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APICAL : Polyimide FilmCONTENTS
DescriptionAPICAL AV
GradePhysical PropertiesTensile Stress Strain CurvesStress Relaxation and CreepIsotropy of Tensile ModulusThermal PropertiesThermal AgingDimensional StabilityElectrical PropertiesChemical PropertiesAlkaline ResistanceAdhesion PropertiesAPICAL AF
GradePhysical PropertiesThermal PropertiesElectrical PropertiesChemical PropertiesAPICAL NP
GradePhysical PropertiesIsotropy of Tensile ModulusThermal PropertiesDimensional Stability - 1 -Dimensional Stability - 2 -Electrical PropertiesChemical PropertiesAlkaline ResistanceCOMPARISON DATA
APICAL DIVISION KANEKA TEXAS CORPORATION
6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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United States
APICAL DIVISION
KANEKA TEXAS CORPORATION
6161 Underwood Rd.Pasadena, TX 77507U.S.A.800-222-8128FAX: 281-291-2110
Europe
KANEKA BELGIUM N.V.
Boulevard Du Triomphe 1731160 Brussels Belgium32-2-672-0190FAX: 32-2-675 22 68
Japan
KANEKA CORPORATION
1-12-32, Akasaka, Minato-kuTokyo 107 Japan81-3-5574-8101FAX: 81-3-5574-8401
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APICAL : Polyimide FilmDESCRIPTIONAPICAL polyimide film possesses an excellent balance of physical, thermal, electrical and chemi-cal properties over a wide range of temperature (-269°C [-452°F] to 400°C [752°F]). More precise thickness control, superior web flatness, plus improved adhesion and excellent dimen-sional stability are standard features with Apical polyimide films. Applications for APICAL poly-imide film include flexible printed circuits (FPC),tape automated bonding (TAB), motor generator insulation, wire and cable insulation, bar code label and pressure sensitive tape. APICAL is produced by the polycondensation reaction between an aromatic dianhydride and an aromatic diamine.APICAL DIVISION KANEKA TEXAS CORPORATION PRODUCES THREE TYPES OF APICAL FILM.
APICAL AVAPICAL AV has been sucessfully used in appli-cations where a wide operating temperature (-269°C to 400°C) combined with excellent physical, electrical and chemical properties is
-ture is as follows.
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APICAL AFAPICAL AF is a FEP fluoropolymer resin coated/laminated polyimide film developed for high temperature applications where heat sealabil-ity or improved moisture and chemical resistance is required. APICAL AF is available in a variety of constructions. (see Table 7)
APICAL NPAPICAL NP is developed by using state of the art technology designed specifically for applications where superior dimensional stability is essential. The superior dimensional stability characteristics of Apical NP make it particularly well suited for use in FPC and TAB applications.
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APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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®APICAL : Polyimide FilmTABLE 1 APICAL AV GRADES
PRODUCT NOMINAL THICKNESS APPROXIMATE AREA FACTOR
50AV 0.5 12.5 56 27575AV 0.75 19.0 36 175100AV 1.0 25.0 28 138200AV 2.0 50.0 14 69300AV 3.0 75.0 9 46500AV 5.0 125.0 6 27100AVY* 1.0 25.0 28 138
2 2
APICAL DIVISION KANEKA TEXAS CORPORATION 800-222-8128
DISCLAIMER:
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APICAL : Polyimide FilmTable 2 PHYSICAL PROPERTIES OF APICAL AV(APICAL 100AV 1MIL)
PROPERTY UNIT TYPICAL VALUE TEST METHOD -195°C 23°C 200°CUltimate Tensile Strength (MD) psi 48,000 35,000 20,000 ASTM D-882 Mpa 330 241 138Yield Point at 3% Elongation (MD) psi 10,000 6,000 ASTM D-882 Mpa 69 41Stress at 5% Elongation (MD) psi 13,000 8,000 ASTM D-882 Mpa 90 55Ultimate Elongation % 20 95 103 ASTM D-882Tensile Modulus psi 610,000 460,000 260,000 ASTM D-882 Gpa 4.2 3.2 1.8Folding Endurance cycles >100,000 ASTM D-2176 Tear Strength Propagating g 7 ASTM-1938(Single tear) lbs 0.02Tear Strength Initial g 520 ASTM D-1004(Graves) lbs 1.15Density g/cm 1.42 ASTM D-1505Coefficient of Friction [Kinetic] - 0.40 ASTM D-1894(Film to Film)Coefficient of Friction [Static] - 0.50 ASTM D-1894(Film to Film)
APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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®APICAL : Polyimide Film
TENSILE STRESS STRAIN CURVES OF
APICAL AV
The usual values of tensile strength, tensile
modulus, and ultimate elongation at various
temperatures appear in the typical stress strain
curves shown in Figure 1. Such properties as
tensile strength and modulus decrease at higher
temperature, while elongation reaches a maxi-
mum value at about 200°C (392°F).
