longhornaap.comlonghornaap.com/system/assets/AdminRecord/2018/2018...September 29, 2018 Marcia Olive Bhate Environmental Associates, Inc. 445 Union Blvd Ste 129 Lakewood, CO 80228

LONGHORN ARMY AMMUNITION PLANT

KARNACK, TEXAS

ADMINISTRATIVE RECORD

Volume 51

2018

Bate Stamp Numbers 00914507 – 00915174

Prepared for

Department of the Army Longhorn Army Ammunition Plant

1976 – 2018

LONGHORN ARMY AMMUNITION PLANT KARNACK, TEXAS

ADMINISTRATIVE RECORD – CHRONOLOGICAL INDEX

VOLUME 51 2018 A. Title: Report (cont’d) – Quarterly Evaluation Report, 3rd Quarter (July–September) 2018, Groundwater Treatment Plant, Longhorn Army Ammunition Plant, Karnack, Texas, December 2018 Author(s): Bhate Environmental Associates, Inc.

Recipient: U.S. Army Corps of Engineers, Tulsa District Date: December 18, 2018

Bate Stamp: 00914507 – 00915172 B. Title: Transmittal Letter – Draft Remedial Design/Remedial Action Work Plan, LHAAP-17 Burning Ground No. 2 / Flashing Area, Group 2, Longhorn Army Ammunition Plant, Karnack, Texas, December 2018 Author(s): Department of the Army

Recipient: Environmental Protection Agency Date: December 27, 2018 Bate Stamp: 00915173 – 00915173

C. Title: Transmittal Letter – Draft Remedial Design/Remedial Action Work Plan, LHAAP-17 Burning Ground No. 2 / Flashing Area, Group 2, Longhorn Army Ammunition Plant, Karnack, Texas, December 2018 Author(s): Department of the Army

Recipient: Texas Commission on Environmental Quality Date: December 27, 2018 Bate Stamp: 00915174 – 00915174

00914507

September 29, 2018

Marcia OliveBhate Environmental Associates, Inc.445 Union Blvd Ste 129Lakewood, CO 80228

The analytical data provided relates directly to the samples received by ALS Environmental and for only the analyses requested. Results are expressed as "as received" unless otherwise noted.

QC sample results for this data met EPA or laboratory specifications except as noted in the Case Narrative or as noted with qualifiers in the QC batch information. Should this laboratory report need to be reproduced, it should be reproduced in full unless written approval has been obtained by ALS Environmental. Samples will be disposed in 30 days unless storage arrangements are made.

If you have any questions regarding this report, please feel free to call me.

Sincerely,

ALS Environmental received 3 sample(s) on Sep 14, 2018 for the analysis presented in the following report.

Laboratory Results for: Longhorn GW Treatment Plant

Dear Marcia,

Work Order: HS18090657

Project Manager

Generated By: JUMOKE.LAWAL

RJ Modashia

10450 Stancliff Rd. Suite 210 Houston, TX 77099 T: +1 281 530 5656 F: +1 281 530 5887

www.alsglobal.comRight Solutions • Right Partner

1 of 140

00914508

Client: Bhate Environmental Associates, Inc.

Work Order: HS18090657Project: Longhorn GW Treatment Plant SAMPLE SUMMARY

Lab Samp ID Client Sample ID Collection DateMatrix TagNo Date Received Hold

HS18090657-01 13-Sep-2018 14:00 14-Sep-2018 08:46LH18/24-SP650_091318 Water

HS18090657-02 13-Sep-2018 14:00 14-Sep-2018 08:46LH18/24-SP650_091318_AIX Water

HS18090657-03 13-Sep-2018 14:00 14-Sep-2018 08:46LH18/24-SP650_091318_BIX Water

ALS Houston, US 29-Sep-18Date:

2 of 140

00914509

Client: CASE NARRATIVE

Work Order:Longhorn GW Treatment PlantBhate Environmental Associates, Inc.

Project:

Work Order Comments

The analysis for Perchlorate was subcontracted to ALS Salt Lake City, UT. Final report attached.•

Work Order Comments

The analysis for TOC was subcontracted to ALS Environmental in Kelso, WA. Final report attached.•

WetChemistry by Method E365.3

Batch ID: R323999

The test results meet requirements of the current NELAP standards, state requirements or programs where applicable.•


Batch ID: R323597



3 of 140

00914510

Client:Project:Sample ID:

Bhate Environmental Associates, Inc.Longhorn GW Treatment PlantLH18/24-SP650_091318

WorkOrder:Lab ID:

Collection Date:

HS18090657HS18090657-01

13-Sep-2018 14:00 Matrix:Water

ANALYTICAL REPORT

ANALYSES RESULT LOQDILUTION FACTORUNITS

DATE ANALYZEDQUAL DL LOD

AMMONIA AS N BY E350.3(ISE) Method:E350.3 Analyst: MZD10mg/L 18-Sep-2018 10:152.0Nitrogen, Ammonia (As N) 2.089 2.0

ORTHO PHOSPHATE (PO4) AS P BY E365.3

Method:E365.3 Analyst: MZD

50mg/L 14-Sep-2018 12:400.500Phosphorus, Total Orthophosphate (As P)

1.252.80 1.25

SUBCONTRACT ANALYSIS - TOC ANALYSIS

Method:NA Analyst: SUBK

1NA 29-Sep-2018 12:310Subcontract Analysis See Attached 0

29-Sep-18Date: ALS Houston, US

Note: See Qualifiers Page for a list of qualifiers and their explanation.

4 of 140

00914511


Bhate Environmental Associates, Inc.Longhorn GW Treatment PlantLH18/24-SP650_091318_AIX

WorkOrder:Lab ID:

Collection Date:

HS18090657HS18090657-02


ANALYTICAL REPORT



SUBCONTRACT ANALYSIS - PERCHLORATE (EPA 6850)

Method:NA Analyst: SUB




5 of 140

00914512


Bhate Environmental Associates, Inc.Longhorn GW Treatment PlantLH18/24-SP650_091318_BIX

WorkOrder:Lab ID:

Collection Date:

HS18090657HS18090657-03


ANALYTICAL REPORT








6 of 140

00914513

Client:Longhorn GW Treatment PlantBhate Environmental Associates, Inc.

WorkOrder:Project:

HS18090657DATES REPORT

Collection Date Prep Date Analysis DateClient Samp IDSample ID TCLP Date DF

Batch ID R323597 Test Name : AMMONIA AS N BY E350.3(ISE) Matrix: Water

18 Sep 2018 10:15HS18090657-01 13 Sep 2018 14:00 10LH18/24-SP650_091318

Batch ID R323999 Test Name : ORTHO PHOSPHATE (PO4) AS P BY E365.3 Matrix: Water

14 Sep 2018 12:40HS18090657-01 13 Sep 2018 14:00 50LH18/24-SP650_091318

Batch ID R324282 Test Name : SUBCONTRACT ANALYSIS - PERCHLORATE (EPA 6850) Matrix: Water

27 Sep 2018 15:27HS18090657-02 13 Sep 2018 14:00 1LH18/24-SP650_091318_AIX

27 Sep 2018 15:27HS18090657-03 13 Sep 2018 14:00 1LH18/24-SP650_091318_BIX

Batch ID R324421 Test Name : SUBCONTRACT ANALYSIS - TOC ANALYSIS Matrix: Water

29 Sep 2018 12:31HS18090657-01 13 Sep 2018 14:00 1LH18/24-SP650_091318


7 of 140

00914514

Client:Project:

Bhate Environmental Associates, Inc.Longhorn GW Treatment Plant

WorkOrder: HS18090657

QC BATCH REPORT

Batch ID: R323597 Instrument: WetChem_HS Method: E350.3

Sample ID: MBLK-323597 Units: mg/L Analysis Date: 18-Sep-2018 10:15

Run ID: WetChem_HS_323597 SeqNo: 4729933 PrepDate: DF: 1

Analyte SPK ValPQLResultSPK Ref

Value %RECControl

LimitRPD Ref

Value %RPDRPD Limit Qual

MBLK

Client ID:

Nitrogen, Ammonia (As N) 0.20 U0.20

Sample ID: LCS-323597 Units: mg/L Analysis Date: 18-Sep-2018 10:15



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Nitrogen, Ammonia (As N) 10.12 10 0 101 80 - 1200.20

Sample ID: HS18090414-01MS Units: mg/L Analysis Date: 18-Sep-2018 10:15



Value %RECControl

LimitRPD Ref


MS

Client ID:

Nitrogen, Ammonia (As N) 9.491 10 0.4188 90.7 80 - 1200.20

Sample ID: HS18090414-01MSD Units: mg/L Analysis Date: 18-Sep-2018 10:15



Value %RECControl

LimitRPD Ref


MSD

Client ID:

Nitrogen, Ammonia (As N) 9.504 10 0.4188 90.9 80 - 120 9.491 0.137 200.20

The following samples were analyzed in this batch: HS18090657-01

ALS Houston, US Date: 29-Sep-18


8 of 140

00914515

Client:Project:



QC BATCH REPORT

Batch ID: R323999 Instrument: UV-2450 Method: E365.3


Run ID: UV-2450_323999 SeqNo: 4738113 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Phosphorus, Total Orthophosphate (As P)

0.0250 U0.0250




Value %RECControl

LimitRPD Ref


LCS

Client ID:


0.25 0.25 0 100 85 - 1150.0250




Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP650_091318


14.95 12.5 2.8 97.2 80 - 1201.25




Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP650_091318


14.45 12.5 2.8 93.2 80 - 120 14.95 3.4 201.25




9 of 140

00914516

QUALIFIERS, ACRONYMS, UNITS

Client:Project:WorkOrder:

Bhate Environmental Associates, Inc.Longhorn GW Treatment PlantHS18090657

Qualifier Description* Value exceeds Regulatory Limit

a Not accredited

B Analyte detected in the associated Method Blank above the Reporting Limit

E Value above quantitation range

H Analyzed outside of Holding Time

J Analyte detected below quantitation limit

M Manually integrated, see raw data for justification

n Not offered for accreditation

ND Not Detected at the Reporting Limit

O Sample amount is > 4 times amount spiked

P Dual Column results percent difference > 40%

R RPD above laboratory control limit

S Spike Recovery outside laboratory control limits

U Analyzed but not detected above the MDL/SDL

Acronym DescriptionDCS Detectability Check Study

DUP Method Duplicate

LCS Laboratory Control Sample

LCSD Laboratory Control Sample Duplicate

MBLK Method Blank

MDL Method Detection Limit

MQL Method Quantitation Limit

MS Matrix Spike

MSD Matrix Spike Duplicate

PDS Post Digestion Spike

PQL Practical Quantitaion Limit

SD Serial Dilution

SDL Sample Detection Limit

TRRP Texas Risk Reduction Program


10 of 140

00914517

CERTIFICATIONS,ACCREDITATIONS & LICENSES

Agency Number Expire Date

North Carolina 624-2018 31-Dec-2018

Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019

North Dakota R193 2018-2019 30-Apr-2019

Illinois 004438 29-Jun-2019

Louisiana 03087 30-Jun-2019

Dept of Defense ANAB L2231 22-Dec-2018

Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


11 of 140

00914518

RPG

14-Sep-2018 08:46Date/Time Received:

HS18090657

Bhate Environmental

Work Order:

Client Name:

Sample Receipt Checklist

Received by:

Shipping container/cooler in good condition?

Custody seals intact on shipping container/cooler?

Custody seals intact on sample bottles?

Chain of custody present?

Chain of custody signed when relinquished and received?

Chain of custody agrees with sample labels?

Samples in proper container/bottle?

Sample containers intact?

Sufficient sample volume for indicated test?

All samples received within holding time?

Container/Temp Blank temperature in compliance?

Temperature(s)/Thermometer(s):

Cooler(s)/Kit(s):

Date/Time sample(s) sent to storage:

Water - VOA vials have zero headspace?

Water - pH acceptable upon receipt?

pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

0.8C/0.4C UC/C IR # 11432539/14/2018 11:15

Yes No No VOA vials submitted

Yes No N/A

Yes No N/A

Checklist completed by: Pablo MarinezDateeSignatureDateeSignature

14-Sep-201814-Sep-2018

FedEx Priority OvernightWATER Carrier name:Matrices:

Reviewed by: RJ Modashia

Client Contacted: Date Contacted: Person Contacted:

Contacted By: Regarding:

Comments:

Corrective Action:

Yes

NoYesTX1005 solids received in hermetically sealed vials? N/A


12 of 140

00914519

13 o

f 140

00914520

14 o

f 140

00914521

September 28, 2018 Analytical Report for Service Request No: K1808915

RJ ModashiaALS Laboratory Group10450 Stancliff RoadSuite 210Houston, TX 77099-4338

Analyses were performed according to our laboratory’s NELAP-approved quality assurance program. The test results meet requirements of the current NELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP-accredited analytes, refer to the certifications section at www.alsglobal.com. All results are intended to be considered in their entirety, and ALS Group USA Corp. dba ALS Environmental (ALS) is not responsible for use of less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report.

For your reference, these analyses have been assigned our service request numberEnclosed are the results of the sample(s) submitted to our laboratory September 15, 2018

RE: ALS Houston DOD TOC

Dear RJ,

K1808915.

Please contact me if you have any questions. My extension is 3350. You may also contact me via email at [email protected].

Respectfully submitted,

ALS Group USA, Corp. dba ALS Environmental

for Kelley Lovejoy Project Manager

ALS Group USA, Corp1317 South 13th AvenueKelso, WA 98626

+1 360 577 7222+1 360 636 1068

T :F :

ALS Environmental

www.alsglobal.com

RIGHT SOLUTIONS | RIGHT PARTNER15 of 140

00914522

mark.harris

Mark Harris

www.alsglobal.com

ALS Environmental

F :T :

+1 360 636 1068+1 360 577 7222

Kelso, WA 986261317 South 13th AvenueALS Group USA, Corp

Table of Contents

RIGHT SOLUTIONS | RIGHT PARTNER

Acronyms

Qualifiers

State Certifications, Accreditations, And Licenses

Case Narrative

Chain of Custody

General Chemistry

Raw Data

General Chemistry

16 of 140

00914523

ASTM American Society for Testing and Materials

A2LA American Association for Laboratory Accreditation

CARB California Air Resources Board

CAS Number Chemical Abstract Service registry Number

CFC Chlorofluorocarbon

CFU Colony-Forming Unit

DEC Department of Environmental Conservation

DEQ Department of Environmental Quality

DHS Department of Health Services

DOE Department of Ecology

DOH Department of Health

EPA U. S. Environmental Protection Agency

ELAP Environmental Laboratory Accreditation Program

GC Gas Chromatography

GC/MS Gas Chromatography/Mass Spectrometry

LOD Limit of Detection

LOQ Limit of Quantitation

LUFT Leaking Underground Fuel Tank

M ModifiedMCL Maximum Contaminant Level is the highest permissible concentration of a substance

allowed in drinking water as established by the USEPA.


MPN Most Probable Number

MRL Method Reporting Limit

NA Not Applicable

NC Not Calculated

NCASI National Council of the Paper Industry for Air and Stream Improvement

ND Not Detected

NIOSH National Institute for Occupational Safety and Health

PQL Practical Quantitation Limit

RCRA Resource Conservation and Recovery Act

SIM Selected Ion Monitoring

TPH Total Petroleum Hydrocarbonstr Trace level is the concentration of an analyte that is less than the PQL but greater than or

equal to the MDL.

Acronyms

17 of 140

00914524

Inorganic Data Qualifiers* The result is an outlier. See case narrative.

# The control limit criteria is not applicable. See case narrative.

B The analyte was found in the associated method blank at a level that is significant relative to the sample result as defined by the DOD or NELAC standards.

E The result is an estimate amount because the value exceeded the instrument calibration range.

J The result is an estimated value.

U The analyte was analyzed for, but was not detected ("Non-detect") at or above the MRL/MDL. DOD-QSM 4.2 definition : Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection limit is adjusted for dilution.

i The MRL/MDL or LOQ/LOD is elevated due to a matrix interference.

X See case narrative.

Q See case narrative. One or more quality control criteria was outside the limits.

H The holding time for this test is immediately following sample collection. The samples were analyzed as soon as possible afterreceipt by the laboratory.

Metals Data Qualifiers# The control limit criteria is not applicable. See case narrative.


E The percent difference for the serial dilution was greater than 10%, indicating a possible matrix interference in the sample.

M The duplicate injection precision was not met.

N The Matrix Spike sample recovery is not within control limits. See case narrative.

S The reported value was determined by the Method of Standard Additions (MSA).


W The post-digestion spike for furnace AA analysis is out of control limits, while sample absorbance is less than 50% of spike absorbance.



+ The correlation coefficient for the MSA is less than 0.995.


Organic Data Qualifiers* The result is an outlier. See case narrative.


A A tentatively identified compound, a suspected aldol-condensation product.


C The analyte was qualitatively confirmed using GC/MS techniques, pattern recognition, or by comparing to historical data.

D The reported result is from a dilution.

E The result is an estimated value.


N The result is presumptive. The analyte was tentatively identified, but a confirmation analysis was not performed.

P The GC or HPLC confirmation criteria was exceeded. The relative percent difference is greater than 40% between the two analytical results.


i The MRL/MDL or LOQ/LOD is elevated due to a chromatographic interference.



Additional Petroleum Hydrocarbon Specific QualifiersF The chromatographic fingerprint of the sample matches the elution pattern of the calibration standard.

L The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of lighter molecular weight constituents than the calibration standard.

H The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of heavier molecular weight constituents than the calibration standard.

O The chromatographic fingerprint of the sample resembles an oil, but does not match the calibration standard.Y The chromatographic fingerprint of the sample resembles a petroleum product eluting in approximately the correct carbon range,

but the elution pattern does not match the calibration standard.

Z The chromatographic fingerprint does not resemble a petroleum product.

18 of 140

00914525

Agency Web Site Number

Alaska DEH http://dec.alaska.gov/eh/lab/cs/csapproval.htm UST-040

Arizona DHS http://www.azdhs.gov/lab/license/env.htm AZ0339

Arkansas - DEQ http://www.adeq.state.ar.us/techsvs/labcert.htm 88-0637

California DHS (ELAP) http://www.cdph.ca.gov/certlic/labs/Pages/ELAP.aspx 2795

DOD ELAP http://www.denix.osd.mil/edqw/Accreditation/AccreditedLabs.cfm L16-58-R4

Florida DOH http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm E87412

Hawaii DOH http://health.hawaii.gov/ - ISO 17025 http://www.pjlabs.com/ L16-57

Louisiana DEQ http://www.deq.louisiana.gov/page/la-lab-accreditation 03016

Maine DHS http://www.maine.gov/dhhs/ WA01276

Minnesota DOH http://www.health.state.mn.us/accreditation 053-999-457

Nevada DEP http://ndep.nv.gov/bsdw/labservice.htm WA01276

New Jersey DEP http://www.nj.gov/dep/enforcement/oqa.html WA005

New York - DOH https://www.wadsworth.org/regulatory/elap 12060

North Carolina DEQ

https://deq.nc.gov/about/divisions/water-resources/water-resources-data/water-sciences-home-page/laboratory-certification-branch/non-field-lab-certification 605

Oklahoma DEQ http://www.deq.state.ok.us/CSDnew/labcert.htm 9801

Oregon – DEQ (NELAP)http://public.health.oregon.gov/LaboratoryServices/EnvironmentalLaboratoryAccreditation/Pages/index.aspx WA100010

South Carolina DHEC http://www.scdhec.gov/environment/EnvironmentalLabCertification/ 61002

Texas CEQ http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html T104704427

Washington DOE http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html C544

Wyoming (EPA Region 8) https://www.epa.gov/region8-waterops/epa-region-8-certified-drinking-water- -

Kelso Laboratory Website www.alsglobal.com NA

ALS Group USA Corp. dba ALS Environmental (ALS) - KelsoState Certifications, Accreditations, and Licenses

Analyses were performed according to our laboratory’s NELAP-approved quality assurance program. A complete listing of specific NELAP-certified analytes, can be found in the certification section at www.ALSGlobal.com or at the accreditation bodies web site.Please refer to the certification and/or accreditation body's web site if samples are submitted for compliance purposes. The states highlighted above, require the analysis be listed on the state certification if used for compliance purposes and if the method/anlayte is offered by that state.

19 of 140

00914526

Case Narrative

ALS Environmental—Kelso Laboratory 1317 South 13th Avenue, Kelso, WA 98626 Phone (360)577-7222 Fax (360)636-1068 www.alsglobal.com

RIGHT SOLUTIONS | RIGHT PARTNER 20 of 140

00914527

CASE NARRATIVE

Client:Project:Sample Matrix:

Service Request:Date Received:

ALS Environmental - USALS Houston DOD TOCWater

K180891509/15/2018

All analyses were performed consistent with the quality assurance program of ALS Environmental. This report contains analytical results for samples designated for Tier IV validation deliverables including summary forms and all of the associated raw data for each of the analyses. When appropriate to the method, method blank results have been reported with each analytical test.

Sample Receipt:One water sample was received for analysis at ALS Environmental on 09/15/2018. The sample was received in good condition and consistent with the accompanying chain of custody form. The samples were stored in a refrigerator at 4ºC upon receipt at the laboratory.General Chemistry:No significant anomalies were noted with this analysis.

1317 South 13th Ave, Kelso, WA 98626 | 1-360-577-7222 | www.alsglobal.com

Approved by Date 09/28/201821 of 140

00914528

mark.harris

Mark Harris

Chain of Custody



00914529

1. ~t~

kf fJ!S9t'5 10450 Stancliff Rd, Ste 210

Houston, TX 77099

T: + 1 281 530 5656

F: + 1 281 530 5887

www.alsglobal.com

Subcontract Chain of Custody

SUBCONTRACT TO:

ALS Environmental Kelso

1317 S. 13th Avenue

Kelso, WA 98626

CUSTOMER INFORMATION:

Company:

Contact:

Address:

Phone:

Email:

Alternate Contact: Email:

ALS Houston

RJ Modashia

10450 Stancliff Rd, Ste 210

+1 281 530 5656

RJ. Modashia@a lsg lob a I. com

Jumoke M, Lawal

[email protected]

LAB SAMPLE ID CLIENT SAMPLE ID ANALYSIS REQUESTED

1. HS18090657-01 LH18/24-SP650_091318

TOC Analysis for DOD Level IV

Comments: Please analyze for the analysis listed above. Send report to the emails shown above.

QC Level: DOD IV (DoD Data Package)

Relinquished By: ¥?.. G,~ Received By; ~AM!1& !uA1'{/

Cooler ID(s):

COC ID: 9817

Phone: +1 360 501 3312

INVOICE INFORMATION:

Company: ALS Houston

Contact: Accounts Payable

Address: 10450 Stancliff Rd, Ste 210

Phone: + 1 281 530 5656

Reference: HS18090657

TSR: Danielle Winnings

MATRIX

Water

Date/Time:

Date/Time:

Temperature(s):

COLLECT DATE DUE DATE

13 Sep 2018 14:00

24 Sep 2018

q \ 11.,\ I%" I% "15".>

Y1s--1g Of)o

23 of 140

00914530

A rck_L A Cooler Receipt and Preservation Form

Clientl~- ~(c;u.<:,'"',J Serice RequestKJ8 D l/V{ Received: 9-1)-:.1~ Opened: 'f-13>-·//., By: IJS.P Unloaded: f.157/, By: J# I. Samples were received via? USPS ~ UPS

2. Samples were received in: (circle) ~ ~ Box

3. Were custody seals on coolers? NA CI) N

DHL PDX Courier Hand Delivered

Envelope __ NA

If yes, how many and where? ,;;l To/J ~A/{ Otfter ______ --;~

If present, were custody seals intact? (!) N If present, were they signed and dated? G N

Corrected. Raw Corrected Corr. Thermometer Tracking Number \ Raw I CoolerTemp Cooler Tame Temn Blank Temn Blank Factor ID

CooterlCOC (~ NA NA Filed

I

ii

f), /.. c.c:; lf_,) !/ ) f&,J _·v; I 419/\ clc;Z') .

4. Packing material: Inserts "'iiiiJ/d--, Bubble Wrap Gel Packs Cw~Dry Ice Sleeves ~~ --~

5. Were custody papers properly filled out (ink, signed, etc.)?

6. Were samples received in good condition (temperature, unbroken)? Indicate in the table below.

If applicable, tissue samples were received: Frozen Partially Tftawed Tit awed 7. Were all sample labels complete (i.e analysis, preservation, etc.)?

8. Did all sample labels and tags agree with custody papers? Indicate major discrepancies in the table on page 2.

9. Were appropriate bottles/containers and volumes received for the tests indicated?

10. Were the pH-preserved bottles (see SMO GEN SOP) received at the appropriate pH? Indicate in the table below

11. Were VOA vials received without headspace? Indicate in the table below.

12. Was C 12/Res negative?

!

!err

NA

NA

NA

NA

NA

-

(NA ~~' ( '

(~

i Sample ID on Bottle Sample ID on COC Identified by:

I

' '

'

Bottle Count Out of Head- Volume Reagent Lot

6> C!) Q Q QJ y

y

y

I Samele ID Bottle Tvpe Temo soace Broke DH Reaaent added Number Initials

!

I ' l

N

N

N

N

N

N

N

N

Time

Notes, Discrepancies, & Resolutions: _____________________________________ _

7125116 Page __ of __ _ 24 of 140

00914531

General Chemistry



00914532

Client:

09/15/18

K1808915

Date Received:Date Collected:

Service Request:

WaterALS Houston DOD TOCALS Environmental - US

Sample Matrix:Project: 09/13/18

Carbon, Total Organic

Basis:Units: mg/L

NASM 5310 CNonePrep Method:

Analysis Method:

Lab CodeSample Name LODDate

AnalyzedDil.MDLLOQResult Q

LH18/24-SP650_091318 09/27/18 10:445041025935K1808915-001Method Blank 09/27/18 12:2110.070.200.50 UNDK1808915-MB3

Analytical Report


Printed 9/28/2018 4:48:53 PM 18-0000482166 rev 00Superset Reference:26 of 140

00914533

ALS Group USA, Corp.dba ALS Environmental

QA/QC Report

Client:ProjectSample Matrix:

Prep Method:Analysis Method:


SM 5310 CNone

Service Request:Date Collected:Date Received:

Basis:Units:

K180891509/13/1809/15/18

mg/LNA

Replicate Sample SummaryCarbon, Total Organic

Sample Name: Lab Code:Date

AnalyzedRPDLimitLOQMRL MDL RPD

DuplicateResult Average

SampleResult

4 25 4 935 899 917 1010LH18/24-SP650_091318 K1808915-001DUP2 09/27/18

Results flagged with an asterisk (*) indicate values outside control criteria.

Results flagged with a pound (#) indicate the control criteria is not applicable.

Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded.


00914534

QA/QC Report

mg/LK1808915-001 Basis:Lab Code:

Units:Sample Name: LH18/24-SP650_091318

Carbon, Total OrganicMatrix Spike Summary

NA



Service Request:

Date Analyzed:Date Received:

K1808915

09/27/1809/15/18

Date Collected: 09/13/18

NoneSM 5310 C


Analyte Name ResultSample Result Spike Amount % Rec

Matrix SpikeK1808915-001MS2

% Rec Limits


NADate Extracted:

Carbon, Total Organic 935 2210 1250 102 83-117





00914535

QA/QC Report


Units:Sample Name: Batch QC

Carbon, Total OrganicDuplicate Matrix Spike Summary

NA



Service Request:


K1808915

09/27/18N/A

Date Collected: N/A

NoneSM 5310 C


Analyte NameRPD LimitRPDResult

Sample Result

Spike Amount % Rec

Matrix SpikeK1808768-001MS2 K1808768-001DMS2

Duplicate Matrix Spike

% RecSpike

AmountResult% Rec Limits


NADate Extracted:

Carbon, Total Organic 1.95 26.8 25.0 99 27.4 25.0 102 83-117 2 10





00914536

Sample Name

K1808915Date Analyzed:Service Request:

WaterALS Houston DOD TOCALS Environmental - US

Sample Matrix:Project:Client:

Lab Control Sample SummaryCarbon, Total Organic

Analysis Method:Prep Method:

SM 5310 CNone NA

mg/LBasis:Units:

Analysis Lot: 608452

09/27/18

Spike AmountResult % Rec

% Rec Limits

NADate Extracted:

Lab Code

dba ALS EnvironmentalALS Group USA, Corp.

QA/QC Report

Lab Control Sample 83-11797 21.921.2K1808915-LCS3

18-0000482166 rev 00Superset Reference:Printed 9/28/2018 4:49:35 PM

30 of 140

00914537

ALS Group USA, Corp.


QA/QC Report

Continuing Calibration Verification (CCV) Summary

Analysis Lot Lab Code

Date Analyzed

True Value

Measured Value

Percent Recovery Acceptance Limits

Project:ALS Environmental - USALS Houston DOD TOC

Client: Service Request: K1808915

Analysis Method: SM 5310 C mg/LUnits:

dba ALS Environmental

90-1109824.5608452 25.009/27/18 06:44KQ1813712-29CCV190-1109824.5608452 25.009/27/18 11:48KQ1813712-30CCV290-1109824.5608452 25.009/27/18 16:52KQ1813712-31CCV390-1109824.5608452 25.009/27/18 21:26KQ1813712-32CCV490-1109724.2608452 25.009/28/18 04:19KQ1813712-33CCV5

18-0000482166 rev 00Printed 9/28/2018 4:49:47 PM Superset Reference:

31 of 140

00914538


SM 5310 C


Client:Project:

ALS Environmental - US Service Request:K1808915

QA/QC Report

mg/L

ALS Houston DOD TOC

Analysis Method:

Continuing Calibration Blank (CCB) Summary

Units:


Date Analyzed LOQ LOD MDL QResult


CCB1 KQ1813712-34 09/27/18 07:00 0.50608452 0.20 0.07 UNDCCB2 KQ1813712-35 09/27/18 12:04 0.50608452 0.20 0.07 UNDCCB3 KQ1813712-36 09/27/18 17:09 0.50608452 0.20 0.07 UNDCCB4 KQ1813712-37 09/27/18 21:43 0.50608452 0.20 0.07 UNDCCB5 KQ1813712-38 09/28/18 04:35 0.50608452 0.20 0.07 UND


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00914539

Raw Data



00914540

General Chemistry



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00914618

Case Narrative

Method: 6850 Analysis: Perchlorate Analysis SOP: LC-MS-CLO4 ALS WO ID(s): 1826185; 1826186; 1826197; 1826550

Client: ALS Laboratories (Houston, TX) Matrix: Water ELMS Batch (HBN): 2144 (223442)

General Set Information: There were five field samples in these Work Orders. The samples were analyzed for perchlorate.

Method Summary: Each sample was prepared as noted below and analyzed using an Agilent 1100 LC/MSD system in select ion monitoring (SIM) mode at m/z 83 and 85, which corresponds to the loss of one oxygen atom from the perchlorate molecule. ChemStation software was used for instrument control and data analysis. The ion ratio of m/z 83 to 85 was used to positively identify the response peak as perchlorate. Quantitation was performed using the m/z 83 peak area. An internal standard (ISTD) of 18O labeled perchlorate was added to each sample to establish the perchlorate peak retention time and used in quantitation.

Sample Preparation: A 10.0mL aliquot of each sample was transferred into a 15-mL centrifuge tube. 50µL of an 18O labeled perchlorate solution was added to each sample as an internal standard. The samples were then capped, vortexed, and filtered into autosampler vial using Phenex PES membrane 0.45µm Syringe filters.

Holding Times: Holding times were met for all analyses.

Dilutions: Sample 1826197001 was analyzed and reported from a 1:1,000 dilution. Samples 1826185001, 1826186001/02 and 1826550001 failed the 50-150% method requirement for ISTD recovery. The samples were re-analyzed and reported from 1:10 dilutions. The reporting limits have been adjusted accordingly.

Method QC data: The method blank (LMB 620036) was less than 1/2 the CRDL. The recovery for the LCS (620037) was within acceptable parameters.

112 of 140

00914619

MS/MSD Analysis: MS/MSD was performed on sample 1826185001 (Client ID: LH18/24-SP650_091318_AIX). 5.0µl of Working Standard Solution Horizon ID 41828 was added to 10.0mL of sample preparation. The parent sample and the MS/MSD were analyzed at 1:10 dilutions. The effective spike target was 50.µg/L. The percent recoveries and relative percent difference (RPD) were within the performance limits. Instrument QC: Instrument initial and continuing calibrations were performed in accordance with published procedures. NC/CAR(s): NA Sample Calculation: Samples were reported in µg/L. Results were calculated in µg/L by the equation (A)x(B),

where: A = Analyte concentration from the standard curve (µg/L) B = Dilution performed at time of analysis Miscellaneous Comments: These samples were analyzed in accordance with the requirements found in the DOD QSM Version 5.1. Due to limitations of the Chemstation Software, some of the chromatographic peaks require manual integration. A manual integration was performed for datafile 26SEPPD03.

Thomas Bosch September 27, 2018 Analyst Date

113 of 140

00914620

ANALYTICAL REPORT

RJ ModashiaALS Environmental (Houston)10450 Stancliff RoadSuite 210Houston, TX 77099

Phone:

E-mail:

281 530-5656

[email protected]

Report Date: September 27, 2018

34-1826186Workorder:

HS18090657 091318HS18090657Purchase Order:

Project ID:

Project Manager Kevin W. Griffiths

Sampling SiteReceive DateCollect DateLab IDClient Sample ID

1826186001 09/13/18LH18/24-SP650_091318_AIX 09/18/18

1826186002 09/13/18LH18/24-SP650_091318_BIX 09/18/18

Page 1 of 3 Thu, 09/27/18 1:36 PM ENVREP-V4.8

ADDRESS 960 West LeVoy Drive, Salt Lake City, Utah, 84123 USA PHONE FAX+1 801 266 7700 +1 801 268 9992

ALS GROUP USA, CORP. An ALS Limited Company

||

114 of 140

00914621

ANALYTICAL REPORT

Project Manager: Kevin W. Griffiths

Client: ALS Environmental(Houston)

Workorder: 34-1826186

Analytical Results

Sample ID: 09/13/201809/18/20181826186001Lab ID:

Collected:Received:

LH18/24-SP650_091318_AIX NA

Sampling Parameter: NAMatrix:

Media:

Water

125 mL NalgeneSampling Site:

Analysis: EPA 6850, DoD QSM Water

Analyzed: 09/26/2018 12:32Batch:

Instrument ID:ELMS/2144 (HBN: 223442) Percent Solid: NA

LCMS04

Report Basis: Wet

Preparation: Not Applicable

Result (ug/L)Analyte DL (ug/L) LOD (ug/L) QualLOQ (ug/L) Dilution

Analysis Method - EPA 6850, DoD QSM

4010ND 20 UPerchlorate 10

Sample ID: 09/13/201809/18/20181826186002Lab ID:

Collected:Received:

LH18/24-SP650_091318_BIX NA


Media:

Water





LCMS04

Report Basis: Wet





Report Authorization

Analyst Peer ReviewMethod

(/S/ is an electronic signature that complies with 21 CFR Part 11)

EPA 6850, DoD QSM /S/ Thomas Bosch09/27/2018 10:32 09/27/2018 13:01

/S/ Stephen Brose

Laboratory Contact Information(801) [email protected]

ALS Environmental960 W Levoy DriveSalt Lake City, Utah 84123

Phone:Email:Web:


115 of 140

00914622

ANALYTICAL REPORT




The results provided in this report relate only to the items tested.Samples were received in acceptable condition unless otherwise noted.Samples have not been blank corrected unless otherwise noted.This test report shall not be reproduced, except in full, without written approval of ALS.

General Lab Comments

ALS provides professional analytical services for all samples submitted. ALS is not in a position to interpret the data andassumes no responsibility for the quality of the samples submitted.

All quality control samples processed with the samples in this report yielded acceptable results unless otherwise noted.

ALS is accredited for specific fields of testing (scopes) in the following testing sectors. The quality system implemented at ALSconforms to accreditation requirements and is applied to all analytical testing performed by ALS. The following table lists testingsector, accreditation body, accreditation number and website. Please contact these accrediting bodies or your ALS projectmanager for the current scope of accreditation that applies to your analytical testing.

Testing Sector Accreditation Body Certificate Number

Website

Environmental PJLA (DoD ELAP)

Utah (TNI)NevadaOklahomaIowa

MDL = Method Detection Limit, a statistical estimate of method/media/instrument sensitivity.RL = Reporting Limit, a verified value of method/media/instrument sensitivity.CRDL = Contract Required Detection LimitReg. Limit = Regulatory Limit.ND = Not Detected, testing result not detected above the MDL or RL.< This testing result is less than the numerical value.** No result could be reported, see sample comments for details.

U = Qualifier indicates that the analyte was not detected above the MDL.J = Qualifier Indicates that the analyte value is between the MDL and the RL. It is also used to indicate an estimated value fortentatively identified compounds in mass spectrometry where a 1:1 response is assumed.B = Qualifier indicates that the analyte was detected in the blank.E = Qualifier indicates that the analyte result exceeds calibration range.P = Qualifier indicates that the RPD between the two columns is greater than 40%.

Result Symbol Definitions

Qualifier Symbol Definitions


116 of 140

00914623

Analysis:

Analyzed By:ELMS/2144 (HBN: 223442)Thomas Bosch

Workorder: 1826186

EPA 6850, DoD QSMBatch: NA

Prepared By: NABatch:

Preparation: NAClient SOW/Contract SpecifiedDoD QSM

Limits:Basis:

Analysis Information

Blank

LMB:

Analyte

Units:

Result

Analyzed:62003609/26/2018 08:52

ug/L

MDL RL

Perchlorate 1 2.00ND

Laboratory Control Sample

Dilution: 1ug/L

Analyte Result % Rec QC Limits

LCS:Analyzed:

62003709/26/2018 09:06

Units:

Target

Perchlorate 5.06 5.00 78.8 123.8101

Matrix Spike - Matrix Spike Duplicate

MS:Analyzed:

Dilution:Units: ug/L

1009/26/2018 12:03620038Sample:

Analyzed:Dilution:

Units: ug/L1009/26/2018 11:481826185001

Result RPD QC Limits

MSD:Analyzed:

62003909/26/2018 12:18

% Rec

Units: ug/LDilution: 10

Analyte Result Result % RecTarget QC Limits

Perchlorate ND 78.8 123.850 94.247.1 20.00.046.8 0.55893.7

Continuing Calibration Verification

Analyte Result % Rec.

CCV:Analyzed:

62003309/26/2018 08:09

Units:

Target

ug/LCriteria: ± 15%

Result % Rec.

CCV:Analyzed:

62004009/26/2018 11:17

Units:

Target


Result % Rec.

CCV:Analyzed:

62018909/26/2018 13:14

Units:

Target


Perchlorate 25.0 25.0 100 24.0 25.0 96.1 24.1 25.0 96.6

Interference Check Sample


ICSA:Analyzed:

62003509/26/2018 08:38

Units:

Target


Perchlorate 0.731 1.00 73.1

Limit of Detection Verification


LODV:Analyzed:

62003409/26/2018 08:24

Units:

Target


Result % Rec.

LODV:Analyzed:

62004109/26/2018 11:31

Units:

Target


Result % Rec.

LODV:Analyzed:

62019009/26/2018 13:29

Units:

Target


Perchlorate 1.17 1.00 117 1.19 1.00 119 1.19 1.00 119

Page 1 of 2 Thursday, September 27, 2018

Quality Control SampleBatch Report

QCS V4.4117 of 140

00914624

Analysis:


Workorder: 1826186




Limits:Basis:


QC Report Authorization (/S/ is an electronic signature that complies with 21 CFR Part 11)

- Sample result is greater than 4 times the spike added- Analyte above reporting limit or outside of control limits

Symbols and DefinitionsRPD - Relative % Difference (Spike / Spike Duplicate)ND - Not Detected (U - Qualifier also flags analyte as not detected)

QC results are not adjusted for moisture correction, where applicable- Sample and Matrix Duplicate less than 5 times the reporting limit NA - Not Applicable- Result is above the calibration range

The Matrix Spike, Matrix Spike duplicate or Matrix Duplicate isreported for your information only. The sample matrix may beinappropriate for the method selected.

# -

Analyst Peer Review

/S/ Thomas Bosch /S/ Stephen Brose

09/27/2018 10:32 09/27/2018 13:01



QCS V4.4118 of 140

00914625

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00914647

September 28, 2018





Sincerely,



Dear Marcia,


Project Manager


RJ Modashia



1 of 43

00914648






2 of 43

00914649



Project:

Work Order Comments


Metals by Method SW6020

Batch ID: 132542


WetChemistry by Method SW7196

Batch ID: R323660Sample ID: LH18/24-SP140_091318 (HS18090658-01)

Sample Filtered•


3 of 43

00914650



WorkOrder:Lab ID:

Collection Date:

HS18090658HS18090658-01


ANALYTICAL REPORT



ICP-MS METALS BY SW6020A Method:SW6020 Analyst: JDEPrep:SW3010A / 18-Sep-2018

1mg/L 28-Sep-2018 12:33J 0.00110Selenium 0.002000.00126 0.002001mg/L 28-Sep-2018 12:33U 0.000200Silver 0.002000.00100 0.00100

HEXAVALENT CHROMIUM BY SW7196A Method:SW7196 Analyst: KVLPrep:SW7196

5mg/L 14-Sep-2018 12:30U 0.0300Chromium, Hexavalent 0.05000.0500 0.0500SUBCONTRACT ANALYSIS - PERCHLORATE (EPA 6850)





4 of 43

00914651

WEIGHT LOG

HS18090658Longhorn GW Treatment PlantBhate Environmental Associates, Inc.

WorkOrder:Project:Client:

Batch ID: 132542 Method: ICP-MS METALS BY SW6020A 3010APrep:

ContainerSampIDSample Wt/Vol

Final Volume

Prep Factor

HS18090658-01 1 10 10 (mL) 1


5 of 43

00914652


WorkOrder:Project:



Batch ID 132542 Test Name : ICP-MS METALS BY SW6020A Matrix: Water

18 Sep 2018 13:00 28 Sep 2018 12:33HS18090658-01 13 Sep 2018 14:00 1LH18/24-SP140_091318

Batch ID R323660 Test Name : HEXAVALENT CHROMIUM BY SW7196A Matrix: Water

14 Sep 2018 12:30HS18090658-01 13 Sep 2018 14:00 5LH18/24-SP140_091318


27 Sep 2018 15:27HS18090658-01 13 Sep 2018 14:00 1LH18/24-SP140_091318


6 of 43

00914653

Client:Project:



QC BATCH REPORT

Batch ID: 132542 Instrument: ICPMS05 Method: SW6020


Run ID: ICPMS05_324340 SeqNo: 4746838 PrepDate: 18-Sep-2018 DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Selenium 0.00200 U0.00200

Silver 0.00100 U0.00200




Value %RECControl

LimitRPD Ref


LCS

Client ID:

Selenium 0.04975 0.05 0 99.5 80 - 1200.00200

Silver 0.0497 0.05 0 99.4 80 - 1200.00200




Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP140_091318

Selenium 0.05094 0.05 0.001256 99.4 80 - 1200.00200

Silver 0.04744 0.05 0.000026 94.8 80 - 1200.00200




Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP140_091318

Selenium 0.05233 0.05 0.001256 102 80 - 120 0.05094 2.7 200.00200

Silver 0.04631 0.05 0.000026 92.6 80 - 120 0.04744 2.41 200.00200

Sample ID: HS18090658-01PDS Units: mg/L Analysis Date: 28-Sep-2018 12:41



Value %RECControl

LimitRPD Ref


PDS

Client ID: LH18/24-SP140_091318

Selenium 0.1132 0.1 0.001256 112 75 - 1250.00200

Silver 0.1014 0.1 0.000026 101 75 - 1250.00200



7 of 43

00914654

Client:Project:



QC BATCH REPORT


Sample ID: HS18090658-01SD Units: mg/L Analysis Date: 28-Sep-2018 12:35



Value %RECControl

LimitRPD Ref

Value %D%D Limit Qual

SD

Client ID: LH18/24-SP140_091318

Selenium 0.0100 0.001256 0 10 U0.0100

Silver 0.00500 0.000026 0 10 U0.0100




8 of 43

00914655

Client:Project:



QC BATCH REPORT

Batch ID: R323660 Instrument: UV-2450 Method: SW7196

Sample ID: MBLK-R323660 Units: mg/L Analysis Date: 14-Sep-2018 12:30



Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Chromium, Hexavalent 0.0100 U0.0100

Sample ID: LCS-R323660 Units: mg/L Analysis Date: 14-Sep-2018 12:30



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Chromium, Hexavalent 0.249 0.25 0 99.6 80 - 1200.0100




Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP140_091318

Chromium, Hexavalent 1.19 1.25 0 95.2 75 - 1250.0500




Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP140_091318

Chromium, Hexavalent 1.195 1.25 0 95.6 75 - 125 1.19 0.419 200.0500




9 of 43

00914656





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




10 of 43

00914657




Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


11 of 43

00914658

RPG


HS18090658

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

0.8C/0.4C UC/C IR # 11432539/14/2018 11:15


Yes No N/A

Yes No N/A


14-Sep-201814-Sep-2018





Comments:

Corrective Action:

Yes



12 of 43

00914659

13 o

f 43

00914660

14 o

f 43

00914661

Case Narrative Method: 6850 Analysis: Perchlorate Analysis SOP: LC-MS-CLO4 ALS WO ID(s): 1826185; 1826186; 1826197; 1826550


General Set Information: There were five field samples in these Work Orders. The samples were analyzed for perchlorate. Method Summary: Each sample was prepared as noted below and analyzed using an Agilent 1100 LC/MSD system in select ion monitoring (SIM) mode at m/z 83 and 85, which corresponds to the loss of one oxygen atom from the perchlorate molecule. ChemStation software was used for instrument control and data analysis. The ion ratio of m/z 83 to 85 was used to positively identify the response peak as perchlorate. Quantitation was performed using the m/z 83 peak area. An internal standard (ISTD) of 18O labeled perchlorate was added to each sample to establish the perchlorate peak retention time and used in quantitation. Sample Preparation: A 10.0mL aliquot of each sample was transferred into a 15-mL centrifuge tube. 50µL of an 18O labeled perchlorate solution was added to each sample as an internal standard. The samples were then capped, vortexed, and filtered into autosampler vial using Phenex PES membrane 0.45µm Syringe filters. Holding Times: Holding times were met for all analyses. Dilutions: Sample 1826197001 was analyzed and reported from a 1:1,000 dilution. Samples 1826185001, 1826186001/02 and 1826550001 failed the 50-150% method requirement for ISTD recovery. The samples were re-analyzed and reported from 1:10 dilutions. The reporting limits have been adjusted accordingly. Method QC data: The method blank (LMB 620036) was less than 1/2 the CRDL. The recovery for the LCS (620037) was within acceptable parameters.

15 of 43

00914662




16 of 43

00914663

ANALYTICAL REPORT


Phone:

E-mail:

281 530-5656

[email protected]




Project ID:



1826197001 09/13/18LH18/24-SP140_091318 09/18/18




||

17 of 43

00914664

ANALYTICAL REPORT




Analytical Results

Sample ID: 09/13/201809/18/20181826197001Lab ID:

Collected:Received:

LH18/24-SP140_091318 NA


Media:

Water





LCMS04

Report Basis: Wet




400010007100 2000Perchlorate 1000





/S/ Stephen Brose



Phone:Email:Web:


18 of 43

00914665

ANALYTICAL REPORT










Website








19 of 43

00914666

Analysis:


Workorder: 1826197




Limits:Basis:


Blank

LMB:

Analyte

Units:

Result

Analyzed:62003609/26/2018 08:52

ug/L

MDL RL



Dilution: 1ug/L


LCS:Analyzed:

62003709/26/2018 09:06

Units:

Target

Perchlorate 5.06 5.00 78.8 123.8101


MS:Analyzed:


1009/26/2018 12:03620038Sample:

Analyzed:Dilution:

Units: ug/L1009/26/2018 11:481826185001


MSD:Analyzed:

62003909/26/2018 12:18

% Rec



Perchlorate ND 78.8 123.850 94.247.1 20.00.046.8 0.55893.7



CCV:Analyzed:

62003309/26/2018 08:09

Units:

Target


Result % Rec.

CCV:Analyzed:

62004009/26/2018 11:17

Units:

Target


Result % Rec.

CCV:Analyzed:

62018909/26/2018 13:14

Units:

Target


Perchlorate 25.0 25.0 100 24.0 25.0 96.1 24.1 25.0 96.6



ICSA:Analyzed:

62003509/26/2018 08:38

Units:

Target





LODV:Analyzed:

62003409/26/2018 08:24

Units:

Target


Result % Rec.

