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Slide 1
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Operations LevelOperations LevelResponder ReviewResponder Review
Special Hazards Training BranchSpecial Hazards Training BranchMassachusetts Firefighting AcademyMassachusetts Firefighting Academy
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DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 4
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 5
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Carbon Monoxide +Carbon Monoxide +Hydrogen Chloride +Hydrogen Chloride +Hydrogen Cyanide +Hydrogen Cyanide +
Phosgene +Phosgene +Ammonia +Ammonia +Chlorine =Chlorine =
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Residential Building FireResidential Building Fire
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Slide 6
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
UN 1193 MEKUN 1193 MEK
SPCSPCOROR
CPC ?CPC ?
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Slide 7
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
THERMALTHERMALPROTECTIONPROTECTION LIMITEDLIMITED
TO NO CHEMICALTO NO CHEMICALPROTECTIONPROTECTION
NO THERMALNO THERMALPROTECTION BUTPROTECTION BUT
VAPOR/LIQUIDVAPOR/LIQUIDPROTECTIONPROTECTION
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Slide 8
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Hazard & Risk AssessmentHazard & Risk Assessment
RescueRescue -- Is the First Tactical PriorityIs the First Tactical Priorityconsidered during a hazmat incidentconsidered during a hazmat incident
Line of sight rescueLine of sight rescueTier II/III, SPC, SCBA,Tier II/III, SPC, SCBA,Vapor Control/Vapor Control/Emergency Decon LineEmergency Decon LineKeep Me Safe DetectionKeep Me Safe Detection
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Slide 9
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Hazard & Risk AssessmentHazard & Risk Assessment
Just what are we looking for ?Just what are we looking for ? Clues Clues
What you hear (dispatch) ?What you hear (dispatch) ?What you see (windshield) ?What you see (windshield) ?
What you hear (bystanders)?What you hear (bystanders)?
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Slide 10
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Hazard & Risk AssessmentHazard & Risk Assessment
Just what are we looking for ?Just what are we looking for ?Clues: Clues:
TransportationTransportation ERGERG
NIOSHNIOSHPlacards/PapersPlacards/Papers
Fixed FacilityFixed Facility NFPA 704NFPA 704NIOSHNIOSHMSDS/SDSMSDS/SDS
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Slide 11
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
FIRST DUEFIRST DUE referencesreferencesHazard & Risk AssessmentHazard & Risk Assessment
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Slide 12
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Hazard & Risk AssessmentHazard & Risk AssessmentKeepKeep EmEm Safe DetectionSafe Detection
O2/CO/LEL/HCNO2/CO/LEL/HCN RadRad HeatHeat
pHpH M8/M9M8/M9
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Slide 13
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
WHAT IS YOUR MISSION ?WHAT IS YOUR MISSION ?
Rescue:Rescue: Line of SightLine of SightKEEP OUT OF PRODUCT !!KEEP OUT OF PRODUCT !!
Body Recovery:Body Recovery: No Rush No Rush Plumbing or Product Control:Plumbing or Product Control: No Rush No Rush Crime Scene:Crime Scene: No Rush No Rush Environmental:Environmental: No Rush No Rush
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Slide 14
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
YOUR OPTIONS: YOUR OPTIONS:
Life HazardsLife Hazards -- Call a HM Tier II/IIICall a HM Tier II/IIIHazard & Risk AssessmentHazard & Risk Assessment
GO or NO GOGO or NO GO
Initial EvacuationInitial EvacuationSolid = 75Solid = 75
Liquid = 150Liquid = 150
Gas = 300Gas = 300
DefensiveDefensive -- KEEP OUT OF PRODUCT KEEP OUT OF PRODUCT
KEEP OUT OF PRODUCT KEEP OUT OF PRODUCT
Establish Control ZonesEstablish Control Zones
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Slide 15
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
WHATEVER ACTION YOU TAKE, JUSTWHATEVER ACTION YOU TAKE, JUSTDONDON T POSE FOR HOLY PICTUREST POSE FOR HOLY PICTURES
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Slide 16
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Haz Haz - - Mat Definit ion Mat Definit ion Material that poses an unreasonableMaterial that poses an unreasonablerisk to the health and safety ofrisk to the health and safety ofoperating emergency personnel, theoperating emergency personnel, the
public, and or the environment if it ispublic, and or the environment if it isnot properly controlled duringnot properly controlled duringhandling, storage, manufacture,handling, storage, manufacture,processing, packaging, use andprocessing, packaging, use anddisposal or transportationdisposal or transportation
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DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 19
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Hazardous occupancies should be identifiedHazardous occupancies should be identifiedduring Preduring Pre --Incident PlanningIncident Planning
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Slide 20
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Using senses of smell, touch or taste isUsing senses of smell, touch or taste isunsafeunsafe !!
