4.6-Trichlorophenol <1.0 <1.0 <1.0 <1.0µg/L188-06-2
<1.02.4.5-Trichlorophenol <1.0 <1.0 <1.0 <1.0µg/L195-95-4
<2.0Pentachlorophenol <2.0 <2.0 <2.0 <2.0µg/L287-86-5
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
<1.0Naphthalene <1.0 <1.0 <1.0 <1.0µg/L191-20-3
<1.0Acenaphthylene <1.0 <1.0 <1.0 <1.0µg/L1208-96-8
<1.0Acenaphthene <1.0 <1.0 <1.0 <1.0µg/L183-32-9
<1.0Fluorene <1.0 <1.0 <1.0 <1.0µg/L186-73-7
<1.0Phenanthrene <1.0 <1.0 <1.0 <1.0µg/L185-01-8
<1.0Anthracene <1.0 <1.0 <1.0 <1.0µg/L1120-12-7
<1.0Fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1206-44-0
<1.0Pyrene <1.0 <1.0 <1.0 <1.0µg/L1129-00-0
<1.0Benz(a)anthracene <1.0 <1.0 <1.0 <1.0µg/L156-55-3
<1.0Chrysene <1.0 <1.0 <1.0 <1.0µg/L1218-01-9
<1.0Benzo(b+j)fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1205-99-2 205-82-3
<1.0Benzo(k)fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1207-08-9
<0.5Benzo(a)pyrene <0.5 <0.5 <0.5 <0.5µg/L0.550-32-8
<1.0Indeno(1.2.3.cd)pyrene <1.0 <1.0 <1.0 <1.0µg/L1193-39-5
<1.0Dibenz(a.h)anthracene <1.0 <1.0 <1.0 <1.0µg/L153-70-3
<1.0Benzo(g.h.i)perylene <1.0 <1.0 <1.0 <1.0µg/L1191-24-2
A
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EP1702764
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EMERGE ASSOCIATES
Analytical Results
GWQA13MW5MW4MW3MW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)
21-Mar-2017 00:0021-Mar-2017 00:0022-Mar-2017 00:0021-Mar-2017 00:0022-Mar-2017 00:00Client sampling date / time
EP1702764-005EP1702764-004EP1702764-003EP1702764-002EP1702764-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued
<0.5^ <0.5 <0.5 <0.5 <0.5µg/L0.5----Sum of polycyclic aromatic hydrocarbons
<0.5^ <0.5 <0.5 <0.5 <0.5µg/L0.5----Benzo(a)pyrene TEQ (zero)
EP080/071: Total Petroleum Hydrocarbons
<20 <20 <20 <20 <20µg/L20----C6 - C9 Fraction
<50 <50 <50 <50 <50µg/L50----C10 - C14 Fraction
<100 120 <100 <100 160µg/L100----C15 - C28 Fraction
<50 <50 <50 <50 <50µg/L50----C29 - C36 Fraction
<50^ 120 <50 <50 160µg/L50----C10 - C36 Fraction (sum)
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
<20C6 - C10 Fraction <20 <20 <20 <20µg/L20C6_C10
<20^ C6 - C10 Fraction minus BTEX
(F1)
<20 <20 <20 <20µg/L20C6_C10-BTEX
<100 <100 <100 <100 <100µg/L100---->C10 - C16 Fraction
<100 130 <100 <100 170µg/L100---->C16 - C34 Fraction
<100 <100 <100 <100 <100µg/L100---->C34 - C40 Fraction
<100^ 130 <100 <100 170µg/L100---->C10 - C40 Fraction (sum)
<100^ <100 <100 <100 <100µg/L100---->C10 - C16 Fraction minus Naphthalene
(F2)
EP080: BTEXN
<1Benzene <1 <1 <1 <1µg/L171-43-2
<2Toluene <2 <2 <2 <2µg/L2108-88-3
<2Ethylbenzene <2 <2 <2 <2µg/L2100-41-4
<2meta- & para-Xylene <2 <2 <2 <2µg/L2108-38-3 106-42-3
<2ortho-Xylene <2 <2 <2 <2µg/L295-47-6
<2^ Total Xylenes <2 <2 <2 <2µg/L21330-20-7
<1^ <1 <1 <1 <1µg/L1----Sum of BTEX
<5Naphthalene <5 <5 <5 <5µg/L591-20-3
EP066S: PCB Surrogate
82.3Decachlorobiphenyl 79.0 87.2 87.9 89.1%12051-24-3
EP068S: Organochlorine Pesticide Surrogate
87.7Dibromo-DDE 79.4 84.0 94.5 88.9%0.521655-73-2
EP068T: Organophosphorus Pesticide Surrogate
77.7DEF 75.7 77.1 88.9 87.2%0.578-48-8
EP075(SIM)S: Phenolic Compound Surrogates
A
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Analytical Results
GWQA13MW5MW4MW3MW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)
21-Mar-2017 00:0021-Mar-2017 00:0022-Mar-2017 00:0021-Mar-2017 00:0022-Mar-2017 00:00Client sampling date / time
EP1702764-005EP1702764-004EP1702764-003EP1702764-002EP1702764-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP075(SIM)S: Phenolic Compound Surrogates - Continued
24.9Phenol-d6 24.5 22.8 26.6 28.4%113127-88-3
74.22-Chlorophenol-D4 70.5 65.1 78.3 76.8%193951-73-6
71.22.4.6-Tribromophenol 72.1 63.4 80.1 77.1%1118-79-6
EP075(SIM)T: PAH Surrogates
88.62-Fluorobiphenyl 81.7 73.3 97.0 86.6%1321-60-8
79.3Anthracene-d10 75.7 72.8 86.9 80.1%11719-06-8
86.04-Terphenyl-d14 80.3 79.2 92.0 85.1%11718-51-0
EP080S: TPH(V)/BTEX Surrogates
98.91.2-Dichloroethane-D4 103 99.6 107 110%217060-07-0
102Toluene-D8 102 104 100 99.5%22037-26-5
94.94-Bromofluorobenzene 95.1 94.9 95.0 93.8%2460-00-4
A
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Surrogate Control Limits
Recovery Limits (%)Sub-Matrix: WATER
Compound CAS Number Low High
EP066S: PCB Surrogate
Decachlorobiphenyl 2051-24-3 27 136
EP068S: Organochlorine Pesticide Surrogate
Dibromo-DDE 21655-73-2 50 146
EP068T: Organophosphorus Pesticide Surrogate
DEF 78-48-8 27 153
EP075(SIM)S: Phenolic Compound Surrogates
Phenol-d6 13127-88-3 10 67
2-Chlorophenol-D4 93951-73-6 29 120
2.4.6-Tribromophenol 118-79-6 10 131
EP075(SIM)T: PAH Surrogates
2-Fluorobiphenyl 321-60-8 34 131
Anthracene-d10 1719-06-8 43 127
4-Terphenyl-d14 1718-51-0 41 142
EP080S: TPH(V)/BTEX Surrogates
1.2-Dichloroethane-D4 17060-07-0 61 141
Toluene-D8 2037-26-5 73 126
4-Bromofluorobenzene 460-00-4 60 125
A
False
8 8.00False
Environmental
QUALITY CONTROL REPORTWork Order : EP1702764 Page : 1 of 12
:: LaboratoryClient Environmental Division PerthEMERGE ASSOCIATES
:Contact MR SIMON GREGG :Contact Luke Jones
:Address SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
Address : 10 Hod Way Malaga WA Australia 6090
::Telephone +61 08 9380 4988 08 9209 7631:Telephone
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 23-Mar-2017
:Order number ---- Date Analysis Commenced : 24-Mar-2017
:C-O-C number ---- Issue Date : 31-Mar-2017
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EP/683/15
No. of samples received 5:
No. of samples analysed 5:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limits
l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits
l Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Canhuang Ke Metals Instrument Chemist Perth Inorganics, Malaga, WA
Efua Wilson Metals Chemist Perth Inorganics, Malaga, WA
Huynh Huynh Organic Chemist Perth Organics, Malaga, WA
Indra Astuty Instrument Chemist Perth Inorganics, Malaga, WA
Jeremy Truong Laboratory Manager Perth Inorganics, Malaga, WA
Tyrone Cole Inorganics Preparation Supervisor Perth Inorganics, Malaga, WA
Vanessa Nguyen Organic Chemist Perth Organics, Malaga, WA
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with 150/IEC 17025 - Testing
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General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
RPD = Relative Percentage Difference
# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) Report
The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges
for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:
No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QC Lot: 812143)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 214 212 0.939 0% - 20%Anonymous EP1702722-001
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 170000 163000 4.04 0% - 20%Anonymous EP1702760-009
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QC Lot: 812879)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 196 185 6.03 0% - 50%Anonymous EP1702726-001
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 240 240 0.417 0% - 20%Anonymous EP1702726-009
ED037P: Alkalinity by PC Titrator (QC Lot: 811224)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EP1702748-003
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 284 310 8.70 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 284 310 8.70 0% - 20%
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EP1702748-001
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 377 349 7.77 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 377 349 7.77 0% - 20%
ED045G: Chloride by Discrete Analyser (QC Lot: 808854)
ED045G: Chloride 16887-00-6 1 mg/L 313 312 0.00 0% - 20%MW3 EP1702764-002
ED045G: Chloride 16887-00-6 1 mg/L 12800 12900 0.930 0% - 20%Anonymous EP1702767-003
ED093F: Dissolved Major Cations (QC Lot: 812103)
ED093F: Calcium 7440-70-2 1 mg/L 1080 1090 0.917 0% - 20%Anonymous EP1702760-008
ED093F: Magnesium 7439-95-4 1 mg/L 6280 6410 2.00 0% - 20%
ED093F: Sodium 7440-23-5 1 mg/L 56700 57500 1.31 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 964 1000 4.00 0% - 20%
ED093F: Calcium 7440-70-2 1 mg/L 2 2 0.00 No LimitMW5 EP1702764-004
ED093F: Magnesium 7439-95-4 1 mg/L 21 21 0.00 0% - 20%
A
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
ED093F: Dissolved Major Cations (QC Lot: 812103) - continued
ED093F: Sodium 7440-23-5 1 mg/L 224 226 0.932 0% - 20%MW5 EP1702764-004
ED093F: Potassium 7440-09-7 1 mg/L 10 11 0.00 0% - 50%
EG020F: Dissolved Metals by ICP-MS (QC Lot: 812101)
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EP1702739-001
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 <0.005 0.00 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L 0.0050 0.0051 2.02 No LimitAnonymous EP1702760-007
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.020 <0.020 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.020 <0.020 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.020 <0.020 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L 0.218 0.227 4.09 0% - 50%
EG020A-F: Manganese 7439-96-5 0.001 mg/L 7.57 7.82 3.29 0% - 20%
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.151 0.145 3.69 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.100 <0.100 0.00 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L 27.5 27.8 1.30 0% - 20%
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.20 <0.20 0.00 No Limit
EG020F: Dissolved Metals by ICP-MS (QC Lot: 812104)
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitMW3 EP1702764-002
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.864 0.889 2.85 0% - 20%
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.001 0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.017 0.018 0.00 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L 0.05 0.05 0.00 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020T: Total Metals by ICP-MS (QC Lot: 812070)
EG020A-T: Iron 7439-89-6 0.05 mg/L <0.05 <0.05 0.00 No LimitAnonymous EP1702715-001
EG020A-T: Iron 7439-89-6 0.05 mg/L 11.3 11.3 0.205 0% - 20%Anonymous EP1702733-004
EG035F: Dissolved Mercury by FIMS (QC Lot: 812102)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EP1702739-006
A
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EG035F: Dissolved Mercury by FIMS (QC Lot: 812102) - continued
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EP1702765-002
EK055G: Ammonia as N by Discrete Analyser (QC Lot: 808861)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.10 0.12 18.4 0% - 50%MW3 EP1702764-002
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.75 0.77 1.59 0% - 20%Anonymous EP1702767-003
EK057G: Nitrite as N by Discrete Analyser (QC Lot: 808853)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No LimitMW3 EP1702764-002
EK057G: Nitrite as N 14797-65-0 0.01 mg/L 0.03 0.03 0.00 No LimitAnonymous EP1702767-003
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QC Lot: 808862)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 0.01 0.00 No LimitMW3 EP1702764-002
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 0.14 0.14 0.00 0% - 50%Anonymous EP1702767-003
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QC Lot: 810525)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 <0.1 0.00 No LimitAnonymous EP1702727-007
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 <0.1 0.00 No LimitAnonymous EP1702747-005
EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 810524)
EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EP1702727-007
EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EP1702747-005
EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 810526)
EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.08 0.06 17.3 No LimitAnonymous EP1702765-001
EP005: Total Organic Carbon (TOC) (QC Lot: 808199)
EP005: Total Organic Carbon ---- 1 mg/L 3 2 0.00 No LimitAnonymous EP1702732-001
EP005: Total Organic Carbon ---- 1 mg/L <1 <1 0.00 No LimitMW5 EP1702764-004
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QC Lot: 813574)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L 17 17 0.00 No LimitAnonymous EP1702727-001
EP026SP: Chemical Oxygen Demand ---- 10 mg/L <10 <10 0.00 No LimitAnonymous EP1702747-003
EP075(SIM)A: Phenolic Compounds (QC Lot: 808929)
EP075(SIM): Phenol 108-95-2 1 µg/L <1.0 <1.0 0.00 No LimitAnonymous EP1702744-001
EP075(SIM): 2-Chlorophenol 95-57-8 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): 2-Methylphenol 95-48-7 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): 2-Nitrophenol 88-75-5 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): 2.4-Dimethylphenol 105-67-9 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): 2.4-Dichlorophenol 120-83-2 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): 2.6-Dichlorophenol 87-65-0 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): 4-Chloro-3-methylphenol 59-50-7 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): 2.4.6-Trichlorophenol 88-06-2 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): 2.4.5-Trichlorophenol 95-95-4 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): 3- & 4-Methylphenol 1319-77-3 2 µg/L <2.0 <2.0 0.00 No Limit
EP075(SIM): Pentachlorophenol 87-86-5 2 µg/L <2.0 <2.0 0.00 No Limit
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QC Lot: 808929)
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QC Lot: 808929) - continued
EP075(SIM): Benzo(a)pyrene 50-32-8 0.5 µg/L <0.5 <0.5 0.00 No LimitAnonymous EP1702744-001
EP075(SIM): Sum of polycyclic aromatic
hydrocarbons
---- 0.5 µg/L <0.5 <0.5 0.00 No Limit
EP075(SIM): Naphthalene 91-20-3 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Acenaphthylene 208-96-8 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Acenaphthene 83-32-9 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Fluorene 86-73-7 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Phenanthrene 85-01-8 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Anthracene 120-12-7 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Fluoranthene 206-44-0 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Pyrene 129-00-0 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Benz(a)anthracene 56-55-3 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Chrysene 218-01-9 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Benzo(b+j)fluoranthene 205-99-2
205-82-3
1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Benzo(k)fluoranthene 207-08-9 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Indeno(1.2.3.cd)pyrene 193-39-5 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Dibenz(a.h)anthracene 53-70-3 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Benzo(g.h.i)perylene 191-24-2 1 µg/L <1.0 <1.0 0.00 No Limit
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 808930)
EP071: C15 - C28 Fraction ---- 100 µg/L 150 120 18.2 No LimitAnonymous EP1702744-002
EP071: C10 - C14 Fraction ---- 50 µg/L 50 <50 0.00 No Limit
EP071: C29 - C36 Fraction ---- 50 µg/L <50 <50 0.00 No Limit
EP071: C15 - C28 Fraction ---- 100 µg/L <100 <100 0.00 No LimitAnonymous EP1702744-001
EP071: C10 - C14 Fraction ---- 50 µg/L <50 <50 0.00 No Limit
EP071: C29 - C36 Fraction ---- 50 µg/L <50 <50 0.00 No Limit
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 810399)
EP080: C6 - C9 Fraction ---- 20 µg/L <0.02 <20 0.00 No LimitAnonymous EP1702747-001
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitMW4 EP1702764-003
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 808930)
EP071: >C10 - C16 Fraction ---- 100 µg/L <100 <100 0.00 No LimitAnonymous EP1702744-002
EP071: >C16 - C34 Fraction ---- 100 µg/L 140 110 23.9 No Limit
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 <100 0.00 No Limit
EP071: >C10 - C16 Fraction ---- 100 µg/L <100 <100 0.00 No LimitAnonymous EP1702744-001
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 <100 0.00 No Limit
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 <100 0.00 No Limit
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 810399)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <0.02 <20 0.00 No LimitAnonymous EP1702747-001
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitMW4 EP1702764-003
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP080: BTEXN (QC Lot: 810399)
EP080: Benzene 71-43-2 1 µg/L <0.001 <1 0.00 No LimitAnonymous EP1702747-001
EP080: Toluene 108-88-3 2 µg/L <0.002 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <0.002 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <0.002 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <0.002 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <0.005 <5 0.00 No Limit
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitMW4 EP1702764-003
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
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Method Blank (MB) and Laboratory Control Spike (LCS) Report
The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC
parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target
analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QCLot: 812143)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 1022000 mg/L 11183
<10 1041000 mg/L 13070
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QCLot: 812879)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 1052000 mg/L 11183
<10 1101000 mg/L 13070
ED037P: Alkalinity by PC Titrator (QCLot: 811224)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-00
1
1 mg/L <1 -------- --------
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 -------- --------
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L <1 -------- --------
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L <1 10520 mg/L 12676
<1 96.3200 mg/L 10690
ED045G: Chloride by Discrete Analyser (QCLot: 808854)
ED045G: Chloride 16887-00-6 1 mg/L <1 98.910 mg/L 12084
<1 1011000 mg/L 11084
ED093F: Dissolved Major Cations (QCLot: 812103)
ED093F: Calcium 7440-70-2 1 mg/L <1 10250 mg/L 10991
ED093F: Magnesium 7439-95-4 1 mg/L <1 95.650 mg/L 10890
ED093F: Sodium 7440-23-5 1 mg/L <1 97.450 mg/L 11187
ED093F: Potassium 7440-09-7 1 mg/L <1 99.650 mg/L 11090
EG020F: Dissolved Metals by ICP-MS (QCLot: 812101)
EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 90.70.5 mg/L 11684
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 97.10.1 mg/L 10884
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 92.30.1 mg/L 10886
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 93.30.1 mg/L 10985
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 89.80.1 mg/L 11084
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 93.40.1 mg/L 10785
EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 95.20.1 mg/L 10985
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 93.30.1 mg/L 11284
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 97.50.1 mg/L 11288
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 97.90.1 mg/L 11589
EG020F: Dissolved Metals by ICP-MS (QCLot: 812104)
EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 91.70.5 mg/L 11684
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 1010.1 mg/L 10884
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EG020F: Dissolved Metals by ICP-MS (QCLot: 812104) - continued
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 93.00.1 mg/L 10886
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 91.20.1 mg/L 10985
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 92.50.1 mg/L 11084
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 93.40.1 mg/L 10785
EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 92.20.1 mg/L 10985
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 94.40.1 mg/L 11284
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 1040.1 mg/L 11288
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 94.80.1 mg/L 11589
EG020T: Total Metals by ICP-MS (QCLot: 812070)
EG020A-T: Iron 7439-89-6 0.05 mg/L <0.05 93.00.5 mg/L 12077
EG035F: Dissolved Mercury by FIMS (QCLot: 812102)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 1140.01 mg/L 11692
EK055G: Ammonia as N by Discrete Analyser (QCLot: 808861)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 98.61 mg/L 11587
EK057G: Nitrite as N by Discrete Analyser (QCLot: 808853)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 98.80.5 mg/L 11286
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 808862)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 1060.5 mg/L 11292
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 810525)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 84.710 mg/L 11082
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 810524)
EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 96.14.42 mg/L 13070
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 810526)
EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 89.94.42 mg/L 13070
EP005: Total Organic Carbon (TOC) (QCLot: 808199)
EP005: Total Organic Carbon ---- 1 mg/L <1 98.610 mg/L 11179
<1 106100 mg/L 11179
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 813574)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L <10 10650 mg/L 11282
<10 94.8500 mg/L 11383
EP066: Polychlorinated Biphenyls (PCB) (QCLot: 808931)
EP066: Total Polychlorinated biphenyls ---- 1 µg/L <1 52.05 µg/L 9036
EP068A: Organochlorine Pesticides (OC) (QCLot: 808932)
EP068: alpha-BHC 319-84-6 0.5 µg/L <0.5 66.95 µg/L 11242
EP068: Hexachlorobenzene (HCB) 118-74-1 0.5 µg/L <0.5 69.05 µg/L 10839
EP068: beta-BHC 319-85-7 0.5 µg/L <0.5 69.55 µg/L 11646
EP068: gamma-BHC 58-89-9 0.5 µg/L <0.5 71.05 µg/L 11843
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP068A: Organochlorine Pesticides (OC) (QCLot: 808932) - continued
EP068: delta-BHC 319-86-8 0.5 µg/L <0.5 68.85 µg/L 11546
EP068: Heptachlor 76-44-8 0.5 µg/L <0.5 64.55 µg/L 11139
EP068: Aldrin 309-00-2 0.5 µg/L <0.5 67.25 µg/L 11440
EP068: Heptachlor epoxide 1024-57-3 0.5 µg/L <0.5 83.15 µg/L 12242
EP068: trans-Chlordane 5103-74-2 0.5 µg/L <0.5 71.15 µg/L 12144
EP068: alpha-Endosulfan 959-98-8 0.5 µg/L <0.5 78.95 µg/L 12942
EP068: cis-Chlordane 5103-71-9 0.5 µg/L <0.5 71.75 µg/L 12343
EP068: Dieldrin 60-57-1 0.5 µg/L <0.5 65.05 µg/L 12142
EP068: 4.4`-DDE 72-55-9 0.5 µg/L <0.5 69.75 µg/L 12344
EP068: Endrin 72-20-8 0.5 µg/L <0.5 59.75 µg/L 12727
EP068: beta-Endosulfan 33213-65-9 0.5 µg/L <0.5 70.05 µg/L 12845
EP068: 4.4`-DDD 72-54-8 0.5 µg/L <0.5 70.95 µg/L 12842
EP068: Endrin aldehyde 7421-93-4 0.5 µg/L <0.5 62.45 µg/L 12132
EP068: Endosulfan sulfate 1031-07-8 0.5 µg/L <0.5 69.45 µg/L 12041
EP068: 4.4`-DDT 50-29-3 2 µg/L <2.0 69.95 µg/L 12332
EP068: Endrin ketone 53494-70-5 0.5 µg/L <0.5 69.85 µg/L 12436
EP068: Methoxychlor 72-43-5 2 µg/L <2.0 64.25 µg/L 12425
EP075(SIM)A: Phenolic Compounds (QCLot: 808929)
EP075(SIM): Phenol 108-95-2 1 µg/L <1.0 29.610 µg/L 469
EP075(SIM): 2-Chlorophenol 95-57-8 1 µg/L <1.0 76.910 µg/L 9734
EP075(SIM): 2-Methylphenol 95-48-7 1 µg/L <1.0 64.910 µg/L 9325
EP075(SIM): 3- & 4-Methylphenol 1319-77-3 2 µg/L <2.0 58.920 µg/L 8322
EP075(SIM): 2-Nitrophenol 88-75-5 1 µg/L <1.0 64.910 µg/L 10434
EP075(SIM): 2.4-Dimethylphenol 105-67-9 1 µg/L <1.0 83.810 µg/L 10234
EP075(SIM): 2.4-Dichlorophenol 120-83-2 1 µg/L <1.0 75.310 µg/L 10434
EP075(SIM): 2.6-Dichlorophenol 87-65-0 1 µg/L <1.0 82.910 µg/L 10238
EP075(SIM): 4-Chloro-3-methylphenol 59-50-7 1 µg/L <1.0 74.710 µg/L 10630
EP075(SIM): 2.4.6-Trichlorophenol 88-06-2 1 µg/L <1.0 72.710 µg/L 10932
EP075(SIM): 2.4.5-Trichlorophenol 95-95-4 1 µg/L <1.0 67.010 µg/L 11034
EP075(SIM): Pentachlorophenol 87-86-5 2 µg/L <2.0 57.510 µg/L 10414
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 808929)
EP075(SIM): Naphthalene 91-20-3 1 µg/L <1.0 91.510 µg/L 9942
EP075(SIM): Acenaphthylene 208-96-8 1 µg/L <1.0 80.310 µg/L 11336
EP075(SIM): Acenaphthene 83-32-9 1 µg/L <1.0 87.610 µg/L 10236
EP075(SIM): Fluorene 86-73-7 1 µg/L <1.0 89.210 µg/L 11334
EP075(SIM): Phenanthrene 85-01-8 1 µg/L <1.0 80.210 µg/L 11537
EP075(SIM): Anthracene 120-12-7 1 µg/L <1.0 82.910 µg/L 10946
EP075(SIM): Fluoranthene 206-44-0 1 µg/L <1.0 80.710 µg/L 12440
EP075(SIM): Pyrene 129-00-0 1 µg/L <1.0 80.910 µg/L 12340
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 808929) - continued
EP075(SIM): Benz(a)anthracene 56-55-3 1 µg/L <1.0 75.010 µg/L 12640
EP075(SIM): Chrysene 218-01-9 1 µg/L <1.0 79.910 µg/L 12146
EP075(SIM): Benzo(b+j)fluoranthene 205-99-2
205-82-3
1 µg/L <1.0 72.910 µg/L 12343
EP075(SIM): Benzo(k)fluoranthene 207-08-9 1 µg/L <1.0 77.810 µg/L 12147
EP075(SIM): Benzo(a)pyrene 50-32-8 0.5 µg/L <0.5 71.310 µg/L 12345
EP075(SIM): Indeno(1.2.3.cd)pyrene 193-39-5 1 µg/L <1.0 85.510 µg/L 12039
EP075(SIM): Dibenz(a.h)anthracene 53-70-3 1 µg/L <1.0 84.210 µg/L 11939
EP075(SIM): Benzo(g.h.i)perylene 191-24-2 1 µg/L <1.0 83.810 µg/L 12340
EP075(SIM): Sum of polycyclic aromatic hydrocarbons ---- 0.5 µg/L <0.5 -------- --------
EP080/071: Total Petroleum Hydrocarbons (QCLot: 808930)
EP071: C10 - C14 Fraction ---- 50 µg/L <50 72.9400 µg/L 9535
EP071: C15 - C28 Fraction ---- 100 µg/L <100 87.0400 µg/L 11134
EP071: C29 - C36 Fraction ---- 50 µg/L <50 92.3400 µg/L 10534
EP080/071: Total Petroleum Hydrocarbons (QCLot: 810399)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 104320 µg/L 11374
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 808930)
EP071: >C10 - C16 Fraction ---- 100 µg/L <100 76.5400 µg/L 9937
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 90.4600 µg/L 10835
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 93.0200 µg/L 11711
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 810399)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 105370 µg/L 11574
EP080: BTEXN (QCLot: 810399)
EP080: Benzene 71-43-2 1 µg/L <1 98.520 µg/L 11484
EP080: Toluene 108-88-3 2 µg/L <2 95.720 µg/L 11581
EP080: Ethylbenzene 100-41-4 2 µg/L <2 10420 µg/L 11384
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 10140 µg/L 11484
EP080: ortho-Xylene 95-47-6 2 µg/L <2 98.820 µg/L 11187
EP080: Naphthalene 91-20-3 5 µg/L <5 99.120 µg/L 11877
Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on
analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
ED045G: Chloride by Discrete Analyser (QCLot: 808854)
MW2 EP1702764-001 16887-00-6ED045G: Chloride 1031000 mg/L 13070
EG020F: Dissolved Metals by ICP-MS (QCLot: 812101)
Anonymous EP1702739-002 7440-38-2EG020A-F: Arsenic 1030.2 mg/L 13070
7440-43-9EG020A-F: Cadmium 98.20.05 mg/L 13070
7440-47-3EG020A-F: Chromium 99.10.2 mg/L 13070
7440-50-8EG020A-F: Copper 94.30.2 mg/L 13070
7439-92-1EG020A-F: Lead 95.60.2 mg/L 13070
7439-96-5EG020A-F: Manganese 97.20.2 mg/L 13070
7440-02-0EG020A-F: Nickel 99.30.2 mg/L 13070
7440-66-6EG020A-F: Zinc 1030.2 mg/L 13070
EG020F: Dissolved Metals by ICP-MS (QCLot: 812104)
MW4 EP1702764-003 7440-38-2EG020A-F: Arsenic 1030.2 mg/L 13070
7440-43-9EG020A-F: Cadmium 99.00.05 mg/L 13070
7440-47-3EG020A-F: Chromium 98.00.2 mg/L 13070
7440-50-8EG020A-F: Copper 98.40.2 mg/L 13070
7439-92-1EG020A-F: Lead 99.00.2 mg/L 13070
7439-96-5EG020A-F: Manganese 98.90.2 mg/L 13070
7440-02-0EG020A-F: Nickel 1020.2 mg/L 13070
7440-66-6EG020A-F: Zinc 1060.2 mg/L 13070
EG035F: Dissolved Mercury by FIMS (QCLot: 812102)
Anonymous EP1702739-007 7439-97-6EG035F: Mercury 1000.01 mg/L 13070
EK055G: Ammonia as N by Discrete Analyser (QCLot: 808861)
MW2 EP1702764-001 7664-41-7EK055G: Ammonia as N 79.41 mg/L 13070
EK057G: Nitrite as N by Discrete Analyser (QCLot: 808853)
MW2 EP1702764-001 14797-65-0EK057G: Nitrite as N 79.80.5 mg/L 13070
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 808862)
MW2 EP1702764-001 ----EK059G: Nitrite + Nitrate as N 1040.5 mg/L 13070
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 810525)
Anonymous EP1702733-001 ----EK061G: Total Kjeldahl Nitrogen as N 85.35 mg/L 13070
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 810524)
Anonymous EP1702733-001 ----EK067G: Total Phosphorus as P 91.81 mg/L 13070
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 810526)
Anonymous EP1702765-002 ----EK067G: Total Phosphorus as P 86.21 mg/L 13070
EP005: Total Organic Carbon (TOC) (QCLot: 808199)
Anonymous EP1702732-002 ----EP005: Total Organic Carbon 119100 mg/L 13070
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 813574)
Anonymous EP1702727-001 ----EP026SP: Chemical Oxygen Demand 90.747.6 mg/L 13070
EP075(SIM)A: Phenolic Compounds (QCLot: 808929)
Anonymous EP1702744-002 108-95-2EP075(SIM): Phenol 25.210 µg/L 5919
95-57-8EP075(SIM): 2-Chlorophenol 68.610 µg/L 12234
88-75-5EP075(SIM): 2-Nitrophenol 67.510 µg/L 13432
59-50-7EP075(SIM): 4-Chloro-3-methylphenol 75.410 µg/L 11839
87-86-5EP075(SIM): Pentachlorophenol 54.110 µg/L 11818
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 808929)
Anonymous EP1702744-002 83-32-9EP075(SIM): Acenaphthene 75.710 µg/L 12444
129-00-0EP075(SIM): Pyrene 69.610 µg/L 12162
EP080/071: Total Petroleum Hydrocarbons (QCLot: 808930)
Anonymous EP1702744-001 ----EP071: C10 - C14 Fraction 69.2400 µg/L 12245
----EP071: C15 - C28 Fraction 73.0400 µg/L 14355
----EP071: C29 - C36 Fraction 79.0400 µg/L 12854
EP080/071: Total Petroleum Hydrocarbons (QCLot: 810399)
Anonymous EP1702747-002 ----EP080: C6 - C9 Fraction 114240 µg/L 13777
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 808930)
Anonymous EP1702744-001 ----EP071: >C10 - C16 Fraction 69.4400 µg/L 12245
----EP071: >C16 - C34 Fraction 77.6600 µg/L 14355
----EP071: >C34 - C40 Fraction 68.1200 µg/L 12854
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 810399)
Anonymous EP1702747-002 C6_C10EP080: C6 - C10 Fraction 113290 µg/L 13777
EP080: BTEXN (QCLot: 810399)
Anonymous EP1702747-002 71-43-2EP080: Benzene 82.720 µg/L 12277
108-88-3EP080: Toluene 78.120 µg/L 12674
A
True
Environmental
QA/QC Compliance Assessment to assist with Quality ReviewWork Order : EP1702764 Page : 1 of 10
:: LaboratoryClient Environmental Division PerthEMERGE ASSOCIATES
:Contact MR SIMON GREGG Telephone : 08 9209 7631
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 23-Mar-2017
Site : ---- Issue Date : 31-Mar-2017
MITCHELL RITIKIS:Sampler No. of samples received : 5
:Order number ---- No. of samples analysed : 5
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated
reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this
report contribute to the overall DQO assessment and reporting for guideline compliance.
Brief method summaries and references are also provided to assist in traceability.
Summary of Outliers
Outliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.
l NO Duplicate outliers occur.
l NO Laboratory Control outliers occur.
l NO Matrix Spike outliers occur.
l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliance
l Analysis Holding Time Outliers exist - please see following pages for full details.
Outliers : Frequency of Quality Control Samples
l Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Outliers : Analysis Holding Time Compliance
Matrix: WATER
AnalysisExtraction / Preparation
Date analysedDate extractedContainer / Client Sample ID(s) Days
overdue
Days
overdue
Due for extraction Due for analysis
Method
EK057G: Nitrite as N by Discrete Analyser
Clear Plastic Bottle - Natural
23-Mar-2017----MW3, MW5,
GWQA13
24-Mar-2017---- ---- 1
Outliers : Frequency of Quality Control Samples
Matrix: WATER
Quality Control SpecificationQuality Control Sample Type
Method ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC StandardPesticides by GCMS 0.00 10.000 5
NEPM 2013 B3 & ALS QC StandardPolychlorinated Biphenyls (PCB) 0.00 10.000 8
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC StandardPesticides by GCMS 0.00 5.000 5
NEPM 2013 B3 & ALS QC StandardPolychlorinated Biphenyls (PCB) 0.00 5.000 8
NEPM 2013 B3 & ALS QC StandardTotal Metals by ICP-MS - Suite A 0.00 5.000 10
Analysis Holding Time Compliance
Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and
should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.
Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics
14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.
If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.
This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container
provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EA015: Total Dissolved Solids dried at 180 ± 5 °C
Clear Plastic Bottle - Natural (EA015H)
MW3, MW5,
GWQA13
28-Mar-2017---- 28-Mar-2017----21-Mar-2017 ---- ü
Clear Plastic Bottle - Natural (EA015H)
MW2, MW4 29-Mar-2017---- 28-Mar-2017----22-Mar-2017 ---- üED037P: Alkalinity by PC Titrator
Clear Plastic Bottle - Natural (ED037-P)
MW3, MW5,
GWQA13
04-Apr-2017---- 27-Mar-2017----21-Mar-2017 ---- ü
Clear Plastic Bottle - Natural (ED037-P)
MW2, MW4 05-Apr-2017---- 27-Mar-2017----22-Mar-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
ED045G: Chloride by Discrete Analyser
Clear Plastic Bottle - Natural (ED045G)
MW3, MW5,
GWQA13
18-Apr-2017---- 24-Mar-2017----21-Mar-2017 ---- ü
Clear Plastic Bottle - Natural (ED045G)
MW2, MW4 19-Apr-2017---- 24-Mar-2017----22-Mar-2017 ---- üED093F: Dissolved Major Cations
Clear Plastic Bottle - Filtered; Lab-acidified (ED093F)
MW3, MW5,
GWQA13
18-Apr-2017---- 29-Mar-2017----21-Mar-2017 ---- ü
Clear Plastic Bottle - Filtered; Lab-acidified (ED093F)
MW2, MW4 19-Apr-2017---- 29-Mar-2017----22-Mar-2017 ---- üEG020F: Dissolved Metals by ICP-MS
Clear Plastic Bottle - Filtered; Lab-acidified (EG020A-F)
MW3, MW5,
GWQA13
17-Sep-2017---- 29-Mar-2017----21-Mar-2017 ---- ü
Clear Plastic Bottle - Filtered; Lab-acidified (EG020A-F)
MW2, MW4 18-Sep-2017---- 29-Mar-2017----22-Mar-2017 ---- üEG020T: Total Metals by ICP-MS
Clear Plastic Bottle - Unfiltered; Lab-acidified (EG020A-T)
MW3, MW5,
GWQA13
17-Sep-201717-Sep-2017 28-Mar-201728-Mar-201721-Mar-2017 ü ü
Clear Plastic Bottle - Unfiltered; Lab-acidified (EG020A-T)
MW2, MW4 18-Sep-201718-Sep-2017 28-Mar-201728-Mar-201722-Mar-2017 ü üEG035F: Dissolved Mercury by FIMS
Clear Plastic Bottle - Filtered; Lab-acidified (EG035F)
MW3, MW5,
GWQA13
18-Apr-2017---- 29-Mar-2017----21-Mar-2017 ---- ü
Clear Plastic Bottle - Filtered; Lab-acidified (EG035F)
MW2, MW4 19-Apr-2017---- 29-Mar-2017----22-Mar-2017 ---- üEK055G: Ammonia as N by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK055G)
MW3, MW5,
GWQA13
18-Apr-2017---- 24-Mar-2017----21-Mar-2017 ---- ü
Clear Plastic Bottle - Sulfuric Acid (EK055G)
MW2, MW4 19-Apr-2017---- 24-Mar-2017----22-Mar-2017 ---- üEK057G: Nitrite as N by Discrete Analyser
Clear Plastic Bottle - Natural (EK057G)
MW3, MW5,
GWQA13
23-Mar-2017---- 24-Mar-2017----21-Mar-2017 ---- û
Clear Plastic Bottle - Natural (EK057G)
MW2, MW4 24-Mar-2017---- 24-Mar-2017----22-Mar-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK059G)
MW3, MW5,
GWQA13
18-Apr-2017---- 24-Mar-2017----21-Mar-2017 ---- ü
Clear Plastic Bottle - Sulfuric Acid (EK059G)
MW2, MW4 19-Apr-2017---- 24-Mar-2017----22-Mar-2017 ---- üEK061G: Total Kjeldahl Nitrogen By Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK061G)
MW3, MW5,
GWQA13
18-Apr-201718-Apr-2017 28-Mar-201728-Mar-201721-Mar-2017 ü ü
Clear Plastic Bottle - Sulfuric Acid (EK061G)
MW2, MW4 19-Apr-201719-Apr-2017 28-Mar-201728-Mar-201722-Mar-2017 ü üEK067G: Total Phosphorus as P by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK067G)
MW3, MW5,
GWQA13
18-Apr-201718-Apr-2017 28-Mar-201728-Mar-201721-Mar-2017 ü ü
Clear Plastic Bottle - Sulfuric Acid (EK067G)
MW2, MW4 19-Apr-201719-Apr-2017 28-Mar-201728-Mar-201722-Mar-2017 ü üEP005: Total Organic Carbon (TOC)
Amber TOC Vial - Sulfuric Acid (EP005)
MW3, MW5,
GWQA13
18-Apr-2017---- 24-Mar-2017----21-Mar-2017 ---- ü
Amber TOC Vial - Sulfuric Acid (EP005)
MW2, MW4 19-Apr-2017---- 24-Mar-2017----22-Mar-2017 ---- üEP026SP: Chemical Oxygen Demand (Spectrophotometric)
Clear Plastic Bottle - Sulfuric Acid (EP026SP)
MW3, MW5,
GWQA13
18-Apr-2017---- 29-Mar-2017----21-Mar-2017 ---- ü
Clear Plastic Bottle - Sulfuric Acid (EP026SP)
MW2, MW4 19-Apr-2017---- 29-Mar-2017----22-Mar-2017 ---- üEP066: Polychlorinated Biphenyls (PCB)
Amber Glass Bottle - Unpreserved (EP066)
MW3, MW5,
GWQA13
06-May-201728-Mar-2017 27-Mar-201727-Mar-201721-Mar-2017 ü ü
Amber Glass Bottle - Unpreserved (EP066)
MW2, MW4 06-May-201729-Mar-2017 27-Mar-201727-Mar-201722-Mar-2017 ü üEP068A: Organochlorine Pesticides (OC)
Amber Glass Bottle - Unpreserved (EP068)
MW3, MW5,
GWQA13
06-May-201728-Mar-2017 27-Mar-201727-Mar-201721-Mar-2017 ü ü
Amber Glass Bottle - Unpreserved (EP068)
MW2, MW4 06-May-201729-Mar-2017 27-Mar-201727-Mar-201722-Mar-2017 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP075(SIM)A: Phenolic Compounds
Amber Glass Bottle - Unpreserved (EP075(SIM))
MW3, MW5,
GWQA13
06-May-201728-Mar-2017 27-Mar-201727-Mar-201721-Mar-2017 ü ü
Amber Glass Bottle - Unpreserved (EP075(SIM))
MW2, MW4 06-May-201729-Mar-2017 27-Mar-201727-Mar-201722-Mar-2017 ü üEP075(SIM)B: Polynuclear Aromatic Hydrocarbons
Amber Glass Bottle - Unpreserved (EP075(SIM))
MW3, MW5,
GWQA13
06-May-201728-Mar-2017 27-Mar-201727-Mar-201721-Mar-2017 ü ü
Amber Glass Bottle - Unpreserved (EP075(SIM))
MW2, MW4 06-May-201729-Mar-2017 27-Mar-201727-Mar-201722-Mar-2017 ü üEP080/071: Total Petroleum Hydrocarbons
Amber Glass Bottle - Unpreserved (EP071)
MW3, MW5,
GWQA13
06-May-201728-Mar-2017 27-Mar-201727-Mar-201721-Mar-2017 ü ü
Amber Glass Bottle - Unpreserved (EP071)
MW2, MW4 06-May-201729-Mar-2017 27-Mar-201727-Mar-201722-Mar-2017 ü üAmber VOC Vial - Sulfuric Acid (EP080)
MW3, MW5,
GWQA13
04-Apr-201704-Apr-2017 27-Mar-201727-Mar-201721-Mar-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
MW2, MW4 05-Apr-201705-Apr-2017 27-Mar-201727-Mar-201722-Mar-2017 ü üEP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
Amber Glass Bottle - Unpreserved (EP071)
MW3, MW5,
GWQA13
06-May-201728-Mar-2017 27-Mar-201727-Mar-201721-Mar-2017 ü ü
Amber Glass Bottle - Unpreserved (EP071)
MW2, MW4 06-May-201729-Mar-2017 27-Mar-201727-Mar-201722-Mar-2017 ü üAmber VOC Vial - Sulfuric Acid (EP080)
MW3, MW5,
GWQA13
04-Apr-201704-Apr-2017 27-Mar-201727-Mar-201721-Mar-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
MW2, MW4 05-Apr-201705-Apr-2017 27-Mar-201727-Mar-201722-Mar-2017 ü üEP080: BTEXN
Amber VOC Vial - Sulfuric Acid (EP080)
MW3, MW5,
GWQA13
04-Apr-201704-Apr-2017 27-Mar-201727-Mar-201721-Mar-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
MW2, MW4 05-Apr-201705-Apr-2017 27-Mar-201727-Mar-201722-Mar-2017 ü ü
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Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to
the expected rate. A listing of breaches is provided in the Summary of Outliers.
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 13.33 10.002 15 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 14.29 10.002 14 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 10.00 10.003 30 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 12.50 10.002 16 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 14.29 10.001 7 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 5 ûPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 8 ûPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 11.11 10.004 36 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 20.00 10.002 10 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 13.33 10.002 15 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 12.00 10.003 25 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 14.29 10.002 14 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 11.11 10.002 18 üTRH Volatiles/BTEX EP080
Laboratory Control Samples (LCS)
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 6.67 5.002 30 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 12.50 5.001 8 üPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 11.11 10.004 36 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 13.33 10.002 15 üTotal Organic Carbon EP005
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Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Control Samples (LCS) - Continued
NEPM 2013 B3 & ALS QC Standard 8.00 5.002 25 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üTRH Volatiles/BTEX EP080
Method Blanks (MB)
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 6.67 5.002 30 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 12.50 5.001 8 üPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 5.56 5.002 36 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 8.00 5.002 25 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üTRH Volatiles/BTEX EP080
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 6.67 5.002 30 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 5 ûPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 8 ûPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 10 ûTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 8.00 5.002 25 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üTRH Volatiles/BTEX EP080
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EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the
Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 2540C. A gravimetric procedure that determines the amount of `filterable` residue
in an aqueous sample. A well-mixed sample is filtered through a glass fibre filter (1.2um). The filtrate is
evaporated to dryness and dried to constant weight at 180+/-5C. This method is compliant with NEPM (2013)
Schedule B(3)
Total Dissolved Solids (High Level) EA015H WATER
In house: Referenced to APHA 2320 B This procedure determines alkalinity by automated measurement (e.g. PC
Titrate) using pH 4.5 for indicating the total alkalinity end-point. This method is compliant with NEPM (2013)
Schedule B(3)
Alkalinity by PC Titrator ED037-P WATER
In house: Referenced to APHA 4500 Cl - G.The thiocyanate ion is liberated from mercuric thiocyanate through
sequestration of mercury by the chloride ion to form non-ionised mercuric chloride.in the presence of ferric ions
the librated thiocynate forms highly-coloured ferric thiocynate which is measured at 480 nm APHA 21st edition
seal method 2 017-1-L april 2003
Chloride by Discrete Analyser ED045G WATER
In house: Referenced to APHA 3120 and 3125; USEPA SW 846 - 6010 and 6020; Cations are determined by
either ICP-AES or ICP-MS techniques. This method is compliant with NEPM (2013) Schedule B(3)
Sodium Adsorption Ratio is calculated from Ca, Mg and Na which determined by ALS in house method
QWI-EN/ED093F. This method is compliant with NEPM (2013) Schedule B(3)
Hardness parameters are calculated based on APHA 2340 B. This method is compliant with NEPM (2013)
Schedule B(3)
Major Cations - Dissolved ED093F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. Samples are 0.45µm filtered
prior to analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions
are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct
mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Dissolved Metals by ICP-MS - Suite A EG020A-F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. The ICPMS technique utilizes
a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass
spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their
measurement by a discrete dynode ion detector.
Total Metals by ICP-MS - Suite A EG020A-T WATER
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS)
Samples are 0.45µm filtered prior to analysis. FIM-AAS is an automated flameless atomic absorption technique.
A bromate/bromide reagent is used to oxidise any organic mercury compounds in the filtered sample. The ionic
mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell.
Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM
(2013) Schedule B(3)
Dissolved Mercury by FIMS EG035F WATER
In house: Referenced to APHA 4500-NH3 G Ammonia is determined by direct colorimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Ammonia as N by Discrete analyser EK055G WATER
In house: Referenced to APHA 4500-NO2- B. Nitrite is determined by direct colourimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Nitrite as N by Discrete Analyser EK057G WATER
A
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Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500-NO3- F. Nitrate is reduced to nitrite by way of a chemical reduction followed
by quantification by Discrete Analyser. Nitrite is determined seperately by direct colourimetry and result for Nitrate
calculated as the difference between the two results. This method is compliant with NEPM (2013) Schedule B(3)
Nitrate as N by Discrete Analyser EK058G WATER
In house: Referenced to APHA 4500-NO3- F. Combined oxidised Nitrogen (NO2+NO3) is determined by
Chemical Reduction and direct colourimetry by Discrete Analyser. This method is compliant with NEPM (2013)
Schedule B(3)
Nitrite and Nitrate as N (NOx) by Discrete
Analyser
EK059G WATER
In house: Referenced to APHA 4500-Norg D (In house). An aliquot of sample is digested using a high
temperature Kjeldahl digestion to convert nitrogenous compounds to ammonia. Ammonia is determined
colorimetrically by discrete analyser. This method is compliant with NEPM (2013) Schedule B(3)
Total Kjeldahl Nitrogen as N By Discrete
Analyser
EK061G WATER
In house: Referenced to APHA 4500-Norg / 4500-NO3-. This method is compliant with NEPM (2013) Schedule
B(3)
Total Nitrogen as N (TKN + Nox) By
Discrete Analyser
EK062G WATER
In house: Referenced to APHA 4500-P H, Jirka et al (1976), Zhang et al (2006). This procedure involves
sulphuric acid digestion of a sample aliquot to break phosphorus down to orthophosphate. The orthophosphate
reacts with ammonium molybdate and antimony potassium tartrate to form a complex which is then reduced and
its concentration measured at 880nm using discrete analyser. This method is compliant with NEPM (2013)
Schedule B(3)
Total Phosphorus as P By Discrete
Analyser
EK067G WATER
In house: Referenced to APHA 5310 B, The automated TOC analyzer determines Total and Inorganic Carbon by
IR cell. TOC is calculated as the difference. This method is compliant with NEPM (2013) Schedule B(3)
Total Organic Carbon EP005 WATER
In house: Referenced to APHA 5220 D. Samples are digested with a known excess of an acidic potassium
dichromate solution using silver sulfate as a catalyst. The chromium is reduced from the Cr (VI) oxidation state
to the Cr (III) state by the oxygen present in the organic material. Both of these chromium species are coloued
and absorb in the visible region of (400nm & 600nm) the spectrum. The oxidisable organic matter can be
calculated in terms of oxygen equivalents.