Other factors, such as humidity and film thickness
have only a negligible effect on the shape of the
stress strain curves.
120100806040
Strain (%)
200
0
50
100
150
Stress
(MPa)
200
250
300
FIGURE 1
TENSILE STRESS STRAIN CURVES
(APICAL 100AV 1MIL)
APICAL DIVISION KANEKA TEXAS CORPORATION
6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110
www.kanekatexas.com
DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or
warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion
described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or
warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume
that toxicity data or safety measures are fully indicated or that other measures may not be required.
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Stress relaxation is shown in Figure 2 and Creep is shown in Figure 3. Stress relaxation and Creep can happen during film processing or in application.
Ratio of Stress(%)
105
100
95
90
850 10 20 30 40 50 60 70
Time (Minutes)
Stress relaxation is observed as the film is strained by elongation.
0.05
0.04
0.03
0.01
0
0.02
0 10 20 30 40 50 60 70
Figure 3 CREEP
(APICAL 100AV 1MIL) INITIAL STRESS 5688psi
Time (Minutes)
Creep is observed as the film is strained by stress.
Strain(%)
Figure 2 STRESS RELAXATION
(APICAL 100AV 1MIL) INITIAL STRAIN 0.3%
APICAL : Polyimide FilmSTRESS RELAXATION AND CREEP OF
APICAL AV
APICAL DIVISION KANEKA TEXAS CORPORATION
6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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APICAL : Polyimide FilmISOTROPY OF TENSILE MODULUS OF
APICAL AV
2.0
0
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Figure 4 ISOTROPY OF TENSILE MODULUS
(APICAL 100AV 1MIL) (UNIT: GPa)
2.0
0
2.0
0
E C W
MD
DD (Left) 4.0 DD (Right)MD
DD (Left) 4.0 DD (Right)MD
DD (Left) 4.0 DD (Right)
TDTDTD
E (East), C (Center), W (West) describe the location on the web.Measurement was done in four directions across the web (Machine direction [MD],Transverse direction [TD] and 2 Diagonal directions [DD]), shown as dots.
®Tensile Modulus of Apical AV is isotropicFigure 4 describes the isotropy of tensile modulus at positions across the web.
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APICAL DIVISION KANEKA TEXAS CORPORATION
6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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ASTM E 794
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®Table 3 THERMAL PROPERTIES OF APICAL AV(APICAL 100AV 1MIL)
PROPERTY UNIT TYPICAL VALUE TEST METHOD
APICAL DIVISION KANEKA TEXAS CORPORATION
DISCLAIMER:
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APICAL : Polyimide Film
THERMAL AGING OF APICAL AVThe life of APICAL polyimide film at high
temperature significantly depends on the environ-
ment. APICAL is degraded by oxygen. Its useful
life in nitrogen is at least an order of magnitude
greater than in air. The weight loss characteristics
of APICAL in air and nitrogen at elevated
temperatures are shown in Figure 5 and the
isothermal weight loss in air at several tempera-
tures is shown in Figure 6.