LODV:Analyzed:

62004109/26/2018 11:31

Units:

Target


Result % Rec.

LODV:Analyzed:

62019009/26/2018 13:29

Units:

Target


Perchlorate 1.17 1.00 117 1.19 1.00 119 1.19 1.00 119



QCS V4.420 of 43

00914667

Analysis:


Workorder: 1826197




Limits:Basis:







# -

Analyst Peer Review


09/27/2018 10:32 09/27/2018 13:01



QCS V4.421 of 43

00914668

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00914670

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00914671

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00914687

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00914689

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00914690

October 15, 2018





Sincerely,



Dear Marcia,


Project Manager

Generated By: DAYNA.FISHER

RJ Modashia



00914691






HS18091005-03 19-Sep-2018 14:00 20-Sep-2018 08:45LH18/24-SP650_091918_AIX Water

ALS Houston, US 15-Oct-18Date:

00914692



Project:HS18091005

Work Order Comments


The analysis for TOC was subcontracted to ALS Environmental in Kelso, WA. Final report attached.•


Batch ID: R324075



Batch ID: R324061



00914693



WorkOrder:Lab ID:

Collection Date:

HS18091005HS18091005-01


ANALYTICAL REPORT



AMMONIA AS N BY E350.3(ISE) Method:E350.3 Analyst: MZD1mg/L 25-Sep-2018 10:450.20Nitrogen, Ammonia (As N) 0.2027 0.20



1NA 13-Oct-2018 09:240Subcontract Analysis See Attached 0

15-Oct-18Date: ALS Houston, US


00914694



WorkOrder:Lab ID:

Collection Date:

HS18091005HS18091005-02


ANALYTICAL REPORT






0.2501.94 0.250



00914695


Bhate Environmental Associates, Inc.Longhorn GW Treatment PlantLH18/24-SP650_091918_AIX

WorkOrder:Lab ID:

Collection Date:

HS18091005HS18091005-03


ANALYTICAL REPORT








00914696


WorkOrder:Project:




25 Sep 2018 10:45HS18091005-01 19 Sep 2018 14:00 1LH18/24-SP650_091918


20 Sep 2018 15:09HS18091005-02 19 Sep 2018 14:00 10LH18/24-SP650_091918


27 Sep 2018 15:27HS18091005-03 19 Sep 2018 14:00 1LH18/24-SP650_091918_AIX


13 Oct 2018 09:24HS18091005-01 19 Sep 2018 14:00 1LH18/24-SP650_091918


00914697

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:





Value %RECControl

LimitRPD Ref


LCS

Client ID:

Nitrogen, Ammonia (As N) 9.981 10 0 99.8 80 - 1200.20




Value %RECControl

LimitRPD Ref


MS

Client ID:





Value %RECControl

LimitRPD Ref


MSD

Client ID:



ALS Houston, US Date: 15-Oct-18

00914698

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:


0.0250 U0.0250




Value %RECControl

LimitRPD Ref


LCS

Client ID:


0.236 0.25 0 94.4 85 - 1150.0250




Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP650_091918


4.25 2.5 1.94 92.4 80 - 1200.250




Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP650_091918


4.27 2.5 1.94 93.2 80 - 120 4.25 0.469 200.250



00914699





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




00914700




Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


00914701

JRM


HS18091005

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

2.2c/1.8c uc/c IR 114423509/20/2018 11:55


Yes No N/A

Yes No N/A

Checklist completed by: Raegen GigaDateeSignatureDateeSignature

20-Sep-2018

FedEx Priority Overnightwater Carrier name:Matrices:

Reviewed by:



Comments:

Corrective Action:

Yes



00914702

00914703

00914704

Case Narrative Method: 6850 Analysis: Perchlorate Analysis SOP: LC-MS-CLO4 ALS WO ID(s): 1826185; 1826186; 1826197; 1826550


General Set Information: There were five field samples in these Work Orders. The samples were analyzed for perchlorate. Method Summary: Each sample was prepared as noted below and analyzed using an Agilent 1100 LC/MSD system in select ion monitoring (SIM) mode at m/z 83 and 85, which corresponds to the loss of one oxygen atom from the perchlorate molecule. ChemStation software was used for instrument control and data analysis. The ion ratio of m/z 83 to 85 was used to positively identify the response peak as perchlorate. Quantitation was performed using the m/z 83 peak area. An internal standard (ISTD) of 18O labeled perchlorate was added to each sample to establish the perchlorate peak retention time and used in quantitation. Sample Preparation: A 10.0mL aliquot of each sample was transferred into a 15-mL centrifuge tube. 50µL of an 18O labeled perchlorate solution was added to each sample as an internal standard. The samples were then capped, vortexed, and filtered into autosampler vial using Phenex PES membrane 0.45µm Syringe filters. Holding Times: Holding times were met for all analyses. Dilutions: Sample 1826197001 was analyzed and reported from a 1:1,000 dilution. Samples 1826185001, 1826186001/02 and 1826550001 failed the 50-150% method requirement for ISTD recovery. The samples were re-analyzed and reported from 1:10 dilutions. The reporting limits have been adjusted accordingly. Method QC data: The method blank (LMB 620036) was less than 1/2 the CRDL. The recovery for the LCS (620037) was within acceptable parameters.

00914705




00914706

ANALYTICAL REPORT


Phone:

E-mail:

281 530-5656

[email protected]




Project ID:



1826550001 09/19/18LH18/24-SP650_091918_AIX 09/21/18




||

00914707

ANALYTICAL REPORT




Analytical Results

Sample ID: 09/19/201809/21/20181826550001Lab ID:

Collected:Received:

LH18/24-SP650_091918_AIX NA


Media:

Water





LCMS04

Report Basis: Wet









/S/ Stephen Brose



Phone:Email:Web:


00914708

ANALYTICAL REPORT










Website








00914709

Analysis:


Workorder: 1826550




Limits:Basis:


Blank

LMB:

Analyte

Units:

Result

Analyzed:62003609/26/2018 08:52

ug/L

MDL RL



Dilution: 1ug/L


LCS:Analyzed:

62003709/26/2018 09:06

Units:

Target

Perchlorate 5.06 5.00 78.8 123.8101


MS:Analyzed:


1009/26/2018 12:03620038Sample:

Analyzed:Dilution:

Units: ug/L1009/26/2018 11:481826185001


MSD:Analyzed:

62003909/26/2018 12:18

% Rec



Perchlorate ND 78.8 123.850 94.247.1 20.00.046.8 0.55893.7



CCV:Analyzed:

62003309/26/2018 08:09

Units:

Target


Result % Rec.

CCV:Analyzed:

62004009/26/2018 11:17

Units:

Target


Result % Rec.

CCV:Analyzed:

62018909/26/2018 13:14

Units:

Target


Perchlorate 25.0 25.0 100 24.0 25.0 96.1 24.1 25.0 96.6



ICSA:Analyzed:

62003509/26/2018 08:38

Units:

Target





LODV:Analyzed:

62003409/26/2018 08:24

Units:

Target


Result % Rec.

LODV:Analyzed:

62004109/26/2018 11:31

Units:

Target


Result % Rec.

LODV:Analyzed:

62019009/26/2018 13:29

Units:

Target


Perchlorate 1.17 1.00 117 1.19 1.00 119 1.19 1.00 119



QCS V4.4

00914710

Analysis:


Workorder: 1826550




Limits:Basis:







# -

Analyst Peer Review


09/27/2018 10:32 09/27/2018 13:01



QCS V4.4

00914711

00914712

00914713

00914714

00914715

00914716

00914717

00914718

00914719

00914720

00914721

00914722

00914723

00914724

00914725

00914726

00914727

00914728

00914729

00914730

00914731

00914732

00914733

October 12, 2018 Analytical Report for Service Request No: K1809166



For your reference, these analyses have been assigned our service request numberEnclosed are the results of the sample(s) submitted to our laboratory September 21, 2018

RE: ALS Houston DOD TOC / HS18091005

Dear RJ,

K1809166.




Kelley LovejoyProject Manager


+1 360 577 7222+1 360 636 1068

T :F :

ALS Environmental

www.alsglobal.com

RIGHT SOLUTIONS | RIGHT PARTNERPage 1 of 40

00914734

kelley.lovejoy

Kelley Lovejoy

www.alsglobal.com

ALS Environmental

F :T :

+1 360 636 1068+1 360 577 7222


Table of Contents


Acronyms

Qualifiers


Case Narrative

Chain of Custody

General Chemistry

Raw Data

General Chemistry

Page 2 of 40

00914735
























NA Not Applicable

NC Not Calculated


ND Not Detected






equal to the MDL.

Acronyms

Page 3 of 40

00914736











































Page 4 of 40

00914737















North Carolina DEQ











Page 5 of 40

00914738

Case Narrative



Page 6 of 40

00914739

CASE NARRATIVE

Client:

Project:

Sample Matrix:

Service Request:

Date Received:

ALS Environmental - US

ALS Houston DOD TOC

Water

K1809166

09/21/2018


Sample Receipt:

One water sample was received for analysis at ALS Environmental on 09/21/2018. The sample was received in good condition and consistent with the accompanying chain of custody form. The sample was stored in a refrigerator at 4ºC upon receipt at the laboratory.General Chemistry:

No significant anomalies were noted with this analysis.


Approved by Date 10/12/2018

Page 7 of 40

00914740

kelley.lovejoy

Kelley Lovejoy

Chain of Custody



Page 8 of 40

00914741

.. ~-=-"""'==-"-'"'

A 10450 Stancliff Rd, Ste 210

Houston, TX 77099

T: +1 281 530 5656

F: +1 281 530 5887

www.alsglobal.com


SUBCONTRACT TO:


1317 S. 13th Avenue

Kelso, WA 98626


Company:

Contact:

Address:

Phone:

Email:


ALS Houston

RJ Modashia


+1 281 530 5656

[email protected]

Jumoke M. Lawal

[email protected]

LAB SAf'-IP.~E.lp .• S~E~T ~P,'.'JP!.E lD •ANALYSIS ~q!iJES'.l;EJ:) ..

1. HS18091005-01 LH18/24-SP650_091918


Comments: Please analyze for the analysis listed above. Send report to the emails shown above.


Relinquished By: 1

=:f, ~~

Received sy: .f<n7c 1· V Ob< Prl;? Cooler ID(s):

COC ID: 9866

Phone: +1 360 501 3312





Phone: + 1 281 530 5656



Water

Date/Time:

Date(Time:

T em perature{s);

.COLLECT DATE :.D.\'.leo.A.te

19 Sep 2018 14:00

28 Sep 2018

"1/UJ//t I )?:CYQ

c)rid r? (o;,l)

~ l 98e:r l '7~

Page 9 of 40

00914742

A PC£ Cooler Receipt and Preservation Form

Client . BL'>· ti01A STDY\ , ~iceRequestKJBo~f~~ / g{J]jq Opened: @i /2-c / {<? By: ~ Unloaded: C['ij/ Y sfJ{~ ~· Received: If o<-1 1 1 x

I. Samples were received via? USPS ~ UPS DHl PDX, Courier Hand Delivered

2. Samples were received in: (circle) e _\Box

Were custody seals on coolers? NA {v. ) N

If present, were custody ·seals intact? ~ N

Envelope Otlter NA

If yes, how many and where? ,?:, -ffI)'<\ .-f=."'--lfpresent, were they signed and dated? 6) N

3.

i Raw Corrected. Raw1_v.:1 J\~'.'.'.'."~)£

Corr. Thermometer Cooler/COC ID ' Cooler Temp Cooler Te- 7,---91 ;._ Factor ID NA

l:n , ·o- Oc ( I\\ I Ll < \ ,, +o ( l :=zs i C1\fl n L" 4:SxD i l'l.1 ., 'v '

I

I .---.,,,-,.,.--. -,

4. Packing material: Inserts Baggies .~ Gel Packs ~~Dry Ice Sleeves

5. Were custody papers properly filled out (ink, signed, etc.)?

6. Were samples received in good condition (temperature, unbroken)? Indicate in tlte bble below. If applicable, tissue samples were received: Frozen Partially Thawed

7. Were all sample labels complete (i.e analysis, preservation, etc.)?

Tracking Number • NA

C-1 ") ?"2- 7q;,:;:<i

Thawed

.

NA CY:)

NA Ct)

Flied

N

N


NALJ)

NA 8/) N

N

N

N

N

NA Y'

~?~: ~ y : : '

~. Were appropriate bottles/containers and volumes received for the tests indicated?



·-II

Samole ID on Bottle Samole ID on COC lde.ntified tw:

Bottle Count Out of Head- Volume Reagent Lot Sample ID Bottle Tvpe Terrio space Broke pH Reaaent added Number Initials Time

Votes, Discrepancies, & Resolutions: _____________________________________ _

7125116 Page __ oj __ _

Page 10 of 40

00914743

General Chemistry



Page 11 of 40

00914744

Client:

09/21/18

K1809166


Service Request:

WaterALS Houston DOD TOC/HS18091005ALS Environmental - US



Basis:Units: mg/L


Analysis Method:



LH18/24-SP650_091918 10/10/18 08:522502050130370K1809166-001Method Blank 10/10/18 04:3410.070.200.50 UNDK1809166-MB

Analytical Report


Printed 10/12/18 2:08:31 PM 18-0000483690 rev 00Superset Reference:

Page 12 of 40

00914745


QA/QC Report

Client:ProjectSample Matrix: Water

ALS Houston DOD TOC/HS18091005ALS Environmental - US Service Request: K1809166

09/19/18Date Collected:Date Received: 09/21/18

10/10/18Date Analyzed:

Replicate Sample SummaryGeneral Chemistry Parameters

LH18/24-SP650_091918 mg/LBasis:Units:

K1809166-001 NALab Code:Sample Name:

RPD LimitLODLOQ MDLAnalysis Method RPD

Duplicate Sample

K1809166-001DUP Result Average

SampleResultAnalyte Name


Carbon, Total Organic 3 130 20 370 360 364 1050SM 5310 C





Page 13 of 40

00914746

QA/QC Report


Units:Sample Name: LH18/24-SP650_091918


NA


ALS Environmental - USALS Houston DOD TOC/HS18091005Water

Service Request:


K1809166

10/10/1809/21/18


NoneSM 5310 C



Matrix SpikeK1809166-001MS

% Rec Limits


NADate Extracted:

Carbon, Total Organic 370 6570 6250 99 83-117





Page 14 of 40

00914747

Sample Name


WaterALS Houston DOD TOC/HS18091005ALS Environmental - US




SM 5310 CNone NA

mg/LBasis:Units:


10/10/18


% Rec Limits

NADate Extracted:

Lab Code


QA/QC Report

Lab Control Sample 83-11799 21.921.8K1809166-LCS


Page 15 of 40

00914748



QA/QC Report



Date Analyzed

True Value

Measured Value


Project:ALS Environmental - USALS Houston DOD TOC/HS18091005




90-1109824.5610329 25.010/09/18 22:57KQ1814465-14CCV190-11010024.9610329 25.010/10/18 04:01KQ1814465-15CCV290-1109724.4610329 25.010/10/18 08:19KQ1814465-16CCV390-1109724.2610329 25.010/10/18 10:12KQ1814465-17CCV4


Page 16 of 40

00914749


SM 5310 C


Client:Project:


QA/QC Report

mg/L

ALS Houston DOD TOC/HS18091005

Analysis Method:


Units:




CCB1 KQ1814465-18 10/09/18 23:13 0.50610329 0.20 0.07 UNDCCB2 KQ1814465-19 10/10/18 04:17 0.50610329 0.20 0.07 UNDCCB3 KQ1814465-20 10/10/18 08:36 0.50610329 0.20 0.07 UNDCCB4 KQ1814465-21 10/10/18 10:29 0.50610329 0.20 0.07 UND


Page 17 of 40

00914750

Raw Data



Page 18 of 40

00914751

General Chemistry



Page 19 of 40

00914752

Page 20 of 40

00914753

Page 21 of 40

00914754

Page 22 of 40

00914755

Page 23 of 40

00914756

Page 24 of 40

00914757

Page 25 of 40

00914758

Page 26 of 40

00914759

Page 27 of 40

00914760

Page 28 of 40

00914761

Page 29 of 40

00914762

Page 30 of 40

00914763

Page 31 of 40

00914764

Page 32 of 40

00914765

Page 33 of 40

00914766

Page 34 of 40

00914767

Page 35 of 40

00914768

Page 36 of 40

00914769

Page 37 of 40

00914770

Page 38 of 40

00914771

Page 39 of 40

00914772

Page 40 of 40

00914773

October 03, 2018





Sincerely,



Dear Marcia,


Project Manager

Generated By: DAYNA.FISHER

RJ Modashia



00914774






HS18091007-03 19-Sep-2018 14:00 20-Sep-2018 08:45Trip Blank ALS-080918-100 Water


00914775



Project:HS18091007

GCMS Volatiles by Method SW8260

Batch ID: R324602Sample ID: VLCSW-181002

Hexachlorobutadiene exceeded QC limits for LCS. CCV is OK.•

Sample ID: LH18/24-SP650_091918 (HS18091007-01MS)

MS and/or MSD recovered outside control limits for multiple compounds•


Batch ID: R324409



00914776



WorkOrder:Lab ID:

Collection Date:

HS18091007HS18091007-01


ANALYTICAL REPORT



VOLATILES ORGANICS BY METHOD 8260C

Method:SW8260 Analyst: PC

1ug/L 02-Oct-2018 17:35U 0.301,1,1,2-Tetrachloroethane 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.201,1,1-Trichloroethane 1.00.50 0.50



1ug/L 02-Oct-2018 17:35U 0.201,1-Dichloroethane 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.201,1-Dichloroethene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.301,1-Dichloropropene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.401,2,3-Trichlorobenzene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.501,2,3-Trichloropropane 1.00.50 0.50


1ug/L 02-Oct-2018 17:35U 0.301,2,4-Trimethylbenzene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.201,2-Dibromo-3-chloropropane 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.201,2-Dibromoethane 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.501,2-Dichlorobenzene 1.00.50 0.50


1ug/L 02-Oct-2018 17:35U 0.501,2-Dichloropropane 1.00.50 0.50






1ug/L 02-Oct-2018 17:350.502-Butanone 2.024 1.01ug/L 02-Oct-2018 17:35U 0.302-Chlorotoluene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 1.02-Hexanone 2.01.0 1.0

1ug/L 02-Oct-2018 17:35U 0.404-Chlorotoluene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.304-Isopropyltoluene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35J 0.704-Methyl-2-pentanone 2.01.0 1.01ug/L 02-Oct-2018 17:350.40Acetone 2.0180 2.01ug/L 02-Oct-2018 17:35U 0.20Benzene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.40Bromobenzene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.20Bromochloromethane 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.20Bromodichloromethane 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.40Bromoform 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.40Bromomethane 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.60Carbon disulfide 2.01.0 1.0

1ug/L 02-Oct-2018 17:35U 0.50Carbon tetrachloride 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.30Chlorobenzene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.30Chloroethane 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.20Chloroform 1.00.50 0.50



00914777



WorkOrder:Lab ID:

Collection Date:

HS18091007HS18091007-01


ANALYTICAL REPORT





1ug/L 02-Oct-2018 17:35U 0.20Chloromethane 1.00.50 0.50

1ug/L 02-Oct-2018 17:350.20cis-1,2-Dichloroethene 1.04.0 0.501ug/L 02-Oct-2018 17:35U 0.10cis-1,3-Dichloropropene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.30Dibromochloromethane 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.20Dibromomethane 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.30Dichlorodifluoromethane 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.30Ethylbenzene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 1.0Hexachlorobutadiene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.30Isopropylbenzene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.50m,p-Xylene 2.01.0 1.0

1ug/L 02-Oct-2018 17:35U 0.40Methylene chloride 2.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.40n-Butylbenzene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.30n-Propylbenzene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.30Naphthalene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.30o-Xylene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.30sec-Butylbenzene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.30Styrene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.30tert-Butylbenzene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.30Tetrachloroethene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35J 0.20Toluene 1.00.73 0.501ug/L 02-Oct-2018 17:35U 0.20trans-1,2-Dichloroethene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.20trans-1,3-Dichloropropene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.20Trichloroethene 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.30Trichlorofluoromethane 1.00.50 0.50

1ug/L 02-Oct-2018 17:35U 0.20Vinyl chloride 1.00.50 0.50

Surr: 1,2-Dichloroethane-d4 1%REC 02-Oct-2018 17:3595.6 81-1180Surr: 4-Bromofluorobenzene 1%REC 02-Oct-2018 17:3595.6 85-1140Surr: Dibromofluoromethane 1%REC 02-Oct-2018 17:3592.5 80-1190Surr: Toluene-d8 1%REC 02-Oct-2018 17:35109 89-1120



00914778



WorkOrder:Lab ID:

Collection Date:

HS18091007HS18091007-02


ANALYTICAL REPORT



ANIONS BY SW9056A Method:SW9056 Analyst: AJH10mg/L 28-Sep-2018 20:462.00Chloride 5.00661 5.0010mg/L 28-Sep-2018 20:462.00Sulfate 5.0065.6 5.00



00914779


Bhate Environmental Associates, Inc.Longhorn GW Treatment PlantTrip Blank ALS-080918-100

WorkOrder:Lab ID:

Collection Date:

HS18091007HS18091007-03


ANALYTICAL REPORT


























1ug/L 02-Oct-2018 17:10U 0.502-Butanone 2.01.0 1.0





1ug/L 02-Oct-2018 17:10U 0.704-Methyl-2-pentanone 2.01.0 1.0

1ug/L 02-Oct-2018 17:10U 0.40Acetone 2.02.0 2.0

1ug/L 02-Oct-2018 17:10U 0.20Benzene 1.00.50 0.50













00914780


Bhate Environmental Associates, Inc.Longhorn GW Treatment PlantTrip Blank ALS-080918-100

WorkOrder:Lab ID:

Collection Date:

HS18091007HS18091007-03


ANALYTICAL REPORT






1ug/L 02-Oct-2018 17:10U 0.20cis-1,2-Dichloroethene 1.00.50 0.50

1ug/L 02-Oct-2018 17:10U 0.10cis-1,3-Dichloropropene 1.00.50 0.50












1ug/L 02-Oct-2018 17:10U 0.30o-Xylene 1.00.50 0.50


1ug/L 02-Oct-2018 17:10U 0.30Styrene 1.00.50 0.50



1ug/L 02-Oct-2018 17:10U 0.20Toluene 1.00.50 0.50

1ug/L 02-Oct-2018 17:10U 0.20trans-1,2-Dichloroethene 1.00.50 0.50








00914781


WorkOrder:Project:



Batch ID R324409 Test Name : ANIONS BY SW9056A Matrix: Water

28 Sep 2018 20:46HS18091007-02 19 Sep 2018 14:00 10LH18/24-SP650_091918

Batch ID R324602 Test Name : VOLATILES ORGANICS BY METHOD 8260C Matrix: Water

02 Oct 2018 17:35HS18091007-01 19 Sep 2018 14:00 1LH18/24-SP650_091918

02 Oct 2018 17:10HS18091007-03 19 Sep 2018 14:00 1Trip Blank ALS-080918-100


00914782

Client:Project:



QC BATCH REPORT

Batch ID: R324602 Instrument: VOA9 Method: SW8260

Sample ID: VBLKW-181002 Units: ug/L Analysis Date: 02-Oct-2018 16:44

Run ID: VOA9_324602 SeqNo: 4752383 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

1,1,1,2-Tetrachloroethane 0.50 U1.0

1,1,1-Trichloroethane 0.50 U1.0



1,1-Dichloroethane 0.50 U1.0

1,1-Dichloroethene 0.50 U1.0

1,1-Dichloropropene 0.50 U1.0

1,2,3-Trichlorobenzene 0.50 U1.0

1,2,3-Trichloropropane 0.50 U1.0


1,2,4-Trimethylbenzene 0.50 U1.0

1,2-Dibromo-3-chloropropane 0.50 U1.0

1,2-Dibromoethane 0.50 U1.0

1,2-Dichlorobenzene 0.50 U1.0


1,2-Dichloropropane 0.50 U1.0






2-Butanone 1.0 U2.0

2-Chlorotoluene 0.50 U1.0

2-Hexanone 1.0 U2.0


4-Isopropyltoluene 0.50 U1.0

4-Methyl-2-pentanone 1.0 U2.0

Acetone 2.0 U2.0

Benzene 0.50 U1.0

Bromobenzene 0.50 U1.0

Bromochloromethane 0.50 U1.0

Bromodichloromethane 0.50 U1.0

Bromoform 0.50 U1.0

Bromomethane 0.50 U1.0



00914783

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Carbon disulfide 1.0 U2.0

Carbon tetrachloride 0.50 U1.0

Chlorobenzene 0.50 U1.0

Chloroethane 0.50 U1.0

Chloroform 0.50 U1.0

Chloromethane 0.50 U1.0

cis-1,2-Dichloroethene 0.50 U1.0

cis-1,3-Dichloropropene 0.50 U1.0

Dibromochloromethane 0.50 U1.0

Dibromomethane 0.50 U1.0

Dichlorodifluoromethane 0.50 U1.0

Ethylbenzene 0.50 U1.0

Hexachlorobutadiene 0.50 U1.0

Isopropylbenzene 0.50 U1.0

m,p-Xylene 1.0 U2.0

Methylene chloride 0.50 U2.0

Naphthalene 0.50 U1.0

n-Butylbenzene 0.50 U1.0

n-Propylbenzene 0.50 U1.0

o-Xylene 0.50 U1.0

sec-Butylbenzene 0.50 U1.0

Styrene 0.50 U1.0

tert-Butylbenzene 0.50 U1.0

Tetrachloroethene 0.50 U1.0

Toluene 0.50 U1.0

trans-1,2-Dichloroethene 0.50 U1.0

trans-1,3-Dichloropropene 0.50 U1.0

Trichloroethene 0.50 U1.0

Trichlorofluoromethane 0.50 U1.0

Vinyl chloride 0.50 U1.0

47.96 50 0 95.9 81 - 1181.0Surr: 1,2-Dichloroethane-d4

47.53 50 0 95.1 85 - 1141.0Surr: 4-Bromofluorobenzene

43.48 50 0 87.0 80 - 1191.0Surr: Dibromofluoromethane

54.38 50 0 109 89 - 1121.0Surr: Toluene-d8



00914784

Client:Project:



QC BATCH REPORT


Sample ID: VLCSW-181002 Units: ug/L Analysis Date: 02-Oct-2018 15:54



Value %RECControl

LimitRPD Ref


LCS

Client ID:

1,1,1,2-Tetrachloroethane 19.89 20 0 99.5 78 - 1241.0

1,1,1-Trichloroethane 18.44 20 0 92.2 74 - 1311.0

1,1,2,2-Tetrachloroethane 22.39 20 0 112 71 - 1211.0

1,1,2-Trichloroethane 21.63 20 0 108 80 - 1191.0

1,1-Dichloroethane 20.5 20 0 103 77 - 1251.0

1,1-Dichloroethene 19.34 20 0 96.7 71 - 1311.0

1,1-Dichloropropene 21.51 20 0 108 78 - 1251.0

1,2,3-Trichlorobenzene 22.94 20 0 115 69 - 1291.0

1,2,3-Trichloropropane 20.65 20 0 103 73 - 1221.0


1,2,4-Trimethylbenzene 22.96 20 0 115 76 - 1241.0

1,2-Dibromo-3-chloropropane 18.44 20 0 92.2 62 - 1281.0

1,2-Dibromoethane 20.88 20 0 104 77 - 1211.0

1,2-Dichlorobenzene 22.5 20 0 112 80 - 1191.0

1,2-Dichloroethane 21.04 20 0 105 73 - 1281.0

1,2-Dichloropropane 21.56 20 0 108 78 - 1221.0





2,2-Dichloropropane 19.9 20 0 99.5 60 - 1391.0

2-Butanone 43.16 40 0 108 56 - 1432.0

2-Chlorotoluene 22.71 20 0 114 79 - 1221.0

2-Hexanone 42.43 40 0 106 57 - 1392.0

4-Chlorotoluene 22.84 20 0 114 78 - 1221.0

4-Isopropyltoluene 23.67 20 0 118 77 - 1271.0

4-Methyl-2-pentanone 42.49 40 0 106 67 - 1302.0

Acetone 49.71 40 0 124 39 - 1602.0

Benzene 21.82 20 0 109 79 - 1201.0

Bromobenzene 20.72 20 0 104 80 - 1201.0

Bromochloromethane 20.54 20 0 103 78 - 1231.0

Bromodichloromethane 18.7 20 0 93.5 79 - 1251.0

Bromoform 16.32 20 0 81.6 66 - 1301.0

Bromomethane 18.21 20 0 91.0 53 - 1411.0



00914785

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:

Carbon disulfide 44.04 40 0 110 64 - 1332.0

Carbon tetrachloride 19.39 20 0 96.9 72 - 1361.0

Chlorobenzene 21.34 20 0 107 82 - 1181.0

Chloroethane 20.73 20 0 104 60 - 1381.0

Chloroform 20.09 20 0 100 79 - 1241.0

Chloromethane 21.44 20 0 107 50 - 1391.0

cis-1,2-Dichloroethene 19.93 20 0 99.7 78 - 1231.0

cis-1,3-Dichloropropene 19.08 20 0 95.4 75 - 1241.0

Dibromochloromethane 19.01 20 0 95.0 74 - 1261.0

Dibromomethane 19.8 20 0 99.0 79 - 1231.0

Dichlorodifluoromethane 26.9 20 0 135 32 - 1521.0

Ethylbenzene 21.14 20 0 106 79 - 1211.0

Hexachlorobutadiene 26.96 20 0 135 66 - 134 S1.0

Isopropylbenzene 21.78 20 0 109 72 - 1311.0

m,p-Xylene 42.49 40 0 106 80 - 1212.0

Methylene chloride 21.94 20 0 110 74 - 1242.0

Naphthalene 22.57 20 0 113 61 - 1281.0

n-Butylbenzene 24.8 20 0 124 75 - 1281.0

n-Propylbenzene 23.57 20 0 118 76 - 1261.0

o-Xylene 20.95 20 0 105 78 - 1221.0

sec-Butylbenzene 23.78 20 0 119 77 - 1261.0

Styrene 21.61 20 0 108 78 - 1231.0

tert-Butylbenzene 24.07 20 0 120 78 - 1241.0

Tetrachloroethene 21.36 20 0 107 74 - 1291.0

Toluene 21.97 20 0 110 80 - 1211.0

trans-1,2-Dichloroethene 20.41 20 0 102 75 - 1241.0

trans-1,3-Dichloropropene 19.01 20 0 95.0 73 - 1271.0

Trichloroethene 19.91 20 0 99.6 79 - 1231.0

Trichlorofluoromethane 20 20 0 100 65 - 1411.0

Vinyl chloride 22.47 20 0 112 58 - 1371.0


50.08 50 0 100 85 - 1141.0Surr: 4-Bromofluorobenzene


53.77 50 0 108 89 - 1121.0Surr: Toluene-d8



00914786

Client:Project:



QC BATCH REPORT


Sample ID: HS18091007-01MS Units: ug/L Analysis Date: 02-Oct-2018 19:15



Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP650_091918





1,1-Dichloroethane 22.53 20 0 113 77 - 1251.0

1,1-Dichloroethene 21.93 20 0 110 71 - 1311.0







1,2-Dibromoethane 22.39 20 0 112 77 - 1211.0

1,2-Dichlorobenzene 23.82 20 0 119 80 - 119 S1.0

1,2-Dichloroethane 22.75 20 0 114 73 - 1281.0





1,4-Dichlorobenzene 23.64 20 0 118 79 - 118 S1.0


2-Butanone 66.58 40 24.04 106 56 - 1432.0

2-Chlorotoluene 23.78 20 0 119 79 - 1221.0

2-Hexanone 46.74 40 0 117 57 - 1392.0

4-Chlorotoluene 23.88 20 0 119 78 - 1221.0


4-Methyl-2-pentanone 44.27 40 1.044 108 67 - 1302.0

Acetone 227.1 40 179.3 120 39 - 160 O2.0

Benzene 24.38 20 0 122 79 - 120 S1.0

Bromobenzene 21.99 20 0 110 80 - 1201.0


Bromodichloromethane 20.88 20 0 104 79 - 1251.0

Bromoform 17.53 20 0 87.6 66 - 1301.0

Bromomethane 10.55 20 0 52.8 53 - 141 S1.0



00914787

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP650_091918

Carbon disulfide 57.65 40 0 144 64 - 133 S2.0

Carbon tetrachloride 21.52 20 0 108 72 - 1361.0

Chlorobenzene 22.71 20 0 114 82 - 1181.0

Chloroethane 23.09 20 0 115 60 - 1381.0

Chloroform 22.15 20 0 111 79 - 1241.0

Chloromethane 24.17 20 0 121 50 - 1391.0

cis-1,2-Dichloroethene 26.24 20 4.033 111 78 - 1231.0

cis-1,3-Dichloropropene 20.13 20 0 101 75 - 1241.0

Dibromochloromethane 21.12 20 0 106 74 - 1261.0

Dibromomethane 22.03 20 0 110 79 - 1231.0


Ethylbenzene 22.84 20 0 114 79 - 1211.0

Hexachlorobutadiene 24.45 20 0 122 66 - 1341.0


m,p-Xylene 45.69 40 0 114 80 - 1212.0


Naphthalene 22.75 20 0 114 61 - 1281.0

n-Butylbenzene 24.93 20 0 125 75 - 1281.0

n-Propylbenzene 24.86 20 0 124 76 - 1261.0

o-Xylene 22.66 20 0 113 78 - 1221.0


Styrene 22.88 20 0 114 78 - 1231.0

tert-Butylbenzene 25.06 20 0 125 78 - 124 S1.0


Toluene 24.42 20 0.7339 118 80 - 1211.0



Trichloroethene 23.11 20 0 116 79 - 1231.0

Trichlorofluoromethane 21.46 20 0 107 65 - 1411.0

Vinyl chloride 26.07 20 0 130 58 - 1371.0




53.66 50 0 107 89 - 1121.0Surr: Toluene-d8



00914788

Client:Project:



QC BATCH REPORT


Sample ID: HS18091007-01MSD Units: ug/L Analysis Date: 02-Oct-2018 19:40



Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP650_091918

1,1,1,2-Tetrachloroethane 20.7 20 0 103 78 - 124 21.36 3.17 201.0

1,1,1-Trichloroethane 19.96 20 0 99.8 74 - 131 20.92 4.71 201.0


1,1,2-Trichloroethane 22.48 20 0 112 80 - 119 22.96 2.12 201.0

1,1-Dichloroethane 21.92 20 0 110 77 - 125 22.53 2.75 201.0

1,1-Dichloroethene 21.05 20 0 105 71 - 131 21.93 4.1 201.0

1,1-Dichloropropene 22.97 20 0 115 78 - 125 24.13 4.89 201.0

1,2,3-Trichlorobenzene 22.2 20 0 111 69 - 129 22.6 1.81 201.0

1,2,3-Trichloropropane 20.47 20 0 102 73 - 122 20.29 0.851 201.0


1,2,4-Trimethylbenzene 23.42 20 0 117 76 - 124 24.01 2.49 201.0

1,2-Dibromo-3-chloropropane 18.46 20 0 92.3 62 - 128 18.26 1.08 201.0

1,2-Dibromoethane 21.85 20 0 109 77 - 121 22.39 2.42 201.0

1,2-Dichlorobenzene 23.01 20 0 115 80 - 119 23.82 3.45 201.0

1,2-Dichloroethane 22.07 20 0 110 73 - 128 22.75 3.05 201.0

1,2-Dichloropropane 23.43 20 0 117 78 - 122 23.79 1.51 201.0





2,2-Dichloropropane 18.17 20 0 90.8 60 - 139 18.87 3.8 201.0

2-Butanone 68.36 40 24.04 111 56 - 143 66.58 2.65 202.0

2-Chlorotoluene 22.94 20 0 115 79 - 122 23.78 3.56 201.0

2-Hexanone 47.2 40 0 118 57 - 139 46.74 0.98 202.0

4-Chlorotoluene 23.06 20 0 115 78 - 122 23.88 3.5 201.0

4-Isopropyltoluene 23.49 20 0 117 77 - 127 24.31 3.47 201.0

4-Methyl-2-pentanone 44.93 40 1.044 110 67 - 130 44.27 1.49 202.0

Acetone 223 40 179.3 109 39 - 160 227.1 1.83 20 O2.0

Benzene 23.44 20 0 117 79 - 120 24.38 3.93 201.0

Bromobenzene 21.13 20 0 106 80 - 120 21.99 4.01 201.0

Bromochloromethane 21.95 20 0 110 78 - 123 22.84 4 201.0

Bromodichloromethane 20.96 20 0 105 79 - 125 20.88 0.415 201.0

Bromoform 16.97 20 0 84.8 66 - 130 17.53 3.23 201.0

Bromomethane 8.195 20 0 41.0 53 - 141 10.55 25.1 20 SR1.0



00914789

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP650_091918

Carbon disulfide 58.44 40 0 146 64 - 133 57.65 1.36 20 S2.0

Carbon tetrachloride 21.46 20 0 107 72 - 136 21.52 0.292 201.0

Chlorobenzene 22.01 20 0 110 82 - 118 22.71 3.13 201.0

Chloroethane 25.15 20 0 126 60 - 138 23.09 8.53 201.0

Chloroform 21.35 20 0 107 79 - 124 22.15 3.66 201.0

Chloromethane 27.98 20 0 140 50 - 139 24.17 14.6 20 S1.0

cis-1,2-Dichloroethene 24.91 20 4.033 104 78 - 123 26.24 5.18 201.0

cis-1,3-Dichloropropene 19.86 20 0 99.3 75 - 124 20.13 1.37 201.0

Dibromochloromethane 20.72 20 0 104 74 - 126 21.12 1.9 201.0

Dibromomethane 21.81 20 0 109 79 - 123 22.03 1.01 201.0

Dichlorodifluoromethane 24.17 20 0 121 32 - 152 24.54 1.53 201.0

Ethylbenzene 22.18 20 0 111 79 - 121 22.84 2.91 201.0

Hexachlorobutadiene 24.34 20 0 122 66 - 134 24.45 0.474 201.0

Isopropylbenzene 22.71 20 0 114 72 - 131 23.25 2.35 201.0

m,p-Xylene 44.43 40 0 111 80 - 121 45.69 2.79 202.0

Methylene chloride 22.95 20 0 115 74 - 124 23.59 2.78 202.0

Naphthalene 22.64 20 0 113 61 - 128 22.75 0.455 201.0

n-Butylbenzene 24.52 20 0 123 75 - 128 24.93 1.66 201.0

n-Propylbenzene 24.03 20 0 120 76 - 126 24.86 3.4 201.0

o-Xylene 21.74 20 0 109 78 - 122 22.66 4.12 201.0

sec-Butylbenzene 23.89 20 0 119 77 - 126 24.54 2.69 201.0

Styrene 22.03 20 0 110 78 - 123 22.88 3.75 201.0

tert-Butylbenzene 24.55 20 0 123 78 - 124 25.06 2.06 201.0

Tetrachloroethene 23.34 20 0 117 74 - 129 22.73 2.68 201.0

Toluene 23.75 20 0.7339 115 80 - 121 24.42 2.8 201.0

trans-1,2-Dichloroethene 21.85 20 0 109 75 - 124 23.16 5.8 201.0

trans-1,3-Dichloropropene 19.54 20 0 97.7 73 - 127 19.86 1.62 201.0

Trichloroethene 22.09 20 0 110 79 - 123 23.11 4.49 201.0

Trichlorofluoromethane 21.12 20 0 106 65 - 141 21.46 1.61 201.0

Vinyl chloride 25.26 20 0 126 58 - 137 26.07 3.14 201.0

47.87 50 0 95.7 81 - 118 47.46 0.857 201.0Surr: 1,2-Dichloroethane-d4

50.24 50 0 100 85 - 114 49.72 1.04 201.0Surr: 4-Bromofluorobenzene

47.64 50 0 95.3 80 - 119 47.12 1.1 201.0Surr: Dibromofluoromethane

53.74 50 0 107 89 - 112 53.66 0.143 201.0Surr: Toluene-d8



00914790

Client:Project:



QC BATCH REPORT


The following samples were analyzed in this batch: HS18091007-01 HS18091007-03



00914791

Client:Project:



QC BATCH REPORT

Batch ID: R324409 Instrument: ICS3K2 Method: SW9056

Sample ID: WBLKW2-092718 Units: mg/L Analysis Date: 28-Sep-2018 11:59

Run ID: ICS3K2_324409 SeqNo: 4747830 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Chloride 0.500 U0.500

Sulfate 0.500 U0.500

Sample ID: WLCSW2-092718 Units: mg/L Analysis Date: 28-Sep-2018 12:21



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Chloride 21.85 20 0 109 80 - 1200.500

Sulfate 21.38 20 0 107 80 - 1200.500

Sample ID: WLCSDW2-092718 Units: mg/L Analysis Date: 28-Sep-2018 12:42



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Chloride 22.94 20 0 115 80 - 120 21.85 4.88 200.500

Sulfate 22.84 20 0 114 80 - 120 21.38 6.58 200.500




Value %RECControl

LimitRPD Ref


MS

Client ID:

Chloride 362.7 100 256.1 107 80 - 1205.00

Sulfate 301.3 100 194.7 107 80 - 1205.00




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Chloride 362.1 100 256.1 106 80 - 120 362.7 0.165 205.00

Sulfate 301.3 100 194.7 107 80 - 120 301.3 0.0193 205.00




00914792





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution



Unit Reported Descriptionmg/L Milligrams per Liter


00914793




Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


00914794

JRM


HS18091007

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

2.2c/1.8c uc/c IR 114423509/20/2018 11:55


Yes No N/A

Yes No N/A

Checklist completed by: Raegen GigaDateeSignatureDateeSignature

20-Sep-201820-Sep-2018

FedEx Priority Overnightwater Carrier name:Matrices:




Comments:

Corrective Action:

Yes



00914795

00914796

00914797

October 17, 2018





Sincerely,


Laboratory Results for: Groundwater Treatment Plant Quarterly Influent Samples

Dear Marcia,


Project Manager


RJ Modashia



00914798


Work Order: HS18091519Project: Groundwater Treatment Plant Quarterly Influent Samples SAMPLE SUMMARY




HS18091519-03 27-Sep-2018 00:00ALS-050418-35

28-Sep-2018 08:55Trip Blank Water


00914799


Work Order:Groundwater Treatment Plant Quarterly Influent SamplesBhate Environmental Associates, Inc.

Project:

Work Order Comments


Work Order Comments


GCMS Semivolatiles by Method SW8270SIM

Batch ID: 133017Sample ID: LH18/24-SP140_092718 (HS18091519-01)

The surrogate recoveries could not be determined due to dilution below the calibration range. •


Batch ID: R325350Sample ID: LH18/24-SP140_092718 (HS18091519-01)

Sample was analyzed outside of the holding time for cis-1,2-Dichloroethene ,Methylene chloride and Trichloroethene. The compounds were over the calibration range in the original run. Reanalysis was performed outside of the holding time due to laboratory error. Sample results should be considered estimated.

•

Sample ID: LH18/24-SP140_092718 (HS18091519-01MSD)

The recovery of the Matrix Spike Duplicate (MSD) associated to this analyte was outside of the established control limits. However, the LCS was within control limits. The failed recovery of the MSD may be due to sample matrix interference.

•

Batch ID: R325306Sample ID: HS18091560-01MS

MS and MSD are for an unrelated sample•


Batch ID: 133116



Batch ID: 133107Sample ID: HS18091510-01MS

MS/MSD and DUPs are for an unrelated sample•



MS and MSD are for an unrelated sample (Chloride,Sulfate)•


Batch ID: R324887


00914800


Work Order:Groundwater Treatment Plant Quarterly Influent SamplesBhate Environmental Associates, Inc.

Project:


Batch ID: R324887The test results meet requirements of the current NELAP standards, state requirements or programs where applicable.•

WetChemistry by Method E1664A

Batch ID: R324857



00914801


Bhate Environmental Associates, Inc.Groundwater Treatment Plant Quarterly Influent SamplesLH18/24-SP140_092718

WorkOrder:Lab ID:

Collection Date:

HS18091519HS18091519-01


ANALYTICAL REPORT




Method:SW8260 Analyst: AKP


1ug/L 11-Oct-2018 15:050.201,1,1-Trichloroethane 1.01.6 0.501ug/L 11-Oct-2018 15:05U 0.501,1,2,2-Tetrachloroethane 1.00.50 0.50

1ug/L 11-Oct-2018 15:050.301,1,2-Trichloroethane 1.03.2 0.501ug/L 11-Oct-2018 15:050.201,1-Dichloroethane 1.014 0.501ug/L 11-Oct-2018 15:050.201,1-Dichloroethene 1.076 0.501ug/L 11-Oct-2018 15:05U 0.301,1-Dichloropropene 1.00.50 0.50








1ug/L 11-Oct-2018 15:050.201,2-Dichloroethane 1.048 0.501ug/L 11-Oct-2018 15:05U 0.501,2-Dichloropropane 1.00.50 0.50












1ug/L 11-Oct-2018 15:05U 0.40Acetone 2.02.0 2.0

1ug/L 11-Oct-2018 15:050.20Benzene 1.02.9 0.501ug/L 11-Oct-2018 15:05U 0.40Bromobenzene 1.00.50 0.50






1ug/L 11-Oct-2018 15:050.50Carbon tetrachloride 1.03.1 0.501ug/L 11-Oct-2018 15:05U 0.30Chlorobenzene 1.00.50 0.50


1ug/L 11-Oct-2018 15:050.20Chloroform 1.018 0.50



00914802



WorkOrder:Lab ID:

Collection Date:

HS18091519HS18091519-01


ANALYTICAL REPORT






100ug/L 12-Oct-2018 14:28H 20cis-1,2-Dichloroethene 1004,700 501ug/L 11-Oct-2018 15:05U 0.10cis-1,3-Dichloropropene 1.00.50 0.50








100ug/L 12-Oct-2018 14:28H 40Methylene chloride 2005,800 1001ug/L 11-Oct-2018 15:05U 0.40n-Butylbenzene 1.00.50 0.50



1ug/L 11-Oct-2018 15:05U 0.30o-Xylene 1.00.50 0.50


1ug/L 11-Oct-2018 15:05U 0.30Styrene 1.00.50 0.50


1ug/L 11-Oct-2018 15:050.30Tetrachloroethene 1.041 0.501ug/L 11-Oct-2018 15:050.20Toluene 1.02.7 0.501ug/L 11-Oct-2018 15:050.20trans-1,2-Dichloroethene 1.028 0.501ug/L 11-Oct-2018 15:05U 0.20trans-1,3-Dichloropropene 1.00.50 0.50

100ug/L 12-Oct-2018 14:28H 20Trichloroethene 1006,500 501ug/L 11-Oct-2018 15:05U 0.30Trichlorofluoromethane 1.00.50 0.50

1ug/L 11-Oct-2018 15:050.20Vinyl chloride 1.0170 0.50Surr: 1,2-Dichloroethane-d4 1%REC 11-Oct-2018 15:0595.3 81-1180Surr: 1,2-Dichloroethane-d4 100%REC 12-Oct-2018 14:2892.8 81-1180Surr: 4-Bromofluorobenzene 1%REC 11-Oct-2018 15:0599.5 85-1140Surr: 4-Bromofluorobenzene 100%REC 12-Oct-2018 14:2898.5 85-1140Surr: Dibromofluoromethane 1%REC 11-Oct-2018 15:0598.1 80-1190Surr: Dibromofluoromethane 100%REC 12-Oct-2018 14:2897.6 80-1190Surr: Toluene-d8 1%REC 11-Oct-2018 15:0593.7 89-1120Surr: Toluene-d8 100%REC 12-Oct-2018 14:2893.2 89-1120

SEMIVOLATILES SIM Method:SW8270SIM Analyst: ACNPrep:SW3510 / 01-Oct-2018

100ug/L 04-Oct-2018 13:481.01,4-Dioxane 1.05.7 1.0Surr: 2-Fluorobiphenyl 100%REC 04-Oct-2018 13:48S0 40-1400

Surr: 4-Terphenyl-d14 100%REC 04-Oct-2018 13:48S0 40-1400

Surr: Nitrobenzene-d5 100%REC 04-Oct-2018 13:48S0 40-1400



00914803



WorkOrder:Lab ID:

Collection Date:

HS18091519HS18091519-01


ANALYTICAL REPORT



ICP-MS METALS BY SW6020A Method:SW6020 Analyst: JDEPrep:SW3010A / 03-Oct-2018

1mg/L 12-Oct-2018 15:590.00180Aluminum 0.01000.0375 0.005001mg/L 12-Oct-2018 15:59U 0.000400Antimony 0.002000.00100 0.00100

1mg/L 12-Oct-2018 15:59J 0.000400Arsenic 0.002000.00148 0.001001mg/L 12-Oct-2018 15:590.00190Barium 0.004000.901 0.002501mg/L 12-Oct-2018 15:59J 0.000200Beryllium 0.002000.000371 0.001001mg/L 12-Oct-2018 15:59J 0.000200Cadmium 0.002000.000374 0.001001mg/L 12-Oct-2018 15:590.0340Calcium 0.50052.1 0.1001mg/L 12-Oct-2018 15:59J 0.000400Chromium 0.004000.00284 0.001001mg/L 12-Oct-2018 15:590.000200Cobalt 0.005000.0137 0.001001mg/L 12-Oct-2018 15:590.0120Iron 0.2001.50 0.1001mg/L 12-Oct-2018 15:59U 0.000600Lead 0.002000.00100 0.00100

1mg/L 12-Oct-2018 15:590.0100Magnesium 0.20041.9 0.1001mg/L 12-Oct-2018 15:590.000700Manganese 0.005000.888 0.001001mg/L 12-Oct-2018 15:590.000600Nickel 0.002000.0201 0.001001mg/L 12-Oct-2018 15:590.0180Potassium 0.2001.34 0.1001mg/L 12-Oct-2018 15:59U 0.00110Selenium 0.002000.00200 0.00200

1mg/L 12-Oct-2018 15:59U 0.000200Silver 0.002000.00100 0.00100

10mg/L 12-Oct-2018 17:370.140Sodium 2.00245 1.001mg/L 12-Oct-2018 15:59U 0.000200Thallium 0.002000.00100 0.00100

1mg/L 12-Oct-2018 15:59J 0.000600Vanadium 0.005000.00145 0.001001mg/L 12-Oct-2018 15:590.00200Zinc 0.004000.0317 0.00250

MERCURY BY SW7470A Method:SW7470 Analyst: JCJPrep:SW7470 / 03-Oct-2018

1mg/L 03-Oct-2018 16:53U 0.0000300Mercury 0.0002000.000100 0.000100

OIL & GREASE (HEM) BY E1664A Method:E1664A Analyst: KAH1mg/L 05-Oct-2018 14:40U 0.610Oil and Grease 2.001.00 1.00

CHEMICAL OXYGEN DEMAND BY E410.4 Method:E410.4 Analyst: AJH1mg/L 06-Oct-2018 15:00J 5.00Chemical Oxygen Demand 15.010.0 10.0

ANIONS BY SW9056A Method:SW9056 Analyst: KMU10mg/L 11-Oct-2018 07:442.00Chloride 5.00564 5.0010mg/L 11-Oct-2018 07:442.00Sulfate 5.0038.4 5.00



00914804


Bhate Environmental Associates, Inc.Groundwater Treatment Plant Quarterly Influent SamplesLH18/24-SP140_092718_BIX

WorkOrder:Lab ID:

Collection Date:

HS18091519HS18091519-02


ANALYTICAL REPORT








00914805


Bhate Environmental Associates, Inc.Groundwater Treatment Plant Quarterly Influent SamplesTrip Blank

WorkOrder:Lab ID:

Collection Date:

HS18091519HS18091519-03


ANALYTICAL REPORT
































1ug/L 11-Oct-2018 14:16U 0.40Acetone 2.02.0 2.0

1ug/L 11-Oct-2018 14:16U 0.20Benzene 1.00.50 0.50













00914806


Bhate Environmental Associates, Inc.Groundwater Treatment Plant Quarterly Influent SamplesTrip Blank

WorkOrder:Lab ID:

Collection Date:

HS18091519HS18091519-03


ANALYTICAL REPORT



















1ug/L 11-Oct-2018 14:16U 0.30o-Xylene 1.00.50 0.50


1ug/L 11-Oct-2018 14:16U 0.30Styrene 1.00.50 0.50



1ug/L 11-Oct-2018 14:16U 0.20Toluene 1.00.50 0.50






Surr: 1,2-Dichloroethane-d4 1%REC 11-Oct-2018 14:1692.1 81-1180Surr: 4-Bromofluorobenzene 1%REC 11-Oct-2018 14:1698.2 85-1140Surr: Dibromofluoromethane 1%REC 11-Oct-2018 14:1698.3 80-1190Surr: Toluene-d8 1%REC 11-Oct-2018 14:1692.3 89-1120



00914807

WEIGHT LOG

HS18091519Groundwater Treatment Plant Quarterly Influent SamplesBhate Environmental Associates, Inc.