GoodGood
Not GoodNot Good
Sight and hearingSight and hearingare the onlyare the onlysenses used !senses used !
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Slide 21
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Hazardous Materials can be foundHazardous Materials can be foundanywhere including:anywhere including:
Private homes;Private homes;Doctor Doctor s offices;s offices;Hardware Stores;Hardware Stores;Supermarkets;Supermarkets;Fire Stations;Fire Stations;And So On !And So On ! It isIt isnot just chemicalnot just chemicalfacilities, trains,facilities, trains,trucks, etctrucks, etc ....
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Slide 22
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Hazmat incidents are more complexHazmat incidents are more complexthan other types of emergenciesthan other types of emergencies
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DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 24
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
SHELTER IN PLACE (S.I.P.)SHELTER IN PLACE (S.I.P.)
People inside a building should remainPeople inside a building should remaininside until the danger passesinside until the danger passes
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Slide 25
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
SHELTER IN PLACE (S.I.P.)SHELTER IN PLACE (S.I.P.)
Close all windows, doorsClose all windows, doorsMonitor local TV and radioMonitor local TV and radioReverse EReverse E --911911
Shut down the HVAC SystemShut down the HVAC System
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Slide 26
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
EvacuateEvacuate
Moving people threatened to a safe areaMoving people threatened to a safe area
One Factor that changes evacuation,One Factor that changes evacuation,wind directionwind direction
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Slide 27
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Evacuate or SIP or BothEvacuate or SIP or Both
No preferred methodNo preferred method
Not an easy decisionNot an easy decision
Risk Based ResponseRisk Based Response
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Slide 28
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
IsolateIsolate -- Keep people not directlyKeep people not directlyinvolved away from the incidentinvolved away from the incident
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DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 31
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
The APIE ProcessThe APIE Process
RISK BASED RESPONSE FRAMEWORKRISK BASED RESPONSE FRAMEWORK
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Slide 32
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
VERIFY & QUESTIONVERIFY & QUESTION
Fire Alarm/Dispatch InformationFire Alarm/Dispatch Information
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Slide 33
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Building/Facility IncidentBuilding/Facility IncidentExact location of the BUILDING/PLANTExact location of the BUILDING/PLANT
Inside or Outside of a buildingInside or Outside of a buildingCommercial/Residential or MixedCommercial/Residential or MixedUseUse
Building Markings (NFPA 704)Building Markings (NFPA 704)
Type of BusinessType of Business
PrePre --Incident Plans/MSDS AvailableIncident Plans/MSDS Available
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Slide 34
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Control Centers ResponsibilityControl Centers Responsibility
CLUES ?CLUES ?
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DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
CLUES ?CLUES ?
Building/Facility IncidentBuilding/Facility Incident
PrePre --Incident PlansIncident Plans ResourcesResources
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Slide 36
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
CLUES ? What wouldWhat would
happen if thehappen if thePatr iots hi t thePatr iots hi t thefield without af ield withou t agame p lan? game p lan?
WhatWhat s Thes TheGame Plan?Game Plan?
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Slide 37
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
PROBLEMPROBLEMContainer TypeContainer Type
How much material is involved ?How much material is involved ?SpillSpillLeakLeakReleaseRelease
Explosive Devices?Explosive Devices?Suspicious PackagesSuspicious Packages
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Slide 38
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Exact location of the HIGHWAY incidentExact location of the HIGHWAY incident
Direction of TravelDirection of Travel --NB/SB/EB/WBNB/SB/EB/WB
Type of VehicleType of Vehiclecar/van/suvcar/van/suvfreight truckfreight trucktanker trucktanker truck
DOT Placards & MarkingsDOT Placards & MarkingsShipping Papers AvailableShipping Papers Available
HIGHWAY INCIDENTHIGHWAY INCIDENT
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Slide 39
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
PROBLEMPROBLEMContainer TypeContainer Type
How much material is involved ?How much material is involved ?SpillSpillLeakLeakReleaseRelease
SolidSolid --LiquidLiquid --Gas ?Gas ?
