-
------2012 --
-
++
-
3.2009~2011 I
2009201020117STS89Li-Al/FeS10B1112:13
-
3.2009~2011 II
2009201020111414NaFeNNa2OFe2O3Na2CO3NaHCO315FeIS1515141516151417X14
-
2626[14]CDXYZXYZXYZ10DGJMI0920102011
-
2612
-
2615XXXANaOHXABCDCNaOHBACD12161(1) C (2) X (3) A________(4) D
(5) X_______(6) CNaOHYY [25KSPMg(OH)2=5.611012KSPAl(OH)3=31034]
-
121IO35I6H===3I23H2O2Fe 3 2I==2Fe 2
I24KIO22H2O==2I24KOH201126
-
2
-
326(15)SO2NOxNa+Mg2+NH4+Cl-SO32-SO42-NO3-NO2-4KIBaCl2NaOHAgNO3KMnO4Ksp(Ag2SO4)
= 1.2010-51 2KI 3Cl- 4NONOSO2O2 NO 2012
-
201013)NO2-SO42-SO32-CO32-Cl-I-5pHpH7AgNO3BaCl2BaCl2NH42FeSO42KSCNNO2-CO32-Cl-A.
B. C. D.
-
(l)Na+Mg 2+NH 4+Cl- S032-S042-N03-N02-4S032- N02- ?
AKIBBaCl2CNaOHDKMnO4(2)OH-H+NH4+Cl-c(NH4+)>cCl- (3)25Ksp(RX)=1.8
X 10-10, Ksp(RY)=1.8X 10-16, Ksp(R2Z)=1.8 X 10-12 RXRYR2ZR+
-
K+Na+Fe 2+Fe 3+SO4 2-NO2-CO32-20mL (1) (2)NaOHxg (3)0.10
molL-lKMnO4VmL(4)ANa+Fe 3+SO42-K+CO32-B(1)SO42-C(2)(3)Fe
3+D(3)NO2-
-
27109102
-
KSP pH()
-
.2011157002LCOH2O,CO(g)H2O(g) CO2H2(g) t1t2:A.t1minv(H2)0.40/t1
molL1 min1B.0.60molCO1.20 molH2On(CO2)0.40
molC.0.20molH2OCOH2OD.8000.64
/minn(CO)/molH2O/ mol01.200.60t10.80t20.20
-
27(15)(t-BuNO)2(t-BuNO)2 2(t-BuNO) 1(t-BuNO)2c00.50 molL-12065
%20K = 2(t-BuNO)2 201227(2)0.10 molL-1 2060%20K
=___________________( (4)________()2CH3COCH3(aq)
CH3COCH2COH(CH3)2(aq)
-
.NO2N2O4N2O42NO2()NO2N2O41 L
(1)XYX NO2abcdbd Xbd
-
NO2N2O4N2O42NO2()NO2N2O41 L
(2)10 minNO2v(NO2)=0.04mol/(Lmin)25 min0.4 mol
NO20.04mol/(Lmin)0.4 mol NO2
-
NO2N2O4N2O42NO2()NO2N2O41 L
(3)25 min( ) A. B. C. D.N2O4B D
-
NO2N2O4N2O42NO2()NO2N2O41 L
(4)K( )()c(NO2)/c(N2O4)( )() A.N2O4 B.NO2 C. D.DAB
-
15 pHZn2+ Zn(OH)42-
1ZnCl22Zn(OH)2K sp= 3Zn2+ Zn2+ pH 41L 1.00 molL-1
ZnCl2NaOHpH=6NaOH 525PbCl2cHCl/ molL-1 0.50 1.00 2.04 2.90 4.02
5.16 5.78103 cPbCl2/ molL-15.10 4.91 5.21 5.90 7.48 10.81 14.01
aPbCl2 bPbCl20.50 molL-1 cPbCl2 dPbCl2 1NaOHZn(OH)42-
2pH=7lgZn2+=-3.0 Ksp=C(Zn2+) C2 (OH-)=10-3(10-7)2=10-17 3pH(8.0
12.0) 4Ksp=10-17pH=6C(Zn2+)=0.1mol/Ln(Zn2+)=0.9moln(NaOH)=1.8mol
5PbCl2Cl-PbCl2 Cl-PbCl2PbCl2 (1)Zn2++4OH-=[Zn(OH)4]2+ (2)10-17
(3)(8.0 12.0) (4)1.80 (5)abcd
-
1+1
-
1212
-
1.20117A.pHpHB.20 mL0.5000 molL1 H2SO480mL0.1000 molL1
H2SO4C.2D.3Cl2HClD
-
O2 H2 Cl2HCl H2S NH3CO2 SO2 NO2 NO COC2H4 C2H2
-
1231234
123
-
MgSO4NaClpH
-
(?)
-
2010
-
2009Cl2
-
16. ABCDE 1AKCl2DCl2CDDCO2HClD_ _______C_ ________ 1 2Cl2 + 2H2O
(g) + C = 4HCl + CO2HClD
-
2E___________________ 3DKACl2B_________B__________ 2E 3 Cl216.
ABCDE
-
412 mol L 110 mLMnO2Cl20.03 mol____5E______________ 45 Cl2 + 2OH
= Cl + ClO + H2O 16. ABCDE
-
C12Na2CO3(1)A (2)Y A. CC14 BNaCl C DNaHCO3(3)C NaHCO3D C 1NaHC03
2NaHC03 ()HN03BaCl2AgNO3
-
4)CNa2CO30.1molCl2.1C
lcab 2 3
-
1123
-
Na2O2H2OH2O2Na2O2H2OH2O2()_________________________________________________________________MnO2,KMnO4
,KI,Na2S,H2SFeCl2KSCN5 AFe2O3BCuOCNa2SiO3DMgSO4
-
2HCNO
-
3NaClOFeSO4
3mol/LH2SO4,0.01mol/KMnO4,3%H2O2-.
-
*
gcm-320161.197.8*0.9624 155.695*0.9478100.00.9982
-
H2SO4 55600.5h TKK a151155b34.61.83~48.0cdNaCl eMgSO4
-
____________________________________________________
___________________________ cd dNaCl eMgSO4______________ ________
___ _____ _________________
-
1 2221K13d b e c a (2) 11 1 142
-
29111 2
-
2009
-
201010. B2AC17H22N4O6BCO2CNH3D
-
201111ABpHCD
-
12345
-
1---
-NH-O
-
ABCDFED
-
....pKapKa=-lgKa
-COOH-SHH2OpKa3.79.816
-
XC12H13O6Br
-
2010
-
10-2 B
-
ABCXC16H14O41
-
C4H8O275
-
1---=0=1=2 4
-
C20H16N2O5
-
2---321C4H10O2C4H8O2
-
2---CO2
-
1Mannich23
-
E1AA B E
-
20119613-AA9-1ABCA B C
-
ABC
-
,
-
,
-
2912FC16H16O2 3D-COOH4DE 5E6B