Chemical Oxygen Demand (COD)
(Spectrophotometric)
EP026SP WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS and
quantification is by comparison against an established 5 point calibration curve. This method is compliant with
NEPM (2013) Schedule B(3)
Polychlorinated Biphenyls (PCB) EP066 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS and
quantification is by comparison against an established 5 point calibration curve. This method is compliant with
NEPM (2013) Schedule B(3)
Pesticides by GCMS EP068 WATER
In house: Referenced to USEPA SW 846 - 8015A The sample extract is analysed by Capillary GC/FID and
quantification is by comparison against an established 5 point calibration curve of n-Alkane standards. This
method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH - Semivolatile Fraction EP071 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS in SIM Mode
and quantification is by comparison against an established 5 point calibration curve. This method is compliant
with NEPM (2013) Schedule B(3)
PAH/Phenols (GC/MS - SIM) EP075(SIM) WATER
In house: Referenced to USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by
Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve.
Alternatively, a sample is equilibrated in a headspace vial and a portion of the headspace determined by GCMS
analysis. This method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH Volatiles/BTEX EP080 WATER
Preparation Methods Method DescriptionsMatrixMethod
A
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EP1702764
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Preparation Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 Norg - D; APHA 4500 P - H. This method is compliant with NEPM (2013)
Schedule B(3)
TKN/TP Digestion EK061/EK067 WATER
In house: Referenced to USEPA SW846-3005. Method 3005 is a Nitric/Hydrochloric acid digestion procedure
used to prepare surface and ground water samples for analysis by ICPAES or ICPMS. This method is compliant
with NEPM (2013) Schedule B(3)
Digestion for Total Recoverable Metals EN25 WATER
In house: Referenced to USEPA SW 846 - 3510B 100 mL to 1L of sample is transferred to a separatory funnel
and serially extracted three times using 60mL DCM for each extract. The resultant extracts are combined,
dehydrated and concentrated for analysis. This method is compliant with NEPM (2013) Schedule B(3) . ALS
default excludes sediment which may be resident in the container.
Separatory Funnel Extraction of Liquids ORG14 WATER
A 5 mL aliquot or 5 mL of a diluted sample is added to a 40 mL VOC vial for sparging.Volatiles Water Preparation ORG16-W WATER
A
CHAIN OF CUSTODY c'!UEilT: Emerge Associates
PROJECT MANAGER: Simon Gregg
PROJECT ID.: EP15-050(05)
SAMPLER(S): Mitchell Ritikis
QUOTE NO.: EP/009116 ORDER NO.:
SAMPLE DETAILS
Lab ID Sample ID Matrix
l GWQA-14 Water
POSTAL AODRESS: Suite 4, 26 Railway Road, Subiaco WA 6008
CONTACT PHONE: 9380 4988
PROJECT NAME: SAMR Monitoring - Davis Road
SAMPLERS PHONE: 0449 198 721
Date
21/03/17
Comments/special handling/storage or disposal
Please forward to SYDNEY ALS Please note short holding time for some analysis.
CONTAINER INFORMATION
Type & Preservative
2 SP, 3VS, 1P, 2AP, 1AG
Total No.
9
~m~rgal r.:t,~1-.:r2n ;:,,:!tf".£.~ .!. D~-s,,u1
Email invoice to: accounts@emergeassociates.com.au
ANALYSIS REQUIRED
w I I ~2
r ~-~ ~
<O Cl. Ill 2-'-'-'-' " $ -zu. <= rn-Ix- ro::t:: It) O'.'.w'-' "'"-!::..1-Q 'E Cl)~ ,._ "' U) "' "' 0:, ..... 0 J ~-~£ :i:" 0 oz Z2W
X X
H Additional information (likely contaminants, dilutions or specific QC -analysis)
Mislabelled "SPLIT1"
Please log as per COG
Environmental Divisic-n Sydney
, .. - ...... ~ , ·+-----+-----,f---+----t---+----t~ Work Order Reference
1=S1707191
111111!11111 Telephone : + 61-2-8784 8556
RELINQUISHED BY: RECEIVED BY CoC emailed to ALS?
I NAME: Mitchell Ritikis DATE: 23/03/2017 I NAME: ,Nif DATE: '!r/'f/)?- I IS] Yes □ No 11
OF: EmerQe Associates TIME: 11 :45 OF: TIME: J'Z: NAME: DATE: I NAME: DATE: Water Container Codes: P = Unpreserved Plastic; N = Nitric Preserved Plastic; ORC = Nitric Preserved ORC; SH = Sodium Hydroxide/Cd Preserved; S = Sodium Hydroxide Preserved Plastic; AG = Amber Glass Unpreserved; AP = Airtreight Unpreserved Plastic; V = VOA Vial HCI Preserved; VB= VOA Vial Sodium Bisulphate Preserved; VS= VOA Vial Sulfuric Preserved; AV= Airfreight Unpreserved Vial; SG = Sulfuric Preserved Amber Glass; H = HCl preserved Plastic; HS= HCI Preserved Speciation bottle; SP= Sulfuric Preserved Plastic; F = Formaldehyde Preserved Glass; Z = Zinc Acetate Preserved Bottle; E = EDTA Preserved Bottles; ST= Sterile Bottle; LI= Lugols Iodine Preserved Bottles; STT = Sterile' Sodium Thios~ate Preserved Bottles. Soil Container Codes: J = Jar; ASS = Plastic Bag for Acid Sulfate Soils; B = Unpreserved Bag;
Helen Simpson
From: Sent:
Jeremy Payet <jeremy.payet@emergeassociates.com.au> Monday, 27 March 2017 2:21 PM
To: Helen Simpson Subject: Sample GWQA-14 analysis
Hi Helen,
Thanks for bringing this issue to my attention. I have had a look at the EP-683-15 quote and it looks like we will need to conduct analysis of all analytes for groundwater sample GWQA-14.
Let me know if you need me to send through a revised CoC.
Kind regards
Jeremy
Jeremy Payet Environmental Consultant -Contaminated Land & Acid Sulfate Soils e jeremy.payet@emergeassociates.com.au Suite 4, 26 Railway Road, Subiaco WA 6008 w emergeassociates.com.au II t +618 9380 4988 II f +618 9380 9636
Recent recipients of;
201G UDi/\ W/\ Rlisse!I Perry u,·ban Deveiopment Excellence Award, Osprey Waters for Mirvac.
2(.116 UDIA WA Env1ronrnental EHt.ellenno Award, Osprey Waters for Mirvac. 2016 UD1/\ W/\ Rising Star Award, Northlink Industrial for Uric f)ropetty
2016 UDIA WA Residential Developriwnt under 250 lots Award, Fliza Pon Os for GWF. 2016 UDIA Wf-\ Master p!3nned Deveiopment Award, Vale tar Stockland
2016 UDI/.\ W/1 ::r1v1ro Development Chairman's Choice, Alkimos Beach for Lend Lease
2.015 AILA WA State Award for Parks and Open Space, Braithwaite Park Nat t,1 e Play for City of VmcenL 2016 AllA National Aw,,i-d For Parks and Open Space, Braithwaite Park Nature Play for City of Vincent.
ALS Group: Click here to report this email as spam.
1
Tailored Analytical Services & Charges - Waters ~1t,.~'".,l;w~'<'.}•''·"'c'." .' . .!: ,: '''ii : ';\, ,:",',. "'i'i:r ' ''•"'',2:,;,:i.;g~·--.--. ~1-' t?~v~ ,-~,;,",,,' ."' ,ii;ifii,,tl·i,• :::1 " ltft~~ "'"*s-~_,,~·~1•"'1\J='; '><:, ~~~, "•~-"ifij "t , ~Z'.{ %1" ~~ ~ ;-~ <" '"'' Ute" zffit: , ~~z~ii:,,,,, "",:,,~r.;.~.-: ·.', '1: " . ' ;~~, \I.\ e ' . Jrel~en~, ' ~or1s lllf~ate,\;f: , Siffl'l•,i':,"': '• i; §to:.,M; ,;;'.i)§;JJ¥,.1'.,,.~t_j:'s,1\:,\fYtr;,".;;,J;:~~i¾lf"'"':...,.J, ,,c,,:~ , ~,,""'' -c ~~ , - ~' ,;i'> ,~~ ' _,§ •~ ~ "-""' c~ •""" • 1/''•~t.l\'
Total Dissolved Solids (TDS)- Std EA015H APHA 2540 C l 0 9.00
Major Cations: Ca, Mg, Na, K NT-1 APHA 3120 l l 0.00
Major Anions: Cl, SO,, Alkalinity NT-2 Various l 16.00
APHA 4500 NH,- H
Total Nitrogen, TKN, NOx, NO,.NO, NH, NT-8 APHA 4500 Noc,/NO, 0.01 54.00
Total Phosphorus APHA 4500 P - H TN: 0.1
APHA 4500 P - G
Chemical Oxygen Demand (COD) EP026SP APHA 5220 B 5 24.00
Carbon - Total Organic (TOC) EP00S APHA5310B l 24.00
8 Metals - Dissolved Cd:0.0001
USEPA 6020, ICP/MS Zn:0.005 (As, Cd, Cr, Cu, Ni, Pb, Zn) W-2F Others: 0.001 22.00
Hg CV /Fl MS/ICP /MS 0.0001
Additional Dissolved Metals by ICPMS -EG020F USEPA 6020 ICPMS 0.0001 - 0.01 6.00
Al, Mn, Se '
Total Recoverable Metals by ICPMS (incl EG020T USEPA 6020 ICPMS 0.0001 - 0.01 12.00 digest) - Fe
Total sample cost for water samples (Ex:GSTI: , ' ' ,, ·,
177.00 '• ., '. ----. -· · .. '
,,,, __ ._ ,' ·- .. ·, ' ,' ·' ·,_ ·'
General ALS Service Inclusions
The ALS service includes the following at no extra charge;
• Provision of sample containers, appropriately prepared, labelled and preserved, eskies and freight for primary analytical test-work in major metropolitan areas Bottle Order Form
• ALS COC protocols including receipt notification and advice of any non-conformances plus a rapid advice of ALS batch/tracking numbers.
• Webtrieve™ access to real time results and ALS technical support. WebtrieveTM EnviroMail™ • Local technical support via the ALS technical and management team Perth Contact List
• Electronics results including COA, QC and DQO reports plus tailored formats such as ESDAT, EQulS and many others. EDDs - EOUJS and ESDAT info & support
Quality, Sampling, Submission, Holding Times and Automated DQO Reporting
ALS has a comprehensive best practice QA/QC program designed to provide highly defensible analytical data in accordance with NEPM, ANZECC, ADWG, NAGD guidelines. ALS provides Laboratory Control Samples (LCS), Method Blanks (MB), Matrix Spikes (MS), Laboratory Duplicates (Dups) and Surrogates (where applicable), at frequencies at or above the NEPM guidelines - revised 2013. Should you require further details please contact ALS customer services.
• ALS is NATA accredited for all tests listed in this proposal unless advised otherwise.
• For further information on short holding times please see: ALS Environmental - Pocket Guide 2014
• ALS QA/QC is reliant upon appropriate replicate samples bottles/volumes especially for waters, air filters and sorbents. High contamination may negate ALS reporting of matrix spike recovery data.
• Please advise via COC where additional sample has been provided for QA/QC purposes e.g. by noting "Lab QC' (for both Dup and MS) or "Lab Dup" or "Lab MS".
• QA/QC, holding times, QC frequency and preservation compliance are summarised in ALS DQO reports to assist in quality review.
Quote EP/6.44/1 ~·~-~erge 4th September 2015 Page 2 of 5
RIGHT SOLUTIONS J RIGHT PARTNER
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 8ES1707191
:: LaboratoryClient EMERGE ASSOCIATES Environmental Division Sydney
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
277-289 Woodpark Road Smithfield NSW Australia 2164
:Telephone +61 08 9380 4988 :Telephone 08 9209 7631
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 27-Mar-2017 12:15
:Order number ---- Date Analysis Commenced : 27-Mar-2017
:C-O-C number ---- Issue Date : 03-Apr-2017 09:17
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EP/683/15
1:No. of samples received
1:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:
l General Comments
l Analytical Results
l Surrogate Control Limits
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with
Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Dilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VIC
Edwandy Fadjar Organic Coordinator Sydney Organics, Smithfield, NSW
Raymond Commodore Instrument Chemist Sydney Inorganics, Smithfield, NSW
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with 1S0/IEC 17025 - Testing
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EMERGE ASSOCIATES
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When no sampling time is provided, the sampling time will default 00:00 on the date of sampling. If no sampling date is provided, the sampling date will be assumed by the laboratory and displayed in brackets without a
time component.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
^ = This result is computed from individual analyte detections at or above the level of reporting
ø = ALS is not NATA accredited for these tests.
~ = Indicates an estimated value.
Key :
Benzo(a)pyrene Toxicity Equivalent Quotient (TEQ) is the sum total of the concentration of the eight carcinogenic PAHs multiplied by their Toxicity Equivalence Factor (TEF) relative to Benzo(a)pyrene. TEF values
are provided in brackets as follows: Benz(a)anthracene (0.1), Chrysene (0.01), Benzo(b+j) & Benzo(k)fluoranthene (0.1), Benzo(a)pyrene (1.0), Indeno(1.2.3.cd)pyrene (0.1), Dibenz(a.h)anthracene (1.0),
Benzo(g.h.i)perylene (0.01). Less than LOR results for 'TEQ Zero' are treated as zero.
l
A
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Analytical Results
----------------GWQA-14Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------21-Mar-2017 00:00Client sampling date / time
--------------------------------ES1707191-001UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EA015: Total Dissolved Solids dried at 180 ± 5 °C
591 ---- ---- ---- ----mg/L10----Total Dissolved Solids @180°C
ED037P: Alkalinity by PC Titrator
<1Hydroxide Alkalinity as CaCO3 ---- ---- ---- ----mg/L1DMO-210-001
<1Carbonate Alkalinity as CaCO3 ---- ---- ---- ----mg/L13812-32-6
<1Bicarbonate Alkalinity as CaCO3 ---- ---- ---- ----mg/L171-52-3
<1 ---- ---- ---- ----mg/L1----Total Alkalinity as CaCO3
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
90Sulfate as SO4 - Turbidimetric ---- ---- ---- ----mg/L114808-79-8
ED045G: Chloride by Discrete Analyser
302Chloride ---- ---- ---- ----mg/L116887-00-6
ED093F: Dissolved Major Cations
1Calcium ---- ---- ---- ----mg/L17440-70-2
15Magnesium ---- ---- ---- ----mg/L17439-95-4
174Sodium ---- ---- ---- ----mg/L17440-23-5
2Potassium ---- ---- ---- ----mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS
4.45Aluminium ---- ---- ---- ----mg/L0.017429-90-5
<0.001Arsenic ---- ---- ---- ----mg/L0.0017440-38-2
<0.0001Cadmium ---- ---- ---- ----mg/L0.00017440-43-9
<0.001Chromium ---- ---- ---- ----mg/L0.0017440-47-3
0.003Copper ---- ---- ---- ----mg/L0.0017440-50-8
<0.001Nickel ---- ---- ---- ----mg/L0.0017440-02-0
<0.001Lead ---- ---- ---- ----mg/L0.0017439-92-1
0.017Zinc ---- ---- ---- ----mg/L0.0057440-66-6
0.871Manganese ---- ---- ---- ----mg/L0.0017439-96-5
<0.01Selenium ---- ---- ---- ----mg/L0.017782-49-2
EG020T: Total Metals by ICP-MS
43.8Iron ---- ---- ---- ----mg/L0.057439-89-6
EG035F: Dissolved Mercury by FIMS
<0.0001Mercury ---- ---- ---- ----mg/L0.00017439-97-6
EK055G: Ammonia as N by Discrete Analyser
0.13Ammonia as N ---- ---- ---- ----mg/L0.017664-41-7
EK057G: Nitrite as N by Discrete Analyser
<0.01Nitrite as N ---- ---- ---- ----mg/L0.0114797-65-0
A
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Analytical Results
----------------GWQA-14Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------21-Mar-2017 00:00Client sampling date / time
--------------------------------ES1707191-001UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EK058G: Nitrate as N by Discrete Analyser
0.03Nitrate as N ---- ---- ---- ----mg/L0.0114797-55-8
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
0.03 ---- ---- ---- ----mg/L0.01----Nitrite + Nitrate as N
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser
0.7 ---- ---- ---- ----mg/L0.1----Total Kjeldahl Nitrogen as N
EK062G: Total Nitrogen as N (TKN + NOx) by Discrete Analyser
0.7^ ---- ---- ---- ----mg/L0.1----Total Nitrogen as N
EK067G: Total Phosphorus as P by Discrete Analyser
0.18 ---- ---- ---- ----mg/L0.01----Total Phosphorus as P
EP005: Total Organic Carbon (TOC)
4 ---- ---- ---- ----mg/L1----Total Organic Carbon
EP026SP: Chemical Oxygen Demand (Spectrophotometric)
12 ---- ---- ---- ----mg/L10----Chemical Oxygen Demand
EP066: Polychlorinated Biphenyls (PCB)
<1 ---- ---- ---- ----µg/L1----Total Polychlorinated biphenyls
EP068A: Organochlorine Pesticides (OC)
<0.5alpha-BHC ---- ---- ---- ----µg/L0.5319-84-6
<0.5Hexachlorobenzene (HCB) ---- ---- ---- ----µg/L0.5118-74-1
<0.5beta-BHC ---- ---- ---- ----µg/L0.5319-85-7
<0.5gamma-BHC ---- ---- ---- ----µg/L0.558-89-9
<0.5delta-BHC ---- ---- ---- ----µg/L0.5319-86-8
<0.5Heptachlor ---- ---- ---- ----µg/L0.576-44-8
<0.5Aldrin ---- ---- ---- ----µg/L0.5309-00-2
<0.5Heptachlor epoxide ---- ---- ---- ----µg/L0.51024-57-3
<0.5trans-Chlordane ---- ---- ---- ----µg/L0.55103-74-2
<0.5alpha-Endosulfan ---- ---- ---- ----µg/L0.5959-98-8
<0.5cis-Chlordane ---- ---- ---- ----µg/L0.55103-71-9
<0.5Dieldrin ---- ---- ---- ----µg/L0.560-57-1
<0.54.4`-DDE ---- ---- ---- ----µg/L0.572-55-9
<0.5Endrin ---- ---- ---- ----µg/L0.572-20-8
<0.5beta-Endosulfan ---- ---- ---- ----µg/L0.533213-65-9
<0.54.4`-DDD ---- ---- ---- ----µg/L0.572-54-8
<0.5Endrin aldehyde ---- ---- ---- ----µg/L0.57421-93-4
<0.5Endosulfan sulfate ---- ---- ---- ----µg/L0.51031-07-8
A
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:Client
ES1707191
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
----------------GWQA-14Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------21-Mar-2017 00:00Client sampling date / time
--------------------------------ES1707191-001UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EP068A: Organochlorine Pesticides (OC) - Continued
<2.04.4`-DDT ---- ---- ---- ----µg/L250-29-3
<0.5Endrin ketone ---- ---- ---- ----µg/L0.553494-70-5
<2.0Methoxychlor ---- ---- ---- ----µg/L272-43-5
<0.5^ ---- ---- ---- ----µg/L0.5----Total Chlordane (sum)
<0.5^ Sum of DDD + DDE + DDT ---- ---- ---- ----µg/L0.572-54-8/72-55-9/5
0-2
<0.5^ Sum of Aldrin + Dieldrin ---- ---- ---- ----µg/L0.5309-00-2/60-57-1
EP075(SIM)A: Phenolic Compounds
<1.0Phenol ---- ---- ---- ----µg/L1108-95-2
<1.02-Chlorophenol ---- ---- ---- ----µg/L195-57-8
<1.02-Methylphenol ---- ---- ---- ----µg/L195-48-7
<2.03- & 4-Methylphenol ---- ---- ---- ----µg/L21319-77-3
<1.02-Nitrophenol ---- ---- ---- ----µg/L188-75-5
<1.02.4-Dimethylphenol ---- ---- ---- ----µg/L1105-67-9
<1.02.4-Dichlorophenol ---- ---- ---- ----µg/L1120-83-2
<1.02.6-Dichlorophenol ---- ---- ---- ----µg/L187-65-0
<1.04-Chloro-3-methylphenol ---- ---- ---- ----µg/L159-50-7
<1.02.4.6-Trichlorophenol ---- ---- ---- ----µg/L188-06-2
<1.02.4.5-Trichlorophenol ---- ---- ---- ----µg/L195-95-4
<2.0Pentachlorophenol ---- ---- ---- ----µg/L287-86-5
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
<1.0Naphthalene ---- ---- ---- ----µg/L191-20-3
<1.0Acenaphthylene ---- ---- ---- ----µg/L1208-96-8
<1.0Acenaphthene ---- ---- ---- ----µg/L183-32-9
<1.0Fluorene ---- ---- ---- ----µg/L186-73-7
<1.0Phenanthrene ---- ---- ---- ----µg/L185-01-8
<1.0Anthracene ---- ---- ---- ----µg/L1120-12-7
<1.0Fluoranthene ---- ---- ---- ----µg/L1206-44-0
<1.0Pyrene ---- ---- ---- ----µg/L1129-00-0
<1.0Benz(a)anthracene ---- ---- ---- ----µg/L156-55-3
<1.0Chrysene ---- ---- ---- ----µg/L1218-01-9
<1.0Benzo(b+j)fluoranthene ---- ---- ---- ----µg/L1205-99-2 205-82-3
<1.0Benzo(k)fluoranthene ---- ---- ---- ----µg/L1207-08-9
<0.5Benzo(a)pyrene ---- ---- ---- ----µg/L0.550-32-8
<1.0Indeno(1.2.3.cd)pyrene ---- ---- ---- ----µg/L1193-39-5
A
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:Client
ES1707191
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
----------------GWQA-14Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------21-Mar-2017 00:00Client sampling date / time
--------------------------------ES1707191-001UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued
<1.0Dibenz(a.h)anthracene ---- ---- ---- ----µg/L153-70-3
<1.0Benzo(g.h.i)perylene ---- ---- ---- ----µg/L1191-24-2
<0.5^ ---- ---- ---- ----µg/L0.5----Sum of polycyclic aromatic hydrocarbons
<0.5^ ---- ---- ---- ----µg/L0.5----Benzo(a)pyrene TEQ (zero)
EP080/071: Total Petroleum Hydrocarbons
<20 ---- ---- ---- ----µg/L20----C6 - C9 Fraction
<50 ---- ---- ---- ----µg/L50----C10 - C14 Fraction
<100 ---- ---- ---- ----µg/L100----C15 - C28 Fraction
<50 ---- ---- ---- ----µg/L50----C29 - C36 Fraction
<50^ ---- ---- ---- ----µg/L50----C10 - C36 Fraction (sum)
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
<20C6 - C10 Fraction ---- ---- ---- ----µg/L20C6_C10
<20^ C6 - C10 Fraction minus BTEX
(F1)
---- ---- ---- ----µg/L20C6_C10-BTEX
<100 ---- ---- ---- ----µg/L100---->C10 - C16 Fraction
<100 ---- ---- ---- ----µg/L100---->C16 - C34 Fraction
<100 ---- ---- ---- ----µg/L100---->C34 - C40 Fraction
<100^ ---- ---- ---- ----µg/L100---->C10 - C40 Fraction (sum)
<100^ ---- ---- ---- ----µg/L100---->C10 - C16 Fraction minus Naphthalene
(F2)
EP080: BTEXN
<1Benzene ---- ---- ---- ----µg/L171-43-2
<2Toluene ---- ---- ---- ----µg/L2108-88-3
<2Ethylbenzene ---- ---- ---- ----µg/L2100-41-4
<2meta- & para-Xylene ---- ---- ---- ----µg/L2108-38-3 106-42-3
<2ortho-Xylene ---- ---- ---- ----µg/L295-47-6
<2^ Total Xylenes ---- ---- ---- ----µg/L21330-20-7
<1^ ---- ---- ---- ----µg/L1----Sum of BTEX
<5Naphthalene ---- ---- ---- ----µg/L591-20-3
EP066S: PCB Surrogate
91.9Decachlorobiphenyl ---- ---- ---- ----%12051-24-3
EP068S: Organochlorine Pesticide Surrogate
72.9Dibromo-DDE ---- ---- ---- ----%0.521655-73-2
EP068T: Organophosphorus Pesticide Surrogate
A
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:Client
ES1707191
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
----------------GWQA-14Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------21-Mar-2017 00:00Client sampling date / time
--------------------------------ES1707191-001UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EP068T: Organophosphorus Pesticide Surrogate - Continued
73.9DEF ---- ---- ---- ----%0.578-48-8
EP075(SIM)S: Phenolic Compound Surrogates
15.6Phenol-d6 ---- ---- ---- ----%113127-88-3
38.82-Chlorophenol-D4 ---- ---- ---- ----%193951-73-6
86.02.4.6-Tribromophenol ---- ---- ---- ----%1118-79-6
EP075(SIM)T: PAH Surrogates
68.72-Fluorobiphenyl ---- ---- ---- ----%1321-60-8
55.5Anthracene-d10 ---- ---- ---- ----%11719-06-8
76.34-Terphenyl-d14 ---- ---- ---- ----%11718-51-0
EP080S: TPH(V)/BTEX Surrogates
1071.2-Dichloroethane-D4 ---- ---- ---- ----%217060-07-0
101Toluene-D8 ---- ---- ---- ----%22037-26-5
1074-Bromofluorobenzene ---- ---- ---- ----%2460-00-4
A
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:Client
ES1707191
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Surrogate Control Limits
Recovery Limits (%)Sub-Matrix: WATER
Compound CAS Number Low High
EP066S: PCB Surrogate
Decachlorobiphenyl 2051-24-3 29 129
EP068S: Organochlorine Pesticide Surrogate
Dibromo-DDE 21655-73-2 30 120
EP068T: Organophosphorus Pesticide Surrogate
DEF 78-48-8 27 129
EP075(SIM)S: Phenolic Compound Surrogates
Phenol-d6 13127-88-3 10 44
2-Chlorophenol-D4 93951-73-6 14 94
2.4.6-Tribromophenol 118-79-6 17 125
EP075(SIM)T: PAH Surrogates
2-Fluorobiphenyl 321-60-8 20 104
Anthracene-d10 1719-06-8 27 113
4-Terphenyl-d14 1718-51-0 32 112
EP080S: TPH(V)/BTEX Surrogates
1.2-Dichloroethane-D4 17060-07-0 71 137
Toluene-D8 2037-26-5 79 131
4-Bromofluorobenzene 460-00-4 70 128
A
Environmental
SAMPLE RECEIPT NOTIFICATION (SRN)Work Order : ES1707191
:: LaboratoryClient Environmental Division SydneyEMERGE ASSOCIATES
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA
6008
277-289 Woodpark Road Smithfield
NSW Australia 2164
:: E-mailE-mail simon.gregg@emergeassociates.co
m.au
LUKE.JONES@alsglobal.com
:: TelephoneTelephone +61 08 9380 4988 08 9209 7631
:: FacsimileFacsimile +61 08 9380 9636 +61-2-8784 8500
::Project EP15-050(05) SAMR Monitoring -
Davis Road
Page 1 of 3
:Order number ---- :Quote number EP2015EMEASS0045 (EP/683/15)
:C-O-C number ---- :QC Level NEPM 2013 B3 & ALS QC Standard
Site : ----
Sampler : MITCHELL RITIKIS
DatesDate Samples Received : Issue Date : 27-Mar-201727-Mar-2017 12:15
Scheduled Reporting Date: 31-Mar-2017:Client Requested Due
Date
31-Mar-2017
Delivery DetailsMode of Delivery : :Undefined Not AvailableSecurity Seal
No. of coolers/boxes : :1 Temperature 17.5'C - Ice present
: : 1 / 1Receipt Detail No. of samples received / analysed
General Comments
This report contains the following information:l
- Sample Container(s)/Preservation Non-Compliances
- Summary of Sample(s) and Requested Analysis
- Proactive Holding Time Report
- Requested Deliverables
l Please refer to the Proactive Holding Time Report table below which summarises breaches of
recommended holding times that have occurred prior to samples/instructions being received at
the laboratory. The absence of this summary table indicates that all samples have been received
within the recommended holding times for the analysis requested.l TOC Analysis to be conducted by ALS MELBOURNE
l Please direct any queries you have regarding this work order to the above ALS laboratory contact.
l Analytical work for this work order will be conducted at ALS Sydney.
l Sample Disposal - Aqueous (14 days), Solid (60 days) from date of completion of work order.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
:Client EMERGE ASSOCIATES
Work Order : ES1707191 Amendment 02 of 3:Page
27-Mar-2017:Issue Date
Sample Container(s)/Preservation Non-Compliances
All comparisons are made against pretreatment/preservation AS, APHA, USEPA standards.
l No sample container / preservation non-compliance exists.
Summary of Sample(s) and Requested Analysis
Some items described below may be part of a laboratory
process necessary for the execution of client requested
tasks. Packages may contain additional analyses, such
as the determination of moisture content and preparation
tasks, that are included in the package.
If no sampling time is provided, the sampling time will
default 00:00 on the date of sampling. If no sampling date
is provided, the sampling date will be assumed by the
laboratory and displayed in brackets without a time
component
WA
TE
R -
EG
020F
Dis
solv
ed M
eta
ls b
y IC
PM
S
WA
TE
R -
EP
026S
P
Chem
ical O
xygen D
em
and (
CO
D)
WA
TE
R -
NT
-01
Majo
r C
atio
ns
(Ca, M
g, N
a, K
)
WA
TE
R -
NT
-02
Majo
r A
nio
ns
(Chlo
ride, S
ulp
hate
, A
lkalin
ity)
WA
TE
R -
NT
-08
Tota
l Nitr
ogen +
NO
2 +
NO
3 +
NH
3 +
Tota
l P
WA
TE
R -
W-0
2
8 M
eta
ls
WA
TE
R -
W-1
7
TR
H/B
TE
XN
/PA
H/P
henols
/OC
/PC
B
ES1707191-001 21-Mar-2017 00:00 GWQA-14 ü ü ü ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
WA
TE
R -
EA
01
5H
To
tal D
isso
lve
d S
olid
s -
Hig
h L
eve
l
WA
TE
R -
EG
02
0T
To
tal R
eco
vera
ble
Me
tals
by
ICP
MS
(in
clu
din
g
WA
TE
R -
EP
00
5
To
tal O
rga
nic
Ca
rbo
n (
TO
C)
ES1707191-001 21-Mar-2017 00:00 GWQA-14 ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
Proactive Holding Time Report
The following table summarises breaches of recommended holding times that have occurred prior to samples/instructions being
received at the laboratory.
Evaluation: û = Holding time breach ; ü = Within holding time. Matrix: WATER
EvaluationClient Sample ID(s)
Due for
extraction
Due for
analysis Evaluation
Samples Received Instructions Received
Date Date
Method
Container
EK057G: Nitrite as N by Discrete Analyser
GWQA-14 û --------27-Mar-201723-Mar-2017----Clear Plastic Bottle - Natural
I I I
I I I
: ! :
:Client EMERGE ASSOCIATES
Work Order : ES1707191 Amendment 03 of 3:Page
27-Mar-2017:Issue Date
Requested Deliverables
ACCOUNTS (INVOICES)
- A4 - AU Tax Invoice (INV) Email accounts@emergeassociates.com.
au
JEREMY PAYET
- *AU Certificate of Analysis - NATA (COA) Email jeremy.payet@emergeassociates.co
m.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email jeremy.payet@emergeassociates.co
m.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email jeremy.payet@emergeassociates.co
m.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email jeremy.payet@emergeassociates.co
m.au
- Chain of Custody (CoC) (COC) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - ENMRG (ENMRG) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - ESDAT (ESDAT) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - XTab (XTAB) Email jeremy.payet@emergeassociates.co
m.au
MITCHELL RITIKIS
- *AU Certificate of Analysis - NATA (COA) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email mitchell.ritikis@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email mitchell.ritikis@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - ENMRG (ENMRG) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email mitchell.ritikis@emergeassociates.c
om.au
SIMON GREGG
- *AU Certificate of Analysis - NATA (COA) Email simon.gregg@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email simon.gregg@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email simon.gregg@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email simon.gregg@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - ENMRG (ENMRG) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email simon.gregg@emergeassociates.c
om.au
False
4 4.00True
Environmental
QUALITY CONTROL REPORTWork Order : ES1707191 Page : 1 of 9
:: LaboratoryClient Environmental Division SydneyEMERGE ASSOCIATES
:Contact MR SIMON GREGG :Contact Luke Jones
:Address SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
Address : 277-289 Woodpark Road Smithfield NSW Australia 2164
::Telephone +61 08 9380 4988 08 9209 7631:Telephone
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 27-Mar-2017
:Order number ---- Date Analysis Commenced : 27-Mar-2017
:C-O-C number ---- Issue Date : 03-Apr-2017
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EP/683/15
No. of samples received 1:
No. of samples analysed 1:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limits
l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits
l Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Dilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VIC
Edwandy Fadjar Organic Coordinator Sydney Organics, Smithfield, NSW
Raymond Commodore Instrument Chemist Sydney Inorganics, Smithfield, NSW
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with 150/IEC 17025 - Testing
2 of 9:Page
Work Order :
:Client
ES1707191
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
RPD = Relative Percentage Difference
# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) Report
The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges
for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:
No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QC Lot: 812122)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 100 101 0.00 0% - 50%Anonymous ES1707040-020
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 432 476 9.58 0% - 20%Anonymous ES1707137-007
ED037P: Alkalinity by PC Titrator (QC Lot: 811444)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous ES1707040-022
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 6 6 0.00 No Limit
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 6 6 0.00 No Limit
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitGWQA-14 ES1707191-001
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L <1 <1 0.00 No Limit
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L <1 <1 0.00 No Limit
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QC Lot: 811481)
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 90 110 19.9 0% - 20%GWQA-14 ES1707191-001
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L <1 <1 0.00 No LimitAnonymous ES1707220-012
ED045G: Chloride by Discrete Analyser (QC Lot: 811482)
ED045G: Chloride 16887-00-6 1 mg/L 302 293 2.94 0% - 20%GWQA-14 ES1707191-001
ED045G: Chloride 16887-00-6 1 mg/L <1 <1 0.00 No LimitAnonymous ES1707220-012
ED093F: Dissolved Major Cations (QC Lot: 811725)
ED093F: Calcium 7440-70-2 1 mg/L 1 1 0.00 No LimitGWQA-14 ES1707191-001
ED093F: Magnesium 7439-95-4 1 mg/L 15 15 0.00 0% - 50%
ED093F: Sodium 7440-23-5 1 mg/L 174 175 0.00 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 2 2 0.00 No Limit
EG020F: Dissolved Metals by ICP-MS (QC Lot: 811722)
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous ES1707182-021
A
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EG020F: Dissolved Metals by ICP-MS (QC Lot: 811722) - continued
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No LimitAnonymous ES1707182-021
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.019 0.018 0.00 0% - 50%
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 <0.005 0.00 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L 0.25 0.25 0.00 0% - 20%
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitGWQA-14 ES1707191-001
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.003 0.003 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.871 0.890 2.14 0% - 20%
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.017 0.018 0.00 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L 4.45 4.44 0.00 0% - 20%
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020T: Total Metals by ICP-MS (QC Lot: 811732)
EG020A-T: Iron 7439-89-6 0.05 mg/L 0.76 0.78 2.36 0% - 50%Anonymous ES1706890-005
EG020A-T: Iron 7439-89-6 0.05 mg/L 0.09 0.10 10.3 No LimitAnonymous ES1707220-001
EG035F: Dissolved Mercury by FIMS (QC Lot: 811723)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous ES1707182-018
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous ES1707182-025
EK055G: Ammonia as N by Discrete Analyser (QC Lot: 811696)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.13 0.15 13.6 0% - 50%GWQA-14 ES1707191-001
EK057G: Nitrite as N by Discrete Analyser (QC Lot: 811479)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L 0.06 0.06 0.00 No LimitAnonymous EW1701354-001
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No LimitGWQA-14 ES1707191-001
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QC Lot: 811695)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 0.08 0.09 0.00 No LimitAnonymous ES1707182-021
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 0.03 0.04 0.00 No LimitGWQA-14 ES1707191-001
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QC Lot: 811687)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 0.5 0.5 0.00 No LimitAnonymous ES1707182-021
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 8.1 8.0 1.57 0% - 20%Anonymous ES1707194-001
EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 811686)
EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.01 0.01 0.00 No LimitAnonymous ES1707182-021
EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous ES1707194-001
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP005: Total Organic Carbon (TOC) (QC Lot: 818167)
EP005: Total Organic Carbon ---- 1 mg/L 40 41 3.66 0% - 20%Anonymous EM1703748-001
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QC Lot: 815502)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L 1490 1490 0.00 0% - 20%Anonymous ES1706988-001
EP026SP: Chemical Oxygen Demand ---- 10 mg/L 12 12 0.00 No LimitGWQA-14 ES1707191-001
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 811496)
EP080: C6 - C9 Fraction ---- 20 µg/L 340 290 15.0 0% - 50%Anonymous ES1707151-001
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitAnonymous ES1707202-006
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 811496)
EP080: C6 - C10 Fraction C6_C10 20 µg/L 320 280 15.0 0% - 50%Anonymous ES1707151-001
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitAnonymous ES1707202-006
EP080: BTEXN (QC Lot: 811496)
EP080: Benzene 71-43-2 1 µg/L 11 10 9.78 0% - 50%Anonymous ES1707151-001
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L 5 4 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L 8 7 13.5 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitAnonymous ES1707202-006
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
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Method Blank (MB) and Laboratory Control Spike (LCS) Report
The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC
parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target
analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QCLot: 812122)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 1012000 mg/L 10987
<10 120293 mg/L 12666
ED037P: Alkalinity by PC Titrator (QCLot: 811444)
ED037-P: Total Alkalinity as CaCO3 ---- ---- mg/L ---- 95.4200 mg/L 11181
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 811481)
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L <1 91.425 mg/L 12282
ED045G: Chloride by Discrete Analyser (QCLot: 811482)
ED045G: Chloride 16887-00-6 1 mg/L <1 94.410 mg/L 12781
<1 1011000 mg/L 12781
ED093F: Dissolved Major Cations (QCLot: 811725)
ED093F: Calcium 7440-70-2 1 mg/L <1 10450 mg/L 11480
ED093F: Magnesium 7439-95-4 1 mg/L <1 10750 mg/L 11690
ED093F: Sodium 7440-23-5 1 mg/L <1 10350 mg/L 12082
ED093F: Potassium 7440-09-7 1 mg/L <1 10850 mg/L 11385
EG020F: Dissolved Metals by ICP-MS (QCLot: 811722)
EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 82.80.5 mg/L 11680
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 95.60.1 mg/L 11485
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 1090.1 mg/L 11084
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 92.90.1 mg/L 11185
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 91.50.1 mg/L 11181
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 92.80.1 mg/L 11183
EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 98.30.1 mg/L 11082
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 94.50.1 mg/L 11282
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 96.70.1 mg/L 11585
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 97.00.1 mg/L 11781
EG020T: Total Metals by ICP-MS (QCLot: 811732)
EG020A-T: Iron 7439-89-6 0.05 mg/L <0.05 96.80.5 mg/L 11785
EG035F: Dissolved Mercury by FIMS (QCLot: 811723)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 99.60.01 mg/L 10583
EK055G: Ammonia as N by Discrete Analyser (QCLot: 811696)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 1031 mg/L 11490
EK057G: Nitrite as N by Discrete Analyser (QCLot: 811479)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 1010.5 mg/L 11482
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 811695)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 1040.5 mg/L 11391
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 811687)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 73.310 mg/L 10169
<0.1 1061 mg/L 11870
<0.1 1095 mg/L 11874
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 811686)
EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 86.34.42 mg/L 10171
<0.01 83.20.442 mg/L 10872
<0.01 90.01 mg/L 11878
EP005: Total Organic Carbon (TOC) (QCLot: 818167)
EP005: Total Organic Carbon ---- 1 mg/L <1 98.0100 mg/L 10981
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 815502)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L <10 10450 mg/L 11282
<10 97.6500 mg/L 11383
EP066: Polychlorinated Biphenyls (PCB) (QCLot: 811260)
EP066: Total Polychlorinated biphenyls ---- 1 µg/L <1 92.010 µg/L 10762
EP068A: Organochlorine Pesticides (OC) (QCLot: 811258)
EP068: alpha-BHC 319-84-6 0.5 µg/L <0.5 81.35 µg/L 11365
EP068: Hexachlorobenzene (HCB) 118-74-1 0.5 µg/L <0.5 1015 µg/L 11454
EP068: beta-BHC 319-85-7 0.5 µg/L <0.5 90.95 µg/L 11769
EP068: gamma-BHC 58-89-9 0.5 µg/L <0.5 83.45 µg/L 11270
EP068: delta-BHC 319-86-8 0.5 µg/L <0.5 91.75 µg/L 11767
EP068: Heptachlor 76-44-8 0.5 µg/L <0.5 80.95 µg/L 11363
EP068: Aldrin 309-00-2 0.5 µg/L <0.5 82.55 µg/L 11666
EP068: Heptachlor epoxide 1024-57-3 0.5 µg/L <0.5 84.55 µg/L 12359
EP068: trans-Chlordane 5103-74-2 0.5 µg/L <0.5 83.75 µg/L 12161
EP068: alpha-Endosulfan 959-98-8 0.5 µg/L <0.5 91.05 µg/L 12066
EP068: cis-Chlordane 5103-71-9 0.5 µg/L <0.5 87.25 µg/L 12064
EP068: Dieldrin 60-57-1 0.5 µg/L <0.5 93.75 µg/L 12066
EP068: 4.4`-DDE 72-55-9 0.5 µg/L <0.5 93.95 µg/L 11967
EP068: Endrin 72-20-8 0.5 µg/L <0.5 89.65 µg/L 12266
EP068: beta-Endosulfan 33213-65-9 0.5 µg/L <0.5 93.45 µg/L 11971
EP068: 4.4`-DDD 72-54-8 0.5 µg/L <0.5 90.35 µg/L 12272
EP068: Endrin aldehyde 7421-93-4 0.5 µg/L <0.5 81.95 µg/L 11664
EP068: Endosulfan sulfate 1031-07-8 0.5 µg/L <0.5 81.05 µg/L 12660
EP068: 4.4`-DDT 50-29-3 2 µg/L <2.0 86.25 µg/L 12260
EP068: Endrin ketone 53494-70-5 0.5 µg/L <0.5 84.95 µg/L 12462
EP068: Methoxychlor 72-43-5 2 µg/L <2.0 78.65 µg/L 12753
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP075(SIM)A: Phenolic Compounds (QCLot: 811259)
EP075(SIM): Phenol 108-95-2 1 µg/L <1.0 36.85 µg/L 6225
EP075(SIM): 2-Chlorophenol 95-57-8 1 µg/L <1.0 73.25 µg/L 9052
EP075(SIM): 2-Methylphenol 95-48-7 1 µg/L <1.0 67.35 µg/L 9151
EP075(SIM): 3- & 4-Methylphenol 1319-77-3 2 µg/L <2.0 61.010 µg/L 8844
EP075(SIM): 2-Nitrophenol 88-75-5 1 µg/L <1.0 71.25 µg/L 10048
EP075(SIM): 2.4-Dimethylphenol 105-67-9 1 µg/L <1.0 78.65 µg/L 9949
EP075(SIM): 2.4-Dichlorophenol 120-83-2 1 µg/L <1.0 80.65 µg/L 10553
EP075(SIM): 2.6-Dichlorophenol 87-65-0 1 µg/L <1.0 87.25 µg/L 10557
EP075(SIM): 4-Chloro-3-methylphenol 59-50-7 1 µg/L <1.0 77.85 µg/L 9953
EP075(SIM): 2.4.6-Trichlorophenol 88-06-2 1 µg/L <1.0 80.55 µg/L 10650
EP075(SIM): 2.4.5-Trichlorophenol 95-95-4 1 µg/L <1.0 73.35 µg/L 10551
EP075(SIM): Pentachlorophenol 87-86-5 2 µg/L <2.0 43.010 µg/L 9510
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 811259)
EP075(SIM): Naphthalene 91-20-3 1 µg/L <1.0 70.05 µg/L 9450
EP075(SIM): Acenaphthylene 208-96-8 1 µg/L <1.0 69.35 µg/L 11464
EP075(SIM): Acenaphthene 83-32-9 1 µg/L <1.0 65.75 µg/L 11362
EP075(SIM): Fluorene 86-73-7 1 µg/L <1.0 75.65 µg/L 11564
EP075(SIM): Phenanthrene 85-01-8 1 µg/L <1.0 74.75 µg/L 11663
EP075(SIM): Anthracene 120-12-7 1 µg/L <1.0 81.65 µg/L 11664
EP075(SIM): Fluoranthene 206-44-0 1 µg/L <1.0 83.65 µg/L 11864
EP075(SIM): Pyrene 129-00-0 1 µg/L <1.0 83.95 µg/L 11863
EP075(SIM): Benz(a)anthracene 56-55-3 1 µg/L <1.0 70.85 µg/L 11764
EP075(SIM): Chrysene 218-01-9 1 µg/L <1.0 67.95 µg/L 11663
EP075(SIM): Benzo(b+j)fluoranthene 205-99-2
205-82-3
1 µg/L <1.0 69.35 µg/L 11962
EP075(SIM): Benzo(k)fluoranthene 207-08-9 1 µg/L <1.0 71.15 µg/L 11563
EP075(SIM): Benzo(a)pyrene 50-32-8 0.5 µg/L <0.5 78.55 µg/L 11763
EP075(SIM): Indeno(1.2.3.cd)pyrene 193-39-5 1 µg/L <1.0 96.15 µg/L 11860
EP075(SIM): Dibenz(a.h)anthracene 53-70-3 1 µg/L <1.0 96.35 µg/L 11761
EP075(SIM): Benzo(g.h.i)perylene 191-24-2 1 µg/L <1.0 94.55 µg/L 11859
EP080/071: Total Petroleum Hydrocarbons (QCLot: 811257)
EP071: C10 - C14 Fraction ---- 50 µg/L <50 92.22000 µg/L 11676
EP071: C15 - C28 Fraction ---- 100 µg/L <100 1023000 µg/L 10983
EP071: C29 - C36 Fraction ---- 50 µg/L <50 1032000 µg/L 11375
EP080/071: Total Petroleum Hydrocarbons (QCLot: 811496)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 97.5260 µg/L 12775
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 811257)
EP071: >C10 - C16 Fraction ---- 100 µg/L <100 1022500 µg/L 11476
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 811257) - continued
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 94.73500 µg/L 11181
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 1061500 µg/L 11977
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 811496)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 98.4310 µg/L 12775
EP080: BTEXN (QCLot: 811496)
EP080: Benzene 71-43-2 1 µg/L <1 93.510 µg/L 12270
EP080: Toluene 108-88-3 2 µg/L <2 99.210 µg/L 12369
EP080: Ethylbenzene 100-41-4 2 µg/L <2 91.910 µg/L 12070
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 94.910 µg/L 12169
EP080: ortho-Xylene 95-47-6 2 µg/L <2 98.010 µg/L 12272
EP080: Naphthalene 91-20-3 5 µg/L <5 97.310 µg/L 12070
Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on
analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 811481)
GWQA-14 ES1707191-001 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric # Not
Determined
10 mg/L 13070
ED045G: Chloride by Discrete Analyser (QCLot: 811482)
GWQA-14 ES1707191-001 16887-00-6ED045G: Chloride 95.2250 mg/L 13070
EG020F: Dissolved Metals by ICP-MS (QCLot: 811722)
Anonymous ES1707182-017 7440-38-2EG020A-F: Arsenic 88.71 mg/L 13070
7440-43-9EG020A-F: Cadmium 1040.25 mg/L 13070
7440-47-3EG020A-F: Chromium 90.51 mg/L 13070
7440-50-8EG020A-F: Copper 92.51 mg/L 13070
7439-92-1EG020A-F: Lead 88.61 mg/L 13070
7439-96-5EG020A-F: Manganese 89.41 mg/L 13070
7440-02-0EG020A-F: Nickel 91.21 mg/L 13070
7440-66-6EG020A-F: Zinc 93.81 mg/L 13070
EG035F: Dissolved Mercury by FIMS (QCLot: 811723)
Anonymous ES1707182-016 7439-97-6EG035F: Mercury 72.10.01 mg/L 13070
EK055G: Ammonia as N by Discrete Analyser (QCLot: 811696)
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EK055G: Ammonia as N by Discrete Analyser (QCLot: 811696) - continued
GWQA-14 ES1707191-001 7664-41-7EK055G: Ammonia as N 83.61 mg/L 13070
EK057G: Nitrite as N by Discrete Analyser (QCLot: 811479)
GWQA-14 ES1707191-001 14797-65-0EK057G: Nitrite as N 96.00.5 mg/L 13070
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 811695)
Anonymous ES1707182-021 ----EK059G: Nitrite + Nitrate as N 97.00.5 mg/L 13070
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 811687)
Anonymous ES1707182-022 ----EK061G: Total Kjeldahl Nitrogen as N 1015 mg/L 13070
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 811686)
Anonymous ES1707182-022 ----EK067G: Total Phosphorus as P 85.01 mg/L 13070
EP005: Total Organic Carbon (TOC) (QCLot: 818167)
Anonymous EM1703748-002 ----EP005: Total Organic Carbon 93.1100 mg/L 11480
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 815502)
Anonymous ES1706988-001 ----EP026SP: Chemical Oxygen Demand 97.647.6 mg/L 13070
EP080/071: Total Petroleum Hydrocarbons (QCLot: 811496)
Anonymous ES1707151-001 ----EP080: C6 - C9 Fraction 114325 µg/L 13070
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 811496)
Anonymous ES1707151-001 C6_C10EP080: C6 - C10 Fraction 111375 µg/L 13070
EP080: BTEXN (QCLot: 811496)
Anonymous ES1707151-001 71-43-2EP080: Benzene 88.825 µg/L 13070
108-88-3EP080: Toluene 98.425 µg/L 13070
100-41-4EP080: Ethylbenzene 10425 µg/L 13070
108-38-3
106-42-3
EP080: meta- & para-Xylene 10025 µg/L 13070
95-47-6EP080: ortho-Xylene 10225 µg/L 13070
91-20-3EP080: Naphthalene 90.425 µg/L 13070
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True
Environmental
QA/QC Compliance Assessment to assist with Quality ReviewWork Order : ES1707191 Page : 1 of 10
:: LaboratoryClient Environmental Division SydneyEMERGE ASSOCIATES
:Contact MR SIMON GREGG Telephone : 08 9209 7631
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 27-Mar-2017
Site : ---- Issue Date : 03-Apr-2017
MITCHELL RITIKIS:Sampler No. of samples received : 1
:Order number ---- No. of samples analysed : 1
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated
reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this
report contribute to the overall DQO assessment and reporting for guideline compliance.