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Slide 40
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
CLUES CLUES ! ! Highway/Railroad/WaterwayHighway/Railroad/Waterway
Vehicle Type;Vehicle Type;
Tanker TruckTanker TruckFreight TruckFreight TruckRailcar Railcar VesselVessel
Vehicle markings or PlacardsVehicle markings or Placards
Shipping Papers AvailableShipping Papers Available
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Slide 41
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
CLUESCLUES
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Slide 42
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
CLUESCLUES
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Slide 43
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
CLUESCLUES
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Slide 44
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
CLUESCLUESCLUESCLUES
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Slide 45
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
NOT SO OBVIOUS CLUESNOT SO OBVIOUS CLUES
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Slide 46
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
CLUESCLUES
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Slide 47
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
NOT SO OBVIOUS CLUESNOT SO OBVIOUS CLUESWhat is it? Butylated HydroxytouleneWhat is it? Butylated Hydroxytoulene
Major Uses: FOOD ADDITIVEMajor Uses: FOOD ADDITIVEIts also put in the cardboard of cereal andIts also put in the cardboard of cereal andmacaroni boxes as a preservativemacaroni boxes as a preservative
What is it used for?:What is it used for?:AnAn antianti --oxidant in embalming fluidoxidant in embalming fluidWhat does it do to you? BHT dust is irritating ifWhat does it do to you? BHT dust is irritating ifin contact with the eyes, nose or throatin contact with the eyes, nose or throat
Just because i t has aJust becau se it has a scary name scary name doesn ' t mean i t ' s a l l that bad.doesn ' t mean i t ' s a l l that bad.
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Slide 48
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
TRANSPORTATION INCIDENTTRANSPORTATION INCIDENT
Exact locationExact location
SUBWAYSUBWAY
AMTRAKAMTRAK
AIRPORT TERMINALAIRPORT TERMINAL
SEAPORT TERMINALSEAPORT TERMINALWHARF/PIER/DOCKWHARF/PIER/DOCK
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Slide 49
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
PROBLEMPROBLEM
AccidentsAccidents
Explosive Devices ?Explosive Devices ?
Secondary DevicesSecondary DevicesSuspicious PackagesSuspicious Packages
Biohazard ReleaseBiohazard ReleaseChemical ReleaseChemical Release
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Slide 50
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
CLUESCLUES
Multiple victimsMultiple victims
Signs & SymptomsSigns & Symptoms(SLUDGEM)(SLUDGEM)
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Slide 51
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
MINOR EVENT OR MCIMINOR EVENT OR MCIWhat happened ?What happened ?
Injuries ?Injuries ?How Many ?How Many ?Trauma/BlastTrauma/BlastInjuriesInjuries
NonNon --TraumaTrauma
CBRN/Chemical/CBRN/Chemical/Bio/Delayed/Bio/Delayed/Radiation/Nuclear Radiation/Nuclear
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Slide 52
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
GEOGRAPHY/TOPOGRAPHYGEOGRAPHY/TOPOGRAPHY
Area GeographyArea Geography
Densely populatedDensely populatedRuralRuralLowLow --lying arealying areaWaterwaysWaterways
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Slide 53
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
HowHow s The Weather ?s The Weather ?VERIFY !VERIFY !
Weather Weather Current/ChangeCurrent/Change
Wind speed &Wind speed &directiondirection Wind out of the __ Wind out of the __
or or
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Slide 54
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Heat Index ChartHeat Index Chart
TemperatureTemperature
Heat/Cold IndexHeat/Cold Index
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Slide 55
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
SOLID/LIQUID/GASWhat is the material ?What is the material ?
Physical Properties MP,Physical Properties MP, FrzFrz P, MW/SG, VDP, MW/SG, VDFP, IT, LEL & UELFP, IT, LEL & UEL
RememberRememberthe NIOSHthe NIOSH
Book ?Book ?