Batch ID: 133017 Method: SEMIVOLATILES SIM 3510_B_SIMPrep:


Final Volume

Prep Factor

HS18091519-01 1 1000 1 (mL) 0.001



Final Volume

Prep Factor

HS18091519-01 1 10 10 (mL) 1

Batch ID: 133116 Method: MERCURY BY SW7470A HG_WPRPrep:


Final Volume

Prep Factor

HS18091519-01 1 10 (mL) 10 (mL) 1

17-Oct-18Date: ALS Houston, US00914808

Client:Groundwater Treatment Plant Quarterly Influent SamplesBhate Environmental Associates, Inc.

WorkOrder:Project:



Batch ID 133017 Test Name : SEMIVOLATILES SIM Matrix: Water

01 Oct 2018 14:05 04 Oct 2018 13:48HS18091519-01 27 Sep 2018 14:00 100LH18/24-SP140_092718




Batch ID 133116 Test Name : MERCURY BY SW7470A Matrix: Water


Batch ID R324857 Test Name : OIL & GREASE (HEM) BY E1664A Matrix: Water

05 Oct 2018 14:40HS18091519-01 27 Sep 2018 14:00 1LH18/24-SP140_092718

Batch ID R324887 Test Name : CHEMICAL OXYGEN DEMAND BY E410.4 Matrix: Water

06 Oct 2018 15:00HS18091519-01 27 Sep 2018 14:00 1LH18/24-SP140_092718


11 Oct 2018 07:44HS18091519-01 27 Sep 2018 14:00 10LH18/24-SP140_092718


11 Oct 2018 15:05HS18091519-01 27 Sep 2018 14:00 1LH18/24-SP140_092718

11 Oct 2018 14:16HS18091519-03 27 Sep 2018 00:00 1Trip Blank


12 Oct 2018 14:28HS18091519-01 27 Sep 2018 14:00 100LH18/24-SP140_092718


17 Oct 2018 09:45HS18091519-02 27 Sep 2018 14:00 1LH18/24-SP140_092718_BIX


00914809

Client:Project:

Bhate Environmental Associates, Inc.Groundwater Treatment Plant Quarterly Influent Samples


QC BATCH REPORT


Sample ID: MBLK-133107 Units: mg/L Analysis Date: 12-Oct-2018 14:11

Run ID: ICPMS05_325303 SeqNo: 4770574 PrepDate: 03-Oct-2018 DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Aluminum 0.003938 J 0.0100

Antimony 0.00100 U0.00200

Arsenic 0.00100 U0.00200

Barium 0.00250 U0.00400

Beryllium 0.00100 U0.00200

Cadmium 0.00100 U0.00200

Calcium 0.100 U0.500

Chromium 0.00100 U0.00400

Cobalt 0.00100 U0.00500

Iron 0.100 U0.200

Lead 0.00100 U0.00200

Magnesium 0.01631 J 0.200

Manganese 0.000827 J 0.00500

Nickel 0.00100 U0.00200

Potassium 0.100 U0.200

Selenium 0.00200 U0.00200

Silver 0.00100 U0.00200

Sodium 0.04046 J 0.200

Thallium 0.00100 U0.00200

Vanadium 0.00100 U0.00500

Zinc 0.00250 U0.00400


00914810

Client:Project:



QC BATCH REPORT


Sample ID: LCS-133107 Units: mg/L Analysis Date: 12-Oct-2018 14:13



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Aluminum 0.09632 0.1 0 96.3 80 - 1200.0100

Antimony 0.04314 0.05 0 86.3 80 - 1200.00200

Arsenic 0.04584 0.05 0 91.7 80 - 1200.00200

Barium 0.04195 0.05 0 83.9 80 - 1200.00400

Beryllium 0.04591 0.05 0 91.8 80 - 1200.00200

Cadmium 0.04485 0.05 0 89.7 80 - 1200.00200

Calcium 4.536 5 0 90.7 80 - 1200.500

Chromium 0.04653 0.05 0 93.1 80 - 1200.00400

Cobalt 0.04521 0.05 0 90.4 80 - 1200.00500

Iron 4.734 5 0 94.7 80 - 1200.200

Lead 0.0492 0.05 0 98.4 80 - 1200.00200

Magnesium 4.643 5 0 92.9 80 - 1200.200

Manganese 0.04672 0.05 0 93.4 80 - 1200.00500

Nickel 0.04794 0.05 0 95.9 80 - 1200.00200

Potassium 4.479 5 0 89.6 80 - 1200.200

Selenium 0.04466 0.05 0 89.3 80 - 1200.00200

Silver 0.04366 0.05 0 87.3 80 - 1200.00200

Sodium 4.66 5 0 93.2 80 - 1200.200

Thallium 0.04066 0.05 0 81.3 80 - 1200.00200

Vanadium 0.04449 0.05 0 89.0 80 - 1200.00500

Zinc 0.04813 0.05 0 96.3 80 - 1200.00400


00914811

Client:Project:



QC BATCH REPORT


Sample ID: HS18091510-01MS Units: mg/L Analysis Date: 12-Oct-2018 15:49



Value %RECControl

LimitRPD Ref


MS

Client ID:

Aluminum 4.726 0.1 0.5282 4200 80 - 120 SEO 0.0100

Antimony 0.04247 0.05 0.000119 84.7 80 - 1200.00200

Arsenic 0.0468 0.05 0.000926 91.7 80 - 1200.00200

Barium 0.1138 0.05 0.05916 109 80 - 1200.00400

Beryllium 0.05194 0.05 0.000176 104 80 - 1200.00200

Cadmium 0.0463 0.05 0.000141 92.3 80 - 1200.00200

Calcium 24.36 5 19.43 98.6 80 - 1200.500

Chromium 0.05258 0.05 0.001736 102 80 - 1200.00400

Cobalt 0.04673 0.05 0.003111 87.2 80 - 1200.00500

Iron 8.85 5 1.06 156 80 - 120 S 0.200

Lead 0.051 0.05 0.00156 98.9 80 - 1200.00200

Magnesium 19.04 5 14.62 88.5 80 - 1200.200

Manganese 0.1588 0.05 0.1081 101 80 - 1200.00500

Nickel 0.05439 0.05 0.005499 97.8 80 - 1200.00200

Potassium 5.112 5 0.3724 94.8 80 - 1200.200

Selenium 0.04482 0.05 -0.000243 90.1 80 - 1200.00200

Silver 0.04304 0.05 0.000012 86.1 80 - 1200.00200

Sodium 71.07 5 67.3 75.3 80 - 120 SO 0.200

Thallium 0.04247 0.05 0.000044 84.8 80 - 1200.00200

Vanadium 0.05476 0.05 0.002494 105 80 - 1200.00500

Zinc 0.06572 0.05 0.013 105 80 - 1200.00400

Sample ID: HS18091510-01MSD Units: mg/L Analysis Date: 12-Oct-2018 17:50



Value %RECControl

LimitRPD Ref


MSD

Client ID:

Aluminum 5.463 0.1 0.5282 4930 80 - 120 4.726 14.5 20 SEO 0.0100

Calcium 25.64 5 19.43 124 80 - 120 24.36 5.14 20 S 0.500

Iron 9.125 5 1.06 161 80 - 120 8.85 3.07 20 S 0.200


00914812

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID:

Antimony 0.04177 0.05 0.000119 83.3 80 - 120 0.04247 1.67 200.00200

Arsenic 0.04676 0.05 0.000926 91.7 80 - 120 0.0468 0.0941 200.00200

Barium 0.1127 0.05 0.05916 107 80 - 120 0.1138 0.925 200.00400

Beryllium 0.04994 0.05 0.000176 99.5 80 - 120 0.05194 3.92 200.00200

Cadmium 0.04465 0.05 0.000141 89.0 80 - 120 0.0463 3.63 200.00200

Chromium 0.05627 0.05 0.001736 109 80 - 120 0.05258 6.78 200.00400

Cobalt 0.04857 0.05 0.003111 90.9 80 - 120 0.04673 3.87 200.00500

Lead 0.0513 0.05 0.00156 99.5 80 - 120 0.051 0.602 200.00200

Magnesium 18.96 5 14.62 86.9 80 - 120 19.04 0.428 200.200

Manganese 0.1622 0.05 0.1081 108 80 - 120 0.1588 2.08 200.00500

Nickel 0.05772 0.05 0.005499 104 80 - 120 0.05439 5.95 200.00200

Potassium 5.179 5 0.3724 96.1 80 - 120 5.112 1.3 200.200

Selenium 0.04326 0.05 -0.000243 87.0 80 - 120 0.04482 3.55 200.00200

Silver 0.04192 0.05 0.000012 83.8 80 - 120 0.04304 2.63 200.00200

Sodium 68.54 5 67.3 24.7 80 - 120 71.07 3.62 20 SO 0.200

Thallium 0.04137 0.05 0.000044 82.6 80 - 120 0.04247 2.62 200.00200

Vanadium 0.05928 0.05 0.002494 114 80 - 120 0.05476 7.93 200.00500

Zinc 0.06998 0.05 0.013 114 80 - 120 0.06572 6.29 200.00400


00914813

Client:Project:



QC BATCH REPORT


Sample ID: HS18091510-01PDS Units: mg/L Analysis Date: 12-Oct-2018 15:53



Value %RECControl

LimitRPD Ref


PDS

Client ID:

Aluminum 1.424 0.1 0.5282 896 75 - 125 SO 0.0100

Antimony 0.07982 0.1 0.000119 79.7 75 - 1250.00200

Arsenic 0.09224 0.1 0.000926 91.3 75 - 1250.00200

Barium 0.1421 0.1 0.05916 83.0 75 - 1250.00400

Beryllium 0.08857 0.1 0.000176 88.4 75 - 1250.00200

Cadmium 0.08591 0.1 0.000141 85.8 75 - 1250.00200

Calcium 25.62 10 19.43 61.9 75 - 125 S 0.500

Chromium 0.09602 0.1 0.001736 94.3 75 - 1250.00400

Cobalt 0.09176 0.1 0.003111 88.7 75 - 1250.00500

Iron 12.38 10 1.06 113 75 - 1250.200

Lead 0.0991 0.1 0.00156 97.5 75 - 1250.00200

Magnesium 22.89 10 14.62 82.7 75 - 1250.200

Manganese 0.1982 0.1 0.1081 90.1 75 - 1250.00500

Nickel 0.1024 0.1 0.005499 96.9 75 - 1250.00200

Potassium 8.668 10 0.3724 83.0 75 - 1250.200

Selenium 0.08765 0.1 -0.000243 87.9 75 - 1250.00200

Silver 0.08348 0.1 0.000012 83.5 75 - 1250.00200

Sodium 72.5 10 67.3 52.0 75 - 125 SO 0.200

Thallium 0.08515 0.1 0.000044 85.1 75 - 1250.00200

Vanadium 0.09683 0.1 0.002494 94.3 75 - 1250.00500

Zinc 0.1093 0.1 0.013 96.3 75 - 1250.00400


00914814

Client:Project:



QC BATCH REPORT


Sample ID: HS18091510-01SD Units: mg/L Analysis Date: 12-Oct-2018 15:47



Value %RECControl

LimitRPD Ref


SD

Client ID:

Aluminum 0.5592 0.5282 5.86 100.0500

Antimony 0.00500 0.000119 0 10 U0.0100

Arsenic 0.00500 0.000926 0 10 U0.0100

Barium 0.0582 0.05916 1.63 100.0200

Beryllium 0.00500 0.000176 0 10 U0.0100

Cadmium 0.00500 0.000141 0 10 U0.0100

Calcium 18.7 19.43 3.76 102.50

Chromium 0.00500 0.001736 0 10 U0.0200

Cobalt 0.003176 0.003111 0 10 J 0.0250

Iron 1.076 1.06 1.54 101.00

Lead 0.00500 0.00156 0 10 U0.0100

Magnesium 15.56 14.62 6.47 101.00

Manganese 0.1133 0.1081 4.76 100.0250

Nickel 0.00446 0.005499 0 10 J 0.0100

Potassium 0.500 0.3724 0 10 U1.00

Selenium 0.0100 -0.000243 0 10 U0.0100

Silver 0.00500 0.000012 0 10 U0.0100

Sodium 69.24 67.3 2.87 101.00

Thallium 0.00500 0.000044 0 10 U0.0100

Vanadium 0.00500 0.002494 0 10 U0.0250

Zinc 0.0131 0.013 0 10 J 0.0200



00914815

Client:Project:



QC BATCH REPORT

Batch ID: 133116 Instrument: HG03 Method: SW7470


Run ID: HG03_324646 SeqNo: 4753641 PrepDate: 03-Oct-2018 DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Mercury 0.000100 U0.000200




Value %RECControl

LimitRPD Ref


LCS

Client ID:

Mercury 0.00487 0.005 0 97.4 80 - 1200.000200




Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP140_092718

Mercury 0.00426 0.005 0.00001 85.0 75 - 1250.000200




Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP140_092718

Mercury 0.00425 0.005 0.00001 84.8 75 - 125 0.00426 0.235 200.000200



00914816

Client:Project:



QC BATCH REPORT

Batch ID: 133017 Instrument: SV-5 Method: SW8270SIM

Sample ID: MBLK-133017 Units: ug/L Analysis Date: 04-Oct-2018 13:27

Run ID: SV-5_324715 SeqNo: 4754369 PrepDate: 01-Oct-2018 DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

1,4-Dioxane 0.010 U0.010

0.1031 0.08 0 129 40 - 1400Surr: 2-Fluorobiphenyl

0.07746 0.08 0 96.8 40 - 1400Surr: 4-Terphenyl-d14

0.05452 0.08 0 68.2 40 - 1400Surr: Nitrobenzene-d5

Sample ID: LCS-133017 Units: ug/L Analysis Date: 04-Oct-2018 12:01



Value %RECControl

LimitRPD Ref


LCS

Client ID:

1,4-Dioxane 0.0837 0.08 0 105 40 - 1400.010


0.08479 0.08 0 106 40 - 1400Surr: 4-Terphenyl-d14


Sample ID: LCSD-133017 Units: ug/L Analysis Date: 04-Oct-2018 12:22



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

1,4-Dioxane 0.0849 0.08 0 106 40 - 140 0.0837 1.43 200.010

0.1077 0.08 0 135 40 - 140 0.09856 8.83 200Surr: 2-Fluorobiphenyl

0.09281 0.08 0 116 40 - 140 0.08479 9.03 200Surr: 4-Terphenyl-d14

0.04611 0.08 0 57.6 40 - 140 0.0429 7.23 200Surr: Nitrobenzene-d5



00914817

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:






















2-Butanone 1.0 U2.0


2-Hexanone 1.0 U2.0




Acetone 2.0 U2.0

Benzene 0.50 U1.0




Bromoform 0.50 U1.0



00914818

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:















m,p-Xylene 1.0 U2.0





o-Xylene 0.50 U1.0


Styrene 0.50 U1.0



Toluene 0.50 U1.0









46.12 50 0 92.2 89 - 1121.0Surr: Toluene-d8


00914819

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:





1,1-Dichloroethane 20.06 20 0 100 77 - 1251.0

1,1-Dichloroethene 18.7 20 0 93.5 71 - 1311.0


1,2,3-Trichlorobenzene 18.69 20 0 93.5 69 - 1291.0

1,2,3-Trichloropropane 17.88 20 0 89.4 73 - 1221.0




1,2-Dibromoethane 20.82 20 0 104 77 - 1211.0


1,2-Dichloroethane 20.77 20 0 104 73 - 1281.0


1,3,5-Trimethylbenzene 19.65 20 0 98.2 75 - 1241.0





2-Butanone 36.82 40 0 92.1 56 - 1432.0

2-Chlorotoluene 21.67 20 0 108 79 - 1221.0

2-Hexanone 35.97 40 0 89.9 57 - 1392.0

4-Chlorotoluene 22.15 20 0 111 78 - 1221.0

4-Isopropyltoluene 18.88 20 0 94.4 77 - 1271.0

4-Methyl-2-pentanone 37.82 40 0 94.5 67 - 1302.0

Acetone 38.36 40 0 95.9 39 - 1602.0

Benzene 20.89 20 0 104 79 - 1201.0

Bromobenzene 20.11 20 0 101 80 - 1201.0



Bromoform 19.71 20 0 98.5 66 - 1301.0

Bromomethane 23.57 20 0 118 53 - 1411.0


00914820

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:

Carbon disulfide 38.55 40 0 96.4 64 - 1332.0


Chlorobenzene 21.39 20 0 107 82 - 1181.0

Chloroethane 19.99 20 0 99.9 60 - 1381.0

Chloroform 19.96 20 0 99.8 79 - 1241.0

Chloromethane 18.73 20 0 93.6 50 - 1391.0

cis-1,2-Dichloroethene 21.17 20 0 106 78 - 1231.0


Dibromochloromethane 20.78 20 0 104 74 - 1261.0

Dibromomethane 21.62 20 0 108 79 - 1231.0

Dichlorodifluoromethane 16.52 20 0 82.6 32 - 1521.0

Ethylbenzene 22.77 20 0 114 79 - 1211.0



m,p-Xylene 45.76 40 0 114 80 - 1212.0


Naphthalene 17.05 20 0 85.3 61 - 1281.0

n-Butylbenzene 20.89 20 0 104 75 - 1281.0

n-Propylbenzene 22.03 20 0 110 76 - 1261.0

o-Xylene 22.68 20 0 113 78 - 1221.0

sec-Butylbenzene 18.97 20 0 94.9 77 - 1261.0

Styrene 21.7 20 0 109 78 - 1231.0



Toluene 20.32 20 0 102 80 - 1211.0


trans-1,3-Dichloropropene 23.52 20 0 118 73 - 1271.0


Trichlorofluoromethane 19.71 20 0 98.5 65 - 1411.0

Vinyl chloride 19.68 20 0 98.4 58 - 1371.0




45.07 50 0 90.1 89 - 1121.0Surr: Toluene-d8


00914821

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS

Client ID:





1,1-Dichloroethane 19.79 20 0 99.0 77 - 1251.0

1,1-Dichloroethene 20.54 20 0 103 71 - 1311.0







1,2-Dibromoethane 19.69 20 0 98.4 77 - 1211.0

1,2-Dichlorobenzene 18.62 20 0 93.1 80 - 1191.0

1,2-Dichloroethane 20.34 20 0 102 73 - 1281.0


1,3,5-Trimethylbenzene 18.69 20 0 93.5 75 - 1241.0





2-Butanone 34.75 40 0 86.9 56 - 1432.0

2-Chlorotoluene 20.78 20 0 104 79 - 1221.0

2-Hexanone 33.39 40 0 83.5 57 - 1392.0

4-Chlorotoluene 20.66 20 0 103 78 - 1221.0

4-Isopropyltoluene 18.23 20 0 91.1 77 - 1271.0


Acetone 30.49 40 0 76.2 39 - 1602.0

Benzene 20.36 20 0 102 79 - 1201.0

Bromobenzene 18.53 20 0 92.7 80 - 1201.0

Bromochloromethane 19.75 20 0 98.8 78 - 1231.0


Bromoform 18.21 20 0 91.1 66 - 1301.0

Bromomethane 20.88 20 0 104 53 - 1411.0


00914822

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS

Client ID:



Chlorobenzene 20.04 20 0 100 82 - 1181.0

Chloroethane 19.92 20 0 99.6 60 - 1381.0

Chloroform 19.29 20 0 96.4 79 - 1241.0

Chloromethane 20.42 20 0 102 50 - 1391.0

cis-1,2-Dichloroethene 21.92 20 6.295 78.1 78 - 1231.0



Dibromomethane 19.85 20 0 99.2 79 - 1231.0

Dichlorodifluoromethane 16.07 20 0 80.4 32 - 1521.0

Ethylbenzene 22.09 20 0 110 79 - 1211.0

Hexachlorobutadiene 18.71 20 0 93.5 66 - 1341.0


m,p-Xylene 44.16 40 0 110 80 - 1212.0

Methylene chloride 21.36 20 3.64 88.6 74 - 1242.0

Naphthalene 14.24 20 0 71.2 61 - 1281.0

n-Butylbenzene 19.73 20 0 98.6 75 - 1281.0

n-Propylbenzene 21.28 20 0 106 76 - 1261.0

o-Xylene 21.71 20 0 109 78 - 1221.0

sec-Butylbenzene 18.77 20 0 93.8 77 - 1261.0

Styrene 20.12 20 0 101 78 - 1231.0

tert-Butylbenzene 21 20 0 105 78 - 1241.0


Toluene 19.95 20 0 99.8 80 - 1211.0


trans-1,3-Dichloropropene 21.34 20 0 107 73 - 1271.0

Trichloroethene 25.86 20 15.06 54.0 79 - 123 S1.0


Vinyl chloride 21.37 20 0 107 58 - 1371.0




44.72 50 0 89.4 89 - 1121.0Surr: Toluene-d8


00914823

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID:

1,1,1,2-Tetrachloroethane 19.69 20 0 98.4 78 - 124 19.53 0.828 201.0


1,1,2,2-Tetrachloroethane 16.71 20 0 83.5 71 - 121 16.71 0.00947 201.0


1,1-Dichloroethane 19.5 20 0 97.5 77 - 125 19.79 1.49 201.0

1,1-Dichloroethene 19.52 20 0 97.6 71 - 131 20.54 5.12 201.0


1,2,3-Trichlorobenzene 16.84 20 0 84.2 69 - 129 16.28 3.4 201.0

1,2,3-Trichloropropane 16.81 20 0 84.1 73 - 122 16.5 1.91 201.0

1,2,4-Trichlorobenzene 18.05 20 0 90.3 69 - 130 17.2 4.83 201.0



1,2-Dibromoethane 19.33 20 0 96.7 77 - 121 19.69 1.8 201.0

1,2-Dichlorobenzene 18.66 20 0 93.3 80 - 119 18.62 0.176 201.0

1,2-Dichloroethane 20.44 20 0 102 73 - 128 20.34 0.468 201.0


1,3,5-Trimethylbenzene 18.17 20 0 90.8 75 - 124 18.69 2.84 201.0





2-Butanone 35.16 40 0 87.9 56 - 143 34.75 1.18 202.0

2-Chlorotoluene 20.04 20 0 100 79 - 122 20.78 3.58 201.0

2-Hexanone 34.12 40 0 85.3 57 - 139 33.39 2.16 202.0

4-Chlorotoluene 20.54 20 0 103 78 - 122 20.66 0.583 201.0

4-Isopropyltoluene 17.72 20 0 88.6 77 - 127 18.23 2.85 201.0

4-Methyl-2-pentanone 35.29 40 0 88.2 67 - 130 35.1 0.562 202.0

Acetone 32.51 40 0 81.3 39 - 160 30.49 6.41 202.0

Benzene 19.64 20 0 98.2 79 - 120 20.36 3.58 201.0

Bromobenzene 18.44 20 0 92.2 80 - 120 18.53 0.518 201.0

Bromochloromethane 19.99 20 0 100.0 78 - 123 19.75 1.19 201.0

Bromodichloromethane 19.93 20 0 99.7 79 - 125 20.5 2.79 201.0

Bromoform 18.63 20 0 93.1 66 - 130 18.21 2.26 201.0

Bromomethane 21.28 20 0 106 53 - 141 20.88 1.92 201.0


00914824

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID:

Carbon disulfide 38.55 40 0 96.4 64 - 133 40.49 4.9 202.0

Carbon tetrachloride 19.89 20 0 99.5 72 - 136 21.02 5.48 201.0

Chlorobenzene 19.81 20 0 99.1 82 - 118 20.04 1.16 201.0

Chloroethane 19.08 20 0 95.4 60 - 138 19.92 4.31 201.0

Chloroform 18.77 20 0 93.8 79 - 124 19.29 2.74 201.0

Chloromethane 17.82 20 0 89.1 50 - 139 20.42 13.6 201.0

cis-1,2-Dichloroethene 20.46 20 6.295 70.8 78 - 123 21.92 6.9 20 S1.0

cis-1,3-Dichloropropene 20.9 20 0 105 75 - 124 21.54 3.03 201.0

Dibromochloromethane 19.45 20 0 97.3 74 - 126 18.93 2.71 201.0

Dibromomethane 18.96 20 0 94.8 79 - 123 19.85 4.58 201.0

Dichlorodifluoromethane 14.38 20 0 71.9 32 - 152 16.07 11.1 201.0

Ethylbenzene 21.69 20 0 108 79 - 121 22.09 1.79 201.0

Hexachlorobutadiene 18.6 20 0 93.0 66 - 134 18.71 0.611 201.0

Isopropylbenzene 19.39 20 0 97.0 72 - 131 20.08 3.51 201.0

m,p-Xylene 43.7 40 0 109 80 - 121 44.16 1.03 202.0

Methylene chloride 20.1 20 3.64 82.3 74 - 124 21.36 6.1 202.0

Naphthalene 15.26 20 0 76.3 61 - 128 14.24 6.92 201.0

n-Butylbenzene 19.87 20 0 99.3 75 - 128 19.73 0.704 201.0

n-Propylbenzene 20.66 20 0 103 76 - 126 21.28 2.95 201.0

o-Xylene 21.18 20 0 106 78 - 122 21.71 2.49 201.0

sec-Butylbenzene 18.07 20 0 90.3 77 - 126 18.77 3.79 201.0

Styrene 20.3 20 0 102 78 - 123 20.12 0.927 201.0

tert-Butylbenzene 20.04 20 0 100 78 - 124 21 4.69 201.0

Tetrachloroethene 19.39 20 0 96.9 74 - 129 20.24 4.3 201.0

Toluene 19.4 20 0 97.0 80 - 121 19.95 2.8 201.0

trans-1,2-Dichloroethene 19.96 20 0 99.8 75 - 124 20.89 4.56 201.0

trans-1,3-Dichloropropene 21.33 20 0 107 73 - 127 21.34 0.0145 201.0

Trichloroethene 22.71 20 15.06 38.3 79 - 123 25.86 13 20 S1.0

Trichlorofluoromethane 19.85 20 0 99.2 65 - 141 21.17 6.47 201.0

Vinyl chloride 19.56 20 0 97.8 58 - 137 21.37 8.86 201.0


50.23 50 0 100 85 - 114 50.1 0.253 201.0Surr: 4-Bromofluorobenzene


45.36 50 0 90.7 89 - 112 44.72 1.43 201.0Surr: Toluene-d8


00914825

Client:Project:



QC BATCH REPORT




00914826

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:







46.62 50 0 93.2 89 - 1121.0Surr: Toluene-d8




Value %RECControl

LimitRPD Ref


LCS

Client ID:







45.39 50 0 90.8 89 - 1121.0Surr: Toluene-d8




Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP140_092718

cis-1,2-Dichloroethene 6548 2000 4744 90.2 78 - 123100

Methylene chloride 7708 2000 5846 93.1 74 - 124200

Trichloroethene 8442 2000 6518 96.2 79 - 123100

4784 5000 0 95.7 81 - 118100Surr: 1,2-Dichloroethane-d4

5075 5000 0 101 85 - 114100Surr: 4-Bromofluorobenzene

4657 5000 0 93.1 80 - 119100Surr: Dibromofluoromethane

4550 5000 0 91.0 89 - 112100Surr: Toluene-d8


00914827

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP140_092718

cis-1,2-Dichloroethene 6412 2000 4744 83.4 78 - 123 6548 2.1 20100

Methylene chloride 7650 2000 5846 90.2 74 - 124 7708 0.756 20200

Trichloroethene 8013 2000 6518 74.7 79 - 123 8442 5.22 20 S100

4738 5000 0 94.8 81 - 118 4784 0.946 20100Surr: 1,2-Dichloroethane-d4

5134 5000 0 103 85 - 114 5075 1.16 20100Surr: 4-Bromofluorobenzene

4842 5000 0 96.8 80 - 119 4657 3.9 20100Surr: Dibromofluoromethane

4576 5000 0 91.5 89 - 112 4550 0.564 20100Surr: Toluene-d8



00914828

Client:Project:



QC BATCH REPORT

Batch ID: R324857 Instrument: Balance1 Method: E1664A

Sample ID: WBLKW-100518 Units: mg/L Analysis Date: 05-Oct-2018 14:40

Run ID: Balance1_324857 SeqNo: 4760511 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Oil and Grease 1.00 U2.00

Sample ID: WLCSW-100518 Units: mg/L Analysis Date: 05-Oct-2018 14:40



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Oil and Grease 38.8 40 0 97.0 78 - 1142.00

Sample ID: WLCSDW-100518 Units: mg/L Analysis Date: 05-Oct-2018 14:40



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Oil and Grease 39.2 40 0 98.0 78 - 114 38.8 1.03 182.00




Value %RECControl

LimitRPD Ref


MS

Client ID:

Oil and Grease 37.5 40 1.667 89.6 78 - 1142.00



00914829

Client:Project:



QC BATCH REPORT


Sample ID: MBLK-R324887 Units: mg/L Analysis Date: 06-Oct-2018 15:00



Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Chemical Oxygen Demand 10.0 U15.0

Sample ID: LCS-R324887 Units: mg/L Analysis Date: 06-Oct-2018 15:00



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Chemical Oxygen Demand 100 100 0 100 85 - 11515.0




Value %RECControl

LimitRPD Ref


MS

Client ID:


Sample ID: HS18091379-01DUP Units: mg/L Analysis Date: 06-Oct-2018 15:00



Value %RECControl

LimitRPD Ref


DUP

Client ID:

Chemical Oxygen Demand 5 6 0 20 J 15.0



00914830

Client:Project:



QC BATCH REPORT

Batch ID: R325252 Instrument: ICS2100 Method: SW9056

Sample ID: WBLKW1-101018 Units: mg/L Analysis Date: 10-Oct-2018 21:18

Run ID: ICS2100_325252 SeqNo: 4768832 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:



Sample ID: WLCSW1-101018 Units: mg/L Analysis Date: 10-Oct-2018 21:33



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Chloride 20.31 20 0 102 80 - 1200.500

Sulfate 20.22 20 0 101 80 - 1200.500

Sample ID: WLCSDW1-101018 Units: mg/L Analysis Date: 10-Oct-2018 21:47



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Chloride 20.01 20 0 100 80 - 120 20.31 1.49 200.500

Sulfate 20.01 20 0 100 80 - 120 20.22 1.02 200.500




Value %RECControl

LimitRPD Ref


MS

Client ID:

Chloride 380.1 100 286.7 93.5 80 - 1205.00

Sulfate 965.3 100 904.7 60.6 80 - 120 SO 5.00




Value %RECControl

LimitRPD Ref


MS

Client ID:

Chloride 290.3 10 273.9 164 80 - 120 SEO 0.500

Sulfate 885.2 10 852.3 330 80 - 120 SEO 0.500


00914831

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS

Client ID:

Chloride 292.7 10 280.7 120 80 - 120 EO 0.500

Sulfate 888.8 10 870.9 179 80 - 120 SEO 0.500




Value %RECControl

LimitRPD Ref


MS

Client ID:

Chloride 455.1 200 271.7 91.7 80 - 12010.0

Sulfate 992.9 200 853.2 69.9 80 - 120 SO 10.0




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Chloride 277.8 10 273.9 39.5 80 - 120 292.7 5.21 20 SEO 0.500

Sulfate 848.5 10 852.3 -37.9 80 - 120 888.8 4.64 20 SEO 0.500




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Chloride 376.5 100 286.7 89.9 80 - 120 380.1 0.953 205.00

Sulfate 957.5 100 904.7 52.8 80 - 120 965.3 0.811 20 SO 5.00




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Chloride 473.2 200 271.7 101 80 - 120 455.1 3.91 2010.0

Sulfate 1032 200 853.2 89.4 80 - 120 992.9 3.86 20 O 10.0


00914832

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID:

Chloride 283 10 280.7 22.8 80 - 120 292.7 3.37 20 SEO 0.500

Sulfate 865.7 10 870.9 -51.5 80 - 120 888.8 2.62 20 SEO 0.500



00914833



Bhate Environmental Associates, Inc.Groundwater Treatment Plant Quarterly Influent SamplesHS18091519


a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution





00914834




Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


00914835

NDD


HS18091519

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

3.2C/2.8C UC/C IR # 11431029/28/2018 15:00


Yes No N/A

Yes No N/A


28-Sep-201828-Sep-2018





Comments:

Corrective Action:

Yes



00914836

00914837

00914838

Case Narrative Method: 6850 Analysis: Perchlorate Analysis SOP: LC-MS-CLO4 ALS WO ID(s): 1827567; 1827568; 1827569


General Set Information: There were three field samples in these Work Orders. The samples were analyzed for perchlorate. Method Summary: Each sample was prepared as noted below and analyzed using an Agilent 1100 LC/MSD system in select ion monitoring (SIM) mode at m/z 83 and 85, which corresponds to the loss of one oxygen atom from the perchlorate molecule. ChemStation software was used for instrument control and data analysis. The ion ratio of m/z 83 to 85 was used to positively identify the response peak as perchlorate. Quantitation was performed using the m/z 83 peak area. An internal standard (ISTD) of 18O labeled perchlorate was added to each sample to establish the perchlorate peak retention time and used in quantitation. Sample Preparation: A 10.0mL aliquot of each sample was transferred into a 15-mL centrifuge tube. 50µL of an 18O labeled perchlorate solution was added to each sample as an internal standard. The samples were then capped, vortexed, and filtered into autosampler vial using Phenex PES membrane 0.45µm Syringe filters. Holding Times: Holding times were met for all analyses. Dilutions: Sample 1827568001 was analyzed and reported from a 1:1,000 dilution. The reporting limit has been adjusted accordingly. Method QC data: The method blank (LMB 621931) was less than 1/2 the CRDL. The recovery for the LCS (621932) was within acceptable parameters.

00914839

MS/MSD Analysis: MS/MSD was performed on sample 1827567001 (Client ID: LH18/24-SP650_092718_BIX). 5.0µl of Working Standard Solution Horizon ID 41828 was added to 10.0mL of sample preparation. The spike target was 5.µg/L. The percent recoveries and relative percent difference (RPD) were within the performance limits. Instrument QC: Instrument initial and continuing calibrations were performed in accordance with published procedures. NC/CAR(s): NA Sample Calculation: Samples were reported in µg/L. Results were calculated in µg/L by the equation (A)x(B),

where: A = Analyte concentration from the standard curve (µg/L) B = Dilution performed at time of analysis Miscellaneous Comments: These samples were analyzed in accordance with the requirements found in the DOD QSM Version 5.1. Due to limitations of the Chemstation Software, some of the chromatographic peaks require manual integration. A manual integration was performed for datafile 09OCTD10.

Thomas Bosch October 12, 2018 Analyst Date

00914840

ANALYTICAL REPORT


Phone:

E-mail:

281 530-5656

[email protected]

Report Date: October 15, 2018



Project ID:



1827568001 09/27/18LH18/24-SP140_092718_BIX 10/02/18

Page 1 of 3 Mon, 10/15/18 7:56 PM ENVREP-V4.8



||

00914841

ANALYTICAL REPORT




Analytical Results

Sample ID: 09/27/201810/02/20181827568001Lab ID:

Collected:Received:

LH18/24-SP140_092718_BIX NA


Media:

Water





LCMS04

Report Basis: Wet




400010008800 2000Perchlorate 1000

Comments

Quality Control: EPA 6850, DoD QSM - (HBN: 224328)

Sample 1827568001 was analyzed and reported from a 1:1,000 dilution. The reporting limit has been adjusted accordingly.





/S/ Stephen Brose



Phone:Email:Web:


00914842

ANALYTICAL REPORT










Website








00914843

Analysis:


Workorder: 1827568




Limits:Basis:


Blank

LMB:

Analyte

Units:

Result

Analyzed:62193110/09/2018 09:45

ug/L

MDL RL



Dilution: 1ug/L


LCS:Analyzed:

62193210/09/2018 09:59

Units:

Target

Perchlorate 5.23 5.00 78.8 123.8105


MS:Analyzed:


110/09/2018 10:29621933Sample:

Analyzed:Dilution:

Units: ug/L110/09/2018 10:151827567001


MSD:Analyzed:

62193410/09/2018 10:43

% Rec



Perchlorate ND 78.8 123.85 96.44.82 20.00.04.74 1.6394.8



CCV:Analyzed:

62192810/09/2018 09:02

Units:

Target


Result % Rec.

CCV:Analyzed:

62193510/09/2018 11:36

Units:

Target


Perchlorate 24.5 25.0 98.0 24.4 25.0 97.6



ICSA:Analyzed:

62193010/09/2018 09:31

Units:

Target


Perchlorate 1.02 1.00 102



LODV:Analyzed:

62192910/09/2018 09:17

Units:

Target


Result % Rec.

LODV:Analyzed:

62193610/09/2018 11:50

Units:

Target


Perchlorate 1.02 1.00 102 0.958 1.00 95.8

Page 1 of 2 Monday, October 15, 2018


QCS V4.4

00914844

Analysis:


Workorder: 1827568




Limits:Basis:


CommentsSample 1827568001 was analyzed and reported from a 1:1,000 dilution. The reporting limit has been adjusted accordingly.






# -

Analyst Peer Review


10/12/2018 14:19 10/15/2018 08:43



QCS V4.4

00914845

00914846

00914847

00914848

00914849

00914850

00914851

00914852

00914853

00914854

00914855

00914856

00914857

00914858

00914859

00914860

00914861

00914862

00914863

00914864

00914865

00914866

00914867

October 17, 2018





Sincerely,


Laboratory Results for: Groundwater Treatment Plant Quarterly Effluent Samples

Dear Marcia,


Project Manager


RJ Modashia



00914868


Work Order: HS18091521Project: Groundwater Treatment Plant Quarterly Effluent Samples SAMPLE SUMMARY




HS18091521-03 27-Sep-2018 14:00ALS-050418-45

28-Sep-2018 08:55Trip Blank Water


00914869


Work Order:Groundwater Treatment Plant Quarterly Effluent SamplesBhate Environmental Associates, Inc.

Project:

Work Order Comments


GCMS Semivolatiles by Method SW8270SIM

Batch ID: 133017Sample ID: LH18/24-SP650_092718 (HS18091521-01)

The surrogate recoveries could not be determined due to dilution below the calibration range. •



MS and MSD are for an unrelated sample•


Batch ID: 133116



Batch ID: 133107Sample ID: HS18091510-01MS

MS/MSD and DUPs are for an unrelated sample•



MS and MSD are for an unrelated sample (Chloride,Sulfate)•


Batch ID: R324887


WetChemistry by Method E1664A

Batch ID: R324857



00914870


Bhate Environmental Associates, Inc.Groundwater Treatment Plant Quarterly Effluent SamplesLH18/24-SP650_092718

WorkOrder:Lab ID:

Collection Date:

HS18091521HS18091521-01


ANALYTICAL REPORT
































1ug/L 10-Oct-2018 15:24U 0.40Acetone 2.02.0 2.0

1ug/L 10-Oct-2018 15:24U 0.20Benzene 1.00.50 0.50













00914871



WorkOrder:Lab ID:

Collection Date:

HS18091521HS18091521-01


ANALYTICAL REPORT






1ug/L 10-Oct-2018 15:240.20cis-1,2-Dichloroethene 1.03.0 0.501ug/L 10-Oct-2018 15:24U 0.10cis-1,3-Dichloropropene 1.00.50 0.50












1ug/L 10-Oct-2018 15:24U 0.30o-Xylene 1.00.50 0.50


1ug/L 10-Oct-2018 15:24U 0.30Styrene 1.00.50 0.50



1ug/L 10-Oct-2018 15:24U 0.20Toluene 1.00.50 0.50



1ug/L 10-Oct-2018 15:24J 0.20Trichloroethene 1.00.82 0.501ug/L 10-Oct-2018 15:24U 0.30Trichlorofluoromethane 1.00.50 0.50



SEMIVOLATILES SIM Method:SW8270SIM Analyst: ACNPrep:SW3510 / 01-Oct-2018

100ug/L 04-Oct-2018 14:091.01,4-Dioxane 1.07.5 1.0Surr: 2-Fluorobiphenyl 100%REC 04-Oct-2018 14:09S0 40-1400

Surr: 4-Terphenyl-d14 100%REC 04-Oct-2018 14:09S0 40-1400

Surr: Nitrobenzene-d5 100%REC 04-Oct-2018 14:09S0 40-1400



00914872



WorkOrder:Lab ID:

Collection Date:

HS18091521HS18091521-01


ANALYTICAL REPORT



ICP-MS METALS BY SW6020A Method:SW6020 Analyst: JDEPrep:SW3010A / 03-Oct-2018

1mg/L 12-Oct-2018 16:01J 0.00180Aluminum 0.01000.00919 0.005001mg/L 12-Oct-2018 16:01U 0.000400Antimony 0.002000.00100 0.00100

1mg/L 12-Oct-2018 16:01J 0.000400Arsenic 0.002000.000643 0.001001mg/L 12-Oct-2018 16:010.00190Barium 0.004000.149 0.002501mg/L 12-Oct-2018 16:01U 0.000200Beryllium 0.002000.00100 0.00100

1mg/L 12-Oct-2018 16:01U 0.000200Cadmium 0.002000.00100 0.00100

1mg/L 12-Oct-2018 16:010.0340Calcium 0.50012.9 0.1001mg/L 12-Oct-2018 16:01J 0.000400Chromium 0.004000.00120 0.001001mg/L 12-Oct-2018 16:01J 0.000200Cobalt 0.005000.000427 0.001001mg/L 12-Oct-2018 16:01J 0.0120Iron 0.2000.0997 0.1001mg/L 12-Oct-2018 16:01U 0.000600Lead 0.002000.00100 0.00100

1mg/L 12-Oct-2018 16:010.0100Magnesium 0.20032.0 0.1001mg/L 12-Oct-2018 16:010.000700Manganese 0.005000.107 0.001001mg/L 12-Oct-2018 16:010.000600Nickel 0.002000.00353 0.001001mg/L 12-Oct-2018 16:010.0180Potassium 0.2001.57 0.1001mg/L 12-Oct-2018 16:01U 0.00110Selenium 0.002000.00200 0.00200

1mg/L 12-Oct-2018 16:01U 0.000200Silver 0.002000.00100 0.00100

10mg/L 12-Oct-2018 17:390.140Sodium 2.00433 1.001mg/L 12-Oct-2018 16:01U 0.000200Thallium 0.002000.00100 0.00100

1mg/L 12-Oct-2018 16:01J 0.000600Vanadium 0.005000.000853 0.001001mg/L 12-Oct-2018 16:010.00200Zinc 0.004000.0130 0.00250

MERCURY BY SW7470A Method:SW7470 Analyst: JCJPrep:SW7470 / 03-Oct-2018

1mg/L 03-Oct-2018 17:01U 0.0000300Mercury 0.0002000.000100 0.000100

OIL & GREASE (HEM) BY E1664A Method:E1664A Analyst: KAH1mg/L 05-Oct-2018 14:400.610Oil and Grease 2.006.20 1.00

CHEMICAL OXYGEN DEMAND BY E410.4 Method:E410.4 Analyst: AJH1mg/L 06-Oct-2018 15:005.00Chemical Oxygen Demand 15.047.0 10.0

ANIONS BY SW9056A Method:SW9056 Analyst: KMU10mg/L 11-Oct-2018 08:132.00Chloride 5.00572 5.0010mg/L 11-Oct-2018 08:132.00Sulfate 5.0041.4 5.00



00914873


Bhate Environmental Associates, Inc.Groundwater Treatment Plant Quarterly Effluent SamplesLH18/24-SP650_092718_BIX

WorkOrder:Lab ID:

Collection Date:

HS18091521HS18091521-02


ANALYTICAL REPORT








00914874


Bhate Environmental Associates, Inc.Groundwater Treatment Plant Quarterly Effluent SamplesTrip Blank

WorkOrder:Lab ID:

Collection Date:

HS18091521HS18091521-03


ANALYTICAL REPORT
































1ug/L 10-Oct-2018 14:09U 0.40Acetone 2.02.0 2.0

1ug/L 10-Oct-2018 14:09U 0.20Benzene 1.00.50 0.50













00914875


Bhate Environmental Associates, Inc.Groundwater Treatment Plant Quarterly Effluent SamplesTrip Blank

WorkOrder:Lab ID:

Collection Date:

HS18091521HS18091521-03


ANALYTICAL REPORT



















1ug/L 10-Oct-2018 14:09U 0.30o-Xylene 1.00.50 0.50


1ug/L 10-Oct-2018 14:09U 0.30Styrene 1.00.50 0.50



1ug/L 10-Oct-2018 14:09U 0.20Toluene 1.00.50 0.50









00914876

WEIGHT LOG

HS18091521Groundwater Treatment Plant Quarterly Effluent SamplesBhate Environmental Associates, Inc.


