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Li, Wenhua ; Gan , Jiangang ; Ma, Dawei . Total synthesis of piperazimycin A: A cytotoxic cyclic hexadepsipeptide . Angewandte Chemie , International Edition (2009), 48(47), 8891-8895, S8891/1-S8891/85. Cbz = carbobenzyloxy (removed by hydrogenolysis ). - PowerPoint PPT Presentation
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Li, Wenhua; Gan, Jiangang; Ma, Dawei. Total synthesis of piperazimycin A: A cytotoxic cyclic hexadepsipeptide. Angewandte Chemie, International Edition (2009), 48(47), 8891-8895, S8891/1-S8891/85.
Cbz = carbobenzyloxy (removed by hydrogenolysis)
Troc = trichloroethoxycarbonyl (removed by beta-elimination, usually enacted by treatment with zinc)
Appel Reaction
Appel Reaction
FmocOSu =
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