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KIT – University of the State of Baden-Wuerttemberg and National Research Center of the Helmholtz Association INSTITUTE FOR TECHNICAL CHEMISTRY www.kit.edu O VERVIEW OF WASTE INCINERATION TECHNOLOGIES Jürgen Vehlow IEA Bioenergy Workshop ExCo 71 May 21, Cape Town, South Africa www.ieabioenergytask36.org

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Page 1: OVERVIEW OF WASTE …

KIT – University of the State of Baden-Wuerttemberg and National Research Center of the Helmholtz Association

INSTITUTE FOR TECHNICAL CHEMISTRY

www.kit.edu

OVERVIEW OF WASTE INCINERATION

TECHNOLOGIES

Jürgen Vehlow

IEA Bioenergy Workshop ExCo 71

May 21, Cape Town, South Africa

www.ieabioenergytask36.org

Page 2: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

primary goals of thermal waste treatment

inertisation

mass and volume reduction

environmental compatibility

control of pollutants

side conditions

resource recovery

energy (≈ 50 % biogenic) materials (building materials, metals)

Page 3: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

incineration of residual MSW in %

<10 <25 <50 <75 <90 >90

Page 4: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

process chain of thermal waste treatment

thermal process

energy recovery

air pollution control

residue management

Page 5: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

thermal processes

combustion oxygen surplus products: flue gas, ash/slag)

gasification incomplete combustion products: syngas (CO + H2) / slag

pyrolysis oxygen free products: pyrolysis gas, - oil, - coke

Page 6: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

types of combustion furnaces

grate

MSW RDF/SRF biomass

fluidised bed

pretreated MSW RDF/SRF biomass

rotary kiln/post comb.

hazardous waste

Page 7: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

1874 ‘Destructor’ in Nottingham 1875 + London, Manchester, ... 1900 60 plants

first waste incineration plants in the UK

Page 8: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

reciprocating grate

grate types

roller grate reverse acting grate

Page 9: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

combustion chambers

with

different grates

roller grate

reciprocating grate

reverse acting grate

Page 10: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

waste incinerators

F - Chartres I - Brescia

DK - Esbjerg J – Saitama J – Maishima (Osaka)

Page 11: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

fluidised bed

incinerators

bubbling

circulating

revolving

Page 12: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

energy recovery

combustion process

boiler

ener

gy

waste

flue gas

losses

steam generation

(η=75-90%)

steam utilisation / district heating

power production

energy utilisation/ conversion

24 - 30%

60 - 75%

≈ 50% biogenic

CHP >60%

Page 13: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

energy efficient plants

source: J. Martin

Page 14: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

APC (air pollution control)

removal of

dust

acid gases

HCl, HF, SO2

NOx

dioxins

Hg

Page 15: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

dedusting devices

fabric filter

collector plate

collector plate

30 – 100 KV spray-electrode wires

dust-free gas

raw gas

precipitated fly ash

electrostatic precipitator (1 – 10 mg/m3)

raw gas

dust-free gas

filter ash

filter bag

bag cleaning by compressed air jet

compressed air

supporting metal wire cage

fabric filter (<1 mg/m3)

electrostatic precipitator

cleaned gas

ash particles

raw gas

cyclone (50 – 100 mg/m3)

Page 16: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

wet scrubbing with liquid effluents

treatment

filter ash 7 - 15 kg

salts 12 -18 kg

ESP scrubber acid neutral

to sewer

(residue data per Mg of MSW)

Page 17: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

wet scrubbing without liquid effluents

treatment

salts 12 - 18 kg

ESP scrubber acid neutral

filter ash 7 - 15 kg

fabric filter

spray drier

(residue data per Mg of MSW)

Page 18: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

(semi) dry scrubbing

fly ash + salts

+ reagent surplus 30 – 60 kg

fabric filter spray drier

T < 160 °C

Ca(OH)2 / CaCO3

(residue data per Mg of MSW)

Page 19: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

carbon adsorption • fixed or moving bed • entrained flow

oxidation catalyst ad/absorption by polymers

dioxin abatement

NOx abatement

SCR (selective catalytic reduction)

SNCR (selctive non-catalytic reduction

Page 20: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

MSWI Bielefeld (Germany)

source: K. Koch, 10.01.07

13 Kombi-Kat 14 Analytik

15 Kamin

ESP 1 ESP 2

spray dryer (scrubber effluents)

acid / neutral scrubber

DeNOx catalyst

aerosol precipitator

fabric filter

APC

Page 21: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

MSWI Lauta (Germany)

fabric filter

spray dryer district heating turbine

waste pit

grate activated

carbon

APC

Page 22: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

alternatives

to conventional

waste incineration

Page 23: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

one and two stage thermal processes

waste Input

size reduction

pre-

treatment

1st thermal process

grate combustion

fluidised bed combustion

2nd thermal process

gasification

pyrolysis

combustion (chamber)

combustion (chamber)

storage / mixing

Page 24: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

pyrolysis plant Burgau (30,000 tons/a)

CaCO3

cyclone

boiler

Kamin

turbine

waste

combustion chamber

pyrolysis coke

Page 25: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

shaft furnace gasification : Nippon Steel

status: Nippon Steel: 28 plants, 57 lines, 6 400 Mg/d total: 47 plants, 93 lines, 8 400 Mg/d

Page 26: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

fluidised bed gasification : Ebara TIFG/TwinReg

status: 1. pilot 1995 (300 kg/h), 2. pilot 1999 (1 Mg/h), Aomori 2000 12 plants, 21 lines, 3 100 Mg/d

Page 27: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

JFE/NKK Thermoselect

status: 5 plants, 12 lines, 1 725 000 Mg/a

Page 28: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

Mitsui Environmental Systems R21 (lic. Siemens)

status: MES: 7 plants, 15 lines, 1 840 Mg/d Takuma: 4 plants, 7 lines, 518 Mg/d

Page 29: OVERVIEW OF WASTE …

J. Vehlow -- INSTITUTE FOR TECHNICAL CHEMISTRY (2013) www.ieabioenergytask36.org

status of thermal waste treatment

energy recovery becomes a key parameter growing interest in metal recovery alternative processes (Japan ↔ Europe) R&D need for small, efficient, and economic plants for

emerging and developing countries

WtE by waste incineration is in many countries practised as inertising pre-treatment prior to final disposal

meanwhile an environmentally compatible process still opposed in some areas

outlook