Batch ID: 133017 Method: SEMIVOLATILES SIM 3510_B_SIMPrep:


Final Volume

Prep Factor

HS18091521-01 1 990 1 (mL) 0.00101



Final Volume

Prep Factor

HS18091521-01 1 10 10 (mL) 1

Batch ID: 133116 Method: MERCURY BY SW7470A HG_WPRPrep:


Final Volume

Prep Factor

HS18091521-01 1 10 (mL) 10 (mL) 1

17-Oct-18Date: ALS Houston, US00914877

Client:Groundwater Treatment Plant Quarterly Effluent SamplesBhate Environmental Associates, Inc.

WorkOrder:Project:



Batch ID 133017 Test Name : SEMIVOLATILES SIM Matrix: Water





Batch ID 133116 Test Name : MERCURY BY SW7470A Matrix: Water


Batch ID R324857 Test Name : OIL & GREASE (HEM) BY E1664A Matrix: Water

05 Oct 2018 14:40HS18091521-01 27 Sep 2018 14:00 1LH18/24-SP650_092718

Batch ID R324887 Test Name : CHEMICAL OXYGEN DEMAND BY E410.4 Matrix: Water

06 Oct 2018 15:00HS18091521-01 27 Sep 2018 14:00 1LH18/24-SP650_092718


10 Oct 2018 15:24HS18091521-01 27 Sep 2018 14:00 1LH18/24-SP650_092718

10 Oct 2018 14:09HS18091521-03 27 Sep 2018 14:00 1Trip Blank


11 Oct 2018 08:13HS18091521-01 27 Sep 2018 14:00 10LH18/24-SP650_092718




00914878

Client:Project:

Bhate Environmental Associates, Inc.Groundwater Treatment Plant Quarterly Effluent Samples


QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Aluminum 0.003938 J 0.0100

Antimony 0.00100 U0.00200

Arsenic 0.00100 U0.00200

Barium 0.00250 U0.00400

Beryllium 0.00100 U0.00200

Cadmium 0.00100 U0.00200

Calcium 0.100 U0.500

Chromium 0.00100 U0.00400

Cobalt 0.00100 U0.00500

Iron 0.100 U0.200

Lead 0.00100 U0.00200

Magnesium 0.01631 J 0.200

Manganese 0.000827 J 0.00500

Nickel 0.00100 U0.00200

Potassium 0.100 U0.200

Selenium 0.00200 U0.00200

Silver 0.00100 U0.00200

Sodium 0.04046 J 0.200

Thallium 0.00100 U0.00200

Vanadium 0.00100 U0.00500

Zinc 0.00250 U0.00400


00914879

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:

Aluminum 0.09632 0.1 0 96.3 80 - 1200.0100

Antimony 0.04314 0.05 0 86.3 80 - 1200.00200

Arsenic 0.04584 0.05 0 91.7 80 - 1200.00200

Barium 0.04195 0.05 0 83.9 80 - 1200.00400

Beryllium 0.04591 0.05 0 91.8 80 - 1200.00200

Cadmium 0.04485 0.05 0 89.7 80 - 1200.00200

Calcium 4.536 5 0 90.7 80 - 1200.500

Chromium 0.04653 0.05 0 93.1 80 - 1200.00400

Cobalt 0.04521 0.05 0 90.4 80 - 1200.00500

Iron 4.734 5 0 94.7 80 - 1200.200

Lead 0.0492 0.05 0 98.4 80 - 1200.00200

Magnesium 4.643 5 0 92.9 80 - 1200.200

Manganese 0.04672 0.05 0 93.4 80 - 1200.00500

Nickel 0.04794 0.05 0 95.9 80 - 1200.00200

Potassium 4.479 5 0 89.6 80 - 1200.200

Selenium 0.04466 0.05 0 89.3 80 - 1200.00200

Silver 0.04366 0.05 0 87.3 80 - 1200.00200

Sodium 4.66 5 0 93.2 80 - 1200.200

Thallium 0.04066 0.05 0 81.3 80 - 1200.00200

Vanadium 0.04449 0.05 0 89.0 80 - 1200.00500

Zinc 0.04813 0.05 0 96.3 80 - 1200.00400


00914880

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS

Client ID:

Aluminum 4.726 0.1 0.5282 4200 80 - 120 SEO 0.0100

Antimony 0.04247 0.05 0.000119 84.7 80 - 1200.00200

Arsenic 0.0468 0.05 0.000926 91.7 80 - 1200.00200

Barium 0.1138 0.05 0.05916 109 80 - 1200.00400

Beryllium 0.05194 0.05 0.000176 104 80 - 1200.00200

Cadmium 0.0463 0.05 0.000141 92.3 80 - 1200.00200

Calcium 24.36 5 19.43 98.6 80 - 1200.500

Chromium 0.05258 0.05 0.001736 102 80 - 1200.00400

Cobalt 0.04673 0.05 0.003111 87.2 80 - 1200.00500

Iron 8.85 5 1.06 156 80 - 120 S 0.200

Lead 0.051 0.05 0.00156 98.9 80 - 1200.00200

Magnesium 19.04 5 14.62 88.5 80 - 1200.200

Manganese 0.1588 0.05 0.1081 101 80 - 1200.00500

Nickel 0.05439 0.05 0.005499 97.8 80 - 1200.00200

Potassium 5.112 5 0.3724 94.8 80 - 1200.200

Selenium 0.04482 0.05 -0.000243 90.1 80 - 1200.00200

Silver 0.04304 0.05 0.000012 86.1 80 - 1200.00200

Sodium 71.07 5 67.3 75.3 80 - 120 SO 0.200

Thallium 0.04247 0.05 0.000044 84.8 80 - 1200.00200

Vanadium 0.05476 0.05 0.002494 105 80 - 1200.00500

Zinc 0.06572 0.05 0.013 105 80 - 1200.00400




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Aluminum 5.463 0.1 0.5282 4930 80 - 120 4.726 14.5 20 SEO 0.0100

Calcium 25.64 5 19.43 124 80 - 120 24.36 5.14 20 S 0.500

Iron 9.125 5 1.06 161 80 - 120 8.85 3.07 20 S 0.200


00914881

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID:

Antimony 0.04177 0.05 0.000119 83.3 80 - 120 0.04247 1.67 200.00200

Arsenic 0.04676 0.05 0.000926 91.7 80 - 120 0.0468 0.0941 200.00200

Barium 0.1127 0.05 0.05916 107 80 - 120 0.1138 0.925 200.00400

Beryllium 0.04994 0.05 0.000176 99.5 80 - 120 0.05194 3.92 200.00200

Cadmium 0.04465 0.05 0.000141 89.0 80 - 120 0.0463 3.63 200.00200

Chromium 0.05627 0.05 0.001736 109 80 - 120 0.05258 6.78 200.00400

Cobalt 0.04857 0.05 0.003111 90.9 80 - 120 0.04673 3.87 200.00500

Lead 0.0513 0.05 0.00156 99.5 80 - 120 0.051 0.602 200.00200

Magnesium 18.96 5 14.62 86.9 80 - 120 19.04 0.428 200.200

Manganese 0.1622 0.05 0.1081 108 80 - 120 0.1588 2.08 200.00500

Nickel 0.05772 0.05 0.005499 104 80 - 120 0.05439 5.95 200.00200

Potassium 5.179 5 0.3724 96.1 80 - 120 5.112 1.3 200.200

Selenium 0.04326 0.05 -0.000243 87.0 80 - 120 0.04482 3.55 200.00200

Silver 0.04192 0.05 0.000012 83.8 80 - 120 0.04304 2.63 200.00200

Sodium 68.54 5 67.3 24.7 80 - 120 71.07 3.62 20 SO 0.200

Thallium 0.04137 0.05 0.000044 82.6 80 - 120 0.04247 2.62 200.00200

Vanadium 0.05928 0.05 0.002494 114 80 - 120 0.05476 7.93 200.00500

Zinc 0.06998 0.05 0.013 114 80 - 120 0.06572 6.29 200.00400


00914882

Client:Project:



QC BATCH REPORT


Sample ID: HS18091510-01PDS Units: mg/L Analysis Date: 12-Oct-2018 15:53



Value %RECControl

LimitRPD Ref


PDS

Client ID:

Aluminum 1.424 0.1 0.5282 896 75 - 125 SO 0.0100

Antimony 0.07982 0.1 0.000119 79.7 75 - 1250.00200

Arsenic 0.09224 0.1 0.000926 91.3 75 - 1250.00200

Barium 0.1421 0.1 0.05916 83.0 75 - 1250.00400

Beryllium 0.08857 0.1 0.000176 88.4 75 - 1250.00200

Cadmium 0.08591 0.1 0.000141 85.8 75 - 1250.00200

Calcium 25.62 10 19.43 61.9 75 - 125 S 0.500

Chromium 0.09602 0.1 0.001736 94.3 75 - 1250.00400

Cobalt 0.09176 0.1 0.003111 88.7 75 - 1250.00500

Iron 12.38 10 1.06 113 75 - 1250.200

Lead 0.0991 0.1 0.00156 97.5 75 - 1250.00200

Magnesium 22.89 10 14.62 82.7 75 - 1250.200

Manganese 0.1982 0.1 0.1081 90.1 75 - 1250.00500

Nickel 0.1024 0.1 0.005499 96.9 75 - 1250.00200

Potassium 8.668 10 0.3724 83.0 75 - 1250.200

Selenium 0.08765 0.1 -0.000243 87.9 75 - 1250.00200

Silver 0.08348 0.1 0.000012 83.5 75 - 1250.00200

Sodium 72.5 10 67.3 52.0 75 - 125 SO 0.200

Thallium 0.08515 0.1 0.000044 85.1 75 - 1250.00200

Vanadium 0.09683 0.1 0.002494 94.3 75 - 1250.00500

Zinc 0.1093 0.1 0.013 96.3 75 - 1250.00400


00914883

Client:Project:



QC BATCH REPORT


Sample ID: HS18091510-01SD Units: mg/L Analysis Date: 12-Oct-2018 15:47



Value %RECControl

LimitRPD Ref


SD

Client ID:

Aluminum 0.5592 0.5282 5.86 100.0500

Antimony 0.00500 0.000119 0 10 U0.0100

Arsenic 0.00500 0.000926 0 10 U0.0100

Barium 0.0582 0.05916 1.63 100.0200

Beryllium 0.00500 0.000176 0 10 U0.0100

Cadmium 0.00500 0.000141 0 10 U0.0100

Calcium 18.7 19.43 3.76 102.50

Chromium 0.00500 0.001736 0 10 U0.0200

Cobalt 0.003176 0.003111 0 10 J 0.0250

Iron 1.076 1.06 1.54 101.00

Lead 0.00500 0.00156 0 10 U0.0100

Magnesium 15.56 14.62 6.47 101.00

Manganese 0.1133 0.1081 4.76 100.0250

Nickel 0.00446 0.005499 0 10 J 0.0100

Potassium 0.500 0.3724 0 10 U1.00

Selenium 0.0100 -0.000243 0 10 U0.0100

Silver 0.00500 0.000012 0 10 U0.0100

Sodium 69.24 67.3 2.87 101.00

Thallium 0.00500 0.000044 0 10 U0.0100

Vanadium 0.00500 0.002494 0 10 U0.0250

Zinc 0.0131 0.013 0 10 J 0.0200



00914884

Client:Project:



QC BATCH REPORT

Batch ID: 133116 Instrument: HG03 Method: SW7470




Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Mercury 0.000100 U0.000200




Value %RECControl

LimitRPD Ref


LCS

Client ID:

Mercury 0.00487 0.005 0 97.4 80 - 1200.000200




Value %RECControl

LimitRPD Ref


MS

Client ID:

Mercury 0.00426 0.005 0.00001 85.0 75 - 1250.000200




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Mercury 0.00425 0.005 0.00001 84.8 75 - 125 0.00426 0.235 200.000200



00914885

Client:Project:



QC BATCH REPORT

Batch ID: 133017 Instrument: SV-5 Method: SW8270SIM

Sample ID: MBLK-133017 Units: ug/L Analysis Date: 04-Oct-2018 13:27



Value %RECControl

LimitRPD Ref


MBLK

Client ID:

1,4-Dioxane 0.010 U0.010


0.07746 0.08 0 96.8 40 - 1400Surr: 4-Terphenyl-d14


Sample ID: LCS-133017 Units: ug/L Analysis Date: 04-Oct-2018 12:01



Value %RECControl

LimitRPD Ref


LCS

Client ID:

1,4-Dioxane 0.0837 0.08 0 105 40 - 1400.010


0.08479 0.08 0 106 40 - 1400Surr: 4-Terphenyl-d14


Sample ID: LCSD-133017 Units: ug/L Analysis Date: 04-Oct-2018 12:22



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

1,4-Dioxane 0.0849 0.08 0 106 40 - 140 0.0837 1.43 200.010

0.1077 0.08 0 135 40 - 140 0.09856 8.83 200Surr: 2-Fluorobiphenyl

0.09281 0.08 0 116 40 - 140 0.08479 9.03 200Surr: 4-Terphenyl-d14

0.04611 0.08 0 57.6 40 - 140 0.0429 7.23 200Surr: Nitrobenzene-d5



00914886

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:






















2-Butanone 1.0 U2.0


2-Hexanone 1.0 U2.0




Acetone 2.0 U2.0

Benzene 0.50 U1.0




Bromoform 0.50 U1.0



00914887

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:















m,p-Xylene 1.0 U2.0





o-Xylene 0.50 U1.0


Styrene 0.50 U1.0



Toluene 0.50 U1.0









53.57 50 0 107 89 - 1121.0Surr: Toluene-d8


00914888

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:





1,1-Dichloroethane 18.77 20 0 93.8 77 - 1251.0

1,1-Dichloroethene 18.27 20 0 91.4 71 - 1311.0

1,1-Dichloropropene 19.97 20 0 99.8 78 - 1251.0






1,2-Dibromoethane 19.84 20 0 99.2 77 - 1211.0


1,2-Dichloroethane 19.91 20 0 99.6 73 - 1281.0







2-Butanone 37.7 40 0 94.2 56 - 1432.0

2-Chlorotoluene 20.57 20 0 103 79 - 1221.0

2-Hexanone 37.77 40 0 94.4 57 - 1392.0

4-Chlorotoluene 20.9 20 0 104 78 - 1221.0



Acetone 49.81 40 0 125 39 - 1602.0

Benzene 21.02 20 0 105 79 - 1201.0

Bromobenzene 19.73 20 0 98.6 80 - 1201.0

Bromochloromethane 19.93 20 0 99.6 78 - 1231.0


Bromoform 15.07 20 0 75.4 66 - 1301.0

Bromomethane 17.72 20 0 88.6 53 - 1411.0


00914889

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:

Carbon disulfide 39.93 40 0 99.8 64 - 1332.0

Carbon tetrachloride 17.63 20 0 88.1 72 - 1361.0

Chlorobenzene 20.05 20 0 100 82 - 1181.0

Chloroethane 20.68 20 0 103 60 - 1381.0

Chloroform 18.91 20 0 94.6 79 - 1241.0

Chloromethane 19.26 20 0 96.3 50 - 1391.0

cis-1,2-Dichloroethene 18.98 20 0 94.9 78 - 1231.0



Dibromomethane 19.13 20 0 95.6 79 - 1231.0


Ethylbenzene 19.79 20 0 99.0 79 - 1211.0


Isopropylbenzene 19.69 20 0 98.4 72 - 1311.0

m,p-Xylene 39.47 40 0 98.7 80 - 1212.0


Naphthalene 20.37 20 0 102 61 - 1281.0

n-Butylbenzene 22.13 20 0 111 75 - 1281.0

n-Propylbenzene 21.06 20 0 105 76 - 1261.0

o-Xylene 19.91 20 0 99.5 78 - 1221.0


Styrene 20.13 20 0 101 78 - 1231.0


Tetrachloroethene 19.8 20 0 99.0 74 - 1291.0

Toluene 20.76 20 0 104 80 - 1211.0

trans-1,2-Dichloroethene 19.3 20 0 96.5 75 - 1241.0


Trichloroethene 19.21 20 0 96.0 79 - 1231.0

Trichlorofluoromethane 17.89 20 0 89.5 65 - 1411.0

Vinyl chloride 21.14 20 0 106 58 - 1371.0




53.41 50 0 107 89 - 1121.0Surr: Toluene-d8


00914890

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS

Client ID:





1,1-Dichloroethane 21.37 20 0 107 77 - 1251.0

1,1-Dichloroethene 21.44 20 0 107 71 - 1311.0







1,2-Dibromoethane 21.41 20 0 107 77 - 1211.0


1,2-Dichloroethane 21.44 20 0 107 73 - 1281.0


1,3,5-Trimethylbenzene 22 20 0 110 75 - 1241.0





2-Butanone 40.86 40 0 102 56 - 1432.0

2-Chlorotoluene 22.09 20 0 110 79 - 1221.0

2-Hexanone 40.55 40 0 101 57 - 1392.0

4-Chlorotoluene 22.11 20 0 111 78 - 1221.0


4-Methyl-2-pentanone 40.55 40 0 101 67 - 1302.0

Acetone 52.15 40 0 130 39 - 1602.0

Benzene 23.12 20 0 116 79 - 1201.0

Bromobenzene 20.98 20 0 105 80 - 1201.0



Bromoform 16.92 20 0 84.6 66 - 1301.0

Bromomethane 6.088 20 0 30.4 53 - 141 S1.0


00914891

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS

Client ID:



Chlorobenzene 21.97 20 0 110 82 - 1181.0

Chloroethane 27.8 20 0 139 60 - 138 S 1.0

Chloroform 20.84 20 0 104 79 - 1241.0

Chloromethane 17 20 0 85.0 50 - 1391.0




Dibromomethane 21.14 20 0 106 79 - 1231.0


Ethylbenzene 21.52 20 0 108 79 - 1211.0


Isopropylbenzene 22 20 0 110 72 - 1311.0

m,p-Xylene 43.29 40 0 108 80 - 1212.0


Naphthalene 21.39 20 0 107 61 - 1281.0

n-Butylbenzene 23.43 20 0 117 75 - 1281.0

n-Propylbenzene 22.97 20 0 115 76 - 1261.0

o-Xylene 21.45 20 0 107 78 - 1221.0


Styrene 21.65 20 0 108 78 - 1231.0



Toluene 22.73 20 0 114 80 - 1211.0





Vinyl chloride 23.01 20 0 115 58 - 1371.0




53.14 50 0 106 89 - 1121.0Surr: Toluene-d8


00914892

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID:




1,1,2-Trichloroethane 22.1 20 0 111 80 - 119 21.87 1.06 201.0

1,1-Dichloroethane 20.75 20 0 104 77 - 125 21.37 2.97 201.0

1,1-Dichloroethene 20.63 20 0 103 71 - 131 21.44 3.85 201.0



1,2,3-Trichloropropane 20.24 20 0 101 73 - 122 20.25 0.0532 201.0




1,2-Dibromoethane 21.27 20 0 106 77 - 121 21.41 0.632 201.0


1,2-Dichloroethane 21.27 20 0 106 73 - 128 21.44 0.82 201.0


1,3,5-Trimethylbenzene 21.34 20 0 107 75 - 124 22 3.06 201.0





2-Butanone 41.96 40 0 105 56 - 143 40.86 2.66 202.0

2-Chlorotoluene 21.66 20 0 108 79 - 122 22.09 1.98 201.0

2-Hexanone 41.5 40 0 104 57 - 139 40.55 2.32 202.0

4-Chlorotoluene 21.86 20 0 109 78 - 122 22.11 1.14 201.0

4-Isopropyltoluene 22.52 20 0 113 77 - 127 22.93 1.78 201.0

4-Methyl-2-pentanone 40.71 40 0 102 67 - 130 40.55 0.394 202.0

Acetone 53.86 40 0 135 39 - 160 52.15 3.22 202.0

Benzene 22.4 20 0 112 79 - 120 23.12 3.15 201.0

Bromobenzene 20.47 20 0 102 80 - 120 20.98 2.44 201.0

Bromochloromethane 20.69 20 0 103 78 - 123 21.63 4.44 201.0

Bromodichloromethane 19.21 20 0 96.0 79 - 125 19.68 2.44 201.0

Bromoform 16.77 20 0 83.9 66 - 130 16.92 0.867 201.0

Bromomethane 7.45 20 0 37.3 53 - 141 6.088 20.1 20 SR1.0


00914893

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID:

Carbon disulfide 54.62 40 0 137 64 - 133 47.13 14.7 20 S2.0

Carbon tetrachloride 20.58 20 0 103 72 - 136 21.48 4.26 201.0

Chlorobenzene 21.53 20 0 108 82 - 118 21.97 2.02 201.0

Chloroethane 25.39 20 0 127 60 - 138 27.8 9.04 201.0

Chloroform 20.32 20 0 102 79 - 124 20.84 2.53 201.0

Chloromethane 15.29 20 0 76.5 50 - 139 17 10.6 201.0

cis-1,2-Dichloroethene 19.77 20 0 98.9 78 - 123 20.33 2.76 201.0

cis-1,3-Dichloropropene 18.78 20 0 93.9 75 - 124 19.35 2.99 201.0

Dibromochloromethane 19.48 20 0 97.4 74 - 126 19.81 1.68 201.0

Dibromomethane 20.76 20 0 104 79 - 123 21.14 1.82 201.0

Dichlorodifluoromethane 22.35 20 0 112 32 - 152 23.04 3.03 201.0

Ethylbenzene 21.28 20 0 106 79 - 121 21.52 1.1 201.0

Hexachlorobutadiene 24.53 20 0 123 66 - 134 24.31 0.92 201.0

Isopropylbenzene 21.65 20 0 108 72 - 131 22 1.62 201.0

m,p-Xylene 42.86 40 0 107 80 - 121 43.29 0.98 202.0

Methylene chloride 26.65 20 0 133 74 - 124 22.42 17.2 20 S2.0

Naphthalene 21.33 20 0 107 61 - 128 21.39 0.277 201.0

n-Butylbenzene 23.1 20 0 116 75 - 128 23.43 1.39 201.0

n-Propylbenzene 22.54 20 0 113 76 - 126 22.97 1.88 201.0

o-Xylene 20.96 20 0 105 78 - 122 21.45 2.32 201.0

sec-Butylbenzene 22.58 20 0 113 77 - 126 23.02 1.92 201.0

Styrene 20.82 20 0 104 78 - 123 21.65 3.89 201.0

tert-Butylbenzene 22.88 20 0 114 78 - 124 23.33 1.92 201.0

Tetrachloroethene 21.9 20 0 109 74 - 129 22.54 2.92 201.0

Toluene 22.42 20 0 112 80 - 121 22.73 1.35 201.0

trans-1,2-Dichloroethene 20.62 20 0 103 75 - 124 21.59 4.61 201.0

trans-1,3-Dichloropropene 18.55 20 0 92.7 73 - 127 19.42 4.59 201.0

Trichloroethene 20.96 20 0 105 79 - 123 21.35 1.82 201.0

Trichlorofluoromethane 20.65 20 0 103 65 - 141 21.82 5.51 201.0

Vinyl chloride 21.51 20 0 108 58 - 137 23.01 6.74 201.0


49.52 50 0 99.0 85 - 114 48.84 1.38 201.0Surr: 4-Bromofluorobenzene


53.49 50 0 107 89 - 112 53.14 0.653 201.0Surr: Toluene-d8


00914894

Client:Project:



QC BATCH REPORT




00914895

Client:Project:



QC BATCH REPORT

Batch ID: R324857 Instrument: Balance1 Method: E1664A

Sample ID: WBLKW-100518 Units: mg/L Analysis Date: 05-Oct-2018 14:40



Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Oil and Grease 1.00 U2.00

Sample ID: WLCSW-100518 Units: mg/L Analysis Date: 05-Oct-2018 14:40



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Oil and Grease 38.8 40 0 97.0 78 - 1142.00

Sample ID: WLCSDW-100518 Units: mg/L Analysis Date: 05-Oct-2018 14:40



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Oil and Grease 39.2 40 0 98.0 78 - 114 38.8 1.03 182.00




Value %RECControl

LimitRPD Ref


MS

Client ID:

Oil and Grease 37.5 40 1.667 89.6 78 - 1142.00



00914896

Client:Project:



QC BATCH REPORT


Sample ID: MBLK-R324887 Units: mg/L Analysis Date: 06-Oct-2018 15:00



Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Chemical Oxygen Demand 10.0 U15.0

Sample ID: LCS-R324887 Units: mg/L Analysis Date: 06-Oct-2018 15:00



Value %RECControl

LimitRPD Ref


LCS

Client ID:





Value %RECControl

LimitRPD Ref


MS

Client ID:


Sample ID: HS18091379-01DUP Units: mg/L Analysis Date: 06-Oct-2018 15:00



Value %RECControl

LimitRPD Ref


DUP

Client ID:

Chemical Oxygen Demand 5 6 0 20 J 15.0



00914897

Client:Project:



QC BATCH REPORT


Sample ID: WBLKW1-101018 Units: mg/L Analysis Date: 10-Oct-2018 21:18



Value %RECControl

LimitRPD Ref


MBLK

Client ID:



Sample ID: WLCSW1-101018 Units: mg/L Analysis Date: 10-Oct-2018 21:33



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Chloride 20.31 20 0 102 80 - 1200.500

Sulfate 20.22 20 0 101 80 - 1200.500

Sample ID: WLCSDW1-101018 Units: mg/L Analysis Date: 10-Oct-2018 21:47



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Chloride 20.01 20 0 100 80 - 120 20.31 1.49 200.500

Sulfate 20.01 20 0 100 80 - 120 20.22 1.02 200.500




Value %RECControl

LimitRPD Ref


MS

Client ID:

Chloride 290.3 10 273.9 164 80 - 120 SEO 0.500

Sulfate 885.2 10 852.3 330 80 - 120 SEO 0.500




Value %RECControl

LimitRPD Ref


MS

Client ID:

Chloride 292.7 10 280.7 120 80 - 120 EO 0.500

Sulfate 888.8 10 870.9 179 80 - 120 SEO 0.500


00914898

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS

Client ID:

Chloride 380.1 100 286.7 93.5 80 - 1205.00

Sulfate 965.3 100 904.7 60.6 80 - 120 SO 5.00




Value %RECControl

LimitRPD Ref


MS

Client ID:

Chloride 455.1 200 271.7 91.7 80 - 12010.0

Sulfate 992.9 200 853.2 69.9 80 - 120 SO 10.0




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Chloride 283 10 280.7 22.8 80 - 120 292.7 3.37 20 SEO 0.500

Sulfate 865.7 10 870.9 -51.5 80 - 120 888.8 2.62 20 SEO 0.500




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Chloride 473.2 200 271.7 101 80 - 120 455.1 3.91 2010.0

Sulfate 1032 200 853.2 89.4 80 - 120 992.9 3.86 20 O 10.0




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Chloride 376.5 100 286.7 89.9 80 - 120 380.1 0.953 205.00

Sulfate 957.5 100 904.7 52.8 80 - 120 965.3 0.811 20 SO 5.00


00914899

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD

Client ID:

Chloride 277.8 10 273.9 39.5 80 - 120 292.7 5.21 20 SEO 0.500

Sulfate 848.5 10 852.3 -37.9 80 - 120 888.8 4.64 20 SEO 0.500



00914900



Bhate Environmental Associates, Inc.Groundwater Treatment Plant Quarterly Effluent SamplesHS18091521


a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution





00914901




Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


00914902


Work Order: HS18091521Project: Groundwater Treatment Plant Quarterly Effluent Samples SAMPLE TRACKING

Lab Samp ID Client Sample ID Action Date Person New Location

HS18091521-01 LH18/24-SP650_092718 Login 9/28/2018 2:55:46 PM PJM WET077

HS18091521-01 LH18/24-SP650_092718 Login 9/28/2018 2:55:46 PM PJM EXT140



HS18091521-01 LH18/24-SP650_092718 Login 9/28/2018 2:55:46 PM PJM MET081

HS18091521-01 LH18/24-SP650_092718 Login 9/28/2018 2:55:46 PM PJM VOA040

HS18091521-02 LH18/24-SP650_092718_BIX Login 9/28/2018 2:55:46 PM PJM Sub

HS18091521-03 Trip Blank Login 9/28/2018 2:55:46 PM PJM VOA040


00914903

NDD


HS18091521

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

3.2C/2.8C UC/C IR # 11431029/28/2018 15:00


Yes No N/A

Yes No N/A


28-Sep-201828-Sep-2018





Comments:

Corrective Action:

Yes



00914904

00914905

00914906




00914907




00914908

ANALYTICAL REPORT


Phone:

E-mail:

281 530-5656

[email protected]




Project ID:



1827567001 09/27/18LH18/24-SP650_092718_BIX 10/02/18




||

00914909

ANALYTICAL REPORT




Analytical Results

Sample ID: 09/27/201810/02/20181827567001Lab ID:

Collected:Received:

LH18/24-SP650_092718_BIX NA


Media:

Water





LCMS04

Report Basis: Wet




4.01.0ND 2.0 UPerchlorate 1

Comments







/S/ Stephen Brose



Phone:Email:Web:


00914910

ANALYTICAL REPORT










Website








00914911

Analysis:


Workorder: 1827567




Limits:Basis:


Blank

LMB:

Analyte

Units:

Result

Analyzed:62193110/09/2018 09:45

ug/L

MDL RL



Dilution: 1ug/L


LCS:Analyzed:

62193210/09/2018 09:59

Units:

Target

Perchlorate 5.23 5.00 78.8 123.8105


MS:Analyzed:


110/09/2018 10:29621933Sample:

Analyzed:Dilution:

Units: ug/L110/09/2018 10:151827567001


MSD:Analyzed:

62193410/09/2018 10:43

% Rec



Perchlorate ND 78.8 123.85 96.44.82 20.00.04.74 1.6394.8



CCV:Analyzed:

62192810/09/2018 09:02

Units:

Target


Result % Rec.

CCV:Analyzed:

62193510/09/2018 11:36

Units:

Target


Perchlorate 24.5 25.0 98.0 24.4 25.0 97.6



ICSA:Analyzed:

62193010/09/2018 09:31

Units:

Target





LODV:Analyzed:

62192910/09/2018 09:17

Units:

Target


Result % Rec.

LODV:Analyzed:

62193610/09/2018 11:50

Units:

Target


Perchlorate 1.02 1.00 102 0.958 1.00 95.8



QCS V4.4

00914912

Analysis:


Workorder: 1827567




Limits:Basis:








# -

Analyst Peer Review


10/12/2018 14:19 10/15/2018 08:43



QCS V4.4

00914913

00914914

00914915

00914916

00914917

00914918

00914919

00914920

00914921

00914922

00914923

00914924

00914925

00914926

00914927

00914928

00914929

00914930

00914931

00914932

00914933

00914934

00914935

October 17, 2018





Sincerely,



Dear Marcia,


Project Manager


RJ Modashia



00914936







00914937



Project:

Work Order Comments



Batch ID: R324661



Batch ID: R324627



00914938



WorkOrder:Lab ID:

Collection Date:

HS18091522HS18091522-01


ANALYTICAL REPORT



AMMONIA AS N BY E350.3(ISE) Method:E350.3 Analyst: MZD1mg/L 03-Oct-2018 11:100.20Nitrogen, Ammonia (As N) 0.2013 0.20




0.2501.57 0.250






00914939


Bhate Environmental Associates, Inc.Longhorn GW Treatment PlantLH18/24-SP650_092718_BIX

WorkOrder:Lab ID:

Collection Date:

HS18091522HS18091522-02


ANALYTICAL REPORT








00914940


WorkOrder:Project:




03 Oct 2018 11:10HS18091522-01 27 Sep 2018 14:00 1LH18/24-SP650_092718


28 Sep 2018 17:44HS18091522-01 27 Sep 2018 14:00 10LH18/24-SP650_092718




09 Oct 2018 11:24HS18091522-01 27 Sep 2018 14:00 1LH18/24-SP650_092718


00914941

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:





Value %RECControl

LimitRPD Ref


LCS

Client ID:

Nitrogen, Ammonia (As N) 10.02 10 0 100 80 - 1200.20




Value %RECControl

LimitRPD Ref


MS

Client ID:





Value %RECControl

LimitRPD Ref


MSD

Client ID:




00914942

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:


0.0250 U0.0250




Value %RECControl

LimitRPD Ref


LCS

Client ID:


0.225 0.25 0 90.0 85 - 1150.0250




Value %RECControl

LimitRPD Ref


MS

Client ID: LH18/24-SP650_092718


4.35 2.5 1.57 111 80 - 1200.250




Value %RECControl

LimitRPD Ref


MSD

Client ID: LH18/24-SP650_092718


4.4 2.5 1.57 113 80 - 120 4.35 1.14 200.250



00914943





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution




00914944




Arkansas 88-0356 27-Mar-2019

Texas T10470231-18-21 30-Apr-2019





Kentucky 123043 - 2018 30-Apr-2019

Kansas E-10352 2018-2019 31-Jul-2019

Oklahoma 2018-156 31-Aug-2019


00914945

NDD


HS18091522

Bhate Environmental

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

3.2C/2.8C UC/C IR # 11431029/28/2018 15:15


Yes No N/A

Yes No N/A

Quantity does not match, CoC = 4 Rec'd = 5


28-Sep-201828-Sep-2018





Comments:

Corrective Action:

Yes



00914946

00914947

00914948

October 09, 2018 Analytical Report for Service Request No: K1809489



For your reference, these analyses have been assigned our service request numberEnclosed are the results of the sample(s) submitted to our laboratory October 02, 2018

RE: HS18091522

Dear RJ,

K1809489.




Kelley LovejoyProject Manager


+1 360 577 7222+1 360 636 1068

T :F :

ALS Environmental

www.alsglobal.com

RIGHT SOLUTIONS | RIGHT PARTNERPage 1 of 57

00914949

kelley.lovejoy

Kelley Lovejoy

www.alsglobal.com

ALS Environmental

F :T :

+1 360 636 1068+1 360 577 7222


Table of Contents


Acronyms

Qualifiers


Case Narrative

Chain of Custody

General Chemistry

Raw Data

General Chemistry

Page 2 of 57

00914950
























NA Not Applicable

NC Not Calculated


ND Not Detected






equal to the MDL.

Acronyms

Page 3 of 57

00914951











































Page 4 of 57

00914952















North Carolina DEQ











Page 5 of 57

00914953

Case Narrative



Page 6 of 57

00914954

CASE NARRATIVE

Client:

Project:

Sample Matrix:

Service Request:

Date Received:

ALS Environmental - US

HS18091522

Water

K1809489

10/02/2018


Sample Receipt:

One water sample was received for analysis at ALS Environmental on 10/02/2018. The sample was received in good condition and consistent with the accompanying chain of custody form. The sample was stored in a refrigerator at 4ºC upon receipt at the laboratory.General Chemistry:

No significant anomalies were noted with this analysis.


Approved by Date 10/09/2018

Page 7 of 57

00914955

kelley.lovejoy

Kelley Lovejoy

Chain of Custody



Page 8 of 57

00914956

' ~\ 5oq~8! 10450 Stancliff Rd, Ste 210

Houston, TX 77099

T: +1 281 530 5656

F: +1 281 530 5887

www.alsglobal.com


SUBCONTRACT TO:


1317 S. 13th Avenue

Kelso, WA 98626


Company:

Contact:

Address:

Phone:

Email:


ALS Houston

RJ Modashia


+1 281 530 5656

[email protected]

Jumoke M. Lawal

[email protected]

LABS.AMPLE.I[} . CUENTSAMpLE ID ANALYSIS J'lEQtJESTED .,

1. H518091522-01 LH18/24-SP650_092718


Comments: Please analyze for the analysis Hsted above. Send report to the ema'ils shown above.


Relinquished By:

Received By: ./:i

Cooler ID(s):

COC ID: 9916

Phone: +1 360 501 3312





Phone: + 1 281 530 5656



MATRIX ··.·· .·· ~OLLECTDATE <btJE DATE

Water 27 Sep 2018 14:00

08 Oct 2018

Date/Time: \c\\ \ \\{ \ 8 o::;,c;, '

Date/Time: 1 o I Jr 'i?' o '/'3 o Temperature(s):

Page 9 of 57

00914957

A PC r<j,,-/ Cooler Receipt and Preservation Form

/ l/ p

Clio"< Ai,~ //,., t~ Sooi~Roq~dJ8 ~~ '" ~ Received: 10/iftff Opened: t0/t/t ~ By: a:¢ Unloaded: to/ I 8' By~ I. Samples were received via? USPS~ UPS

2. Samples were received in: (circle) C!!}!J!f> Box

3. Were custody seals on coolers? NA CJ> N

If present, were custody seals intact? c:t/ N

DHL PDX Courier Hand Delivered

Envelope Other __________ ~

If yes, how many and where? Z- fY-,,,J If present, were they signed and dated?

Raw Corrected. Raw Corrected Corr. Thermometer Cooler/COC ID Tracking Number

NA

6) N

Cooler Temp CoolerTemti Temo Blank TemnBlank Factor ID - NA NA Filed

-(. f -J.Z.. -o.'!> -~. Lf ~0.1 "'3 i::...? U\V\ \lo i-t 3 'to q13 5.3

' n __ ,_: ____ ._ __ :_1_

'- - --·-QSaggi~e5 -• ... - .. - ~--_,. ___ "- n..

.. t., hll,.,,1 ,,.,. ..,.,. , ~•~ ... ~A ,

6. Were samples received in good condition (temperature, unbroken)? Indicate in the table below.

If applicable, tissue samples were received: Frozen Partially Thawed Thawed 7. Were all sample labels complete (i.e analysis, preservation, etc.)?


9. Were appropriate bottles/containers and volumes received for the tests indicated?



12. Was Cl2/Res negative?

I !

072.7

CJ) NA 0 NA co NA CD NA d'.)

@) y

~y C!!) y

I Samnle ID on Bottle Samole ID on COC Identified bv: ' I

l Bottle Count Out of Head- Volume Reagent lot Samnle ID BottleT•~ Teriiri s....,.ce Broke pH Reaoent added Number Initials

;i

[ i i i l I

Notes, Discrepand

7125116 Paf(e of

N

N

N

N

N

N

N

Time

Page 10 of 57

00914958

General Chemistry



Page 11 of 57

00914959

Client:

10/2/18

K1809489


Service Request:

WaterHS18091522ALS Environmental - US



Basis:Units: mg/L


Analysis Method:



HS18091522-01 10/04/18 19:5010.070.200.5011.9K1809489-001Method Blank 10/04/18 20:5510.070.200.50 UNDK1809489-MB

Analytical Report



Page 12 of 57

00914960


QA/QC Report

Client:ProjectSample Matrix: Water

HS18091522ALS Environmental - US Service Request: K1809489

09/27/18Date Collected:Date Received: 10/02/18

10/04/18Date Analyzed:

Replicate Sample SummaryGeneral Chemistry Parameters

HS18091522-01 mg/LBasis:Units:

K1809489-001 NALab Code:Sample Name:

RPD LimitLODLOQ MDLAnalysis Method RPD

Duplicate Sample

K1809489-001DUP Result Average

SampleResultAnalyte Name


Carbon, Total Organic 3 0.50 0.07 11.9 11.6 11.7 100.20SM 5310 C





Page 13 of 57

00914961

QA/QC Report


Units:Sample Name: HS18091522-01


NA


ALS Environmental - USHS18091522Water

Service Request:


K1809489

10/4/1810/02/18


NoneSM 5310 C



Matrix SpikeK1809489-001MS

% Rec Limits


NADate Extracted:

Carbon, Total Organic 11.9 34.4 25.0 90 83-117





Page 14 of 57

00914962

Sample Name


WaterHS18091522ALS Environmental - US




SM 5310 CNone NA

mg/LBasis:Units:


10/04/18


% Rec Limits

NADate Extracted:

Lab Code


QA/QC Report

Lab Control Sample 83-11795 21.920.8K1809489-LCS


Page 15 of 57

00914963



QA/QC Report



Date Analyzed

True Value

Measured Value


Project:ALS Environmental - USHS18091522




90-1109724.3609436 25.010/04/18 10:29KQ1814370-23CCV190-1109924.7609436 25.010/04/18 15:17KQ1814370-24CCV290-1109824.4609436 25.010/04/18 20:22KQ1814370-25CCV390-1109824.6609436 25.010/05/18 00:38KQ1814370-26CCV490-1109624.0609436 25.010/05/18 05:10KQ1814370-27CCV5


Page 16 of 57

00914964


SM 5310 C


Client:Project:


QA/QC Report

mg/L

HS18091522

Analysis Method:


Units:




CCB1 KQ1814370-28 10/04/18 10:45 0.50609436 0.20 0.07 UNDCCB2 KQ1814370-29 10/04/18 15:34 0.50609436 0.20 0.07 UNDCCB3 KQ1814370-30 10/04/18 20:38 0.50609436 0.20 0.07 UNDCCB4 KQ1814370-31 10/05/18 00:55 0.50609436 0.20 0.07 UNDCCB5 KQ1814370-32 10/05/18 05:26 0.50609436 0.20 0.07 UND


Page 17 of 57

00914965




00914966




00914967

ANALYTICAL REPORT


Phone:

E-mail:

281 530-5656

[email protected]




Project ID:



1827569001 09/27/18LH18/24-SP650_092718_BIX 10/02/18




||

00914968

ANALYTICAL REPORT




Analytical Results

Sample ID: 09/27/201810/02/20181827569001Lab ID:

Collected:Received:

LH18/24-SP650_092718_BIX NA


Media:

Water





LCMS04

Report Basis: Wet




4.01.0ND 2.0 UPerchlorate 1

Comments







/S/ Stephen Brose



Phone:Email:Web:


00914969

ANALYTICAL REPORT










Website








00914970

Analysis:


Workorder: 1827569




Limits:Basis:


Blank

LMB:

Analyte

Units:

Result

Analyzed:62193110/09/2018 09:45

ug/L

MDL RL



Dilution: 1ug/L


LCS:Analyzed:

62193210/09/2018 09:59

Units:

Target

Perchlorate 5.23 5.00 78.8 123.8105


MS:Analyzed:


110/09/2018 10:29621933Sample:

Analyzed:Dilution:

Units: ug/L110/09/2018 10:151827567001


MSD:Analyzed:

62193410/09/2018 10:43

% Rec



Perchlorate ND 78.8 123.85 96.44.82 20.00.04.74 1.6394.8



CCV:Analyzed:

62192810/09/2018 09:02

Units:

Target


Result % Rec.

CCV:Analyzed:

62193510/09/2018 11:36

Units:

Target


Perchlorate 24.5 25.0 98.0 24.4 25.0 97.6



ICSA:Analyzed:

62193010/09/2018 09:31

Units:

Target





LODV:Analyzed:

62192910/09/2018 09:17

Units:

Target


Result % Rec.

LODV:Analyzed:

62193610/09/2018 11:50

Units:

Target


Perchlorate 1.02 1.00 102 0.958 1.00 95.8



QCS V4.4

00914971

Analysis:


Workorder: 1827569




Limits:Basis:








# -

Analyst Peer Review


10/12/2018 14:19 10/15/2018 08:43



QCS V4.4

00914972

00914973

00914974

00914975

00914976

00914977

00914978

00914979

00914980

00914981

00914982

00914983

00914984

00914985

00914986

00914987

00914988

00914989

00914990

00914991

00914992

00914993

00914994

GWTP QUARTERLY EVALUATION REPORT – 3RD QUARTER 2018 LONGHORN ARMY AMMUNITION PLANT

December 2018 Appendix D

APPENDIX D

PROTOCOL FOR DISCHARGING GWTP EFFLUENT

00914995


Appendix D December 2018

This page intentionally left blank.

00914996

Page 1

MEMORANDUM

DATE: August 28, 2017

PROJECT NAME: Remediation of Multiple Sites, Longhorn Army Ammunition Plant, Karnack, TX

TO: Richard Mayer Senior Project Engineer US Environmental Protection Agency Federal Facilities Section (6PD-F)

April Palmie Project and Grant Manager Superfund Section, Remediation Division Texas Commission on Environmental Quality

FROM: Rose M. Zeiler, Ph.D. Longhorn AAP Site Manager

SUBJECT: Protocol for Discharging GWTP Effluent Longhorn Army Ammunition Plant, Karnack, TX (Contract: W912DY-09-D-0059, Task Order DS01)

INTRODUCTION The purpose of this memo is to document the protocol for discharging Longhorn Army Ammunition Plant groundwater treatment plant (GWTP) effluent to Harrison Bayou, the INF-Pond, or LHAAP- 18/24.

The GWTP is designed to:

• Extract groundwater from LHAAP-18/24 and LHAAP-16 for hydraulic control;

• Remove metals by pH adjustment, polymer addition, and gravity separation;

• Remove volatile organic compounds (VOCs) by air stripping;

• Remove perchlorate in a fluidized bed reactor (FBR) and an ion exchange scavenger system; and

• Discharge the effluent continuously.

00914997

Page 2

DISCHARGE CRITERIA The discharge criteria established for discharge to Harrison Bayou are:

Parameter

Discharge Criteria (μg/L)

Daily Average Daily Maximum

Volatiles 1,1,1-Trichloroethane 3,417 7,230 1,1,2-Trichloroethane 102.5 216.9 1,1-Dichloroethane 6,633 14,032 1,1-Dichloroethene 119 253 1,2-Dichloroethane 85 181 Acetone 1,132 2,395 Benzene 85 181 Carbon Tetrachloride 85 181 Chlorobenzene 22,300 47,180 Chloroform 1,708 3,615 Ethylbenzene 26,954 57,025 Xylenes 39.5 83.6 Methylene Chloride 803 1,699 Styrene 2,829 5,987 Tetrachloroethene 85.4 180.7 Toluene 1,980 4,189 Trichloroethene 85 181 Vinyl Chloride 34 72 Anions Chloride * * Sulfate * * Perchlorate** 278 589 Metals Aluminum 777 1,644 Arsenic 365 772 Barium 1,000 2,000 Cadmium 1.6 3.4 Chromium, Total 355 752 Chromium, Hexavalent 58 124 Cobalt 5,433 11,495 Iron 1,132 2,395 Lead 2.2 4.6 Nickel 87 184 Manganese 7,323 15,494 Silver 1.4 3 Selenium 5.7 12 Vanadium 1,698 3,592 Zinc 146 310 Other Hexachlorobenzene 0.22 0.47 1,4-Dioxane 134.2 Oil and Grease 15 Chemical Oxygen Demand 200

* - Based upon flow in Harrison Bayou ** - Discharge criteria, when diverted to the INF Pond, is 17 µg/L

00914998

Page 3

PROTOCOL FOR DISCHARGING GWTP EFFLUENT In accordance with the Sampling and Analysis Plan, Groundwater Treatment Plant and Well Fields (SAP) Table 2-2, indicator parameters for the FBR, such as temperature, pH and oxidation reduction potential (ORP), are monitored in real time to predict FBR performance and perchlorate removal. Based upon these indicator parameters, the operator of the GWTP can make adjustments such as:

• Bring the ion exchange system online;

• Increase or decrease the addition rate of electron donor (acetic acid);

• Increase or decrease the nutrient addition rate (urea or phosphoric acid); or

• Increase or decrease the FBR recirculation rate Samples of the GWTP effluent are collected weekly, analyzed for perchlorate, nutrients (ammonia- nitrogen and ortho-phosphate), total organic carbon (TOC), chloride, and sulfate, with the results received from the laboratory 14 days later. Other parameters (e.g. Record of Decision metals and volatiles) are collected and analyzed in GWTP effluent samples according to the frequencies listed in Table 2-1 of the SAP.