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Slide 56
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
LIGHTER THAN AIR GASLIGHTER THAN AIR GASHAHAHAHA --MICEMICE 44 --H MEDIC ANNAH MEDIC ANNA
HHydrogenydrogen HHydrogenydrogenAAmmoniammonia HHeliumeliumHHeliumelium HHydrogenydrogen CyanideCyanideAAcetylenecetylene HHydrogenydrogen FluorideFluorideMMethaneethane MMethaneethaneIIlluminatinglluminating GasesGases EEthylenethyleneCCarbonarbon MonoxideMonoxide DDiboraneiboraneEEthylenethylene IIlluminatinglluminating GasesGases
CCarbonarbon MonoxideMonoxideAAcetylenecetyleneNNeoneonNNitrogenitrogenAAmmoniammonia
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Slide 57
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
An ExampleAn Example
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Slide 58
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 59
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 60
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
CALCIUM CARBIDE + H20 ACETYLENE GASCALCIUM CARBIDE + H20 ACETYLENE GAS
METHANE & PROPANE THERMAL CRACKINGMETHANE & PROPANE THERMAL CRACKING
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Slide 61
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Various acetylene low pressure cylindersVarious acetylene low pressure cylinders15 psi Storage Pressure 250#15 psi Storage Pressure 250#
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Slide 62
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Flame TemperatureFlame Temperature
4217 in air 4217 in air
5710 in oxygen5710 in oxygen
MW: 26MW: 26
FP:FP:
IP: 11.40IP: 11.40RGasDRGasD : 0.91: 0.91
VP: 44.2VP: 44.2 atmatm
UEL: 100%UEL: 100%
LEL: 2.5LEL: 2.5
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Slide 63
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 64
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 65
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Calcium silicateCalcium silicate --sand lime andsand lime and
asbestoesasbestoes
Filler Looks solidFiller Looks solidbut actually is 92%but actually is 92%NothingNothing
Prevents pockets ofPrevents pockets offree acetylenefree acetylene
Cylinder is filledCylinder is filledwith acetone beforewith acetone beforeacetylene is pumpedacetylene is pumpedinto it.into it.
Dissolved in acetoneDissolved in acetoneacetylene is stableacetylene is stable
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Slide 66
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Acetone or DMFAcetone or DMF
Soft Plug meltsSoft Plug meltsat 212at 212 FF
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Slide 67
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Decomposing acetyleneDecomposing acetyleneflame can propagateflame can propagateback into its cylinder.back into its cylinder.Fire may appear to beFire may appear to beout. Unless a cooling fogout. Unless a cooling fogstream is kept upon it, itstream is kept upon it, itwill probably explode.will probably explode.
Straight streams willStraight streams willknock unsecuredknock unsecuredcylinders over ! Use Fogcylinders over ! Use Fogstreamsstreams
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Slide 68
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Acetylene IncidentAcetylene Incident
Why we donWhy we don t store Acetylenet store Acetylenein a closed up vehicle !in a closed up vehicle !
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Slide 69
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 73
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Awareness Level PersonnelAwareness Level Personnel
Calling for help / making the appropriateCalling for help / making the appropriatenotificationsnotifications
Protect themselvesProtect themselves Isolate the areaIsolate the area Recognizing the presence of hazardousRecognizing the presence of hazardous
materialsmaterials Recognizing the need for additional resourcesRecognizing the need for additional resources
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Slide 74
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 75
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
RecognizeRecognize -- IdentifyIdentify -- IsolateIsolate
Defensive StrategiesDefensive Strategies
Product Control Measures:Product Control Measures:
Containment, ConfinementContainment, ConfinementDamming, Diking,Damming, Diking,Diversion and RetentionDiversion and Retention
Operations Level Responder Operations Level Responder
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Slide 76
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
DiversionDiversion -- the redirection ofthe redirection ofproduct away from an area.product away from an area.
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Slide 77
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
AbsorptionAbsorption Defensive, use of aDefensive, use of amaterial to soak up a spillmaterial to soak up a spill
Requires FFRequires FF s to be in closes to be in closeproximity to spillproximity to spill
Absorbent may react with hazardousAbsorbent may react with hazardoussubstancesubstance
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Slide 78
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
ConfinementConfinement method tomethod tokeep a material controlledkeep a material controlledin local areas; damming,in local areas; damming,diversion.diversion.