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Figure 5 WEIGHT LOSS BY USING THERMOGRAVIMETRIC ANALYSIS(APICAL 100AV 1MIL)
Rate of temperature rise in °C was 10 °C/min. (18° F/min.)
Weight loss
%
Nitrogen
Air
-100
-80
-60
-40
-20
-0
200
(392)
0 400
(752)
600
(1112)
800
(1472)
1000
(1832)
Temperature °C (°F)
Figure 6 ISOTHERMAL WEIGHT LOSS AT SEVERAL TEMPERATURES(APICAL 100AV 1MIL)
2 4 6 8 10 12 14 16 18 200-70
-60
-40
-20
-0
-10
-30
-50
Time (Hours)
Weight loss
%
APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110
www.kanekatexas.com
DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or
warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion
described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or
warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume
that toxicity data or safety measures are fully indicated or that other measures may not be required.
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MDDD (Left) 4.0 DD (Right)
MDDD (Left) 4.0 DD (Right)
MDDD (Left) 4.0 DD (Right)
temperatures as indicated in Figure 7, Coefficient
of Thermal Expansion (CTE) is also one of the
important factors for dimensional stability. CTE
of Apical is isotropic. The isotropy of CTE on
APICAL AV is shown in Figure 8.
APICAL : Polyimide Film
DIMENSIONAL STABILITY OF APICAL AVShrinkage is one of the important factors for
dimensional stability. APICAL shows residual
shrinkage after its first exposure to elevated
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Figure 7 RESIDUAL SHRINKAGE VS EXPOSURE TIMEAT SEVERAL TEMPERATURES(APICAL 100AV 1MIL)
0.20
0.18
0.16
0.14
0.12
0.10
0.08
0.06
0.04
0.02
020 40 60 80 100 120 140 160 180 2000
Time (Minutes)
Shrinkage %
2
0
E
TD
2
0
2
0
C W
TDTD
Figure 8 ISOTROPY OF CTE (APICAL 100AV 1MIL)
(UNIT: X10 / °C,TEMPERATURE 100-200°C)
E (East),C (Center),W (West) describes the location on the web.
Measurements were done in four directions across the web (Machine direction [MD],
Transverse direction [TO] and 2 Diagonal directions [DO]), shown as dots.
APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110
www.kanekatexas.com
DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or
warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion
described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or
warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume
that toxicity data or safety measures are fully indicated or that other measures may not be required.
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Dielectric Strength V/mil ASTM D-149 METHOD A 100AV (1mil) 7,800 Type 3 electrodes, 60Hz 200AV (2mil) 5,600 300AV (3mil) 4,600 500AV (5mil) 3,600
Dielectric Constant IPC TM-650 Method 2.5.5.3 100AV (1mil) 3.3 1KHz 3.3 1MHz
Dissipation Factor IPC TM-650 Method 2.5.5.3 100AV (1mil) 0.001 1 KHz 0.005 1MHz
Volume Resistivity ohm-cm ASTM D-257, 500V 100AV (1mil) > 10
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®APICAL : Polyimide FilmTable 4 ELECTRICAL PROPERTIES OF APICAL AV
PROPERTY UNIT TYPICAL VALUE TEST METHOD
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APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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Hygroscopic Coefficient cm/cm/%RH 1.95X10 35°C, 20-80%RHof Expansion
Moisture Absorption % 1.3 23°C, 50%RH 2.9 23°C, immersion 24hrs.