As shown in Figure 1, groundwater is continuously extracted, treated, and discharged. If Harrison Bayou is flowing and indicator parameters are within their historical optimal ranges, then the ion exchange vessels can be bypassed and the GWTP effluent sample will be collected after the FBR. If Harrison Bayou is not flowing or the indicator parameters are not within historical optimal ranges, then the ion exchange vessels will be put on line, and the GWTP effluent sample will be collected between the lead and lag ion exchange vessel. Professional judgement may also be used as to when to bring the ion exchange vessels online, such as after a power outage or during anticipated cold temperatures when the FBR has historically not performed optimally. If a parameter is measured in the effluent at a concentration above the discharge criteria, then a confirmation sample and an effluent sample after the lag ion exchange vessel will be collected and analyzed for the parameter with a 24-hour turnaround time. Corrective measures (e.g. increased nutrient or electron donor addition rates, bring ion exchange vessels on line) will be implemented as appropriate to bring the parameter back within the discharge criteria. If an upset condition in the FBR leads to high concentrations of perchlorate going into the lead ion exchange vessel and breaking through at the sample location between the vessels, the lag vessel will still remove perchlorate before it is discharged to Harrison Bayou, the INF Pond, or LHAAP-18/24. It is estimated that the lag ion exchange vessel can remove all of the perchlorate from two weeks of typical groundwater extraction at a concentration of 920 μg/L. If the residual perchlorate concentration after the FBR and lead ion exchange vessel is only 600 μg/L, the lag ion exchange vessel could last almost 2.5 years before perchlorate would be detected in the discharged effluent.

If a parameter exceeds the discharge criteria by more than 40% (see Appendix A-2, SAP, Section 7c of Monitoring and Reporting Requirements) or reaches 920 μg/L of perchlorate, then the GWTP will be put into full recycle mode (no discharge) until the parameter is below the discharge criteria again. Appendix A-2 of the SAP requires GWTP data to be provided to TCEQ monthly including a list of noncompliance(s), if applicable.

00914999

Page 4

Discharge to Harrison Bayou As shown in Figure 1, the GWTP effluent will be discharged to Harrison Bayou as long as it has a measurable flow. The flowrate in Harrison Bayou is estimated by measuring the height of water with a staff gauge and velocity in feet/sec at intervals along the width as described in the Installation-Wide Work Plan, Standard Operating Procedures, Attachment 18 – Water Depth and Velocity Measurements (AECOM, July 2014).

The allowable flow rate of GWTP effluent that can be discharged to Harrison Bayou is given by:

QE ≤ QS (CC – CA) (CE – CC)

where QE = GWTP effluent flow QS = Harrison Bayou flow CC = Criteria concentration (100 mg/L for chloride, 50 mg/L for sulfate) CA = Ambient concentration = 10 mg/L CE = Chloride or sulfate concentration in GWTP effluent

The allowable GWTP effluent flow will be the lower of the calculated values given the measured concentrations of chloride and sulfate in the discharge stream. For each day that GWTP effluent is discharged to Harrison Bayou, the measured Harrison Bayou flow, the allowable effluent flow, and the actual effluent flow are recorded.

Discharge to INF Pond If Harrison Bayou is not flowing, then GWTP effluent will be discharged to the Intermediate-Range Nuclear Forces (INF) Pond for temporary storage until Harrison Bayou flow resumes. Perchlorate concentration detected in the effluent must be 17 µg/L or less, when this occurs. The INF Pond has a flexible membrane liner protected by a soil cover with a gravity discharge pipe (and valve) to Harrison Bayou. The INF Pond has a nominal capacity of 3 million gallons with a staff gage to measure the height of water stored in the pond. The GWTP operator maintains the INF Pond by visually inspecting for erosion, vegetative growth including tree growth along the anchor trench, and liner integrity and making necessary repairs. Periodically, accumulated debris must be removed from the influent and effluent piping to the INF Pond.

Prior to discharging to the INF Pond, a lead and lag ion exchange vessel will be brought online. The GWTP Operator will also confirm that the discharge valve is closed, will record the reading on the effluent totalizer, and will record the height of water using the staff gage. The GWTP Operator will then configure valves and pumps to direct GWTP effluent to the INF Pond. The height of water in the INF Pond and totalizer reading will be recorded at the beginning and end of each shift for the duration of active discharge. When the height of water in the pond reaches 3 feet below the height of the berm (freeboard), the GWTP Operator will stop discharging to the INF Pond and TCEQ will be notified. After the TCEQ acknowledges the INF Pond level, GWTP effluent may be discharged to the INF Pond again until 2 feet of freeboard is reached. The GWTP Operator will stop discharging to the INF Pond and TCEQ will be notified again. After the TCEQ acknowledges 2 feet of freeboard in the INF Pond,GWTP effluent may be discharged again until 1 foot of freeboard remains. No additional GWTP effluent can be accepted at the INF Pond until greater than 1 foot of freeboard is measured.

00915000

Page 5

As soon as flow in Harrison Bayou returns, stored GWTP effluent from the INF Pond will be discharged. As with direct discharges from the GWTP to Harrison Bayou, the allowable flowrate of effluent from the INF Pond is calculated based upon the chloride and sulfate concentrations in the pond and the flow in Harrison Bayou. If effluent from the INF Pond and the GWTP are discharged simultaneously, total flow of both streams together should not exceed the calculated discharge level for either discharge location. For each day that INF Pond contents are discharged to Harrison Bayou, the measured Harrison Bayou flow, the allowable effluent flow, and the actual effluent flow are recorded.

Irrigation onto LHAAP-18/24 If Harrison Bayou is not flowing and the INF Pond has less than 1 foot of freeboard, then GWTP effluent will be irrigated onto LHAAP-18/24 using one of the three main sprinkler lines. To avoid pooling and runoff of irrigation water, only one line will be used for half a day at a time, with a separate line being used the second half of the day. If needed, the irrigation will occur 5 days a week for 8 hours each day (using 3 sprinklers in each line). If conditions are wet due to rain events, irrigation will not be conducted to avoid ponding and potential runoff, the GWTP will be put into recycle mode, and groundwater extraction will be interrupted if storage space is not available.

While irrigating, site inspections will be performed to ensure pooling and runoff are not occurring. During the irrigation activities, inspections will be performed twice a day, once approximately three hours and again approximately six hours into the 8-hour irrigation shift. The system will be inspected to ensure that the sprinkler heads are operating properly and not leaking large amounts of water. If ponding or runoff is observed, irrigation at that sprinkler line will cease, and irrigation at another sprinkler line will be started if possible. Volumes of GWTP effluent and twice daily inspections will be recorded daily and reported monthly until flow resumes in Harrison Bayou or greater than 1 foot of freeboard is available in the INF Pond.

00915001

Continuously Extract

Groundwater and Operate GWTP1

Recycle Effluent to TK-140.

No

Is Harrison Bayou flowing

AND No pH/ORP are within

optimal range2?

Are Parameters less than 140% of

discharge limits or 920 µg/L perchlorate3?

Yes

Yes

Bypass I/X Vessels. Bring Two I/X Vessels on line.

Collect and Analyze

Confirmation and After Lag I/X

Vessel Samples (24 hr TAT)

Collect and Analyze Sample

from FBR Effluent (14 day TAT)

Collect and Analyze Effluent

Sample from between I/X

Vessels (14 day TAT)

Take Corrective Action4. Report Noncompliance5.

Are Parameters less No than discharge Limits7?

Yes

Is INF Pond Full? Yes Irrigate onto 18/24

Is Harrison No No Bayou flowing ?

Yes

Discharge to INF Pond

Store Until Harrison Bayou is

flowing

Collect and Anaylze INF Pond

sample for Chloride and Sulfate.

Notes: 1. GWTP extracts, treats, and discharges continuously.2. pH between 7.1 and 7.4 ORP less than -400 mVThe lag ion exchange vessel can remove two weeks oftypical groundwater extraction at 920 µg/L of perchloratebefore breakthrough.4. Corrective actions can include ion exchangevessels on-line, change electron donor addition rate, change nutrient addition rate, etc… 5. GWTP validated data reported to EPA and TCEQmonthly. Parameters above discharge criteria arehighlighted.6. Perchlorate concentration measured between ionexchange vessels. If breakthrough occurs after the lead vessel, the lag vessel will be treating effluent prior to discharge until laboratory sample results are received. 7. Discharge to INF Pond must have 17 ug/L or less ofperchlorate.

Figure 1. Continuous Discharge Protocol Flowchart

Continuously Discharge to

Harrison Bayou at rates allowed by

Chloride and Sulfate

00915002


December 2018 Appendix E

APPENDIX E QUALITY CONTROL SUMMARY REPORT

00915003


Appendix E December 2018


00915004

QUARTERLY CONTROL SUMMARY REPORT 3rd QUARTER (JULY-SEPTEMBER) 2018

GROUNDWATER TREATMENT PLANT LONGHORN ARMY AMMUNITION PLANT

KARNACK, TEXAS

November 2018

Contract Number: W9128F-13-D-0012 Task Order Number: W912BV17F0150 Prepared By:

1608 13th Avenue South, Suite 300 Birmingham, Alabama 35205 1-800-806-4001 • www.bhate.com

Prepared For:

Longhorn Army Ammunition Plant Karnack, Texas

Under Contract To:

U.S. Army Corps of Engineers Tulsa District Tulsa, Oklahoma

00915005

Quality Control Summary Report GWTP 3rd Quarter 2018 (July-Sept) Longhorn Army Ammunition Plant, Karnack, Texas November 2018

2

Table of Contents 1 INTRODUCTION ......................................................................................................................................... 3

1.1 Intended Use of Data ................................................................................................................... 3

1.2 Preservation and Holding Times ........................................................................................................ 4

1.3 Calibrations ......................................................................................................................................... 4

1.3.1 Continuing Calibration Verifications .......................................................................................... 4

1.4 Blanks .................................................................................................................................................. 4

1.4.1 SW6020 ........................................................................................................................................ 4

1.4.2 SW8260 ........................................................................................................................................ 4

1.5 Surrogates ........................................................................................................................................... 4

1.6 Laboratory Control Sample (LCS)/Laboratory Control Sample Duplicate (LCSD) ............................ 5

1.7 Matrix Spike (MS)/Matrix Spike Duplicate Sample (MSD) ............................................................... 5

1.7.1 SW8260 ........................................................................................................................................ 5

1.8 Internal Standards .............................................................................................................................. 5

1.9 Precision ............................................................................................................................................. 5

1.9.1 Field Duplicate ............................................................................................................................. 5

2 DATA USABILITY SUMMARY ..................................................................................................................... 5

Tables Table 1: Field Sample Identification and Laboratory Packages Table 2: Qualified Analytical Data Table 3: Completeness by Method

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3

1 INTRODUCTION Bhate reviewed 28 data packages from ALS Environmental, Houston, Texas. Groundwater samples were collected July 6, 2018, through September 27, 2018, at the Groundwater Treatment Plant (GWTP), Karnack, Texas. Data were reviewed for conformance to the requirements of the following guidance documents: [U.S. Environmental Protection Agency] USEPA Contract Laboratory Program [CLP] National Functional Guidelines for Superfund Organic Methods Data Review (USEPA, January 2017); USEPA Contract Laboratory Program National Functional Guidelines for Inorganic Superfund Data Review (USEPA, January 2017); and the Final Basewide Uniform Federal Policy [UFP] – Quality Assurance Project Plan [QAPP] Longhorn Army Ammunition Plant which is in Appendix C of the Final Installation-Wide Work Plan for Longhorn Army Ammunition Plant Karnack, Texas (Bhate, May 2018). 1.1 Intended Use of Data The objective of sampling at the GWTP is to monitor effluent streams to confirm compliance with discharge limits. Analyses performed include:

• SW6850 – Perchlorate • E350.3/SM4500 NH3 – Nitrogen, Ammonia • E365.3/SM4500 P – Orthophosphate • E415.1/SM5310 – Total Organic Carbon • SW8260C – Volatile Organic Compounds (VOCs) • SW8270D SIM - 1,4-Dioxane • SW6020A/7470A – Metals • SW9056A – Chloride (Cl) and Sulfate (SO4) • SW7196A – Hexavalent Chromium • E410.4 – Chemical Oxygen Demand • E1664A – Oil and Grease • TO-15 – Volatiles in Air

Table 1 lists the sample identification numbers (IDs) and their associated laboratory package. Table 2 lists qualified results with the qualification flag and reason code. The following narrative is a brief synopsis of data that required qualification due to quality control discrepancies.

00915007


4

1.2 Preservation and Holding Times Sample identification data were evaluated for agreement with the chain-of-custody (COC). All samples were received in appropriate containers, within the proper temperature range, in good condition, and within the required hold time with the following exceptions.

• The weekly perchlorate sample LH18/24-SP650_082318 was received by the Salt Lake City lab with a temperature of 18oC. This was outside the 4 + 2oC range and the data was qualified as estimated, non-detected, “UJ”.

• The dilution analysis of cis-1,2-dichloroethene, methylene chloride, and trichloroethene were performed one day outside hold time in quarterly influent sample LH18/24-SP140_092718. These compound results were considered estimated and flagged “J”.

1.3 Calibrations All analytes reported must be present in the initial and continuing calibration. The calibrations must meet the acceptance criteria specified in Worksheet 24 (Analytical Instrument Calibration) of the QAPP. All results reported must be within the calibration range. Samples were diluted, if necessary, to bring analyte responses within the calibration range.

1.3.1 Continuing Calibration Verifications The calibrations must meet the following criteria otherwise the compound is qualified J or UJ: The continuing calibration verification (CCV) criteria are 20 percent difference (%D) for VOCs and Semi-volatile Organic Compounds (SVOCs) and 50% for closing CCVs. Metals and general chemistry - 10%D; perchlorate - 15%D; and volatiles in air - 30%D. All CCVs were within control limits. 1.4 Blanks If the analyte result for an associated sample was less than 5X (10X for common laboratory contaminants) the analyte concentration in the blank, that result was qualified “UB” and considered an artifact of blank contamination. Where the sample result for the affected analyte was non-detect or greater than 5X the amount in the blank, no qualifier was applied. 1.4.1 SW6020 Aluminum in quarterly effluent sample LH18/24-SP650_092718 was detected at a concentration < 5X the method blank concentration and qualified “UB”.

1.4.2 SW8260 Biweekly sample LH18/24-SP650_090618 reported acetone < 10X the trip blank concentration. It was flagged “UB” and considered an artifact of blank contamination.

1.5 Surrogates Surrogates were evaluated using limits defined by each method in the project-specific QAPP Worksheet 28.

00915008


5

No surrogates were reported outside control limits.

1.6 Laboratory Control Sample (LCS)/Laboratory Control Sample Duplicate (LCSD) LCS/LCSD recoveries were evaluated using limits defined in the project-specific QAPP Worksheet 15. All sample recoveries were within control limits. 1.7 Matrix Spike (MS)/Matrix Spike Duplicate Sample (MSD) MS/MSD recoveries were evaluated using limits defined in Worksheet 15 of the project-specific QAPP. When sample results were greater than 4X the spike amount, control limits were not applicable and require no qualification. Furthermore, if a MS/MSD analyses was performed on a batched (unrelated) sample no qualification was made to the sample data. Otherwise, only the sample used for spiking requires qualification. 1.7.1 SW8260 The matrix spike duplicate recovery of trichloroethene (74.7%) was below control limits in quarterly influent sample LH18/24-SP140_092718 and qualified estimated “J”.

1.8 Internal Standards If the %R for an internal standard in a sample is not within the limit, the associated sample is qualified for those analytes associated with the internal standard(s) outside of the limit. Internal standards were within acceptance criteria for the associated compounds. 1.9 Precision Precision is the measure of variability of individual sample measurements. Evaluation of laboratory and/or field duplicates for precision was done using the relative percent difference (RPD). The RPD is defined as the difference between two duplicate samples divided by the mean and expressed as a percent. Field duplicate RPD limits were set at <30% for groundwater and air matrices. Laboratory duplicate RPD limits were set at <25% for air matrices. 1.9.1 Field Duplicate The field duplicate RPD for vinyl chloride between air samples LH18/24-Air_091018_Stripper and LH18/24-Air_091018_Stripper_a was above laboratory defined control limits. Vinyl chloride was qualified as estimated, “J”, in both samples.

2 DATA USABILITY SUMMARY The data are usable for the intended purposes of the project (Table 3). The data quality objectives have been met for the project.

00915009


6

Table 1: Field Sample Identification and Laboratory Packages

Client Sample ID Lab Package

SW6850

E350.3/ SM4500 N

H3

E365.3/ SM4500 P

E415.1

SW8270D SIM

SW8260C

SW6020A

SW9056A

SW7196A

E410.4

1664A

TO-15

GWTP Samples LH18/24-SP650_070618 HS18070297 X X X X LH18/24-SP650_070618 HS18070295 X X X X X LH18/24-SP140_070618 HS18070296 X X X LH18/24-SP650_072618 HS18071388 X X LH18/24-SP650_072618 HS18071383 X LH18/24-SP650_072618 HS18071386 X X X LH18/24_SP650_080618 HS18080340 X LH18/24-SP650_080618 HS18080375 X X X LH18/24-SP650_081518 HS18080789 X X LH18/24-SP650_081518 HS18080783 X X X LH18/24-SP650_081518 HS18080840 X LH18/24-SP650_082318 HS18081206 X X X X LH18/24-SP650_082718 HS18081379 X LH18/24-SP650_083018 HS18081539 X X X X LH18/24-SP650_083018 HS18081540 X X X X X LH18/24-SP140_083018 HS18081541 X X X LH18/24-SP650_090618 HS18090255 X X X LH18/24-SP650_090618 HS18090275 X LH18/24-SP650_090618 HS18090257 X X LH18/24-SP650_091318 HS18090654 X X X X

LH18/24-SP650_091318_AIX HS18090654 X LH18/24-SP140_091318 HS18090658 X X X LH18/24-SP650_091318 HS18090657 X X X X

LH18/24-SP650_091318_BIX HS18090657 X LH18/24-SP650_091318_AIX HS18090657 X

LH18/24-SP650_091918 HS18091005 X X X LH18/24-SP650_091918_AIX HS18091005 X

LH18/24-SP650_091918 HS18091007 X X LH18/24-SP140_092718 HS18091519 X X X X X X

LH18/24-SP140_092718_BIX HS18091519 X LH18/24-SP650_092718 HS18091521 X X X X X X

LH18/24-SP650_092718_BIX HS18091521 X LH18/24-SP650_092718 HS18091522 X X X

LH18/24-SP650_092718_BIX HS18091522 X Air Samples

LH18/24-Air_091018_Stripper P1804830 X LH18/24-Air_091018_Stripper_a P1804830 X LH18/24-Air_091018_GWTP P1804830 X LH18/24-Air_091018_Downwind P1804830 X Notes: MW – Monitoring Well SM – Standard Method SW-846 - Test Methods for Evaluating Solid Waste, Physical/Chemical Methods. E – U.S. Environmental Protection Agency Method HS – Houston

00915010


7

Table 2: Qualified Analytical Data Client Sample ID Laboratory

Laboratory Package

Analyte Name Data Validation Qualifier

Reason for Qualification

GWTP LH18/24-Air_091018_Stripper P1804830 Vinyl Chloride 230 J Dup RPD LH18/24-Air_091018_Stripper_a P1804830 Vinyl Chloride 330 J Dup RPD LH18/24-SP650_082318 HS18081206 Perchlorate < 10 UJ Temperature LH18/24-SP650_090618 HS18090257 Acetone 3.2 UB TB

LH18/24-SP140_092718 HS18091519 cis-1,2-Dichloroethene

Methylene chloride Trichloroethene

4,700 J 5,800 J 6,500 J

HT HT

HT/MSD < LH18/24-SP650_092718 HS18091521 Aluminum 0.00919 UB MB Notes: J – Estimated: The analyte was positively identified, the quantitation is an estimation due to discrepancies in meeting certain analyte-specific quality control criteria. UJ – estimated non-detected; The analyte was not positively identified, the quantitation is an estimation due to discrepancies in meeting certain analyte-specific quality control criteria. UB – considered artifact of blank contamination Dup RPD – Field Duplicate Relative Percent Difference outside control limits TB – trip blank MB – method blank MSD < - matrix spike duplicate recovery below control limits HS – Houston

Table 3: Completeness by Method

Method No. of Rejected Results % Completeness SW6850 0 100 E350.3/ SM4500 NH3 0 100 E365.3/ SM4500 P 0 100 E415.1/ SM5310 0 100 SW8270D 0 100 SW8260B 0 100 SW6020A 0 100 SW9056 0 100 SW7196A 0 100 E410.4 0 100 E1664 0 100 TO-15 0 100

00915011


December 2018 Appendix F

APPENDIX F AIR MONITORING DATA – 3RD QUARTER 2018

00915012


Appendix F December 2018


00915013



ATTACHMENT 1: AIR MONITORING CALCULATIONS

00915014

Pollutant CAS #Short Term ESL

March 2012AMCVs

(ST Health)GWTP Ambient Air Concentrations (1) Status (3)

Downwind Ambient Air Concentrations

(2) Status (3)μg/m3 μg/m3 μg/m3 μg/m3

1,1-Dichloroethane 75-34-3 4,000 4,047 0.64 U PASS 0.73 U PASS1,1-Dichloroethene 75-35-4 210 714 0.67 U PASS 0.76 U PASS1,2-Dichloroethane 107-06-2 160 162 0.66 U PASS 0.75 U PASSAcetone 67-64-1 5,900 NA 6.7 U PASS 10.0 PASSBenzene 71-43-2 170 575 0.64 U PASS 0.73 U PASSCarbon disulfide 75-15-0 30 NA 1.4 U PASS 1.6 U PASSChloroform 67-66-3 100 98 0.67 U PASS 0.76 U PASScis-1,2-Dichloroethene 156-59-2 7,900 NA 6.6 PASS 0.75 U PASSMethylene chloride 75-09-2 3,600 12,158 2.5 PASS 0.76 U PASSTetrachloroethene 127-18-4 2,000 6,782 0.66 U PASS 0.75 U PASStrans-1,2-Dichloroethene 156-60-5 7,900 NA 0.66 U PASS 0.75 U PASSTrichloroethene 79-01-6 540 537 18 PASS 0.75 U PASSVinyl chloride 75-01-4 20,000 66,460 0.66 U PASS 0.75 U PASSn-Hexane 110-54-3 5,300 6,336 0.73 PASS 0.79 PASSStyrene 100-42-5 110 21,725 0.66 U PASS 0.75 U PASSToluene 108-88-3 640 15,074 0.66 U PASS 0.75 U PASSEthylbenzene 100-41-4 740 86,844 0.64 U PASS 0.73 U PASSm,p-Xylenes 179601-23-1 180 7,382 1.4 U PASS 1.6 U PASSo-Xylene 95-47-6 1,600 7,382 0.66 U PASS 0.75 U PASS1,3-Dichlorobenzene 541-73-1 720 NA 0.67 U PASS 0.76 U PASSPropene (C3 H6) 115-07-1 Asphyxiant Asphyxiant 0.64 U NA 0.73 U NADichlorodifluoromethane (CCl2F2) 75-71-8 50,000 49,452 1.7 PASS 1.7 PASSEthanol 64-17-5 18,800 NA 6.3 U PASS 7.2 U PASSTrichlorofluoromethane (CCl3F) 75-69-4 28,000 56,184 1 PASS 1.1 PASSTrichlorotrifluoroethane (C2Cl3F3) 76-13-1 38,000 NA 30 PASS 0.75 U PASSalpha-Pinene 80-56-8 60 3,499 0.68 PASS 2.0 PASSd-Limonene 5989-27-5 1,100 NA 0.63 U PASS 0.72 U PASSNotes:(1) Sample collected over an 8-hour period on Sept 11, 2018, between 8 AM and 4 PM

(2) Sample collected over a 24-hour period beginning on Sept 11, 2018, at 6:30 AM and ending on Sept 12, 2018 at 6:30 AM

CAS # = Chemcial Abstracts Service Number

GWTP = Groundwater Treatment Plant

J = estiamted value

U = non-detect

µg/m3 = micrograms per cubic meter

Longhorn Army Ammunition PlantTable 1. Ambient Air Data - September 2018

Groundwater Treatment Plant

(3) Status based on comparison of air sample result to Air Monitoring Comparison Values (AMCVs). When there is no AMCV value for a chemical, the air sample concentration is compared to the short-term Effects Screening Level (ESL).

00915015

Pollutant CAS #

Measured Air Stripper Stack

Concentrations (1)

Air Stripper Emission Rates (2)

Air Stripper Emission

Rates (2a)

Allowable Annual

Emission (3) Status (4) TLV (L) TLV Reference Compliance section

Distance Downwind to nearest off-site Receptor (D)

(K) conversion value

Allowable Maximum Hourly Emission Limit at Nearest off-site Receptor (6)(7)

(E) = L/K Status (8)μg/m3 lb/hr tpy tpy mg/m3 feet lb/hr

1,1-Dichloroethane 75-34-3 120 U 9.84E-04 U 6.39E-04 U 5 PASS 405 ACGIH List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 1.0 PASS1,1-Dichloroethene 75-35-4 160 2.62E-03 1.71E-03 5 PASS 20 ACGIH List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 1.4 PASS1,2-Dichloroethane 107-06-2 160 2.62E-03 1.71E-03 5 PASS 40 ACGIH List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 2.9 PASSAcetone 67-64-1 1,200 U 9.84E-03 U 6.39E-03 U 5 PASS 590 106.262 List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 1.0 PASSBenzene 71-43-2 120 U 9.84E-04 U 6.39E-04 U 5 PASS 3 106.262 List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 0.21 PASSCarbon disulfide 75-15-0 250 U 2.05E-03 U 1.33E-03 U 5 PASS 31 ACGIH List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 2.2 PASSChloroform 67-66-3 120 U 9.84E-04 U 6.39E-04 U 5 PASS 10 106.262 List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 0.71 PASScis-1,2-Dichloroethene 156-59-2 8,900 1.46E-01 9.48E-02 5 PASS 793 ACGIH List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 1.0 PASSMethylene chloride 75-09-2 2,400 3.93E-02 2.56E-02 5 PASS 26 106.262 List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 1.9 PASSTetrachloroethene 127-18-4 160 2.62E-03 1.71E-03 5 PASS 33.5 106.262 List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 2.4 PASStrans-1,2-Dichloroethene 156-60-5 120 U 9.84E-04 U 6.39E-04 U 5 PASS 793 ACGIH List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 1.0 PASSTrichloroethene 79-01-6 22,000 3.61E-01 2.34E-01 5 PASS 135 106.262 List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 6.0 PASSVinyl chloride 75-01-4 330 J 5.41E-03 3.52E-03 5 PASS 2 106.262 List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 0.14 PASSn-Hexane 110-54-3 120 U 9.84E-04 U 6.39E-04 U 5 PASS 1,800 ACGIH List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 1.0 PASSStyrene 100-42-5 120 U 9.84E-04 U 6.39E-04 U 5 PASS 21 106.262 List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 1.5 PASSToluene 108-88-3 120 U 9.84E-04 U 6.39E-04 U 5 PASS 188 ACGIH List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 6.0 PASSEthylbenzene 100-41-4 120 U 9.84E-04 U 6.39E-04 U 5 PASS 434 ACGIH List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 1.0 PASSm,p-Xylenes 179601-23-1 250 U 2.05E-03 U 1.33E-03 U 5 PASS 434 ACGIH List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 1.0 PASSo-Xylene 95-47-6 120 U 9.84E-04 U 6.39E-04 U 5 PASS 434 ACGIH List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 1.0 PASS1,3-Dichlorobenzene 541-73-1 120 U 9.84E-04 U 6.39E-04 U 5 PASS (5) -- 30 TAC 106.533(f)(1)(A)(i) 2,000 14 1.0 PASSPropene (C3 H6) 115-07-1 120 U 9.84E-04 U 6.39E-04 U 5 PASS (5) -- 30 TAC 106.533(f)(1)(A)(i) 2,000 14 6.0 PASSDichlorodifluoromethane (CCl2F2) 75-71-8 120 U 9.84E-04 U 6.39E-04 U 5 PASS 4,950 ACGIH List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 1.0 PASSEthanol 64-17-5 1,200 U 9.84E-03 U 6.39E-03 U 5 PASS 1,880 ACGIH List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 1.0 PASSTrichlorofluoromethane (CCl3F) 75-69-4 120 U 9.84E-04 U 6.39E-04 U 5 PASS 5,620 ACGIH List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 1.0 PASSTrichlorotrifluoroethane (C2Cl3F3) 76-13-1 12,000 1.97E-01 1.28E-01 5 PASS 7,670 ACGIH List 30 TAC 106.533(f)(1)(A)(ii) 2,000 14 1.0 PASSalpha-Pinene 80-56-8 120 U 9.84E-04 U 6.39E-04 U 5 PASS (5) -- 30 TAC 106.533(f)(1)(A)(i) 2,000 14 1.0 PASSd-Limonene 5989-27-5 120 U 9.84E-04 U 6.39E-04 U 5 PASS (5) -- 30 TAC 106.533(f)(1)(A)(i) 2,000 14 1.0 PASS

TOTAL 0.794Notes:(1) Sample collected on Sept 11, 2018. The higher value of the sample or duplicate is reported.(2) Based on a blower flow rate of 4,390 cubic feet per minute (cfm). Note that plant operations is less than or equal to 25 hours per week. 1/2 of detection limit was used for estimating mass rate.(2a) Based on operation of 25 hours per week, 52 weeks per year.(3) Per 30TAC 106.533(f)(1)(B)(4) Based on comparing the calculated air stripper stack sample emission rate in tons per year (tpy) to the allowable annual emission limit per chemical of 5 tpy.(5) No Threshold Limit Values (TLVs) for these chemicals(6) The maximum hourly limit allowed by 30 Texas Administrative Code (TAC) 106.262, per pollutant, is 6 pounds per hour (lb/hr) per "Figure 1: 30 TAC 106.262(a)". The E value was overridden with 6 lb/hr when the calculated E was higher.(7) The maximum hourly emission rate allowed by 30 TAC 106.261(a)(3) for chemicals with a limit value (L) greater than 200 mg/m3 is 1 lb/hr.(8) Based on comparing the calculated air stripper stack sample emission rate in lb/hr to the allowable maximum emission limit per chemical based on distance downwind to nearest off-site receptor.CAS # = Chemical Abstracts Service Numbermg/m3 = milligrams per cubic meterµg/m3 = micrograms per cubic meterU = non-detect

Longhorn Army Ammunition PlantGroundwater Treatment Plant

Table 2. Emission Stack Air Data - September 2018

00915016



ATTACHMENT 2: PID READINGS AND CALIBRATION LOGS

00915017

Table 3: PID Readings

Date Time LocationAir Flow Rate at

Blower Instrument ID Person Collecting PID Reading Weather Conditions7/2/2018 8:00 Outside GWTP Office 3905 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Clear 77 degrees7/2/2018 8:00 Downwind 3905 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Clear 77 degrees7/2/2018 8:00 Stripper 3905 ACFM MiniRAE 3000 Kennie Moore Max. 22.3 ppm Steady State 6.1 ppm Clear 77 degrees7/2/2018 13:00 Outside GWTP Office 3700 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Clear 96 degrees7/2/2018 13:00 Downwind 3700 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Clear 96 degrees7/2/2018 13:00 Stripper 3700 ACFM MiniRAE 3000 Kennie Moore Max. 20.5 ppm Steady State 4.9 ppm Clear 96 degrees

7/24/2018 8:00 Outside GWTP Office 4072 ACFM MiniRAE 3000 Scott Beesinger 0.0 ppm Clear 74 degrees7/24/2018 8:00 Downwind 4072 ACFM MiniRAE 3000 Scott Beesinger 0.0 ppm Clear 74 degrees7/24/2018 8:00 Stripper 4072 ACFM MiniRAE 3000 Scott Beesinger Max. 23.1 ppm Steady State 8.9 ppm Clear 74 degrees7/24/2018 14:00 Outside GWTP Office 3843 ACFM MiniRAE 3000 Scott Beesinger 0.0 ppm Clear 93 degrees7/24/2018 14:00 Downwind 3843 ACFM MiniRAE 3000 Scott Beesinger 0.0 ppm Clear 93 degrees7/24/2018 14:00 Stripper 3843 ACFM MiniRAE 3000 Scott Beesinger Max. 21.5 ppm Steady State 6.4 ppm Clear 93 degrees

8/15/2018 8:00 Outside GWTP Office 3819 ACFM MiniRAE 3000 Scott Beesinger 0.0 ppm Clear 77 degrees8/15/2018 8:00 Downwind 3819 ACFM MiniRAE 3000 Scott Beesinger 0.0 ppm Clear 77 degrees8/15/2018 8:00 Stripper 3819 ACFM MiniRAE 3000 Scott Beesinger Max. 23.1 ppm Steady State 8.9 ppm Clear 77 degrees8/15/2018 14:00 Outside GWTP Office 3714 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Clear 92 degrees8/15/2018 14:00 Downwind 3714 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Clear 92 degrees8/15/2018 14:00 Stripper 3714 ACFM MiniRAE 3000 Kennie Moore Max. 21.5 ppm Steady State 6.4 ppm Clear 92 degrees

8/24/2018 8:00 Outside GWTP Office 3819 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Clear 70 degrees8/24/2018 8:00 Downwind 3819 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Clear 70 degrees8/24/2018 8:00 Stripper 3819 ACFM MiniRAE 3000 Kennie Moore Max. 18.7 ppm Steady State 7.9 ppm Clear 70 degrees

9/4/2018 8:00 Outside GWTP Office 3781 ACFM MiniRAE 3000 Scott Beesinger 0.0 ppm Clear 76 degrees9/4/2018 8:00 Downwind 3781 ACFM MiniRAE 3000 Scott Beesinger 0.0 ppm Clear 76 degrees9/4/2018 8:00 Stripper 3781 ACFM MiniRAE 3000 Scott Beesinger Max. 21.7 ppm Steady State 6.3 ppm Clear 76 degrees9/4/2018 14:00 Outside GWTP Office 3715 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Clear 88 degrees9/4/2018 14:00 Downwind 3715 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Clear 88 degrees9/4/2018 14:00 Stripper 3715 ACFM MiniRAE 3000 Kennie Moore Max. 19.9 ppm Steady State 5.2 ppm Clear 88 degrees

9/11/2018 8:00 Outside GWTP Office 3795 ACFM MiniRAE 3000 Scott Beesinger 0.0 ppm Cloudy 67 degrees9/11/2018 8:00 Downwind 3795 ACFM MiniRAE 3000 Scott Beesinger 0.0 ppm Cloudy 67 degrees9/11/2018 8:00 Stripper 3795 ACFM MiniRAE 3000 Scott Beesinger Max. 22.3 ppm Steady State 7.1 ppm Cloudy 67 degrees9/11/2018 14:00 Outside GWTP Office 3725 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Cloudy 75 degrees9/11/2018 14:00 Downwind 3725 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Cloudy 75 degrees9/11/2018 14:00 Stripper 3725 ACFM MiniRAE 3000 Kennie Moore Max. 24.7 ppm Steady State 8.9 ppm Cloudy 75 degrees

9/17/2018 8:00 Outside GWTP Office 3730 ACFM MiniRAE 3000 Scott Beesinger 0.0 ppm Clear 75 degrees

00915018

Table 3: PID Readings

Date Time LocationAir Flow Rate at

Blower Instrument ID Person Collecting PID Reading Weather Conditions9/17/2018 8:00 Downwind 3730 ACFM MiniRAE 3000 Scott Beesinger 0.0 ppm Clear 75 degrees9/17/2018 8:00 Stripper 3730 ACFM MiniRAE 3000 Scott Beesinger Max. 24.2 ppm Steady State 7.3 ppm Clear 75 degrees9/17/2018 14:00 Outside GWTP Office 3621 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Clear 94 degrees9/17/2018 14:00 Downwind 3621 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Clear 94 degrees9/17/2018 14:00 Stripper 3621 ACFM MiniRAE 3000 Kennie Moore Max. 21.3 ppm Steady State 6.1 ppm Clear 94 degrees

9/24/2018 8:00 Outside GWTP Office 3750 ACFM MiniRAE 3000 Scott Beesinger 0.0 ppm Cloudy 73 degrees9/24/2018 8:00 Downwind 3750 ACFM MiniRAE 3000 Scott Beesinger 0.0 ppm Cloudy 73 degrees9/24/2018 8:00 Stripper 3750 ACFM MiniRAE 3000 Scott Beesinger Max. 23.0 ppm Steady State 6.1 ppm Cloudy 73 degrees9/24/2018 14:00 Outside GWTP Office 3675 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Cloudy 80 degrees9/24/2018 14:00 Downwind 3675 ACFM MiniRAE 3000 Kennie Moore 0.0 ppm Cloudy 80 degrees9/24/2018 14:00 Stripper 3675 ACFM MiniRAE 3000 Kennie Moore Max. 21.6 ppm Steady State 5.4 ppm Cloudy 80 degrees

00915019

00915020

00915021

00915022

00915023

00915024

00915025

00915026

00915027

00915028



ATTACHMENT 3: AIR ANALYTICAL LABORATORY REPORT

00915029


Appendix F December 2018


00915030

2655 Park Center Dr., Suite A Simi Valley, CA 93065 T: +1 805 526 7161 F: +1 805 526 7270 www.alsglobal.com

R I G H T S O L U T I O N S | R I G H T P A R T N E R

LABORATORY REPORT October 1, 2018 Marcia Olive Bhate Environmental Associates, Inc. 445 Union Blvd Suite 129 Lakewood, CO 80228 RE: LHAAP-GWTP / NW01312.0150 Dear Marcia: Enclosed are the results of the samples submitted to our laboratory on September 17, 2018. For your reference, these analyses have been assigned our service request number P1804830. All analyses were performed according to our laboratory’s NELAP and DoD-ELAP-approved quality assurance program. The test results meet requirements of the current NELAP and DoD-ELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP and DoD-ELAP-accredited analytes, refer to the certifications section at www.alsglobal.com. Results are intended to be considered in their entirety and apply only to the samples analyzed and reported herein. If you have any questions, please call me at (805) 526-7161. Respectfully submitted, ALS | Environmental Kate Kaneko Laboratory Director

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http://www.alsglobal.com/


kate.kaneko

Kate



Client: Bhate Environmental Associates, Inc. Service Request No: P1804830 Project: LHAAP-GWTP / NW01312.0150 _______________________________________________________________________________

CASE NARRATIVE

The samples were received intact under chain of custody on September 17, 2018 and were stored in accordance with the analytical method requirements. Please refer to the sample acceptance check form for additional information. The results reported herein are applicable only to the condition of the samples at the time of sample receipt. Volatile Organic Compound Analysis The samples were analyzed for volatile organic compounds in accordance with EPA Method TO-15 from the Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, Second Edition (EPA/625/R-96/010b), January, 1999. This procedure is described in laboratory SOP VOA-TO15. The analytical system was comprised of a gas chromatograph / mass spectrometer (GC/MS) interfaced to a whole-air preconcentrator. This method is included on the laboratory’s NELAP and DoD-ELAP scope of accreditation. Any analytes flagged with an X are not included on the NELAP or DoD-ELAP accreditation. The containers were cleaned, prior to sampling, down to the method reporting limit (MRL) reported for this project. For projects requiring DoD QSM 5.1 compliance canisters were cleaned to <1/2 the MRL. Please note, projects which require reporting below the MRL could have results between the MRL and method detection limit (MDL) that are biased high. _______________________________________________________________________________________ The results of analyses are given in the attached laboratory report. All results are intended to be considered in their entirety, and ALS Environmental (ALS) is not responsible for utilization of less than the complete report. Use of ALS Environmental (ALS)’s Name. Client shall not use ALS’s name or trademark in any marketing or reporting materials, press releases or in any other manner (“Materials”) whatsoever and shall not attribute to ALS any test result, tolerance or specification derived from ALS’s data (“Attribution”) without ALS’s prior written consent, which may be withheld by ALS for any reason in its sole discretion. To request ALS’s consent, Client shall provide copies of the proposed Materials or Attribution and describe in writing Client’s proposed use of such Materials or Attribution. If ALS has not provided written approval of the Materials or Attribution within ten (10) days of receipt from Client, Client’s request to use ALS’s name or trademark in any Materials or Attribution shall be deemed denied. ALS may, in its discretion, reasonably charge Client for its time in reviewing Materials or Attribution requests. Client acknowledges and agrees that the unauthorized use of ALS’s name or trademark may cause ALS to incur irreparable harm for which the recovery of money damages will be inadequate. Accordingly, Client acknowledges and agrees that a violation shall justify preliminary injunctive relief. For questions contact the laboratory.

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ALS Environmental – Simi Valley

CERTIFICATIONS, ACCREDITATIONS, AND REGISTRATIONS


Alaska DEC http://dec.alaska.gov/eh/lab.aspx 17-019

Arizona DHS http://www.azdhs.gov/preparedness/state-laboratory/lab-licensure-certification/index.php#laboratory-licensure-home

AZ0694

Florida DOH (NELAP)

http://www.floridahealth.gov/licensing-and-regulation/environmental-laboratories/index.html

E871020

Louisiana DEQ (NELAP)

http://www.deq.louisiana.gov/page/la-lab-accreditation 05071

Maine DHHS http://www.maine.gov/dhhs/mecdc/environmental-health/dwp/professionals/labCert.shtml

2016036

Minnesota DOH (NELAP)

http://www.health.state.mn.us/accreditation 1347317

New Jersey DEP (NELAP)

http://www.nj.gov/dep/enforcement/oqa.html CA009

New York DOH (NELAP)

http://www.wadsworth.org/labcert/elap/elap.html 11221

Oregon PHD (NELAP)

http://www.oregon.gov/oha/ph/LaboratoryServices/EnvironmentalLaboratoryAccreditation/Pages/index.aspx

4068-005

Pennsylvania DEP http://www.dep.pa.gov/Business/OtherPrograms/Labs/Pages/Laboratory-Accreditation-Program.aspx

68-03307 (Registration)

PJLA (DoD ELAP)

http://www.pjlabs.com/search-accredited-labs 65818

(Testing) Texas CEQ (NELAP)

http://www.tceq.texas.gov/agency/qa/env_lab_accreditation.html T104704413-

18-9 Utah DOH (NELAP)

http://health.utah.gov/lab/lab_cert_env CA01627201

8-9


Analyses were performed according to our laboratory’s NELAP and DoD-ELAP approved quality assurance program. A complete listing of specific NELAP and DoD-ELAP certified analytes can be found in the certifications section at www.alsglobal.com, or at the accreditation body’s website. Each of the certifications listed above have an explicit Scope of Accreditation that applies to specific matrices/methods/analytes; therefore, please contact the laboratory for information corresponding to a particular certification.

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00915033


http://dec.alaska.gov/eh/lab.aspx

http://www.azdhs.gov/preparedness/state-laboratory/lab-licensure-certification/index.php#laboratory-licensure-home

http://www.azdhs.gov/preparedness/state-laboratory/lab-licensure-certification/index.php#laboratory-licensure-home



http://www.deq.louisiana.gov/page/la-lab-accreditation

http://www.maine.gov/dhhs/mecdc/environmental-health/dwp/professionals/labCert.shtml

http://www.maine.gov/dhhs/mecdc/environmental-health/dwp/professionals/labCert.shtml

http://www.health.state.mn.us/accreditation

http://www.nj.gov/dep/enforcement/oqa.html

http://www.wadsworth.org/labcert/elap/elap.html



http://www.dep.pa.gov/Business/OtherPrograms/Labs/Pages/Laboratory-Accreditation-Program.aspx

http://www.dep.pa.gov/Business/OtherPrograms/Labs/Pages/Laboratory-Accreditation-Program.aspx

http://www.pjlabs.com/search-accredited-labs

http://www.tceq.texas.gov/agency/qa/env_lab_accreditation.html

http://health.utah.gov/lab/lab_cert_env

http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html


P1804830_Detail Summary_1809291336_RG.xls - DETAIL SUMMARY

Client: Bhate Environmental Associates, Inc. Service Request: P1804830Project ID: LHAAP-GWTP / NW01312.0150

Date Received: 9/17/2018Time Received: 09:15

Client Sample ID Lab Code MatrixDate

CollectedTime

CollectedContainer

IDPi1

(psig)Pf1

(psig)

LH18/24-Air_091018_Stripper P1804830-001 Air 9/11/2018 14:00 SC01504 -0.20 3.57 XLH18/24-Air_091018_Stripper_a P1804830-002 Air 9/11/2018 14:00 SC01995 -1.21 3.86 XLH18/24-Air_091018_GWTP P1804830-003 Air 9/11/2018 14:15 AC00927 -0.04 3.53 XLH18/24-Air_091018_Downwind P1804830-004 Air 9/12/2018 06:30 AC02066 -1.66 3.73 X

ALS ENVIRONMENTAL

DETAIL SUMMARY REPORT

TO-1

5 - V

OC

Can

s

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00915034

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10/1/18 3:07 PMP1804830_Bhate Environmental Associates, Inc._LHAAP-GWTP _ NW01312.0150.xls - Page 1 of 1

ALS EnvironmentalSample Acceptance Check Form

Client: Bhate Environmental Associates, Inc. Work order: P1804830Project: LHAAP-GWTP / NW01312.0150Sample(s) received on: 9/17/18 Date opened: 9/17/18 by: AARON GONZALEZ

Note: This form is used for all samples received by ALS. The use of this form for custody seals is strictly meant to indicate presence/absence and not as an indication of

compliance or nonconformity. Thermal preservation and pH will only be evaluated either at the request of the client and/or as required by the method/SOP.Yes No N/A

1 Were sample containers properly marked with client sample ID? 2 Did sample containers arrive in good condition? 3 Were chain-of-custody papers used and filled out? 4 Did sample container labels and/or tags agree with custody papers? 5 Was sample volume received adequate for analysis? 6 Are samples within specified holding times? 7 Was proper temperature (thermal preservation) of cooler at receipt adhered to?

8 Were custody seals on outside of cooler/Box/Container? Location of seal(s)? Sealing Lid?

Were signature and date included? Were seals intact?

9 Is there a client indication that the submitted samples are pH preserved? Were VOA vials checked for presence/absence of air bubbles?

10 Tubes: Are the tubes capped and intact? 11 Badges: Are the badges properly capped and intact?

Are dual bed badges separated and individually capped and intact?

Lab Sample ID Container Required Received Adjusted VOA HeadspaceDescription pH * pH pH (Presence/Absence) Comments

6.0 L Source Can6.0 L Source Can6.0 L Ambient Can 6.0 L Ambient Can

RSK - MEEPP, HCL (pH<2); RSK - CO2, (pH 5-8); Sulfur (pH>4)

Do containers have appropriate preservation, according to method/SOP or Client specified information?

Does the client/method/SOP require that the analyst check the sample pH and if necessary alter it?

Receipt / Preservation

P1804830-001.01P1804830-002.01P1804830-003.01P1804830-004.01

Explain any discrepancies: (include lab sample ID numbers):

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00915036

TO15SCAN.XLS - 75 Compounds - PageNo.:P1804830_TO15_1809291244_SC.xls - Sample

ALS ENVIRONMENTAL

RESULTS OF ANALYSISPage 1 of 3

Client: Bhate Environmental Associates, Inc.LH18/24-Air_091018_Stripper ALS Project ID: P1804830

ALS Sample ID: P1804830-001

Test Code: EPA TO-15 Date Collected: 9/11/18Instrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date Received: 9/17/18Analyst: Anusha Bayyarapu Date Analyzed: 9/28/18Sample Type: 6.0 L Summa Canister Volume(s) Analyzed: 0.010 Liter(s)Test Notes: 0.0040 Liter(s)Container ID: SC01504

Initial Pressure (psig): -0.20 Final Pressure (psig): 3.57

Container Dilution Factor: 1.26

CAS # Compound MRL MRL Dataµg/m³ ppbV Qualifier

115-07-1 Propene ND 66 ND 38 75-71-8 Dichlorodifluoromethane (CFC 12) ND 66 ND 13 74-87-3 Chloromethane ND 63 ND 31

76-14-2 1,2-Dichloro-1,1,2,2-tetrafluoroethane (CFC 114) ND 64 ND 9.2

75-01-4 Vinyl Chloride 230 67 91 26 106-99-0 1,3-Butadiene ND 66 ND 30 74-83-9 Bromomethane ND 63 ND 16 75-00-3 Chloroethane ND 64 ND 24 64-17-5 Ethanol ND 640 ND 340 75-05-8 Acetonitrile ND 66 ND 39 107-02-8 Acrolein ND 130 ND 55 67-64-1 Acetone ND 680 ND 290 75-69-4 Trichlorofluoromethane (CFC 11) ND 67 ND 12 67-63-0 2-Propanol (Isopropyl Alcohol) ND 260 ND 110 107-13-1 Acrylonitrile ND 66 ND 30 75-35-4 1,1-Dichloroethene 130 68 34 17 75-09-2 Methylene Chloride 2,000 68 590 20 107-05-1 3-Chloro-1-propene (Allyl Chloride) ND 67 ND 21 76-13-1 Trichlorotrifluoroethane (CFC 113) 9,900 67 1,300 8.7 75-15-0 Carbon Disulfide ND 140 ND 45 156-60-5 trans-1,2-Dichloroethene ND 67 ND 17 75-34-3 1,1-Dichloroethane ND 66 ND 16 1634-04-4 Methyl tert-Butyl Ether ND 68 ND 19 108-05-4 Vinyl Acetate ND 670 ND 190 78-93-3 2-Butanone (MEK) ND 130 ND 43

ND = Compound was analyzed for, but not detected above the laboratory reporting limit.MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method.