ContainmentContainment plugging,plugging,patching a container patching a container
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Slide 79
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Vapor SuppressionVapor Suppression -- reduce the emissionreduce the emissionof vapors (foam)of vapors (foam)
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Slide 80
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Vapor DispersionVapor Dispersion
Defensive strategiesDefensive strategies Fire Streams or Fans to reFire Streams or Fans to re --direct vapors awaydirect vapors away Not always a good idea with flammablesNot always a good idea with flammables Product does not need to be water Product does not need to be water --solublesoluble
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Slide 81
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
When assessing scene with aWhen assessing scene with avapor cloud:vapor cloud:
OLR personnelOLR personnel do notdo not enter the hotenter the hotzone (Exceptionzone (Exception the mission isthe mission isRESCUERESCUE ))
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Slide 82
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 83
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
HazHaz --Mat Technician Level..Mat Technician Level..Analyze a hazardous materials/WMDAnalyze a hazardous materials/WMDincident to determine the complexity of theincident to determine the complexity of theproblem and potential outcomes byproblem and potential outcomes bycompleting the following tasks:completing the following tasks:
Survey the hazardous materials/WMDSurvey the hazardous materials/WMDincident to identify special containersincident to identify special containersinvolved,involved,
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Slide 84
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
HazHaz --Mat Technician Level..Mat Technician Level..Identify or classify unknown materials, andIdentify or classify unknown materials, andverify the presence and concentrations ofverify the presence and concentrations ofhazardous materials/WMD through the usehazardous materials/WMD through the useof monitoring equipment.of monitoring equipment.
Collect and interpret hazard and responseCollect and interpret hazard and responseinformation from printed and technicalinformation from printed and technicalresources, computer databases, andresources, computer databases, andmonitoring equipment.monitoring equipment.
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Slide 85
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Use of monitoring equipment inUse of monitoring equipment inan endangered area done by HMRTan endangered area done by HMRT
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Slide 86
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 87
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Use CHEMTREC for product infoUse CHEMTREC for product info
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Slide 88
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
An agency to contact whenAn agency to contact whenattempting to collect informationattempting to collect informationduring a hazmat eventduring a hazmat event
11 --800800 --424424 --93009300
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Slide 89
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Principal agency to providePrincipal agency to provideimmediate technical assistance toimmediate technical assistance toan emergency responder an emergency responder
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Slide 90
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
AdviseAdvise of the following:of the following:
Caller name and call back number Caller name and call back number Type of container or vehicleType of container or vehicleMaterial, shipper & manufacturer Material, shipper & manufacturer
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Slide 91
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Provides:Provides:
Hazard information warningsHazard information warningsData basesData bases
Technical informationTechnical information
Does notDoes not provide advice on remediationprovide advice on remediationcontractorscontractors
NOTE: It is not mandatory for chemicalNOTE: It is not mandatory for chemicalmanufacturers and etc. to belong to thismanufacturers and etc. to belong to thisorganization. It is a service !!organization. It is a service !!
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Slide 92
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 93
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Warm ZoneWarm Zone
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Slide 94
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Emergency DeconEmergency Decon
Does not need to take placeDoes not need to take placein the decon corridor in the decon corridor
Removal of contaminationRemoval of contaminationof victims in need ofof victims in need ofmedical attentionmedical attention
Goal of is to quickly removeGoal of is to quickly removepossible contaminationpossible contamination
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Slide 95
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Emergency DeconEmergency Decon
Does not need formal decon areaDoes not need formal decon area
Provides only gross deconProvides only gross decon
Victim may still pose threat to secondaryVictim may still pose threat to secondarycontaminationcontamination
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Slide 96
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Designed to remove contaminants thatDesigned to remove contaminants thatare an immediate threat to lifeare an immediate threat to life
RunRun --Off ControlOff Control -- try to divert to an area totry to divert to an area tobe handled later be handled later
Emergency DeconEmergency Decon
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Slide 97
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 98
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Being exposed to a hazardous materialBeing exposed to a hazardous materialdoes not mean you are contaminateddoes not mean you are contaminated
EXPOSED ?EXPOSED ?
CONTAMINATED ?CONTAMINATED ?