Resistance to Chemicals Tensile properties retained (%) Condition
Chemicals Tensile Elongation Modulus StrengthBenzene 100 85 130 20°C immersion 14daysToluene 100 90 110 20°C immersion 14daysMethanol 100 85 120 20°C immersion 14daysAcetone 95 85 115 20°C immersion 14daysMEK 100 85 115 20°C immersion 14days10% HCI 95 90 115 20°C immersion 14days10% H SO 95 90 120 20°C immersion 14days10% NaOH Degraded Degraded Degraded 20°C immersion 4days5% NaOH 80 75 115 50°C immersion 3min.FeCI 90 70 120 20°C immersion 14daysCuCI 60 55 115 20°C immersion 14daysH OPH = 1 60 20 125 100°C immersion 14daysPH =4 60 30 130 100°C immersion 14daysPH = 7 75 60 120 100°C immersion 14daysPH = 10 20 15 100 100°C immersion 4days
2 4
3
2
2
APICAL : Polyimide FilmTable 5 CHEMICAL PROPERTIES OF APICAL AV(APICAL 100AV 1MIL)
PROPERTY UNIT TYPICAL VALUE TEST METHOD
5
APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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APICAL : Polyimide FilmALKALINE RESISTANCE OF APICAL AVAPICAL AV can be etched by caustic solution as shown in Figure 9 and 10. Figure 9 shows the weight loss of APICAL AV in caustic solution.
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Figure 10 shows the etching rate in caustic solution. (Solvent is a mixture of water and ethanol)weight lossof APICAL AV in caustic solution. Figure 10 shows the etching rate in caustic solution. (Solvent is a mixture of water and ethanol)
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Figure 9 WEIGHT LOSS IN CAUSTIC SOLUTION VS EXPOSURE TIME (APICAL 100AV 1MIL.)
Figure 10 ETCHING RATE IN CAUSTIC SOLUTION (APICAL 100AV 1MIL.)
0 1.0 2.0 3.00
5
10
15
Weight Loss%
Time in caustic solution (Minutes)
0 20 40 60 80 100
1.0
2.0
3.0
Etching rate(%/Min.)
Weight of Ethanol to Water (wt%)
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APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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APICAL : Polyimide Film
Table 6 ADHESION PROPERTIES OF APICAL AV(APICAL 100AV 1MIL)
PROPERTY UNIT TYPICAL VALUE TEST METHOD
APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110
www.kanekatexas.com
DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or
warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion
described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or
warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume
that toxicity data or safety measures are fully indicated or that other measures may not be required.
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Contact angle ° 40 Water, 20°C, 50%RH,1atm
Surface tension dyne/cm 60 ASTM D2578
Peel strength p/i 6.2 Kaneka Method using Kaneka
kg/cm 1.1 proprietary Epoxy adhesive
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®Table 7 GRADE OF APICAL AF
PRODUCT NOMINAL THICKNESS CONSTRUCTION (MIL) APPROXIMATE AREA FACTOR
APICAL DIVISION KANEKA TEXAS CORPORATION
DISCLAIMER:
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®APICAL : Polyimide FilmTable 7 GRADE OF APICAL AF
PRODUCT NOMINAL THICKNESS CONSTRUCTION (MIL) APPROXIMATE AREA FACTOR
2 2
APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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J11A7 0.95 24.1 0.1 0.75 0.1 28 135
P50A10 1.5 38.1 0.0 1.0 0.5 16 81
P77A10 2.4 61.0 0.7 1.0 0.7 15 77
T10A10 1.1 28.1 0.1 1.0 0.0 24 116
T10N10 1.1 27.4 0.1 1.0 0.0 24 117
T11A7 0.95 24 0.1 0.75 0.1 26 128
T11N7 0.9 22.9 0.1 0.7 0.1 27 133
T11N10 1.2 30.0 0.1 1.0 0.1 21 103
T55N10 2.0 50.3 0.5 1.0 0.5 11 56
T55N20 3.0 75.4 0.5 2.0 0.5 8 39