Brief method summaries and references are also provided to assist in traceability.
Summary of Outliers
Outliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.
l NO Duplicate outliers occur.
l NO Laboratory Control outliers occur.
l Matrix Spike outliers exist - please see following pages for full details.
l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliance
l Analysis Holding Time Outliers exist - please see following pages for full details.
Outliers : Frequency of Quality Control Samples
l Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Outliers : Quality Control Samples
Duplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes
Matrix: WATER
Compound Group Name CommentLimitsDataAnalyteClient Sample IDLaboratory Sample ID CAS Number
Matrix Spike (MS) Recoveries
ES1707191--001 14808-79-8Sulfate as SO4 -
Turbidimetric
GWQA-14 MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
Outliers : Analysis Holding Time Compliance
Matrix: WATER
AnalysisExtraction / Preparation
Date analysedDate extractedContainer / Client Sample ID(s) Days
overdue
Days
overdue
Due for extraction Due for analysis
Method
EK057G: Nitrite as N by Discrete Analyser
Clear Plastic Bottle - Natural
23-Mar-2017----GWQA-14 27-Mar-2017---- ---- 4
Outliers : Frequency of Quality Control Samples
Matrix: WATER
Quality Control SpecificationQuality Control Sample Type
Method ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 10.000 2
NEPM 2013 B3 & ALS QC StandardPesticides by GCMS 0.00 10.000 1
NEPM 2013 B3 & ALS QC StandardPolychlorinated Biphenyls (PCB) 0.00 10.000 1
NEPM 2013 B3 & ALS QC StandardTRH - Semivolatile Fraction 0.00 10.000 7
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 5.000 2
NEPM 2013 B3 & ALS QC StandardPesticides by GCMS 0.00 5.000 1
NEPM 2013 B3 & ALS QC StandardPolychlorinated Biphenyls (PCB) 0.00 5.000 1
NEPM 2013 B3 & ALS QC StandardTotal Metals by ICP-MS - Suite A 0.00 5.000 12
NEPM 2013 B3 & ALS QC StandardTRH - Semivolatile Fraction 0.00 5.000 7
Analysis Holding Time Compliance
Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and
should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.
Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics
14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.
If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.
This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container
provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EA015: Total Dissolved Solids dried at 180 ± 5 °C
Clear Plastic Bottle - Natural (EA015H)
GWQA-14 28-Mar-2017---- 28-Mar-2017----21-Mar-2017 ---- üED037P: Alkalinity by PC Titrator
Clear Plastic Bottle - Natural (ED037-P)
GWQA-14 04-Apr-2017---- 27-Mar-2017----21-Mar-2017 ---- üED041G: Sulfate (Turbidimetric) as SO4 2- by DA
Clear Plastic Bottle - Natural (ED041G)
GWQA-14 18-Apr-2017---- 27-Mar-2017----21-Mar-2017 ---- üED045G: Chloride by Discrete Analyser
Clear Plastic Bottle - Natural (ED045G)
GWQA-14 18-Apr-2017---- 27-Mar-2017----21-Mar-2017 ---- üED093F: Dissolved Major Cations
Clear Plastic Bottle - Filtered; Lab-acidified (ED093F)
GWQA-14 18-Apr-2017---- 28-Mar-2017----21-Mar-2017 ---- üEG020F: Dissolved Metals by ICP-MS
Clear Plastic Bottle - Filtered; Lab-acidified (EG020A-F)
GWQA-14 17-Sep-2017---- 28-Mar-2017----21-Mar-2017 ---- üEG020T: Total Metals by ICP-MS
Clear Plastic Bottle - Unfiltered; Lab-acidified (EG020A-T)
GWQA-14 17-Sep-201717-Sep-2017 28-Mar-201728-Mar-201721-Mar-2017 ü üEG035F: Dissolved Mercury by FIMS
Clear Plastic Bottle - Filtered; Lab-acidified (EG035F)
GWQA-14 18-Apr-2017---- 29-Mar-2017----21-Mar-2017 ---- üEK055G: Ammonia as N by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK055G)
GWQA-14 18-Apr-2017---- 28-Mar-2017----21-Mar-2017 ---- üEK057G: Nitrite as N by Discrete Analyser
Clear Plastic Bottle - Natural (EK057G)
GWQA-14 23-Mar-2017---- 27-Mar-2017----21-Mar-2017 ---- ûEK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK059G)
GWQA-14 18-Apr-2017---- 28-Mar-2017----21-Mar-2017 ---- üEK061G: Total Kjeldahl Nitrogen By Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK061G)
GWQA-14 18-Apr-201718-Apr-2017 28-Mar-201728-Mar-201721-Mar-2017 ü üEK067G: Total Phosphorus as P by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK067G)
GWQA-14 18-Apr-201718-Apr-2017 28-Mar-201728-Mar-201721-Mar-2017 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP005: Total Organic Carbon (TOC)
Amber TOC Vial - Sulfuric Acid (EP005)
GWQA-14 18-Apr-2017---- 31-Mar-2017----21-Mar-2017 ---- üEP026SP: Chemical Oxygen Demand (Spectrophotometric)
Clear Plastic Bottle - Sulfuric Acid (EP026SP)
GWQA-14 18-Apr-2017---- 30-Mar-2017----21-Mar-2017 ---- üEP066: Polychlorinated Biphenyls (PCB)
Amber Glass Bottle - Unpreserved (EP066)
GWQA-14 06-May-201728-Mar-2017 28-Mar-201727-Mar-201721-Mar-2017 ü üEP068A: Organochlorine Pesticides (OC)
Amber Glass Bottle - Unpreserved (EP068)
GWQA-14 06-May-201728-Mar-2017 28-Mar-201727-Mar-201721-Mar-2017 ü üEP075(SIM)A: Phenolic Compounds
Amber Glass Bottle - Unpreserved (EP075(SIM))
GWQA-14 06-May-201728-Mar-2017 28-Mar-201727-Mar-201721-Mar-2017 ü üEP075(SIM)B: Polynuclear Aromatic Hydrocarbons
Amber Glass Bottle - Unpreserved (EP075(SIM))
GWQA-14 06-May-201728-Mar-2017 28-Mar-201727-Mar-201721-Mar-2017 ü üEP080/071: Total Petroleum Hydrocarbons
Amber Glass Bottle - Unpreserved (EP071)
GWQA-14 06-May-201728-Mar-2017 28-Mar-201727-Mar-201721-Mar-2017 ü üAmber VOC Vial - Sulfuric Acid (EP080)
GWQA-14 04-Apr-201704-Apr-2017 28-Mar-201728-Mar-201721-Mar-2017 ü üEP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
Amber Glass Bottle - Unpreserved (EP071)
GWQA-14 06-May-201728-Mar-2017 28-Mar-201727-Mar-201721-Mar-2017 ü üAmber VOC Vial - Sulfuric Acid (EP080)
GWQA-14 04-Apr-201704-Apr-2017 28-Mar-201728-Mar-201721-Mar-2017 ü üEP080: BTEXN
Amber VOC Vial - Sulfuric Acid (EP080)
GWQA-14 04-Apr-201704-Apr-2017 28-Mar-201728-Mar-201721-Mar-2017 ü ü
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Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to
the expected rate. A listing of breaches is provided in the Summary of Outliers.
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC Standard 10.53 10.002 19 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 20.00 10.001 5 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 20.00 10.002 10 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 12.50 10.002 16 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 12.50 10.002 16 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 100.00 10.001 1 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 10.53 10.002 19 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 22.22 10.002 9 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 2 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 1 ûPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 1 ûPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 12.50 10.002 16 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 16.67 10.002 12 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 11.11 10.001 9 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 7 ûTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTRH Volatiles/BTEX EP080
Laboratory Control Samples (LCS)
NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 20.00 10.002 10 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 100.00 5.001 1 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 50.00 5.001 2 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 100.00 5.001 1 üPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 100.00 5.001 1 üPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 15.00 15.003 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
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Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Control Samples (LCS) - Continued
NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 15.00 15.003 20 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH Volatiles/BTEX EP080
Method Blanks (MB)
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 100.00 5.001 1 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 50.00 5.001 2 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 100.00 5.001 1 üPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 100.00 5.001 1 üPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH Volatiles/BTEX EP080
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 2 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 1 ûPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 1 ûPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 12 ûTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üTotal Organic Carbon EP005
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Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Matrix Spikes (MS) - Continued
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 7 ûTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH Volatiles/BTEX EP080
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Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the
Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 2540C. A gravimetric procedure that determines the amount of `filterable` residue
in an aqueous sample. A well-mixed sample is filtered through a glass fibre filter (1.2um). The filtrate is
evaporated to dryness and dried to constant weight at 180+/-5C. This method is compliant with NEPM (2013)
Schedule B(3)
Total Dissolved Solids (High Level) EA015H WATER
In house: Referenced to APHA 2320 B This procedure determines alkalinity by automated measurement (e.g. PC
Titrate) using pH 4.5 for indicating the total alkalinity end-point. This method is compliant with NEPM (2013)
Schedule B(3)
Alkalinity by PC Titrator ED037-P WATER
In house: Referenced to APHA 4500-SO4. Dissolved sulfate is determined in a 0.45um filtered sample. Sulfate
ions are converted to a barium sulfate suspension in an acetic acid medium with barium chloride. Light
absorbance of the BaSO4 suspension is measured by a photometer and the SO4-2 concentration is determined
by comparison of the reading with a standard curve. This method is compliant with NEPM (2013) Schedule B(3)
Sulfate (Turbidimetric) as SO4 2- by
Discrete Analyser
ED041G WATER
In house: Referenced to APHA 4500 Cl - G.The thiocyanate ion is liberated from mercuric thiocyanate through
sequestration of mercury by the chloride ion to form non-ionised mercuric chloride.in the presence of ferric ions
the librated thiocynate forms highly-coloured ferric thiocynate which is measured at 480 nm APHA 21st edition
seal method 2 017-1-L april 2003
Chloride by Discrete Analyser ED045G WATER
In house: Referenced to APHA 3120 and 3125; USEPA SW 846 - 6010 and 6020; Cations are determined by
either ICP-AES or ICP-MS techniques. This method is compliant with NEPM (2013) Schedule B(3)
Sodium Adsorption Ratio is calculated from Ca, Mg and Na which determined by ALS in house method
QWI-EN/ED093F. This method is compliant with NEPM (2013) Schedule B(3)
Hardness parameters are calculated based on APHA 2340 B. This method is compliant with NEPM (2013)
Schedule B(3)
Major Cations - Dissolved ED093F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. Samples are 0.45µm filtered
prior to analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions
are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct
mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Dissolved Metals by ICP-MS - Suite A EG020A-F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. The ICPMS technique utilizes
a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass
spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their
measurement by a discrete dynode ion detector.
Total Metals by ICP-MS - Suite A EG020A-T WATER
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS)
Samples are 0.45µm filtered prior to analysis. FIM-AAS is an automated flameless atomic absorption technique.
A bromate/bromide reagent is used to oxidise any organic mercury compounds in the filtered sample. The ionic
mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell.
Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM
(2013) Schedule B(3)
Dissolved Mercury by FIMS EG035F WATER
A
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Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500-NH3 G Ammonia is determined by direct colorimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Ammonia as N by Discrete analyser EK055G WATER
In house: Referenced to APHA 4500-NO2- B. Nitrite is determined by direct colourimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Nitrite as N by Discrete Analyser EK057G WATER
In house: Referenced to APHA 4500-NO3- F. Nitrate is reduced to nitrite by way of a chemical reduction followed
by quantification by Discrete Analyser. Nitrite is determined seperately by direct colourimetry and result for Nitrate
calculated as the difference between the two results. This method is compliant with NEPM (2013) Schedule B(3)
Nitrate as N by Discrete Analyser EK058G WATER
In house: Referenced to APHA 4500-NO3- F. Combined oxidised Nitrogen (NO2+NO3) is determined by
Chemical Reduction and direct colourimetry by Discrete Analyser. This method is compliant with NEPM (2013)
Schedule B(3)
Nitrite and Nitrate as N (NOx) by Discrete
Analyser
EK059G WATER
In house: Referenced to APHA 4500-Norg D (In house). An aliquot of sample is digested using a high
temperature Kjeldahl digestion to convert nitrogenous compounds to ammonia. Ammonia is determined
colorimetrically by discrete analyser. This method is compliant with NEPM (2013) Schedule B(3)
Total Kjeldahl Nitrogen as N By Discrete
Analyser
EK061G WATER
In house: Referenced to APHA 4500-Norg / 4500-NO3-. This method is compliant with NEPM (2013) Schedule
B(3)
Total Nitrogen as N (TKN + Nox) By
Discrete Analyser
EK062G WATER
In house: Referenced to APHA 4500-P H, Jirka et al (1976), Zhang et al (2006). This procedure involves
sulphuric acid digestion of a sample aliquot to break phosphorus down to orthophosphate. The orthophosphate
reacts with ammonium molybdate and antimony potassium tartrate to form a complex which is then reduced and
its concentration measured at 880nm using discrete analyser. This method is compliant with NEPM (2013)
Schedule B(3)
Total Phosphorus as P By Discrete
Analyser
EK067G WATER
In house: Referenced to APHA 5310 B, The automated TOC analyzer determines Total and Inorganic Carbon by
IR cell. TOC is calculated as the difference. This method is compliant with NEPM (2013) Schedule B(3)
Total Organic Carbon EP005 WATER
In house: Referenced to APHA 5220 D. Samples are digested with a known excess of an acidic potassium
dichromate solution using silver sulfate as a catalyst. The chromium is reduced from the Cr (VI) oxidation state
to the Cr (III) state by the oxygen present in the organic material. Both of these chromium species are coloued
and absorb in the visible region of (400nm & 600nm) the spectrum. The oxidisable organic matter can be
calculated in terms of oxygen equivalents.
Chemical Oxygen Demand (COD)
(Spectrophotometric)
EP026SP WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS and
quantification is by comparison against an established 5 point calibration curve. This method is compliant with
NEPM (2013) Schedule B(3)
Polychlorinated Biphenyls (PCB) EP066 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS and
quantification is by comparison against an established 5 point calibration curve. This method is compliant with
NEPM (2013) Schedule B(3)
Pesticides by GCMS EP068 WATER
In house: Referenced to USEPA SW 846 - 8015A The sample extract is analysed by Capillary GC/FID and
quantification is by comparison against an established 5 point calibration curve of n-Alkane standards. This
method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH - Semivolatile Fraction EP071 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS in SIM Mode
and quantification is by comparison against an established 5 point calibration curve. This method is compliant
with NEPM (2013) Schedule B(3)
PAH/Phenols (GC/MS - SIM) EP075(SIM) WATER
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Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by
Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve.
Alternatively, a sample is equilibrated in a headspace vial and a portion of the headspace determined by GCMS
analysis. This method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH Volatiles/BTEX EP080 WATER
Preparation Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 Norg - D; APHA 4500 P - H. This method is compliant with NEPM (2013)
Schedule B(3)
TKN/TP Digestion EK061/EK067 WATER
In house: Referenced to USEPA SW846-3005. Method 3005 is a Nitric/Hydrochloric acid digestion procedure
used to prepare surface and ground water samples for analysis by ICPAES or ICPMS. This method is compliant
with NEPM (2013) Schedule B(3)
Digestion for Total Recoverable Metals EN25 WATER
In house: Referenced to USEPA SW 846 - 3510B 100 mL to 1L of sample is transferred to a separatory funnel
and serially extracted three times using 60mL DCM for each extract. The resultant extracts are combined,
dehydrated and concentrated for analysis. This method is compliant with NEPM (2013) Schedule B(3) . ALS
default excludes sediment which may be resident in the container.
Separatory Funnel Extraction of Liquids ORG14 WATER
A 5 mL aliquot or 5 mL of a diluted sample is added to a 40 mL VOC vial for sparging.Volatiles Water Preparation ORG16-W WATER
A
CHAIN OF CUSTODY ~fD~fg~ CLIENT: Emerge Associates POSTAL ADDRESS: Suite 4, 26 Railway Road, Subiaco WA 6008 r:ror;-;l?□ s~.cnt? & D~'i·):y1
PROJECT MANAGER: Simon Gregg CONTACT PHONE: 9380 4988
PROJECT ID.: EP15-050(05) PROJECT NAME: SAMR Monitoring - Davis Road
SAMPLER(S): Mitchell Ritikis SAMPLERS PHONE: 0449 198 721
QUOTE NO.: EPBQ/009/16 ORDER NO.:
" Comments/special handling/storage or disposal
SAMPLE DETAILS CONTAINER INFORMATION
Lab ID Sample ID Matrix Date Type & Preservative
MW2 Water 31/05/2017 2 SP, 1VS, 2 P
MW3 Water 31/05/2017 2 SP, 1VS, 2 P
MW4 Water 31/05/2017 2 SP, 1VS, 2 P
MW5 Water 31/05/2017 2 SP, 1VS, 2 P
SW2 Water 31/05/2017 2 SP, 1VS, 2 P
GWQA-15 Water 31/05/2017 2 SP, 1VS, 2 P
Total No.
5
5
5
5
5
5
Email invoice to: accounts@emergeassociates.com.au
ANALYSIS REQUIRED
12 I.O~ - ~ el 00 ro oo "' ~ -c "- ·-wE
X
X
X
X
X
X
1:::~v1rohme1¾1a1 01v1s1~1, Perth
Work Order Reference
EP1705848
111111. RELINQUISHED BY: RECEIVED BY
NAME : IV', W t,--.,-L{ / NAME : Mitchell Ritikis DATE: 02/06/2017 DATE:£
OF: Erner e Associates TIME: 9:30am OF: \....,j TIME: (l..U NAME: DATE: NAME: DATE:
AP= Airf(ei§lif Unpreserved Plastic: V = VOA Vlal HCI Preserved; VB= VOA Vial Sodium Bisulphate Preserved; VS= VOA Vial Sulfuric Preserved; AV= Airfreight Unpreserved Vial; SG = Sulfuric Preserved Amber Glass;
Additional information (likely contaminants, dilutions or specific QC analysis)
Mislabelled as GWQA01
Coe emailed to ALS?
[8J Yes D No
H = HCI preserved Plastic; HS= HCI Preserved Speciation bottle; SP= Sulfuric Preserved Plastic; F = Formaldehyde Preserved Glass; Z = Zinc Acetate Preserved Bottle; E = EDTA Preseived Bottles; ST= Sterile Bottle; LI = Lugols Iodine Preseived Bottles; STT = Sterile Sodium Thiosulfate Preserved Bottles. Soil Container Codes: J = Jar, ASS-= Plastic Ba for Acid Sulfate So'ils; B = Unpreserved Ba ;
Major Cations: Ca, Mg, Na, K NT-1 APHA 3120 1-0.00
Major Anions: Cl, 50,, Alkalinity NT-2 Various 16.00
APHA 4 SQQ NHi·- H
Total Nitrogen, TKN, NOx, NOl.NOi. NH~. NT-8 APHA 4S00 No,9/NO, 0.01
54.00 Total Phosphorus APHA 4500 P- H TN: 0.1
APHA 4S0Q P - G
Chemical Oxygen Dem~!_l-~_SCOD) EP026SP ~-~~A 5220 B 24.00 Carbor:i __ - _Total Organic (TOC) ······· j~ EP00S APHA 531 OB l 24.00
8 Metals• Dissolved Cd:0.0001
' USEPA 6020, ICP/MS zn:0.005 (As, Cd, Cr, Cu, Ni, Pb, Zn) W-2F Others: 0.001 22.00
Hg _L_ - CV/FIMS/ICP/MS 0.0001
Additional Dissolved Metals by ICPMS -EG020F USEPA 6020 ICPMS 0.0001 · 0.01 6.00
Al, Mn, Se Total Recoverable Metals by ICPMS (incl EG020T USEPA 6020 ICPMS 0.0001 - 0.01 12.00 digest) - Fe
Tptai:sample cost for water.samples ·(Ex GS"Q;: 177.00
General ALS Service Inclusions
The ALS service includes the following at no extra charge;
Provision of sample containers, appropriately prepared, labelled and preserved, eskies and freight for primary analytical test-work in major metropolitan areas Bottle Order Form ALS COC protocols including receipt notification and advice of any non-conformances plus a rapid advice of ALS batch/tracking numbers. Webtrieve1
1o1 access to real time results and ALS technical support. WebtrieveTM EnviroMaifM Local technical support via the ALS technical and management team Perth Contact List
Electronics results including COA, QC and DQO reports plus tailored formats such as ESDAT, EQulS and many others. EDDs - EQUIS and ESDAT info & support
Quality, Sampling. Submission. Holding Times and Automated DQO Reporting
ALS has a comprehensive best practice QA/QC program designed to provide highly defensible analytical data in accordance with NEPM, ANZECC, ADWG, NAGD guidelines. ALS provides Laboratory Control Samples (LCS), Method Blanks (MB), Matrix Spikes (MS), Laboratory Duplicates (Dups) and Surrogates (where applicable), at frequencies at or above the NEPM guidelines - revised 2013. Should you require further details please contact ALS customer services.
• ALS is NATA accredited for all tests listed in this proposal unless advised otherwise.
• For further information on short holding times please see: ALS Environmental· Pocket Cu;de 2014
• ALS QA/QC is reliant upon appropriate replicate samples bottles/volumes especially for waters, air filters and sorbents. High contamination may negate ALS reporting of matrix spike recovery data.
• Please advise via COC where additional sample has been provided for QA/QC purposes e.g. by noting "Lab QC" (for both Dup and MS) or "Lab Dup" or "Lab MS".
~--~---,-·--·- -QA/-QC;-,-~~A.o!d-i A '3 ti m e !i , ~ --f-f-e-qU-GR-cy -and ~(i)re s c rvati o A ea FFt pliaAte-ttfe---S-ttm mar t5-ed--t n" A-I:.~~.-~ ~ reports to assist in quality review.
Quote EP/644/15 Emerge 41h September 20 1 5 Page 2 of 5
RIGHT SOLUTIONS I RIGHT PARTNEf{
Environmental
SAMPLE RECEIPT NOTIFICATION (SRN)Work Order : EP1705848
:: LaboratoryClient Environmental Division PerthEMERGE ASSOCIATES
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA
6008
10 Hod Way Malaga WA Australia 6090
:: E-mailE-mail simon.gregg@emergeassociates.co
m.au
LUKE.JONES@alsglobal.com
:: TelephoneTelephone +61 08 9380 4988 08 9209 7631
:: FacsimileFacsimile +61 08 9380 9636 +61-8-9209 7600
::Project EP15-050(05) SAMR Monitoring -
Davis Road
Page 1 of 3
:Order number ---- :Quote number EP2015EMEASS0045 (EP/683/15)
:C-O-C number ---- :QC Level NEPM 2013 B3 & ALS QC Standard
Site : ----
Sampler : MITCHELL RITIKIS
DatesDate Samples Received : Issue Date : 06-Jun-201702-Jun-2017 12:15
Scheduled Reporting Date: 12-Jun-2017:Client Requested Due
Date
12-Jun-2017
Delivery DetailsMode of Delivery : :Carrier Intact.Security Seal
No. of coolers/boxes : :1 Temperature 15.7 - Ice present
: : 6 / 6Receipt Detail No. of samples received / analysed
General Comments
This report contains the following information:l
- Sample Container(s)/Preservation Non-Compliances
- Summary of Sample(s) and Requested Analysis
- Proactive Holding Time Report
- Requested Deliverables
l Please see scanned COC for sample discrepencies: extra samples , samples not received etc.
l Please direct any queries related to sample condition / numbering / breakages to Sample Receipt (SamplesPerth@alsenviro.com)
l Analytical work for this work order will be conducted at ALS Environmental Perth.
l Please direct any turnaround / technical queries to the laboratory contact designated above.
l Sample Disposal - Aqueous (14 days), Solid (60 days) from date of completion of Work Order.
l COD analysis will be conducted by ALS Environmental, Sydney, NATA accreditation no. 825, Site
No. 10911.l pH analysis should be conducted within 6 hours of sampling.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
:Client EMERGE ASSOCIATES
Work Order : EP1705848 Amendment 02 of 3:Page
06-Jun-2017:Issue Date
Sample Container(s)/Preservation Non-Compliances
All comparisons are made against pretreatment/preservation AS, APHA, USEPA standards.
l No sample container / preservation non-compliance exists.
Summary of Sample(s) and Requested Analysis
Some items described below may be part of a laboratory
process necessary for the execution of client requested
tasks. Packages may contain additional analyses, such
as the determination of moisture content and preparation
tasks, that are included in the package.
If no sampling time is provided, the sampling time will
default 00:00 on the date of sampling. If no sampling date
is provided, the sampling date will be assumed by the
laboratory and displayed in brackets without a time
component
WA
TE
R -
EG
020F
Dis
solv
ed M
eta
ls b
y IC
PM
S
WA
TE
R -
EN
055 -
PG
Ionic
Bala
nce
by
ED
037P
, E
D041G
, E
D045G
&
WA
TE
R -
EP
026S
P
Chem
ical O
xygen D
em
and (
CO
D)
WA
TE
R -
NT
-01
Majo
r C
atio
ns
(Ca, M
g, N
a, K
)
WA
TE
R -
NT
-02
Majo
r A
nio
ns
(Chlo
ride, S
ulp
hate
, A
lkalin
ity)
WA
TE
R -
NT
-08
Tota
l Nitr
ogen +
NO
2 +
NO
3 +
NH
3 +
Tota
l P
WA
TE
R -
W-0
2
8 M
eta
ls
EP1705848-001 31-May-2017 00:00 MW2 ü ü ü ü ü ü ü
EP1705848-002 31-May-2017 00:00 MW3 ü ü ü ü ü ü ü
EP1705848-003 31-May-2017 00:00 MW4 ü ü ü ü ü ü ü
EP1705848-004 31-May-2017 00:00 MW5 ü ü ü ü ü ü ü
EP1705848-005 31-May-2017 00:00 SW2 ü ü ü ü ü ü ü
EP1705848-006 31-May-2017 00:00 GWQA-15 ü ü ü ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
WA
TE
R -
EA
01
5H
To
tal D
isso
lve
d S
olid
s -
Hig
h L
eve
l
WA
TE
R -
EG
02
0T
To
tal R
eco
vera
ble
Me
tals
by
ICP
MS
(in
clu
din
g
WA
TE
R -
EP
00
5
To
tal O
rga
nic
Ca
rbo
n (
TO
C)
EP1705848-001 31-May-2017 00:00 MW2 ü ü ü
EP1705848-002 31-May-2017 00:00 MW3 ü ü ü
EP1705848-003 31-May-2017 00:00 MW4 ü ü ü
EP1705848-004 31-May-2017 00:00 MW5 ü ü ü
EP1705848-005 31-May-2017 00:00 SW2 ü ü ü
EP1705848-006 31-May-2017 00:00 GWQA-15 ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
Proactive Holding Time Report
Sample(s) have been received within the recommended holding times for the requested analysis.
:Client EMERGE ASSOCIATES
Work Order : EP1705848 Amendment 03 of 3:Page
06-Jun-2017:Issue Date
Requested Deliverables
ACCOUNTS (INVOICES)
- A4 - AU Tax Invoice (INV) Email accounts@emergeassociates.com.
au
JEREMY PAYET
- *AU Certificate of Analysis - NATA (COA) Email jeremy.payet@emergeassociates.co
m.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email jeremy.payet@emergeassociates.co
m.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email jeremy.payet@emergeassociates.co
m.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email jeremy.payet@emergeassociates.co
m.au
- Chain of Custody (CoC) (COC) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - ENMRG (ENMRG) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - ESDAT (ESDAT) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - XTab (XTAB) Email jeremy.payet@emergeassociates.co
m.au
MITCHELL RITIKIS
- *AU Certificate of Analysis - NATA (COA) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email mitchell.ritikis@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email mitchell.ritikis@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - ENMRG (ENMRG) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email mitchell.ritikis@emergeassociates.c
om.au
SIMON GREGG
- *AU Certificate of Analysis - NATA (COA) Email simon.gregg@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email simon.gregg@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email simon.gregg@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email simon.gregg@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - ENMRG (ENMRG) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email simon.gregg@emergeassociates.c
om.au
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 6EP1705848
:: LaboratoryClient EMERGE ASSOCIATES Environmental Division Perth
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
10 Hod Way Malaga WA Australia 6090
:Telephone +61 08 9380 4988 :Telephone 08 9209 7631
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 02-Jun-2017 12:15
:Order number ---- Date Analysis Commenced : 02-Jun-2017
:C-O-C number ---- Issue Date : 12-Jun-2017 16:22
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EP/683/15
6:No. of samples received
6:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:
l General Comments
l Analytical Results
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with
Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Canhuang Ke Metals Instrument Chemist Perth Inorganics, Malaga, WA
Indra Astuty Instrument Chemist Perth Inorganics, Malaga, WA
Jeremy Truong Laboratory Manager Perth Inorganics, Malaga, WA
Tyrone Cole Inorganics Preparation Supervisor Perth Inorganics, Malaga, WA
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with 1S0/IEC 17025 - Testing
2 of 6:Page
Work Order :
:Client
EP1705848
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When no sampling time is provided, the sampling time will default 00:00 on the date of sampling. If no sampling date is provided, the sampling date will be assumed by the laboratory and displayed in brackets without a
time component.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
^ = This result is computed from individual analyte detections at or above the level of reporting
ø = ALS is not NATA accredited for these tests.
~ = Indicates an estimated value.
Key :
COD conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.l
It is recognised that TKN (EK061G) is less than ammonia (EK055G) for sample 'SW2'. However, the difference is within experimental variation of the methods.l
EK061G/EK067G: TKN/TP results for samples 'MW3' and 'GWQA-15' confirmed by re-extraction and re-analysis.l
A
3 of 6:Page
Work Order :
:Client
EP1705848
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
SW2MW5MW4MW3MW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)
31-May-2017 00:0031-May-2017 00:0031-May-2017 00:0031-May-2017 00:0031-May-2017 00:00Client sampling date / time
EP1705848-005EP1705848-004EP1705848-003EP1705848-002EP1705848-001UnitLORCAS NumberCompound
Result Result Result Result Result
EA015: Total Dissolved Solids dried at 180 ± 5 °C
442 661 224 831 276mg/L10----Total Dissolved Solids @180°C
ED037P: Alkalinity by PC Titrator
<1Hydroxide Alkalinity as CaCO3 <1 <1 <1 <1mg/L1DMO-210-001
<1Carbonate Alkalinity as CaCO3 <1 <1 <1 <1mg/L13812-32-6
10Bicarbonate Alkalinity as CaCO3 7 <1 64 39mg/L171-52-3
10 7 <1 64 39mg/L1----Total Alkalinity as CaCO3
ED045G: Chloride by Discrete Analyser
231Chloride 334 81 481 136mg/L116887-00-6
ED093F: Dissolved Major Cations
22Calcium 2 1 3 9mg/L17440-70-2
5Magnesium 19 7 29 11mg/L17439-95-4
112Sodium 197 56 265 82mg/L17440-23-5
14Potassium 3 2 14 3mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS
0.04Aluminium 0.02 0.36 <0.01 0.01mg/L0.017429-90-5
<0.001Arsenic <0.001 <0.001 <0.001 <0.001mg/L0.0017440-38-2
<0.0001Cadmium <0.0001 <0.0001 0.0001 <0.0001mg/L0.00017440-43-9
<0.001Chromium <0.001 <0.001 <0.001 <0.001mg/L0.0017440-47-3
<0.001Copper <0.001 0.003 <0.001 <0.001mg/L0.0017440-50-8
<0.001Nickel 0.002 0.002 0.009 <0.001mg/L0.0017440-02-0
<0.001Lead <0.001 <0.001 <0.001 <0.001mg/L0.0017439-92-1
0.023Zinc 0.020 0.008 0.114 <0.005mg/L0.0057440-66-6
0.004Manganese 1.09 0.008 1.62 0.252mg/L0.0017439-96-5
<0.01Selenium <0.01 <0.01 <0.01 <0.01mg/L0.017782-49-2
EG020T: Total Metals by ICP-MS
50.5Iron 62.0 0.76 57.4 9.17mg/L0.057439-89-6
EG035F: Dissolved Mercury by FIMS
<0.0001Mercury <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017439-97-6
EK055G: Ammonia as N by Discrete Analyser
0.85Ammonia as N 0.20 0.05 0.21 0.26mg/L0.017664-41-7
EK057G: Nitrite as N by Discrete Analyser
<0.01Nitrite as N <0.01 <0.01 <0.01 <0.01mg/L0.0114797-65-0
EK058G: Nitrate as N by Discrete Analyser
0.01Nitrate as N 0.02 0.61 0.01 0.01mg/L0.0114797-55-8
A
---------------
4 of 6:Page
Work Order :
:Client
EP1705848
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
SW2MW5MW4MW3MW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)
31-May-2017 00:0031-May-2017 00:0031-May-2017 00:0031-May-2017 00:0031-May-2017 00:00Client sampling date / time
EP1705848-005EP1705848-004EP1705848-003EP1705848-002EP1705848-001UnitLORCAS NumberCompound
Result Result Result Result Result
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
0.01 0.02 0.61 0.01 0.01mg/L0.01----Nitrite + Nitrate as N
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser
1.7 3.8 0.1 0.4 0.2mg/L0.1----Total Kjeldahl Nitrogen as N
EK062G: Total Nitrogen as N (TKN + NOx) by Discrete Analyser
1.7^ 3.8 0.7 0.4 0.2mg/L0.1----Total Nitrogen as N
EK067G: Total Phosphorus as P by Discrete Analyser
0.32 0.06 0.04 0.64 <0.01mg/L0.01----Total Phosphorus as P
EN055: Ionic Balance
7.46 12.3 2.85 16.2 5.01meq/L0.01----Total Anions
6.74 10.3 3.11 14.4 5.00meq/L0.01----Total Cations
5.11 8.68 4.46 5.68 0.13%0.01----Ionic Balance
EP005: Total Organic Carbon (TOC)
13 10 10 10 4mg/L1----Total Organic Carbon
EP026SP: Chemical Oxygen Demand (Spectrophotometric)
21 17 <10 19 <10mg/L10----Chemical Oxygen Demand
A
---------------
5 of 6:Page
Work Order :
:Client
EP1705848
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
----------------GWQA-15Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------31-May-2017 00:00Client sampling date / time
--------------------------------EP1705848-006UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EA015: Total Dissolved Solids dried at 180 ± 5 °C
454 ---- ---- ---- ----mg/L10----Total Dissolved Solids @180°C
ED037P: Alkalinity by PC Titrator
<1Hydroxide Alkalinity as CaCO3 ---- ---- ---- ----mg/L1DMO-210-001
<1Carbonate Alkalinity as CaCO3 ---- ---- ---- ----mg/L13812-32-6
10Bicarbonate Alkalinity as CaCO3 ---- ---- ---- ----mg/L171-52-3
10 ---- ---- ---- ----mg/L1----Total Alkalinity as CaCO3
ED045G: Chloride by Discrete Analyser
229Chloride ---- ---- ---- ----mg/L116887-00-6
ED093F: Dissolved Major Cations
20Calcium ---- ---- ---- ----mg/L17440-70-2
5Magnesium ---- ---- ---- ----mg/L17439-95-4
112Sodium ---- ---- ---- ----mg/L17440-23-5
14Potassium ---- ---- ---- ----mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS
0.04Aluminium ---- ---- ---- ----mg/L0.017429-90-5
<0.001Arsenic ---- ---- ---- ----mg/L0.0017440-38-2
<0.0001Cadmium ---- ---- ---- ----mg/L0.00017440-43-9
<0.001Chromium ---- ---- ---- ----mg/L0.0017440-47-3
<0.001Copper ---- ---- ---- ----mg/L0.0017440-50-8
<0.001Nickel ---- ---- ---- ----mg/L0.0017440-02-0
<0.001Lead ---- ---- ---- ----mg/L0.0017439-92-1
0.023Zinc ---- ---- ---- ----mg/L0.0057440-66-6
0.004Manganese ---- ---- ---- ----mg/L0.0017439-96-5
<0.01Selenium ---- ---- ---- ----mg/L0.017782-49-2
EG020T: Total Metals by ICP-MS
50.7Iron ---- ---- ---- ----mg/L0.057439-89-6
EG035F: Dissolved Mercury by FIMS
<0.0001Mercury ---- ---- ---- ----mg/L0.00017439-97-6
EK055G: Ammonia as N by Discrete Analyser
0.85Ammonia as N ---- ---- ---- ----mg/L0.017664-41-7
EK057G: Nitrite as N by Discrete Analyser
<0.01Nitrite as N ---- ---- ---- ----mg/L0.0114797-65-0
EK058G: Nitrate as N by Discrete Analyser
0.01Nitrate as N ---- ---- ---- ----mg/L0.0114797-55-8
A
---------------
6 of 6:Page
Work Order :
:Client
EP1705848
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
----------------GWQA-15Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------31-May-2017 00:00Client sampling date / time
--------------------------------EP1705848-006UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
0.01 ---- ---- ---- ----mg/L0.01----Nitrite + Nitrate as N
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser
0.9 ---- ---- ---- ----mg/L0.1----Total Kjeldahl Nitrogen as N
EK062G: Total Nitrogen as N (TKN + NOx) by Discrete Analyser
0.9^ ---- ---- ---- ----mg/L0.1----Total Nitrogen as N
EK067G: Total Phosphorus as P by Discrete Analyser
0.03 ---- ---- ---- ----mg/L0.01----Total Phosphorus as P
EN055: Ionic Balance
7.39 ---- ---- ---- ----meq/L0.01----Total Anions
6.64 ---- ---- ---- ----meq/L0.01----Total Cations
5.34 ---- ---- ---- ----%0.01----Ionic Balance
EP005: Total Organic Carbon (TOC)
9 ---- ---- ---- ----mg/L1----Total Organic Carbon
EP026SP: Chemical Oxygen Demand (Spectrophotometric)
25 ---- ---- ---- ----mg/L10----Chemical Oxygen Demand
A
---------------
False
5 5.00True
Environmental
QUALITY CONTROL REPORTWork Order : EP1705848 Page : 1 of 7
:: LaboratoryClient Environmental Division PerthEMERGE ASSOCIATES
:Contact MR SIMON GREGG :Contact Luke Jones
:Address SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
Address : 10 Hod Way Malaga WA Australia 6090
::Telephone +61 08 9380 4988 08 9209 7631:Telephone
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 02-Jun-2017
:Order number ---- Date Analysis Commenced : 02-Jun-2017
:C-O-C number ---- Issue Date : 12-Jun-2017
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EP/683/15
No. of samples received 6:
No. of samples analysed 6:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limits
l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits
l Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Canhuang Ke Metals Instrument Chemist Perth Inorganics, Malaga, WA
Indra Astuty Instrument Chemist Perth Inorganics, Malaga, WA
Jeremy Truong Laboratory Manager Perth Inorganics, Malaga, WA
Tyrone Cole Inorganics Preparation Supervisor Perth Inorganics, Malaga, WA
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with 150/IEC 17025 - Testing
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General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
RPD = Relative Percentage Difference
# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) Report
The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges
for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:
No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QC Lot: 930342)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 28400 31500 10.3 0% - 20%Anonymous EP1705847-001
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 98600 99000 0.324 0% - 20%Anonymous EP1705861-001
ED037P: Alkalinity by PC Titrator (QC Lot: 934082)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EP1705843-002
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 78 92 16.3 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 78 92 16.3 0% - 20%
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EP1705823-005
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 221 262 16.7 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 221 262 16.7 0% - 20%
ED045G: Chloride by Discrete Analyser (QC Lot: 928923)
ED045G: Chloride 16887-00-6 1 mg/L 552 552 0.00 0% - 20%Anonymous EP1705851-001
ED045G: Chloride 16887-00-6 1 mg/L 14700 14500 1.44 0% - 20%Anonymous EP1705847-001
ED093F: Dissolved Major Cations (QC Lot: 930579)
ED093F: Calcium 7440-70-2 1 mg/L 20 22 11.0 0% - 20%GWQA-15 EP1705848-006
ED093F: Magnesium 7439-95-4 1 mg/L 5 5 0.00 No Limit
ED093F: Sodium 7440-23-5 1 mg/L 112 110 1.17 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 14 14 0.00 0% - 50%
ED093F: Calcium 7440-70-2 1 mg/L 68 69 2.27 0% - 20%Anonymous EP1705845-001
ED093F: Magnesium 7439-95-4 1 mg/L 6 6 0.00 No Limit
ED093F: Sodium 7440-23-5 1 mg/L 23 23 0.00 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 3 3 0.00 No Limit
EG020F: Dissolved Metals by ICP-MS (QC Lot: 930581)
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EG020F: Dissolved Metals by ICP-MS (QC Lot: 930581) - continued
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitGWQA-15 EP1705848-006
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.004 0.005 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.023 0.022 0.00 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L 0.04 0.04 0.00 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EP1705845-001
EG020A-F: Arsenic 7440-38-2 0.001 mg/L 0.041 0.041 0.00 0% - 20%
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.114 0.115 0.00 0% - 20%
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.001 0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 <0.005 0.00 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020T: Total Metals by ICP-MS (QC Lot: 930720)
EG020A-T: Iron 7439-89-6 0.05 mg/L 0.26 0.29 11.4 No LimitAnonymous EP1705824-007
EG020A-T: Iron 7439-89-6 0.05 mg/L 62.0 61.9 0.167 0% - 20%MW3 EP1705848-002
EG035F: Dissolved Mercury by FIMS (QC Lot: 930580)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitSW2 EP1705848-005
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EP1705845-001
EK055G: Ammonia as N by Discrete Analyser (QC Lot: 932441)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 4.99 4.85 2.87 0% - 20%Anonymous EP1705841-001
EK057G: Nitrite as N by Discrete Analyser (QC Lot: 928922)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L 0.01 0.02 0.00 No LimitAnonymous EP1705851-001
EK057G: Nitrite as N 14797-65-0 0.01 mg/L 0.29 0.29 0.00 0% - 20%Anonymous EP1705847-001
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QC Lot: 932442)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 4.94 4.77 3.38 0% - 20%Anonymous EP1705849-001
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 14.9 14.6 1.96 0% - 20%Anonymous EP1705841-001
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QC Lot: 930488)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 6.8 7.2 5.77 0% - 50%Anonymous EP1705821-014
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 1.0 1.5 38.2 0% - 50%Anonymous EP1705844-001
EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 930489)
EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.20 0.24 17.6 No LimitAnonymous EP1705821-014
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 930489) - continued
EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.08 0.07 0.00 No LimitAnonymous EP1705844-001
EP005: Total Organic Carbon (TOC) (QC Lot: 928656)
EP005: Total Organic Carbon ---- 1 mg/L 9730 9610 1.19 No LimitAnonymous EP1705738-003
EP005: Total Organic Carbon ---- 1 mg/L 9 9 0.00 No LimitGWQA-15 EP1705848-006
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QC Lot: 935261)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L <10 <10 0.00 No LimitAnonymous EP1705823-001
EP026SP: Chemical Oxygen Demand ---- 10 mg/L 19 19 0.00 No LimitMW5 EP1705848-004
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Method Blank (MB) and Laboratory Control Spike (LCS) Report
The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC
parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target
analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QCLot: 930342)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 90.82000 mg/L 11183
<10 97.01000 mg/L 13070
ED037P: Alkalinity by PC Titrator (QCLot: 934082)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-00
1
1 mg/L <1 -------- --------
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 -------- --------
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L <1 -------- --------
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L <1 10420 mg/L 12676
<1 97.5200 mg/L 10690
ED045G: Chloride by Discrete Analyser (QCLot: 928923)
ED045G: Chloride 16887-00-6 1 mg/L <1 10110 mg/L 12084
<1 1081000 mg/L 11084
ED093F: Dissolved Major Cations (QCLot: 930579)
ED093F: Calcium 7440-70-2 1 mg/L <1 99.450 mg/L 10991
ED093F: Magnesium 7439-95-4 1 mg/L <1 10250 mg/L 10890
ED093F: Sodium 7440-23-5 1 mg/L <1 10850 mg/L 11187
ED093F: Potassium 7440-09-7 1 mg/L <1 10150 mg/L 11090
EG020F: Dissolved Metals by ICP-MS (QCLot: 930581)
EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 99.80.5 mg/L 11684
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 1050.1 mg/L 10884
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 96.40.1 mg/L 10886
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 98.20.1 mg/L 10985
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 97.60.1 mg/L 11084
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 95.20.1 mg/L 10785
EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 1010.1 mg/L 10985
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 1000.1 mg/L 11284
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 1000.1 mg/L 11288
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 99.20.1 mg/L 11589
EG020T: Total Metals by ICP-MS (QCLot: 930720)
EG020A-T: Iron 7439-89-6 0.05 mg/L <0.05 95.50.5 mg/L 12077
EG035F: Dissolved Mercury by FIMS (QCLot: 930580)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 99.10.01 mg/L 11692
EK055G: Ammonia as N by Discrete Analyser (QCLot: 932441)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 1081 mg/L 11587
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EK057G: Nitrite as N by Discrete Analyser (QCLot: 928922)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 1000.5 mg/L 11286
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 932442)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 1020.5 mg/L 11292
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 930488)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 87.810 mg/L 11082
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 930489)
EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 91.44.42 mg/L 13070
EP005: Total Organic Carbon (TOC) (QCLot: 928656)
EP005: Total Organic Carbon ---- 1 mg/L <1 85.710 mg/L 11179
<1 96.6100 mg/L 11179
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 935261)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L <10 10650 mg/L 11282
<10 100500 mg/L 11383
Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on
analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
ED045G: Chloride by Discrete Analyser (QCLot: 928923)
Anonymous EP1705841-001 16887-00-6ED045G: Chloride 1021000 mg/L 13070
EG020F: Dissolved Metals by ICP-MS (QCLot: 930581)
Anonymous EP1705845-002 7440-38-2EG020A-F: Arsenic 1060.2 mg/L 13070
7440-43-9EG020A-F: Cadmium 98.90.05 mg/L 13070
7440-47-3EG020A-F: Chromium 1020.2 mg/L 13070
7440-50-8EG020A-F: Copper 99.10.2 mg/L 13070
7439-92-1EG020A-F: Lead 94.00.2 mg/L 13070
7439-96-5EG020A-F: Manganese 1020.2 mg/L 13070
7440-02-0EG020A-F: Nickel 1020.2 mg/L 13070
7440-66-6EG020A-F: Zinc 1020.2 mg/L 13070
EG035F: Dissolved Mercury by FIMS (QCLot: 930580)
Anonymous EP1705845-003 7439-97-6EG035F: Mercury 1010.01 mg/L 13070
EK055G: Ammonia as N by Discrete Analyser (QCLot: 932441)
Anonymous EP1705841-001 7664-41-7EK055G: Ammonia as N # Not
Determined
1 mg/L 13070
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EK057G: Nitrite as N by Discrete Analyser (QCLot: 928922)
Anonymous EP1705841-001 14797-65-0EK057G: Nitrite as N # Not
Determined
0.5 mg/L 13070
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 932442)
Anonymous EP1705841-001 ----EK059G: Nitrite + Nitrate as N # Not
Determined
0.5 mg/L 13070
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 930488)
Anonymous EP1705821-014 ----EK061G: Total Kjeldahl Nitrogen as N 76.85 mg/L 13070
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 930489)
Anonymous EP1705821-014 ----EK067G: Total Phosphorus as P 97.51 mg/L 13070
EP005: Total Organic Carbon (TOC) (QCLot: 928656)
Anonymous EP1705738-004 ----EP005: Total Organic Carbon # Not
Determined
100 mg/L 13070
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 935261)
Anonymous EP1705823-001 ----EP026SP: Chemical Oxygen Demand 10647.6 mg/L 13070
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True
Environmental
QA/QC Compliance Assessment to assist with Quality ReviewWork Order : EP1705848 Page : 1 of 8
:: LaboratoryClient Environmental Division PerthEMERGE ASSOCIATES
:Contact MR SIMON GREGG Telephone : 08 9209 7631
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 02-Jun-2017
Site : ---- Issue Date : 12-Jun-2017
MITCHELL RITIKIS:Sampler No. of samples received : 6
:Order number ---- No. of samples analysed : 6
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated
reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this
report contribute to the overall DQO assessment and reporting for guideline compliance.