µg/m³

Client Sample ID:Client Project ID:

Result

LHAAP-GWTP / NW01312.0150

ResultppbV

7 of 142

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ALS ENVIRONMENTAL








156-59-2 cis-1,2-Dichloroethene 7,400 67 1,900 17 141-78-6 Ethyl Acetate ND 140 ND 38 110-54-3 n-Hexane ND 68 ND 19 67-66-3 Chloroform ND 68 ND 14 109-99-9 Tetrahydrofuran (THF) ND 67 ND 23 107-06-2 1,2-Dichloroethane 130 67 33 17 71-55-6 1,1,1-Trichloroethane ND 68 ND 12 71-43-2 Benzene ND 66 ND 21 56-23-5 Carbon Tetrachloride ND 66 ND 10 110-82-7 Cyclohexane ND 130 ND 37 78-87-5 1,2-Dichloropropane ND 68 ND 15 75-27-4 Bromodichloromethane ND 67 ND 10 79-01-6 Trichloroethene 22,000 170 4,000 31 D123-91-1 1,4-Dioxane ND 67 ND 19 80-62-6 Methyl Methacrylate ND 140 ND 34 142-82-5 n-Heptane ND 68 ND 17 10061-01-5 cis-1,3-Dichloropropene ND 71 ND 16 108-10-1 4-Methyl-2-pentanone ND 67 ND 16 10061-02-6 trans-1,3-Dichloropropene ND 67 ND 15 79-00-5 1,1,2-Trichloroethane ND 68 ND 12 108-88-3 Toluene ND 67 ND 18 591-78-6 2-Hexanone ND 68 ND 17 124-48-1 Dibromochloromethane ND 68 ND 8.0 106-93-4 1,2-Dibromoethane ND 68 ND 8.9 123-86-4 n-Butyl Acetate ND 68 ND 14

ND = Compound was analyzed for, but not detected above the laboratory reporting limit.MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method.D = The reported result is from a dilution.

ResultppbV

Resultµg/m³



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ALS ENVIRONMENTAL







MRL MRL Data CAS # Compound µg/m³ ppbV Qualifier

111-65-9 n-Octane ND 68 ND 15 127-18-4 Tetrachloroethene 140 67 21 9.9 108-90-7 Chlorobenzene ND 67 ND 15 100-41-4 Ethylbenzene ND 66 ND 15 179601-23-1 m,p-Xylenes ND 140 ND 32 75-25-2 Bromoform ND 67 ND 6.5 100-42-5 Styrene ND 67 ND 16 95-47-6 o-Xylene ND 67 ND 15 111-84-2 n-Nonane ND 68 ND 13 79-34-5 1,1,2,2-Tetrachloroethane ND 67 ND 9.7 98-82-8 Cumene ND 67 ND 14 80-56-8 alpha-Pinene ND 66 ND 12 103-65-1 n-Propylbenzene ND 68 ND 14 622-96-8 4-Ethyltoluene ND 67 ND 14 108-67-8 1,3,5-Trimethylbenzene ND 67 ND 14 95-63-6 1,2,4-Trimethylbenzene ND 67 ND 14 100-44-7 Benzyl Chloride ND 140 ND 27 541-73-1 1,3-Dichlorobenzene ND 68 ND 11 106-46-7 1,4-Dichlorobenzene ND 68 ND 11 95-50-1 1,2-Dichlorobenzene ND 68 ND 11 5989-27-5 d-Limonene ND 64 ND 12 96-12-8 1,2-Dibromo-3-chloropropane ND 66 ND 6.8 120-82-1 1,2,4-Trichlorobenzene ND 67 ND 9.0 91-20-3 Naphthalene ND 64 ND 12 87-68-3 Hexachlorobutadiene ND 67 ND 6.3


Client Project ID:

ResultResultppbV

µg/m³

Client Sample ID:LHAAP-GWTP / NW01312.0150

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00915039

TO15SCAN.XLS - 75 Compounds - PageNo.:P1804830_TO15_1809291244_SC.xls - Sample (2)

ALS ENVIRONMENTAL


Client: Bhate Environmental Associates, Inc.LH18/24-Air_091018_Stripper_a ALS Project ID: P1804830


Test Code: EPA TO-15 Date Collected: 9/11/18Instrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date Received: 9/17/18Analyst: Anusha Bayyarapu Date Analyzed: 9/28/18Sample Type: 6.0 L Summa Canister Volume(s) Analyzed: 0.0060 Liter(s)Test Notes: Container ID: SC01995




115-07-1 Propene ND 120 ND 70 75-71-8 Dichlorodifluoromethane (CFC 12) ND 120 ND 24 74-87-3 Chloromethane ND 120 ND 56

76-14-2 1,2-Dichloro-1,1,2,2-tetrafluoroethane (CFC 114) ND 120 ND 17

75-01-4 Vinyl Chloride 330 120 130 48 106-99-0 1,3-Butadiene ND 120 ND 54 74-83-9 Bromomethane ND 120 ND 30 75-00-3 Chloroethane ND 120 ND 44 64-17-5 Ethanol ND 1,200 ND 620 75-05-8 Acetonitrile ND 120 ND 71 107-02-8 Acrolein ND 230 ND 100 67-64-1 Acetone ND 1,200 ND 520 75-69-4 Trichlorofluoromethane (CFC 11) ND 120 ND 22 67-63-0 2-Propanol (Isopropyl Alcohol) ND 480 ND 200 107-13-1 Acrylonitrile ND 120 ND 55 75-35-4 1,1-Dichloroethene 160 120 39 31 75-09-2 Methylene Chloride 2,400 120 690 36 107-05-1 3-Chloro-1-propene (Allyl Chloride) ND 120 ND 39 76-13-1 Trichlorotrifluoroethane (CFC 113) 12,000 120 1,500 16 75-15-0 Carbon Disulfide ND 250 ND 81 156-60-5 trans-1,2-Dichloroethene ND 120 ND 31 75-34-3 1,1-Dichloroethane ND 120 ND 30 1634-04-4 Methyl tert-Butyl Ether ND 120 ND 34 108-05-4 Vinyl Acetate ND 1,200 ND 350 78-93-3 2-Butanone (MEK) ND 230 ND 78



Result


ResultppbVµg/m³

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ALS ENVIRONMENTAL








156-59-2 cis-1,2-Dichloroethene 8,900 120 2,200 31 141-78-6 Ethyl Acetate ND 250 ND 70 110-54-3 n-Hexane ND 120 ND 35 67-66-3 Chloroform ND 120 ND 25 109-99-9 Tetrahydrofuran (THF) ND 120 ND 41 107-06-2 1,2-Dichloroethane 160 120 38 30 71-55-6 1,1,1-Trichloroethane ND 120 ND 23 71-43-2 Benzene ND 120 ND 37 56-23-5 Carbon Tetrachloride ND 120 ND 19 110-82-7 Cyclohexane ND 230 ND 67 78-87-5 1,2-Dichloropropane ND 120 ND 27 75-27-4 Bromodichloromethane ND 120 ND 18 79-01-6 Trichloroethene 19,000 120 3,500 23 123-91-1 1,4-Dioxane ND 120 ND 34 80-62-6 Methyl Methacrylate ND 250 ND 62 142-82-5 n-Heptane ND 120 ND 30 10061-01-5 cis-1,3-Dichloropropene ND 130 ND 28 108-10-1 4-Methyl-2-pentanone ND 120 ND 30 10061-02-6 trans-1,3-Dichloropropene ND 120 ND 27 79-00-5 1,1,2-Trichloroethane ND 120 ND 23 108-88-3 Toluene ND 120 ND 32 591-78-6 2-Hexanone ND 120 ND 30 124-48-1 Dibromochloromethane ND 120 ND 15 106-93-4 1,2-Dibromoethane ND 120 ND 16 123-86-4 n-Butyl Acetate ND 120 ND 26




ResultppbV

Resultµg/m³

11 of 142

00915041


ALS ENVIRONMENTAL








111-65-9 n-Octane ND 120 ND 27 127-18-4 Tetrachloroethene 160 120 24 18 108-90-7 Chlorobenzene ND 120 ND 26 100-41-4 Ethylbenzene ND 120 ND 28 179601-23-1 m,p-Xylenes ND 250 ND 58 75-25-2 Bromoform ND 120 ND 12 100-42-5 Styrene ND 120 ND 29 95-47-6 o-Xylene ND 120 ND 28 111-84-2 n-Nonane ND 120 ND 24 79-34-5 1,1,2,2-Tetrachloroethane ND 120 ND 18 98-82-8 Cumene ND 120 ND 25 80-56-8 alpha-Pinene ND 120 ND 21 103-65-1 n-Propylbenzene ND 120 ND 25 622-96-8 4-Ethyltoluene ND 120 ND 25 108-67-8 1,3,5-Trimethylbenzene ND 120 ND 25 95-63-6 1,2,4-Trimethylbenzene ND 120 ND 25 100-44-7 Benzyl Chloride ND 250 ND 49 541-73-1 1,3-Dichlorobenzene ND 120 ND 21 106-46-7 1,4-Dichlorobenzene ND 120 ND 21 95-50-1 1,2-Dichlorobenzene ND 120 ND 21 5989-27-5 d-Limonene ND 120 ND 21 96-12-8 1,2-Dibromo-3-chloropropane ND 120 ND 12 120-82-1 1,2,4-Trichlorobenzene ND 120 ND 16 91-20-3 Naphthalene ND 120 ND 22 87-68-3 Hexachlorobutadiene ND 120 ND 11


ResultResultppbV

µg/m³

Client Sample ID:LHAAP-GWTP / NW01312.0150Client Project ID:

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00915042


ALS ENVIRONMENTAL


Client: Bhate Environmental Associates, Inc.LH18/24-Air_091018_GWTP ALS Project ID: P1804830


Test Code: EPA TO-15 Date Collected: 9/11/18Instrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date Received: 9/17/18Analyst: Anusha Bayyarapu Date Analyzed: 9/28/18Sample Type: 6.0 L Summa Canister Volume(s) Analyzed: 1.00 Liter(s)Test Notes: Container ID: AC00927




115-07-1 Propene ND 0.64 ND 0.37 75-71-8 Dichlorodifluoromethane (CFC 12) 1.7 0.64 0.34 0.13 74-87-3 Chloromethane ND 0.62 ND 0.30

76-14-2 1,2-Dichloro-1,1,2,2-tetrafluoroethane (CFC 114) ND 0.63 ND 0.091

75-01-4 Vinyl Chloride ND 0.66 ND 0.26 106-99-0 1,3-Butadiene ND 0.64 ND 0.29 74-83-9 Bromomethane ND 0.62 ND 0.16 75-00-3 Chloroethane ND 0.63 ND 0.24 64-17-5 Ethanol ND 6.3 ND 3.4 75-05-8 Acetonitrile ND 0.64 ND 0.38 107-02-8 Acrolein ND 1.2 ND 0.54 67-64-1 Acetone ND 6.7 ND 2.8 75-69-4 Trichlorofluoromethane (CFC 11) 1.0 0.66 0.18 0.12 67-63-0 2-Propanol (Isopropyl Alcohol) ND 2.6 ND 1.1 107-13-1 Acrylonitrile ND 0.64 ND 0.30 75-35-4 1,1-Dichloroethene ND 0.67 ND 0.17 75-09-2 Methylene Chloride 2.5 0.67 0.71 0.19 107-05-1 3-Chloro-1-propene (Allyl Chloride) ND 0.66 ND 0.21 76-13-1 Trichlorotrifluoroethane (CFC 113) 30 0.66 4.0 0.086 75-15-0 Carbon Disulfide ND 1.4 ND 0.44 156-60-5 trans-1,2-Dichloroethene ND 0.66 ND 0.17 75-34-3 1,1-Dichloroethane ND 0.64 ND 0.16 1634-04-4 Methyl tert-Butyl Ether ND 0.67 ND 0.19 108-05-4 Vinyl Acetate ND 6.6 ND 1.9 78-93-3 2-Butanone (MEK) 1.5 1.2 0.51 0.42


µg/m³


Result


ResultppbV

13 of 142

00915043


ALS ENVIRONMENTAL








156-59-2 cis-1,2-Dichloroethene 6.6 0.66 1.7 0.17 141-78-6 Ethyl Acetate ND 1.4 ND 0.38 110-54-3 n-Hexane 0.73 0.67 0.21 0.19 67-66-3 Chloroform ND 0.67 ND 0.14 109-99-9 Tetrahydrofuran (THF) ND 0.66 ND 0.22 107-06-2 1,2-Dichloroethane ND 0.66 ND 0.16 71-55-6 1,1,1-Trichloroethane ND 0.67 ND 0.12 71-43-2 Benzene ND 0.64 ND 0.20 56-23-5 Carbon Tetrachloride ND 0.64 ND 0.10 110-82-7 Cyclohexane ND 1.2 ND 0.36 78-87-5 1,2-Dichloropropane ND 0.67 ND 0.14 75-27-4 Bromodichloromethane ND 0.66 ND 0.098 79-01-6 Trichloroethene 18 0.66 3.3 0.12 123-91-1 1,4-Dioxane ND 0.66 ND 0.18 80-62-6 Methyl Methacrylate ND 1.4 ND 0.33 142-82-5 n-Heptane ND 0.67 ND 0.16 10061-01-5 cis-1,3-Dichloropropene ND 0.69 ND 0.15 108-10-1 4-Methyl-2-pentanone ND 0.66 ND 0.16 10061-02-6 trans-1,3-Dichloropropene ND 0.66 ND 0.14 79-00-5 1,1,2-Trichloroethane ND 0.67 ND 0.12 108-88-3 Toluene ND 0.66 ND 0.17 591-78-6 2-Hexanone ND 0.67 ND 0.16 124-48-1 Dibromochloromethane ND 0.67 ND 0.079 106-93-4 1,2-Dibromoethane ND 0.67 ND 0.087 123-86-4 n-Butyl Acetate ND 0.67 ND 0.14


ResultppbV

Resultµg/m³



14 of 142

00915044


ALS ENVIRONMENTAL








111-65-9 n-Octane ND 0.67 ND 0.14 127-18-4 Tetrachloroethene ND 0.66 ND 0.097 108-90-7 Chlorobenzene ND 0.66 ND 0.14 100-41-4 Ethylbenzene ND 0.64 ND 0.15 179601-23-1 m,p-Xylenes ND 1.4 ND 0.31 75-25-2 Bromoform ND 0.66 ND 0.064 100-42-5 Styrene ND 0.66 ND 0.15 95-47-6 o-Xylene ND 0.66 ND 0.15 111-84-2 n-Nonane ND 0.67 ND 0.13 79-34-5 1,1,2,2-Tetrachloroethane ND 0.66 ND 0.096 98-82-8 Cumene ND 0.66 ND 0.13 80-56-8 alpha-Pinene 0.68 0.64 0.12 0.12 103-65-1 n-Propylbenzene ND 0.67 ND 0.14 622-96-8 4-Ethyltoluene ND 0.66 ND 0.13 108-67-8 1,3,5-Trimethylbenzene ND 0.66 ND 0.13 95-63-6 1,2,4-Trimethylbenzene ND 0.66 ND 0.13 100-44-7 Benzyl Chloride ND 1.4 ND 0.26 541-73-1 1,3-Dichlorobenzene ND 0.67 ND 0.11 106-46-7 1,4-Dichlorobenzene ND 0.67 ND 0.11 95-50-1 1,2-Dichlorobenzene ND 0.67 ND 0.11 5989-27-5 d-Limonene ND 0.63 ND 0.11 96-12-8 1,2-Dibromo-3-chloropropane ND 0.64 ND 0.067 120-82-1 1,2,4-Trichlorobenzene ND 0.66 ND 0.089 91-20-3 Naphthalene ND 0.63 ND 0.12 87-68-3 Hexachlorobutadiene ND 0.66 ND 0.062


Client Project ID:

ResultResultppbV

µg/m³

Client Sample ID:LHAAP-GWTP / NW01312.0150

15 of 142

00915045


ALS ENVIRONMENTAL


Client: Bhate Environmental Associates, Inc.LH18/24-Air_091018_Downwind ALS Project ID: P1804830






115-07-1 Propene ND 0.73 ND 0.43 75-71-8 Dichlorodifluoromethane (CFC 12) 1.7 0.73 0.35 0.15 74-87-3 Chloromethane ND 0.71 ND 0.34


75-01-4 Vinyl Chloride ND 0.75 ND 0.29 106-99-0 1,3-Butadiene ND 0.73 ND 0.33 74-83-9 Bromomethane ND 0.71 ND 0.18 75-00-3 Chloroethane ND 0.72 ND 0.27 64-17-5 Ethanol ND 7.2 ND 3.8 75-05-8 Acetonitrile ND 0.73 ND 0.44 107-02-8 Acrolein ND 1.4 ND 0.62 67-64-1 Acetone 10 7.6 4.4 3.2 M175-69-4 Trichlorofluoromethane (CFC 11) 1.1 0.75 0.19 0.13 67-63-0 2-Propanol (Isopropyl Alcohol) ND 3.0 ND 1.2 107-13-1 Acrylonitrile ND 0.73 ND 0.34 75-35-4 1,1-Dichloroethene ND 0.76 ND 0.19 75-09-2 Methylene Chloride ND 0.76 ND 0.22 107-05-1 3-Chloro-1-propene (Allyl Chloride) ND 0.75 ND 0.24 76-13-1 Trichlorotrifluoroethane (CFC 113) ND 0.75 ND 0.098 75-15-0 Carbon Disulfide ND 1.6 ND 0.50 156-60-5 trans-1,2-Dichloroethene ND 0.75 ND 0.19 75-34-3 1,1-Dichloroethane ND 0.73 ND 0.18 1634-04-4 Methyl tert-Butyl Ether ND 0.76 ND 0.21 108-05-4 Vinyl Acetate ND 7.5 ND 2.1 78-93-3 2-Butanone (MEK) 1.6 1.4 0.53 0.48

ND = Compound was analyzed for, but not detected above the laboratory reporting limit.MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method.M1 = Matrix interference due to coelution with a non-target compound; results may be biased high.


Result


ResultppbVµg/m³

16 of 142

00915046


ALS ENVIRONMENTAL








156-59-2 cis-1,2-Dichloroethene ND 0.75 ND 0.19 141-78-6 Ethyl Acetate ND 1.6 ND 0.43 110-54-3 n-Hexane 0.79 0.76 0.22 0.22 67-66-3 Chloroform ND 0.76 ND 0.16 109-99-9 Tetrahydrofuran (THF) ND 0.75 ND 0.25 107-06-2 1,2-Dichloroethane ND 0.75 ND 0.18 71-55-6 1,1,1-Trichloroethane ND 0.76 ND 0.14 71-43-2 Benzene ND 0.73 ND 0.23 56-23-5 Carbon Tetrachloride ND 0.73 ND 0.12 110-82-7 Cyclohexane ND 1.4 ND 0.41 78-87-5 1,2-Dichloropropane ND 0.76 ND 0.16 75-27-4 Bromodichloromethane ND 0.75 ND 0.11 79-01-6 Trichloroethene ND 0.75 ND 0.14 123-91-1 1,4-Dioxane ND 0.75 ND 0.21 80-62-6 Methyl Methacrylate ND 1.6 ND 0.38 142-82-5 n-Heptane ND 0.76 ND 0.19 10061-01-5 cis-1,3-Dichloropropene ND 0.79 ND 0.17 108-10-1 4-Methyl-2-pentanone ND 0.75 ND 0.18 10061-02-6 trans-1,3-Dichloropropene ND 0.75 ND 0.16 79-00-5 1,1,2-Trichloroethane ND 0.76 ND 0.14 108-88-3 Toluene ND 0.75 ND 0.20 591-78-6 2-Hexanone ND 0.76 ND 0.19 124-48-1 Dibromochloromethane ND 0.76 ND 0.089 106-93-4 1,2-Dibromoethane ND 0.76 ND 0.099 123-86-4 n-Butyl Acetate ND 0.76 ND 0.16




ResultppbV

Resultµg/m³

17 of 142

00915047


ALS ENVIRONMENTAL








111-65-9 n-Octane ND 0.76 ND 0.16 127-18-4 Tetrachloroethene ND 0.75 ND 0.11 108-90-7 Chlorobenzene ND 0.75 ND 0.16 100-41-4 Ethylbenzene ND 0.73 ND 0.17 179601-23-1 m,p-Xylenes ND 1.6 ND 0.36 75-25-2 Bromoform ND 0.75 ND 0.072 100-42-5 Styrene ND 0.75 ND 0.18 95-47-6 o-Xylene ND 0.75 ND 0.17 111-84-2 n-Nonane ND 0.76 ND 0.15 79-34-5 1,1,2,2-Tetrachloroethane ND 0.75 ND 0.11 98-82-8 Cumene ND 0.75 ND 0.15 80-56-8 alpha-Pinene 2.0 0.73 0.37 0.13 103-65-1 n-Propylbenzene ND 0.76 ND 0.15 622-96-8 4-Ethyltoluene ND 0.75 ND 0.15 108-67-8 1,3,5-Trimethylbenzene ND 0.75 ND 0.15 95-63-6 1,2,4-Trimethylbenzene ND 0.75 ND 0.15 100-44-7 Benzyl Chloride ND 1.6 ND 0.30 541-73-1 1,3-Dichlorobenzene ND 0.76 ND 0.13 106-46-7 1,4-Dichlorobenzene ND 0.76 ND 0.13 95-50-1 1,2-Dichlorobenzene ND 0.76 ND 0.13 5989-27-5 d-Limonene ND 0.72 ND 0.13 96-12-8 1,2-Dibromo-3-chloropropane ND 0.73 ND 0.076 120-82-1 1,2,4-Trichlorobenzene ND 0.75 ND 0.10 91-20-3 Naphthalene ND 0.72 ND 0.14 87-68-3 Hexachlorobutadiene ND 0.75 ND 0.070


ResultResultppbV

µg/m³

Client Sample ID:LHAAP-GWTP / NW01312.0150Client Project ID:

18 of 142

00915048

TO15SCAN.XLS - 75 Compounds - PageNo.:P1804830_TO15_1809291244_SC.xls - MBlank

ALS ENVIRONMENTAL


Client: Bhate Environmental Associates, Inc.Method Blank ALS Project ID: P1804830

ALS Sample ID: P180928-MB Test Code: EPA TO-15 Date Collected: NAInstrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date Received: NAAnalyst: Anusha Bayyarapu Date Analyzed: 9/28/18Sample Type: 6.0 L Summa Canister Volume(s) Analyzed: 1.00 Liter(s)Test Notes:



115-07-1 Propene ND 0.52 ND 0.30 75-71-8 Dichlorodifluoromethane (CFC 12) ND 0.52 ND 0.11 74-87-3 Chloromethane ND 0.50 ND 0.24


75-01-4 Vinyl Chloride ND 0.53 ND 0.21 106-99-0 1,3-Butadiene ND 0.52 ND 0.24 74-83-9 Bromomethane ND 0.50 ND 0.13 75-00-3 Chloroethane ND 0.51 ND 0.19 64-17-5 Ethanol ND 5.1 ND 2.7 75-05-8 Acetonitrile ND 0.52 ND 0.31 107-02-8 Acrolein ND 1.0 ND 0.44 67-64-1 Acetone ND 5.4 ND 2.3 75-69-4 Trichlorofluoromethane (CFC 11) ND 0.53 ND 0.094 67-63-0 2-Propanol (Isopropyl Alcohol) ND 2.1 ND 0.85 107-13-1 Acrylonitrile ND 0.52 ND 0.24 75-35-4 1,1-Dichloroethene ND 0.54 ND 0.14 75-09-2 Methylene Chloride ND 0.54 ND 0.16 107-05-1 3-Chloro-1-propene (Allyl Chloride) ND 0.53 ND 0.17 76-13-1 Trichlorotrifluoroethane (CFC 113) ND 0.53 ND 0.069 75-15-0 Carbon Disulfide ND 1.1 ND 0.35 156-60-5 trans-1,2-Dichloroethene ND 0.53 ND 0.13 75-34-3 1,1-Dichloroethane ND 0.52 ND 0.13 1634-04-4 Methyl tert-Butyl Ether ND 0.54 ND 0.15 108-05-4 Vinyl Acetate ND 5.3 ND 1.5 78-93-3 2-Butanone (MEK) ND 1.0 ND 0.34


Client Sample ID:Client Project ID: LHAAP-GWTP / NW01312.0150

ResultppbV

Resultµg/m³

19 of 142

00915049


ALS ENVIRONMENTAL



ALS Sample ID: P180928-MB

Test Code: EPA TO-15 Date Collected: NAInstrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date Received: NAAnalyst: Anusha Bayyarapu Date Analyzed: 9/28/18Sample Type: 6.0 L Summa Canister Volume(s) Analyzed: 1.00 Liter(s)Test Notes:



156-59-2 cis-1,2-Dichloroethene ND 0.53 ND 0.13 141-78-6 Ethyl Acetate ND 1.1 ND 0.31 110-54-3 n-Hexane ND 0.54 ND 0.15 67-66-3 Chloroform ND 0.54 ND 0.11 109-99-9 Tetrahydrofuran (THF) ND 0.53 ND 0.18 107-06-2 1,2-Dichloroethane ND 0.53 ND 0.13 71-55-6 1,1,1-Trichloroethane ND 0.54 ND 0.099 71-43-2 Benzene ND 0.52 ND 0.16 56-23-5 Carbon Tetrachloride ND 0.52 ND 0.083 110-82-7 Cyclohexane ND 1.0 ND 0.29 78-87-5 1,2-Dichloropropane ND 0.54 ND 0.12 75-27-4 Bromodichloromethane ND 0.53 ND 0.079 79-01-6 Trichloroethene ND 0.53 ND 0.099 123-91-1 1,4-Dioxane ND 0.53 ND 0.15 80-62-6 Methyl Methacrylate ND 1.1 ND 0.27 142-82-5 n-Heptane ND 0.54 ND 0.13 10061-01-5 cis-1,3-Dichloropropene ND 0.56 ND 0.12 108-10-1 4-Methyl-2-pentanone ND 0.53 ND 0.13 10061-02-6 trans-1,3-Dichloropropene ND 0.53 ND 0.12 79-00-5 1,1,2-Trichloroethane ND 0.54 ND 0.099 108-88-3 Toluene ND 0.53 ND 0.14 591-78-6 2-Hexanone ND 0.54 ND 0.13 124-48-1 Dibromochloromethane ND 0.54 ND 0.063 106-93-4 1,2-Dibromoethane ND 0.54 ND 0.070 123-86-4 n-Butyl Acetate ND 0.54 ND 0.11


ppbVResultµg/m³

Client Sample ID:Client Project ID: LHAAP-GWTP / NW01312.0150

Result

20 of 142

00915050


ALS ENVIRONMENTAL



ALS Sample ID: P180928-MB




111-65-9 n-Octane ND 0.54 ND 0.12 127-18-4 Tetrachloroethene ND 0.53 ND 0.078 108-90-7 Chlorobenzene ND 0.53 ND 0.12 100-41-4 Ethylbenzene ND 0.52 ND 0.12 179601-23-1 m,p-Xylenes ND 1.1 ND 0.25 75-25-2 Bromoform ND 0.53 ND 0.051 100-42-5 Styrene ND 0.53 ND 0.12 95-47-6 o-Xylene ND 0.53 ND 0.12 111-84-2 n-Nonane ND 0.54 ND 0.10 79-34-5 1,1,2,2-Tetrachloroethane ND 0.53 ND 0.077 98-82-8 Cumene ND 0.53 ND 0.11 80-56-8 alpha-Pinene ND 0.52 ND 0.093 103-65-1 n-Propylbenzene ND 0.54 ND 0.11 622-96-8 4-Ethyltoluene ND 0.53 ND 0.11 108-67-8 1,3,5-Trimethylbenzene ND 0.53 ND 0.11 95-63-6 1,2,4-Trimethylbenzene ND 0.53 ND 0.11 100-44-7 Benzyl Chloride ND 1.1 ND 0.21 541-73-1 1,3-Dichlorobenzene ND 0.54 ND 0.090 106-46-7 1,4-Dichlorobenzene ND 0.54 ND 0.090 95-50-1 1,2-Dichlorobenzene ND 0.54 ND 0.090 5989-27-5 d-Limonene ND 0.51 ND 0.092 96-12-8 1,2-Dibromo-3-chloropropane ND 0.52 ND 0.054 120-82-1 1,2,4-Trichlorobenzene ND 0.53 ND 0.071 91-20-3 Naphthalene ND 0.51 ND 0.097 87-68-3 Hexachlorobutadiene ND 0.53 ND 0.050


ResultppbV


Resultµg/m³


21 of 142

00915051

TO15SCAN.XLS - 75 Compounds - PageNo.:P1804830_TO15_1809291244_SC.xls - Surrogates

ALS ENVIRONMENTAL

SURROGATE SPIKE RECOVERY RESULTSPage 1 of 1

Client: Bhate Environmental Associates, Inc.ALS Project ID: P1804830

Test Code: EPA TO-15Instrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date(s) Collected: 9/11 - 9/12/18Analyst: Anusha Bayyarapu Date(s) Received: 9/17/18Sample Type: 6.0 L Summa Canister(s) Date(s) Analyzed: 9/28/18Test Notes:

Client Sample ID ALS Sample ID Acceptance DataLimits Qualifier

P180928-MB 70-130 P180928-LCS 70-130 P1804830-001 70-130 P1804830-002 70-130 P1804830-003 70-130 P1804830-004 70-130

P1804830-004DUP 70-130

Surrogate percent recovery is verified and accepted based on the on-column result.Reported results are shown in concentration units and as a result of the calculation, may vary slightly from the on-column percent recovery.

118


Toluene-d81,2-Dichloroethane-d4Percent

Recovered

9190

95

95

95116

94

116

116

96

PercentRecovered

90

Bromofluorobenzene

Recovered

88

Percent

91

11499Method Blank96Lab Control Sample 86 114

11689

Client Project ID:

LH18/24-Air_091018_Downwind

LH18/24-Air_091018_Stripper_aLH18/24-Air_091018_Stripper

LH18/24-Air_091018_GWTPLH18/24-Air_091018_Downwind

22 of 142

00915052

TO15SCAN.XLS - 75 Compounds - PageNo.:P1804830_TO15_1809291244_SC.xls - LCS

ALS ENVIRONMENTAL

LABORATORY CONTROL SAMPLE SUMMARYPage 1 of 3

Client: Bhate Environmental Associates, Inc.Lab Control Sample ALS Project ID: P1804830

ALS Sample ID: P180928-LCS


CAS # Compound Data Qualifier

115-07-1 Propene 71 54-13375-71-8 Dichlorodifluoromethane (CFC 12) 70 64-11574-87-3 Chloromethane 66 47-140

76-14-2 1,2-Dichloro-1,1,2,2-tetrafluoroethane (CFC 114) 70 60-112

75-01-4 Vinyl Chloride 67 63-127106-99-0 1,3-Butadiene 68 57-14974-83-9 Bromomethane 78 63-13275-00-3 Chloroethane 70 68-12964-17-5 Ethanol 83 62-13175-05-8 Acetonitrile 82 56-136107-02-8 Acrolein 91 60-13267-64-1 Acetone 74 63-12475-69-4 Trichlorofluoromethane (CFC 11) 80 65-11367-63-0 2-Propanol (Isopropyl Alcohol) 88 62-135107-13-1 Acrylonitrile 94 68-13875-35-4 1,1-Dichloroethene 90 72-11875-09-2 Methylene Chloride 85 67-116107-05-1 3-Chloro-1-propene (Allyl Chloride) 94 61-14376-13-1 Trichlorotrifluoroethane (CFC 113) 87 68-11375-15-0 Carbon Disulfide 87 68-120156-60-5 trans-1,2-Dichloroethene 86 71-12575-34-3 1,1-Dichloroethane 77 68-1181634-04-4 Methyl tert-Butyl Ether 85 60-123108-05-4 Vinyl Acetate 85 73-13578-93-3 2-Butanone (MEK) 84 70-129

Laboratory Control Sample percent recovery is verified and accepted based on the on-column result.Reported results are shown in concentration units and as a result of the calculation, may vary slightly.

175208

364194196

204185

218

413

217

207218

205 1861,060211

787168

150148

143214

147143

211

211

211

1,020 846169

150212210

Limitsµg/m³ µg/m³


ALSAcceptanceSpike Amount % Recovery

188190

216

210


Result

140

206

166214

216

9061,060

216214

166181

214 185

23 of 142

00915053


ALS ENVIRONMENTAL





CAS # Compound Data Qualifier

156-59-2 cis-1,2-Dichloroethene 81 69-121141-78-6 Ethyl Acetate 82 66-140110-54-3 n-Hexane 64 61-12467-66-3 Chloroform 79 69-113109-99-9 Tetrahydrofuran (THF) 86 66-121107-06-2 1,2-Dichloroethane 73 62-12071-55-6 1,1,1-Trichloroethane 90 65-11671-43-2 Benzene 84 66-11156-23-5 Carbon Tetrachloride 95 64-122110-82-7 Cyclohexane 88 69-11578-87-5 1,2-Dichloropropane 89 69-12175-27-4 Bromodichloromethane 93 69-12379-01-6 Trichloroethene 90 69-112123-91-1 1,4-Dioxane 93 74-12380-62-6 Methyl Methacrylate 96 75-125142-82-5 n-Heptane 84 68-11810061-01-5 cis-1,3-Dichloropropene 102 74-129108-10-1 4-Methyl-2-pentanone 98 66-13810061-02-6 trans-1,3-Dichloropropene 101 75-13079-00-5 1,1,2-Trichloroethane 95 73-117108-88-3 Toluene 81 66-114591-78-6 2-Hexanone 84 58-146124-48-1 Dibromochloromethane 98 67-130106-93-4 1,2-Dibromoethane 94 70-127123-86-4 n-Butyl Acetate 95 62-140


214

215

216

215213

431

Client Sample ID:

211

Client Project ID:

µg/m³Spike Amount


Result

216

209

436 357

µg/m³ Limits170

214

217

416

209

% Recovery

138

192

178

ALS

171185

Acceptance

412

218181

204

205

204

171179

212214213 208

216366

213198

215191

219

201

216

216157215

212

194215211

201

24 of 142

00915054


ALS ENVIRONMENTAL





CAS # Compound DataQualifier

111-65-9 n-Octane 81 65-121127-18-4 Tetrachloroethene 90 62-119108-90-7 Chlorobenzene 84 66-115100-41-4 Ethylbenzene 85 69-117179601-23-1 m,p-Xylenes 84 67-11775-25-2 Bromoform 106 67-135100-42-5 Styrene 98 70-12895-47-6 o-Xylene 85 67-118111-84-2 n-Nonane 84 61-12779-34-5 1,1,2,2-Tetrachloroethane 88 70-12598-82-8 Cumene 87 68-11680-56-8 alpha-Pinene 94 69-122103-65-1 n-Propylbenzene 88 70-118622-96-8 4-Ethyltoluene 94 69-124108-67-8 1,3,5-Trimethylbenzene 87 65-11795-63-6 1,2,4-Trimethylbenzene 90 67-124100-44-7 Benzyl Chloride 100 75-142541-73-1 1,3-Dichlorobenzene 96 70-124106-46-7 1,4-Dichlorobenzene 95 63-12495-50-1 1,2-Dichlorobenzene 93 66-1255989-27-5 d-Limonene 90 64-13596-12-8 1,2-Dibromo-3-chloropropane 110 73-136120-82-1 1,2,4-Trichlorobenzene 107 70-14191-20-3 Naphthalene 102 71-14687-68-3 Hexachlorobutadiene 105 63-126


208

190229

220

207205

192

215

216

230

201

217

187

426

187

194

199

226359

214201192

212

188180

216

Spike Amount

217

213

216211209214

209203

176217


AcceptanceALS

Limits% Recovery

208

211

214215

182

181181215

214

218214

213

µg/m³

212

214

Resultµg/m³

Client Project ID:Client Sample ID:

25 of 142

00915055

TO15SCAN.XLS - 75 Compounds - PageNo.:P1804830_TO15_1809291244_SC.xls - Dup (4)

ALS ENVIRONMENTAL

LABORATORY DUPLICATE SUMMARY RESULTSPage 1 of 3

Client: Bhate Environmental Associates, Inc.Client Sample ID: LH18/24-Air_091018_Downwind ALS Project ID: P1804830Client Project ID: ALS Sample ID: P1804830-004DUP



Container Dilution Factor: 1.41 DuplicateCompound Sample Result Sample Result Average % RPD RPD Data

µg/m³ ppbV µg/m³ ppbV µg/m³ Limit QualifierPropene ND ND ND ND - - 25 Dichlorodifluoromethane (CFC 12) 1.73 0.350 1.70 0.343 1.715 2 25 Chloromethane ND ND ND ND - - 25 1,2-Dichloro-1,1,2,2-tetrafluoroethane (CFC 114) ND ND ND ND - - 25 Vinyl Chloride ND ND ND ND - - 25 1,3-Butadiene ND ND ND ND - - 25 Bromomethane ND ND ND ND - - 25 Chloroethane ND ND ND ND - - 25 Ethanol ND ND ND ND - - 25 Acetonitrile ND ND ND ND - - 25 Acrolein ND ND ND ND - - 25 Acetone 10.4 4.37 10.5 4.44 10.45 1 25 M1Trichlorofluoromethane 1.06 0.188 1.03 0.184 1.045 3 25 2-Propanol (Isopropyl Alcohol) ND ND ND ND - - 25 Acrylonitrile ND ND ND ND - - 25 1,1-Dichloroethene ND ND ND ND - - 25 Methylene Chloride ND ND ND ND - - 25 3-Chloro-1-propene (Allyl Chloride) ND ND ND ND - - 25 Trichlorotrifluoroethane ND ND ND ND - - 25 Carbon Disulfide ND ND ND ND - - 25 trans-1,2-Dichloroethene ND ND ND ND - - 25 1,1-Dichloroethane ND ND ND ND - - 25 Methyl tert-Butyl Ether ND ND ND ND - - 25 Vinyl Acetate ND ND ND ND - - 25 2-Butanone (MEK) 1.57 0.533 1.52 0.515 1.545 3 25

ND = Compound was analyzed for, but not detected above the laboratory reporting limit.M1 = Matrix interference due to coelution with a non-target compound; results may be biased high.


26 of 142

00915056


ALS ENVIRONMENTAL





Container Dilution Factor: 1.41Duplicate

Compound Sample Result Sample Result Average % RPD RPD Dataµg/m³ ppbV µg/m³ ppbV µg/m³ Limit Qualifier

cis-1,2-Dichloroethene ND ND ND ND - - 25 Ethyl Acetate ND ND ND ND - - 25 n-Hexane 0.787 0.223 ND ND - - 25 Chloroform ND ND ND ND - - 25 Tetrahydrofuran (THF) ND ND ND ND - - 25 1,2-Dichloroethane ND ND ND ND - - 25 1,1,1-Trichloroethane ND ND ND ND - - 25 Benzene ND ND ND ND - - 25 Carbon Tetrachloride ND ND ND ND - - 25 Cyclohexane ND ND ND ND - - 25 1,2-Dichloropropane ND ND ND ND - - 25 Bromodichloromethane ND ND ND ND - - 25 Trichloroethene ND ND ND ND - - 25 1,4-Dioxane ND ND ND ND - - 25 Methyl Methacrylate ND ND ND ND - - 25 n-Heptane ND ND ND ND - - 25 cis-1,3-Dichloropropene ND ND ND ND - - 25 4-Methyl-2-pentanone ND ND ND ND - - 25 trans-1,3-Dichloropropene ND ND ND ND - - 25 1,1,2-Trichloroethane ND ND ND ND - - 25 Toluene ND ND ND ND - - 25 2-Hexanone ND ND ND ND - - 25 Dibromochloromethane ND ND ND ND - - 25 1,2-Dibromoethane ND ND ND ND - - 25 n-Butyl Acetate ND ND ND ND - - 25

ND = Compound was analyzed for, but not detected above the laboratory reporting limit.


27 of 142

00915057


ALS ENVIRONMENTAL





Container Dilution Factor: 1.41Duplicate

Compound Sample Result Sample Result Average % RPD RPD Dataµg/m³ ppbV µg/m³ ppbV µg/m³ Limit Qualifier

n-Octane ND ND ND ND - - 25 Tetrachloroethene ND ND ND ND - - 25 Chlorobenzene ND ND ND ND - - 25 Ethylbenzene ND ND ND ND - - 25 m,p-Xylenes ND ND ND ND - - 25 Bromoform ND ND ND ND - - 25 Styrene ND ND ND ND - - 25 o-Xylene ND ND ND ND - - 25 n-Nonane ND ND ND ND - - 25 1,1,2,2-Tetrachloroethane ND ND ND ND - - 25 Cumene ND ND ND ND - - 25 alpha-Pinene 2.04 0.367 2.01 0.361 2.025 1 25 n-Propylbenzene ND ND ND ND - - 25 4-Ethyltoluene ND ND ND ND - - 25 1,3,5-Trimethylbenzene ND ND ND ND - - 25 1,2,4-Trimethylbenzene ND ND ND ND - - 25 Benzyl Chloride ND ND ND ND - - 25 1,3-Dichlorobenzene ND ND ND ND - - 25 1,4-Dichlorobenzene ND ND ND ND - - 25 1,2-Dichlorobenzene ND ND ND ND - - 25 d-Limonene ND ND ND ND - - 25 1,2-Dibromo-3-chloropropane ND ND ND ND - - 25 1,2,4-Trichlorobenzene ND ND ND ND - - 25 Naphthalene ND ND ND ND - - 25 Hexachlorobutadiene ND ND ND ND - - 25

ND = Compound was analyzed for, but not detected above the laboratory reporting limit.


28 of 142

00915058

TO15SCAN.XLS - 75 Compounds - PageNo.:P1804830_TO15_1809291244_SC.xls - ISS

ALS ENVIRONMENTAL


Client: Bhate Environmental Associates, Inc. ALS Project ID: P1804830LHAAP-GWTP / NW01312.0150

Internal Standard Area and RT Summary

Test Code: EPA TO-15Instrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Lab File ID: 09281803.DAnalyst: Anusha Bayyarapu Date Analyzed: 9/28/18Sample Type: 6.0 L Summa Canister(s) Time Analyzed: 05:27

Test Notes:

IS1 (BCM) IS2 (DFB) IS3 (CBZ)AREA # RT # AREA # RT # AREA # RT #

24 Hour Standard 170590 11.29 681914 13.41 341722 17.72 Upper Limit 238826 11.62 954680 13.74 478411 18.05 Lower Limit 102354 10.96 409148 13.08 205033 17.39

Client Sample ID01 Method Blank 175641 11.28 771571 13.41 359884 17.7202 Lab Control Sample 184873 11.30 735550 13.41 363832 17.7203 LH18/24-Air_091018_Stripper (Dilution) 197020 11.29 828417 13.41 404556 17.7204 LH18/24-Air_091018_Stripper 188782 11.29 785539 13.41 388045 17.7205 LH18/24-Air_091018_Stripper_a 188948 11.29 794936 13.41 388480 17.7206 LH18/24-Air_091018_GWTP 188589 11.28 813019 13.41 403664 17.7207 LH18/24-Air_091018_Downwind 178631 11.29 776705 13.41 385636 17.7208 LH18/24-Air_091018_Downwind (Lab Duplicate 181911 11.28 761943 13.41 382680 17.72091011121314151617181920

IS1 (BCM) = BromochloromethaneIS2 (DFB) = 1,4-DifluorobenzeneIS3 (CBZ) = Chlorobenzene-d5

AREA UPPER LIMIT = 140% of internal standard areaAREA LOWER LIMIT = 60% of internal standard areaRT UPPER LIMIT = 0.33 minutes of internal standard RTRT LOWER LIMIT = 0.33 minutes of internal standard RT

# Column used to flag values outside QC limits with an I.I = Internal standard not within the specified limits.

Client Project ID:

29 of 142

00915059

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281820.D Acq On : 28 Sep 2018 15:58 Operator: AB Sample : P1804830-001 (10mL) Misc : S31-09081801 ALS Vial : 4 Sample Multiplier: 1 Quant Time: Sep 29 09:34:25 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.29 130 188782 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 13.41 114 785539 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 17.72 82 388045 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 264507 10.978 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 87.84% 57) Toluene-d8 (SS2) 15.86 98 899642 11.896 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.20% 73) Bromofluorobenzene (SS3) 19.09 174 330413 14.448 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 115.60% Target Compounds Qvalue 2) Propene 0.00 42 0 N.D. 3) Dichlorodifluoromethan... 4.27 85 2542 N.D. 4) Chloromethane 0.00 50 0 N.D. 5) 1,2-Dichloro-1,1,2,2-t... 0.00 135 0 N.D. 6) Vinyl Chloride 5.10 62 53440 1.840 ng 98 7) 1,3-Butadiene 0.00 54 0 N.D. 8) Bromomethane 0.00 94 0 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 6.53 45 626 N.D. 11) Acetonitrile 0.00 41 0 N.D. 12) Acrolein 0.00 56 0 N.D. 13) Acetone 7.22 58 5494 N.D. 14) Trichlorofluoromethane 7.60 101 156 N.D. 15) 2-Propanol (Isopropanol) 0.00 45 0 N.D. 16) Acrylonitrile 0.00 53 0 N.D. 17) 1,1-Dichloroethene 8.36 96 18017 1.069 ng 95 18) 2-Methyl-2-Propanol (t... 8.36 59 682 N.D. 19) Methylene Chloride 8.57 84 303429 16.124 ng 93 20) 3-Chloro-1-propene (Al... 0.00 41 0 N.D. 21) Trichlorotrifluoroethane 9.00 151 1259526 78.316 ng 97 22) Carbon Disulfide 8.86 76 10534 N.D. 23) trans-1,2-Dichloroethene 9.86 61 4512 N.D. 24) 1,1-Dichloroethane 10.10 63 6782 N.D. 25) Methyl tert-Butyl Ether 0.00 73 0 N.D. 26) Vinyl Acetate 0.00 86 0 N.D. 27) 2-Butanone (MEK) 0.00 72 0 N.D. 28) cis-1,2-Dichloroethene 11.11 61 1565012 58.998 ng 97 29) Diisopropyl Ether 11.46 87 597 N.D. 30) Ethyl Acetate 0.00 61 0 N.D. 31) n-Hexane 0.00 57 0 N.D. 32) Chloroform 11.46 83 7142 N.D. 34) Tetrahydrofuran (THF) 0.00 72 0 N.D. 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 12.26 62 27191 1.063 ng 99 38) 1,1,1-Trichloroethane 12.55 97 547 N.D. 39) Isopropyl Acetate 0.00 61 0 N.D. 40) 1-Butanol 0.00 56 0 N.D. 41) Benzene 13.03 78 3846 N.D. 42) Carbon Tetrachloride 13.18 117 817 N.D. 43) Cyclohexane 13.32 84 1983 N.D. 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 13.88 63 699 N.D. 46) Bromodichloromethane 0.00 83 0 N.D. d 47) Trichloroethene 14.11 130 2400968 122.802 ng 99 48) 1,4-Dioxane 0.00 88 0 N.D. 49) 2,2,4-Trimethylpentane... 14.18 57 237 N.D.