130EF616B 1.3 33.0 0.15 1.0 0.15 21 101
150AF019B 1.5 38.1 0.0 1.0 0.5 16 79
120AF616 150AF019 200AF919Ultimate Tensile Strength [23°C] psi 28,000 23,000 20,000 ASTM D-882(MD) Mpa 193 159 138 [200°C] psi 14,500 13,500 10,700 Mpa 100 93 74
Stress at 5% Elongation [23°C] psi 10,500 8,500 7,100 ASTM D-882(MD) Mpa 72 59 49 [200°C] psi 7,000 5,700 4,300 Mpa 48 39 30
Ultimate Elongation [23°C] % 90 95 100 ASTM D-882 [200°C] psi 100 105 105
Tensile Modulus [23°C] psi 405,000 343,000 310,000 ASTM D-2176 Gpa 2.8 2.4 2.1 [200C] psi 205,000 185,000 130,000 Gpa 1.4 1.3 0.9
Tear Strength Propagating g 12 25 34 ASTM D-1938(Single tear) Ibs 0.03 0.06 0.08
Tear Strength Initial g 590 700 800 ASTM D-1004(Graves) Ibs 1.32 1.55 1.77
Density g/cm 1.53 1.67 1.79 ASTM D-1505
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®APICAL : Polyimide FilmTable 8 PHYSICAL PROPERTIES OF APICAL AF
PROPERTY UNIT TYPICAL VALUE METHOD
3
APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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120AF616 150AF019 200AF919Shrinkage MD % 0.08 0.09 0.12 IPC TM-650 2.2.4 TD 0.03 0.02 0.03 Method AHeat seal Strength MIL P-461128Coated side to coated side g/in 1,000 1,200 1,100Coated side to uncoated side - 900 -
Table 10 ELECTRICAL PROPERTIES OF APICAL AF
PROPERTY UNIT TYPICAL VALUE TEST METHOD
120AF616 150AF019 200AF919Dielectric Strength V/mil 6,900 5,000 4,800 ASTM D-149 METHOD A Type 3 electrodes, 60Hz
Dielectric Constant - 3.1 2.7 2.5 ASTM D-150 AC 1KHz
Dissipation Factor - 0.0014 0.0012 0.0008 ASTM D-150 AC 1KHz Volume Resistivity ohm-cm >10 >10 >10 ASTM D-257 DC 500V 1minute
Table 11 CHEMICAL PROPERTIES OF APICAL AF
PROPERTY UNIT TYPICAL VALUE TEST METHOD
120AF616 150AF019 200AF919Moisture Absorption % 0.8 0.8 0.4 23°C, 50%RH 1.7 1.7 1.2 23°C, immersion 24hrs.
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APICAL : Polyimide FilmTable 9 THERMAL PROPERTIES OF APICAL AF
PROPERTY UNIT TYPICAL VALUE TEST METHOD
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APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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®APICAL : Polyimide FilmTable 12 GRADE OF APICAL NP
PROPERTY NOMINAL THICKNESS APPROXIMATE AREA FACTOR
50NP 0.5 12.5 55 269100NP 1.0 25.0 28 135200NP 2.0 50.0 14 67300NP 3.0 75.0 9 45500NP 5.0 125.0 6 27
2 2
APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110
DISCLAIMER:
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Ultimate Tensile Strength (MD) psi 44,000 ASTM D-882
Mpa 303
Ultimate Elongation % 90 ASTM D-882
Tensile Modulus psi 600,000 ASTM D-2176
Gpa 4.1
Folding Endurance cycles >100,000 ASTM D-2176
Tear Strength Propagating g 7 ASTM-1938
(Single tear) lbs 0.02
Tear Strength Initial g 600 ASTM D-1004
(Graves) Ibs 1.33
Density g/Cm 1.45 ASTM D-1505
Coefficient of Friction Kinetic 0.50 ASTM D-1894
Contact Angle ° 40 Water, 20°C, 50%RH, 1atm
Surface Tension dyne/cm 60 ASTM D2578
Peel Strength p/i 6.2 Kaneka Method using
kg/cm 1.1 Kaneka propietary
Epoxy adhesive
APICAL : Polyimide Film
Table 13 PHYSICAL PROPERTIES OF APICAL NP(APICAL 100NP 1MIL)
PROPERTY UNIT TYPICAL VALUE TEST METHOD
3
APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110
www.kanekatexas.com
DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or
warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion
described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or
warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume
that toxicity data or safety measures are fully indicated or that other measures may not be required.