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Slide 99
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Persons and Equipment contaminated without DeconPersons and Equipment contaminated without Deconwould likely result in secondary contamination (spread)would likely result in secondary contamination (spread)
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Slide 100
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Expect contaminated equipment andExpect contaminated equipment andpersonnel when:personnel when:
Working in Hot ZoneWorking in Hot Zone
Working downwind and downhillWorking downwind and downhill
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Slide 101
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Expect contaminated equipment andExpect contaminated equipment andpersonnel when:personnel when:
Parking apparatus downwindParking apparatus downwind
Working in the decon areaWorking in the decon area
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Slide 102
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Best work uphill and upwindBest work uphill and upwind
??
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Slide 103
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 104
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 105
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Hot/Exclusion ZoneHot/Exclusion Zone
Contamination has occurred or mayContamination has occurred or mayoccur and requires established entryoccur and requires established entryand exit control pointsand exit control points
Highest known hazardHighest known hazard
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Slide 106
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Warm ZoneWarm Zone
Located just outside the Hot/ExclusionLocated just outside the Hot/ExclusionZoneZone
Includes the decon areaIncludes the decon area
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Slide 107
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Cold ZoneCold Zone
Command Post and StagingCommand Post and Staging
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Slide 108
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Warm ZoneWarm Zone
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Slide 109
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 110
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
NFPA 704 is the standard for identifyingNFPA 704 is the standard for identifyingchemical hazards at fixed facilitieschemical hazards at fixed facilities
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Slide 111
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Engine 3 ArrivalEngine 3 Arrival
Use the NFPA 704 system to identifyUse the NFPA 704 system to identifyhealth, flammability, reactivity and specialhealth, flammability, reactivity and specialhazards of stored material in a facilityhazards of stored material in a facility
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Slide 112
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Provides a general hazard andProvides a general hazard anddegree of severitydegree of severity
00 -- 44
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Slide 113
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Number 4 indicates aNumber 4 indicates asevere hazardsevere hazard
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Slide 114
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Most dangerous chemicalsMost dangerous chemicalswould have 4would have 4 s in eachs in eachcategorycategory
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Slide 115
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Red diamond indicates fireRed diamond indicates fire
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Slide 116
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Blue diamond indicates healthBlue diamond indicates health
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Slide 117
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Yellow diamond indicates reactivity Yellow diamond indicates reactivity
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Slide 118
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
White diamond indicates special hazardWhite diamond indicates special hazard
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Slide 119
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
White quadrant indicatesWhite quadrant indicates
special hazards:special hazards:
WW OXYOXY ACIDACIDALKALK CORCOR
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Slide 120
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Water reactive would beWater reactive would beindicated in the white quadrantindicated in the white quadrant
WW
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Slide 121
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
NFPA 704 doesNFPA 704 does NOTNOT provideprovide
a chemical namea chemical name
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Slide 122
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 123
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
TheThe ERG is the reference bookERG is the reference bookcarriedcarried on all fire apparatus in USon all fire apparatus in US
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Slide 124
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Use the ERG to determine anUse the ERG to determine anendangered areaendangered area
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Slide 125
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
The ERG deals with protective actionThe ERG deals with protective actiondistances involving poisonousdistances involving poisonoussubstancessubstances
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Slide 126
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
The ERG orange section provides fire,The ERG orange section provides fire,explosion and health hazardexplosion and health hazardinformation.information.
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Slide 127
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
IIf a chemical name is highlighted in the ERG,f a chemical name is highlighted in the ERG,the initial isolation distances would be foundthe initial isolation distances would be foundin the green pages.in the green pages.
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Slide 128
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Table of Isolation distances, a large spill isTable of Isolation distances, a large spill isdefined as a quantity greater than 55 gallonsdefined as a quantity greater than 55 gallons
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Slide 129
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
A placard is required if the gross weight ofA placard is required if the gross weight ofproduct(s) is greater than 1001#product(s) is greater than 1001#
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Slide 130
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
A tractor A tractor trailertrailercarrying 975# ofcarrying 975# ofOrganic PeroxideOrganic Peroxideother than Type Bother than Type B --no placardno placardrequired (see chartrequired (see chart1414 Table 1 & 2)Table 1 & 2)
DOT Chart 14DOT Chart 14
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Slide 131
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
UN/DOT placards indicateUN/DOT placards indicatea general hazard by thea general hazard by theUN/NA hazard class #UN/NA hazard class #
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Slide 132
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Number at bottom of placardNumber at bottom of placardindicates the UN hazard classindicates the UN hazard class
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Slide 133
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Orange Placard with a number 1Orange Placard with a number 1EXPLOSIVESEXPLOSIVES
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Slide 134
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
While rescuing victims where a fire involving aWhile rescuing victims where a fire involving aClass 1 materialClass 1 material
Primary HazardPrimary Hazard -- Explosion Explos ion
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Slide 135
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Placard with a number 2Placard with a number 2- - All Gases All Gases - -
WhiteWhite
RedRed
Yellow Yellow
GreenGreen
PlacardPlacardB a c k g r o u n d s B a c k g r o u n d s
?