Brief method summaries and references are also provided to assist in traceability.
Summary of Outliers
Outliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.
l NO Duplicate outliers occur.
l NO Laboratory Control outliers occur.
l Matrix Spike outliers exist - please see following pages for full details.
l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliance
l NO Analysis Holding Time Outliers exist.
Outliers : Frequency of Quality Control Samples
l Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Outliers : Quality Control Samples
Duplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes
Matrix: WATER
Compound Group Name CommentLimitsDataAnalyteClient Sample IDLaboratory Sample ID CAS Number
Matrix Spike (MS) Recoveries
EP1705841--001 7664-41-7Ammonia as NAnonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EK055G: Ammonia as N by Discrete Analyser
EP1705841--001 14797-65-0Nitrite as NAnonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EK057G: Nitrite as N by Discrete Analyser
EP1705841--001 ----Nitrite + Nitrate as NAnonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
EP1705738--004 ----Total Organic CarbonAnonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP005: Total Organic Carbon (TOC)
Outliers : Frequency of Quality Control Samples
Matrix: WATER
Quality Control SpecificationQuality Control Sample Type
Method ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC StandardTotal Metals by ICP-MS - Suite A 0.00 5.000 14
Analysis Holding Time Compliance
Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and
should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.
Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics
14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.
If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.
This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container
provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EA015: Total Dissolved Solids dried at 180 ± 5 °C
Clear Plastic Bottle - Natural (EA015H)
MW2, MW3,
MW4, MW5,
SW2, GWQA-15
07-Jun-2017---- 07-Jun-2017----31-May-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
ED037P: Alkalinity by PC Titrator
Clear Plastic Bottle - Natural (ED037-P)
MW2, MW3,
MW4, MW5,
SW2, GWQA-15
14-Jun-2017---- 08-Jun-2017----31-May-2017 ---- ü
ED045G: Chloride by Discrete Analyser
Clear Plastic Bottle - Natural (ED045G)
MW2, MW3,
MW4, MW5,
SW2, GWQA-15
28-Jun-2017---- 02-Jun-2017----31-May-2017 ---- ü
ED093F: Dissolved Major Cations
Clear Plastic Bottle - Filtered; Lab-acidified (ED093F)
MW2, MW3,
MW4, MW5,
SW2, GWQA-15
28-Jun-2017---- 07-Jun-2017----31-May-2017 ---- ü
EG020F: Dissolved Metals by ICP-MS
Clear Plastic Bottle - Filtered; Lab-acidified (EG020A-F)
MW2, MW3,
MW4, MW5,
SW2, GWQA-15
27-Nov-2017---- 07-Jun-2017----31-May-2017 ---- ü
EG020T: Total Metals by ICP-MS
Clear Plastic Bottle - Unfiltered; Lab-acidified (EG020A-T)
MW2, MW3,
MW4, MW5,
SW2, GWQA-15
27-Nov-201727-Nov-2017 08-Jun-201708-Jun-201731-May-2017 ü ü
EG035F: Dissolved Mercury by FIMS
Clear Plastic Bottle - Filtered; Lab-acidified (EG035F)
MW2, MW3,
MW4, MW5,
SW2, GWQA-15
28-Jun-2017---- 07-Jun-2017----31-May-2017 ---- ü
EK055G: Ammonia as N by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK055G)
MW2, MW3,
MW4, MW5,
SW2, GWQA-15
28-Jun-2017---- 08-Jun-2017----31-May-2017 ---- ü
EK057G: Nitrite as N by Discrete Analyser
Clear Plastic Bottle - Natural (EK057G)
MW2, MW3,
MW4, MW5,
SW2, GWQA-15
02-Jun-2017---- 02-Jun-2017----31-May-2017 ---- ü
A
4 of 8:Page
Work Order :
:Client
EP1705848
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK059G)
MW2, MW3,
MW4, MW5,
SW2, GWQA-15
28-Jun-2017---- 08-Jun-2017----31-May-2017 ---- ü
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK061G)
MW2, MW3,
MW4, MW5,
SW2, GWQA-15
28-Jun-201728-Jun-2017 08-Jun-201707-Jun-201731-May-2017 ü ü
EK067G: Total Phosphorus as P by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK067G)
MW2, MW3,
MW4, MW5,
SW2, GWQA-15
28-Jun-201728-Jun-2017 08-Jun-201707-Jun-201731-May-2017 ü ü
EP005: Total Organic Carbon (TOC)
Amber TOC Vial - Sulfuric Acid (EP005)
MW2, MW3,
MW4, MW5,
SW2, GWQA-15
28-Jun-2017---- 06-Jun-2017----31-May-2017 ---- ü
EP026SP: Chemical Oxygen Demand (Spectrophotometric)
Clear Plastic Bottle - Sulfuric Acid (EP026SP)
MW2, MW3,
MW4, MW5,
SW2, GWQA-15
28-Jun-2017---- 09-Jun-2017----31-May-2017 ---- ü
A
5 of 8:Page
Work Order :
:Client
EP1705848
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to
the expected rate. A listing of breaches is provided in the Summary of Outliers.
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 10.00 10.001 10 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 15.38 10.002 13 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 16.67 10.002 12 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 18.18 10.002 11 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 18.18 10.002 11 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 18.18 10.002 11 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 18.18 10.002 11 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 13.33 10.002 15 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 14.29 10.002 14 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 18.18 10.002 11 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Phosphorus as P By Discrete Analyser EK067G
Laboratory Control Samples (LCS)
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 15.38 10.002 13 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 16.67 10.002 12 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 18.18 10.002 11 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067G
Method Blanks (MB)
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 7.69 5.001 13 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üDissolved Metals by ICP-MS - Suite A EG020A-F
6 of 8:Page
Work Order :
:Client
EP1705848
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Method Blanks (MB) - Continued
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067G
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 7.69 5.001 13 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 14 ûTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067G
7 of 8:Page
Work Order :
:Client
EP1705848
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the
Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 2540C. A gravimetric procedure that determines the amount of `filterable` residue
in an aqueous sample. A well-mixed sample is filtered through a glass fibre filter (1.2um). The filtrate is
evaporated to dryness and dried to constant weight at 180+/-5C. This method is compliant with NEPM (2013)
Schedule B(3)
Total Dissolved Solids (High Level) EA015H WATER
In house: Referenced to APHA 2320 B This procedure determines alkalinity by automated measurement (e.g. PC
Titrate) using pH 4.5 for indicating the total alkalinity end-point. This method is compliant with NEPM (2013)
Schedule B(3)
Alkalinity by PC Titrator ED037-P WATER
In house: Referenced to APHA 4500 Cl - G.The thiocyanate ion is liberated from mercuric thiocyanate through
sequestration of mercury by the chloride ion to form non-ionised mercuric chloride.in the presence of ferric ions
the librated thiocynate forms highly-coloured ferric thiocynate which is measured at 480 nm APHA 21st edition
seal method 2 017-1-L april 2003
Chloride by Discrete Analyser ED045G WATER
In house: Referenced to APHA 3120 and 3125; USEPA SW 846 - 6010 and 6020; Cations are determined by
either ICP-AES or ICP-MS techniques. This method is compliant with NEPM (2013) Schedule B(3)
Sodium Adsorption Ratio is calculated from Ca, Mg and Na which determined by ALS in house method
QWI-EN/ED093F. This method is compliant with NEPM (2013) Schedule B(3)
Hardness parameters are calculated based on APHA 2340 B. This method is compliant with NEPM (2013)
Schedule B(3)
Major Cations - Dissolved ED093F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. Samples are 0.45µm filtered
prior to analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions
are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct
mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Dissolved Metals by ICP-MS - Suite A EG020A-F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. The ICPMS technique utilizes
a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass
spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their
measurement by a discrete dynode ion detector.
Total Metals by ICP-MS - Suite A EG020A-T WATER
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS)
Samples are 0.45µm filtered prior to analysis. FIM-AAS is an automated flameless atomic absorption technique.
A bromate/bromide reagent is used to oxidise any organic mercury compounds in the filtered sample. The ionic
mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell.
Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM
(2013) Schedule B(3)
Dissolved Mercury by FIMS EG035F WATER
In house: Referenced to APHA 4500-NH3 G Ammonia is determined by direct colorimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Ammonia as N by Discrete analyser EK055G WATER
In house: Referenced to APHA 4500-NO2- B. Nitrite is determined by direct colourimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Nitrite as N by Discrete Analyser EK057G WATER
A
8 of 8:Page
Work Order :
:Client
EP1705848
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500-NO3- F. Nitrate is reduced to nitrite by way of a chemical reduction followed
by quantification by Discrete Analyser. Nitrite is determined seperately by direct colourimetry and result for Nitrate
calculated as the difference between the two results. This method is compliant with NEPM (2013) Schedule B(3)
Nitrate as N by Discrete Analyser EK058G WATER
In house: Referenced to APHA 4500-NO3- F. Combined oxidised Nitrogen (NO2+NO3) is determined by
Chemical Reduction and direct colourimetry by Discrete Analyser. This method is compliant with NEPM (2013)
Schedule B(3)
Nitrite and Nitrate as N (NOx) by Discrete
Analyser
EK059G WATER
In house: Referenced to APHA 4500-Norg D (In house). An aliquot of sample is digested using a high
temperature Kjeldahl digestion to convert nitrogenous compounds to ammonia. Ammonia is determined
colorimetrically by discrete analyser. This method is compliant with NEPM (2013) Schedule B(3)
Total Kjeldahl Nitrogen as N By Discrete
Analyser
EK061G WATER
In house: Referenced to APHA 4500-Norg / 4500-NO3-. This method is compliant with NEPM (2013) Schedule
B(3)
Total Nitrogen as N (TKN + Nox) By
Discrete Analyser
EK062G WATER
In house: Referenced to APHA 4500-P H, Jirka et al (1976), Zhang et al (2006). This procedure involves
sulphuric acid digestion of a sample aliquot to break phosphorus down to orthophosphate. The orthophosphate
reacts with ammonium molybdate and antimony potassium tartrate to form a complex which is then reduced and
its concentration measured at 880nm using discrete analyser. This method is compliant with NEPM (2013)
Schedule B(3)
Total Phosphorus as P By Discrete
Analyser
EK067G WATER
In house: Referenced to APHA 1030F. This method is compliant with NEPM (2013) Schedule B(3)Ionic Balance by PCT DA and Turbi SO4
DA
EN055 - PG WATER
In house: Referenced to APHA 5310 B, The automated TOC analyzer determines Total and Inorganic Carbon by
IR cell. TOC is calculated as the difference. This method is compliant with NEPM (2013) Schedule B(3)
Total Organic Carbon EP005 WATER
In house: Referenced to APHA 5220 D. Samples are digested with a known excess of an acidic potassium
dichromate solution using silver sulfate as a catalyst. The chromium is reduced from the Cr (VI) oxidation state
to the Cr (III) state by the oxygen present in the organic material. Both of these chromium species are coloued
and absorb in the visible region of (400nm & 600nm) the spectrum. The oxidisable organic matter can be
calculated in terms of oxygen equivalents.
Chemical Oxygen Demand (COD)
(Spectrophotometric)
EP026SP WATER
Preparation Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 Norg - D; APHA 4500 P - H. This method is compliant with NEPM (2013)
Schedule B(3)
TKN/TP Digestion EK061/EK067 WATER
In house: Referenced to USEPA SW846-3005. Method 3005 is a Nitric/Hydrochloric acid digestion procedure
used to prepare surface and ground water samples for analysis by ICPAES or ICPMS. This method is compliant
with NEPM (2013) Schedule B(3)
Digestion for Total Recoverable Metals EN25 WATER
A
CHAIN OF CUSTODY ~m~rg.l CLIENT: Emerge Associates POSTAL ADDRESS: Suite 4, 26 Railway Road, Subiaco WA 6008 r:ora11r. S,:,£:f".(i! ,\ Dcsnp -
PROJECT MANAGER: Simon Gregg CONTACT PHONE: 9380 4988
PROJECT ID.: EP15-050(05) PROJECT NAME: SAMR Monitoring - Davis Road
SAMPLER(S): Mitchell Ritikis SAMPLERS PHONE: 0449198 721
QUOTE NO.: EPBQ/009/16 ORDER NO.:
Comments/special handling/storage or disposal
PLEASE FORWARD TO ALS SYDNEY
SAMPLE DETAILS CONTAINER INFORMATION
Lab ID Sample ID r Matrix Date Type & Preservative
GWQA-16 Water I 31/05/2017 2 SP, 1VS, 2 P
RELINQUISHED BY:
Total No.
5
ANALYSIS REQUIRED
,2 .,,,l'! ~" ;:, "' 00 "' <O" - " 0.. ·-w E
X
RECEIVED BY
Additional information (likely contaminants, dilutions or specific QC analysis)
Mislabelled as GWQA02
Environmental Divisic,n Sydney
'Nork Order Reference
l=S1714019
I I.Ill Telephone: -r- 61-2-8784 8555
Coe emailed to ALS?
NAME: Mitchell Ritikis DATE: 02/06/2017 NAME: 1'J- DATE: :J /2s7D::l 0 Yes D No JI
II OF: Emerge Associates TIME: 9:30am OF: TIME: /5,'t:J(, •------
NAME: DATE: I NAME: DATE: Water Container Codes: P = Unpreserved Plastic; N = Nitric Preserved Plastic; ORC = Nitric Preserved ORC; SH = Sodium Hydroxide/Cd Preserved; S = Sodium Hydroxide-Preserved Plastic; AG - Amber Glass Unpreserved; AP= Airfreight Unpreserved Plastic; V =VOA Vial HCI Preserved; VB= VOA Vial Sodium Bisulphate Preserved; VS= VOA Vial Sulfuric Preserved; AV= Airfreight Unpreserved Vial; SG"' Sulfuric Preserved Amber Glass; H = HCI preserved Plastic; HS= HCI Preserved Speciation bottle: SP= Sulfuric Preserved Plastic; F = Formaldehyde Preserved Glass; Z = Zinc Acetate Preserved Bottle; E = EDTA Preserved Bottles; ST= Sterile Bottle; LI= Lugols Iodine Preserved Bottles; STT = Sterile Sodium
Container Codes: J = Jar; ASS = Plastic Bag for Acid Sulfate Soils; B = Unpreserved Bag;
{
(
A ii.,'nuoronmcn~,:,•
Total Dissolved Solids (TDS)- Std EAOl SH APHA 2540 C
Major Cations: Ca, Mg, Na, K NT·l APHA 3120
Major Anions: Cl, SO., Alkalinity NT-2 Various
APHA 4500 NH;- H
Total Nitrogen, TKN, NOx, NO,. NO,. NHi Total Phosphorus
APHA 4500 N«s/NO, APHA 4500 P - H
APHA 4500 P - G -~--j-----c--+--APHA 5220 B
NT-8
Chemical Oxrnen Demand (COD) EP026SP
10
0.01 TN: 0.1
9.00 --10.00
16.00
54.00
24,00
Carbon - Total Org_a_nic (TOC) I ___ EP0_~-~-- APHA 531 OB .. l . --~~-.. -·-.. Cd:0.0001
').1 00
8 Metals - Dissolved USEPA 6020, ICP/MS Zn:0.005
Others: 0.001 (As, Cd, Cr, Cu, Ni, Pb, Zn) W-2F 22.00
Hg CV/FIMS/ICP/MS 0.000.1 ----
Additional Dissolved Metals by ICPMS - EG020F USEPA 6020 ICPMS I 0.0001 - 0.01
Al, Mn,.~S'!e _____ ~--,-,-,--c-+------+--------t----~---1 --:: ~I-Recoverable Metals by ICPMS (incl
6,00
digest)~~ E.G020T USE.PA 6020 ICPMS 0.0001 · 0.01 12.00
ij~l_:.safuple ·cosr,JOr-~atE!r sample5:'(E,f(iS.TI: 177.00
General ALS Service Inclusions
The ALS service includes the following at no extra charge;
Provision of sample containers, appropriately prepared, labelled and preserved, eskies and freight for primary analytical test-work in major metropolitan areas Bottle Order Form ALS COC protocols including receipt notification and advice of any non-conformances plus a rapid advice of ALS batch/tracking numbers. WebtrieverM access to real time results and ALS technical support. WebtrieveTM EnviroMaif™ Local technical support via the ALS technical and management team Perth Contact List
Electronics results including COA, QC and DQO reports plus tailored formats such as ESDAT, EQulS and many others. EDDs - EQlHS and ESDAT info & support
Quality. Sampling, Submission. Holding Times and Automated DOO Reporting
ALS has a comprehensive best practice QA/QC program designed to provide highly defensible analytical data in accordance with NEPM, ANZECC, ADWG, NAGD guidelines. ALS provides Laboratory Control Samples (LCS), Method Blanks (MB), Matrix Spikes (MS), Laboratory Duplicates (Dups) and Surrogates (where applicable), at frequencies at or above the NEPM guidelines - revised 2013. Should you require further details please contact ALS customer services.
• ALS is NATA accredited for all tests listed in this proposal unless advised otherwise.
• For further information on short holding times please see: ALS Environmental· Pocket Guide 2014
• ALS QA/QC is reliant upon appropriate replicate samples battles/volumes especially for waters, air filters and sorbents. High contamination may negate ALS reporting of matrix spike recovery data.
• Please advise via COC where additional sample has been provided for QA/QC purposes e.g. by noting "Lab QC' (for both Dup and MS) or "Lab Dup" or "Lab MS".
• QA/QC, holding times, QC frequency and preservation compliance are summarised in ALS DQO reports to assist in quality review.
Quot@ EP/644/15 Emerge 4th S@pt@ml:ier 2015 Pag~ 2 of 5 --------RIGHT SOLUTIONS f RIGHT PARTNEH
~
I ~
Environmental
SAMPLE RECEIPT NOTIFICATION (SRN)Work Order : ES1714019
:: LaboratoryClient Environmental Division SydneyEMERGE ASSOCIATES
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA
6008
277-289 Woodpark Road Smithfield
NSW Australia 2164
:: E-mailE-mail simon.gregg@emergeassociates.co
m.au
LUKE.JONES@alsglobal.com
:: TelephoneTelephone +61 08 9380 4988 08 9209 7631
:: FacsimileFacsimile +61 08 9380 9636 +61-2-8784 8500
::Project EP15-050(05) SAMR Monitoring -
Davis Road
Page 1 of 3
:Order number ---- :Quote number EP2016EMEASS0001 (EPBQ-009-16)
:C-O-C number ---- :QC Level NEPM 2013 B3 & ALS QC Standard
Site : ----
Sampler : MITCHELL RITIKIS
DatesDate Samples Received : Issue Date : 08-Jun-201707-Jun-2017 15:00
Scheduled Reporting Date: 15-Jun-2017:Client Requested Due
Date
15-Jun-2017
Delivery DetailsMode of Delivery : :Undefined Intact.Security Seal
No. of coolers/boxes : :7 Temperature 13.5 - Ice present
: : 1 / 1Receipt Detail No. of samples received / analysed
General Comments
This report contains the following information:l
- Sample Container(s)/Preservation Non-Compliances
- Summary of Sample(s) and Requested Analysis
- Proactive Holding Time Report
- Requested Deliverables
l Please refer to the Proactive Holding Time Report table below which summarises breaches of
recommended holding times that have occurred prior to samples/instructions being received at
the laboratory. The absence of this summary table indicates that all samples have been received
within the recommended holding times for the analysis requested.l Please direct any queries you have regarding this work order to the above ALS laboratory contact.
l Analytical work for this work order will be conducted at ALS Sydney.
l Sample Disposal - Aqueous (14 days), Solid (60 days) from date of completion of work order.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
:Client EMERGE ASSOCIATES
Work Order : ES1714019 Amendment 02 of 3:Page
08-Jun-2017:Issue Date
Sample Container(s)/Preservation Non-Compliances
All comparisons are made against pretreatment/preservation AS, APHA, USEPA standards.
l No sample container / preservation non-compliance exists.
Summary of Sample(s) and Requested Analysis
Some items described below may be part of a laboratory
process necessary for the execution of client requested
tasks. Packages may contain additional analyses, such
as the determination of moisture content and preparation
tasks, that are included in the package.
If no sampling time is provided, the sampling time will
default 00:00 on the date of sampling. If no sampling date
is provided, the sampling date will be assumed by the
laboratory and displayed in brackets without a time
component
WA
TE
R -
ED
037-P
Alk
alin
ity a
s C
aC
O3 (
PC
T)
WA
TE
R -
ED
045G
Chlo
ride b
y D
iscr
ete
Analy
ser
WA
TE
R -
EG
020F
Dis
solv
ed M
eta
ls b
y IC
PM
S
WA
TE
R -
EP
026S
P
Chem
ical O
xygen D
em
and (
CO
D)
WA
TE
R -
NT
-01
Majo
r C
atio
ns
(Ca, M
g, N
a, K
)
WA
TE
R -
NT
-08
Tota
l Nitr
ogen +
NO
2 +
NO
3 +
NH
3 +
Tota
l P
WA
TE
R -
W-0
2
8 M
eta
ls
ES1714019-001 31-May-2017 00:00 GWQA-16 ü ü ü ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
WA
TE
R -
EA
01
5H
To
tal D
isso
lve
d S
olid
s -
Hig
h L
eve
l
WA
TE
R -
EG
02
0T
To
tal R
eco
vera
ble
Me
tals
by
ICP
MS
(in
clu
din
g
WA
TE
R -
EP
00
5
To
tal O
rga
nic
Ca
rbo
n (
TO
C)
ES1714019-001 31-May-2017 00:00 GWQA-16 ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
Proactive Holding Time Report
The following table summarises breaches of recommended holding times that have occurred prior to samples/instructions being
received at the laboratory.
Evaluation: û = Holding time breach ; ü = Within holding time. Matrix: WATER
EvaluationClient Sample ID(s)
Due for
extraction
Due for
analysis Evaluation
Samples Received Instructions Received
Date Date
Method
Container
EK057G: Nitrite as N by Discrete Analyser
GWQA-16 û --------07-Jun-201702-Jun-2017----Clear Plastic Bottle - Natural
I I I
I I I
: ! :
:Client EMERGE ASSOCIATES
Work Order : ES1714019 Amendment 03 of 3:Page
08-Jun-2017:Issue Date
Requested Deliverables
ACCOUNTS (INVOICES)
- A4 - AU Tax Invoice (INV) Email accounts@emergeassociates.com.
au
- Chain of Custody (CoC) (COC) Email accounts@emergeassociates.com.
au
JEREMY PAYET
- *AU Certificate of Analysis - NATA (COA) Email jeremy.payet@emergeassociates.co
m.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email jeremy.payet@emergeassociates.co
m.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email jeremy.payet@emergeassociates.co
m.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email jeremy.payet@emergeassociates.co
m.au
- Chain of Custody (CoC) (COC) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - ESDAT (ESDAT) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - XTab (XTAB) Email jeremy.payet@emergeassociates.co
m.au
MITCHELL RITIKIS
- *AU Certificate of Analysis - NATA (COA) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email mitchell.ritikis@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email mitchell.ritikis@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email mitchell.ritikis@emergeassociates.c
om.au
SIMON GREGG
- *AU Certificate of Analysis - NATA (COA) Email simon.gregg@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email simon.gregg@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email simon.gregg@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email simon.gregg@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email simon.gregg@emergeassociates.c
om.au
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 4ES1714019
:: LaboratoryClient EMERGE ASSOCIATES Environmental Division Sydney
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
277-289 Woodpark Road Smithfield NSW Australia 2164
:Telephone +61 08 9380 4988 :Telephone 08 9209 7631
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 07-Jun-2017 15:00
:Order number ---- Date Analysis Commenced : 08-Jun-2017
:C-O-C number ---- Issue Date : 16-Jun-2017 16:22
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EPBQ-009-16
1:No. of samples received
1:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:
l General Comments
l Analytical Results
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with
Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Celine Conceicao Senior Spectroscopist Sydney Inorganics, Smithfield, NSW
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with 1S0/IEC 17025 - Testing
2 of 4:Page
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:Client
ES1714019
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When no sampling time is provided, the sampling time will default 00:00 on the date of sampling. If no sampling date is provided, the sampling date will be assumed by the laboratory and displayed in brackets without a
time component.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
^ = This result is computed from individual analyte detections at or above the level of reporting
ø = ALS is not NATA accredited for these tests.
~ = Indicates an estimated value.
Key :
A
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Analytical Results
----------------GWQA-16Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------31-May-2017 00:00Client sampling date / time
--------------------------------ES1714019-001UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EA015: Total Dissolved Solids dried at 180 ± 5 °C
480 ---- ---- ---- ----mg/L10----Total Dissolved Solids @180°C
ED037P: Alkalinity by PC Titrator
<1Hydroxide Alkalinity as CaCO3 ---- ---- ---- ----mg/L1DMO-210-001
<1Carbonate Alkalinity as CaCO3 ---- ---- ---- ----mg/L13812-32-6
8Bicarbonate Alkalinity as CaCO3 ---- ---- ---- ----mg/L171-52-3
8 ---- ---- ---- ----mg/L1----Total Alkalinity as CaCO3
ED045G: Chloride by Discrete Analyser
213Chloride ---- ---- ---- ----mg/L116887-00-6
ED093F: Dissolved Major Cations
<1Calcium ---- ---- ---- ----mg/L17440-70-2
5Magnesium ---- ---- ---- ----mg/L17439-95-4
100Sodium ---- ---- ---- ----mg/L17440-23-5
<1Potassium ---- ---- ---- ----mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS
0.03Aluminium ---- ---- ---- ----mg/L0.017429-90-5
<0.001Arsenic ---- ---- ---- ----mg/L0.0017440-38-2
<0.0001Cadmium ---- ---- ---- ----mg/L0.00017440-43-9
<0.001Chromium ---- ---- ---- ----mg/L0.0017440-47-3
<0.001Copper ---- ---- ---- ----mg/L0.0017440-50-8
<0.001Nickel ---- ---- ---- ----mg/L0.0017440-02-0
<0.001Lead ---- ---- ---- ----mg/L0.0017439-92-1
0.021Zinc ---- ---- ---- ----mg/L0.0057440-66-6
0.004Manganese ---- ---- ---- ----mg/L0.0017439-96-5
<0.01Selenium ---- ---- ---- ----mg/L0.017782-49-2
EG020T: Total Metals by ICP-MS
51.6Iron ---- ---- ---- ----mg/L0.057439-89-6
EG035F: Dissolved Mercury by FIMS
<0.0001Mercury ---- ---- ---- ----mg/L0.00017439-97-6
EK055G: Ammonia as N by Discrete Analyser
0.47Ammonia as N ---- ---- ---- ----mg/L0.017664-41-7
EK057G: Nitrite as N by Discrete Analyser
<0.01Nitrite as N ---- ---- ---- ----mg/L0.0114797-65-0
EK058G: Nitrate as N by Discrete Analyser
0.02Nitrate as N ---- ---- ---- ----mg/L0.0114797-55-8
A
---------------
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Analytical Results
----------------GWQA-16Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------31-May-2017 00:00Client sampling date / time
--------------------------------ES1714019-001UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
0.02 ---- ---- ---- ----mg/L0.01----Nitrite + Nitrate as N
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser
0.9 ---- ---- ---- ----mg/L0.1----Total Kjeldahl Nitrogen as N
EK062G: Total Nitrogen as N (TKN + NOx) by Discrete Analyser
0.9^ ---- ---- ---- ----mg/L0.1----Total Nitrogen as N
EK067G: Total Phosphorus as P by Discrete Analyser
0.18 ---- ---- ---- ----mg/L0.01----Total Phosphorus as P
EP005: Total Organic Carbon (TOC)
3 ---- ---- ---- ----mg/L1----Total Organic Carbon
EP026SP: Chemical Oxygen Demand (Spectrophotometric)
23 ---- ---- ---- ----mg/L10----Chemical Oxygen Demand
A
False
2 2.00True
Environmental
QUALITY CONTROL REPORTWork Order : ES1714019 Page : 1 of 7
:: LaboratoryClient Environmental Division SydneyEMERGE ASSOCIATES
:Contact MR SIMON GREGG :Contact Luke Jones
:Address SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
Address : 277-289 Woodpark Road Smithfield NSW Australia 2164
::Telephone +61 08 9380 4988 08 9209 7631:Telephone
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 07-Jun-2017
:Order number ---- Date Analysis Commenced : 08-Jun-2017
:C-O-C number ---- Issue Date : 16-Jun-2017
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EPBQ-009-16
No. of samples received 1:
No. of samples analysed 1:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limits
l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits
l Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Celine Conceicao Senior Spectroscopist Sydney Inorganics, Smithfield, NSW
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with 150/IEC 17025 - Testing
2 of 7:Page
Work Order :
:Client
ES1714019
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
RPD = Relative Percentage Difference
# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) Report
The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges
for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:
No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QC Lot: 940585)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 666 606 9.59 0% - 20%Anonymous ES1713417-018
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 402 422 4.73 0% - 20%Anonymous ES1713942-004
ED037P: Alkalinity by PC Titrator (QC Lot: 934899)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous ES1714008-001
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 22 22 0.00 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 22 22 0.00 0% - 20%
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous ES1713965-002
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 615 614 0.195 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 615 614 0.195 0% - 20%
ED045G: Chloride by Discrete Analyser (QC Lot: 934667)
ED045G: Chloride 16887-00-6 1 mg/L 213 212 0.866 0% - 20%GWQA-16 ES1714019-001
ED045G: Chloride 16887-00-6 1 mg/L 106 105 0.00 0% - 20%Anonymous ES1714035-007
ED093F: Dissolved Major Cations (QC Lot: 940562)
ED093F: Calcium 7440-70-2 1 mg/L 25 27 7.75 0% - 20%Anonymous ES1713861-002
ED093F: Magnesium 7439-95-4 1 mg/L 4 4 0.00 No Limit
ED093F: Sodium 7440-23-5 1 mg/L 26 29 10.2 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 3 3 0.00 No Limit
ED093F: Calcium 7440-70-2 1 mg/L 18 18 0.00 0% - 50%Anonymous ES1713914-012
ED093F: Magnesium 7439-95-4 1 mg/L 6 6 0.00 No Limit
ED093F: Sodium 7440-23-5 1 mg/L 22 24 5.80 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 2 2 0.00 No Limit
EG020F: Dissolved Metals by ICP-MS (QC Lot: 940563)
A
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EG020F: Dissolved Metals by ICP-MS (QC Lot: 940563) - continued
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous ES1713888-001
EG020A-F: Arsenic 7440-38-2 0.001 mg/L 0.009 0.008 13.5 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.006 0.006 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L 0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 2.86 2.72 5.01 0% - 20%
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.009 0.007 27.9 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous ES1714023-002
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.048 0.049 2.85 0% - 20%
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 <0.005 0.00 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L 0.01 0.02 0.00 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020T: Total Metals by ICP-MS (QC Lot: 940462)
EG020A-T: Iron 7439-89-6 0.05 mg/L 51.6 52.6 1.91 0% - 20%GWQA-16 ES1714019-001
EG020A-T: Iron 7439-89-6 0.05 mg/L 1.58 1.60 1.10 0% - 20%Anonymous ES1713964-001
EG035F: Dissolved Mercury by FIMS (QC Lot: 940565)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous ES1714021-001
EK055G: Ammonia as N by Discrete Analyser (QC Lot: 937762)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L <1.00 <1.00 0.00 No LimitAnonymous ES1713984-001
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.07 0.06 0.00 No LimitAnonymous ES1714096-002
EK057G: Nitrite as N by Discrete Analyser (QC Lot: 934664)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous ES1713964-001
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous ES1714035-007
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QC Lot: 937763)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 0.02 0.04 62.4 No LimitAnonymous ES1713984-001
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 3.74 3.78 1.12 0% - 20%Anonymous ES1714096-002
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QC Lot: 937754)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 170 245 36.4 No LimitAnonymous ES1713973-001
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 0.7 0.7 0.00 No LimitAnonymous ES1714096-002
EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 937753)
EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.44 0.56 23.3 0% - 50%Anonymous ES1713973-001
A
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 937753) - continued
EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.15 0.14 0.00 0% - 50%Anonymous ES1714096-002
EP005: Total Organic Carbon (TOC) (QC Lot: 943906)
EP005: Total Organic Carbon ---- 1 mg/L 13 12 0.00 0% - 50%Anonymous ES1714031-001
EP005: Total Organic Carbon ---- 1 mg/L 13 14 0.00 0% - 50%Anonymous ES1714033-015
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QC Lot: 940874)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L 23 23 0.00 No LimitGWQA-16 ES1714019-001
A
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Method Blank (MB) and Laboratory Control Spike (LCS) Report
The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC
parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target
analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QCLot: 940585)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 98.62000 mg/L 10987
<10 108293 mg/L 12666
ED037P: Alkalinity by PC Titrator (QCLot: 934899)
ED037-P: Total Alkalinity as CaCO3 ---- ---- mg/L ---- 98.8200 mg/L 11181
ED045G: Chloride by Discrete Analyser (QCLot: 934667)
ED045G: Chloride 16887-00-6 1 mg/L <1 11610 mg/L 12781
<1 97.81000 mg/L 12781
ED093F: Dissolved Major Cations (QCLot: 940562)
ED093F: Calcium 7440-70-2 1 mg/L <1 98.950 mg/L 11480
ED093F: Magnesium 7439-95-4 1 mg/L <1 96.550 mg/L 11690
ED093F: Sodium 7440-23-5 1 mg/L <1 10650 mg/L 12082
ED093F: Potassium 7440-09-7 1 mg/L <1 96.250 mg/L 11385
EG020F: Dissolved Metals by ICP-MS (QCLot: 940563)
EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 96.10.5 mg/L 11680
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 98.00.1 mg/L 11485
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 91.60.1 mg/L 11084
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 90.30.1 mg/L 11185
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 1030.1 mg/L 11181
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 90.30.1 mg/L 11183
EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 1010.1 mg/L 11082
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 93.10.1 mg/L 11282
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 89.10.1 mg/L 11585
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 97.10.1 mg/L 11781
EG020T: Total Metals by ICP-MS (QCLot: 940462)
EG020A-T: Iron 7439-89-6 0.05 mg/L <0.05 95.60.5 mg/L 11785
EG035F: Dissolved Mercury by FIMS (QCLot: 940565)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 97.60.01 mg/L 10583
EK055G: Ammonia as N by Discrete Analyser (QCLot: 937762)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 1031 mg/L 11490
EK057G: Nitrite as N by Discrete Analyser (QCLot: 934664)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 95.00.5 mg/L 11482
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 937763)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 99.60.5 mg/L 11391
A
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 937754)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 70.210 mg/L 10169
<0.1 74.51 mg/L 11870
<0.1 87.35 mg/L 11874
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 937753)
EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 73.94.42 mg/L 10171
<0.01 78.10.442 mg/L 10872
<0.01 86.51 mg/L 11878
EP005: Total Organic Carbon (TOC) (QCLot: 943906)
EP005: Total Organic Carbon ---- 1 mg/L <1 83.410 mg/L 12072
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 940874)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L <10 10550 mg/L 11282
<10 101500 mg/L 11383
Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on
analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
ED045G: Chloride by Discrete Analyser (QCLot: 934667)
GWQA-16 ES1714019-001 16887-00-6ED045G: Chloride 105250 mg/L 13070
EG020F: Dissolved Metals by ICP-MS (QCLot: 940563)
Anonymous ES1713888-003 7440-38-2EG020A-F: Arsenic 1091 mg/L 13070
7440-43-9EG020A-F: Cadmium 1060.25 mg/L 13070
7440-47-3EG020A-F: Chromium 1051 mg/L 13070
7440-50-8EG020A-F: Copper 1071 mg/L 13070
7439-92-1EG020A-F: Lead 1031 mg/L 13070
7439-96-5EG020A-F: Manganese 1061 mg/L 13070
7440-02-0EG020A-F: Nickel 1051 mg/L 13070
7440-66-6EG020A-F: Zinc 1081 mg/L 13070
EG035F: Dissolved Mercury by FIMS (QCLot: 940565)
GWQA-16 ES1714019-001 7439-97-6EG035F: Mercury 80.40.01 mg/L 13070
EK055G: Ammonia as N by Discrete Analyser (QCLot: 937762)
Anonymous ES1713984-001 7664-41-7EK055G: Ammonia as N 1031 mg/L 13070
EK057G: Nitrite as N by Discrete Analyser (QCLot: 934664)
Anonymous ES1713964-001 14797-65-0EK057G: Nitrite as N 1000.5 mg/L 13070
A
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 937763)
Anonymous ES1713984-001 ----EK059G: Nitrite + Nitrate as N 1040.5 mg/L 13070
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 937754)
Anonymous ES1713984-001 ----EK061G: Total Kjeldahl Nitrogen as N 1015 mg/L 13070
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 937753)
Anonymous ES1713984-001 ----EK067G: Total Phosphorus as P 80.21 mg/L 13070
EP005: Total Organic Carbon (TOC) (QCLot: 943906)
Anonymous ES1714031-002 ----EP005: Total Organic Carbon 84.0100 mg/L 13070
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 940874)
GWQA-16 ES1714019-001 ----EP026SP: Chemical Oxygen Demand 10647.6 mg/L 13070
A
True
Environmental
QA/QC Compliance Assessment to assist with Quality ReviewWork Order : ES1714019 Page : 1 of 7
:: LaboratoryClient Environmental Division SydneyEMERGE ASSOCIATES
:Contact MR SIMON GREGG Telephone : 08 9209 7631
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 07-Jun-2017
Site : ---- Issue Date : 16-Jun-2017
MITCHELL RITIKIS:Sampler No. of samples received : 1
:Order number ---- No. of samples analysed : 1
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated
reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this
report contribute to the overall DQO assessment and reporting for guideline compliance.
Brief method summaries and references are also provided to assist in traceability.
Summary of Outliers
Outliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.
l NO Duplicate outliers occur.
l NO Laboratory Control outliers occur.
l NO Matrix Spike outliers occur.
l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliance
l Analysis Holding Time Outliers exist - please see following pages for full details.
Outliers : Frequency of Quality Control Samples
l Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Outliers : Analysis Holding Time Compliance
Matrix: WATER
AnalysisExtraction / Preparation
Date analysedDate extractedContainer / Client Sample ID(s) Days
overdue
Days
overdue
Due for extraction Due for analysis
Method
EA015: Total Dissolved Solids dried at 180 ± 5 °C
Clear Plastic Bottle - Natural
07-Jun-2017----GWQA-16 13-Jun-2017---- ---- 6
EK057G: Nitrite as N by Discrete Analyser
Clear Plastic Bottle - Natural
02-Jun-2017----GWQA-16 08-Jun-2017---- ---- 6
Outliers : Frequency of Quality Control Samples
Matrix: WATER
Quality Control SpecificationQuality Control Sample Type
Method ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC StandardTotal Metals by ICP-MS - Suite A 0.00 5.000 11
Analysis Holding Time Compliance
Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and
should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.
Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics
14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.
If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.
This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container
provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EA015: Total Dissolved Solids dried at 180 ± 5 °C
Clear Plastic Bottle - Natural (EA015H)
GWQA-16 07-Jun-2017---- 13-Jun-2017----31-May-2017 ---- ûED037P: Alkalinity by PC Titrator
Clear Plastic Bottle - Natural (ED037-P)
GWQA-16 14-Jun-2017---- 08-Jun-2017----31-May-2017 ---- üED045G: Chloride by Discrete Analyser
Clear Plastic Bottle - Natural (ED045G)
GWQA-16 28-Jun-2017---- 08-Jun-2017----31-May-2017 ---- üED093F: Dissolved Major Cations
Clear Plastic Bottle - Filtered; Lab-acidified (ED093F)
GWQA-16 28-Jun-2017---- 13-Jun-2017----31-May-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EG020F: Dissolved Metals by ICP-MS
Clear Plastic Bottle - Filtered; Lab-acidified (EG020A-F)
GWQA-16 27-Nov-2017---- 13-Jun-2017----31-May-2017 ---- üEG020T: Total Metals by ICP-MS
Clear Plastic Bottle - Unfiltered; Lab-acidified (EG020A-T)
GWQA-16 27-Nov-201727-Nov-2017 13-Jun-201713-Jun-201731-May-2017 ü üEG035F: Dissolved Mercury by FIMS
Clear Plastic Bottle - Filtered; Lab-acidified (EG035F)
GWQA-16 28-Jun-2017---- 14-Jun-2017----31-May-2017 ---- üEK055G: Ammonia as N by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK055G)
GWQA-16 28-Jun-2017---- 10-Jun-2017----31-May-2017 ---- üEK057G: Nitrite as N by Discrete Analyser
Clear Plastic Bottle - Natural (EK057G)
GWQA-16 02-Jun-2017---- 08-Jun-2017----31-May-2017 ---- ûEK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK059G)
GWQA-16 28-Jun-2017---- 10-Jun-2017----31-May-2017 ---- üEK061G: Total Kjeldahl Nitrogen By Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK061G)
GWQA-16 28-Jun-201728-Jun-2017 10-Jun-201710-Jun-201731-May-2017 ü üEK067G: Total Phosphorus as P by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK067G)
GWQA-16 28-Jun-201728-Jun-2017 10-Jun-201710-Jun-201731-May-2017 ü üEP005: Total Organic Carbon (TOC)
Amber TOC Vial - Sulfuric Acid (EP005)
GWQA-16 28-Jun-2017---- 09-Jun-2017----31-May-2017 ---- üEP026SP: Chemical Oxygen Demand (Spectrophotometric)
Clear Plastic Bottle - Sulfuric Acid (EP026SP)
GWQA-16 28-Jun-2017---- 13-Jun-2017----31-May-2017 ---- ü
A
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Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to
the expected rate. A listing of breaches is provided in the Summary of Outliers.
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC Standard 10.53 10.002 19 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 33.33 10.001 3 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 18.18 10.002 11 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 11.11 10.001 9 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 13.33 10.002 15 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 40.00 10.002 5 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 22.22 10.002 9 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 18.18 10.002 11 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Phosphorus as P By Discrete Analyser EK067G
Laboratory Control Samples (LCS)
NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 66.67 10.002 3 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 18.18 10.002 11 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 15.00 15.003 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 15.00 15.003 20 üTotal Phosphorus as P By Discrete Analyser EK067G
Method Blanks (MB)
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 33.33 5.001 3 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üMajor Cations - Dissolved ED093F
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Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Method Blanks (MB) - Continued
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067G
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 33.33 5.001 3 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 11.11 5.001 9 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 11 ûTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067G
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Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the
Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 2540C. A gravimetric procedure that determines the amount of `filterable` residue
in an aqueous sample. A well-mixed sample is filtered through a glass fibre filter (1.2um). The filtrate is
evaporated to dryness and dried to constant weight at 180+/-5C. This method is compliant with NEPM (2013)
Schedule B(3)
Total Dissolved Solids (High Level) EA015H WATER
In house: Referenced to APHA 2320 B This procedure determines alkalinity by automated measurement (e.g. PC
Titrate) using pH 4.5 for indicating the total alkalinity end-point. This method is compliant with NEPM (2013)
Schedule B(3)
Alkalinity by PC Titrator ED037-P WATER
In house: Referenced to APHA 4500 Cl - G.The thiocyanate ion is liberated from mercuric thiocyanate through
sequestration of mercury by the chloride ion to form non-ionised mercuric chloride.in the presence of ferric ions
the librated thiocynate forms highly-coloured ferric thiocynate which is measured at 480 nm APHA 21st edition
seal method 2 017-1-L april 2003
Chloride by Discrete Analyser ED045G WATER
In house: Referenced to APHA 3120 and 3125; USEPA SW 846 - 6010 and 6020; Cations are determined by
either ICP-AES or ICP-MS techniques. This method is compliant with NEPM (2013) Schedule B(3)
Sodium Adsorption Ratio is calculated from Ca, Mg and Na which determined by ALS in house method
QWI-EN/ED093F. This method is compliant with NEPM (2013) Schedule B(3)
Hardness parameters are calculated based on APHA 2340 B. This method is compliant with NEPM (2013)
Schedule B(3)
Major Cations - Dissolved ED093F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. Samples are 0.45µm filtered
prior to analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions
are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct
mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Dissolved Metals by ICP-MS - Suite A EG020A-F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. The ICPMS technique utilizes
a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass
spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their
measurement by a discrete dynode ion detector.
Total Metals by ICP-MS - Suite A EG020A-T WATER
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS)
Samples are 0.45µm filtered prior to analysis. FIM-AAS is an automated flameless atomic absorption technique.
A bromate/bromide reagent is used to oxidise any organic mercury compounds in the filtered sample. The ionic
mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell.
Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM
(2013) Schedule B(3)
Dissolved Mercury by FIMS EG035F WATER
In house: Referenced to APHA 4500-NH3 G Ammonia is determined by direct colorimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Ammonia as N by Discrete analyser EK055G WATER
In house: Referenced to APHA 4500-NO2- B. Nitrite is determined by direct colourimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Nitrite as N by Discrete Analyser EK057G WATER
A
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Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500-NO3- F. Nitrate is reduced to nitrite by way of a chemical reduction followed
by quantification by Discrete Analyser. Nitrite is determined seperately by direct colourimetry and result for Nitrate
calculated as the difference between the two results. This method is compliant with NEPM (2013) Schedule B(3)
Nitrate as N by Discrete Analyser EK058G WATER
In house: Referenced to APHA 4500-NO3- F. Combined oxidised Nitrogen (NO2+NO3) is determined by
Chemical Reduction and direct colourimetry by Discrete Analyser. This method is compliant with NEPM (2013)
Schedule B(3)
Nitrite and Nitrate as N (NOx) by Discrete
Analyser
EK059G WATER
In house: Referenced to APHA 4500-Norg D (In house). An aliquot of sample is digested using a high
temperature Kjeldahl digestion to convert nitrogenous compounds to ammonia. Ammonia is determined
colorimetrically by discrete analyser. This method is compliant with NEPM (2013) Schedule B(3)
Total Kjeldahl Nitrogen as N By Discrete
Analyser
EK061G WATER
In house: Referenced to APHA 4500-Norg / 4500-NO3-. This method is compliant with NEPM (2013) Schedule
B(3)
Total Nitrogen as N (TKN + Nox) By
Discrete Analyser
EK062G WATER
In house: Referenced to APHA 4500-P H, Jirka et al (1976), Zhang et al (2006). This procedure involves
sulphuric acid digestion of a sample aliquot to break phosphorus down to orthophosphate. The orthophosphate
reacts with ammonium molybdate and antimony potassium tartrate to form a complex which is then reduced and
its concentration measured at 880nm using discrete analyser. This method is compliant with NEPM (2013)
Schedule B(3)
Total Phosphorus as P By Discrete
Analyser
EK067G WATER
In house: Referenced to APHA 5310 B, The automated TOC analyzer determines Total and Inorganic Carbon by
IR cell. TOC is calculated as the difference. This method is compliant with NEPM (2013) Schedule B(3)
Total Organic Carbon EP005 WATER
In house: Referenced to APHA 5220 D. Samples are digested with a known excess of an acidic potassium
dichromate solution using silver sulfate as a catalyst. The chromium is reduced from the Cr (VI) oxidation state
to the Cr (III) state by the oxygen present in the organic material. Both of these chromium species are coloued
and absorb in the visible region of (400nm & 600nm) the spectrum. The oxidisable organic matter can be
calculated in terms of oxygen equivalents.
Chemical Oxygen Demand (COD)
(Spectrophotometric)
EP026SP WATER
Preparation Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 Norg - D; APHA 4500 P - H. This method is compliant with NEPM (2013)
Schedule B(3)
TKN/TP Digestion EK061/EK067 WATER
In house: Referenced to USEPA SW846-3005. Method 3005 is a Nitric/Hydrochloric acid digestion procedure
used to prepare surface and ground water samples for analysis by ICPAES or ICPMS. This method is compliant
with NEPM (2013) Schedule B(3)
Digestion for Total Recoverable Metals EN25 WATER
A
CHAIN OF CUSTODY CLIENT: Emerge Associates POSTAL ADDRESS: Suite 4, 26 Railway Road, Subiaco WA 6008
PROJECT \MANAGER: Simon Gregg CONTACT PHONE: 9380 4988
rage 1 of 1
~m~rgl) inieor.ated Science &: De:s1~o
PROJECT ID.: EP15-050(05) PROJECT NAME: SAMR Mon~oring -Davis Road
SAMPLER(S): Mitchell Ritikis SAMPLERS PHONE: 0449 198 721 11§■1 , _____________ , ________ ,,,,,_
QUOTE NO.: EPBQ/009/16 ORDER NO.: associates.com.au; mitchell.ritikis@emergeassociates.com.au;
SAMPLE DETAILS
Lab ID Sample ID Matrix
' M1 Water
2 i P1 ' Water
·········3 P2 Water
GWQA17
Comments/special handling/storage or disposal Email invoice to: accounts@emergeassociates.com.au
ANALYSIS REQUIRED
Date
05/09/2017
06/09/2017
05/09/2017
"'
CONTAINER INFORMATION
Type & Preservative
- 0 ~ 0 cc .., "' 0
0-'= ·ro ' a_ :,-BI .. "" "' -a:<( cc"'
.QZ ,r a_ - ro e> t:,Z~ O:, Total ,_ X a_
~~u ~ -No. ' "' I- u sl!'o Z-
2 SP, 3 P, 3 V, 1 AG ~;-.,--7-:c:----~--;cc----t--+-
2 SP, 3 P, 3 V, 1 AG
9 X 9 I I
X
.-c--c-=----t---;cc---1 --+--2 SP, 3 P, 3 V, 1 AG
X X
I X __ __ __ 2 SP, 3 P, 3 V, 1 AG 0!i/OA/2017 ~ X X
"a_ ~ I-_
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"§ ~§ :c zz 0
X X
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X X
X X
.€ -~ rn 0 "' 0 X 0 0 0 :,: 0 I- I-
X X X X
X X X X
X X X X
X X X X I Water I!---~--:.;,... -----+ I
i lz c ":, Ou, Additional information .., :, 0..J (likely contaminants, - 0. 230>_ dilutions or specific QC
l .{~ ~ analysis) ~~ffi cc 3=&~ g
X X
X X
X X
X X [ Mislabelled as Dup1
Environ'mental Division Perth
Work Order Reference
EP1709780
I 1111 r elepf1ona : ... 61-8-9209 7655
RELINQUISHED BY: RECEIVED BY CoC emailed to ALS?
NAME : Mitchell Ritikis
OF: Emerge Associates
NAME:
DATE: 07/09/2017 NAME: r;)p_ /,.,.j,,c:,,\.J1 ri DATE:]' Y' IS] Yes O No I
_TIME: 9:30a_r11______ OF: L-t\.,J TIME: /"742,t DATE: NAME: DATE:
Water Container Codes: P = Unpreserved Plastic; N = Nitric Preserved Plastic; ORC = Nitric Preserved ORC; SH = Sodium Hydroxide/Cd Preserved; S =Sodium-Hydroxide Preserved--P/astic; AG= Amber Grass Unp~.e$8rved; AP= Airfreight Unpreserved Plastic; V = VOA Via HCI Preserved; VB= VOA Vial Sodium Bisulphate Preserved; VS= VOA Vial SIJfuric Preserved; AV= Airfreight Unpreserved Vial; SG = Sulfuric Preserved Amber Glass; H = HCI preserved Plastic; HS= HCI Preserved Speciation bottle; SP= Sulfuric Preserved Plastic; F = Formaldehyde Preserved Glass; Z = Zinc Acetate Preserved BotUe; E = EDTA Preserved Bottles; ST= Sterile BJ.rtle; LI= Lugols Iodine Preserved Bottles; STT = Sterile Sodium Thiosu/fate Preserved Bottles. Soil Container Codes: J = Jar; ASS= Plastic Bag for Ac·1d Sulfate §_oils; 8
•
Environmental
SAMPLE RECEIPT NOTIFICATION (SRN)Work Order : EP1709780
:: LaboratoryClient Environmental Division PerthEMERGE ASSOCIATES
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA
6008
10 Hod Way Malaga WA Australia 6090
:: E-mailE-mail simon.gregg@emergeassociates.co
m.au
LUKE.JONES@alsglobal.com
:: TelephoneTelephone +61 08 9380 4988 08 9209 7631
:: FacsimileFacsimile +61 08 9380 9636 +61-8-9209 7600
::Project EP15-050(05) SAMR Monitoring -
Davis Road
Page 1 of 3
:Order number ---- :Quote number EP2016EMEASS0001 (EPBQ-009-16)
:C-O-C number ---- :QC Level NEPM 2013 B3 & ALS QC Standard
Site : ----
Sampler : MITCHELL RITIKIS
DatesDate Samples Received : Issue Date : 07-Sep-201707-Sep-2017 12:08
Scheduled Reporting Date: 14-Sep-2017:Client Requested Due
Date
14-Sep-2017
Delivery DetailsMode of Delivery : :Carrier Not AvailableSecurity Seal
No. of coolers/boxes : :4 Temperature 5.0 - Ice present
: : 4 / 4Receipt Detail No. of samples received / analysed
General Comments
This report contains the following information:l
- Sample Container(s)/Preservation Non-Compliances
- Summary of Sample(s) and Requested Analysis
- Proactive Holding Time Report
- Requested Deliverables
l Please see scanned COC for sample discrepencies: extra samples , samples not received etc.
l Please direct any queries related to sample condition / numbering / breakages to Sample Receipt (SamplesPerth@alsenviro.com)
l Analytical work for this work order will be conducted at ALS Environmental Perth.
l Please direct any turnaround / technical queries to the laboratory contact designated above.
l Sample Disposal - Aqueous (14 days), Solid (60 days) from date of completion of Work Order.
l COD analysis will be conducted by ALS Environmental, Sydney, NATA accreditation no. 825, Site
No. 10911.l pH analysis should be conducted within 6 hours of sampling.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
:Client EMERGE ASSOCIATES
Work Order : EP1709780 Amendment 02 of 3:Page
07-Sep-2017:Issue Date
Sample Container(s)/Preservation Non-Compliances
All comparisons are made against pretreatment/preservation AS, APHA, USEPA standards.
l No sample container / preservation non-compliance exists.
Summary of Sample(s) and Requested Analysis
Some items described below may be part of a laboratory
process necessary for the execution of client requested
tasks. Packages may contain additional analyses, such
as the determination of moisture content and preparation
tasks, that are included in the package.
If no sampling time is provided, the sampling time will
default 00:00 on the date of sampling. If no sampling date
is provided, the sampling date will be assumed by the
laboratory and displayed in brackets without a time
component
WA
TE
R -
ED
037-P
Alk
alin
ity a
s C
aC
O3 (
PC
T)
WA
TE
R -
ED
045G
Chlo
ride b
y D
iscr
ete
Analy
ser
WA
TE
R -
EG
020A
-F
Dis
solv
ed M
eta
ls b
y IC
PM
S -
Suite
A
WA
TE
R -
EP
026S
P
Chem
ical O
xygen D
em
and (
CO
D)
WA
TE
R -
NT
-01
Majo
r C
atio
ns
(Ca, M
g, N
a, K
)
WA
TE
R -
NT
-08
Tota
l Nitr
ogen +
NO
2 +
NO
3 +
NH
3 +
Tota
l P
WA
TE
R -
W-0
2
8 M
eta
ls
EP1709780-001 05-Sep-2017 00:00 M1 ü ü ü ü ü ü ü
EP1709780-002 06-Sep-2017 00:00 P1 ü ü ü ü ü ü ü
EP1709780-003 05-Sep-2017 00:00 P2 ü ü ü ü ü ü ü
EP1709780-004 05-Sep-2017 00:00 GWQA17 ü ü ü ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
WA
TE
R -
EA
01
5H
To
tal D
isso
lve
d S
olid
s -
Hig
h L
eve
l
WA
TE
R -
EG
02
0A
-T
To
tal M
eta
ls b
y IC
PM
S -
Su
ite A
WA
TE
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EP
00
5
To
tal O
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nic
Ca
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TO
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WA
TE
R -
W-1
7
TR
H/B
TE
XN
/PA
H/P
he
no
ls/O
C/P
CB
EP1709780-001 05-Sep-2017 00:00 M1 ü ü ü ü
EP1709780-002 06-Sep-2017 00:00 P1 ü ü ü ü
EP1709780-003 05-Sep-2017 00:00 P2 ü ü ü ü
EP1709780-004 05-Sep-2017 00:00 GWQA17 ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
Proactive Holding Time Report
Sample(s) have been received within the recommended holding times for the requested analysis.
:Client EMERGE ASSOCIATES
Work Order : EP1709780 Amendment 03 of 3:Page
07-Sep-2017:Issue Date
Requested Deliverables
ACCOUNTS (INVOICES)
- A4 - AU Tax Invoice (INV) Email accounts@emergeassociates.com.
au
- Chain of Custody (CoC) (COC) Email accounts@emergeassociates.com.
au
JEREMY PAYET
- *AU Certificate of Analysis - NATA (COA) Email jeremy.payet@emergeassociates.co
m.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email jeremy.payet@emergeassociates.co
m.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email jeremy.payet@emergeassociates.co
m.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email jeremy.payet@emergeassociates.co
m.au
- Chain of Custody (CoC) (COC) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - ESDAT (ESDAT) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - XTab (XTAB) Email jeremy.payet@emergeassociates.co
m.au
MITCHELL RITIKIS
- *AU Certificate of Analysis - NATA (COA) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email mitchell.ritikis@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email mitchell.ritikis@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email mitchell.ritikis@emergeassociates.c
om.au
SIMON GREGG
- *AU Certificate of Analysis - NATA (COA) Email simon.gregg@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email simon.gregg@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email simon.gregg@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email simon.gregg@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email simon.gregg@emergeassociates.c
om.au
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 8EP1709780
:: LaboratoryClient EMERGE ASSOCIATES Environmental Division Perth
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
10 Hod Way Malaga WA Australia 6090
:Telephone +61 08 9380 4988 :Telephone 08 9209 7631
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 07-Sep-2017 12:08
:Order number ---- Date Analysis Commenced : 07-Sep-2017
:C-O-C number ---- Issue Date : 13-Sep-2017 20:26
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EPBQ-009-16
4:No. of samples received
4:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:
l General Comments
l Analytical Results
l Surrogate Control Limits
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with
Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Canhuang Ke Metals Instrument Chemist Perth Inorganics, Malaga, WA
David Viner SENIOR LAB TECH Perth Organics, Malaga, WA
Jeremy Truong Laboratory Manager Perth Inorganics, Malaga, WA
ShukHui Li Client Services - Technical Manager Perth Organics, Malaga, WA
Tyrone Cole Inorganics Preparation Supervisor Perth Inorganics, Malaga, WA
Vanessa Nguyen Organic Chemist Perth Organics, Malaga, WA
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with 1S0/IEC 17025 - Testing
2 of 8:Page
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:Client
EP1709780
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When no sampling time is provided, the sampling time will default 00:00 on the date of sampling. If no sampling date is provided, the sampling date will be assumed by the laboratory and displayed in brackets without a
time component.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
^ = This result is computed from individual analyte detections at or above the level of reporting
ø = ALS is not NATA accredited for these tests.
~ = Indicates an estimated value.
Key :
COD conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.l
Benzo(a)pyrene Toxicity Equivalent Quotient (TEQ) is the sum total of the concentration of the eight carcinogenic PAHs multiplied by their Toxicity Equivalence Factor (TEF) relative to Benzo(a)pyrene. TEF values
are provided in brackets as follows: Benz(a)anthracene (0.1), Chrysene (0.01), Benzo(b+j) & Benzo(k)fluoranthene (0.1), Benzo(a)pyrene (1.0), Indeno(1.2.3.cd)pyrene (0.1), Dibenz(a.h)anthracene (1.0),
Benzo(g.h.i)perylene (0.01). Less than LOR results for 'TEQ Zero' are treated as zero.
l
A
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:Client
EP1709780
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
----GWQA17P2P1M1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----05-Sep-2017 00:0005-Sep-2017 00:0006-Sep-2017 00:0005-Sep-2017 00:00Client sampling date / time
--------EP1709780-004EP1709780-003EP1709780-002EP1709780-001UnitLORCAS NumberCompound
Result Result Result Result ----
EA015: Total Dissolved Solids dried at 180 ± 5 °C
120 239 177 124 ----mg/L10----Total Dissolved Solids @180°C
ED037P: Alkalinity by PC Titrator
<1Hydroxide Alkalinity as CaCO3 <1 <1 <1 ----mg/L1DMO-210-001
<1Carbonate Alkalinity as CaCO3 <1 <1 <1 ----mg/L13812-32-6
24Bicarbonate Alkalinity as CaCO3 197 51 23 ----mg/L171-52-3
24 197 51 23 ----mg/L1----Total Alkalinity as CaCO3
ED045G: Chloride by Discrete Analyser
52Chloride 16 59 53 ----mg/L116887-00-6
ED093F: Dissolved Major Cations
5Calcium 53 16 5 ----mg/L17440-70-2
6Magnesium 5 8 6 ----mg/L17439-95-4
32Sodium 9 37 32 ----mg/L17440-23-5
3Potassium 2 5 3 ----mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS
0.04Aluminium 0.02 <0.01 0.04 ----mg/L0.017429-90-5
<0.001Arsenic <0.001 <0.001 <0.001 ----mg/L0.0017440-38-2
<0.0001Cadmium <0.0001 <0.0001 <0.0001 ----mg/L0.00017440-43-9
<0.001Chromium <0.001 <0.001 <0.001 ----mg/L0.0017440-47-3
<0.001Copper <0.001 <0.001 <0.001 ----mg/L0.0017440-50-8
0.002Manganese 0.081 <0.001 0.002 ----mg/L0.0017439-96-5
<0.001Nickel <0.001 <0.001 <0.001 ----mg/L0.0017440-02-0
<0.001Lead <0.001 <0.001 <0.001 ----mg/L0.0017439-92-1
<0.01Selenium <0.01 <0.01 <0.01 ----mg/L0.017782-49-2
<0.005Zinc 0.013 <0.005 <0.005 ----mg/L0.0057440-66-6
EG020T: Total Metals by ICP-MS
0.72Iron 31.3 0.39 0.74 ----mg/L0.057439-89-6
EG035F: Dissolved Mercury by FIMS
<0.0001Mercury <0.0001 <0.0001 <0.0001 ----mg/L0.00017439-97-6
EK055G: Ammonia as N by Discrete Analyser
0.06Ammonia as N 0.43 0.02 0.06 ----mg/L0.017664-41-7
EK057G: Nitrite as N by Discrete Analyser
<0.01Nitrite as N <0.01 <0.01 <0.01 ----mg/L0.0114797-65-0
EK058G: Nitrate as N by Discrete Analyser
0.09Nitrate as N 0.01 0.24 0.10 ----mg/L0.0114797-55-8
A
---------------
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:Client
EP1709780
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
----GWQA17P2P1M1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----05-Sep-2017 00:0005-Sep-2017 00:0006-Sep-2017 00:0005-Sep-2017 00:00Client sampling date / time
--------EP1709780-004EP1709780-003EP1709780-002EP1709780-001UnitLORCAS NumberCompound
Result Result Result Result ----
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
0.09 0.01 0.24 0.10 ----mg/L0.01----Nitrite + Nitrate as N
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser
0.1 1.7 <0.1 <0.1 ----mg/L0.1----Total Kjeldahl Nitrogen as N
EK062G: Total Nitrogen as N (TKN + NOx) by Discrete Analyser
0.2^ 1.7 0.2 0.1 ----mg/L0.1----Total Nitrogen as N
EK067G: Total Phosphorus as P by Discrete Analyser
<0.01 0.39 <0.01 <0.01 ----mg/L0.01----Total Phosphorus as P
EP005: Total Organic Carbon (TOC)
3 8 <1 3 ----mg/L1----Total Organic Carbon
EP026SP: Chemical Oxygen Demand (Spectrophotometric)
21 45 26 <10 ----mg/L10----Chemical Oxygen Demand
EP066: Polychlorinated Biphenyls (PCB)
<1 <1 <1 <1 ----µg/L1----Total Polychlorinated biphenyls
EP068A: Organochlorine Pesticides (OC)
<0.5alpha-BHC <0.5 <0.5 <0.5 ----µg/L0.5319-84-6
<0.5Hexachlorobenzene (HCB) <0.5 <0.5 <0.5 ----µg/L0.5118-74-1
<0.5beta-BHC <0.5 <0.5 <0.5 ----µg/L0.5319-85-7
<0.5gamma-BHC <0.5 <0.5 <0.5 ----µg/L0.558-89-9
<0.5delta-BHC <0.5 <0.5 <0.5 ----µg/L0.5319-86-8
<0.5Heptachlor <0.5 <0.5 <0.5 ----µg/L0.576-44-8
<0.5Aldrin <0.5 <0.5 <0.5 ----µg/L0.5309-00-2
<0.5Heptachlor epoxide <0.5 <0.5 <0.5 ----µg/L0.51024-57-3
<0.5trans-Chlordane <0.5 <0.5 <0.5 ----µg/L0.55103-74-2
<0.5alpha-Endosulfan <0.5 <0.5 <0.5 ----µg/L0.5959-98-8
<0.5cis-Chlordane <0.5 <0.5 <0.5 ----µg/L0.55103-71-9
<0.5Dieldrin <0.5 <0.5 <0.5 ----µg/L0.560-57-1
<0.54.4`-DDE <0.5 <0.5 <0.5 ----µg/L0.572-55-9
<0.5Endrin <0.5 <0.5 <0.5 ----µg/L0.572-20-8
<0.5beta-Endosulfan <0.5 <0.5 <0.5 ----µg/L0.533213-65-9
<0.54.4`-DDD <0.5 <0.5 <0.5 ----µg/L0.572-54-8
<0.5Endrin aldehyde <0.5 <0.5 <0.5 ----µg/L0.57421-93-4
<0.5Endosulfan sulfate <0.5 <0.5 <0.5 ----µg/L0.51031-07-8
<2.04.4`-DDT <2.0 <2.0 <2.0 ----µg/L2.050-29-3
<0.5Endrin ketone <0.5 <0.5 <0.5 ----µg/L0.553494-70-5
A
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:Client
EP1709780
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EMERGE ASSOCIATES
Analytical Results
----GWQA17P2P1M1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----05-Sep-2017 00:0005-Sep-2017 00:0006-Sep-2017 00:0005-Sep-2017 00:00Client sampling date / time
--------EP1709780-004EP1709780-003EP1709780-002EP1709780-001UnitLORCAS NumberCompound
Result Result Result Result ----
EP068A: Organochlorine Pesticides (OC) - Continued
<2.0Methoxychlor <2.0 <2.0 <2.0 ----µg/L2.072-43-5
<0.5^ <0.5 <0.5 <0.5 ----µg/L0.5----Total Chlordane (sum)
<0.5^ Sum of DDD + DDE + DDT <0.5 <0.5 <0.5 ----µg/L0.572-54-8/72-55-9/5
0-2
<0.5^ Sum of Aldrin + Dieldrin <0.5 <0.5 <0.5 ----µg/L0.5309-00-2/60-57-1
EP075(SIM)A: Phenolic Compounds
<1.0Phenol <1.0 <1.0 <1.0 ----µg/L1.0108-95-2
<1.02-Chlorophenol <1.0 <1.0 <1.0 ----µg/L1.095-57-8
<1.02-Methylphenol <1.0 <1.0 <1.0 ----µg/L1.095-48-7
<2.03- & 4-Methylphenol <2.0 <2.0 <2.0 ----µg/L2.01319-77-3
<1.02-Nitrophenol <1.0 <1.0 <1.0 ----µg/L1.088-75-5
<1.02.4-Dimethylphenol <1.0 <1.0 <1.0 ----µg/L1.0105-67-9
<1.02.4-Dichlorophenol <1.0 <1.0 <1.0 ----µg/L1.0120-83-2
<1.02.6-Dichlorophenol <1.0 <1.0 <1.0 ----µg/L1.087-65-0
<1.04-Chloro-3-methylphenol <1.0 <1.0 <1.0 ----µg/L1.059-50-7
<1.02.4.6-Trichlorophenol <1.0 <1.0 <1.0 ----µg/L1.088-06-2
<1.02.4.5-Trichlorophenol <1.0 <1.0 <1.0 ----µg/L1.095-95-4
<2.0Pentachlorophenol <2.0 <2.0 <2.0 ----µg/L2.087-86-5
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
<1.0Naphthalene <1.0 <1.0 <1.0 ----µg/L1.091-20-3
<1.0Acenaphthylene <1.0 <1.0 <1.0 ----µg/L1.0208-96-8
<1.0Acenaphthene <1.0 <1.0 <1.0 ----µg/L1.083-32-9
<1.0Fluorene <1.0 <1.0 <1.0 ----µg/L1.086-73-7
<1.0Phenanthrene <1.0 <1.0 <1.0 ----µg/L1.085-01-8
<1.0Anthracene <1.0 <1.0 <1.0 ----µg/L1.0120-12-7
<1.0Fluoranthene <1.0 <1.0 <1.0 ----µg/L1.0206-44-0
<1.0Pyrene <1.0 <1.0 <1.0 ----µg/L1.0129-00-0
<1.0Benz(a)anthracene <1.0 <1.0 <1.0 ----µg/L1.056-55-3
<1.0Chrysene <1.0 <1.0 <1.0 ----µg/L1.0218-01-9
<1.0Benzo(b+j)fluoranthene <1.0 <1.0 <1.0 ----µg/L1.0205-99-2 205-82-3
<1.0Benzo(k)fluoranthene <1.0 <1.0 <1.0 ----µg/L1.0207-08-9
<0.5Benzo(a)pyrene <0.5 <0.5 <0.5 ----µg/L0.550-32-8
<1.0Indeno(1.2.3.cd)pyrene <1.0 <1.0 <1.0 ----µg/L1.0193-39-5
<1.0Dibenz(a.h)anthracene <1.0 <1.0 <1.0 ----µg/L1.053-70-3
<1.0Benzo(g.h.i)perylene <1.0 <1.0 <1.0 ----µg/L1.0191-24-2
A
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EP1709780
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
----GWQA17P2P1M1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----05-Sep-2017 00:0005-Sep-2017 00:0006-Sep-2017 00:0005-Sep-2017 00:00Client sampling date / time
--------EP1709780-004EP1709780-003EP1709780-002EP1709780-001UnitLORCAS NumberCompound
Result Result Result Result ----
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued
<0.5^ <0.5 <0.5 <0.5 ----µg/L0.5----Sum of polycyclic aromatic hydrocarbons
<0.5^ <0.5 <0.5 <0.5 ----µg/L0.5----Benzo(a)pyrene TEQ (zero)
EP080/071: Total Petroleum Hydrocarbons
<20 <20 <20 <20 ----µg/L20----C6 - C9 Fraction
<50 <50 <50 <50 ----µg/L50----C10 - C14 Fraction
<100 <100 <100 <100 ----µg/L100----C15 - C28 Fraction
<50 <50 <50 <50 ----µg/L50----C29 - C36 Fraction
<50^ <50 <50 <50 ----µg/L50----C10 - C36 Fraction (sum)
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
<20C6 - C10 Fraction <20 <20 <20 ----µg/L20C6_C10
<20^ C6 - C10 Fraction minus BTEX
(F1)
<20 <20 <20 ----µg/L20C6_C10-BTEX
<100 <100 <100 <100 ----µg/L100---->C10 - C16 Fraction
<100 <100 <100 <100 ----µg/L100---->C16 - C34 Fraction
<100 <100 <100 <100 ----µg/L100---->C34 - C40 Fraction
<100^ <100 <100 <100 ----µg/L100---->C10 - C40 Fraction (sum)
<100^ <100 <100 <100 ----µg/L100---->C10 - C16 Fraction minus Naphthalene
(F2)
EP080: BTEXN
<1Benzene <1 <1 <1 ----µg/L171-43-2
<2Toluene <2 <2 <2 ----µg/L2108-88-3
<2Ethylbenzene <2 <2 <2 ----µg/L2100-41-4
<2meta- & para-Xylene <2 <2 <2 ----µg/L2108-38-3 106-42-3
<2ortho-Xylene <2 <2 <2 ----µg/L295-47-6
<2^ Total Xylenes <2 <2 <2 ----µg/L21330-20-7
<1^ <1 <1 <1 ----µg/L1----Sum of BTEX
<5Naphthalene <5 <5 <5 ----µg/L591-20-3
EP066S: PCB Surrogate
115Decachlorobiphenyl 105 114 107 ----%12051-24-3
EP068S: Organochlorine Pesticide Surrogate
94.5Dibromo-DDE 80.5 96.8 90.2 ----%0.521655-73-2
EP068T: Organophosphorus Pesticide Surrogate
81.6DEF 70.2 88.3 85.8 ----%0.578-48-8
EP075(SIM)S: Phenolic Compound Surrogates
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EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
----GWQA17P2P1M1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----05-Sep-2017 00:0005-Sep-2017 00:0006-Sep-2017 00:0005-Sep-2017 00:00Client sampling date / time
--------EP1709780-004EP1709780-003EP1709780-002EP1709780-001UnitLORCAS NumberCompound
Result Result Result Result ----
EP075(SIM)S: Phenolic Compound Surrogates - Continued
26.1Phenol-d6 23.4 25.3 28.8 ----%1.013127-88-3
73.62-Chlorophenol-D4 63.6 68.0 72.6 ----%1.093951-73-6
1002.4.6-Tribromophenol 89.0 88.0 92.9 ----%1.0118-79-6
EP075(SIM)T: PAH Surrogates
85.02-Fluorobiphenyl 71.4 77.9 80.8 ----%1.0321-60-8
92.4Anthracene-d10 77.3 83.3 87.2 ----%1.01719-06-8
98.44-Terphenyl-d14 85.2 94.5 93.3 ----%1.01718-51-0
EP080S: TPH(V)/BTEX Surrogates
98.81.2-Dichloroethane-D4 106 97.6 104 ----%217060-07-0
96.7Toluene-D8 93.4 97.1 96.0 ----%22037-26-5
92.94-Bromofluorobenzene 93.2 91.9 92.9 ----%2460-00-4
A
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Surrogate Control Limits
Recovery Limits (%)Sub-Matrix: WATER
Compound CAS Number Low High
EP066S: PCB Surrogate
Decachlorobiphenyl 2051-24-3 27 136
EP068S: Organochlorine Pesticide Surrogate
Dibromo-DDE 21655-73-2 50 146
EP068T: Organophosphorus Pesticide Surrogate
DEF 78-48-8 27 153
EP075(SIM)S: Phenolic Compound Surrogates
Phenol-d6 13127-88-3 10 67
2-Chlorophenol-D4 93951-73-6 29 120
2.4.6-Tribromophenol 118-79-6 10 131
EP075(SIM)T: PAH Surrogates
2-Fluorobiphenyl 321-60-8 34 131
Anthracene-d10 1719-06-8 43 127
4-Terphenyl-d14 1718-51-0 41 142
EP080S: TPH(V)/BTEX Surrogates
1.2-Dichloroethane-D4 17060-07-0 61 141
Toluene-D8 2037-26-5 73 126
4-Bromofluorobenzene 460-00-4 60 125
A
False
7 7.00False
Environmental
QUALITY CONTROL REPORTWork Order : EP1709780 Page : 1 of 9
:: LaboratoryClient Environmental Division PerthEMERGE ASSOCIATES
:Contact MR SIMON GREGG :Contact Luke Jones
:Address SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
Address : 10 Hod Way Malaga WA Australia 6090
::Telephone +61 08 9380 4988 08 9209 7631:Telephone
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 07-Sep-2017
:Order number ---- Date Analysis Commenced : 07-Sep-2017
:C-O-C number ---- Issue Date : 13-Sep-2017
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EPBQ-009-16
No. of samples received 4:
No. of samples analysed 4:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limits
l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits
l Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Canhuang Ke Metals Instrument Chemist Perth Inorganics, Malaga, WA
David Viner SENIOR LAB TECH Perth Organics, Malaga, WA
Jeremy Truong Laboratory Manager Perth Inorganics, Malaga, WA
ShukHui Li Client Services - Technical Manager Perth Organics, Malaga, WA
Tyrone Cole Inorganics Preparation Supervisor Perth Inorganics, Malaga, WA
Vanessa Nguyen Organic Chemist Perth Organics, Malaga, WA
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with 150/IEC 17025 - Testing
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General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
RPD = Relative Percentage Difference
# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) Report
The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges
for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:
No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QC Lot: 1107222)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 3230 3200 1.18 0% - 20%Anonymous EP1709662-004
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 196 198 0.760 0% - 50%Anonymous EP1709778-007
ED037P: Alkalinity by PC Titrator (QC Lot: 1105014)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EP1709778-006
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 39 32 18.6 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 39 32 18.6 0% - 20%
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EP1709442-001
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 115 117 1.13 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 115 117 1.13 0% - 20%
ED045G: Chloride by Discrete Analyser (QC Lot: 1100182)
ED045G: Chloride 16887-00-6 1 mg/L 168 173 2.96 0% - 20%Anonymous EP1709778-002
ED045G: Chloride 16887-00-6 1 mg/L 53 53 0.00 0% - 20%GWQA17 EP1709780-004
ED093F: Dissolved Major Cations (QC Lot: 1106838)
ED093F: Calcium 7440-70-2 1 mg/L 12 12 0.00 0% - 50%Anonymous EP1709681-005
ED093F: Magnesium 7439-95-4 1 mg/L 12 12 0.00 0% - 50%
ED093F: Sodium 7440-23-5 1 mg/L 17 17 0.00 0% - 50%
ED093F: Potassium 7440-09-7 1 mg/L 4 4 0.00 No Limit
ED093F: Calcium 7440-70-2 1 mg/L 2 2 0.00 No LimitAnonymous EP1709778-005
ED093F: Magnesium 7439-95-4 1 mg/L 22 22 0.00 0% - 20%
ED093F: Sodium 7440-23-5 1 mg/L 177 177 0.00 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 4 4 0.00 No Limit
EG020F: Dissolved Metals by ICP-MS (QC Lot: 1106836)
A
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EG020F: Dissolved Metals by ICP-MS (QC Lot: 1106836) - continued
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EP1709778-003
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.589 0.597 1.34 0% - 20%
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.001 <0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.011 0.010 0.00 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L 0.04 0.03 0.00 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EP1709681-001
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 <0.005 0.00 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020T: Total Metals by ICP-MS (QC Lot: 1104311)
EG020A-T: Iron 7439-89-6 0.05 mg/L 0.96 0.98 3.04 0% - 50%Anonymous EP1709778-006
EG020A-T: Iron 7439-89-6 0.05 mg/L 0.07 0.12 48.2 No LimitAnonymous EP1709809-001
EG035F: Dissolved Mercury by FIMS (QC Lot: 1106839)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EP1709681-003
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EP1709778-004
EK055G: Ammonia as N by Discrete Analyser (QC Lot: 1100185)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.79 0.82 2.76 0% - 20%Anonymous EP1709766-002
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.02 0.02 0.00 No LimitAnonymous EP1709778-005
EK057G: Nitrite as N by Discrete Analyser (QC Lot: 1100181)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EP1709778-002
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No LimitGWQA17 EP1709780-004
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QC Lot: 1100186)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 0.30 0.30 0.00 0% - 20%Anonymous EP1709766-002
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 0.02 0.04 70.6 No LimitAnonymous EP1709778-005
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QC Lot: 1104429)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 64.6 62.2 3.76 0% - 20%Anonymous EP1709766-001
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 0.4 0.5 0.00 No LimitAnonymous EP1709778-002
EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 1104428)
A
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 1104428) - continued
EK067G: Total Phosphorus as P ---- 0.01 mg/L 8.38 8.96 6.68 0% - 20%Anonymous EP1709766-001
EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EP1709778-002
EP005: Total Organic Carbon (TOC) (QC Lot: 1101910)
EP005: Total Organic Carbon ---- 1 mg/L 1 <1 0.00 No LimitAnonymous EP1709751-001
EP005: Total Organic Carbon ---- 1 mg/L 3 <1 104 No LimitAnonymous EP1709778-002
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QC Lot: 1107645)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L 612 612 0.00 0% - 20%Anonymous EP1709766-001
EP026SP: Chemical Oxygen Demand ---- 10 mg/L 18 18 0.00 No LimitAnonymous EP1709778-004
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 1105276)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitAnonymous EP1709769-001
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitM1 EP1709780-001
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 1105276)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitAnonymous EP1709769-001
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitM1 EP1709780-001
EP080: BTEXN (QC Lot: 1105276)
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitAnonymous EP1709769-001
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitM1 EP1709780-001
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
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Method Blank (MB) and Laboratory Control Spike (LCS) Report
The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC
parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target
analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QCLot: 1107222)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 1002000 mg/L 11183
<10 97.01000 mg/L 13070
ED037P: Alkalinity by PC Titrator (QCLot: 1105014)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-00
1
1 mg/L <1 -------- --------
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 -------- --------
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L <1 -------- --------
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L <1 10220 mg/L 12676
<1 104200 mg/L 10690
ED045G: Chloride by Discrete Analyser (QCLot: 1100182)
ED045G: Chloride 16887-00-6 1 mg/L <1 10010 mg/L 12084
<1 1001000 mg/L 11084
ED093F: Dissolved Major Cations (QCLot: 1106838)
ED093F: Calcium 7440-70-2 1 mg/L <1 98.150 mg/L 10991
ED093F: Magnesium 7439-95-4 1 mg/L <1 10850 mg/L 10890
ED093F: Sodium 7440-23-5 1 mg/L <1 93.450 mg/L 11187
ED093F: Potassium 7440-09-7 1 mg/L <1 10850 mg/L 11090
EG020F: Dissolved Metals by ICP-MS (QCLot: 1106836)
EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 1030.5 mg/L 12084
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 1140.1 mg/L 12084
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 1060.1 mg/L 12086
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 1040.1 mg/L 12085
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 1070.1 mg/L 12084
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 1070.1 mg/L 12085
EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 1110.1 mg/L 12085
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 99.80.1 mg/L 12084
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 1130.1 mg/L 12088
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 1110.1 mg/L 12089
EG020T: Total Metals by ICP-MS (QCLot: 1104311)
EG020A-T: Iron 7439-89-6 0.05 mg/L <0.05 1130.5 mg/L 12077
EG035F: Dissolved Mercury by FIMS (QCLot: 1106839)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 1120.01 mg/L 11692
EK055G: Ammonia as N by Discrete Analyser (QCLot: 1100185)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 1031 mg/L 11587
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EK057G: Nitrite as N by Discrete Analyser (QCLot: 1100181)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 1020.5 mg/L 11286
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 1100186)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 1030.5 mg/L 11292
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 1104429)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 90.710 mg/L 11082
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 1104428)
EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 84.04.42 mg/L 13070
EP005: Total Organic Carbon (TOC) (QCLot: 1101910)
EP005: Total Organic Carbon ---- 1 mg/L <1 91.610 mg/L 11179
<1 101100 mg/L 11179
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 1107645)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L <10 10550 mg/L 11282
<10 95.6500 mg/L 11383
EP066: Polychlorinated Biphenyls (PCB) (QCLot: 1100062)
EP066: Total Polychlorinated biphenyls ---- 1 µg/L <1 56.05 µg/L 9036
EP068A: Organochlorine Pesticides (OC) (QCLot: 1100063)
EP068: alpha-BHC 319-84-6 0.5 µg/L <0.5 63.85 µg/L 11242
EP068: Hexachlorobenzene (HCB) 118-74-1 0.5 µg/L <0.5 53.35 µg/L 10839
EP068: beta-BHC 319-85-7 0.5 µg/L <0.5 62.35 µg/L 11646
EP068: gamma-BHC 58-89-9 0.5 µg/L <0.5 61.65 µg/L 11843
EP068: delta-BHC 319-86-8 0.5 µg/L <0.5 61.75 µg/L 11546
EP068: Heptachlor 76-44-8 0.5 µg/L <0.5 55.55 µg/L 11139
EP068: Aldrin 309-00-2 0.5 µg/L <0.5 62.95 µg/L 11440
EP068: Heptachlor epoxide 1024-57-3 0.5 µg/L <0.5 70.05 µg/L 12242
EP068: trans-Chlordane 5103-74-2 0.5 µg/L <0.5 71.55 µg/L 12144
EP068: alpha-Endosulfan 959-98-8 0.5 µg/L <0.5 65.95 µg/L 12942
EP068: cis-Chlordane 5103-71-9 0.5 µg/L <0.5 66.65 µg/L 12343
EP068: Dieldrin 60-57-1 0.5 µg/L <0.5 69.35 µg/L 12142
EP068: 4.4`-DDE 72-55-9 0.5 µg/L <0.5 75.55 µg/L 12344
EP068: Endrin 72-20-8 0.5 µg/L <0.5 97.25 µg/L 12727
EP068: beta-Endosulfan 33213-65-9 0.5 µg/L <0.5 65.95 µg/L 12845
EP068: 4.4`-DDD 72-54-8 0.5 µg/L <0.5 66.85 µg/L 12842
EP068: Endrin aldehyde 7421-93-4 0.5 µg/L <0.5 89.55 µg/L 12132
EP068: Endosulfan sulfate 1031-07-8 0.5 µg/L <0.5 69.35 µg/L 12041
EP068: 4.4`-DDT 50-29-3 2 µg/L <2.0 74.05 µg/L 12332
EP068: Endrin ketone 53494-70-5 0.5 µg/L <0.5 76.05 µg/L 12436
EP068: Methoxychlor 72-43-5 2 µg/L <2.0 53.05 µg/L 12425
EP075(SIM)A: Phenolic Compounds (QCLot: 1100061)
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP075(SIM)A: Phenolic Compounds (QCLot: 1100061) - continued
EP075(SIM): Phenol 108-95-2 1 µg/L <1.0 16.210 µg/L 469
EP075(SIM): 2-Chlorophenol 95-57-8 1 µg/L <1.0 49.310 µg/L 9734
EP075(SIM): 2-Methylphenol 95-48-7 1 µg/L <1.0 37.510 µg/L 9325
EP075(SIM): 3- & 4-Methylphenol 1319-77-3 2 µg/L <2.0 33.520 µg/L 8322
EP075(SIM): 2-Nitrophenol 88-75-5 1 µg/L <1.0 52.910 µg/L 10434
EP075(SIM): 2.4-Dimethylphenol 105-67-9 1 µg/L <1.0 46.810 µg/L 10234
EP075(SIM): 2.4-Dichlorophenol 120-83-2 1 µg/L <1.0 49.610 µg/L 10434
EP075(SIM): 2.6-Dichlorophenol 87-65-0 1 µg/L <1.0 56.510 µg/L 10238
EP075(SIM): 4-Chloro-3-methylphenol 59-50-7 1 µg/L <1.0 52.710 µg/L 10630
EP075(SIM): 2.4.6-Trichlorophenol 88-06-2 1 µg/L <1.0 56.310 µg/L 10932
EP075(SIM): 2.4.5-Trichlorophenol 95-95-4 1 µg/L <1.0 52.710 µg/L 11034
EP075(SIM): Pentachlorophenol 87-86-5 2 µg/L <2.0 70.810 µg/L 10414
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 1100061)
EP075(SIM): Naphthalene 91-20-3 1 µg/L <1.0 57.810 µg/L 9942
EP075(SIM): Acenaphthylene 208-96-8 1 µg/L <1.0 59.310 µg/L 11336
EP075(SIM): Acenaphthene 83-32-9 1 µg/L <1.0 57.610 µg/L 10236
EP075(SIM): Fluorene 86-73-7 1 µg/L <1.0 62.410 µg/L 11334
EP075(SIM): Phenanthrene 85-01-8 1 µg/L <1.0 67.810 µg/L 11537
EP075(SIM): Anthracene 120-12-7 1 µg/L <1.0 59.210 µg/L 10946
EP075(SIM): Fluoranthene 206-44-0 1 µg/L <1.0 65.810 µg/L 12440
EP075(SIM): Pyrene 129-00-0 1 µg/L <1.0 66.010 µg/L 12340
EP075(SIM): Benz(a)anthracene 56-55-3 1 µg/L <1.0 66.310 µg/L 12640
EP075(SIM): Chrysene 218-01-9 1 µg/L <1.0 69.110 µg/L 12146
EP075(SIM): Benzo(b+j)fluoranthene 205-99-2
205-82-3
1 µg/L <1.0 78.910 µg/L 12343
EP075(SIM): Benzo(k)fluoranthene 207-08-9 1 µg/L <1.0 72.410 µg/L 12147
EP075(SIM): Benzo(a)pyrene 50-32-8 0.5 µg/L <0.5 68.610 µg/L 12345
EP075(SIM): Indeno(1.2.3.cd)pyrene 193-39-5 1 µg/L <1.0 69.210 µg/L 12039
EP075(SIM): Dibenz(a.h)anthracene 53-70-3 1 µg/L <1.0 68.810 µg/L 11939
EP075(SIM): Benzo(g.h.i)perylene 191-24-2 1 µg/L <1.0 67.510 µg/L 12340
EP075(SIM): Sum of polycyclic aromatic hydrocarbons ---- 0.5 µg/L <0.5 -------- --------
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1100060)
EP071: C10 - C14 Fraction ---- 50 µg/L <50 73.0385 µg/L 9535
EP071: C15 - C28 Fraction ---- 100 µg/L <100 78.7385 µg/L 11134
EP071: C29 - C36 Fraction ---- 50 µg/L <50 76.4398 µg/L 10534
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1105276)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 94.0320 µg/L 11374
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 1100060)
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 1100060) - continued
EP071: >C10 - C16 Fraction ---- 100 µg/L <100 76.8380 µg/L 9937
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 78.2597 µg/L 10835
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 71.4168 µg/L 11711
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 1105276)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 96.4370 µg/L 11574
EP080: BTEXN (QCLot: 1105276)
EP080: Benzene 71-43-2 1 µg/L <1 94.920 µg/L 11484
EP080: Toluene 108-88-3 2 µg/L <2 85.720 µg/L 11581
EP080: Ethylbenzene 100-41-4 2 µg/L <2 85.220 µg/L 11384
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 87.840 µg/L 11484
EP080: ortho-Xylene 95-47-6 2 µg/L <2 87.120 µg/L 11187
EP080: Naphthalene 91-20-3 5 µg/L <5 99.720 µg/L 11877
Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on
analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
ED045G: Chloride by Discrete Analyser (QCLot: 1100182)
Anonymous EP1709778-001 16887-00-6ED045G: Chloride 1041000 mg/L 13070
EG020F: Dissolved Metals by ICP-MS (QCLot: 1106836)
Anonymous EP1709681-002 7440-38-2EG020A-F: Arsenic 1030.2 mg/L 13070
7440-43-9EG020A-F: Cadmium 1020.05 mg/L 13070
7440-47-3EG020A-F: Chromium 98.80.2 mg/L 13070
7440-50-8EG020A-F: Copper 1020.2 mg/L 13070
7439-92-1EG020A-F: Lead 1030.2 mg/L 13070
7439-96-5EG020A-F: Manganese 1040.2 mg/L 13070
7440-02-0EG020A-F: Nickel 95.40.2 mg/L 13070
7440-66-6EG020A-F: Zinc 1050.2 mg/L 13070
EG035F: Dissolved Mercury by FIMS (QCLot: 1106839)
Anonymous EP1709681-004 7439-97-6EG035F: Mercury 1130.01 mg/L 13070
EK055G: Ammonia as N by Discrete Analyser (QCLot: 1100185)
Anonymous EP1709766-001 7664-41-7EK055G: Ammonia as N # Not
Determined
1 mg/L 13070
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EK057G: Nitrite as N by Discrete Analyser (QCLot: 1100181)
Anonymous EP1709766-001 14797-65-0EK057G: Nitrite as N 1040.5 mg/L 13070
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 1100186)
Anonymous EP1709766-001 ----EK059G: Nitrite + Nitrate as N 1200.5 mg/L 13070
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 1104429)
Anonymous EP1709766-001 ----EK061G: Total Kjeldahl Nitrogen as N 76.525 mg/L 13070
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 1104428)
Anonymous EP1709766-001 ----EK067G: Total Phosphorus as P 79.75 mg/L 13070
EP005: Total Organic Carbon (TOC) (QCLot: 1101910)
Anonymous EP1709751-002 ----EP005: Total Organic Carbon 105100 mg/L 13070
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 1107645)
Anonymous EP1709766-001 ----EP026SP: Chemical Oxygen Demand 110582 mg/L 13070
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1105276)
Anonymous EP1709769-002 ----EP080: C6 - C9 Fraction 77.0240 µg/L 13777
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 1105276)
Anonymous EP1709769-002 C6_C10EP080: C6 - C10 Fraction 77.3290 µg/L 13777
EP080: BTEXN (QCLot: 1105276)
Anonymous EP1709769-002 71-43-2EP080: Benzene 78.220 µg/L 12277
108-88-3EP080: Toluene 74.420 µg/L 12674
A
True
Environmental
QA/QC Compliance Assessment to assist with Quality ReviewWork Order : EP1709780 Page : 1 of 11
:: LaboratoryClient Environmental Division PerthEMERGE ASSOCIATES
:Contact MR SIMON GREGG Telephone : 08 9209 7631
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 07-Sep-2017
Site : ---- Issue Date : 13-Sep-2017
MITCHELL RITIKIS:Sampler No. of samples received : 4
:Order number ---- No. of samples analysed : 4
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated
reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this
report contribute to the overall DQO assessment and reporting for guideline compliance.