R8091218.M Sat Sep 29 09:42:25 2018 Page: 1

30 of 142

00915060

anusha.bayyarapu

Anusha

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281820.D Acq On : 28 Sep 2018 15:58 Operator: AB Sample : P1804830-001 (10mL) Misc : S31-09081801 ALS Vial : 4 Sample Multiplier: 1 Quant Time: Sep 29 09:34:25 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 0.00 100 0 N.D. d 51) n-Heptane 0.00 71 0 N.D. 52) cis-1,3-Dichloropropene 0.00 75 0 N.D. 53) 4-Methyl-2-pentanone 0.00 58 0 N.D. 54) trans-1,3-Dichloropropene 0.00 75 0 N.D. 55) 1,1,2-Trichloroethane 15.68 97 846 N.D. 58) Toluene 15.96 91 4492 N.D. 59) 2-Hexanone 16.17 43 808 N.D. 60) Dibromochloromethane 0.00 129 0 N.D. 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 0.00 43 0 N.D. 63) n-Octane 0.00 57 0 N.D. 64) Tetrachloroethene 17.10 166 24187 1.110 ng 100 65) Chlorobenzene 0.00 112 0 N.D. 66) Ethylbenzene 18.12 91 967 N.D. 67) m- & p-Xylenes 18.27 91 2547 N.D. 68) Bromoform 0.00 173 0 N.D. 69) Styrene 18.62 104 913 N.D. 70) o-Xylene 18.70 91 1969 N.D. 71) n-Nonane 0.00 43 0 N.D. 72) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. 74) Cumene 19.09 105 303 N.D. 75) alpha-Pinene 0.00 93 0 N.D. 76) n-Propylbenzene 0.00 91 0 N.D. 77) 3-Ethyltoluene 19.76 105 314 N.D. 78) 4-Ethyltoluene 19.76 105 314 N.D. 79) 1,3,5-Trimethylbenzene 19.86 105 110 N.D. 80) alpha-Methylstyrene 0.00 118 0 N.D. 81) 2-Ethyltoluene 20.04 105 343 N.D. 82) 1,2,4-Trimethylbenzene 20.22 105 777 N.D. 83) n-Decane 0.00 58 0 N.D. 84) Benzyl Chloride 0.00 91 0 N.D. 85) 1,3-Dichlorobenzene 0.00 146 0 N.D. 86) 1,4-Dichlorobenzene 0.00 146 0 N.D. 87) sec-Butylbenzene 20.60 105 515 N.D. 88) 4-Isopropyltoluene (p-... 20.60 119 217 N.D. 89) 1,2,3-Trimethylbenzene 20.60 105 515 N.D. 90) 1,2-Dichlorobenzene 0.00 146 0 N.D. 91) d-Limonene 0.00 68 0 N.D. 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 21.40 57 228 N.D. 94) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 95) Naphthalene 22.36 128 379 N.D. 96) n-Dodecane 22.32 57 182 N.D. 97) Hexachlorobutadiene 0.00 225 0 N.D. 98) Cyclohexanone 18.62 55 108 N.D. 99) tert-Butylbenzene 0.00 119 0 N.D. 100) n-Butylbenzene 0.00 91 0 N.D. -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Sat Sep 29 09:42:25 2018 Page: 2

31 of 142

00915061

Quantitation Report (QT Reviewed)

Data File: I:\MS08\Data\2018_09\28\09281820.D Acq On : 28 Sep 2018 15:58 Operator: AB Sample : P1804830-001 (10mL) Misc : S31-09081801 ALS Vial : 4 Sample Multiplier: 1

Quant Time: Sep 29 09:34:25 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M

4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

Time-->

Abundance TIC: 09281820.D\data.ms

Brom

oflu

orob

enze

ne (S

S3),S

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,T

Tolu

ene-

d8 (S

S2),S

Tric

hlor

oeth

ene,

T

1,4-

Difl

uoro

benz

ene

(IS2)

,IR

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),S

Brom

ochl

orom

etha

ne (I

S1),I

Rci

s-1,

2-D

ichl

oroe

then

e,T

Tric

hlor

otrif

luor

oeth

ane,

T

Met

hyle

ne C

hlor

ide,

T1,

1-D

ichl

oroe

then

e,T

Viny

l Chl

orid

e,T

R8091218.M Sat Sep 29 09:42:26 2018 Page: 3

32 of 142

00915062

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281820.D Acq On : 28 Sep 2018 15:58 Operator: AB Sample : P1804830-001 (10mL) Misc : S31-09081801 ALS Vial : 4 Sample Multiplier: 1 Quant Time: Sep 29 09:34:25 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.29 130 188782 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 13.41 114 785539 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 17.72 82 388045 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 264507 10.978 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 87.84% 57) Toluene-d8 (SS2) 15.86 98 899642 11.896 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.20% 73) Bromofluorobenzene (SS3) 19.09 174 330413 14.448 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 115.60% Target Compounds Qvalue 6) Vinyl Chloride 5.10 62 53440 1.840 ng 98 17) 1,1-Dichloroethene 8.36 96 18017 1.069 ng 95 19) Methylene Chloride 8.57 84 303429 16.124 ng 93 21) Trichlorotrifluoroethane 9.00 151 1259526 78.316 ng 97 28) cis-1,2-Dichloroethene 11.11 61 1565012 58.998 ng 97 36) 1,2-Dichloroethane 12.26 62 27191 1.063 ng 99 47) Trichloroethene 14.11 130 2400968 122.802 ng 99 64) Tetrachloroethene 17.10 166 24187 1.110 ng 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Sat Sep 29 09:40:13 2018 Page: 1

33 of 142

00915063

anusha.bayyarapu

Anusha




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

Time-->


Brom

oflu

orob

enze

ne (S

S3),S

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,T

Tolu

ene-

d8 (S

S2),S

Tric

hlor

oeth

ene,

T

1,4-

Difl

uoro

benz

ene

(IS2)

,IR

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),S

Brom

ochl

orom

etha

ne (I

S1),I

Rci

s-1,

2-D

ichl

oroe

then

e,T

Tric

hlor

otrif

luor

oeth

ane,

T

Met

hyle

ne C

hlor

ide,

T1,

1-D

ichl

oroe

then

e,T

Viny

l Chl

orid

e,T

R8091218.M Sat Sep 29 09:40:14 2018 Page: 2

34 of 142

00915064

#6Vinyl ChlorideConcen: 1.84 ng RT: 5.10 min Scan# 241Delta R.T. -0.005 minLab File: 09281820.DAcq: 28 Sep 2018 15:58

Tgt Ion: 62 Resp: 53440Ion Ratio Lower Upper 62 100 64 30.6 11.7 51.7

Ref

Raw

Sub

25 30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->

Abundance Scan 217 (4.855 min): 08021808.D\data.ms (-207) (-)62

35 47 59 6538 50

25 30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->

Abundance Scan 241 (5.097 min): 09281820.D\data.ms62

4735 594440 83

25 30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


35 47 5944 8340

5.00 5.20 5.400

5000

10000

15000

Time-->

Abundance 5.097

#171,1-DichloroetheneConcen: 1.07 ng RT: 8.36 min Scan# 848Delta R.T. -0.016 minLab File: 09281820.DAcq: 28 Sep 2018 15:58


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 827041

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47

8.25 8.30 8.35 8.40 8.450

2000

4000

6000

8000

10000

Time-->

Abundance

8.362

09281820.D R8091218.M Sat Sep 29 09:40:14 2018 Page 3

35 of 142

00915065

#19Methylene ChlorideConcen: 16.12 ng RT: 8.57 min Scan# 886Delta R.T. -0.043 minLab File: 09281820.DAcq: 28 Sep 2018 15:58


Ref

Raw

Sub

25 30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


84

35 8870

25 30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


84

8835 41 7252

25 30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


84

8835 41 7252

8.40 8.60 8.800

50000

100000

Time-->

Abundance

8.567

#21TrichlorotrifluoroethaneConcen: 78.32 ng RT: 9.00 min Scan# 966Delta R.T. -0.016 minLab File: 09281820.DAcq: 28 Sep 2018 15:58

Tgt Ion:151 Resp: 1259526Ion Ratio Lower Upper151 100101 114.8 98.2 138.2

Ref

Raw

Sub

40 60 80 100 120 140 160 1800

50

m/z-->

Abundance Scan 895 (8.714 min): 08021808.D\data.ms (-882) (-)101 151

85

6647 11635 132 167

40 60 80 100 120 140 160 1800

50

m/z-->

Abundance Scan 966 (8.997 min): 09281820.D\data.ms101 151

85

66 1164735 132 167 186

40 60 80 100 120 140 160 1800

50

m/z-->


85

66 1164735 132 167 186

8.80 8.90 9.00 9.10 9.200

100000

200000

300000

400000

500000

Time-->

Abundance

8.997

09281820.D R8091218.M Sat Sep 29 09:40:14 2018 Page 4

36 of 142

00915066

#28cis-1,2-DichloroetheneConcen: 59.00 ng RT: 11.11 min Scan# 1359Delta R.T. -0.027 minLab File: 09281820.DAcq: 28 Sep 2018 15:58


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 7041

30 40 50 60 70 80 90 1000

50

m/z-->


35 47 70 82

30 40 50 60 70 80 90 1000

50

m/z-->


35 47 70 82

11.00 11.20 11.400

200000

400000

600000

Time-->

Abundance11.111

#361,2-DichloroethaneConcen: 1.06 ng RT: 12.26 min Scan# 1573Delta R.T. -0.016 minLab File: 09281820.DAcq: 28 Sep 2018 15:58


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


49

9835 69 8341 55

30 40 50 60 70 80 90 1000

50

m/z-->


49

9835

30 40 50 60 70 80 90 1000

50

m/z-->


49

9835

12.20 12.30 12.400

2000

4000

6000

8000

10000

Time-->

Abundance12.263

09281820.D R8091218.M Sat Sep 29 09:40:14 2018 Page 5

37 of 142

00915067

#47TrichloroetheneConcen: 122.80 ng RT: 14.11 min Scan# 1917Delta R.T. -0.011 minLab File: 09281820.DAcq: 28 Sep 2018 15:58


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

35 47 8270

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

4735 8268

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

4735 8268

14.00 14.20 14.400

200000

400000

600000

800000

1000000

Time-->

Abundance14.113

#64TetrachloroetheneConcen: 1.11 ng RT: 17.10 min Scan# 2473Delta R.T. -0.005 minLab File: 09281820.DAcq: 28 Sep 2018 15:58


Ref

Raw

Sub

40 60 80 100 120 140 1600

50

m/z-->


129

9447 5935 82

11770

40 60 80 100 120 140 1600

50

m/z-->


131

94

47 59 8235

40 60 80 100 120 140 1600

50

m/z-->


131

94

47 59 8235

17.05 17.10 17.150

2000

4000

6000

8000

10000

Time-->

Abundance17.104

09281820.D R8091218.M Sat Sep 29 09:40:15 2018 Page 6

38 of 142

00915068

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281819.D Acq On : 28 Sep 2018 15:25 Operator: AB Sample : P1804830-001dil (4.0mL) Misc : S31-09081801 ALS Vial : 4 Sample Multiplier: 1 Quant Time: Sep 29 09:33:58 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.29 130 197020 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 13.41 114 828417 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 17.72 82 404556 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 277753 11.046 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 88.40% 57) Toluene-d8 (SS2) 15.86 98 943912 11.972 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.76% 73) Bromofluorobenzene (SS3) 19.09 174 345219 14.480 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 115.84% Target Compounds Qvalue 2) Propene 0.00 42 0 N.D. 3) Dichlorodifluoromethan... 4.28 85 1552 N.D. 4) Chloromethane 0.00 50 0 N.D. 5) 1,2-Dichloro-1,1,2,2-t... 0.00 135 0 N.D. 6) Vinyl Chloride 5.10 62 33958 1.120 ng 98 7) 1,3-Butadiene 0.00 54 0 N.D. 8) Bromomethane 0.00 94 0 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 6.53 45 1621 N.D. 11) Acetonitrile 0.00 41 0 N.D. 12) Acrolein 0.00 56 0 N.D. 13) Acetone 7.22 58 4952 N.D. 14) Trichlorofluoromethane 7.18 101 1508 N.D. 15) 2-Propanol (Isopropanol) 0.00 45 0 N.D. 16) Acrylonitrile 0.00 53 0 N.D. 17) 1,1-Dichloroethene 8.36 96 11091 0.630 ng 98 18) 2-Methyl-2-Propanol (t... 8.36 59 323 N.D. 19) Methylene Chloride 8.57 84 188407 9.593 ng 93 20) 3-Chloro-1-propene (Al... 0.00 41 0 N.D. 21) Trichlorotrifluoroethane 9.00 151 797710 47.527 ng 97 22) Carbon Disulfide 8.86 76 8444 N.D. 23) trans-1,2-Dichloroethene 9.85 61 2596 N.D. 24) 1,1-Dichloroethane 10.10 63 4233 N.D. 25) Methyl tert-Butyl Ether 0.00 73 0 N.D. 26) Vinyl Acetate 0.00 86 0 N.D. 27) 2-Butanone (MEK) 0.00 72 0 N.D. 28) cis-1,2-Dichloroethene 11.11 61 953765 34.452 ng 97 29) Diisopropyl Ether 11.45 87 249 N.D. 30) Ethyl Acetate 11.53 61 465 N.D. 31) n-Hexane 0.00 57 0 N.D. 32) Chloroform 11.45 83 4195 N.D. 34) Tetrahydrofuran (THF) 0.00 72 0 N.D. 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 12.26 62 15548 0.582 ng 99 38) 1,1,1-Trichloroethane 12.54 97 304 N.D. 39) Isopropyl Acetate 0.00 61 0 N.D. 40) 1-Butanol 0.00 56 0 N.D. 41) Benzene 13.03 78 2361 N.D. 42) Carbon Tetrachloride 13.19 117 368 N.D. 43) Cyclohexane 13.32 84 1305 N.D. 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 13.88 63 769 N.D. 46) Bromodichloromethane 0.00 83 0 N.D. d 47) Trichloroethene 14.11 130 1421860 68.960 ng 99 48) 1,4-Dioxane 0.00 88 0 N.D. 49) 2,2,4-Trimethylpentane... 0.00 57 0 N.D.

R8091218.M Sat Sep 29 09:42:23 2018 Page: 1

39 of 142

00915069

anusha.bayyarapu

Anusha

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281819.D Acq On : 28 Sep 2018 15:25 Operator: AB Sample : P1804830-001dil (4.0mL) Misc : S31-09081801 ALS Vial : 4 Sample Multiplier: 1 Quant Time: Sep 29 09:33:58 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.11 100 3113 N.D. 51) n-Heptane 0.00 71 0 N.D. 52) cis-1,3-Dichloropropene 0.00 75 0 N.D. 53) 4-Methyl-2-pentanone 0.00 58 0 N.D. 54) trans-1,3-Dichloropropene 0.00 75 0 N.D. 55) 1,1,2-Trichloroethane 15.68 97 232 N.D. 58) Toluene 15.96 91 2591 N.D. 59) 2-Hexanone 16.17 43 702 N.D. 60) Dibromochloromethane 0.00 129 0 N.D. 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 0.00 43 0 N.D. 63) n-Octane 0.00 57 0 N.D. 64) Tetrachloroethene 17.10 166 12491 0.550 ng 100 65) Chlorobenzene 0.00 112 0 N.D. 66) Ethylbenzene 18.13 91 449 N.D. 67) m- & p-Xylenes 18.28 91 1325 N.D. 68) Bromoform 0.00 173 0 N.D. 69) Styrene 18.62 104 157 N.D. 70) o-Xylene 18.70 91 961 N.D. 71) n-Nonane 0.00 43 0 N.D. 72) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. 74) Cumene 19.09 105 393 N.D. 75) alpha-Pinene 0.00 93 0 N.D. 76) n-Propylbenzene 0.00 91 0 N.D. 77) 3-Ethyltoluene 19.76 105 106 N.D. 78) 4-Ethyltoluene 19.76 105 106 N.D. 79) 1,3,5-Trimethylbenzene 19.76 105 106 N.D. 80) alpha-Methylstyrene 0.00 118 0 N.D. 81) 2-Ethyltoluene 20.24 105 469 N.D. 82) 1,2,4-Trimethylbenzene 20.24 105 469 N.D. 83) n-Decane 0.00 58 0 N.D. 84) Benzyl Chloride 0.00 91 0 N.D. 85) 1,3-Dichlorobenzene 0.00 146 0 N.D. 86) 1,4-Dichlorobenzene 0.00 146 0 N.D. 87) sec-Butylbenzene 20.60 105 300 N.D. 88) 4-Isopropyltoluene (p-... 20.61 119 236 N.D. 89) 1,2,3-Trimethylbenzene 20.60 105 300 N.D. 90) 1,2-Dichlorobenzene 0.00 146 0 N.D. 91) d-Limonene 0.00 68 0 N.D. 92) 1,2-Dibromo-3-Chloropr... 21.11 157 589 N.D. 93) n-Undecane 21.40 57 381 N.D. 94) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 95) Naphthalene 0.00 128 0 N.D. 96) n-Dodecane 22.32 57 130 N.D. 97) Hexachlorobutadiene 0.00 225 0 N.D. 98) Cyclohexanone 18.63 55 158 N.D. 99) tert-Butylbenzene 0.00 119 0 N.D. 100) n-Butylbenzene 0.00 91 0 N.D. -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Sat Sep 29 09:42:23 2018 Page: 2

40 of 142

00915070


Data File: I:\MS08\Data\2018_09\28\09281819.D Acq On : 28 Sep 2018 15:25 Operator: AB Sample : P1804830-001dil (4.0mL) Misc : S31-09081801 ALS Vial : 4 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

200000

400000

600000

800000

1000000

1200000

1400000

1600000

1800000

2000000

2200000

2400000

2600000

2800000

3000000

3200000

3400000

3600000

3800000

4000000

Time-->


Brom

oflu

orob

enze

ne (S

S3),S

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,T

Tolu

ene-

d8 (S

S2),S

Tric

hlor

oeth

ene,

T

1,4-

Difl

uoro

benz

ene

(IS2)

,IR

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),S

Brom

ochl

orom

etha

ne (I

S1),I

Rci

s-1,

2-D

ichl

oroe

then

e,T

Tric

hlor

otrif

luor

oeth

ane,

T

Met

hyle

ne C

hlor

ide,

T1,

1-D

ichl

oroe

then

e,T

Viny

l Chl

orid

e,T

R8091218.M Sat Sep 29 09:42:23 2018 Page: 3

41 of 142

00915071

Quantitation Report (Qedit)

Data File: I:\MS08\Data\2018_09\28\09281819.D Acq On : 28 Sep 2018 15:25 Operator: AB Sample : P1804830-001dil (4.0mL) Misc : S31-09081801 ALS Vial : 4 Sample Multiplier: 1


13.10 13.20 13.30 13.40 13.50 13.60 13.70 13.80 13.90 14.00 14.10 14.20 14.30 14.40 14.50 14.60 14.70 14.80 14.90 15.00 15.10 15.20

0

200000

400000

600000

800000

1000000

Time-->

Abundance Ion 129.90 (129.60 to 130.60): 09281819.D\data.ms

14.113|

|

|

|

|

| |||||

|

Ion 131.90 (131.60 to 132.60): 09281819.D\data.ms

25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145

200000

400000

600000

m/z-->


60 134

994735 826550 8570 1377440

25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145

5000

m/z-->


6013488

35 47 9943 826550 7038 55

TIC: 09281819.D\data.ms

0.00 0.00 0.00

0.00 0.00 0.00

131.90 95.20 96.57

129.90 100 100

Ion Exp% Act%

response 1421860

14.113min (-0.011) 68.96ng

(47) Trichloroethene (T)

R8091218.M Sat Sep 29 09:34:08 2018 Page: 1

42 of 142

00915072

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281821.D Acq On : 28 Sep 2018 16:31 Operator: AB Sample : P1804830-002 (6.0mL) Misc : S31-09081801 ALS Vial : 4 Sample Multiplier: 1 Quant Time: Sep 29 09:34:43 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.29 130 188948 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 13.41 114 794936 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 17.72 82 388480 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 266863 11.066 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 88.56% 57) Toluene-d8 (SS2) 15.86 98 906853 11.978 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.84% 73) Bromofluorobenzene (SS3) 19.09 174 331976 14.501 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 116.00% Target Compounds Qvalue 2) Propene 0.00 42 0 N.D. 3) Dichlorodifluoromethan... 4.28 85 1668 N.D. 4) Chloromethane 0.00 50 0 N.D. 5) 1,2-Dichloro-1,1,2,2-t... 0.00 135 0 N.D. 6) Vinyl Chloride 5.10 62 41238 1.419 ng 99 7) 1,3-Butadiene 0.00 54 0 N.D. 8) Bromomethane 0.00 94 0 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 6.54 45 166 N.D. 11) Acetonitrile 0.00 41 0 N.D. 12) Acrolein 0.00 56 0 N.D. 13) Acetone 7.22 58 4897 N.D. 14) Trichlorofluoromethane 7.17 101 1494 N.D. 15) 2-Propanol (Isopropanol) 0.00 45 0 N.D. 16) Acrylonitrile 0.00 53 0 N.D. 17) 1,1-Dichloroethene 8.36 96 11380 0.674 ng 95 18) 2-Methyl-2-Propanol (t... 8.37 59 332 N.D. 19) Methylene Chloride 8.57 84 197126 10.466 ng 93 20) 3-Chloro-1-propene (Al... 0.00 41 0 N.D. 21) Trichlorotrifluoroethane 9.00 151 811061 50.386 ng 97 22) Carbon Disulfide 8.86 76 5172 N.D. 23) trans-1,2-Dichloroethene 9.85 61 2736 N.D. 24) 1,1-Dichloroethane 10.10 63 4350 N.D. 25) Methyl tert-Butyl Ether 0.00 73 0 N.D. 26) Vinyl Acetate 0.00 86 0 N.D. 27) 2-Butanone (MEK) 0.00 72 0 N.D. 28) cis-1,2-Dichloroethene 11.11 61 1027705 38.708 ng 98 29) Diisopropyl Ether 11.46 87 263 N.D. 30) Ethyl Acetate 0.00 61 0 N.D. 31) n-Hexane 0.00 57 0 N.D. 32) Chloroform 11.46 83 4467 N.D. 34) Tetrahydrofuran (THF) 0.00 72 0 N.D. 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 12.26 62 17320 0.677 ng 99 38) 1,1,1-Trichloroethane 12.54 97 337 N.D. 39) Isopropyl Acetate 0.00 61 0 N.D. 40) 1-Butanol 0.00 56 0 N.D. 41) Benzene 13.03 78 2304 N.D. 42) Carbon Tetrachloride 13.18 117 429 N.D. 43) Cyclohexane 13.32 84 1234 N.D. 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 13.88 63 360 N.D. 46) Bromodichloromethane 0.00 83 0 N.D. d 47) Trichloroethene 14.11 130 1601206 80.928 ng 99 48) 1,4-Dioxane 0.00 88 0 N.D. 49) 2,2,4-Trimethylpentane... 0.00 57 0 N.D.

R8091218.M Sat Sep 29 09:42:28 2018 Page: 1

43 of 142

00915073

anusha.bayyarapu

Anusha

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281821.D Acq On : 28 Sep 2018 16:31 Operator: AB Sample : P1804830-002 (6.0mL) Misc : S31-09081801 ALS Vial : 4 Sample Multiplier: 1 Quant Time: Sep 29 09:34:43 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 0.00 100 0 N.D. d 51) n-Heptane 0.00 71 0 N.D. 52) cis-1,3-Dichloropropene 0.00 75 0 N.D. 53) 4-Methyl-2-pentanone 0.00 58 0 N.D. 54) trans-1,3-Dichloropropene 0.00 75 0 N.D. 55) 1,1,2-Trichloroethane 15.68 97 342 N.D. 58) Toluene 15.97 91 2810 N.D. 59) 2-Hexanone 16.17 43 471 N.D. 60) Dibromochloromethane 0.00 129 0 N.D. 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 0.00 43 0 N.D. 63) n-Octane 0.00 57 0 N.D. 64) Tetrachloroethene 17.10 166 15212 0.697 ng 100 65) Chlorobenzene 0.00 112 0 N.D. 66) Ethylbenzene 18.12 91 564 N.D. 67) m- & p-Xylenes 18.28 91 1425 N.D. 68) Bromoform 0.00 173 0 N.D. 69) Styrene 18.62 104 267 N.D. 70) o-Xylene 18.71 91 1053 N.D. 71) n-Nonane 0.00 43 0 N.D. 72) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. 74) Cumene 19.09 105 275 N.D. 75) alpha-Pinene 0.00 93 0 N.D. 76) n-Propylbenzene 0.00 91 0 N.D. 77) 3-Ethyltoluene 0.00 105 0 N.D. 78) 4-Ethyltoluene 0.00 105 0 N.D. 79) 1,3,5-Trimethylbenzene 20.04 105 104 N.D. 80) alpha-Methylstyrene 0.00 118 0 N.D. 81) 2-Ethyltoluene 20.04 105 104 N.D. 82) 1,2,4-Trimethylbenzene 20.23 105 389 N.D. 83) n-Decane 0.00 58 0 N.D. 84) Benzyl Chloride 0.00 91 0 N.D. 85) 1,3-Dichlorobenzene 0.00 146 0 N.D. 86) 1,4-Dichlorobenzene 0.00 146 0 N.D. 87) sec-Butylbenzene 20.61 105 174 N.D. 88) 4-Isopropyltoluene (p-... 20.61 119 164 N.D. 89) 1,2,3-Trimethylbenzene 20.61 105 174 N.D. 90) 1,2-Dichlorobenzene 0.00 146 0 N.D. 91) d-Limonene 0.00 68 0 N.D. 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 0.00 57 0 N.D. 94) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 95) Naphthalene 0.00 128 0 N.D. 96) n-Dodecane 0.00 57 0 N.D. 97) Hexachlorobutadiene 0.00 225 0 N.D. 98) Cyclohexanone 0.00 55 0 N.D. 99) tert-Butylbenzene 0.00 119 0 N.D. 100) n-Butylbenzene 0.00 91 0 N.D. -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Sat Sep 29 09:42:28 2018 Page: 2

44 of 142

00915074


Data File: I:\MS08\Data\2018_09\28\09281821.D Acq On : 28 Sep 2018 16:31 Operator: AB Sample : P1804830-002 (6.0mL) Misc : S31-09081801 ALS Vial : 4 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

200000

400000

600000

800000

1000000

1200000

1400000

1600000

1800000

2000000

2200000

2400000

2600000

2800000

3000000

3200000

3400000

3600000

3800000

4000000

4200000

4400000

Time-->


Brom

oflu

orob

enze

ne (S

S3),S

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,T

Tolu

ene-

d8 (S

S2),S

Tric

hlor

oeth

ene,

T

1,4-

Difl

uoro

benz

ene

(IS2)

,IR

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),S

Brom

ochl

orom

etha

ne (I

S1),I

Rci

s-1,

2-D

ichl

oroe

then

e,T

Tric

hlor

otrif

luor

oeth

ane,

T

Met

hyle

ne C

hlor

ide,

T1,

1-D

ichl

oroe

then

e,T

Viny

l Chl

orid

e,T

R8091218.M Sat Sep 29 09:42:28 2018 Page: 3

45 of 142

00915075

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281821.D Acq On : 28 Sep 2018 16:31 Operator: AB Sample : P1804830-002 (6.0mL) Misc : S31-09081801 ALS Vial : 4 Sample Multiplier: 1 Quant Time: Sep 29 09:34:43 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.29 130 188948 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 13.41 114 794936 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 17.72 82 388480 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 266863 11.066 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 88.56% 57) Toluene-d8 (SS2) 15.86 98 906853 11.978 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.84% 73) Bromofluorobenzene (SS3) 19.09 174 331976 14.501 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 116.00% Target Compounds Qvalue 6) Vinyl Chloride 5.10 62 41238 1.419 ng 99 17) 1,1-Dichloroethene 8.36 96 11380 0.674 ng 95 19) Methylene Chloride 8.57 84 197126 10.466 ng 93 21) Trichlorotrifluoroethane 9.00 151 811061 50.386 ng 97 28) cis-1,2-Dichloroethene 11.11 61 1027705 38.708 ng 98 36) 1,2-Dichloroethane 12.26 62 17320 0.677 ng 99 47) Trichloroethene 14.11 130 1601206 80.928 ng 99 64) Tetrachloroethene 17.10 166 15212 0.697 ng 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Sat Sep 29 09:40:16 2018 Page: 1

46 of 142

00915076

anusha.bayyarapu

Anusha


Data File: I:\MS08\Data\2018_09\28\09281821.D Acq On : 28 Sep 2018 16:31 Operator: AB Sample : P1804830-002 (6.0mL) Misc : S31-09081801 ALS Vial : 4 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

200000

400000

600000

800000

1000000

1200000

1400000

1600000

1800000

2000000

2200000

2400000

2600000

2800000

3000000

3200000

3400000

3600000

3800000

4000000

4200000

4400000

Time-->


Brom

oflu

orob

enze

ne (S

S3),S

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,T

Tolu

ene-

d8 (S

S2),S

Tric

hlor

oeth

ene,

T

1,4-

Difl

uoro

benz

ene

(IS2)

,IR

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),S

Brom

ochl

orom

etha

ne (I

S1),I

Rci

s-1,

2-D

ichl

oroe

then

e,T

Tric

hlor

otrif

luor

oeth

ane,

T

Met

hyle

ne C

hlor

ide,

T1,

1-D

ichl

oroe

then

e,T

Viny

l Chl

orid

e,T

R8091218.M Sat Sep 29 09:40:17 2018 Page: 2

47 of 142

00915077

#6Vinyl ChlorideConcen: 1.42 ng RT: 5.10 min Scan# 242Delta R.T. 0.000 minLab File: 09281821.DAcq: 28 Sep 2018 16:31


Ref

Raw

Sub

25 30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


35 47 59 6538 50

25 30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


4735 40 5944 83

25 30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


35 47 5944 8340

5.00 5.10 5.20 5.30 5.400

5000

10000

Time-->

Abundance 5.102

#171,1-DichloroetheneConcen: 0.67 ng RT: 8.36 min Scan# 848Delta R.T. -0.016 minLab File: 09281821.DAcq: 28 Sep 2018 16:31


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 827041

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47

8.30 8.35 8.40 8.450

2000

4000

6000

Time-->

Abundance

8.362

09281821.D R8091218.M Sat Sep 29 09:40:17 2018 Page 3

48 of 142

00915078



Ref

Raw

Sub

25 30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


84

35 8852 70

25 30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


84

8835 41 7252

25 30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


84

8835 41 7252

8.40 8.60 8.800

20000

40000

60000

80000

Time-->

Abundance

8.567



Ref

Raw

Sub

40 60 80 100 120 140 160 1800

50

m/z-->


85

6647 11635 132 167

40 60 80 100 120 140 160 1800

50

m/z-->


85

66 1164735 132 169 186

40 60 80 100 120 140 160 1800

50

m/z-->


85

66 1164735 132 169 186

8.90 9.00 9.10 9.200

100000

200000

300000

Time-->

Abundance

8.997

09281821.D R8091218.M Sat Sep 29 09:40:17 2018 Page 4

49 of 142

00915079



Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 7041

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 70 82

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 70 82

11.00 11.20 11.400

100000

200000

300000

400000

Time-->

Abundance11.106

#361,2-DichloroethaneConcen: 0.68 ng RT: 12.26 min Scan# 1573Delta R.T. -0.016 minLab File: 09281821.DAcq: 28 Sep 2018 16:31


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


49

9835 69 8341 55

30 40 50 60 70 80 90 1000

50

m/z-->


49

9835

30 40 50 60 70 80 90 1000

50

m/z-->


49

9835

12.20 12.300

2000

4000

6000

Time-->

Abundance12.263

09281821.D R8091218.M Sat Sep 29 09:40:18 2018 Page 5

50 of 142

00915080



Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

35 47 8270

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

4735 8268

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

4735 8268

14.00 14.20 14.400

200000

400000

600000

Time-->

Abundance14.113

#64TetrachloroetheneConcen: 0.70 ng RT: 17.10 min Scan# 2473Delta R.T. -0.005 minLab File: 09281821.DAcq: 28 Sep 2018 16:31


Ref

Raw

Sub

40 60 80 100 120 140 1600

50

m/z-->


129

9447 5935 82

11770

40 60 80 100 120 140 1600

50

m/z-->


131

9447 59 8235

40 60 80 100 120 140 1600

50

m/z-->


131

9447 59 8235

17.05 17.10 17.150

2000

4000

6000

Time-->

Abundance17.104

09281821.D R8091218.M Sat Sep 29 09:40:18 2018 Page 6

51 of 142

00915081

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281822.D Acq On : 28 Sep 2018 17:26 Operator: AB Sample : P1804830-003 (1000mL) Misc : S31-09081801 ALS Vial : 2 Sample Multiplier: 1 Quant Time: Sep 29 09:35:07 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.28 130 188589 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 13.41 114 813019 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 17.72 82 403664 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 272555 11.323 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 90.56% 57) Toluene-d8 (SS2) 15.86 98 930390 11.826 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 94.64% 73) Bromofluorobenzene (SS3) 19.09 174 345099 14.507 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 116.08% Target Compounds Qvalue 2) Propene 4.25 42 8551 N.D. 3) Dichlorodifluoromethan... 4.38 85 49157 1.336 ng 100 4) Chloromethane 4.66 50 4724 N.D. 5) 1,2-Dichloro-1,1,2,2-t... 4.93 135 1015 N.D. 6) Vinyl Chloride 5.08 62 10216 N.D. 7) 1,3-Butadiene 0.00 54 0 N.D. 8) Bromomethane 5.80 94 275 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 6.48 45 33013 2.191 ng 98 11) Acetonitrile 6.76 41 8123 N.D. 12) Acrolein 6.96 56 6632 0.527 ng 97 13) Acetone 7.17 58 82882 4.818 ng # 76 14) Trichlorofluoromethane 7.39 101 24249 0.831 ng 100 15) 2-Propanol (Isopropanol) 7.67 45 24311 0.470 ng 89 16) Acrylonitrile 7.98 53 734 N.D. 17) 1,1-Dichloroethene 8.36 96 3525 N.D. 18) 2-Methyl-2-Propanol (t... 8.58 59 5315 N.D. 19) Methylene Chloride 8.57 84 37374 1.988 ng 93 20) 3-Chloro-1-propene (Al... 8.57 41 1237 N.D. 21) Trichlorotrifluoroethane 8.99 151 393417 24.487 ng 97 22) Carbon Disulfide 8.84 76 13063 N.D. 23) trans-1,2-Dichloroethene 9.84 61 509 N.D. 24) 1,1-Dichloroethane 10.11 63 688 N.D. 25) Methyl tert-Butyl Ether 10.24 73 315 N.D. 26) Vinyl Acetate 10.34 86 10970 2.201 ng # 44 27) 2-Butanone (MEK) 10.62 72 16869 1.224 ng 96 28) cis-1,2-Dichloroethene 11.11 61 141880 5.354 ng 99 29) Diisopropyl Ether 0.00 87 0 N.D. 30) Ethyl Acetate 11.44 61 1524 N.D. 31) n-Hexane 11.40 57 19316 0.587 ng 98 32) Chloroform 11.46 83 2230 N.D. 34) Tetrahydrofuran (THF) 11.91 72 2798 N.D. 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 12.26 62 2208 N.D. 38) 1,1,1-Trichloroethane 0.00 97 0 N.D. 39) Isopropyl Acetate 0.00 61 0 N.D. 40) 1-Butanol 0.00 56 0 N.D. d 41) Benzene 13.02 78 32596 N.D. 42) Carbon Tetrachloride 13.18 117 4986 N.D. 43) Cyclohexane 13.31 84 8956 N.D. 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 13.87 63 1040 N.D. 46) Bromodichloromethane 14.11 83 3323 N.D. 47) Trichloroethene 14.11 130 289732 14.318 ng 98 48) 1,4-Dioxane 0.00 88 0 N.D. 49) 2,2,4-Trimethylpentane... 14.18 57 5957 N.D.

R8091218.M Sat Sep 29 09:42:30 2018 Page: 1

52 of 142

00915082

anusha.bayyarapu

Anusha

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281822.D Acq On : 28 Sep 2018 17:26 Operator: AB Sample : P1804830-003 (1000mL) Misc : S31-09081801 ALS Vial : 2 Sample Multiplier: 1 Quant Time: Sep 29 09:35:07 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.45 100 1577 N.D. 51) n-Heptane 14.44 71 4939 N.D. 52) cis-1,3-Dichloropropene 0.00 75 0 N.D. 53) 4-Methyl-2-pentanone 15.02 58 1673 N.D. 54) trans-1,3-Dichloropropene 0.00 75 0 N.D. 55) 1,1,2-Trichloroethane 0.00 97 0 N.D. 58) Toluene 15.96 91 32740 N.D. 59) 2-Hexanone 16.21 43 9688 N.D. 60) Dibromochloromethane 0.00 129 0 N.D. 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 16.84 43 3087 N.D. 63) n-Octane 16.96 57 1784 N.D. 64) Tetrachloroethene 17.11 166 3461 N.D. 65) Chlorobenzene 17.76 112 751 N.D. 66) Ethylbenzene 18.11 91 5684 N.D. 67) m- & p-Xylenes 18.27 91 12666 N.D. 68) Bromoform 0.00 173 0 N.D. 69) Styrene 18.60 104 2429 N.D. 70) o-Xylene 18.70 91 5462 N.D. 71) n-Nonane 18.88 43 3076 N.D. 72) 1,1,2,2-Tetrachloroethane 18.70 83 322 N.D. 74) Cumene 19.22 105 652 N.D. 75) alpha-Pinene 19.57 93 25677 0.551 ng 99 76) n-Propylbenzene 19.67 91 1846 N.D. 77) 3-Ethyltoluene 19.76 105 3289 N.D. 78) 4-Ethyltoluene 19.79 105 1693 N.D. 79) 1,3,5-Trimethylbenzene 19.86 105 1180 N.D. 80) alpha-Methylstyrene 20.00 118 260 N.D. 81) 2-Ethyltoluene 20.03 105 1456 N.D. 82) 1,2,4-Trimethylbenzene 20.22 105 4513 N.D. 83) n-Decane 20.31 58 178 N.D. 84) Benzyl Chloride 20.35 91 523 N.D. 85) 1,3-Dichlorobenzene 20.42 146 668 N.D. 86) 1,4-Dichlorobenzene 20.42 146 668 N.D. 87) sec-Butylbenzene 20.47 105 608 N.D. 88) 4-Isopropyltoluene (p-... 20.60 119 2417 N.D. 89) 1,2,3-Trimethylbenzene 20.59 105 1698 N.D. 90) 1,2-Dichlorobenzene 0.00 146 0 N.D. 91) d-Limonene 20.72 68 4442 N.D. 92) 1,2-Dibromo-3-Chloropr... 21.10 157 1784 N.D. 93) n-Undecane 21.40 57 2964 N.D. 94) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 95) Naphthalene 22.34 128 11198 N.D. 96) n-Dodecane 22.32 57 5254 N.D. 97) Hexachlorobutadiene 0.00 225 0 N.D. 98) Cyclohexanone 18.41 55 6980 N.D. 99) tert-Butylbenzene 20.22 119 765 N.D. 100) n-Butylbenzene 20.96 91 1981 N.D. -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Sat Sep 29 09:42:30 2018 Page: 2

53 of 142

00915083




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

100000

200000

300000

400000

500000

600000

700000

800000

900000

1000000

1100000

1200000

1300000

1400000

1500000

1600000

1700000

1800000

1900000

2000000

2100000

2200000

2300000

2400000

2500000

2600000

2700000

2800000

2900000

3000000

Time-->


alph

a-Pi

nene

,T

Brom

oflu

orob

enze

ne (S

S3),S

Chl

orob

enze

ne-d

5 (IS

3),IR

Tolu

ene-

d8 (S

S2),S

Tric

hlor

oeth

ene,

T

1,4-

Difl

uoro

benz

ene

(IS2)

,IR

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

n-H

exan

e,T

Brom

ochl

orom

etha

ne (I

S1),I

Rci

s-1,

2-D

ichl

oroe

then

e,T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,T

Tric

hlor

otrif

luor

oeth

ane,

T

Met

hyle

ne C

hlor

ide,

T

2-Pr

opan

ol (I

sopr

opan

ol),T

Tric

hlor

oflu

orom

etha

ne,T

Acet

one,

TAc

role

in,T

Etha

nol,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,T

R8091218.M Sat Sep 29 09:42:30 2018 Page: 3

54 of 142

00915084

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281822.D Acq On : 28 Sep 2018 17:26 Operator: AB Sample : P1804830-003 (1000mL) Misc : S31-09081801 ALS Vial : 2 Sample Multiplier: 1 Quant Time: Sep 29 09:35:07 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.28 130 188589 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 13.41 114 813019 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 17.72 82 403664 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 272555 11.323 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 90.56% 57) Toluene-d8 (SS2) 15.86 98 930390 11.826 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 94.64% 73) Bromofluorobenzene (SS3) 19.09 174 345099 14.507 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 116.08% Target Compounds Qvalue 3) Dichlorodifluoromethan... 4.38 85 49157 1.336 ng 100 10) Ethanol 6.48 45 33013 2.191 ng 98 12) Acrolein 6.96 56 6632 0.527 ng 97 13) Acetone 7.17 58 82882 4.818 ng # 76 14) Trichlorofluoromethane 7.39 101 24249 0.831 ng 100 15) 2-Propanol (Isopropanol) 7.67 45 24311 0.470 ng 89 19) Methylene Chloride 8.57 84 37374 1.988 ng 93 21) Trichlorotrifluoroethane 8.99 151 393417 24.487 ng 97 26) Vinyl Acetate 10.34 86 10970 2.201 ng # 44 27) 2-Butanone (MEK) 10.62 72 16869 1.224 ng 96 28) cis-1,2-Dichloroethene 11.11 61 141880 5.354 ng 99 31) n-Hexane 11.40 57 19316 0.587 ng 98 47) Trichloroethene 14.11 130 289732 14.318 ng 98 75) alpha-Pinene 19.57 93 25677 0.551 ng 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Sat Sep 29 09:40:19 2018 Page: 1

55 of 142

00915085

anusha.bayyarapu

Anusha




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

100000

200000

300000

400000

500000

600000

700000

800000

900000

1000000

1100000

1200000

1300000

1400000

1500000

1600000

1700000

1800000

1900000

2000000

2100000

2200000

2300000

2400000

2500000

2600000

2700000

2800000

2900000

3000000

Time-->


alph

a-Pi

nene

,T

Brom

oflu

orob

enze

ne (S

S3),S

Chl

orob

enze

ne-d

5 (IS

3),IR

Tolu

ene-

d8 (S

S2),S

Tric

hlor

oeth

ene,

T

1,4-

Difl

uoro

benz

ene

(IS2)

,IR

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

n-H

exan

e,T

Brom

ochl

orom

etha

ne (I

S1),I

Rci

s-1,

2-D

ichl

oroe

then

e,T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,T

Tric

hlor

otrif

luor

oeth

ane,

T

Met

hyle

ne C

hlor

ide,

T

2-Pr

opan

ol (I

sopr

opan

ol),T

Tric

hlor

oflu

orom

etha

ne,T

Acet

one,

TAc

role

in,T

Etha

nol,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,T

R8091218.M Sat Sep 29 09:40:20 2018 Page: 2

56 of 142

00915086

#3Dichlorodifluoromethane (CFC 12)Concen: 1.34 ng RT: 4.38 min Scan# 109Delta R.T. -0.000 minLab File: 09281822.DAcq: 28 Sep 2018 17:26

Tgt Ion: 85 Resp: 49157Ion Ratio Lower Upper 85 100 87 32.2 12.4 52.4 101 8.9 0.0 29.1 103 5.8 0.0 25.9

Ref

Raw

Sub

20 30 40 50 60 70 80 90 100 110 1200

50

m/z-->


50 10135 66 12242

20 30 40 50 60 70 80 90 100 110 1200

50

m/z-->


50 10131 6640

20 30 40 50 60 70 80 90 100 110 1200

50

m/z-->


50 10135 66

4.30 4.35 4.40 4.450

10000

20000

Time-->

Abundance 4.378

#10EthanolConcen: 2.19 ng RT: 6.48 min Scan# 499Delta R.T. -0.108 minLab File: 09281822.DAcq: 28 Sep 2018 17:26


Ref

Raw

Sub

32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


43

41 47

32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4340

32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4341

6.40 6.50 6.60 6.700

2000

4000

6000

8000

10000

Time-->

Abundance 6.485

09281822.D R8091218.M Sat Sep 29 09:40:20 2018 Page 3

57 of 142

00915087

#12AcroleinConcen: 0.53 ng RT: 6.96 min Scan# 587Delta R.T. -0.022 minLab File: 09281822.DAcq: 28 Sep 2018 17:26


Ref

Raw

Sub

30 35 40 45 50 55 60 650

50

m/z-->


37 5339 42 58

30 35 40 45 50 55 60 650

50

m/z-->


5840 4438 42 53

30 35 40 45 50 55 60 650

50

m/z-->


38 53

6.90 7.00 7.100

500

1000

1500

2000

Time-->

Abundance 6.958

#13AcetoneConcen: 4.82 ng RT: 7.17 min Scan# 626Delta R.T. -0.038 minLab File: 09281822.DAcq: 28 Sep 2018 17:26

Tgt Ion: 58 Resp: 82882Ion Ratio Lower Upper 58 100 43 360.2 282.4 342.4#

Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 140 150 1600

50

m/z-->


58

30 40 50 60 70 80 90 100 110 120 130 140 150 1600

50

m/z-->


5867 11785 15298 133

30 40 50 60 70 80 90 100 110 120 130 140 150 1600

50

m/z-->


5867 11785 15213398

7.05 7.10 7.15 7.20 7.250

20000

40000

60000

80000

100000

Time-->

Abundance

7.168

09281822.D R8091218.M Sat Sep 29 09:40:21 2018 Page 4

58 of 142

00915088

#14TrichlorofluoromethaneConcen: 0.83 ng RT: 7.39 min Scan# 667Delta R.T. -0.027 minLab File: 09281822.DAcq: 28 Sep 2018 17:26


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


6635 47 82 117

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


664735 58 82 117

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


664735 84

7.30 7.35 7.40 7.450

2000

4000

6000

8000

Time-->

Abundance 7.389

#152-Propanol (Isopropanol)Concen: 0.47 ng RT: 7.67 min Scan# 720Delta R.T. -0.038 minLab File: 09281822.DAcq: 28 Sep 2018 17:26


Ref

Raw

Sub

25 30 35 40 45 50 55 60 65 70 750

50

m/z-->


4233 48

25 30 35 40 45 50 55 60 65 70 750

50

m/z-->


39 6842 59

25 30 35 40 45 50 55 60 65 70 750

50

m/z-->


39 6842 59

7.60 7.70 7.80 7.900

5000

10000

15000

20000

Time-->

Abundance

7.674

09281822.D R8091218.M Sat Sep 29 09:40:21 2018 Page 5

59 of 142

00915089



Ref

Raw

Sub

25 30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


84

35 8852 70

25 30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


35 8841 5944

25 30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


35 8841 5944

8.50 8.60 8.700

5000

10000

15000

Time-->

Abundance

8.572



Ref

Raw

Sub

40 60 80 100 120 140 160 1800

50

m/z-->


85

6647 11635 132 167

40 60 80 100 120 140 160 1800

50

m/z-->


85

66 1164735 132 167 186

40 60 80 100 120 140 160 1800

50

m/z-->


85

66 1164735 132 167 186

8.90 9.00 9.100

50000

100000

150000

Time-->

Abundance

8.992

09281822.D R8091218.M Sat Sep 29 09:40:21 2018 Page 6

60 of 142

00915090

#26Vinyl AcetateConcen: 2.20 ng RT: 10.34 min Scan# 1216Delta R.T. -0.048 minLab File: 09281822.DAcq: 28 Sep 2018 17:26


Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


8659 7140 4637 55

30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


867139 5750 75 7953

30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


71 865739 50 7553

10.30 10.400

10000

20000

Time-->

Abundance

10.342

#272-Butanone (MEK)Concen: 1.22 ng RT: 10.62 min Scan# 1267Delta R.T. -0.011 minLab File: 09281822.DAcq: 28 Sep 2018 17:26


Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72575349

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


725739 50 53

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72

5739 50 53

10.60 10.700

5000

10000

15000

20000

25000

Time-->

Abundance

10.616

09281822.D R8091218.M Sat Sep 29 09:40:21 2018 Page 7

61 of 142

00915091



Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 7041

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 7041

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 70

11.00 11.200

20000

40000

Time-->

Abundance11.106

#31n-HexaneConcen: 0.59 ng RT: 11.40 min Scan# 1412Delta R.T. -0.016 minLab File: 09281822.DAcq: 28 Sep 2018 17:26

Tgt Ion: 57 Resp: 19316Ion Ratio Lower Upper 57 100 56 50.4 39.0 58.4 86 17.4 13.8 20.8

Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


57

8771 10236

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


41

8671 13149

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


41

8671 13149

11.30 11.35 11.40 11.450

2000

4000

6000

8000

Time-->

Abundance11.396

09281822.D R8091218.M Sat Sep 29 09:40:22 2018 Page 8

62 of 142

00915092



Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

35 47 8270

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

4735 8270

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

4735 8270

14.00 14.10 14.200

50000

100000

Time-->

Abundance14.113

#75alpha-PineneConcen: 0.55 ng RT: 19.57 min Scan# 2931Delta R.T. -0.000 minLab File: 09281822.DAcq: 28 Sep 2018 17:26


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


7741 12110553 67 136

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


7741 12110553 13667

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


7739 12110553 67 136

19.50 19.55 19.600

5000

10000

15000

Time-->

Abundance19.568

09281822.D R8091218.M Sat Sep 29 09:40:22 2018 Page 9

63 of 142

00915093

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281823.D Acq On : 28 Sep 2018 17:59 Operator: AB Sample : P1804830-004 (1000mL) Misc : S31-09081801 ALS Vial : 3 Sample Multiplier: 1 Quant Time: Sep 29 09:37:26 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.29 130 178631 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 13.41 114 776705 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 17.72 82 385636 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 260581 11.429 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 91.44% 57) Toluene-d8 (SS2) 15.86 98 894879 11.907 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.28% 73) Bromofluorobenzene (SS3) 19.09 174 329933 14.518 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 116.16% Target Compounds Qvalue 2) Propene 4.26 42 8534 N.D. 3) Dichlorodifluoromethan... 4.38 85 42808 1.228 ng 100 4) Chloromethane 4.67 50 4881 N.D. 5) 1,2-Dichloro-1,1,2,2-t... 4.94 135 863 N.D. 6) Vinyl Chloride 0.00 62 0 N.D. 7) 1,3-Butadiene 0.00 54 0 N.D. 8) Bromomethane 5.80 94 575 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 6.48 45 14004m 0.981 ng 11) Acetonitrile 6.76 41 3716 N.D. 12) Acrolein 6.96 56 6194 0.519 ng 90 13) Acetone 7.16 58 119833 7.354 ng 89 14) Trichlorofluoromethane 7.39 101 20738 0.750 ng 99 15) 2-Propanol (Isopropanol) 7.67 45 17793 N.D. 16) Acrylonitrile 7.99 53 659 N.D. 17) 1,1-Dichloroethene 0.00 96 0 N.D. 18) 2-Methyl-2-Propanol (t... 8.57 59 7284 N.D. 19) Methylene Chloride 8.58 84 4761 N.D. 20) 3-Chloro-1-propene (Al... 8.66 41 289 N.D. 21) Trichlorotrifluoroethane 9.00 151 5470 N.D. 22) Carbon Disulfide 8.85 76 11751 N.D. 23) trans-1,2-Dichloroethene 0.00 61 0 N.D. 24) 1,1-Dichloroethane 0.00 63 0 N.D. 25) Methyl tert-Butyl Ether 0.00 73 0 N.D. 26) Vinyl Acetate 10.32 86 10179 2.156 ng # 43 27) 2-Butanone (MEK) 10.62 72 14555 1.115 ng # 90 28) cis-1,2-Dichloroethene 0.00 61 0 N.D. 29) Diisopropyl Ether 0.00 87 0 N.D. 30) Ethyl Acetate 11.40 61 526 N.D. 31) n-Hexane 11.40 57 17395 0.558 ng 96 32) Chloroform 11.46 83 1609 N.D. 34) Tetrahydrofuran (THF) 11.92 72 1151 N.D. 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 12.26 62 402 N.D. 38) 1,1,1-Trichloroethane 0.00 97 0 N.D. 39) Isopropyl Acetate 13.10 61 850 N.D. 40) 1-Butanol 0.00 56 0 N.D. d 41) Benzene 13.02 78 25080 N.D. 42) Carbon Tetrachloride 13.18 117 4172 N.D. 43) Cyclohexane 13.31 84 7055 N.D. 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 13.76 63 4720 N.D. 46) Bromodichloromethane 13.83 83 553 N.D. 47) Trichloroethene 0.00 130 0 N.D. 48) 1,4-Dioxane 0.00 88 0 N.D. 49) 2,2,4-Trimethylpentane... 14.18 57 4423 N.D.