®
20
MD
DD (Left) 4.0 DD (Right)MD
DD (Left) 4.0 DD (Right)MD
DD (Left) 4.0 DD (Right)
APICAL : Polyimide FilmISOTROPY OF TENSILE MODULUS OF
APICAL NP
Tensile Modulus of APICAL NP is isotropic.
Figure 9 describes the isotropy of tensile modulus at positions across the web. APICAL NP is designed specifically for applications where superior dimensional stability is essential.
2.0
0
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Figure 9 ISOTROPY OF TENSILE MODULUS
(APICAL 100NP 1MIL) (UNIT: GPa)
2.0
0
2.0
0
E C W
TDTDTD
E (East), C (Center), W (West) describe the location on the web.Measurement was done in four directions across the web (Machine direction [MD],Transverse direction [TD] and 2 Diagonal directions [DD]), shown as dots.
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APICAL DIVISION KANEKA TEXAS CORPORATION
6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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®APICAL : Polyimide FilmTable 14 THERMAL PROPERTIES OF APICAL NP(APICAL 100NP 1MIL)
PROPERTY UNIT TYPICAL VALUE TEST METHOD
0.8X101.6X101.8X10
-5
-5
-5
APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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50-150°C Thermal Mechanical 100-200°C Analyzer 150-250°C
Mechanical 200 UL 7468
Flammability 94V-0 UL94Shrinkage % IPC TM-650 2.2.4 Method A 150°C 30min. 0.04 200°C 2hrs. 0.08 400°C 2hrs. 0.65
MDDD (Left) 4 DD (Right)
MDDD (Left) 4 DD (Right)
MDDD (Left) 4 DD (Right)
for dimensional stability. CTE at several tempera-ture is shown in Figure 10. CTE of APICAL is isotropic. The isotropy of CTE on APICAL NP is shown in Figure 11.
APICAL : Polyimide FilmDIMENSIONAL STABILITY OF APICAL NP -1- Coefficient of thermal expansion (CTE), Tensile modulus and Shrinkage are the important factors
2
0
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Figure 11 ISOTROPY OF CTE (APICAL 100NP 1MIL) (UNIT: X 10 /°C, TEMPERATURE
2
TDTD
E (East), C (Center), W (West) describe the location on the web.Measurement was done in four directions across the web (Machine direction [MD],Transverse direction [TD] and 2 Diagonal directions [DD]), shown as dots.
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0
Figure 10 THERMAL EXPANSION PER 1DCVS TEMPERATURE (APICAL 100NP 1MIL)
0 50 (122) 100 (212) 150 (302) 200 (392)0
1
2
3
4
5
CTE-5
2
TD0
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APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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the degree of shrinkage in Transverse direction (TD) when the film is elongated in Machine direction (MD) as shown in Figure 13. Shrinkage of NP is the same as AV shown in Figure 7.
APICAL : Polyimide FilmDIMENSIONAL STABILITY OF APICAL NP - 2 -
Tensile modulus changes according to the tempera-ture as shown in Figure 12. Poisson's ratio indicates
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Figure 12 MODULUS VS TEMPERATURE
(APICAL 100NP 1MIL)
0 50 (122)
100 (212)
150 (302)
200 (392)
0
1
2
3
4
5
TensileModulus
(GPa)
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0 50 (122)
100 (212)
150 (302)
200 (392)
0
0.2
0.4
PoissonsRatio
0.6
0.8
10
Figure 13 Poisson’s Ratio
(APICAL 100NP 1MIL)
APICAL DIVISION KANEKA TEXAS CORPORATION
6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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APICAL : Polyimide FilmTable 15 ELECTRICAL PROPERTIES OF APICAL NP(APICAL 100NP 1MIL)
PROPERTY UNIT TYPICAL VALUE TEST METHOD
16
APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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Dielectric Strength V/mil 8,000 ASTM D-149 METHOD A Type 3 electrodes, 60HzDielectric Constant IPC-TM 650 Method2.5.5.3 3.3 1KHz 3.3 1 MHzDissipation Factor IPC-TM 650 Method2.5.5.3 0.001 1 KHz 0.004 1MHzVolume Resistivity ohm-cm > 10 ASTM D-257, 500V
Hygroscopic Coefficient cm/cm/%RH 0.9X10 35°C, 20-80%RHof Expansion
Moisture Absorption % 1.3 23°C, 50%RH 2.1 23°C, immersion 24hrs.