Brief method summaries and references are also provided to assist in traceability.
Summary of Outliers
Outliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.
l NO Duplicate outliers occur.
l NO Laboratory Control outliers occur.
l Matrix Spike outliers exist - please see following pages for full details.
l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliance
l NO Analysis Holding Time Outliers exist.
Outliers : Frequency of Quality Control Samples
l Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Outliers : Quality Control Samples
Duplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes
Matrix: WATER
Compound Group Name CommentLimitsDataAnalyteClient Sample IDLaboratory Sample ID CAS Number
Matrix Spike (MS) Recoveries
EP1709766--001 7664-41-7Ammonia as NAnonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EK055G: Ammonia as N by Discrete Analyser
Outliers : Frequency of Quality Control Samples
Matrix: WATER
Quality Control SpecificationQuality Control Sample Type
Method ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 10.000 10
NEPM 2013 B3 & ALS QC StandardPesticides by GCMS 0.00 10.000 4
NEPM 2013 B3 & ALS QC StandardPolychlorinated Biphenyls (PCB) 0.00 10.000 4
NEPM 2013 B3 & ALS QC StandardTRH - Semivolatile Fraction 0.00 10.000 14
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 5.000 10
NEPM 2013 B3 & ALS QC StandardPesticides by GCMS 0.00 5.000 4
NEPM 2013 B3 & ALS QC StandardPolychlorinated Biphenyls (PCB) 0.00 5.000 4
NEPM 2013 B3 & ALS QC StandardTotal Metals by ICP-MS - Suite A 0.00 5.000 13
NEPM 2013 B3 & ALS QC StandardTRH - Semivolatile Fraction 0.00 5.000 14
Analysis Holding Time Compliance
Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and
should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.
Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics
14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.
If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.
This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container
provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EA015: Total Dissolved Solids dried at 180 ± 5 °C
Clear Plastic Bottle - Natural (EA015H)
M1, P2,
GWQA17
12-Sep-2017---- 12-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Natural (EA015H)
P1 13-Sep-2017---- 12-Sep-2017----06-Sep-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
ED037P: Alkalinity by PC Titrator
Clear Plastic Bottle - Natural (ED037-P)
M1, P2,
GWQA17
19-Sep-2017---- 11-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Natural (ED037-P)
P1 20-Sep-2017---- 11-Sep-2017----06-Sep-2017 ---- üED045G: Chloride by Discrete Analyser
Clear Plastic Bottle - Natural (ED045G)
M1, P2,
GWQA17
03-Oct-2017---- 07-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Natural (ED045G)
P1 04-Oct-2017---- 07-Sep-2017----06-Sep-2017 ---- üED093F: Dissolved Major Cations
Clear Plastic Bottle - Filtered; Lab-acidified (ED093F)
M1, P2,
GWQA17
03-Oct-2017---- 12-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Filtered; Lab-acidified (ED093F)
P1 04-Oct-2017---- 12-Sep-2017----06-Sep-2017 ---- üEG020F: Dissolved Metals by ICP-MS
Clear Plastic Bottle - Filtered; Lab-acidified (EG020A-F)
M1, P2,
GWQA17
04-Mar-2018---- 12-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Filtered; Lab-acidified (EG020A-F)
P1 05-Mar-2018---- 12-Sep-2017----06-Sep-2017 ---- üEG020T: Total Metals by ICP-MS
Clear Plastic Bottle - Unfiltered; Lab-acidified (EG020A-T)
M1, P2,
GWQA17
04-Mar-201804-Mar-2018 12-Sep-201712-Sep-201705-Sep-2017 ü ü
Clear Plastic Bottle - Unfiltered; Lab-acidified (EG020A-T)
P1 05-Mar-201805-Mar-2018 12-Sep-201712-Sep-201706-Sep-2017 ü üEG035F: Dissolved Mercury by FIMS
Clear Plastic Bottle - Filtered; Lab-acidified (EG035F)
M1, P2,
GWQA17
03-Oct-2017---- 12-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Filtered; Lab-acidified (EG035F)
P1 04-Oct-2017---- 12-Sep-2017----06-Sep-2017 ---- üEK055G: Ammonia as N by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK055G)
M1, P2,
GWQA17
03-Oct-2017---- 07-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Sulfuric Acid (EK055G)
P1 04-Oct-2017---- 07-Sep-2017----06-Sep-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EK057G: Nitrite as N by Discrete Analyser
Clear Plastic Bottle - Natural (EK057G)
M1, P2,
GWQA17
07-Sep-2017---- 07-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Natural (EK057G)
P1 08-Sep-2017---- 07-Sep-2017----06-Sep-2017 ---- üEK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK059G)
M1, P2,
GWQA17
03-Oct-2017---- 07-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Sulfuric Acid (EK059G)
P1 04-Oct-2017---- 07-Sep-2017----06-Sep-2017 ---- üEK061G: Total Kjeldahl Nitrogen By Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK061G)
M1, P2,
GWQA17
03-Oct-201703-Oct-2017 12-Sep-201712-Sep-201705-Sep-2017 ü ü
Clear Plastic Bottle - Sulfuric Acid (EK061G)
P1 04-Oct-201704-Oct-2017 12-Sep-201712-Sep-201706-Sep-2017 ü üEK067G: Total Phosphorus as P by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK067G)
M1, P2,
GWQA17
03-Oct-201703-Oct-2017 12-Sep-201712-Sep-201705-Sep-2017 ü ü
Clear Plastic Bottle - Sulfuric Acid (EK067G)
P1 04-Oct-201704-Oct-2017 12-Sep-201712-Sep-201706-Sep-2017 ü üEP005: Total Organic Carbon (TOC)
Amber TOC Vial - Sulfuric Acid (EP005)
M1, P2,
GWQA17
03-Oct-2017---- 08-Sep-2017----05-Sep-2017 ---- ü
Amber TOC Vial - Sulfuric Acid (EP005)
P1 04-Oct-2017---- 08-Sep-2017----06-Sep-2017 ---- üEP026SP: Chemical Oxygen Demand (Spectrophotometric)
Clear Plastic Bottle - Sulfuric Acid (EP026SP)
M1, P2,
GWQA17
03-Oct-2017---- 12-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Sulfuric Acid (EP026SP)
P1 04-Oct-2017---- 12-Sep-2017----06-Sep-2017 ---- üEP066: Polychlorinated Biphenyls (PCB)
Amber Glass Bottle - Unpreserved (EP066)
M1, P2,
GWQA17
21-Oct-201712-Sep-2017 12-Sep-201711-Sep-201705-Sep-2017 ü ü
Amber Glass Bottle - Unpreserved (EP066)
P1 21-Oct-201713-Sep-2017 12-Sep-201711-Sep-201706-Sep-2017 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP068A: Organochlorine Pesticides (OC)
Amber Glass Bottle - Unpreserved (EP068)
M1, P2,
GWQA17
21-Oct-201712-Sep-2017 12-Sep-201711-Sep-201705-Sep-2017 ü ü
Amber Glass Bottle - Unpreserved (EP068)
P1 21-Oct-201713-Sep-2017 12-Sep-201711-Sep-201706-Sep-2017 ü üEP075(SIM)A: Phenolic Compounds
Amber Glass Bottle - Unpreserved (EP075(SIM))
M1, P2,
GWQA17
21-Oct-201712-Sep-2017 12-Sep-201711-Sep-201705-Sep-2017 ü ü
Amber Glass Bottle - Unpreserved (EP075(SIM))
P1 21-Oct-201713-Sep-2017 12-Sep-201711-Sep-201706-Sep-2017 ü üEP075(SIM)B: Polynuclear Aromatic Hydrocarbons
Amber Glass Bottle - Unpreserved (EP075(SIM))
M1, P2,
GWQA17
21-Oct-201712-Sep-2017 12-Sep-201711-Sep-201705-Sep-2017 ü ü
Amber Glass Bottle - Unpreserved (EP075(SIM))
P1 21-Oct-201713-Sep-2017 12-Sep-201711-Sep-201706-Sep-2017 ü üEP080/071: Total Petroleum Hydrocarbons
Amber Glass Bottle - Unpreserved (EP071)
M1, P2,
GWQA17
21-Oct-201712-Sep-2017 12-Sep-201711-Sep-201705-Sep-2017 ü ü
Amber Glass Bottle - Unpreserved (EP071)
P1 21-Oct-201713-Sep-2017 12-Sep-201711-Sep-201706-Sep-2017 ü üAmber VOC Vial - Sulfuric Acid (EP080)
M1, P2,
GWQA17
19-Sep-201719-Sep-2017 12-Sep-201712-Sep-201705-Sep-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
P1 20-Sep-201720-Sep-2017 12-Sep-201712-Sep-201706-Sep-2017 ü üEP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
Amber Glass Bottle - Unpreserved (EP071)
M1, P2,
GWQA17
21-Oct-201712-Sep-2017 12-Sep-201711-Sep-201705-Sep-2017 ü ü
Amber Glass Bottle - Unpreserved (EP071)
P1 21-Oct-201713-Sep-2017 12-Sep-201711-Sep-201706-Sep-2017 ü üAmber VOC Vial - Sulfuric Acid (EP080)
M1, P2,
GWQA17
19-Sep-201719-Sep-2017 12-Sep-201712-Sep-201705-Sep-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
P1 20-Sep-201720-Sep-2017 12-Sep-201712-Sep-201706-Sep-2017 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP080: BTEXN
Amber VOC Vial - Sulfuric Acid (EP080)
M1, P2,
GWQA17
19-Sep-201719-Sep-2017 12-Sep-201712-Sep-201705-Sep-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
P1 20-Sep-201720-Sep-2017 12-Sep-201712-Sep-201706-Sep-2017 ü ü
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Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to
the expected rate. A listing of breaches is provided in the Summary of Outliers.
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC Standard 12.50 10.002 16 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 10.53 10.002 19 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 18.18 10.002 11 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 10 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 4 ûPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 4 ûPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 14.29 10.002 14 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 15.38 10.002 13 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 14 ûTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTRH Volatiles/BTEX EP080
Laboratory Control Samples (LCS)
NEPM 2013 B3 & ALS QC Standard 12.50 10.002 16 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 10.53 10.002 19 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 18.18 10.002 11 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 14.29 10.002 14 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 7.69 5.001 13 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Organic Carbon EP005
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Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Control Samples (LCS) - Continued
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH Volatiles/BTEX EP080
Method Blanks (MB)
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 25.00 5.001 4 üPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 7.69 5.001 13 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH Volatiles/BTEX EP080
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 10 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 4 ûPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 4 ûPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 13 ûTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 14 ûTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH Volatiles/BTEX EP080
9 of 11:Page
Work Order :
:Client
EP1709780
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the
Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 2540C. A gravimetric procedure that determines the amount of `filterable` residue
in an aqueous sample. A well-mixed sample is filtered through a glass fibre filter (1.2um). The filtrate is
evaporated to dryness and dried to constant weight at 180+/-5C. This method is compliant with NEPM (2013)
Schedule B(3)
Total Dissolved Solids (High Level) EA015H WATER
In house: Referenced to APHA 2320 B This procedure determines alkalinity by automated measurement (e.g. PC
Titrate) using pH 4.5 for indicating the total alkalinity end-point. This method is compliant with NEPM (2013)
Schedule B(3)
Alkalinity by PC Titrator ED037-P WATER
In house: Referenced to APHA 4500 Cl - G.The thiocyanate ion is liberated from mercuric thiocyanate through
sequestration of mercury by the chloride ion to form non-ionised mercuric chloride.in the presence of ferric ions
the librated thiocynate forms highly-coloured ferric thiocynate which is measured at 480 nm APHA 21st edition
seal method 2 017-1-L april 2003
Chloride by Discrete Analyser ED045G WATER
In house: Referenced to APHA 3120 and 3125; USEPA SW 846 - 6010 and 6020; Cations are determined by
either ICP-AES or ICP-MS techniques. This method is compliant with NEPM (2013) Schedule B(3)
Sodium Adsorption Ratio is calculated from Ca, Mg and Na which determined by ALS in house method
QWI-EN/ED093F. This method is compliant with NEPM (2013) Schedule B(3)
Hardness parameters are calculated based on APHA 2340 B. This method is compliant with NEPM (2013)
Schedule B(3)
Major Cations - Dissolved ED093F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. Samples are 0.45µm filtered
prior to analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions
are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct
mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Dissolved Metals by ICP-MS - Suite A EG020A-F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. The ICPMS technique utilizes
a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass
spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their
measurement by a discrete dynode ion detector.
Total Metals by ICP-MS - Suite A EG020A-T WATER
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS)
Samples are 0.45µm filtered prior to analysis. FIM-AAS is an automated flameless atomic absorption technique.
A bromate/bromide reagent is used to oxidise any organic mercury compounds in the filtered sample. The ionic
mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell.
Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM
(2013) Schedule B(3)
Dissolved Mercury by FIMS EG035F WATER
In house: Referenced to APHA 4500-NH3 G Ammonia is determined by direct colorimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Ammonia as N by Discrete analyser EK055G WATER
In house: Referenced to APHA 4500-NO2- B. Nitrite is determined by direct colourimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Nitrite as N by Discrete Analyser EK057G WATER
A
10 of 11:Page
Work Order :
:Client
EP1709780
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500-NO3- F. Nitrate is reduced to nitrite by way of a chemical reduction followed
by quantification by Discrete Analyser. Nitrite is determined seperately by direct colourimetry and result for Nitrate
calculated as the difference between the two results. This method is compliant with NEPM (2013) Schedule B(3)
Nitrate as N by Discrete Analyser EK058G WATER
In house: Referenced to APHA 4500-NO3- F. Combined oxidised Nitrogen (NO2+NO3) is determined by
Chemical Reduction and direct colourimetry by Discrete Analyser. This method is compliant with NEPM (2013)
Schedule B(3)
Nitrite and Nitrate as N (NOx) by Discrete
Analyser
EK059G WATER
In house: Referenced to APHA 4500-Norg D (In house). An aliquot of sample is digested using a high
temperature Kjeldahl digestion to convert nitrogenous compounds to ammonia. Ammonia is determined
colorimetrically by discrete analyser. This method is compliant with NEPM (2013) Schedule B(3)
Total Kjeldahl Nitrogen as N By Discrete
Analyser
EK061G WATER
In house: Referenced to APHA 4500-Norg / 4500-NO3-. This method is compliant with NEPM (2013) Schedule
B(3)
Total Nitrogen as N (TKN + Nox) By
Discrete Analyser
EK062G WATER
In house: Referenced to APHA 4500-P H, Jirka et al (1976), Zhang et al (2006). This procedure involves
sulphuric acid digestion of a sample aliquot to break phosphorus down to orthophosphate. The orthophosphate
reacts with ammonium molybdate and antimony potassium tartrate to form a complex which is then reduced and
its concentration measured at 880nm using discrete analyser. This method is compliant with NEPM (2013)
Schedule B(3)
Total Phosphorus as P By Discrete
Analyser
EK067G WATER
In house: Referenced to APHA 5310 B, The automated TOC analyzer determines Total and Inorganic Carbon by
IR cell. TOC is calculated as the difference. This method is compliant with NEPM (2013) Schedule B(3)
Total Organic Carbon EP005 WATER
In house: Referenced to APHA 5220 D. Samples are digested with a known excess of an acidic potassium
dichromate solution using silver sulfate as a catalyst. The chromium is reduced from the Cr (VI) oxidation state
to the Cr (III) state by the oxygen present in the organic material. Both of these chromium species are coloued
and absorb in the visible region of (400nm & 600nm) the spectrum. The oxidisable organic matter can be
calculated in terms of oxygen equivalents.
Chemical Oxygen Demand (COD)
(Spectrophotometric)
EP026SP WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS and
quantification is by comparison against an established 5 point calibration curve. This method is compliant with
NEPM (2013) Schedule B(3)
Polychlorinated Biphenyls (PCB) EP066 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS and
quantification is by comparison against an established 5 point calibration curve. This method is compliant with
NEPM (2013) Schedule B(3)
Pesticides by GCMS EP068 WATER
In house: Referenced to USEPA SW 846 - 8015A The sample extract is analysed by Capillary GC/FID and
quantification is by comparison against an established 5 point calibration curve of n-Alkane standards. This
method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH - Semivolatile Fraction EP071 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS in SIM Mode
and quantification is by comparison against an established 5 point calibration curve. This method is compliant
with NEPM (2013) Schedule B(3)
PAH/Phenols (GC/MS - SIM) EP075(SIM) WATER
In house: Referenced to USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by
Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve.
Alternatively, a sample is equilibrated in a headspace vial and a portion of the headspace determined by GCMS
analysis. This method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH Volatiles/BTEX EP080 WATER
Preparation Methods Method DescriptionsMatrixMethod
A
11 of 11:Page
Work Order :
:Client
EP1709780
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Preparation Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 Norg - D; APHA 4500 P - H. This method is compliant with NEPM (2013)
Schedule B(3)
TKN/TP Digestion EK061/EK067 WATER
In house: Referenced to USEPA SW846-3005. Method 3005 is a Nitric/Hydrochloric acid digestion procedure
used to prepare surface and ground water samples for analysis by ICPAES or ICPMS. This method is compliant
with NEPM (2013) Schedule B(3)
Digestion for Total Recoverable Metals EN25 WATER
In house: Referenced to USEPA SW 846 - 3510B 100 mL to 1L of sample is transferred to a separatory funnel
and serially extracted three times using 60mL DCM for each extract. The resultant extracts are combined,
dehydrated and concentrated for analysis. This method is compliant with NEPM (2013) Schedule B(3) . ALS
default excludes sediment which may be resident in the container.
Separatory Funnel Extraction of Liquids ORG14 WATER
A 5 mL aliquot or 5 mL of a diluted sample is added to a 40 mL VOC vial for sparging.Volatiles Water Preparation ORG16-W WATER
A
CHAIN OF CUSTODY CLIENT: Emerge Associates POSTAL ADDRESS: Suite 4, 26 Railway Road, Subiaco WA 6008
~m~rg'1 111:egr.iled Science & 0e5i~n
PROJECT MANAGER: Simon Gregg CONTACT PHONE: 9380 4988 le------------------
PROJECT ID.: EP15-050(05) PROJECT NAME: SAMR Monitoring - Davis Road
SAMPLER/S): Mitchell Ritikis SAMPLERS PHONE: 0449 198 721
QUOTE Nl: EPBQ/009/16 ORDER NO.:
Comments/special handling/storage or disposal Email invoice to: accounts@emergeassociates.com.au
ANALYSIS REQUIRED
SAMPLE DETAILS CONTAINER INFORMATION
Lab ID Sample ID Matri¾ Date Type & Preservative Total No.
!!! z C: -o t, :i:;; DC 6 o_ ... " u"' o .c ·ro Additional information I 0... 2 ,-. z I-_ - ..:::, ~ -- .. ~ .M 0...J (likely contaminants, ZI _fl. I~ , § ro~ ;'.Z " - dilutions or specific QC er::~-' ~z~ f- co u ""-1--zCl roo:, zo " ~ I§ .{~;; analysis) -xO O:,; f- z " -~ g ~~~ ~ ro ~cf
·c I:i 0 ;-;N~ ~ 0 CJ) 0 C
511!0 ~8 :c 0 0 0 _g ' .0 " zz 0 <( 0 I- f- ',:o._ Cl)
f MW1 Water 06/09/2017 2 SP, 3 P, 3 V, 1 AG 9 X X X X X X X X X X
2 MW2 Water 05/09/2017 2 SP, 3 P, 3 V, 1 AG 9 X X X X X X X X X X
3 MW3 Water 05/09/2017 2 SP, 3 P, 3 V, 1 AG ~
1f MW4 Water 05/09/2017 2 SP, 3 P, 3 V, 1 AG 9
~ MW5 Water 05/09/2017 2 SP, 3 P, 3 V, 1 AG 9
X X X X X X X X X X I E:nvironmental Di"i11sion X X X X X X X X X X
Pertih X X X X X X X X X X W,ork Order Reference
6------------------ Water ------
2 SP, 3 P, 3 V, 1 AG 9 SW1 05/09/2017 X X X X X X X X X X EP1709778 SW2 Water 05/09/2017 2 SP, 3 P, 3 V, 1 AG 9 X X X X X X X X X X
I 1111 1 elepl)one .. 61 ·8-9?09 765h
RELINQUISHED BY: RECEIVED BY Coe emailed to ALS?
NAME: Mitchell Ritikis ___ DATE: 07/09/2017 NAME: -)~--:i·--;,J_u,:,J::~,,,::\ I DATE: 7jg,_{,,7 I [:gJ Yes D No Ii QF': E:111Eirge llss()ciates TIME: 9:30am OF: KV' _TUv1E:/'2...G8 NAME: DATE: NAME: DATE: Water Contair1er Codes P = Unpreserved Plastic; N = Nitric Preserved Plastic; ORC = Nitric Preserved ORC: SH= Sodium Hydroxide/Cd Preserved,-$= Sodrum Hydroxide Preserved Piastre, AG = Amber Glass Unpreserved, AP= Airfreight Unpreserved Plastic; V = VOA Vial HCI Preserved; VB= VOA Vial Sodium Bisulphate Preserved; VS= VOA Vial Sulfuric Preserved; AV= Airfreight Unpreserved Vial; SG = Sulfuric Preserved Amber Glass; H = HCI preserved Plastic: HS = HCI Preserved Speciation bittle; SP = Sulfuric Preserved Plastic: F = Formaldehyde Preserved Glass; Z = Zinc Acetate Preserved Bottle; E = EDTA Preserved Bottles; ST = Sterile Bottle; LI = Lugols Iodine Preserved Bottles; STT = Sterile Sodium Thiosulfate Preserved Bottles. Soil Container Codes: J = Jar.: ASS= Plastic Bag for Acid Sulfate Soils: B = Unpreserved Bag;
Environmental
SAMPLE RECEIPT NOTIFICATION (SRN)Work Order : EP1709778
:: LaboratoryClient Environmental Division PerthEMERGE ASSOCIATES
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA
6008
10 Hod Way Malaga WA Australia 6090
:: E-mailE-mail simon.gregg@emergeassociates.co
m.au
LUKE.JONES@alsglobal.com
:: TelephoneTelephone +61 08 9380 4988 08 9209 7631
:: FacsimileFacsimile +61 08 9380 9636 +61-8-9209 7600
::Project EP15-050(05) SAMR Monitoring -
Davis Road
Page 1 of 3
:Order number ---- :Quote number EP2016EMEASS0001 (EPBQ-009-16)
:C-O-C number ---- :QC Level NEPM 2013 B3 & ALS QC Standard
Site : ----
Sampler : MITCHELL RITIKIS
DatesDate Samples Received : Issue Date : 07-Sep-201707-Sep-2017 12:08
Scheduled Reporting Date: 14-Sep-2017:Client Requested Due
Date
14-Sep-2017
Delivery DetailsMode of Delivery : :Carrier Not intact.Security Seal
No. of coolers/boxes : :4 Temperature ----
: : 7 / 7Receipt Detail No. of samples received / analysed
General Comments
This report contains the following information:l
- Sample Container(s)/Preservation Non-Compliances
- Summary of Sample(s) and Requested Analysis
- Proactive Holding Time Report
- Requested Deliverables
l Please see scanned COC for sample discrepencies: extra samples , samples not received etc.
l Please direct any queries related to sample condition / numbering / breakages to Sample Receipt (SamplesPerth@alsenviro.com)
l Analytical work for this work order will be conducted at ALS Environmental Perth.
l Please direct any turnaround / technical queries to the laboratory contact designated above.
l Sample Disposal - Aqueous (14 days), Solid (60 days) from date of completion of Work Order.
l Chemical Oxygen Demand analysis will be conducted by ALS Environmental, Sydney, NATA
accreditation no. 825, Site No. 10911.l pH analysis should be conducted within 6 hours of sampling.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
:Client EMERGE ASSOCIATES
Work Order : EP1709778 Amendment 02 of 3:Page
07-Sep-2017:Issue Date
Sample Container(s)/Preservation Non-Compliances
All comparisons are made against pretreatment/preservation AS, APHA, USEPA standards.
l No sample container / preservation non-compliance exists.
Summary of Sample(s) and Requested Analysis
Some items described below may be part of a laboratory
process necessary for the execution of client requested
tasks. Packages may contain additional analyses, such
as the determination of moisture content and preparation
tasks, that are included in the package.
If no sampling time is provided, the sampling time will
default 00:00 on the date of sampling. If no sampling date
is provided, the sampling date will be assumed by the
laboratory and displayed in brackets without a time
component
WA
TE
R -
ED
037-P
Alk
alin
ity a
s C
aC
O3 (
PC
T)
WA
TE
R -
ED
045G
Chlo
ride b
y D
iscr
ete
Analy
ser
WA
TE
R -
EG
020A
-F
Dis
solv
ed M
eta
ls b
y IC
PM
S -
Suite
A
WA
TE
R -
EP
026S
P
Chem
ical O
xygen D
em
and (
CO
D)
WA
TE
R -
NT
-01
Majo
r C
atio
ns
(Ca, M
g, N
a, K
)
WA
TE
R -
NT
-08
Tota
l Nitr
ogen +
NO
2 +
NO
3 +
NH
3 +
Tota
l P
WA
TE
R -
W-0
2
8 M
eta
ls
EP1709778-001 06-Sep-2017 00:00 MW1 ü ü ü ü ü ü ü
EP1709778-002 05-Sep-2017 00:00 MW2 ü ü ü ü ü ü ü
EP1709778-003 05-Sep-2017 00:00 MW3 ü ü ü ü ü ü ü
EP1709778-004 05-Sep-2017 00:00 MW4 ü ü ü ü ü ü ü
EP1709778-005 05-Sep-2017 00:00 MW5 ü ü ü ü ü ü ü
EP1709778-006 05-Sep-2017 00:00 SW1-A ü ü ü ü ü ü ü
EP1709778-007 05-Sep-2017 00:00 SW2-B ü ü ü ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
WA
TE
R -
EA
01
5H
To
tal D
isso
lve
d S
olid
s -
Hig
h L
eve
l
WA
TE
R -
EG
02
0A
-T
To
tal M
eta
ls b
y IC
PM
S -
Su
ite A
WA
TE
R -
EP
00
5
To
tal O
rga
nic
Ca
rbo
n (
TO
C)
WA
TE
R -
W-1
7
TR
H/B
TE
XN
/PA
H/P
he
no
ls/O
C/P
CB
EP1709778-001 06-Sep-2017 00:00 MW1 ü ü ü ü
EP1709778-002 05-Sep-2017 00:00 MW2 ü ü ü ü
EP1709778-003 05-Sep-2017 00:00 MW3 ü ü ü ü
EP1709778-004 05-Sep-2017 00:00 MW4 ü ü ü ü
EP1709778-005 05-Sep-2017 00:00 MW5 ü ü ü ü
EP1709778-006 05-Sep-2017 00:00 SW1-A ü ü ü ü
EP1709778-007 05-Sep-2017 00:00 SW2-B ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
Proactive Holding Time Report
Sample(s) have been received within the recommended holding times for the requested analysis.
:Client EMERGE ASSOCIATES
Work Order : EP1709778 Amendment 03 of 3:Page
07-Sep-2017:Issue Date
Requested Deliverables
ACCOUNTS (INVOICES)
- A4 - AU Tax Invoice (INV) Email accounts@emergeassociates.com.
au
- Chain of Custody (CoC) (COC) Email accounts@emergeassociates.com.
au
JEREMY PAYET
- *AU Certificate of Analysis - NATA (COA) Email jeremy.payet@emergeassociates.co
m.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email jeremy.payet@emergeassociates.co
m.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email jeremy.payet@emergeassociates.co
m.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email jeremy.payet@emergeassociates.co
m.au
- Chain of Custody (CoC) (COC) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - ESDAT (ESDAT) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - XTab (XTAB) Email jeremy.payet@emergeassociates.co
m.au
MITCHELL RITIKIS
- *AU Certificate of Analysis - NATA (COA) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email mitchell.ritikis@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email mitchell.ritikis@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email mitchell.ritikis@emergeassociates.c
om.au
SIMON GREGG
- *AU Certificate of Analysis - NATA (COA) Email simon.gregg@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email simon.gregg@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email simon.gregg@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email simon.gregg@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email simon.gregg@emergeassociates.c
om.au
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 13EP1709778
:Amendment 1:: LaboratoryClient EMERGE ASSOCIATES Environmental Division Perth
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
10 Hod Way Malaga WA Australia 6090
:Telephone +61 08 9380 4988 :Telephone 08 9209 7631
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 07-Sep-2017 12:08
:Order number ---- Date Analysis Commenced : 07-Sep-2017
:C-O-C number ---- Issue Date : 14-Sep-2017 16:18
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EPBQ-009-16
7:No. of samples received
7:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:
l General Comments
l Analytical Results
l Surrogate Control Limits
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with
Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Canhuang Ke Metals Instrument Chemist Perth Inorganics, Malaga, WA
David Viner SENIOR LAB TECH Perth Organics, Malaga, WA
Jeremy Truong Laboratory Manager Perth Inorganics, Malaga, WA
Tyrone Cole Inorganics Preparation Supervisor Perth Inorganics, Malaga, WA
Vanessa Nguyen Organic Chemist Perth Organics, Malaga, WA
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with I50/IEC 1 7025 - Testing
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General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When no sampling time is provided, the sampling time will default 00:00 on the date of sampling. If no sampling date is provided, the sampling date will be assumed by the laboratory and displayed in brackets without a
time component.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
^ = This result is computed from individual analyte detections at or above the level of reporting
ø = ALS is not NATA accredited for these tests.
~ = Indicates an estimated value.
Key :
Chemical Oxygen Demand conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.l
Amendment (14/09/2017): This report has been amended as a result of a request to change sample identification numbers for two samples. Sample 006 has been changed from SW1-A to SW2 and sample 007
has been changed from SW2-B to SW1 as per the CoC. All analysis results are as per the previous report.
l
Benzo(a)pyrene Toxicity Equivalent Quotient (TEQ) is the sum total of the concentration of the eight carcinogenic PAHs multiplied by their Toxicity Equivalence Factor (TEF) relative to Benzo(a)pyrene. TEF values
are provided in brackets as follows: Benz(a)anthracene (0.1), Chrysene (0.01), Benzo(b+j) & Benzo(k)fluoranthene (0.1), Benzo(a)pyrene (1.0), Indeno(1.2.3.cd)pyrene (0.1), Dibenz(a.h)anthracene (1.0),
Benzo(g.h.i)perylene (0.01). Less than LOR results for 'TEQ Zero' are treated as zero.
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Analytical Results
MW5MW4MW3MW2MW1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
05-Sep-2017 00:0005-Sep-2017 00:0005-Sep-2017 00:0005-Sep-2017 00:0006-Sep-2017 00:00Client sampling date / time
EP1709778-005EP1709778-004EP1709778-003EP1709778-002EP1709778-001UnitLORCAS NumberCompound
Result Result Result Result Result
EA015: Total Dissolved Solids dried at 180 ± 5 °C
191 372 405 248 756mg/L10----Total Dissolved Solids @180°C
ED037P: Alkalinity by PC Titrator
<1Hydroxide Alkalinity as CaCO3 <1 <1 <1 <1mg/L1DMO-210-001
<1Carbonate Alkalinity as CaCO3 <1 <1 <1 <1mg/L13812-32-6
33Bicarbonate Alkalinity as CaCO3 <1 <1 <1 <1mg/L171-52-3
33 <1 <1 <1 <1mg/L1----Total Alkalinity as CaCO3
ED045G: Chloride by Discrete Analyser
56Chloride 168 178 85 469mg/L116887-00-6
ED093F: Dissolved Major Cations
4Calcium 1 2 <1 2mg/L17440-70-2
6Magnesium 6 9 6 22mg/L17439-95-4
43Sodium 79 101 46 177mg/L17440-23-5
3Potassium <1 5 1 4mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS
0.05Aluminium 0.11 0.04 0.40 1.37mg/L0.017429-90-5
<0.001Arsenic <0.001 <0.001 <0.001 <0.001mg/L0.0017440-38-2
<0.0001Cadmium <0.0001 <0.0001 <0.0001 0.0002mg/L0.00017440-43-9
<0.001Chromium <0.001 <0.001 <0.001 <0.001mg/L0.0017440-47-3
<0.001Copper <0.001 <0.001 0.008 <0.001mg/L0.0017440-50-8
0.006Manganese 0.005 0.589 0.019 1.84mg/L0.0017439-96-5
<0.001Nickel <0.001 0.001 0.004 0.007mg/L0.0017440-02-0
<0.001Lead <0.001 <0.001 <0.001 <0.001mg/L0.0017439-92-1
<0.01Selenium <0.01 <0.01 <0.01 <0.01mg/L0.017782-49-2
<0.005Zinc 0.255 0.011 0.015 0.060mg/L0.0057440-66-6
EG020T: Total Metals by ICP-MS
9.40Iron 34.9 31.4 0.77 6.54mg/L0.057439-89-6
EG035F: Dissolved Mercury by FIMS
<0.0001Mercury <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017439-97-6
EK055G: Ammonia as N by Discrete Analyser
<0.01Ammonia as N 0.40 0.06 0.02 0.02mg/L0.017664-41-7
EK057G: Nitrite as N by Discrete Analyser
<0.01Nitrite as N <0.01 <0.01 <0.01 <0.01mg/L0.0114797-65-0
EK058G: Nitrate as N by Discrete Analyser
0.01Nitrate as N 0.02 0.05 0.48 0.02mg/L0.0114797-55-8
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:Client
EP1709778 Amendment 1
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
MW5MW4MW3MW2MW1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
05-Sep-2017 00:0005-Sep-2017 00:0005-Sep-2017 00:0005-Sep-2017 00:0006-Sep-2017 00:00Client sampling date / time
EP1709778-005EP1709778-004EP1709778-003EP1709778-002EP1709778-001UnitLORCAS NumberCompound
Result Result Result Result Result
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
0.01 0.02 0.05 0.48 0.02mg/L0.01----Nitrite + Nitrate as N
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser
0.1 0.4 0.2 <0.1 <0.1mg/L0.1----Total Kjeldahl Nitrogen as N
EK062G: Total Nitrogen as N (TKN + NOx) by Discrete Analyser
0.1^ 0.4 0.2 0.5 <0.1mg/L0.1----Total Nitrogen as N
EK067G: Total Phosphorus as P by Discrete Analyser
0.01 <0.01 <0.01 <0.01 <0.01mg/L0.01----Total Phosphorus as P
EP005: Total Organic Carbon (TOC)
12 3 4 6 5mg/L1----Total Organic Carbon
EP026SP: Chemical Oxygen Demand (Spectrophotometric)
26 26 26 18 27mg/L10----Chemical Oxygen Demand
EP066: Polychlorinated Biphenyls (PCB)
<1 <1 <1 <1 <1µg/L1----Total Polychlorinated biphenyls
EP068A: Organochlorine Pesticides (OC)
<0.5alpha-BHC <0.5 <0.5 <0.5 <0.5µg/L0.5319-84-6
<0.5Hexachlorobenzene (HCB) <0.5 <0.5 <0.5 <0.5µg/L0.5118-74-1
<0.5beta-BHC <0.5 <0.5 <0.5 <0.5µg/L0.5319-85-7
<0.5gamma-BHC <0.5 <0.5 <0.5 <0.5µg/L0.558-89-9
<0.5delta-BHC <0.5 <0.5 <0.5 <0.5µg/L0.5319-86-8
<0.5Heptachlor <0.5 <0.5 <0.5 <0.5µg/L0.576-44-8
<0.5Aldrin <0.5 <0.5 <0.5 <0.5µg/L0.5309-00-2
<0.5Heptachlor epoxide <0.5 <0.5 <0.5 <0.5µg/L0.51024-57-3
<0.5trans-Chlordane <0.5 <0.5 <0.5 <0.5µg/L0.55103-74-2
<0.5alpha-Endosulfan <0.5 <0.5 <0.5 <0.5µg/L0.5959-98-8
<0.5cis-Chlordane <0.5 <0.5 <0.5 <0.5µg/L0.55103-71-9
<0.5Dieldrin <0.5 <0.5 <0.5 <0.5µg/L0.560-57-1
<0.54.4`-DDE <0.5 <0.5 <0.5 <0.5µg/L0.572-55-9
<0.5Endrin <0.5 <0.5 <0.5 <0.5µg/L0.572-20-8
<0.5beta-Endosulfan <0.5 <0.5 <0.5 <0.5µg/L0.533213-65-9
<0.54.4`-DDD <0.5 <0.5 <0.5 <0.5µg/L0.572-54-8
<0.5Endrin aldehyde <0.5 <0.5 <0.5 <0.5µg/L0.57421-93-4
<0.5Endosulfan sulfate <0.5 <0.5 <0.5 <0.5µg/L0.51031-07-8
<2.04.4`-DDT <2.0 <2.0 <2.0 <2.0µg/L2.050-29-3
<0.5Endrin ketone <0.5 <0.5 <0.5 <0.5µg/L0.553494-70-5
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:Client
EP1709778 Amendment 1
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EMERGE ASSOCIATES
Analytical Results
MW5MW4MW3MW2MW1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
05-Sep-2017 00:0005-Sep-2017 00:0005-Sep-2017 00:0005-Sep-2017 00:0006-Sep-2017 00:00Client sampling date / time
EP1709778-005EP1709778-004EP1709778-003EP1709778-002EP1709778-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP068A: Organochlorine Pesticides (OC) - Continued
<2.0Methoxychlor <2.0 <2.0 <2.0 <2.0µg/L2.072-43-5
<0.5^ <0.5 <0.5 <0.5 <0.5µg/L0.5----Total Chlordane (sum)
<0.5^ Sum of DDD + DDE + DDT <0.5 <0.5 <0.5 <0.5µg/L0.572-54-8/72-55-9/5
0-2
<0.5^ Sum of Aldrin + Dieldrin <0.5 <0.5 <0.5 <0.5µg/L0.5309-00-2/60-57-1
EP075(SIM)A: Phenolic Compounds
<1.0Phenol <1.0 <1.0 <1.0 <1.0µg/L1.0108-95-2
<1.02-Chlorophenol <1.0 <1.0 <1.0 <1.0µg/L1.095-57-8
<1.02-Methylphenol <1.0 <1.0 <1.0 <1.0µg/L1.095-48-7
<2.03- & 4-Methylphenol <2.0 <2.0 <2.0 <2.0µg/L2.01319-77-3
<1.02-Nitrophenol <1.0 <1.0 <1.0 <1.0µg/L1.088-75-5
<1.02.4-Dimethylphenol <1.0 <1.0 <1.0 <1.0µg/L1.0105-67-9
<1.02.4-Dichlorophenol <1.0 <1.0 <1.0 <1.0µg/L1.0120-83-2
<1.02.6-Dichlorophenol <1.0 <1.0 <1.0 <1.0µg/L1.087-65-0
<1.04-Chloro-3-methylphenol <1.0 <1.0 <1.0 <1.0µg/L1.059-50-7
<1.02.4.6-Trichlorophenol <1.0 <1.0 <1.0 <1.0µg/L1.088-06-2
<1.02.4.5-Trichlorophenol <1.0 <1.0 <1.0 <1.0µg/L1.095-95-4
<2.0Pentachlorophenol <2.0 <2.0 <2.0 <2.0µg/L2.087-86-5
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
<1.0Naphthalene <1.0 <1.0 <1.0 <1.0µg/L1.091-20-3
<1.0Acenaphthylene <1.0 <1.0 <1.0 <1.0µg/L1.0208-96-8
<1.0Acenaphthene <1.0 <1.0 <1.0 <1.0µg/L1.083-32-9
<1.0Fluorene <1.0 <1.0 <1.0 <1.0µg/L1.086-73-7
<1.0Phenanthrene <1.0 <1.0 <1.0 <1.0µg/L1.085-01-8
<1.0Anthracene <1.0 <1.0 <1.0 <1.0µg/L1.0120-12-7
<1.0Fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1.0206-44-0
<1.0Pyrene <1.0 <1.0 <1.0 <1.0µg/L1.0129-00-0
<1.0Benz(a)anthracene <1.0 <1.0 <1.0 <1.0µg/L1.056-55-3
<1.0Chrysene <1.0 <1.0 <1.0 <1.0µg/L1.0218-01-9
<1.0Benzo(b+j)fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1.0205-99-2 205-82-3
<1.0Benzo(k)fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1.0207-08-9
<0.5Benzo(a)pyrene <0.5 <0.5 <0.5 <0.5µg/L0.550-32-8
<1.0Indeno(1.2.3.cd)pyrene <1.0 <1.0 <1.0 <1.0µg/L1.0193-39-5
<1.0Dibenz(a.h)anthracene <1.0 <1.0 <1.0 <1.0µg/L1.053-70-3
<1.0Benzo(g.h.i)perylene <1.0 <1.0 <1.0 <1.0µg/L1.0191-24-2
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:Client
EP1709778 Amendment 1
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
MW5MW4MW3MW2MW1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
05-Sep-2017 00:0005-Sep-2017 00:0005-Sep-2017 00:0005-Sep-2017 00:0006-Sep-2017 00:00Client sampling date / time
EP1709778-005EP1709778-004EP1709778-003EP1709778-002EP1709778-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued
<0.5^ <0.5 <0.5 <0.5 <0.5µg/L0.5----Sum of polycyclic aromatic hydrocarbons
<0.5^ <0.5 <0.5 <0.5 <0.5µg/L0.5----Benzo(a)pyrene TEQ (zero)
EP080/071: Total Petroleum Hydrocarbons
<20 <20 <20 <20 <20µg/L20----C6 - C9 Fraction
<50 <50 <50 <50 <50µg/L50----C10 - C14 Fraction
<100 100 <100 <100 <100µg/L100----C15 - C28 Fraction
<50 <50 <50 <50 <50µg/L50----C29 - C36 Fraction
<50^ 100 <50 <50 <50µg/L50----C10 - C36 Fraction (sum)
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
<20C6 - C10 Fraction <20 <20 <20 <20µg/L20C6_C10
<20^ C6 - C10 Fraction minus BTEX
(F1)
<20 <20 <20 <20µg/L20C6_C10-BTEX
<100 <100 <100 <100 <100µg/L100---->C10 - C16 Fraction
<100 120 <100 <100 <100µg/L100---->C16 - C34 Fraction
<100 <100 <100 <100 <100µg/L100---->C34 - C40 Fraction
<100^ 120 <100 <100 <100µg/L100---->C10 - C40 Fraction (sum)
<100^ <100 <100 <100 <100µg/L100---->C10 - C16 Fraction minus Naphthalene
(F2)
EP080: BTEXN
<1Benzene <1 <1 <1 <1µg/L171-43-2
<2Toluene <2 <2 <2 <2µg/L2108-88-3
<2Ethylbenzene <2 <2 <2 <2µg/L2100-41-4
<2meta- & para-Xylene <2 <2 <2 <2µg/L2108-38-3 106-42-3
<2ortho-Xylene <2 <2 <2 <2µg/L295-47-6
<2^ Total Xylenes <2 <2 <2 <2µg/L21330-20-7
<1^ <1 <1 <1 <1µg/L1----Sum of BTEX
<5Naphthalene <5 <5 <5 <5µg/L591-20-3
EP066S: PCB Surrogate
99.4Decachlorobiphenyl 126 105 116 111%12051-24-3
EP068S: Organochlorine Pesticide Surrogate
85.1Dibromo-DDE 108 91.5 86.6 94.8%0.521655-73-2
EP068T: Organophosphorus Pesticide Surrogate
81.5DEF 114 97.1 103 100%0.578-48-8
EP075(SIM)S: Phenolic Compound Surrogates
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Analytical Results
MW5MW4MW3MW2MW1Client sample IDSub-Matrix: WATER
(Matrix: WATER)
05-Sep-2017 00:0005-Sep-2017 00:0005-Sep-2017 00:0005-Sep-2017 00:0006-Sep-2017 00:00Client sampling date / time
EP1709778-005EP1709778-004EP1709778-003EP1709778-002EP1709778-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP075(SIM)S: Phenolic Compound Surrogates - Continued
26.1Phenol-d6 34.7 26.8 30.5 25.7%1.013127-88-3
64.02-Chlorophenol-D4 82.6 63.0 73.1 62.8%1.093951-73-6
83.22.4.6-Tribromophenol 119 93.4 93.9 84.6%1.0118-79-6
EP075(SIM)T: PAH Surrogates
68.72-Fluorobiphenyl 87.9 68.1 79.6 69.2%1.0321-60-8
94.0Anthracene-d10 121 94.8 104 96.0%1.01719-06-8
85.04-Terphenyl-d14 108 85.9 91.4 90.9%1.01718-51-0
EP080S: TPH(V)/BTEX Surrogates
1121.2-Dichloroethane-D4 104 107 101 96.8%217060-07-0
92.8Toluene-D8 94.9 94.7 95.5 95.4%22037-26-5
94.44-Bromofluorobenzene 91.9 93.0 91.7 91.2%2460-00-4
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Analytical Results
------------SW1SW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)
------------05-Sep-2017 00:0005-Sep-2017 00:00Client sampling date / time
------------------------EP1709778-007EP1709778-006UnitLORCAS NumberCompound
Result Result ---- ---- ----
EA015: Total Dissolved Solids dried at 180 ± 5 °C
178 196 ---- ---- ----mg/L10----Total Dissolved Solids @180°C
ED037P: Alkalinity by PC Titrator
<1Hydroxide Alkalinity as CaCO3 <1 ---- ---- ----mg/L1DMO-210-001
<1Carbonate Alkalinity as CaCO3 <1 ---- ---- ----mg/L13812-32-6
39Bicarbonate Alkalinity as CaCO3 35 ---- ---- ----mg/L171-52-3
39 35 ---- ---- ----mg/L1----Total Alkalinity as CaCO3
ED045G: Chloride by Discrete Analyser
73Chloride 90 ---- ---- ----mg/L116887-00-6
ED093F: Dissolved Major Cations
12Calcium 10 ---- ---- ----mg/L17440-70-2
9Magnesium 10 ---- ---- ----mg/L17439-95-4
40Sodium 48 ---- ---- ----mg/L17440-23-5
3Potassium 4 ---- ---- ----mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS
<0.01Aluminium <0.01 ---- ---- ----mg/L0.017429-90-5
<0.001Arsenic <0.001 ---- ---- ----mg/L0.0017440-38-2
<0.0001Cadmium <0.0001 ---- ---- ----mg/L0.00017440-43-9
<0.001Chromium <0.001 ---- ---- ----mg/L0.0017440-47-3
<0.001Copper <0.001 ---- ---- ----mg/L0.0017440-50-8
0.015Manganese 0.001 ---- ---- ----mg/L0.0017439-96-5
<0.001Nickel <0.001 ---- ---- ----mg/L0.0017440-02-0
<0.001Lead <0.001 ---- ---- ----mg/L0.0017439-92-1
<0.01Selenium <0.01 ---- ---- ----mg/L0.017782-49-2
<0.005Zinc <0.005 ---- ---- ----mg/L0.0057440-66-6
EG020T: Total Metals by ICP-MS
0.96Iron 0.05 ---- ---- ----mg/L0.057439-89-6
EG035F: Dissolved Mercury by FIMS
<0.0001Mercury <0.0001 ---- ---- ----mg/L0.00017439-97-6
EK055G: Ammonia as N by Discrete Analyser
0.02Ammonia as N 0.02 ---- ---- ----mg/L0.017664-41-7
EK057G: Nitrite as N by Discrete Analyser
<0.01Nitrite as N <0.01 ---- ---- ----mg/L0.0114797-65-0
EK058G: Nitrate as N by Discrete Analyser
0.12Nitrate as N 0.06 ---- ---- ----mg/L0.0114797-55-8
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EP1709778 Amendment 1
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
------------SW1SW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)
------------05-Sep-2017 00:0005-Sep-2017 00:00Client sampling date / time
------------------------EP1709778-007EP1709778-006UnitLORCAS NumberCompound
Result Result ---- ---- ----
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
0.12 0.06 ---- ---- ----mg/L0.01----Nitrite + Nitrate as N
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser
0.2 <0.1 ---- ---- ----mg/L0.1----Total Kjeldahl Nitrogen as N
EK062G: Total Nitrogen as N (TKN + NOx) by Discrete Analyser
0.3^ <0.1 ---- ---- ----mg/L0.1----Total Nitrogen as N
EK067G: Total Phosphorus as P by Discrete Analyser
<0.01 <0.01 ---- ---- ----mg/L0.01----Total Phosphorus as P
EP005: Total Organic Carbon (TOC)
3 2 ---- ---- ----mg/L1----Total Organic Carbon
EP026SP: Chemical Oxygen Demand (Spectrophotometric)
23 19 ---- ---- ----mg/L10----Chemical Oxygen Demand
EP066: Polychlorinated Biphenyls (PCB)
<1 <1 ---- ---- ----µg/L1----Total Polychlorinated biphenyls
EP068A: Organochlorine Pesticides (OC)
<0.5alpha-BHC <0.5 ---- ---- ----µg/L0.5319-84-6
<0.5Hexachlorobenzene (HCB) <0.5 ---- ---- ----µg/L0.5118-74-1
<0.5beta-BHC <0.5 ---- ---- ----µg/L0.5319-85-7
<0.5gamma-BHC <0.5 ---- ---- ----µg/L0.558-89-9
<0.5delta-BHC <0.5 ---- ---- ----µg/L0.5319-86-8
<0.5Heptachlor <0.5 ---- ---- ----µg/L0.576-44-8