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Slide 136
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Placard color for a nonPlacard color for a non flammableflammablecompressed gascompressed gas GREENGREEN
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Slide 137
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
While rescuing victims where aWhile rescuing victims where a nonnon flammableflammableClass 2 productClass 2 product is leakingis leaking
Primary HazardPrimary Hazard -- Inhalation Inhalation
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Slide 138
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
REDRED placard with a number 2placard with a number 2FLAMMABLE GAS FLAMMABLE GAS
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Slide 139
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Flammable Gas/Liquid leaksFlammable Gas/Liquid leaks eliminate alleliminate allignition sourcesignition sources
ORORChange the environmentChange the environment
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Slide 140
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
White Background placard with skull andWhite Background placard with skull andcrossbones =crossbones = POISONOUS GASPOISONOUS GAS
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Slide 141
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
REDRED placard with a number 3placard with a number 3FLAMMAB LE LIQUID / COMBUSTIBLE FLAMMAB LE LIQUID / COMBUSTIBLE
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Slide 142
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Container of Flammable LiquidContainer of Flammable LiquidUN/DOT Hazard Class 3UN/DOT Hazard Class 3
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Slide 143
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
TractorTractor trailer hauling gasoline wouldtrailer hauling gasoline woulddisplay a red hazard placard with a hazarddisplay a red hazard placard with a hazardclass 3class 3
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Slide 144
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
striped placard with astriped placard with anumber 4number 4 FLAMMAB LE SOLID FLAMMAB LE SOLID
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Slide 145
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
BLUEBLUE placard with a number 4placard with a number 4DANGEROUS WHEN WET DANGEROUS WHEN WET
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Slide 146
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Yellow Yellow placard with a number 5.1placard with a number 5.1OXYDIZER OXYDIZER
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Slide 147
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Substance that readily yields Oxygen to supportSubstance that readily yields Oxygen to supportcombustion of fuels would have a UN Class 5combustion of fuels would have a UN Class 5
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Slide 148
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Primary hazard of a DOT class 5 isPrimary hazard of a DOT class 5 is
Oxidation which supports combustionOxidation which supports combustion
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Slide 149
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
DOT hazard class 6 includesDOT hazard class 6 includes liquidliquidpoisons, infectious substance,poisons, infectious substance,poison solids.poison solids.
Does not includeDoes not include Poison GasesPoison Gases(which is Class 2)(which is Class 2)
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Slide 150
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
DOT hazard class 6 poisonsDOT hazard class 6 poisons biologicalbiologicaletiological agents and toxins etiological agents and toxins
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Slide 151
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Yellow/White placard with number 7 Yellow/White placard with number 7RADIOACTIVE RADIOACTIVE
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Slide 152
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Hazard Class 8 consists of CorrosivesHazard Class 8 consists of Corrosives
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Slide 153
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
White/Black placard with number 8White/Black placard with number 8CORROSIVE (1,001 # or g reater) CORROSIVE (1,001 # or greater)
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Slide 154
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
DOT hazard class 9DOT hazard class 9 MISCELLANEOUS MISCELLANEOUS
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Slide 155
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
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Slide 156
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
OctagonOctagon --shaped placard with a #1 denotesshaped placard with a #1 denotes --Mass DetonationMass Detonation
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Slide 157
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Explosive with fragmentExplosive with fragmenthazard #2 in an Xhazard #2 in an X
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Slide 158
DEPARTMENT OF FIRE SERVICESHazardous Materials Training Division
Symbol and # for Mass FireSymbol and # for Mass FireHazard #3 TriangleHazard #3 Triangle
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