reduction of pinacol

PRESENTED BY:

HABIBA AYUB BUTTS/2012-1922BS.ED(HONS)

PRESENTATION TOPIC:

REDUCTION OF

PINACOL

REDUCTION OF PINACOLS: It is a bimolecular reduction reaction ketones+magnesium amalgam(Mg-Hg)

+water=Pinacols

PINACOL REARRANGEMENT Pinacol Rearrangement is also called

as Pinacol-Pinacolone rearrangement. It is an acid catalyzed organic chemical

reaction in which 1, 2-diols are converted to carbonyl compounds.

The name comes from the reactant and the product that is pinacol to pinacolone. This reaction is named after a German chemist Wilhelm Rudolph Fittig in 1860.

For example, consider the following reaction:

MECHANISM:

Reduction of Pinacolone with Sodium Borohydride

FOR REDUCTION:

MECHANISM:

REFERENCES: http://

chemistry.tutorvista.com/organic-chemistry/pinacol-rearrangement.html

https://prezi.com/s4c4redxea8d/reduction-of-pinacolone-with-sodium-borohydride/

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