<0.5Aldrin <0.5 ---- ---- ----µg/L0.5309-00-2
<0.5Heptachlor epoxide <0.5 ---- ---- ----µg/L0.51024-57-3
<0.5trans-Chlordane <0.5 ---- ---- ----µg/L0.55103-74-2
<0.5alpha-Endosulfan <0.5 ---- ---- ----µg/L0.5959-98-8
<0.5cis-Chlordane <0.5 ---- ---- ----µg/L0.55103-71-9
<0.5Dieldrin <0.5 ---- ---- ----µg/L0.560-57-1
<0.54.4`-DDE <0.5 ---- ---- ----µg/L0.572-55-9
<0.5Endrin <0.5 ---- ---- ----µg/L0.572-20-8
<0.5beta-Endosulfan <0.5 ---- ---- ----µg/L0.533213-65-9
<0.54.4`-DDD <0.5 ---- ---- ----µg/L0.572-54-8
<0.5Endrin aldehyde <0.5 ---- ---- ----µg/L0.57421-93-4
<0.5Endosulfan sulfate <0.5 ---- ---- ----µg/L0.51031-07-8
<2.04.4`-DDT <2.0 ---- ---- ----µg/L2.050-29-3
<0.5Endrin ketone <0.5 ---- ---- ----µg/L0.553494-70-5
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EP1709778 Amendment 1
EP15-050(05) SAMR Monitoring - Davis Road:Project
EMERGE ASSOCIATES
Analytical Results
------------SW1SW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)
------------05-Sep-2017 00:0005-Sep-2017 00:00Client sampling date / time
------------------------EP1709778-007EP1709778-006UnitLORCAS NumberCompound
Result Result ---- ---- ----
EP068A: Organochlorine Pesticides (OC) - Continued
<2.0Methoxychlor <2.0 ---- ---- ----µg/L2.072-43-5
<0.5^ <0.5 ---- ---- ----µg/L0.5----Total Chlordane (sum)
<0.5^ Sum of DDD + DDE + DDT <0.5 ---- ---- ----µg/L0.572-54-8/72-55-9/5
0-2
<0.5^ Sum of Aldrin + Dieldrin <0.5 ---- ---- ----µg/L0.5309-00-2/60-57-1
EP075(SIM)A: Phenolic Compounds
<1.0Phenol <1.0 ---- ---- ----µg/L1.0108-95-2
<1.02-Chlorophenol <1.0 ---- ---- ----µg/L1.095-57-8
<1.02-Methylphenol <1.0 ---- ---- ----µg/L1.095-48-7
<2.03- & 4-Methylphenol <2.0 ---- ---- ----µg/L2.01319-77-3
<1.02-Nitrophenol <1.0 ---- ---- ----µg/L1.088-75-5
<1.02.4-Dimethylphenol <1.0 ---- ---- ----µg/L1.0105-67-9
<1.02.4-Dichlorophenol <1.0 ---- ---- ----µg/L1.0120-83-2
<1.02.6-Dichlorophenol <1.0 ---- ---- ----µg/L1.087-65-0
<1.04-Chloro-3-methylphenol <1.0 ---- ---- ----µg/L1.059-50-7
<1.02.4.6-Trichlorophenol <1.0 ---- ---- ----µg/L1.088-06-2
<1.02.4.5-Trichlorophenol <1.0 ---- ---- ----µg/L1.095-95-4
<2.0Pentachlorophenol <2.0 ---- ---- ----µg/L2.087-86-5
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
<1.0Naphthalene <1.0 ---- ---- ----µg/L1.091-20-3
<1.0Acenaphthylene <1.0 ---- ---- ----µg/L1.0208-96-8
<1.0Acenaphthene <1.0 ---- ---- ----µg/L1.083-32-9
<1.0Fluorene <1.0 ---- ---- ----µg/L1.086-73-7
<1.0Phenanthrene <1.0 ---- ---- ----µg/L1.085-01-8
<1.0Anthracene <1.0 ---- ---- ----µg/L1.0120-12-7
<1.0Fluoranthene <1.0 ---- ---- ----µg/L1.0206-44-0
<1.0Pyrene <1.0 ---- ---- ----µg/L1.0129-00-0
<1.0Benz(a)anthracene <1.0 ---- ---- ----µg/L1.056-55-3
<1.0Chrysene <1.0 ---- ---- ----µg/L1.0218-01-9
<1.0Benzo(b+j)fluoranthene <1.0 ---- ---- ----µg/L1.0205-99-2 205-82-3
<1.0Benzo(k)fluoranthene <1.0 ---- ---- ----µg/L1.0207-08-9
<0.5Benzo(a)pyrene <0.5 ---- ---- ----µg/L0.550-32-8
<1.0Indeno(1.2.3.cd)pyrene <1.0 ---- ---- ----µg/L1.0193-39-5
<1.0Dibenz(a.h)anthracene <1.0 ---- ---- ----µg/L1.053-70-3
<1.0Benzo(g.h.i)perylene <1.0 ---- ---- ----µg/L1.0191-24-2
A
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Analytical Results
------------SW1SW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)
------------05-Sep-2017 00:0005-Sep-2017 00:00Client sampling date / time
------------------------EP1709778-007EP1709778-006UnitLORCAS NumberCompound
Result Result ---- ---- ----
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued
<0.5^ <0.5 ---- ---- ----µg/L0.5----Sum of polycyclic aromatic hydrocarbons
<0.5^ <0.5 ---- ---- ----µg/L0.5----Benzo(a)pyrene TEQ (zero)
EP080/071: Total Petroleum Hydrocarbons
<20 <20 ---- ---- ----µg/L20----C6 - C9 Fraction
<50 <50 ---- ---- ----µg/L50----C10 - C14 Fraction
<100 <100 ---- ---- ----µg/L100----C15 - C28 Fraction
<50 <50 ---- ---- ----µg/L50----C29 - C36 Fraction
<50^ <50 ---- ---- ----µg/L50----C10 - C36 Fraction (sum)
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
<20C6 - C10 Fraction <20 ---- ---- ----µg/L20C6_C10
<20^ C6 - C10 Fraction minus BTEX
(F1)
<20 ---- ---- ----µg/L20C6_C10-BTEX
<100 <100 ---- ---- ----µg/L100---->C10 - C16 Fraction
<100 <100 ---- ---- ----µg/L100---->C16 - C34 Fraction
<100 <100 ---- ---- ----µg/L100---->C34 - C40 Fraction
<100^ <100 ---- ---- ----µg/L100---->C10 - C40 Fraction (sum)
<100^ <100 ---- ---- ----µg/L100---->C10 - C16 Fraction minus Naphthalene
(F2)
EP080: BTEXN
<1Benzene <1 ---- ---- ----µg/L171-43-2
<2Toluene <2 ---- ---- ----µg/L2108-88-3
<2Ethylbenzene <2 ---- ---- ----µg/L2100-41-4
<2meta- & para-Xylene <2 ---- ---- ----µg/L2108-38-3 106-42-3
<2ortho-Xylene <2 ---- ---- ----µg/L295-47-6
<2^ Total Xylenes <2 ---- ---- ----µg/L21330-20-7
<1^ <1 ---- ---- ----µg/L1----Sum of BTEX
<5Naphthalene <5 ---- ---- ----µg/L591-20-3
EP066S: PCB Surrogate
127Decachlorobiphenyl 115 ---- ---- ----%12051-24-3
EP068S: Organochlorine Pesticide Surrogate
111Dibromo-DDE 101 ---- ---- ----%0.521655-73-2
EP068T: Organophosphorus Pesticide Surrogate
117DEF 103 ---- ---- ----%0.578-48-8
EP075(SIM)S: Phenolic Compound Surrogates
A
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Analytical Results
------------SW1SW2Client sample IDSub-Matrix: WATER
(Matrix: WATER)
------------05-Sep-2017 00:0005-Sep-2017 00:00Client sampling date / time
------------------------EP1709778-007EP1709778-006UnitLORCAS NumberCompound
Result Result ---- ---- ----
EP075(SIM)S: Phenolic Compound Surrogates - Continued
30.0Phenol-d6 25.1 ---- ---- ----%1.013127-88-3
73.52-Chlorophenol-D4 61.7 ---- ---- ----%1.093951-73-6
95.42.4.6-Tribromophenol 77.0 ---- ---- ----%1.0118-79-6
EP075(SIM)T: PAH Surrogates
84.02-Fluorobiphenyl 66.8 ---- ---- ----%1.0321-60-8
113Anthracene-d10 99.4 ---- ---- ----%1.01719-06-8
1054-Terphenyl-d14 96.1 ---- ---- ----%1.01718-51-0
EP080S: TPH(V)/BTEX Surrogates
1101.2-Dichloroethane-D4 101 ---- ---- ----%217060-07-0
93.1Toluene-D8 95.9 ---- ---- ----%22037-26-5
95.04-Bromofluorobenzene 92.0 ---- ---- ----%2460-00-4
A
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Surrogate Control Limits
Recovery Limits (%)Sub-Matrix: WATER
Compound CAS Number Low High
EP066S: PCB Surrogate
Decachlorobiphenyl 2051-24-3 27 136
EP068S: Organochlorine Pesticide Surrogate
Dibromo-DDE 21655-73-2 50 146
EP068T: Organophosphorus Pesticide Surrogate
DEF 78-48-8 27 153
EP075(SIM)S: Phenolic Compound Surrogates
Phenol-d6 13127-88-3 10 67
2-Chlorophenol-D4 93951-73-6 29 120
2.4.6-Tribromophenol 118-79-6 10 131
EP075(SIM)T: PAH Surrogates
2-Fluorobiphenyl 321-60-8 34 131
Anthracene-d10 1719-06-8 43 127
4-Terphenyl-d14 1718-51-0 41 142
EP080S: TPH(V)/BTEX Surrogates
1.2-Dichloroethane-D4 17060-07-0 61 141
Toluene-D8 2037-26-5 73 126
4-Bromofluorobenzene 460-00-4 60 125
A
False
6 6.00False
Environmental
QUALITY CONTROL REPORTWork Order : EP1709778 Page : 1 of 9
:Amendment 1
:: LaboratoryClient Environmental Division PerthEMERGE ASSOCIATES
:Contact MR SIMON GREGG :Contact Luke Jones
:Address SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
Address : 10 Hod Way Malaga WA Australia 6090
::Telephone +61 08 9380 4988 08 9209 7631:Telephone
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 07-Sep-2017
:Order number ---- Date Analysis Commenced : 07-Sep-2017
:C-O-C number ---- Issue Date : 14-Sep-2017
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EPBQ-009-16
No. of samples received 7:
No. of samples analysed 7:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limits
l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits
l Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Canhuang Ke Metals Instrument Chemist Perth Inorganics, Malaga, WA
David Viner SENIOR LAB TECH Perth Organics, Malaga, WA
Jeremy Truong Laboratory Manager Perth Inorganics, Malaga, WA
Tyrone Cole Inorganics Preparation Supervisor Perth Inorganics, Malaga, WA
Vanessa Nguyen Organic Chemist Perth Organics, Malaga, WA
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with 150/IEC 17025 - Testing
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General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
RPD = Relative Percentage Difference
# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) Report
The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges
for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:
No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QC Lot: 1107222)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 3230 3200 1.18 0% - 20%Anonymous EP1709662-004
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 196 198 0.760 0% - 50%SW1 EP1709778-007
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QC Lot: 1107294)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 966 963 0.311 0% - 20%Anonymous EP1709678-001
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 429 428 0.233 0% - 20%Anonymous EP1709678-009
ED037P: Alkalinity by PC Titrator (QC Lot: 1105014)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitSW2 EP1709778-006
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 39 32 18.6 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 39 32 18.6 0% - 20%
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EP1709442-001
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 115 117 1.13 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 115 117 1.13 0% - 20%
ED045G: Chloride by Discrete Analyser (QC Lot: 1100182)
ED045G: Chloride 16887-00-6 1 mg/L 168 173 2.96 0% - 20%MW2 EP1709778-002
ED045G: Chloride 16887-00-6 1 mg/L 53 53 0.00 0% - 20%Anonymous EP1709780-004
ED093F: Dissolved Major Cations (QC Lot: 1106838)
ED093F: Calcium 7440-70-2 1 mg/L 12 12 0.00 0% - 50%Anonymous EP1709681-005
ED093F: Magnesium 7439-95-4 1 mg/L 12 12 0.00 0% - 50%
ED093F: Sodium 7440-23-5 1 mg/L 17 17 0.00 0% - 50%
ED093F: Potassium 7440-09-7 1 mg/L 4 4 0.00 No Limit
ED093F: Calcium 7440-70-2 1 mg/L 2 2 0.00 No LimitMW5 EP1709778-005
ED093F: Magnesium 7439-95-4 1 mg/L 22 22 0.00 0% - 20%
A
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
ED093F: Dissolved Major Cations (QC Lot: 1106838) - continued
ED093F: Sodium 7440-23-5 1 mg/L 177 177 0.00 0% - 20%MW5 EP1709778-005
ED093F: Potassium 7440-09-7 1 mg/L 4 4 0.00 No Limit
EG020F: Dissolved Metals by ICP-MS (QC Lot: 1106836)
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitMW3 EP1709778-003
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.589 0.597 1.34 0% - 20%
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.001 <0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.011 0.010 0.00 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L 0.04 0.03 0.00 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EP1709681-001
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 <0.005 0.00 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020T: Total Metals by ICP-MS (QC Lot: 1104310)
EG020A-T: Iron 7439-89-6 0.05 mg/L 0.38 0.39 2.68 No LimitAnonymous EP1709417-001
EG020A-T: Iron 7439-89-6 0.05 mg/L 1.02 1.03 1.07 0% - 20%Anonymous EP1709766-001
EG020T: Total Metals by ICP-MS (QC Lot: 1104311)
EG020A-T: Iron 7439-89-6 0.05 mg/L 0.96 0.98 3.04 0% - 50%SW2 EP1709778-006
EG020A-T: Iron 7439-89-6 0.05 mg/L 0.07 0.12 48.2 No LimitAnonymous EP1709809-001
EG035F: Dissolved Mercury by FIMS (QC Lot: 1106839)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EP1709681-003
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitMW4 EP1709778-004
EK055G: Ammonia as N by Discrete Analyser (QC Lot: 1100185)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.79 0.82 2.76 0% - 20%Anonymous EP1709766-002
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.02 0.02 0.00 No LimitMW5 EP1709778-005
EK057G: Nitrite as N by Discrete Analyser (QC Lot: 1100181)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No LimitMW2 EP1709778-002
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EP1709780-004
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QC Lot: 1100186)
A
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QC Lot: 1100186) - continued
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 0.30 0.30 0.00 0% - 20%Anonymous EP1709766-002
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 0.02 0.04 70.6 No LimitMW5 EP1709778-005
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QC Lot: 1104429)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 64.6 62.2 3.76 0% - 20%Anonymous EP1709766-001
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 0.4 0.5 0.00 No LimitMW2 EP1709778-002
EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 1104428)
EK067G: Total Phosphorus as P ---- 0.01 mg/L 8.38 8.96 6.68 0% - 20%Anonymous EP1709766-001
EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 <0.01 0.00 No LimitMW2 EP1709778-002
EP005: Total Organic Carbon (TOC) (QC Lot: 1101910)
EP005: Total Organic Carbon ---- 1 mg/L 1 <1 0.00 No LimitAnonymous EP1709751-001
EP005: Total Organic Carbon ---- 1 mg/L 3 <1 104 No LimitMW2 EP1709778-002
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QC Lot: 1107645)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L 612 612 0.00 0% - 20%Anonymous EP1709766-001
EP026SP: Chemical Oxygen Demand ---- 10 mg/L 18 18 0.00 No LimitMW4 EP1709778-004
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 1105276)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitAnonymous EP1709769-001
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitAnonymous EP1709780-001
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 1105276)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitAnonymous EP1709769-001
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitAnonymous EP1709780-001
EP080: BTEXN (QC Lot: 1105276)
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitAnonymous EP1709769-001
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitAnonymous EP1709780-001
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
A
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Method Blank (MB) and Laboratory Control Spike (LCS) Report
The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC
parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target
analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QCLot: 1107222)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 1002000 mg/L 11183
<10 97.01000 mg/L 13070
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QCLot: 1107294)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 98.62000 mg/L 11183
<10 1021000 mg/L 13070
ED037P: Alkalinity by PC Titrator (QCLot: 1105014)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-00
1
1 mg/L <1 -------- --------
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 -------- --------
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L <1 -------- --------
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L <1 10220 mg/L 12676
<1 104200 mg/L 10690
ED045G: Chloride by Discrete Analyser (QCLot: 1100182)
ED045G: Chloride 16887-00-6 1 mg/L <1 10010 mg/L 12084
<1 1001000 mg/L 11084
ED093F: Dissolved Major Cations (QCLot: 1106838)
ED093F: Calcium 7440-70-2 1 mg/L <1 98.150 mg/L 10991
ED093F: Magnesium 7439-95-4 1 mg/L <1 10850 mg/L 10890
ED093F: Sodium 7440-23-5 1 mg/L <1 93.450 mg/L 11187
ED093F: Potassium 7440-09-7 1 mg/L <1 10850 mg/L 11090
EG020F: Dissolved Metals by ICP-MS (QCLot: 1106836)
EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 1030.5 mg/L 12084
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 1140.1 mg/L 12084
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 1060.1 mg/L 12086
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 1040.1 mg/L 12085
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 1070.1 mg/L 12084
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 1070.1 mg/L 12085
EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 1110.1 mg/L 12085
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 99.80.1 mg/L 12084
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 1130.1 mg/L 12088
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 1110.1 mg/L 12089
EG020T: Total Metals by ICP-MS (QCLot: 1104310)
EG020A-T: Iron 7439-89-6 0.05 mg/L <0.05 1140.5 mg/L 12077
EG020T: Total Metals by ICP-MS (QCLot: 1104311)
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EG020T: Total Metals by ICP-MS (QCLot: 1104311) - continued
EG020A-T: Iron 7439-89-6 0.05 mg/L <0.05 1130.5 mg/L 12077
EG035F: Dissolved Mercury by FIMS (QCLot: 1106839)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 1120.01 mg/L 11692
EK055G: Ammonia as N by Discrete Analyser (QCLot: 1100185)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 1031 mg/L 11587
EK057G: Nitrite as N by Discrete Analyser (QCLot: 1100181)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 1020.5 mg/L 11286
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 1100186)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 1030.5 mg/L 11292
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 1104429)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 90.710 mg/L 11082
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 1104428)
EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 84.04.42 mg/L 13070
EP005: Total Organic Carbon (TOC) (QCLot: 1101910)
EP005: Total Organic Carbon ---- 1 mg/L <1 91.610 mg/L 11179
<1 101100 mg/L 11179
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 1107645)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L <10 10550 mg/L 11282
<10 95.6500 mg/L 11383
EP066: Polychlorinated Biphenyls (PCB) (QCLot: 1101540)
EP066: Total Polychlorinated biphenyls ---- 1 µg/L <1 54.05 µg/L 9036
EP068A: Organochlorine Pesticides (OC) (QCLot: 1101542)
EP068: alpha-BHC 319-84-6 0.5 µg/L <0.5 59.25 µg/L 11242
EP068: Hexachlorobenzene (HCB) 118-74-1 0.5 µg/L <0.5 58.25 µg/L 10839
EP068: beta-BHC 319-85-7 0.5 µg/L <0.5 62.55 µg/L 11646
EP068: gamma-BHC 58-89-9 0.5 µg/L <0.5 63.85 µg/L 11843
EP068: delta-BHC 319-86-8 0.5 µg/L <0.5 63.65 µg/L 11546
EP068: Heptachlor 76-44-8 0.5 µg/L <0.5 56.05 µg/L 11139
EP068: Aldrin 309-00-2 0.5 µg/L <0.5 62.25 µg/L 11440
EP068: Heptachlor epoxide 1024-57-3 0.5 µg/L <0.5 68.85 µg/L 12242
EP068: trans-Chlordane 5103-74-2 0.5 µg/L <0.5 65.05 µg/L 12144
EP068: alpha-Endosulfan 959-98-8 0.5 µg/L <0.5 62.55 µg/L 12942
EP068: cis-Chlordane 5103-71-9 0.5 µg/L <0.5 58.25 µg/L 12343
EP068: Dieldrin 60-57-1 0.5 µg/L <0.5 57.55 µg/L 12142
EP068: 4.4`-DDE 72-55-9 0.5 µg/L <0.5 65.25 µg/L 12344
EP068: Endrin 72-20-8 0.5 µg/L <0.5 51.85 µg/L 12727
EP068: beta-Endosulfan 33213-65-9 0.5 µg/L <0.5 62.55 µg/L 12845
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP068A: Organochlorine Pesticides (OC) (QCLot: 1101542) - continued
EP068: 4.4`-DDD 72-54-8 0.5 µg/L <0.5 60.55 µg/L 12842
EP068: Endrin aldehyde 7421-93-4 0.5 µg/L <0.5 73.75 µg/L 12132
EP068: Endosulfan sulfate 1031-07-8 0.5 µg/L <0.5 57.15 µg/L 12041
EP068: 4.4`-DDT 50-29-3 2 µg/L <2.0 60.15 µg/L 12332
EP068: Endrin ketone 53494-70-5 0.5 µg/L <0.5 62.75 µg/L 12436
EP068: Methoxychlor 72-43-5 2 µg/L <2.0 53.85 µg/L 12425
EP075(SIM)A: Phenolic Compounds (QCLot: 1101543)
EP075(SIM): Phenol 108-95-2 1 µg/L <1.0 26.610 µg/L 469
EP075(SIM): 2-Chlorophenol 95-57-8 1 µg/L <1.0 59.410 µg/L 9734
EP075(SIM): 2-Methylphenol 95-48-7 1 µg/L <1.0 50.010 µg/L 9325
EP075(SIM): 3- & 4-Methylphenol 1319-77-3 2 µg/L <2.0 50.420 µg/L 8322
EP075(SIM): 2-Nitrophenol 88-75-5 1 µg/L <1.0 53.610 µg/L 10434
EP075(SIM): 2.4-Dimethylphenol 105-67-9 1 µg/L <1.0 51.910 µg/L 10234
EP075(SIM): 2.4-Dichlorophenol 120-83-2 1 µg/L <1.0 59.310 µg/L 10434
EP075(SIM): 2.6-Dichlorophenol 87-65-0 1 µg/L <1.0 70.810 µg/L 10238
EP075(SIM): 4-Chloro-3-methylphenol 59-50-7 1 µg/L <1.0 68.310 µg/L 10630
EP075(SIM): 2.4.6-Trichlorophenol 88-06-2 1 µg/L <1.0 82.410 µg/L 10932
EP075(SIM): 2.4.5-Trichlorophenol 95-95-4 1 µg/L <1.0 11010 µg/L 11034
EP075(SIM): Pentachlorophenol 87-86-5 2 µg/L <2.0 78.010 µg/L 10414
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 1101543)
EP075(SIM): Naphthalene 91-20-3 1 µg/L <1.0 66.210 µg/L 9942
EP075(SIM): Acenaphthylene 208-96-8 1 µg/L <1.0 60.610 µg/L 11336
EP075(SIM): Acenaphthene 83-32-9 1 µg/L <1.0 69.710 µg/L 10236
EP075(SIM): Fluorene 86-73-7 1 µg/L <1.0 61.710 µg/L 11334
EP075(SIM): Phenanthrene 85-01-8 1 µg/L <1.0 75.010 µg/L 11537
EP075(SIM): Anthracene 120-12-7 1 µg/L <1.0 73.610 µg/L 10946
EP075(SIM): Fluoranthene 206-44-0 1 µg/L <1.0 79.810 µg/L 12440
EP075(SIM): Pyrene 129-00-0 1 µg/L <1.0 65.510 µg/L 12340
EP075(SIM): Benz(a)anthracene 56-55-3 1 µg/L <1.0 61.610 µg/L 12640
EP075(SIM): Chrysene 218-01-9 1 µg/L <1.0 62.010 µg/L 12146
EP075(SIM): Benzo(b+j)fluoranthene 205-99-2
205-82-3
1 µg/L <1.0 69.810 µg/L 12343
EP075(SIM): Benzo(k)fluoranthene 207-08-9 1 µg/L <1.0 72.310 µg/L 12147
EP075(SIM): Benzo(a)pyrene 50-32-8 0.5 µg/L <0.5 74.610 µg/L 12345
EP075(SIM): Indeno(1.2.3.cd)pyrene 193-39-5 1 µg/L <1.0 63.510 µg/L 12039
EP075(SIM): Dibenz(a.h)anthracene 53-70-3 1 µg/L <1.0 63.610 µg/L 11939
EP075(SIM): Benzo(g.h.i)perylene 191-24-2 1 µg/L <1.0 67.510 µg/L 12340
EP075(SIM): Sum of polycyclic aromatic hydrocarbons ---- 0.5 µg/L <0.5 -------- --------
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EP1709778 Amendment 1
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1101541)
EP071: C10 - C14 Fraction ---- 50 µg/L <50 78.4385 µg/L 9535
EP071: C15 - C28 Fraction ---- 100 µg/L <100 89.4385 µg/L 11134
EP071: C29 - C36 Fraction ---- 50 µg/L <50 86.3398 µg/L 10534
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1105276)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 94.0320 µg/L 11374
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 1101541)
EP071: >C10 - C16 Fraction ---- 100 µg/L <100 82.6380 µg/L 9937
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 88.0597 µg/L 10835
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 93.8168 µg/L 11711
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 1105276)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 96.4370 µg/L 11574
EP080: BTEXN (QCLot: 1105276)
EP080: Benzene 71-43-2 1 µg/L <1 94.920 µg/L 11484
EP080: Toluene 108-88-3 2 µg/L <2 85.720 µg/L 11581
EP080: Ethylbenzene 100-41-4 2 µg/L <2 85.220 µg/L 11384
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 87.840 µg/L 11484
EP080: ortho-Xylene 95-47-6 2 µg/L <2 87.120 µg/L 11187
EP080: Naphthalene 91-20-3 5 µg/L <5 99.720 µg/L 11877
Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on
analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
ED045G: Chloride by Discrete Analyser (QCLot: 1100182)
MW1 EP1709778-001 16887-00-6ED045G: Chloride 1041000 mg/L 13070
EG020F: Dissolved Metals by ICP-MS (QCLot: 1106836)
Anonymous EP1709681-002 7440-38-2EG020A-F: Arsenic 1030.2 mg/L 13070
7440-43-9EG020A-F: Cadmium 1020.05 mg/L 13070
7440-47-3EG020A-F: Chromium 98.80.2 mg/L 13070
7440-50-8EG020A-F: Copper 1020.2 mg/L 13070
7439-92-1EG020A-F: Lead 1030.2 mg/L 13070
7439-96-5EG020A-F: Manganese 1040.2 mg/L 13070
7440-02-0EG020A-F: Nickel 95.40.2 mg/L 13070
7440-66-6EG020A-F: Zinc 1050.2 mg/L 13070
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EG035F: Dissolved Mercury by FIMS (QCLot: 1106839)
Anonymous EP1709681-004 7439-97-6EG035F: Mercury 1130.01 mg/L 13070
EK055G: Ammonia as N by Discrete Analyser (QCLot: 1100185)
Anonymous EP1709766-001 7664-41-7EK055G: Ammonia as N # Not
Determined
1 mg/L 13070
EK057G: Nitrite as N by Discrete Analyser (QCLot: 1100181)
Anonymous EP1709766-001 14797-65-0EK057G: Nitrite as N 1040.5 mg/L 13070
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 1100186)
Anonymous EP1709766-001 ----EK059G: Nitrite + Nitrate as N 1200.5 mg/L 13070
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 1104429)
Anonymous EP1709766-001 ----EK061G: Total Kjeldahl Nitrogen as N 76.525 mg/L 13070
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 1104428)
Anonymous EP1709766-001 ----EK067G: Total Phosphorus as P 79.75 mg/L 13070
EP005: Total Organic Carbon (TOC) (QCLot: 1101910)
Anonymous EP1709751-002 ----EP005: Total Organic Carbon 105100 mg/L 13070
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 1107645)
Anonymous EP1709766-001 ----EP026SP: Chemical Oxygen Demand 110582 mg/L 13070
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1105276)
Anonymous EP1709769-002 ----EP080: C6 - C9 Fraction 77.0240 µg/L 13777
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 1105276)
Anonymous EP1709769-002 C6_C10EP080: C6 - C10 Fraction 77.3290 µg/L 13777
EP080: BTEXN (QCLot: 1105276)
Anonymous EP1709769-002 71-43-2EP080: Benzene 78.220 µg/L 12277
108-88-3EP080: Toluene 74.420 µg/L 12674
A
True
Environmental
QA/QC Compliance Assessment to assist with Quality ReviewWork Order : EP1709778 Page : 1 of 11
:Amendment 1
:: LaboratoryClient Environmental Division PerthEMERGE ASSOCIATES
:Contact MR SIMON GREGG Telephone : 08 9209 7631
:Project EP15-050(05) SAMR Monitoring - Davis Road Date Samples Received : 07-Sep-2017
Site : ---- Issue Date : 14-Sep-2017
MITCHELL RITIKIS:Sampler No. of samples received : 7
:Order number ---- No. of samples analysed : 7
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated
reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this
report contribute to the overall DQO assessment and reporting for guideline compliance.
Brief method summaries and references are also provided to assist in traceability.
Summary of Outliers
Outliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.
l NO Duplicate outliers occur.
l NO Laboratory Control outliers occur.
l Matrix Spike outliers exist - please see following pages for full details.
l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliance
l NO Analysis Holding Time Outliers exist.
Outliers : Frequency of Quality Control Samples
l Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Outliers : Quality Control Samples
Duplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes
Matrix: WATER
Compound Group Name CommentLimitsDataAnalyteClient Sample IDLaboratory Sample ID CAS Number
Matrix Spike (MS) Recoveries
EP1709766--001 7664-41-7Ammonia as NAnonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EK055G: Ammonia as N by Discrete Analyser
Outliers : Frequency of Quality Control Samples
Matrix: WATER
Quality Control SpecificationQuality Control Sample Type
Method ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 10.000 18
NEPM 2013 B3 & ALS QC StandardPesticides by GCMS 0.00 10.000 7
NEPM 2013 B3 & ALS QC StandardPolychlorinated Biphenyls (PCB) 0.00 10.000 7
NEPM 2013 B3 & ALS QC StandardTRH - Semivolatile Fraction 0.00 10.000 18
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 5.000 18
NEPM 2013 B3 & ALS QC StandardPesticides by GCMS 0.00 5.000 7
NEPM 2013 B3 & ALS QC StandardPolychlorinated Biphenyls (PCB) 0.00 5.000 7
NEPM 2013 B3 & ALS QC StandardTotal Metals by ICP-MS - Suite A 0.00 5.000 28
NEPM 2013 B3 & ALS QC StandardTRH - Semivolatile Fraction 0.00 5.000 18
Analysis Holding Time Compliance
Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and
should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.
Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics
14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.
If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.
This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container
provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EA015: Total Dissolved Solids dried at 180 ± 5 °C
Clear Plastic Bottle - Natural (EA015H)
MW2, MW3,
MW4, MW5,
SW2, SW1
12-Sep-2017---- 12-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Natural (EA015H)
MW1 13-Sep-2017---- 12-Sep-2017----06-Sep-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
ED037P: Alkalinity by PC Titrator
Clear Plastic Bottle - Natural (ED037-P)
MW2, MW3,
MW4, MW5,
SW2, SW1
19-Sep-2017---- 11-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Natural (ED037-P)
MW1 20-Sep-2017---- 11-Sep-2017----06-Sep-2017 ---- üED045G: Chloride by Discrete Analyser
Clear Plastic Bottle - Natural (ED045G)
MW2, MW3,
MW4, MW5,
SW2, SW1
03-Oct-2017---- 07-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Natural (ED045G)
MW1 04-Oct-2017---- 07-Sep-2017----06-Sep-2017 ---- üED093F: Dissolved Major Cations
Clear Plastic Bottle - Filtered; Lab-acidified (ED093F)
MW2, MW3,
MW4, MW5,
SW2, SW1
03-Oct-2017---- 12-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Filtered; Lab-acidified (ED093F)
MW1 04-Oct-2017---- 12-Sep-2017----06-Sep-2017 ---- üEG020F: Dissolved Metals by ICP-MS
Clear Plastic Bottle - Filtered; Lab-acidified (EG020A-F)
MW2, MW3,
MW4, MW5,
SW2, SW1
04-Mar-2018---- 12-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Filtered; Lab-acidified (EG020A-F)
MW1 05-Mar-2018---- 12-Sep-2017----06-Sep-2017 ---- üEG020T: Total Metals by ICP-MS
Clear Plastic Bottle - Unfiltered; Lab-acidified (EG020A-T)
MW2, MW3,
MW4, MW5,
SW2, SW1
04-Mar-201804-Mar-2018 12-Sep-201712-Sep-201705-Sep-2017 ü ü
Clear Plastic Bottle - Unfiltered; Lab-acidified (EG020A-T)
MW1 05-Mar-201805-Mar-2018 12-Sep-201712-Sep-201706-Sep-2017 ü üEG035F: Dissolved Mercury by FIMS
Clear Plastic Bottle - Filtered; Lab-acidified (EG035F)
MW2, MW3,
MW4, MW5,
SW2, SW1
03-Oct-2017---- 12-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Filtered; Lab-acidified (EG035F)
MW1 04-Oct-2017---- 12-Sep-2017----06-Sep-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EK055G: Ammonia as N by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK055G)
MW2, MW3,
MW4, MW5,
SW2, SW1
03-Oct-2017---- 07-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Sulfuric Acid (EK055G)
MW1 04-Oct-2017---- 07-Sep-2017----06-Sep-2017 ---- üEK057G: Nitrite as N by Discrete Analyser
Clear Plastic Bottle - Natural (EK057G)
MW2, MW3,
MW4, MW5,
SW2, SW1
07-Sep-2017---- 07-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Natural (EK057G)
MW1 08-Sep-2017---- 07-Sep-2017----06-Sep-2017 ---- üEK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK059G)
MW2, MW3,
MW4, MW5,
SW2, SW1
03-Oct-2017---- 07-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Sulfuric Acid (EK059G)
MW1 04-Oct-2017---- 07-Sep-2017----06-Sep-2017 ---- üEK061G: Total Kjeldahl Nitrogen By Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK061G)
MW2, MW3,
MW4, MW5,
SW2, SW1
03-Oct-201703-Oct-2017 12-Sep-201712-Sep-201705-Sep-2017 ü ü
Clear Plastic Bottle - Sulfuric Acid (EK061G)
MW1 04-Oct-201704-Oct-2017 12-Sep-201712-Sep-201706-Sep-2017 ü üEK067G: Total Phosphorus as P by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK067G)
MW2, MW3,
MW4, MW5,
SW2, SW1
03-Oct-201703-Oct-2017 12-Sep-201712-Sep-201705-Sep-2017 ü ü
Clear Plastic Bottle - Sulfuric Acid (EK067G)
MW1 04-Oct-201704-Oct-2017 12-Sep-201712-Sep-201706-Sep-2017 ü üEP005: Total Organic Carbon (TOC)
Amber TOC Vial - Sulfuric Acid (EP005)
MW2, MW3,
MW4, MW5,
SW2, SW1
03-Oct-2017---- 08-Sep-2017----05-Sep-2017 ---- ü
Amber TOC Vial - Sulfuric Acid (EP005)
MW1 04-Oct-2017---- 08-Sep-2017----06-Sep-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP026SP: Chemical Oxygen Demand (Spectrophotometric)
Clear Plastic Bottle - Sulfuric Acid (EP026SP)
MW2, MW3,
MW4, MW5,
SW2, SW1
03-Oct-2017---- 12-Sep-2017----05-Sep-2017 ---- ü
Clear Plastic Bottle - Sulfuric Acid (EP026SP)
MW1 04-Oct-2017---- 12-Sep-2017----06-Sep-2017 ---- üEP066: Polychlorinated Biphenyls (PCB)
Amber Glass Bottle - Unpreserved (EP066)
MW2, MW3,
MW4, MW5,
SW2, SW1
21-Oct-201712-Sep-2017 12-Sep-201711-Sep-201705-Sep-2017 ü ü
Amber Glass Bottle - Unpreserved (EP066)
MW1 21-Oct-201713-Sep-2017 12-Sep-201711-Sep-201706-Sep-2017 ü üEP068A: Organochlorine Pesticides (OC)
Amber Glass Bottle - Unpreserved (EP068)
MW2, MW3,
MW4, MW5,
SW2, SW1
21-Oct-201712-Sep-2017 12-Sep-201711-Sep-201705-Sep-2017 ü ü
Amber Glass Bottle - Unpreserved (EP068)
MW1 21-Oct-201713-Sep-2017 12-Sep-201711-Sep-201706-Sep-2017 ü üEP075(SIM)A: Phenolic Compounds
Amber Glass Bottle - Unpreserved (EP075(SIM))
MW2, MW3,
MW4, MW5,
SW2, SW1
21-Oct-201712-Sep-2017 11-Sep-201711-Sep-201705-Sep-2017 ü ü
Amber Glass Bottle - Unpreserved (EP075(SIM))
MW1 21-Oct-201713-Sep-2017 11-Sep-201711-Sep-201706-Sep-2017 ü üEP075(SIM)B: Polynuclear Aromatic Hydrocarbons
Amber Glass Bottle - Unpreserved (EP075(SIM))
MW2, MW3,
MW4, MW5,
SW2, SW1
21-Oct-201712-Sep-2017 11-Sep-201711-Sep-201705-Sep-2017 ü ü
Amber Glass Bottle - Unpreserved (EP075(SIM))
MW1 21-Oct-201713-Sep-2017 11-Sep-201711-Sep-201706-Sep-2017 ü ü
A
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EP1709778 Amendment 1
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP080/071: Total Petroleum Hydrocarbons
Amber Glass Bottle - Unpreserved (EP071)
MW2, MW3,
MW4, MW5,
SW2, SW1
21-Oct-201712-Sep-2017 11-Sep-201711-Sep-201705-Sep-2017 ü ü
Amber Glass Bottle - Unpreserved (EP071)
MW1 21-Oct-201713-Sep-2017 11-Sep-201711-Sep-201706-Sep-2017 ü üAmber VOC Vial - Sulfuric Acid (EP080)
MW2, MW3,
MW4, MW5,
SW2, SW1
19-Sep-201719-Sep-2017 12-Sep-201712-Sep-201705-Sep-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
MW1 20-Sep-201720-Sep-2017 12-Sep-201712-Sep-201706-Sep-2017 ü üEP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
Amber Glass Bottle - Unpreserved (EP071)
MW2, MW3,
MW4, MW5,
SW2, SW1
21-Oct-201712-Sep-2017 11-Sep-201711-Sep-201705-Sep-2017 ü ü
Amber Glass Bottle - Unpreserved (EP071)
MW1 21-Oct-201713-Sep-2017 11-Sep-201711-Sep-201706-Sep-2017 ü üAmber VOC Vial - Sulfuric Acid (EP080)
MW2, MW3,
MW4, MW5,
SW2, SW1
19-Sep-201719-Sep-2017 12-Sep-201712-Sep-201705-Sep-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
MW1 20-Sep-201720-Sep-2017 12-Sep-201712-Sep-201706-Sep-2017 ü üEP080: BTEXN
Amber VOC Vial - Sulfuric Acid (EP080)
MW2, MW3,
MW4, MW5,
SW2, SW1
19-Sep-201719-Sep-2017 12-Sep-201712-Sep-201705-Sep-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
MW1 20-Sep-201720-Sep-2017 12-Sep-201712-Sep-201706-Sep-2017 ü ü
A
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:Client
EP1709778 Amendment 1
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to
the expected rate. A listing of breaches is provided in the Summary of Outliers.
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC Standard 12.50 10.002 16 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 18.18 10.002 11 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 18 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 7 ûPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 7 ûPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 12.50 10.004 32 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 14.29 10.004 28 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 18 ûTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTRH Volatiles/BTEX EP080
Laboratory Control Samples (LCS)
NEPM 2013 B3 & ALS QC Standard 12.50 10.002 16 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 18.18 10.002 11 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 12.50 10.004 32 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 7.14 5.002 28 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Organic Carbon EP005
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EP1709778 Amendment 1
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Control Samples (LCS) - Continued
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH Volatiles/BTEX EP080
Method Blanks (MB)
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 6.25 5.002 32 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 7.14 5.002 28 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH Volatiles/BTEX EP080
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üNitrite as N by Discrete Analyser EK057G
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 18 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 7 ûPesticides by GCMS EP068
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 7 ûPolychlorinated Biphenyls (PCB) EP066
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 28 ûTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Phosphorus as P By Discrete Analyser EK067G
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 18 ûTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH Volatiles/BTEX EP080
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EP1709778 Amendment 1
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the
Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 2540C. A gravimetric procedure that determines the amount of `filterable` residue
in an aqueous sample. A well-mixed sample is filtered through a glass fibre filter (1.2um). The filtrate is
evaporated to dryness and dried to constant weight at 180+/-5C. This method is compliant with NEPM (2013)
Schedule B(3)
Total Dissolved Solids (High Level) EA015H WATER
In house: Referenced to APHA 2320 B This procedure determines alkalinity by automated measurement (e.g. PC
Titrate) using pH 4.5 for indicating the total alkalinity end-point. This method is compliant with NEPM (2013)
Schedule B(3)
Alkalinity by PC Titrator ED037-P WATER
In house: Referenced to APHA 4500 Cl - G.The thiocyanate ion is liberated from mercuric thiocyanate through
sequestration of mercury by the chloride ion to form non-ionised mercuric chloride.in the presence of ferric ions
the librated thiocynate forms highly-coloured ferric thiocynate which is measured at 480 nm APHA 21st edition
seal method 2 017-1-L april 2003
Chloride by Discrete Analyser ED045G WATER
In house: Referenced to APHA 3120 and 3125; USEPA SW 846 - 6010 and 6020; Cations are determined by
either ICP-AES or ICP-MS techniques. This method is compliant with NEPM (2013) Schedule B(3)
Sodium Adsorption Ratio is calculated from Ca, Mg and Na which determined by ALS in house method
QWI-EN/ED093F. This method is compliant with NEPM (2013) Schedule B(3)
Hardness parameters are calculated based on APHA 2340 B. This method is compliant with NEPM (2013)
Schedule B(3)
Major Cations - Dissolved ED093F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. Samples are 0.45µm filtered
prior to analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions
are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct
mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Dissolved Metals by ICP-MS - Suite A EG020A-F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. The ICPMS technique utilizes
a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass
spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their
measurement by a discrete dynode ion detector.
Total Metals by ICP-MS - Suite A EG020A-T WATER
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS)
Samples are 0.45µm filtered prior to analysis. FIM-AAS is an automated flameless atomic absorption technique.
A bromate/bromide reagent is used to oxidise any organic mercury compounds in the filtered sample. The ionic
mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell.
Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM
(2013) Schedule B(3)
Dissolved Mercury by FIMS EG035F WATER
In house: Referenced to APHA 4500-NH3 G Ammonia is determined by direct colorimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Ammonia as N by Discrete analyser EK055G WATER
In house: Referenced to APHA 4500-NO2- B. Nitrite is determined by direct colourimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Nitrite as N by Discrete Analyser EK057G WATER
A
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EP1709778 Amendment 1
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500-NO3- F. Nitrate is reduced to nitrite by way of a chemical reduction followed
by quantification by Discrete Analyser. Nitrite is determined seperately by direct colourimetry and result for Nitrate
calculated as the difference between the two results. This method is compliant with NEPM (2013) Schedule B(3)
Nitrate as N by Discrete Analyser EK058G WATER
In house: Referenced to APHA 4500-NO3- F. Combined oxidised Nitrogen (NO2+NO3) is determined by
Chemical Reduction and direct colourimetry by Discrete Analyser. This method is compliant with NEPM (2013)
Schedule B(3)
Nitrite and Nitrate as N (NOx) by Discrete
Analyser
EK059G WATER
In house: Referenced to APHA 4500-Norg D (In house). An aliquot of sample is digested using a high
temperature Kjeldahl digestion to convert nitrogenous compounds to ammonia. Ammonia is determined
colorimetrically by discrete analyser. This method is compliant with NEPM (2013) Schedule B(3)
Total Kjeldahl Nitrogen as N By Discrete
Analyser
EK061G WATER
In house: Referenced to APHA 4500-Norg / 4500-NO3-. This method is compliant with NEPM (2013) Schedule
B(3)
Total Nitrogen as N (TKN + Nox) By
Discrete Analyser
EK062G WATER
In house: Referenced to APHA 4500-P H, Jirka et al (1976), Zhang et al (2006). This procedure involves
sulphuric acid digestion of a sample aliquot to break phosphorus down to orthophosphate. The orthophosphate
reacts with ammonium molybdate and antimony potassium tartrate to form a complex which is then reduced and
its concentration measured at 880nm using discrete analyser. This method is compliant with NEPM (2013)
Schedule B(3)
Total Phosphorus as P By Discrete
Analyser
EK067G WATER
In house: Referenced to APHA 5310 B, The automated TOC analyzer determines Total and Inorganic Carbon by
IR cell. TOC is calculated as the difference. This method is compliant with NEPM (2013) Schedule B(3)
Total Organic Carbon EP005 WATER
In house: Referenced to APHA 5220 D. Samples are digested with a known excess of an acidic potassium
dichromate solution using silver sulfate as a catalyst. The chromium is reduced from the Cr (VI) oxidation state
to the Cr (III) state by the oxygen present in the organic material. Both of these chromium species are coloued
and absorb in the visible region of (400nm & 600nm) the spectrum. The oxidisable organic matter can be
calculated in terms of oxygen equivalents.
Chemical Oxygen Demand (COD)
(Spectrophotometric)
EP026SP WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS and
quantification is by comparison against an established 5 point calibration curve. This method is compliant with
NEPM (2013) Schedule B(3)
Polychlorinated Biphenyls (PCB) EP066 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS and
quantification is by comparison against an established 5 point calibration curve. This method is compliant with
NEPM (2013) Schedule B(3)
Pesticides by GCMS EP068 WATER
In house: Referenced to USEPA SW 846 - 8015A The sample extract is analysed by Capillary GC/FID and
quantification is by comparison against an established 5 point calibration curve of n-Alkane standards. This
method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH - Semivolatile Fraction EP071 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS in SIM Mode
and quantification is by comparison against an established 5 point calibration curve. This method is compliant
with NEPM (2013) Schedule B(3)
PAH/Phenols (GC/MS - SIM) EP075(SIM) WATER
In house: Referenced to USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by
Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve.