Resistance to Chemicals Tensile Properties retained (%) ConditionChemicals Tensile Strength Elongation ModulusBenzene 100 100 100 20°C immersion 14daysToluene 100 100 100 20°C immersion 14daysMethanol 100 100 100 20°C immersion 14daysAcetone 95 100 100 20°C immersion 14daysMEK 100 100 100 20°C immersion 14days10% HCI 95 90 100 20°C immersion 14days10% H SO 95 90 100 20°C immersion 14days10% NaOH Degraded Degraded Degraded 20°C immersion 4days5% NaOH 80 75 100 50°C immersion 3min.FeCI 90 100 100 20°C immersion 14daysCuCI 60 55 100 20°C immersion 14days
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2 4
3
2
APICAL : Polyimide FilmTable 16 CHEMICAL PROPERTIES OF APICAL NP(APICAL 100NP 1MIL)
PROPERTY UNIT TYPICAL VALUE TEST METHOD
APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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weight loss of APICAL NP in caustic solution. Figure 15 shows the etching rate in caustic solution (Solvent is a mixture of water and ethanol).
APICAL : Polyimide FilmALKALINE RESISTANCE OF APICAL NPAPICAL NP can be etched by caustic solution as shown in Figure 14 and 15. Figure 14 shows the
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Figure 14 WEIGHT LOSS IN CAUSTIC SOLUTION VS EXPOSURE TIME (APICAL 100NP 1MIL)
Figure 15 ETCHING RATE IN CAUSTIC SOLUTION (APICAL 100NP 1MIL)
0 100
810
16
Weight Loss%
Time in caustic solution (Minutes)
0 20 40 60 80 100
1.0
2.0
3.0
Etching rate(%/Min.)
Weight of Ethanol to Water (wt%)
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0
1412
642
5 15 20 25 30
APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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APICAL : Polyimide FilmTABLE 17 COMPARISON DATA
PROPERTY UNIT APICAL APICAL COMPETlTOR* TEST METHOD Ultimate Tensile Strength psi 35,000 44,000 33,500 ASTM D-882(MD) Mpa 241 303 231Ultimate Elongation % 95 90 72 ASTM D-882Tensile Modulus psi 460,000 600,000 370,000 ASTM D-2176 Gpa 3.2 4.1 2.5Density g/cm 1.42 1.45 1.42 ASTM D-1505Coefficient of Friction Kinetic 0.40 0.50 0.48 ASTM D-1894Flammability 94 V-O 94 V-O 94 V-O UL94Coefficient of 3.2X10 1.6X10 3.2X10 Thermal MechanicalThermal Expansion Analyzer(100°C - 200°C)Shrinkage % IPC TM 650, 2.2.4150 - 30min 0.04 0.04 0.03 Method ADielectric Strength V/mil 7,800 8,000 7,700 ASTM D-149Moisture Absorption % ASTM D-57050%RH at 23°C 1.3 1.3 1.8Immersion for 24hrs. at 23°C 2.9 2.1 2.8'These data are derived from OU PONT catalog. (Kapton Type VN film)
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-5
100AV 100NP
-5
-3
APICAL DIVISION KANEKA TEXAS CORPORATION6161 Underwood Road Pasadena,TX 77507 800-222-8128 Phone: 281-447-0755 Fax:281-291-2110www.kanekatexas.com DISCLAIMER: Although all statements and information are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied, and risks and liability for results obtained by use of the products or application of the suggestion described are assumed by the user. Statements or suggestions concerning possible use of our product are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data or safety measures are fully indicated or that other measures may not be required.
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