Alternatively, a sample is equilibrated in a headspace vial and a portion of the headspace determined by GCMS
analysis. This method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH Volatiles/BTEX EP080 WATER
Preparation Methods Method DescriptionsMatrixMethod
A
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EP1709778 Amendment 1
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring - Davis Road:Project
Preparation Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 Norg - D; APHA 4500 P - H. This method is compliant with NEPM (2013)
Schedule B(3)
TKN/TP Digestion EK061/EK067 WATER
In house: Referenced to USEPA SW846-3005. Method 3005 is a Nitric/Hydrochloric acid digestion procedure
used to prepare surface and ground water samples for analysis by ICPAES or ICPMS. This method is compliant
with NEPM (2013) Schedule B(3)
Digestion for Total Recoverable Metals EN25 WATER
In house: Referenced to USEPA SW 846 - 3510B 100 mL to 1L of sample is transferred to a separatory funnel
and serially extracted three times using 60mL DCM for each extract. The resultant extracts are combined,
dehydrated and concentrated for analysis. This method is compliant with NEPM (2013) Schedule B(3) . ALS
default excludes sediment which may be resident in the container.
Separatory Funnel Extraction of Liquids ORG14 WATER
A 5 mL aliquot or 5 mL of a diluted sample is added to a 40 mL VOC vial for sparging.Volatiles Water Preparation ORG16-W WATER
A
r-· ""· i ·~UENT: Emerge Associates POSTAL ADDRESS: Suite 4, 26 Railway Road, Subiaco WA 6008
CHAIN OF CUSTODY ~m~rgl' iMegr.aled S,;:ie~ce & De'.lillfl
PROJECT MANAGER: Simon Gregg CONTACT PHONE: 9380 4988
PROJECT ID.: EP15-050(05) PROJECT NAME: SAMR Monitoring - Davis Road :,_ _________ _,j
SAMPLER(S): Mitchell Ritikis SAMPLERS PHONE: 0449 198 721
Email reports to: simon.gregg@emergeassociates.com.au; mitchell.ritikis@emergeassociates.com.au QUOTE NO.: EP/009/16 ORDER NO.: -------------------------t·i-~r':' .. f!l.Y-P<l.Y~t@e_ri:, __ ~rge_~S,_S,(J~_i_c;1_tE:,_S,-~_(:)_r:D_~-~-~---" ______________________ __,1
SAMPLE DETAILS
Lab ID Sample ID
GWQAJ8
NAME : Mitchell Ritikis
OF: Emerge Associates ..
NAME:
Matrix Date
Water I 05/09/2017
RELINQUISHED BY:
Comments/special handling/storage or disposal
PLEASE FORWARD TO SYDNEY ALS Please note short holding time for some analysis.
CONTAINER INFORMATION
Type & Preservative
2 SP, 3 P, 3 V, 1 AG
Total No.
9
Email invoice to: accounts@emergeassociates.com.au
ANALYSIS REQUIRED
-~ Z_c:-o c 5 X ::,2
Y l f _ '.iE g:_ ~ ~ Additional information 8 I .; "'· z j'. ~ a: (likely contaminants, a:~ .§ ~ ~ ~ _ c'.:l °'- dilutions or specific QC o::: -- iii' 00 · z o w >- ro w :r: <( analys·rs) C,ZO 00> I- 't:I ~ 0 <(""O r-... x n. .,... ~ m z_ ·;::: :E ~ -~ c ...... w-- , - ,No ro O (I) i O c N ro :>~0 1-0 1-0 :c == 0 0 0 0 '.>,6Q) >--0 Z- ZZ O <( 0 I- I- ..=: >CL.W
X X X X X X X ! X X X I Mislabelled as Split1
RECEIVED BY
Environmental Division Sydney
Work Order Reference
1::81722611
11111 Telephone: + 61-:2-8784 8555
Coe emailed to ALS?
DATE: 07/09/2017 I NAME :
TIME: 9:30arn __ JQE: ... ,w - '· lJ DATE:
ISi Yes D No
DATE: INAME: Water Container Codes: P = Unpreserved Plastic; N = Nitric Preserved Plastic; ORC = Nitric Preserved ORC; SH= Sodium Hydroxide/Cd Preserved; S = Sodium Hydroxide Preserved Plastic; AG =-Amber Glass Unpreserved; AP= Airfreight
1Unpreserved Plastic; V = VOA Vial HCI Preserved; VB= VOA Vial Sodium Bisulphate Preserved; VS= VOA Vial Sulfuric Preserved; AV= Airfreight Unpreserved Vial; SG = Sulfuric Preserved Amber Glass:
H = HCI preserved Plastic: HS= HCI Preserved Speciation bottle; SP= Sulfuric Preserved Plastic: F = Formaldehyde Preserved Glass; Z = Zinc Acetate Preserved Bottle; E = EDTA Preserved Bottles; ST= Sterile Bottle; LI= Lugols Iodine Preserved Bottles; STT = Sterile Sodium Thiosulfate Pr~served Bottles. Soil Container Codes: J = Jar: ASS= Plastic Ba~ for Acid Sulfate Soils; _B = Unpreserved Bag;
pJ-r gJCJ)/';J, 11,"30
~·
"
~
'
Matthew Westwell
From: Alicia Manning ----Sent~: ---·
To: ----Th1:Jrsday,7-5e17t-em0er--WH-12~03-PM--- -
Matthew Westwell Cc: Subject: Attachments:
Hey Mat,
Samples Perth FW: SAMR GW Sampling 2017-09-07 Davis Road CoC - Perth (SAMR MWs and SWs).docx; 2017-09-07 Davis Road CoC - Perth (SAMR MWs and SWs).pdf; 2017-09-07 Davis Road CoC - Perth (Licence).docx; 2017-09-07 Davis Road CoC - Perth (Licence).pdf; 2016-09-07 Davis Road CoC - Split.docx; 2016-09-07 Davis Road Coe - Split.pdf
Can you attach this to the paperwork when the samples arrive?
Thanks©
---------------~---· ·- -------··--------From: Mitchell Ritikis [mailto:Mitchell.Ritikis@emergeassociates.com.au] Sent: Thursday, 7 September 2017 11:59 AM To: Samples Perth <Samples.Perth@ALSGlobal.com> Cc: Simon Gregg <Simon.Gregg@emergeassociates.com.au>; Jeremy Payet <jeremy:payet@emergeassociates.com.au> Subject: SAMR GW Sampling
Hi Guys,
Please find attached COCs for the SAMR- Davis Rd Groundwater samples sent in this morning,
Please note that GWQA17 (Dupl) and GWQA18 (Splitl) were mislabelled as per brackets - please report them as per the COC
If you have any issues please contact me - 0449198721
Thank you,
emerg.····· . .1f, .: :;1"" ;,":, · .. :~ ~:>
'
Mitchell Ritikis . • ·.· '
0 ".'G'fadlJafii EfivlrolWi'ieM;a !Co1isillfa1'if 1c'i'ii'ir.:il'/ilff~tei'.!'Uffil& J1.$S"., e Mitchell.Ritikis@emergeassociates.com.au Suite 4, 26 Railway Road, Subiaco WA 6008 w emergeassociates.com.au // t +618 9380 4988
fin!(li}(Tl~f@l1i] Le_,._...~ 1o._.,,. ~J _;::,_,..J L ... _, _ _,
We are a preferred supplier under WALGA's Environmental Consulting Services (NAM) and Engineering Consulting Services (V\fater Management Engineering and Arboriculture & Horticultural Consultancy) Preferred-Supply Contracts.
1
Environmental
SAMPLE RECEIPT NOTIFICATION (SRN)Work Order : ES1722611
:: LaboratoryClient Environmental Division SydneyEMERGE ASSOCIATES
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA
6008
277-289 Woodpark Road Smithfield
NSW Australia 2164
:: E-mailE-mail simon.gregg@emergeassociates.co
m.au
LUKE.JONES@alsglobal.com
:: TelephoneTelephone +61 08 9380 4988 08 9209 7631
:: FacsimileFacsimile +61 08 9380 9636 +61-2-8784 8500
::Project EP15-050(05) SAMR Monitoring-Davis
Road
Page 1 of 3
:Order number ---- :Quote number EP2016EMEASS0001 (EPBQ-009-16)
:C-O-C number ---- :QC Level NEPM 2013 B3 & ALS QC Standard
Site : ----
Sampler : MITCHELL RITIKIS
DatesDate Samples Received : Issue Date : 08-Sep-201708-Sep-2017 15:30
Scheduled Reporting Date: 15-Sep-2017:Client Requested Due
Date
15-Sep-2017
Delivery DetailsMode of Delivery : :Undefined Not intact.Security Seal
No. of coolers/boxes : :1 Temperature 13.5 - Ice present
: : 1 / 1Receipt Detail No. of samples received / analysed
General Comments
This report contains the following information:l
- Sample Container(s)/Preservation Non-Compliances
- Summary of Sample(s) and Requested Analysis
- Proactive Holding Time Report
- Requested Deliverables
l Please refer to the Proactive Holding Time Report table below which summarises breaches of
recommended holding times that have occurred prior to samples/instructions being received at
the laboratory. The absence of this summary table indicates that all samples have been received
within the recommended holding times for the analysis requested.l Sample(s) requiring volatile organic compound analysis received in airtight containers (ZHE).l Please direct any queries you have regarding this work order to the above ALS laboratory contact.
l Analytical work for this work order will be conducted at ALS Sydney.
l Sample Disposal - Aqueous (14 days), Solid (60 days) from date of completion of work order.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
:Client EMERGE ASSOCIATES
Work Order : ES1722611 Amendment 02 of 3:Page
08-Sep-2017:Issue Date
Sample Container(s)/Preservation Non-Compliances
All comparisons are made against pretreatment/preservation AS, APHA, USEPA standards.
l No sample container / preservation non-compliance exists.
Summary of Sample(s) and Requested Analysis
Some items described below may be part of a laboratory
process necessary for the execution of client requested
tasks. Packages may contain additional analyses, such
as the determination of moisture content and preparation
tasks, that are included in the package.
If no sampling time is provided, the sampling time will
default 00:00 on the date of sampling. If no sampling date
is provided, the sampling date will be assumed by the
laboratory and displayed in brackets without a time
component
WA
TE
R -
ED
037-P
Alk
alin
ity a
s C
aC
O3 (
PC
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WA
TE
R -
ED
045G
Chlo
ride b
y D
iscr
ete
Analy
ser
WA
TE
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EP
026S
P
Chem
ical O
xygen D
em
and (
CO
D)
WA
TE
R -
NT
-01
Majo
r C
atio
ns
(Ca, M
g, N
a, K
)
WA
TE
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NT
-08
Tota
l Nitr
ogen +
NO
2 +
NO
3 +
NH
3 +
Tota
l P
WA
TE
R -
W-0
2
8 M
eta
ls
WA
TE
R -
W-1
7
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H/B
TE
XN
/PA
H/P
henols
/OC
/PC
B
ES1722611-001 08-Sep-2017 00:00 GWQA18 ü ü ü ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
WA
TE
R -
EA
01
5H
To
tal D
isso
lve
d S
olid
s -
Hig
h L
eve
l
WA
TE
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EG
02
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To
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Me
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ES1722611-001 08-Sep-2017 00:00 GWQA18 ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
Proactive Holding Time Report
Sample(s) have been received within the recommended holding times for the requested analysis.
I I I
I I I
:Client EMERGE ASSOCIATES
Work Order : ES1722611 Amendment 03 of 3:Page
08-Sep-2017:Issue Date
Requested Deliverables
ACCOUNTS (INVOICES)
- A4 - AU Tax Invoice (INV) Email accounts@emergeassociates.com.
au
- Chain of Custody (CoC) (COC) Email accounts@emergeassociates.com.
au
JEREMY PAYET
- *AU Certificate of Analysis - NATA (COA) Email jeremy.payet@emergeassociates.co
m.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email jeremy.payet@emergeassociates.co
m.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email jeremy.payet@emergeassociates.co
m.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email jeremy.payet@emergeassociates.co
m.au
- Chain of Custody (CoC) (COC) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - ESDAT (ESDAT) Email jeremy.payet@emergeassociates.co
m.au
- EDI Format - XTab (XTAB) Email jeremy.payet@emergeassociates.co
m.au
MITCHELL RITIKIS
- *AU Certificate of Analysis - NATA (COA) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email mitchell.ritikis@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email mitchell.ritikis@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email mitchell.ritikis@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email mitchell.ritikis@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email mitchell.ritikis@emergeassociates.c
om.au
SIMON GREGG
- *AU Certificate of Analysis - NATA (COA) Email simon.gregg@emergeassociates.c
om.au
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email simon.gregg@emergeassociates.c
om.au
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email simon.gregg@emergeassociates.c
om.au
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email simon.gregg@emergeassociates.c
om.au
- Chain of Custody (CoC) (COC) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - ESDAT (ESDAT) Email simon.gregg@emergeassociates.c
om.au
- EDI Format - XTab (XTAB) Email simon.gregg@emergeassociates.c
om.au
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 8ES1722611
:: LaboratoryClient EMERGE ASSOCIATES Environmental Division Sydney
: :ContactContact MR SIMON GREGG Luke Jones
:: AddressAddress SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
277-289 Woodpark Road Smithfield NSW Australia 2164
:Telephone +61 08 9380 4988 :Telephone 08 9209 7631
:Project EP15-050(05) SAMR Monitoring-Davis Road Date Samples Received : 08-Sep-2017 15:30
:Order number ---- Date Analysis Commenced : 08-Sep-2017
:C-O-C number ---- Issue Date : 15-Sep-2017 16:50
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EPBQ-009-16
1:No. of samples received
1:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:
l General Comments
l Analytical Results
l Surrogate Control Limits
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with
Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Edwandy Fadjar Organic Coordinator Sydney Organics, Smithfield, NSW
Raymond Commodore Instrument Chemist Sydney Inorganics, Smithfield, NSW
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with 1S0/IEC 17025 - Testing
2 of 8:Page
Work Order :
:Client
ES1722611
EP15-050(05) SAMR Monitoring-Davis Road:Project
EMERGE ASSOCIATES
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When no sampling time is provided, the sampling time will default 00:00 on the date of sampling. If no sampling date is provided, the sampling date will be assumed by the laboratory and displayed in brackets without a
time component.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
^ = This result is computed from individual analyte detections at or above the level of reporting
ø = ALS is not NATA accredited for these tests.
~ = Indicates an estimated value.
Key :
Benzo(a)pyrene Toxicity Equivalent Quotient (TEQ) is the sum total of the concentration of the eight carcinogenic PAHs multiplied by their Toxicity Equivalence Factor (TEF) relative to Benzo(a)pyrene. TEF values
are provided in brackets as follows: Benz(a)anthracene (0.1), Chrysene (0.01), Benzo(b+j) & Benzo(k)fluoranthene (0.1), Benzo(a)pyrene (1.0), Indeno(1.2.3.cd)pyrene (0.1), Dibenz(a.h)anthracene (1.0),
Benzo(g.h.i)perylene (0.01). Less than LOR results for 'TEQ Zero' are treated as zero.
l
A
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:Client
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EMERGE ASSOCIATES
Analytical Results
----------------GWQA18Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------08-Sep-2017 00:00Client sampling date / time
--------------------------------ES1722611-001UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EA015: Total Dissolved Solids dried at 180 ± 5 °C
135 ---- ---- ---- ----mg/L10----Total Dissolved Solids @180°C
ED037P: Alkalinity by PC Titrator
<1Hydroxide Alkalinity as CaCO3 ---- ---- ---- ----mg/L1DMO-210-001
<1Carbonate Alkalinity as CaCO3 ---- ---- ---- ----mg/L13812-32-6
21Bicarbonate Alkalinity as CaCO3 ---- ---- ---- ----mg/L171-52-3
21 ---- ---- ---- ----mg/L1----Total Alkalinity as CaCO3
ED045G: Chloride by Discrete Analyser
52Chloride ---- ---- ---- ----mg/L116887-00-6
ED093F: Dissolved Major Cations
6Calcium ---- ---- ---- ----mg/L17440-70-2
5Magnesium ---- ---- ---- ----mg/L17439-95-4
34Sodium ---- ---- ---- ----mg/L17440-23-5
3Potassium ---- ---- ---- ----mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS
0.05Aluminium ---- ---- ---- ----mg/L0.017429-90-5
<0.001Arsenic ---- ---- ---- ----mg/L0.0017440-38-2
<0.0001Cadmium ---- ---- ---- ----mg/L0.00017440-43-9
<0.001Chromium ---- ---- ---- ----mg/L0.0017440-47-3
<0.001Copper ---- ---- ---- ----mg/L0.0017440-50-8
<0.001Nickel ---- ---- ---- ----mg/L0.0017440-02-0
<0.001Lead ---- ---- ---- ----mg/L0.0017439-92-1
<0.005Zinc ---- ---- ---- ----mg/L0.0057440-66-6
0.006Manganese ---- ---- ---- ----mg/L0.0017439-96-5
<0.01Selenium ---- ---- ---- ----mg/L0.017782-49-2
EG020T: Total Metals by ICP-MS
0.44Iron ---- ---- ---- ----mg/L0.057439-89-6
EG035F: Dissolved Mercury by FIMS
<0.0001Mercury ---- ---- ---- ----mg/L0.00017439-97-6
EK055G: Ammonia as N by Discrete Analyser
0.06Ammonia as N ---- ---- ---- ----mg/L0.017664-41-7
EK057G: Nitrite as N by Discrete Analyser
<0.01Nitrite as N ---- ---- ---- ----mg/L0.0114797-65-0
EK058G: Nitrate as N by Discrete Analyser
0.12Nitrate as N ---- ---- ---- ----mg/L0.0114797-55-8
A
---------------
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:Client
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EMERGE ASSOCIATES
Analytical Results
----------------GWQA18Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------08-Sep-2017 00:00Client sampling date / time
--------------------------------ES1722611-001UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser
0.12 ---- ---- ---- ----mg/L0.01----Nitrite + Nitrate as N
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser
0.1 ---- ---- ---- ----mg/L0.1----Total Kjeldahl Nitrogen as N
EK062G: Total Nitrogen as N (TKN + NOx) by Discrete Analyser
0.2^ ---- ---- ---- ----mg/L0.1----Total Nitrogen as N
EK067G: Total Phosphorus as P by Discrete Analyser
0.02 ---- ---- ---- ----mg/L0.01----Total Phosphorus as P
EP005: Total Organic Carbon (TOC)
1 ---- ---- ---- ----mg/L1----Total Organic Carbon
EP026SP: Chemical Oxygen Demand (Spectrophotometric)
<10 ---- ---- ---- ----mg/L10----Chemical Oxygen Demand
EP066: Polychlorinated Biphenyls (PCB)
<1 ---- ---- ---- ----µg/L1----Total Polychlorinated biphenyls
EP068A: Organochlorine Pesticides (OC)
<0.5alpha-BHC ---- ---- ---- ----µg/L0.5319-84-6
<0.5Hexachlorobenzene (HCB) ---- ---- ---- ----µg/L0.5118-74-1
<0.5beta-BHC ---- ---- ---- ----µg/L0.5319-85-7
<0.5gamma-BHC ---- ---- ---- ----µg/L0.558-89-9
<0.5delta-BHC ---- ---- ---- ----µg/L0.5319-86-8
<0.5Heptachlor ---- ---- ---- ----µg/L0.576-44-8
<0.5Aldrin ---- ---- ---- ----µg/L0.5309-00-2
<0.5Heptachlor epoxide ---- ---- ---- ----µg/L0.51024-57-3
<0.5trans-Chlordane ---- ---- ---- ----µg/L0.55103-74-2
<0.5alpha-Endosulfan ---- ---- ---- ----µg/L0.5959-98-8
<0.5cis-Chlordane ---- ---- ---- ----µg/L0.55103-71-9
<0.5Dieldrin ---- ---- ---- ----µg/L0.560-57-1
<0.54.4`-DDE ---- ---- ---- ----µg/L0.572-55-9
<0.5Endrin ---- ---- ---- ----µg/L0.572-20-8
<0.5beta-Endosulfan ---- ---- ---- ----µg/L0.533213-65-9
<0.54.4`-DDD ---- ---- ---- ----µg/L0.572-54-8
<0.5Endrin aldehyde ---- ---- ---- ----µg/L0.57421-93-4
<0.5Endosulfan sulfate ---- ---- ---- ----µg/L0.51031-07-8
<2.04.4`-DDT ---- ---- ---- ----µg/L2.050-29-3
<0.5Endrin ketone ---- ---- ---- ----µg/L0.553494-70-5
A
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:Client
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EMERGE ASSOCIATES
Analytical Results
----------------GWQA18Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------08-Sep-2017 00:00Client sampling date / time
--------------------------------ES1722611-001UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EP068A: Organochlorine Pesticides (OC) - Continued
<2.0Methoxychlor ---- ---- ---- ----µg/L2.072-43-5
<0.5^ ---- ---- ---- ----µg/L0.5----Total Chlordane (sum)
<0.5^ Sum of DDD + DDE + DDT ---- ---- ---- ----µg/L0.572-54-8/72-55-9/5
0-2
<0.5^ Sum of Aldrin + Dieldrin ---- ---- ---- ----µg/L0.5309-00-2/60-57-1
EP075(SIM)A: Phenolic Compounds
<1.0Phenol ---- ---- ---- ----µg/L1.0108-95-2
<1.02-Chlorophenol ---- ---- ---- ----µg/L1.095-57-8
<1.02-Methylphenol ---- ---- ---- ----µg/L1.095-48-7
<2.03- & 4-Methylphenol ---- ---- ---- ----µg/L2.01319-77-3
<1.02-Nitrophenol ---- ---- ---- ----µg/L1.088-75-5
<1.02.4-Dimethylphenol ---- ---- ---- ----µg/L1.0105-67-9
<1.02.4-Dichlorophenol ---- ---- ---- ----µg/L1.0120-83-2
<1.02.6-Dichlorophenol ---- ---- ---- ----µg/L1.087-65-0
<1.04-Chloro-3-methylphenol ---- ---- ---- ----µg/L1.059-50-7
<1.02.4.6-Trichlorophenol ---- ---- ---- ----µg/L1.088-06-2
<1.02.4.5-Trichlorophenol ---- ---- ---- ----µg/L1.095-95-4
<2.0Pentachlorophenol ---- ---- ---- ----µg/L2.087-86-5
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
<1.0Naphthalene ---- ---- ---- ----µg/L1.091-20-3
<1.0Acenaphthylene ---- ---- ---- ----µg/L1.0208-96-8
<1.0Acenaphthene ---- ---- ---- ----µg/L1.083-32-9
<1.0Fluorene ---- ---- ---- ----µg/L1.086-73-7
<1.0Phenanthrene ---- ---- ---- ----µg/L1.085-01-8
<1.0Anthracene ---- ---- ---- ----µg/L1.0120-12-7
<1.0Fluoranthene ---- ---- ---- ----µg/L1.0206-44-0
<1.0Pyrene ---- ---- ---- ----µg/L1.0129-00-0
<1.0Benz(a)anthracene ---- ---- ---- ----µg/L1.056-55-3
<1.0Chrysene ---- ---- ---- ----µg/L1.0218-01-9
<1.0Benzo(b+j)fluoranthene ---- ---- ---- ----µg/L1.0205-99-2 205-82-3
<1.0Benzo(k)fluoranthene ---- ---- ---- ----µg/L1.0207-08-9
<0.5Benzo(a)pyrene ---- ---- ---- ----µg/L0.550-32-8
<1.0Indeno(1.2.3.cd)pyrene ---- ---- ---- ----µg/L1.0193-39-5
<1.0Dibenz(a.h)anthracene ---- ---- ---- ----µg/L1.053-70-3
<1.0Benzo(g.h.i)perylene ---- ---- ---- ----µg/L1.0191-24-2
A
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EMERGE ASSOCIATES
Analytical Results
----------------GWQA18Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------08-Sep-2017 00:00Client sampling date / time
--------------------------------ES1722611-001UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued
<0.5^ ---- ---- ---- ----µg/L0.5----Sum of polycyclic aromatic hydrocarbons
<0.5^ ---- ---- ---- ----µg/L0.5----Benzo(a)pyrene TEQ (zero)
EP080/071: Total Petroleum Hydrocarbons
<20 ---- ---- ---- ----µg/L20----C6 - C9 Fraction
<50 ---- ---- ---- ----µg/L50----C10 - C14 Fraction
<100 ---- ---- ---- ----µg/L100----C15 - C28 Fraction
<50 ---- ---- ---- ----µg/L50----C29 - C36 Fraction
<50^ ---- ---- ---- ----µg/L50----C10 - C36 Fraction (sum)
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
<20C6 - C10 Fraction ---- ---- ---- ----µg/L20C6_C10
<20^ C6 - C10 Fraction minus BTEX
(F1)
---- ---- ---- ----µg/L20C6_C10-BTEX
<100 ---- ---- ---- ----µg/L100---->C10 - C16 Fraction
<100 ---- ---- ---- ----µg/L100---->C16 - C34 Fraction
<100 ---- ---- ---- ----µg/L100---->C34 - C40 Fraction
<100^ ---- ---- ---- ----µg/L100---->C10 - C40 Fraction (sum)
<100^ ---- ---- ---- ----µg/L100---->C10 - C16 Fraction minus Naphthalene
(F2)
EP080: BTEXN
<1Benzene ---- ---- ---- ----µg/L171-43-2
<2Toluene ---- ---- ---- ----µg/L2108-88-3
<2Ethylbenzene ---- ---- ---- ----µg/L2100-41-4
<2meta- & para-Xylene ---- ---- ---- ----µg/L2108-38-3 106-42-3
<2ortho-Xylene ---- ---- ---- ----µg/L295-47-6
<2^ Total Xylenes ---- ---- ---- ----µg/L21330-20-7
<1^ ---- ---- ---- ----µg/L1----Sum of BTEX
<5Naphthalene ---- ---- ---- ----µg/L591-20-3
EP066S: PCB Surrogate
74.2Decachlorobiphenyl ---- ---- ---- ----%12051-24-3
EP068S: Organochlorine Pesticide Surrogate
79.3Dibromo-DDE ---- ---- ---- ----%0.521655-73-2
EP068T: Organophosphorus Pesticide Surrogate
81.7DEF ---- ---- ---- ----%0.578-48-8
EP075(SIM)S: Phenolic Compound Surrogates
A
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Analytical Results
----------------GWQA18Client sample IDSub-Matrix: WATER
(Matrix: WATER)
----------------08-Sep-2017 00:00Client sampling date / time
--------------------------------ES1722611-001UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EP075(SIM)S: Phenolic Compound Surrogates - Continued
25.2Phenol-d6 ---- ---- ---- ----%1.013127-88-3
49.62-Chlorophenol-D4 ---- ---- ---- ----%1.093951-73-6
58.62.4.6-Tribromophenol ---- ---- ---- ----%1.0118-79-6
EP075(SIM)T: PAH Surrogates
68.52-Fluorobiphenyl ---- ---- ---- ----%1.0321-60-8
81.2Anthracene-d10 ---- ---- ---- ----%1.01719-06-8
60.44-Terphenyl-d14 ---- ---- ---- ----%1.01718-51-0
EP080S: TPH(V)/BTEX Surrogates
90.91.2-Dichloroethane-D4 ---- ---- ---- ----%217060-07-0
98.6Toluene-D8 ---- ---- ---- ----%22037-26-5
1074-Bromofluorobenzene ---- ---- ---- ----%2460-00-4
A
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EMERGE ASSOCIATES
Surrogate Control Limits
Recovery Limits (%)Sub-Matrix: WATER
Compound CAS Number Low High
EP066S: PCB Surrogate
Decachlorobiphenyl 2051-24-3 29 129
EP068S: Organochlorine Pesticide Surrogate
Dibromo-DDE 21655-73-2 30 120
EP068T: Organophosphorus Pesticide Surrogate
DEF 78-48-8 27 129
EP075(SIM)S: Phenolic Compound Surrogates
Phenol-d6 13127-88-3 10 44
2-Chlorophenol-D4 93951-73-6 14 94
2.4.6-Tribromophenol 118-79-6 17 125
EP075(SIM)T: PAH Surrogates
2-Fluorobiphenyl 321-60-8 20 104
Anthracene-d10 1719-06-8 27 113
4-Terphenyl-d14 1718-51-0 32 112
EP080S: TPH(V)/BTEX Surrogates
1.2-Dichloroethane-D4 17060-07-0 71 137
Toluene-D8 2037-26-5 79 131
4-Bromofluorobenzene 460-00-4 70 128
A
False
3 3.00True
Environmental
QUALITY CONTROL REPORTWork Order : ES1722611 Page : 1 of 9
:: LaboratoryClient Environmental Division SydneyEMERGE ASSOCIATES
:Contact MR SIMON GREGG :Contact Luke Jones
:Address SUITE 4, 26 RAILWAY ROAD
SUBIACO WESTERN AUSTRALIA 6008
Address : 277-289 Woodpark Road Smithfield NSW Australia 2164
::Telephone +61 08 9380 4988 08 9209 7631:Telephone
:Project EP15-050(05) SAMR Monitoring-Davis Road Date Samples Received : 08-Sep-2017
:Order number ---- Date Analysis Commenced : 08-Sep-2017
:C-O-C number ---- Issue Date : 15-Sep-2017
Sampler : MITCHELL RITIKIS
Site : ----
Quote number : EPBQ-009-16
No. of samples received 1:
No. of samples analysed 1:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limits
l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits
l Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Ankit Joshi Inorganic Chemist Sydney Inorganics, Smithfield, NSW
Edwandy Fadjar Organic Coordinator Sydney Organics, Smithfield, NSW
Raymond Commodore Instrument Chemist Sydney Inorganics, Smithfield, NSW
R I G H T S O L U T I O N S | R I G H T P A R T N E R
A NATA
V Accreditation No. 825
Accredited for compliance with 150/IEC 17025 - Testing
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General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
RPD = Relative Percentage Difference
# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) Report
The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges
for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:
No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QC Lot: 1112946)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 247 264 6.65 0% - 20%Anonymous ES1722529-001
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 64 70 8.96 No LimitAnonymous ES1722561-002
ED037P: Alkalinity by PC Titrator (QC Lot: 1108758)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitGWQA18 ES1722611-001
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 21 20 0.00 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 21 20 0.00 0% - 20%
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous ES1722826-002
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 84 81 2.81 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 84 81 2.81 0% - 20%
ED045G: Chloride by Discrete Analyser (QC Lot: 1103142)
ED045G: Chloride 16887-00-6 1 mg/L 52 52 0.00 0% - 20%GWQA18 ES1722611-001
ED093F: Dissolved Major Cations (QC Lot: 1107173)
ED093F: Calcium 7440-70-2 1 mg/L 772 690 11.3 0% - 20%Anonymous ES1722610-001
ED093F: Magnesium 7439-95-4 1 mg/L 656 580 12.2 0% - 20%
ED093F: Sodium 7440-23-5 1 mg/L 5870 5220 11.7 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 143 128 11.1 0% - 20%
ED093F: Calcium 7440-70-2 1 mg/L 89 104 15.6 0% - 20%Anonymous ES1722656-008
ED093F: Magnesium 7439-95-4 1 mg/L 46 54 15.4 0% - 20%
ED093F: Sodium 7440-23-5 1 mg/L 19 21 10.6 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 15 16 9.14 0% - 50%
EG020F: Dissolved Metals by ICP-MS (QC Lot: 1107172)
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous ES1722624-004
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EG020F: Dissolved Metals by ICP-MS (QC Lot: 1107172) - continued
EG020A-F: Arsenic 7440-38-2 0.001 mg/L 0.002 0.002 0.00 No LimitAnonymous ES1722624-004
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.003 0.004 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.018 0.023 25.4 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L 0.07 0.08 18.9 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 0.01 0.00 No Limit
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L 0.0002 0.0002 0.00 No LimitAnonymous ES1722610-001
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 7.74 6.92 11.1 0% - 20%
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.045 0.044 2.75 0% - 20%
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.063 0.057 10.1 0% - 50%
EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L 0.08 0.07 17.4 No Limit
EG020T: Total Metals by ICP-MS (QC Lot: 1107980)
EG020A-T: Iron 7439-89-6 0.05 mg/L 5.41 5.32 1.51 0% - 20%Anonymous ES1722684-004
EG020A-T: Iron 7439-89-6 0.05 mg/L 0.61 0.58 4.62 0% - 50%Anonymous ES1722658-001
EG035F: Dissolved Mercury by FIMS (QC Lot: 1107171)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous ES1722541-001
EK055G: Ammonia as N by Discrete Analyser (QC Lot: 1106739)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 39.4 39.8 0.926 0% - 20%Anonymous ES1722552-001
EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EW1703608-002
EK057G: Nitrite as N by Discrete Analyser (QC Lot: 1103141)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous ES1722607-002
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QC Lot: 1106738)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 0.02 0.04 34.0 No LimitAnonymous ES1722706-004
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 0.03 0.03 0.00 No LimitAnonymous ES1722552-001
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QC Lot: 1106727)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 50.2 51.0 1.58 0% - 20%Anonymous ES1722552-001
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 13.2 11.7 12.4 0% - 20%Anonymous ES1722706-002
EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 1106728)
EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.42 0.44 4.65 0% - 20%Anonymous ES1722672-005
EK067G: Total Phosphorus as P ---- 0.01 mg/L 4.57 4.82 5.30 0% - 20%Anonymous ES1722552-001
EP005: Total Organic Carbon (TOC) (QC Lot: 1110637)
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP005: Total Organic Carbon (TOC) (QC Lot: 1110637) - continued
EP005: Total Organic Carbon ---- 1 mg/L 1 1 0.00 No LimitGWQA18 ES1722611-001
EP005: Total Organic Carbon ---- 1 mg/L 4 4 0.00 No LimitAnonymous ES1722780-001
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QC Lot: 1113408)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L 1060 1060 0.00 0% - 20%Anonymous ES1722544-001
EP026SP: Chemical Oxygen Demand ---- 10 mg/L <10 <10 0.00 No LimitGWQA18 ES1722611-001
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 1110490)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitAnonymous EB1718613-001
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitAnonymous ES1722626-004
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 1110490)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitAnonymous EB1718613-001
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitAnonymous ES1722626-004
EP080: BTEXN (QC Lot: 1110490)
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitAnonymous EB1718613-001
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitAnonymous ES1722626-004
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
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Method Blank (MB) and Laboratory Control Spike (LCS) Report
The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC
parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target
analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QCLot: 1112946)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 92.12000 mg/L 10987
<10 101293 mg/L 12666
ED037P: Alkalinity by PC Titrator (QCLot: 1108758)
ED037-P: Total Alkalinity as CaCO3 ---- ---- mg/L ---- 97.7200 mg/L 11181
ED045G: Chloride by Discrete Analyser (QCLot: 1103142)
ED045G: Chloride 16887-00-6 1 mg/L <1 11010 mg/L 12781
<1 96.81000 mg/L 12781
ED093F: Dissolved Major Cations (QCLot: 1107173)
ED093F: Calcium 7440-70-2 1 mg/L <1 98.450 mg/L 11480
ED093F: Magnesium 7439-95-4 1 mg/L <1 91.750 mg/L 11690
ED093F: Sodium 7440-23-5 1 mg/L <1 93.750 mg/L 12082
ED093F: Potassium 7440-09-7 1 mg/L <1 99.450 mg/L 11385
EG020F: Dissolved Metals by ICP-MS (QCLot: 1107172)
EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 93.50.5 mg/L 11680
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 98.80.1 mg/L 11485
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 91.20.1 mg/L 11084
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 85.30.1 mg/L 11185
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 87.30.1 mg/L 11181
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 98.50.1 mg/L 11183
EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 86.70.1 mg/L 11082
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 90.10.1 mg/L 11282
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 99.60.1 mg/L 11585
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 95.50.1 mg/L 11781
EG020T: Total Metals by ICP-MS (QCLot: 1107980)
EG020A-T: Iron 7439-89-6 0.05 mg/L <0.05 96.70.5 mg/L 11785
EG035F: Dissolved Mercury by FIMS (QCLot: 1107171)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 89.80.01 mg/L 10583
EK055G: Ammonia as N by Discrete Analyser (QCLot: 1106739)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 97.41 mg/L 11490
EK057G: Nitrite as N by Discrete Analyser (QCLot: 1103141)
EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 1040.5 mg/L 11482
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 1106738)
EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 1020.5 mg/L 11391
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 1106727)
EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 83.610 mg/L 10169
<0.1 84.91 mg/L 11870
<0.1 1065 mg/L 11874
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 1106728)
EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 94.04.42 mg/L 10171
<0.01 93.00.442 mg/L 10872
<0.01 1161 mg/L 11878
EP005: Total Organic Carbon (TOC) (QCLot: 1110637)
EP005: Total Organic Carbon ---- 1 mg/L <1 89.910 mg/L 12072
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 1113408)
EP026SP: Chemical Oxygen Demand ---- 10 mg/L <10 98.450 mg/L 11282
<10 96.0500 mg/L 11383
EP066: Polychlorinated Biphenyls (PCB) (QCLot: 1104504)
EP066: Total Polychlorinated biphenyls ---- 1 µg/L <1 10410 µg/L 10762
EP068A: Organochlorine Pesticides (OC) (QCLot: 1104501)
EP068: alpha-BHC 319-84-6 0.5 µg/L <0.5 84.25 µg/L 11365
EP068: Hexachlorobenzene (HCB) 118-74-1 0.5 µg/L <0.5 80.55 µg/L 11454
EP068: beta-BHC 319-85-7 0.5 µg/L <0.5 83.45 µg/L 11769
EP068: gamma-BHC 58-89-9 0.5 µg/L <0.5 85.05 µg/L 11270
EP068: delta-BHC 319-86-8 0.5 µg/L <0.5 85.55 µg/L 11767
EP068: Heptachlor 76-44-8 0.5 µg/L <0.5 77.45 µg/L 11363
EP068: Aldrin 309-00-2 0.5 µg/L <0.5 81.45 µg/L 11666
EP068: Heptachlor epoxide 1024-57-3 0.5 µg/L <0.5 80.95 µg/L 12359
EP068: trans-Chlordane 5103-74-2 0.5 µg/L <0.5 80.95 µg/L 12161
EP068: alpha-Endosulfan 959-98-8 0.5 µg/L <0.5 82.55 µg/L 12066
EP068: cis-Chlordane 5103-71-9 0.5 µg/L <0.5 82.65 µg/L 12064
EP068: Dieldrin 60-57-1 0.5 µg/L <0.5 81.55 µg/L 12066
EP068: 4.4`-DDE 72-55-9 0.5 µg/L <0.5 79.05 µg/L 11967
EP068: Endrin 72-20-8 0.5 µg/L <0.5 77.65 µg/L 12266
EP068: beta-Endosulfan 33213-65-9 0.5 µg/L <0.5 84.65 µg/L 11971
EP068: 4.4`-DDD 72-54-8 0.5 µg/L <0.5 84.35 µg/L 12272
EP068: Endrin aldehyde 7421-93-4 0.5 µg/L <0.5 81.75 µg/L 11664
EP068: Endosulfan sulfate 1031-07-8 0.5 µg/L <0.5 84.75 µg/L 12660
EP068: 4.4`-DDT 50-29-3 2 µg/L <2.0 1075 µg/L 12260
EP068: Endrin ketone 53494-70-5 0.5 µg/L <0.5 84.55 µg/L 12462
EP068: Methoxychlor 72-43-5 2 µg/L <2.0 77.55 µg/L 12753
EP075(SIM)A: Phenolic Compounds (QCLot: 1104502)
EP075(SIM): Phenol 108-95-2 1 µg/L <1.0 38.75 µg/L 6225
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP075(SIM)A: Phenolic Compounds (QCLot: 1104502) - continued
EP075(SIM): 2-Chlorophenol 95-57-8 1 µg/L <1.0 71.85 µg/L 9052
EP075(SIM): 2-Methylphenol 95-48-7 1 µg/L <1.0 70.15 µg/L 9151
EP075(SIM): 3- & 4-Methylphenol 1319-77-3 2 µg/L <2.0 60.310 µg/L 8844
EP075(SIM): 2-Nitrophenol 88-75-5 1 µg/L <1.0 63.25 µg/L 10048
EP075(SIM): 2.4-Dimethylphenol 105-67-9 1 µg/L <1.0 66.95 µg/L 9949
EP075(SIM): 2.4-Dichlorophenol 120-83-2 1 µg/L <1.0 68.45 µg/L 10553
EP075(SIM): 2.6-Dichlorophenol 87-65-0 1 µg/L <1.0 76.45 µg/L 10557
EP075(SIM): 4-Chloro-3-methylphenol 59-50-7 1 µg/L <1.0 82.45 µg/L 9953
EP075(SIM): 2.4.6-Trichlorophenol 88-06-2 1 µg/L <1.0 80.75 µg/L 10650
EP075(SIM): 2.4.5-Trichlorophenol 95-95-4 1 µg/L <1.0 72.35 µg/L 10551
EP075(SIM): Pentachlorophenol 87-86-5 2 µg/L <2.0 30.910 µg/L 9510
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 1104502)
EP075(SIM): Naphthalene 91-20-3 1 µg/L <1.0 75.65 µg/L 9450
EP075(SIM): Acenaphthylene 208-96-8 1 µg/L <1.0 86.55 µg/L 11464
EP075(SIM): Acenaphthene 83-32-9 1 µg/L <1.0 85.35 µg/L 11362
EP075(SIM): Fluorene 86-73-7 1 µg/L <1.0 85.25 µg/L 11564
EP075(SIM): Phenanthrene 85-01-8 1 µg/L <1.0 74.25 µg/L 11663
EP075(SIM): Anthracene 120-12-7 1 µg/L <1.0 78.45 µg/L 11664
EP075(SIM): Fluoranthene 206-44-0 1 µg/L <1.0 77.55 µg/L 11864
EP075(SIM): Pyrene 129-00-0 1 µg/L <1.0 80.55 µg/L 11863
EP075(SIM): Benz(a)anthracene 56-55-3 1 µg/L <1.0 76.55 µg/L 11764
EP075(SIM): Chrysene 218-01-9 1 µg/L <1.0 76.25 µg/L 11663
EP075(SIM): Benzo(b+j)fluoranthene 205-99-2
205-82-3
1 µg/L <1.0 74.65 µg/L 11962
EP075(SIM): Benzo(k)fluoranthene 207-08-9 1 µg/L <1.0 86.25 µg/L 11563
EP075(SIM): Benzo(a)pyrene 50-32-8 0.5 µg/L <0.5 69.45 µg/L 11763
EP075(SIM): Indeno(1.2.3.cd)pyrene 193-39-5 1 µg/L <1.0 70.75 µg/L 11860
EP075(SIM): Dibenz(a.h)anthracene 53-70-3 1 µg/L <1.0 71.25 µg/L 11761
EP075(SIM): Benzo(g.h.i)perylene 191-24-2 1 µg/L <1.0 69.85 µg/L 11859
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1104503)
EP071: C10 - C14 Fraction ---- 50 µg/L <50 99.62000 µg/L 11676
EP071: C15 - C28 Fraction ---- 100 µg/L <100 93.63000 µg/L 10983
EP071: C29 - C36 Fraction ---- 50 µg/L <50 88.72000 µg/L 11375
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1110490)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 89.0260 µg/L 12775
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 1104503)
EP071: >C10 - C16 Fraction ---- 100 µg/L <100 88.72500 µg/L 11476
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 90.53500 µg/L 11181
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 1104503) - continued
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 96.11500 µg/L 11977
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 1110490)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 91.0310 µg/L 12775
EP080: BTEXN (QCLot: 1110490)
EP080: Benzene 71-43-2 1 µg/L <1 89.110 µg/L 12270
EP080: Toluene 108-88-3 2 µg/L <2 98.110 µg/L 12369
EP080: Ethylbenzene 100-41-4 2 µg/L <2 85.310 µg/L 12070
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 93.610 µg/L 12169
EP080: ortho-Xylene 95-47-6 2 µg/L <2 97.410 µg/L 12272
EP080: Naphthalene 91-20-3 5 µg/L <5 10210 µg/L 12070
Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on
analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
ED045G: Chloride by Discrete Analyser (QCLot: 1103142)
GWQA18 ES1722611-001 16887-00-6ED045G: Chloride 129250 mg/L 13070
EG020F: Dissolved Metals by ICP-MS (QCLot: 1107172)
Anonymous ES1722541-002 7440-38-2EG020A-F: Arsenic 92.11 mg/L 13070
7440-43-9EG020A-F: Cadmium 91.60.25 mg/L 13070
7440-47-3EG020A-F: Chromium 91.21 mg/L 13070
7440-50-8EG020A-F: Copper 79.51 mg/L 13070
7439-92-1EG020A-F: Lead 89.91 mg/L 13070
7439-96-5EG020A-F: Manganese 90.71 mg/L 13070
7440-02-0EG020A-F: Nickel 90.51 mg/L 13070
7440-66-6EG020A-F: Zinc 92.01 mg/L 13070
EG035F: Dissolved Mercury by FIMS (QCLot: 1107171)
Anonymous ES1722529-004 7439-97-6EG035F: Mercury 73.60.01 mg/L 13070
EK055G: Ammonia as N by Discrete Analyser (QCLot: 1106739)
Anonymous ES1722552-001 7664-41-7EK055G: Ammonia as N # Not
Determined
1 mg/L 13070
EK057G: Nitrite as N by Discrete Analyser (QCLot: 1103141)
Anonymous ES1722607-002 14797-65-0EK057G: Nitrite as N 1170.5 mg/L 13070
A
9 of 9:Page
Work Order :
:Client
ES1722611
EMERGE ASSOCIATES
EP15-050(05) SAMR Monitoring-Davis Road:Project
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 1106738)
Anonymous ES1722552-001 ----EK059G: Nitrite + Nitrate as N 1050.5 mg/L 13070
EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 1106727)
Anonymous ES1722552-002 ----EK061G: Total Kjeldahl Nitrogen as N 73.25 mg/L 13070
EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 1106728)
Anonymous ES1722552-002 ----EK067G: Total Phosphorus as P 82.31 mg/L 13070
EP005: Total Organic Carbon (TOC) (QCLot: 1110637)
Anonymous ES1722708-004 ----EP005: Total Organic Carbon 87.0100 mg/L 13070
EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 1113408)
Anonymous ES1722544-001 ----EP026SP: Chemical Oxygen Demand 1111164 mg/L 13070
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1110490)
Anonymous EB1718613-001 ----EP080: C6 - C9 Fraction 102325 µg/L 13070
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 1110490)
Anonymous EB1718613-001 C6_C10EP080: C6 - C10 Fraction 102375 µg/L 13070
EP080: BTEXN (QCLot: 1110490)
Anonymous EB1718613-001 71-43-2EP080: Benzene 89.425 µg/L 13070
108-88-3EP080: Toluene 10825 µg/L 13070
100-41-4EP080: Ethylbenzene 92.925 µg/L 13070
108-38-3
106-42-3
EP080: meta- & para-Xylene 93.525 µg/L 13070
95-47-6EP080: ortho-Xylene 96.325 µg/L 13070
91-20-3EP080: Naphthalene 10525 µg/L 13070
A
True
Environmental
QA/QC Compliance Assessment to assist with Quality ReviewWork Order : ES1722611 Page : 1 of 9
:: LaboratoryClient Environmental Division SydneyEMERGE ASSOCIATES
:Contact MR SIMON GREGG Telephone : 08 9209 7631
:Project EP15-050(05) SAMR Monitoring-Davis Road Date Samples Received : 08-Sep-2017
Site : ---- Issue Date : 15-Sep-2017
MITCHELL RITIKIS:Sampler No. of samples received : 1
:Order number ---- No. of samples analysed : 1
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated
reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this
report contribute to the overall DQO assessment and reporting for guideline compliance.
Brief method summaries and references are also provided to assist in traceability.
Summary of Outliers
Outliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.
l NO Duplicate outliers occur.
l NO Laboratory Control outliers occur.
l Matrix Spike outliers exist - please see following pages for full details.
l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliance
l NO Analysis Holding Time Outliers exist.
Outliers : Frequency of Quality Control Samples
l Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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