R8091218.M Sat Sep 29 09:42:32 2018 Page: 1

64 of 142

00915094

anusha.bayyarapu

Anusha

anusha.bayyarapu

M

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281823.D Acq On : 28 Sep 2018 17:59 Operator: AB Sample : P1804830-004 (1000mL) Misc : S31-09081801 ALS Vial : 3 Sample Multiplier: 1 Quant Time: Sep 29 09:37:26 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.44 100 1327 N.D. 51) n-Heptane 14.44 71 4229 N.D. 52) cis-1,3-Dichloropropene 14.87 75 717 N.D. 53) 4-Methyl-2-pentanone 15.03 58 1023 N.D. 54) trans-1,3-Dichloropropene 15.53 75 102 N.D. 55) 1,1,2-Trichloroethane 0.00 97 0 N.D. 58) Toluene 15.96 91 28072 N.D. 59) 2-Hexanone 16.21 43 10329 N.D. 60) Dibromochloromethane 0.00 129 0 N.D. 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 16.84 43 2217 N.D. 63) n-Octane 16.96 57 1284 N.D. 64) Tetrachloroethene 17.11 166 169 N.D. 65) Chlorobenzene 17.78 112 152 N.D. 66) Ethylbenzene 18.11 91 3705 N.D. 67) m- & p-Xylenes 18.26 91 8816 N.D. 68) Bromoform 0.00 173 0 N.D. 69) Styrene 18.59 104 4866 N.D. 70) o-Xylene 18.70 91 3828 N.D. 71) n-Nonane 18.89 43 2973 N.D. 72) 1,1,2,2-Tetrachloroethane 18.71 83 530 N.D. 74) Cumene 19.22 105 891 N.D. 75) alpha-Pinene 19.57 93 64560 1.450 ng 100 76) n-Propylbenzene 19.66 91 1337 N.D. 77) 3-Ethyltoluene 19.76 105 2212 N.D. 78) 4-Ethyltoluene 19.80 105 1277 N.D. 79) 1,3,5-Trimethylbenzene 19.86 105 837 N.D. 80) alpha-Methylstyrene 19.99 118 3184 N.D. 81) 2-Ethyltoluene 20.03 105 926 N.D. 82) 1,2,4-Trimethylbenzene 20.22 105 2947 N.D. 83) n-Decane 0.00 58 0 N.D. d 84) Benzyl Chloride 20.34 91 498 N.D. 85) 1,3-Dichlorobenzene 20.42 146 349 N.D. 86) 1,4-Dichlorobenzene 20.42 146 349 N.D. 87) sec-Butylbenzene 20.47 105 716 N.D. 88) 4-Isopropyltoluene (p-... 20.60 119 3108 N.D. 89) 1,2,3-Trimethylbenzene 20.59 105 1063 N.D. 90) 1,2-Dichlorobenzene 0.00 146 0 N.D. 91) d-Limonene 20.72 68 14319m 0.459 ng 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 21.40 57 3638 N.D. 94) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 95) Naphthalene 22.33 128 4208 N.D. 96) n-Dodecane 22.32 57 7678 N.D. 97) Hexachlorobutadiene 0.00 225 0 N.D. 98) Cyclohexanone 18.41 55 4146 N.D. 99) tert-Butylbenzene 20.22 119 487 N.D. 100) n-Butylbenzene 20.93 91 1502 N.D. -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Sat Sep 29 09:42:32 2018 Page: 2

65 of 142

00915095




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

100000

200000

300000

400000

500000

600000

700000

800000

900000

1000000

1100000

1200000

1300000

1400000

1500000

1600000

1700000

1800000

1900000

2000000

2100000

2200000

2300000

2400000

2500000

2600000

2700000

2800000

Time-->


d-Li

mon

ene,

T

alph

a-Pi

nene

,T

Brom

oflu

orob

enze

ne (S

S3),S

Chl

orob

enze

ne-d

5 (IS

3),IR

Tolu

ene-

d8 (S

S2),S

1,4-

Difl

uoro

benz

ene

(IS2)

,IR

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

n-H

exan

e,T

Brom

ochl

orom

etha

ne (I

S1),I

R

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,T

Tric

hlor

oflu

orom

etha

ne,T

Acet

one,

TAc

role

in,T

Etha

nol,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,T

R8091218.M Sat Sep 29 09:42:33 2018 Page: 3

66 of 142

00915096

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281823.D Acq On : 28 Sep 2018 17:59 Operator: AB Sample : P1804830-004 (1000mL) Misc : S31-09081801 ALS Vial : 3 Sample Multiplier: 1 Quant Time: Sep 29 09:37:26 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.29 130 178631 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 13.41 114 776705 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 17.72 82 385636 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 260581 11.429 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 91.44% 57) Toluene-d8 (SS2) 15.86 98 894879 11.907 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.28% 73) Bromofluorobenzene (SS3) 19.09 174 329933 14.518 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 116.16% Target Compounds Qvalue 3) Dichlorodifluoromethan... 4.38 85 42808 1.228 ng 100 10) Ethanol 6.48 45 14004m 0.981 ng 12) Acrolein 6.96 56 6194 0.519 ng 90 13) Acetone 7.16 58 119833 7.354 ng 89 14) Trichlorofluoromethane 7.39 101 20738 0.750 ng 99 26) Vinyl Acetate 10.32 86 10179 2.156 ng # 43 27) 2-Butanone (MEK) 10.62 72 14555 1.115 ng # 90 31) n-Hexane 11.40 57 17395 0.558 ng 96 75) alpha-Pinene 19.57 93 64560 1.450 ng 100 91) d-Limonene 20.72 68 14319m 0.459 ng -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Sat Sep 29 09:40:24 2018 Page: 1

67 of 142

00915097

anusha.bayyarapu

Anusha

anusha.bayyarapu

M




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

100000

200000

300000

400000

500000

600000

700000

800000

900000

1000000

1100000

1200000

1300000

1400000

1500000

1600000

1700000

1800000

1900000

2000000

2100000

2200000

2300000

2400000

2500000

2600000

2700000

2800000

Time-->


d-Li

mon

ene,

T

alph

a-Pi

nene

,T

Brom

oflu

orob

enze

ne (S

S3),S

Chl

orob

enze

ne-d

5 (IS

3),IR

Tolu

ene-

d8 (S

S2),S

1,4-

Difl

uoro

benz

ene

(IS2)

,IR

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

n-H

exan

e,T

Brom

ochl

orom

etha

ne (I

S1),I

R

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,T

Tric

hlor

oflu

orom

etha

ne,T

Acet

one,

TAc

role

in,T

Etha

nol,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,T

R8091218.M Sat Sep 29 09:40:24 2018 Page: 2

68 of 142

00915098

#3Dichlorodifluoromethane (CFC 12)Concen: 1.23 ng RT: 4.38 min Scan# 110Delta R.T. 0.006 minLab File: 09281823.DAcq: 28 Sep 2018 17:59


Ref

Raw

Sub

20 30 40 50 60 70 80 90 100 110 1200

50

m/z-->


50 10135 66 12242

20 30 40 50 60 70 80 90 100 110 1200

50

m/z-->


50 10129 6637

20 30 40 50 60 70 80 90 100 110 1200

50

m/z-->


50 10131 6640

4.30 4.35 4.40 4.450

5000

10000

15000

20000

25000

Time-->

Abundance 4.384

#10EthanolConcen: 0.98 ng mRT: 6.48 min Scan# 499Delta R.T. -0.108 minLab File: 09281823.DAcq: 28 Sep 2018 17:59


Ref

Raw

Sub

30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


43

41 47

30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


434041

30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4341

6.40 6.50 6.600

1000

2000

3000

4000

Time-->

Abundance 6.485

09281823.D R8091218.M Sat Sep 29 09:40:24 2018 Page 3

69 of 142

00915099



Ref

Raw

Sub

30 35 40 45 50 55 60 650

50

m/z-->


37 5339 42 58

30 35 40 45 50 55 60 650

50

m/z-->


40 4438

30 35 40 45 50 55 60 650

50

m/z-->


38

6.90 7.00 7.100

1000

2000

3000

Time-->

Abundance

6.958



Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


58

39 5236 55

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


58

39 5336 72

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


58

39 5336 72

7.00 7.20 7.400

20000

40000

60000

80000

100000

Time-->

Abundance

7.157

09281823.D R8091218.M Sat Sep 29 09:40:25 2018 Page 4

70 of 142

00915100



Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


6635 47 82 117

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


6635 47 8258 119

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


6635 47 82 119

7.30 7.35 7.40 7.450

2000

4000

6000

8000

Time-->

Abundance 7.394



Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


8659 7140 4637 55

30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


865539 7050 75

30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


86715350 5637 75

10.30 10.400

5000

10000

15000

20000

Time-->

Abundance

10.321

09281823.D R8091218.M Sat Sep 29 09:40:25 2018 Page 5

71 of 142

00915101



Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72575349

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


725739 50

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72

5737 50

10.60 10.700

5000

10000

15000

20000

Time-->

Abundance

10.616



Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


57

8771 102

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


41

867133 13049

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


41

867133 13049

11.30 11.35 11.40 11.450

2000

4000

6000

Time-->

Abundance11.402

09281823.D R8091218.M Sat Sep 29 09:40:25 2018 Page 6

72 of 142

00915102

#75alpha-PineneConcen: 1.45 ng RT: 19.57 min Scan# 2931Delta R.T. 0.000 minLab File: 09281823.DAcq: 28 Sep 2018 17:59


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


7741 12110553 67 136

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


7741 121105 13653 67

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


7712139 105 1366753

19.50 19.55 19.600

10000

20000

30000

Time-->

Abundance19.568

#91d-LimoneneConcen: 0.46 ng mRT: 20.72 min Scan# 3145Delta R.T. -0.011 minLab File: 09281823.DAcq: 28 Sep 2018 17:59


Ref

Raw

Sub

40 60 80 100 120 140 160 180 2000

50

m/z-->


93

11139 53

80123

40 60 80 100 120 140 160 180 2000

50

m/z-->


93

39 53 121 13610781207

40 60 80 100 120 140 160 180 2000

50

m/z-->


93

121 13653 81 105 20740

20.65 20.70 20.750

2000

4000

6000

8000

Time-->

Abundance20.719

09281823.D R8091218.M Sat Sep 29 09:40:26 2018 Page 7

73 of 142

00915103




5.60 5.70 5.80 5.90 6.00 6.10 6.20 6.30 6.40 6.50 6.60 6.70 6.80 6.90 7.00 7.10 7.20 7.30 7.40 7.50 7.60 7.70

0

100

200

300

400

500

600

Time-->


6.603

|

|

|

|

|

|

|

|

|

|

|

2d 1

Ion 46.10 (45.80 to 46.80): 09281823.D\data.ms

30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57

200

300

m/z-->


40

45

30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57

5000

m/z-->


4643

4241 44 4740 48


0.00 0.00 0.00

0.00 0.00 0.00

46.10 40.90 0.00#

45.10 100 100

Ion Exp% Act%

response 100

6.603min (+0.011) 0.01ng

(10) Ethanol (T)

R8091218.M Sat Sep 29 09:35:24 2018 Page: 1

74 of 142

00915104




5.50 5.60 5.70 5.80 5.90 6.00 6.10 6.20 6.30 6.40 6.50 6.60 6.70 6.80 6.90 7.00 7.10 7.20 7.30 7.40 7.50 7.60 7.70

0

1000

2000

3000

4000

5000

6000

7000

Time-->


6.485 |

|

|

|

|

|

|||

|||

2d 1

Ion 46.10 (45.80 to 46.80): 09281823.D\data.ms

30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57

2000

4000

m/z-->


46

43444240 41

30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57

5000

m/z-->


4643

4241 44 4740 48


0.00 0.00 0.00

0.00 0.00 0.00

46.10 40.90 0.00#

45.10 100 100

Ion Exp% Act%

response 14004

6.485min (-0.108) 0.98ng m

(10) Ethanol (T)

R8091218.M Sat Sep 29 09:35:32 2018 Page: 1

75 of 142

00915105

anusha.bayyarapu

Anusha

anusha.bayyarapu

MP

chris.parnell

Chris




20.50 20.55 20.60 20.65 20.70 20.75 20.80 20.85 20.90 20.95 21.00

0

1000

2000

3000

4000

5000

6000

7000

Time-->

Abundance Ion 68.10 (67.80 to 68.80): 09281823.D\data.ms20.719

|

|

|

|

|||4d3d 2d1

Ion 93.10 (92.80 to 93.80): 09281823.D\data.ms

30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210

5000

m/z-->


93

7939 53 121 136107

44 20763 11558

30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210

5000

m/z-->


93

79 11139 53 121 13674

10563 8447 58 15199 116 131


0.00 0.00 0.00

0.00 0.00 0.00

93.10 67.30 123.08#

68.10 100 100

Ion Exp% Act%

response 14660

20.719min (-0.011) 0.47ng

(91) d-Limonene (T)

R8091218.M Sat Sep 29 09:37:23 2018 Page: 1

76 of 142

00915106




20.50 20.55 20.60 20.65 20.70 20.75 20.80 20.85 20.90 20.95 21.00

0

1000

2000

3000

4000

5000

6000

7000

Time-->

Abundance Ion 68.10 (67.80 to 68.80): 09281823.D\data.ms20.719

|

|

|

|

|||4d3d 2d1

Ion 93.10 (92.80 to 93.80): 09281823.D\data.ms

30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210

5000

m/z-->


93

7939 53 121 136107

44 20763 11558

30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210

5000

m/z-->


93

79 11139 53 121 13674

10563 8447 58 15199 116 131


0.00 0.00 0.00

0.00 0.00 0.00

93.10 67.30 126.01#

68.10 100 100

Ion Exp% Act%

response 14319

20.719min (-0.011) 0.46ng m

(91) d-Limonene (T)

R8091218.M Sat Sep 29 09:37:30 2018 Page: 1

77 of 142

00915107

anusha.bayyarapu

IPC

anusha.bayyarapu

Anusha

chris.parnell

Chris

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281805.D Acq On : 28 Sep 2018 6:45 Operator: AB Sample : MB R8092818_1000mL Misc : S31-09081801 ALS Vial : 1 Sample Multiplier: 1 Quant Time: Sep 28 12:30:26 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.28 130 175641 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 13.41 114 771571 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 17.72 82 359884 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 252339 11.256 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 90.08% 57) Toluene-d8 (SS2) 15.86 98 866350 12.352 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 98.80% 73) Bromofluorobenzene (SS3) 19.09 174 301040 14.194 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 113.52% Target Compounds Qvalue 2) Propene 4.27 42 680 0.032 ng # 46 3) Dichlorodifluoromethan... 4.42 85 730 0.021 ng # 72 4) Chloromethane 0.00 50 0 N.D. d 5) 1,2-Dichloro-1,1,2,2-t... 0.00 135 0 N.D. d 6) Vinyl Chloride 0.00 62 0 N.D. d 7) 1,3-Butadiene 0.00 54 0 N.D. 8) Bromomethane 0.00 94 0 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 6.53 45 2343 0.167 ng 82 11) Acetonitrile 6.80 41 1561 0.042 ng # 55 12) Acrolein 0.00 56 0 N.D. d 13) Acetone 7.21 58 6475 0.404 ng 100 14) Trichlorofluoromethane 7.42 101 639 0.024 ng 76 15) 2-Propanol (Isopropanol) 7.75 45 1689 0.035 ng 64 16) Acrylonitrile 0.00 53 0 N.D. d 17) 1,1-Dichloroethene 8.38 96 234 0.015 ng # 64 18) 2-Methyl-2-Propanol (t... 0.00 59 0 N.D. d 19) Methylene Chloride 8.58 84 547 0.031 ng 98 20) 3-Chloro-1-propene (Al... 0.00 41 0 N.D. d 21) Trichlorotrifluoroethane 9.01 151 237 0.016 ng 89 22) Carbon Disulfide 0.00 76 0 N.D. d 23) trans-1,2-Dichloroethene 9.86 61 301 0.012 ng # 15 24) 1,1-Dichloroethane 0.00 63 0 N.D. d 25) Methyl tert-Butyl Ether 0.00 73 0 N.D. d 26) Vinyl Acetate 0.00 86 0 N.D. 27) 2-Butanone (MEK) 0.00 72 0 N.D. 28) cis-1,2-Dichloroethene 11.12 61 403 0.016 ng 78 29) Diisopropyl Ether 0.00 87 0 N.D. d 30) Ethyl Acetate 0.00 61 0 N.D. 31) n-Hexane 11.40 57 706 0.023 ng # 90 32) Chloroform 11.46 83 661 0.022 ng 89 34) Tetrahydrofuran (THF) 0.00 72 0 N.D. 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 0.00 62 0 N.D. d 38) 1,1,1-Trichloroethane 12.54 97 534 0.021 ng # 68 39) Isopropyl Acetate 0.00 61 0 N.D. d 40) 1-Butanol 0.00 56 0 N.D. d 41) Benzene 13.02 78 3100 0.043 ng 89 42) Carbon Tetrachloride 13.18 117 164 0.008 ng 85 43) Cyclohexane 13.31 84 1475 0.049 ng 98 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 13.87 63 408 0.023 ng # 14 46) Bromodichloromethane 14.05 83 495 0.022 ng # 48 47) Trichloroethene 14.12 130 481 0.025 ng 86 48) 1,4-Dioxane 0.00 88 0 N.D. 49) 2,2,4-Trimethylpentane... 14.18 57 2022 0.025 ng 92

R8091218.M Fri Sep 28 12:30:31 2018 Page: 1

78 of 142

00915108

anusha.bayyarapu

Anusha

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281805.D Acq On : 28 Sep 2018 6:45 Operator: AB Sample : MB R8092818_1000mL Misc : S31-09081801 ALS Vial : 1 Sample Multiplier: 1 Quant Time: Sep 28 12:30:26 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 0.00 100 0 N.D. 51) n-Heptane 14.45 71 377 0.020 ng # 81 52) cis-1,3-Dichloropropene 0.00 75 0 N.D. d 53) 4-Methyl-2-pentanone 0.00 58 0 N.D. 54) trans-1,3-Dichloropropene 0.00 75 0 N.D. 55) 1,1,2-Trichloroethane 15.68 97 248 0.015 ng # 54 58) Toluene 15.97 91 2277 0.030 ng 93 59) 2-Hexanone 0.00 43 0 N.D. 60) Dibromochloromethane 0.00 129 0 N.D. d 61) 1,2-Dibromoethane 16.64 107 107 0.006 ng # 49 62) n-Butyl Acetate 0.00 43 0 N.D. d 63) n-Octane 16.97 57 165 0.010 ng 87 64) Tetrachloroethene 17.10 166 445 0.022 ng 81 65) Chlorobenzene 17.76 112 1304 0.027 ng 86 66) Ethylbenzene 18.12 91 1779 0.021 ng 87 67) m- & p-Xylenes 18.27 91 2930 0.045 ng 88 68) Bromoform 0.00 173 0 N.D. d 69) Styrene 0.00 104 0 N.D. d 70) o-Xylene 18.70 91 1572 0.024 ng 85 71) n-Nonane 18.89 43 462 0.012 ng # 59 72) 1,1,2,2-Tetrachloroethane 18.68 83 606 0.020 ng 91 74) Cumene 19.22 105 1996 0.023 ng 90 75) alpha-Pinene 0.00 93 0 N.D. 76) n-Propylbenzene 19.68 91 1988 0.020 ng # 80 77) 3-Ethyltoluene 19.77 105 1301 0.016 ng 89 78) 4-Ethyltoluene 19.80 105 1467 0.019 ng 82 79) 1,3,5-Trimethylbenzene 19.86 105 1210 0.017 ng 79 80) alpha-Methylstyrene 20.00 118 165 0.005 ng # 17 81) 2-Ethyltoluene 20.03 105 1165 0.014 ng 47 82) 1,2,4-Trimethylbenzene 20.23 105 798 0.012 ng 86 83) n-Decane 0.00 58 0 N.D. 84) Benzyl Chloride 0.00 91 0 N.D. d 85) 1,3-Dichlorobenzene 20.37 146 652 0.017 ng # 61 86) 1,4-Dichlorobenzene 20.42 146 662 0.017 ng 87 87) sec-Butylbenzene 20.46 105 1115 0.012 ng # 58 88) 4-Isopropyltoluene (p-... 20.60 119 1170 0.014 ng # 72 89) 1,2,3-Trimethylbenzene 20.60 105 553 0.008 ng 80 90) 1,2-Dichlorobenzene 20.72 146 526 0.014 ng 99 91) d-Limonene 0.00 68 0 N.D. 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 0.00 57 0 N.D. d 94) 1,2,4-Trichlorobenzene 22.23 180 390 0.015 ng # 73 95) Naphthalene 0.00 128 0 N.D. d 96) n-Dodecane 0.00 57 0 N.D. 97) Hexachlorobutadiene 0.00 225 0 N.D. 98) Cyclohexanone 0.00 55 0 N.D. d 99) tert-Butylbenzene 20.22 119 985 0.014 ng # 52 100) n-Butylbenzene 0.00 91 0 N.D. d -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Fri Sep 28 12:30:31 2018 Page: 2

79 of 142

00915109


Data File: I:\MS08\Data\2018_09\28\09281805.D Acq On : 28 Sep 2018 6:45 Operator: AB Sample : MB R8092818_1000mL Misc : S31-09081801 ALS Vial : 1 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

800000

850000

900000

950000

1000000

1050000

1100000

1150000

1200000

1250000

Time-->


1,2,

4-Tr

ichl

orob

enze

ne,T

1,2-

Dic

hlor

oben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

1,2,

3-Tr

imet

hylb

enze

ne,T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,T1,

2,4-

Trim

ethy

lben

zene

,Tte

rt-Bu

tylb

enze

ne,T

2-Et

hylto

luen

e,T

alph

a-M

ethy

lsty

rene

,T1,

3,5-

Trim

ethy

lben

zene

,T4-

Ethy

ltolu

ene,

T3-

Ethy

ltolu

ene,

Tn-

Prop

ylbe

nzen

e,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

T1,

2-D

ibro

moe

than

e,T

Tolu

ene,

TTo

luen

e-d8

(SS2

),S1,

1,2-

Tric

hlor

oeth

ane,

T

n-H

epta

ne,T

2,2,

4-Tr

imet

hylp

enta

ne (I

sooc

tane

),TTr

ichl

oroe

then

e,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Chl

orof

orm

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

T

Met

hyle

ne C

hlor

ide,

T1,

1-D

ichl

oroe

then

e,T

2-Pr

opan

ol (I

sopr

opan

ol),T

Tric

hlor

oflu

orom

etha

ne,T

Acet

one,

T

Acet

onitr

ile,T

Etha

nol,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R8091218.M Fri Sep 28 12:30:32 2018 Page: 3

80 of 142

00915110

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281810.D Acq On : 28 Sep 2018 9:33 Operator: AB Sample : LCS R8092818_25ng Misc : S31-09081801/S31-09281801 (10/27) ALS Vial : 1 Sample Multiplier: 1 Quant Time: Sep 28 10:09:42 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.30 130 184873 12.500 ng -0.01 37) 1,4-Difluorobenzene (IS2) 13.41 114 735550 12.500 ng -0.01 56) Chlorobenzene-d5 (IS3) 17.72 82 363832 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.15 65 254226 10.774 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 86.16% 57) Toluene-d8 (SS2) 15.86 98 848055 11.960 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.68% 73) Bromofluorobenzene (SS3) 19.09 174 306728 14.305 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 114.48% Target Compounds Qvalue 2) Propene 4.21 42 417331 18.759 ng 99 3) Dichlorodifluoromethan... 4.37 85 667355 18.498 ng 100 4) Chloromethane 4.66 50 525046 17.540 ng 99 5) 1,2-Dichloro-1,1,2,2-t... 4.92 135 369847 18.324 ng 99 6) Vinyl Chloride 5.09 62 509377 17.912 ng 99 7) 1,3-Butadiene 5.36 54 416135 17.814 ng 96 8) Bromomethane 5.80 94 316523 20.705 ng 100 9) Chloroethane 6.13 64 282134 18.750 ng 99 10) Ethanol 6.53 45 1561047 105.689 ng 100 11) Acetonitrile 6.78 41 834488 21.172 ng 99 12) Acrolein 6.96 56 286585 23.221 ng 99 13) Acetone 7.17 58 1658236 98.328 ng 92 14) Trichlorofluoromethane 7.40 101 601006 21.002 ng 99 15) 2-Propanol (Isopropanol) 7.66 45 2308039 45.488 ng 98 16) Acrylonitrile 7.93 53 595871 24.251 ng 100 17) 1,1-Dichloroethene 8.36 96 404972 24.527 ng 94 18) 2-Methyl-2-Propanol (t... 8.53 59 2222759 48.237 ng 98 19) Methylene Chloride 8.59 84 426469 23.141 ng 93 20) 3-Chloro-1-propene (Al... 8.75 41 680460 25.511 ng 99 21) Trichlorotrifluoroethane 9.00 151 370911 23.550 ng 97 22) Carbon Disulfide 8.85 76 1512668 23.799 ng 100 23) trans-1,2-Dichloroethene 9.86 61 598805 23.098 ng 98 24) 1,1-Dichloroethane 10.11 63 693706 20.750 ng 99 25) Methyl tert-Butyl Ether 10.21 73 1233745 22.683 ng 100 26) Vinyl Acetate 10.36 86 553599 113.294 ng # 89 27) 2-Butanone (MEK) 10.61 72 295534 21.868 ng 96 28) cis-1,2-Dichloroethene 11.12 61 550534 21.193 ng 98 29) Diisopropyl Ether 11.42 87 412767 22.206 ng # 90 30) Ethyl Acetate 11.42 61 287884 44.606 ng 97 31) n-Hexane 11.40 57 554841 17.194 ng 98 32) Chloroform 11.47 83 660418 21.328 ng 99 34) Tetrahydrofuran (THF) 11.87 72 284319 23.116 ng 98 35) Ethyl tert-Butyl Ether 12.01 87 529070 23.158 ng 97 36) 1,2-Dichloroethane 12.27 62 491699 19.631 ng 99 38) 1,1,1-Trichloroethane 12.55 97 595632 24.246 ng 96 39) Isopropyl Acetate 12.97 61 511547 47.132 ng # 86 40) 1-Butanol 12.99 56 961197 47.359 ng 99 41) Benzene 13.03 78 1531518 22.309 ng 100 42) Carbon Tetrachloride 13.18 117 522723 25.077 ng 99 43) Cyclohexane 13.32 84 1315484 45.756 ng 100 44) tert-Amyl Methyl Ether 13.66 73 1241354 26.323 ng 98 45) 1,2-Dichloropropane 13.87 63 403088 23.939 ng 99 46) Bromodichloromethane 14.06 83 538411 25.181 ng 100 47) Trichloroethene 14.12 130 436028 23.817 ng 99 48) 1,4-Dioxane 14.09 88 356309 24.766 ng 100 49) 2,2,4-Trimethylpentane... 14.18 57 1860967 23.706 ng 95

R8091218.M Fri Sep 28 16:54:34 2018 Page: 1

81 of 142

00915111

anusha.bayyarapu

Anusha

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281810.D Acq On : 28 Sep 2018 9:33 Operator: AB Sample : LCS R8092818_25ng Misc : S31-09081801/S31-09281801 (10/27) ALS Vial : 1 Sample Multiplier: 1 Quant Time: Sep 28 10:09:42 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.32 100 366510 51.560 ng 93 51) n-Heptane 14.45 71 402214 22.613 ng 100 52) cis-1,3-Dichloropropene 14.98 75 672549 27.228 ng 100 53) 4-Methyl-2-pentanone 15.01 58 413006 25.493 ng 97 54) trans-1,3-Dichloropropene 15.50 75 621391 26.994 ng 99 55) 1,1,2-Trichloroethane 15.67 97 398166 25.643 ng 98 58) Toluene 15.96 91 1644086 21.413 ng 100 59) 2-Hexanone 16.20 43 991854 22.435 ng 98 60) Dibromochloromethane 16.37 129 480818 26.031 ng 99 61) 1,2-Dibromoethane 16.63 107 456560 25.484 ng 100 62) n-Butyl Acetate 16.84 43 1137628 26.146 ng 98 63) n-Octane 16.96 57 365173 21.976 ng 99 64) Tetrachloroethene 17.10 166 489346 23.955 ng 100 65) Chlorobenzene 17.76 112 1125788 22.649 ng 99 66) Ethylbenzene 18.11 91 1937856 22.610 ng 99 67) m- & p-Xylenes 18.27 91 2962665 44.924 ng 99 68) Bromoform 18.34 173 427752 28.217 ng 100 69) Styrene 18.59 104 1250693 25.991 ng 100 70) o-Xylene 18.70 91 1514884 22.793 ng 99 71) n-Nonane 18.89 43 891087 22.475 ng 97 72) 1,1,2,2-Tetrachloroethane 18.67 83 720960 23.457 ng 100 74) Cumene 19.22 105 2013003 23.436 ng 100 75) alpha-Pinene 19.57 93 1047049 24.918 ng 97 76) n-Propylbenzene 19.66 91 2370625 23.988 ng 99 77) 3-Ethyltoluene 19.76 105 1937879 23.364 ng 100 78) 4-Ethyltoluene 19.79 105 1979100 25.180 ng 100 79) 1,3,5-Trimethylbenzene 19.86 105 1655106 23.383 ng 99 80) alpha-Methylstyrene 19.99 118 953858 27.727 ng 93 81) 2-Ethyltoluene 20.03 105 1970804 23.743 ng # 12 82) 1,2,4-Trimethylbenzene 20.22 105 1674554 24.240 ng 99 83) n-Decane 20.30 58 41465 24.761 ng 98 84) Benzyl Chloride 20.34 91 1441234 27.152 ng 99 85) 1,3-Dichlorobenzene 20.36 146 996186 25.901 ng # 64 86) 1,4-Dichlorobenzene 20.41 146 1006026 25.681 ng 100 87) sec-Butylbenzene 20.46 105 2191960 23.638 ng 99 88) 4-Isopropyltoluene (p-... 20.60 119 2048509 23.637 ng 99 89) 1,2,3-Trimethylbenzene 20.60 105 1687610 24.050 ng 99 90) 1,2-Dichlorobenzene 20.71 146 938296 25.170 ng 100 91) d-Limonene 20.72 68 699859 23.781 ng 98 92) 1,2-Dibromo-3-Chloropr... 21.10 157 360920 28.659 ng 90 93) n-Undecane 21.40 57 963436 23.227 ng 100 94) 1,2,4-Trichlorobenzene 22.23 180 738621 28.698 ng 99 95) Naphthalene 22.33 128 2176397 26.043 ng 100 96) n-Dodecane 22.32 57 958057 24.532 ng 99 97) Hexachlorobutadiene 22.66 225 472715 27.490 ng 100 98) Cyclohexanone 18.41 55 639440 23.775 ng 97 99) tert-Butylbenzene 20.22 119 1658766 23.905 ng 100 100) n-Butylbenzene 20.96 91 1709806 23.850 ng 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Fri Sep 28 16:54:34 2018 Page: 2

82 of 142

00915112


Data File: I:\MS08\Data\2018_09\28\09281810.D Acq On : 28 Sep 2018 9:33 Operator: AB Sample : LCS R8092818_25ng Misc : S31-09081801/S31-09281801 (10/27) ALS Vial : 1 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

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ne,T

1,3-

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hlor

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,TBe

nzyl

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1,2,

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hylb

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ltolu

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pha-

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hyls

tyre

ne,T

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imet

hylb

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ne,T

4-Et

hylto

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3-Et

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pha-

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ne,T

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m- &

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lben

zene

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hlor

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zene

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(IS3)

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ane,

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l Ace

tate

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2-D

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ochl

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ne,T

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TTo

luen

e,T

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ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

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s-1,

3-D

ichl

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ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

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lpen

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(Iso

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ne),T

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hlor

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ene,

T1,

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ne,T

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odic

hlor

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ichl

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ne,T

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l Eth

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uoro

benz

ene

(IS2)

,IRC

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ne,T

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bon

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chlo

ride,

TBe

nzen

e,T

1-Bu

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hyl A

ceta

te,T

Diis

opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAcet

onitr

ile,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R8091218.M Fri Sep 28 16:54:35 2018 Page: 3

83 of 142

00915113

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281824.D Acq On : 28 Sep 2018 18:32 Operator: AB Sample : P1804830-004dup (1000mL) Misc : S31-09081801 ALS Vial : 3 Sample Multiplier: 1 Quant Time: Sep 29 09:38:08 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.28 130 181911 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 13.41 114 761943 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 17.72 82 382680 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 261492 11.263 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 90.08% 57) Toluene-d8 (SS2) 15.86 98 872834 11.703 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 93.60% 73) Bromofluorobenzene (SS3) 19.09 174 332795 14.757 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 118.08% Target Compounds Qvalue 2) Propene 4.25 42 8599 N.D. 3) Dichlorodifluoromethan... 4.37 85 42730 1.204 ng 100 4) Chloromethane 4.66 50 5946 N.D. 5) 1,2-Dichloro-1,1,2,2-t... 4.93 135 855 N.D. 6) Vinyl Chloride 0.00 62 0 N.D. 7) 1,3-Butadiene 0.00 54 0 N.D. 8) Bromomethane 5.80 94 620 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 6.47 45 14237 0.980 ng 100 11) Acetonitrile 6.76 41 4597 N.D. 12) Acrolein 6.95 56 6838 0.563 ng 93 13) Acetone 7.15 58 124061 7.476 ng 88 14) Trichlorofluoromethane 7.39 101 20600 0.732 ng 99 15) 2-Propanol (Isopropanol) 7.66 45 16950 N.D. 16) Acrylonitrile 7.99 53 560 N.D. 17) 1,1-Dichloroethene 0.00 96 0 N.D. 18) 2-Methyl-2-Propanol (t... 8.57 59 6190 N.D. 19) Methylene Chloride 8.57 84 4598 N.D. 20) 3-Chloro-1-propene (Al... 8.63 41 544 N.D. 21) Trichlorotrifluoroethane 9.00 151 5544 N.D. 22) Carbon Disulfide 8.84 76 11732 N.D. 23) trans-1,2-Dichloroethene 0.00 61 0 N.D. 24) 1,1-Dichloroethane 0.00 63 0 N.D. 25) Methyl tert-Butyl Ether 0.00 73 0 N.D. 26) Vinyl Acetate 10.32 86 12710 2.643 ng # 35 27) 2-Butanone (MEK) 10.62 72 14314 1.076 ng 94 28) cis-1,2-Dichloroethene 0.00 61 0 N.D. 29) Diisopropyl Ether 0.00 87 0 N.D. 30) Ethyl Acetate 11.40 61 416 N.D. 31) n-Hexane 11.40 57 15989 0.504 ng 97 32) Chloroform 11.45 83 1503 N.D. 34) Tetrahydrofuran (THF) 11.92 72 1149 N.D. 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 12.26 62 367 N.D. 38) 1,1,1-Trichloroethane 0.00 97 0 N.D. 39) Isopropyl Acetate 13.10 61 1000 N.D. 40) 1-Butanol 0.00 56 0 N.D. d 41) Benzene 13.02 78 23973 N.D. 42) Carbon Tetrachloride 13.18 117 3815 N.D. 43) Cyclohexane 13.31 84 6675 N.D. 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 13.74 63 5711 N.D. 46) Bromodichloromethane 13.82 83 420 N.D. 47) Trichloroethene 0.00 130 0 N.D. 48) 1,4-Dioxane 0.00 88 0 N.D. 49) 2,2,4-Trimethylpentane... 14.18 57 4375 N.D.

R8091218.M Sat Sep 29 09:42:35 2018 Page: 1

84 of 142

00915114

anusha.bayyarapu

Anusha

anusha.bayyarapu

M

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281824.D Acq On : 28 Sep 2018 18:32 Operator: AB Sample : P1804830-004dup (1000mL) Misc : S31-09081801 ALS Vial : 3 Sample Multiplier: 1 Quant Time: Sep 29 09:38:08 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.44 100 1117 N.D. 51) n-Heptane 14.44 71 3945 N.D. 52) cis-1,3-Dichloropropene 14.86 75 726 N.D. 53) 4-Methyl-2-pentanone 15.03 58 993 N.D. 54) trans-1,3-Dichloropropene 15.62 75 628 N.D. 55) 1,1,2-Trichloroethane 0.00 97 0 N.D. 58) Toluene 15.96 91 26971 N.D. 59) 2-Hexanone 16.21 43 10295 N.D. 60) Dibromochloromethane 0.00 129 0 N.D. 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 16.84 43 1715 N.D. 63) n-Octane 16.96 57 1246 N.D. 64) Tetrachloroethene 0.00 166 0 N.D. 65) Chlorobenzene 17.79 112 156 N.D. 66) Ethylbenzene 18.11 91 3699 N.D. 67) m- & p-Xylenes 18.27 91 8780 N.D. 68) Bromoform 0.00 173 0 N.D. 69) Styrene 18.59 104 4759 N.D. 70) o-Xylene 18.70 91 3586 N.D. 71) n-Nonane 18.88 43 2322 N.D. 72) 1,1,2,2-Tetrachloroethane 18.71 83 544 N.D. 74) Cumene 19.22 105 912 N.D. 75) alpha-Pinene 19.56 93 63128 1.428 ng 96 76) n-Propylbenzene 19.66 91 1379 N.D. 77) 3-Ethyltoluene 19.76 105 2060 N.D. 78) 4-Ethyltoluene 19.79 105 1314 N.D. 79) 1,3,5-Trimethylbenzene 19.86 105 860 N.D. 80) alpha-Methylstyrene 19.99 118 3389 N.D. 81) 2-Ethyltoluene 20.03 105 955 N.D. 82) 1,2,4-Trimethylbenzene 20.22 105 3011 N.D. 83) n-Decane 0.00 58 0 N.D. d 84) Benzyl Chloride 20.34 91 559 N.D. 85) 1,3-Dichlorobenzene 20.42 146 458 N.D. 86) 1,4-Dichlorobenzene 20.42 146 458 N.D. 87) sec-Butylbenzene 20.47 105 670 N.D. 88) 4-Isopropyltoluene (p-... 20.60 119 2994 N.D. 89) 1,2,3-Trimethylbenzene 20.59 105 1064 N.D. 90) 1,2-Dichlorobenzene 0.00 146 0 N.D. 91) d-Limonene 20.72 68 14082m 0.455 ng 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 21.40 57 3564 N.D. 94) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 95) Naphthalene 22.34 128 4217 N.D. 96) n-Dodecane 22.32 57 7784 N.D. 97) Hexachlorobutadiene 0.00 225 0 N.D. 98) Cyclohexanone 18.41 55 4307 N.D. 99) tert-Butylbenzene 20.22 119 440 N.D. 100) n-Butylbenzene 20.96 91 1685 N.D. -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Sat Sep 29 09:42:35 2018 Page: 2

85 of 142

00915115


Data File: I:\MS08\Data\2018_09\28\09281824.D Acq On : 28 Sep 2018 18:32 Operator: AB Sample : P1804830-004dup (1000mL) Misc : S31-09081801 ALS Vial : 3 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

100000

200000

300000

400000

500000

600000

700000

800000

900000

1000000

1100000

1200000

1300000

1400000

1500000

1600000

1700000

1800000

1900000

Time-->


d-Li

mon

ene,

T

alph

a-Pi

nene

,T

Brom

oflu

orob

enze

ne (S

S3),S

Chl

orob

enze

ne-d

5 (IS

3),IR

Tolu

ene-

d8 (S

S2),S

1,4-

Difl

uoro

benz

ene

(IS2)

,IR

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

n-H

exan

e,T

Brom

ochl

orom

etha

ne (I

S1),I

R

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,T

Tric

hlor

oflu

orom

etha

ne,T

Acet

one,

TAc

role

in,T

Etha

nol,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,T

R8091218.M Sat Sep 29 09:42:35 2018 Page: 3

86 of 142

00915116

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281824.D Acq On : 28 Sep 2018 18:32 Operator: AB Sample : P1804830-004dup (1000mL) Misc : S31-09081801 ALS Vial : 3 Sample Multiplier: 1 Quant Time: Sep 29 09:38:08 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.28 130 181911 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 13.41 114 761943 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 17.72 82 382680 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 261492 11.263 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 90.08% 57) Toluene-d8 (SS2) 15.86 98 872834 11.703 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 93.60% 73) Bromofluorobenzene (SS3) 19.09 174 332795 14.757 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 118.08% Target Compounds Qvalue 3) Dichlorodifluoromethan... 4.37 85 42730 1.204 ng 100 10) Ethanol 6.47 45 14237 0.980 ng 100 12) Acrolein 6.95 56 6838 0.563 ng 93 13) Acetone 7.15 58 124061 7.476 ng 88 14) Trichlorofluoromethane 7.39 101 20600 0.732 ng 99 26) Vinyl Acetate 10.32 86 12710 2.643 ng # 35 27) 2-Butanone (MEK) 10.62 72 14314 1.076 ng 94 31) n-Hexane 11.40 57 15989 0.504 ng 97 75) alpha-Pinene 19.56 93 63128 1.428 ng 96 91) d-Limonene 20.72 68 14082m 0.455 ng -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Sat Sep 29 09:40:27 2018 Page: 1

87 of 142

00915117

anusha.bayyarapu

Anusha

anusha.bayyarapu

M




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

100000

200000

300000

400000

500000

600000

700000

800000

900000

1000000

1100000

1200000

1300000

1400000

1500000

1600000

1700000

1800000

1900000

Time-->


d-Li

mon

ene,

T

alph

a-Pi

nene

,T

Brom

oflu

orob

enze

ne (S

S3),S

Chl

orob

enze

ne-d

5 (IS

3),IR

Tolu

ene-

d8 (S

S2),S

1,4-

Difl

uoro

benz

ene

(IS2)

,IR

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

n-H

exan

e,T

Brom

ochl

orom

etha

ne (I

S1),I

R

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,T

Tric

hlor

oflu

orom

etha

ne,T

Acet

one,

TAc

role

in,T

Etha

nol,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,T

R8091218.M Sat Sep 29 09:40:28 2018 Page: 2

88 of 142

00915118

#3Dichlorodifluoromethane (CFC 12)Concen: 1.20 ng RT: 4.37 min Scan# 108Delta R.T. -0.006 minLab File: 09281824.DAcq: 28 Sep 2018 18:32


Ref

Raw

Sub

20 30 40 50 60 70 80 90 100 110 1200

50

m/z-->


50 10135 66 12242

20 30 40 50 60 70 80 90 100 110 1200

50

m/z-->


50 10131 6640

20 30 40 50 60 70 80 90 100 110 1200

50

m/z-->


50 10131 66

4.30 4.35 4.40 4.450

5000

10000

15000

20000

25000

Time-->

Abundance 4.373

#10EthanolConcen: 0.98 ng RT: 6.47 min Scan# 497Delta R.T. -0.118 minLab File: 09281824.DAcq: 28 Sep 2018 18:32


Ref

Raw

Sub

30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


43

41 47

30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4340

30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


43

40

6.40 6.50 6.600

1000

2000

3000

4000

Time-->

Abundance 6.474

09281824.D R8091218.M Sat Sep 29 09:40:29 2018 Page 3

89 of 142

00915119



Ref

Raw

Sub

30 35 40 45 50 55 60 650

50

m/z-->


37 5339 42 58

30 35 40 45 50 55 60 650

50

m/z-->


404438

30 35 40 45 50 55 60 650

50

m/z-->


38

6.90 7.00 7.100

1000

2000

3000

Time-->

Abundance

6.947



Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


58

39 5236 55

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


58

39 55 725236

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


58

39 725236

7.00 7.20 7.400

50000

100000

Time-->

Abundance

7.152

09281824.D R8091218.M Sat Sep 29 09:40:29 2018 Page 4

90 of 142

00915120



Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


6635 47 82 117

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


664735 8258 117

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


664735 82 117

7.30 7.35 7.40 7.450

2000

4000

6000

8000

Time-->

Abundance 7.389



Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


8659 7140 4637 55

30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


8655 7538 50 70

30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


865038 55 71 75

10.30 10.400

5000

10000

15000

20000

25000

Time-->

Abundance

10.315

09281824.D R8091218.M Sat Sep 29 09:40:29 2018 Page 5

91 of 142

00915121



Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72575349

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


725740 5037

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72

5738 50

10.60 10.700

5000

10000

15000

20000

Time-->

Abundance

10.616



Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


57

8771 102

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


41

86714933 130

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


41

86714933 130

11.30 11.35 11.40 11.450

2000

4000

6000

Time-->

Abundance11.396

09281824.D R8091218.M Sat Sep 29 09:40:30 2018 Page 6

92 of 142

00915122

#75alpha-PineneConcen: 1.43 ng RT: 19.56 min Scan# 2930Delta R.T. -0.005 minLab File: 09281824.DAcq: 28 Sep 2018 18:32


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


7741 12110553 67 136

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


7741 12110553 13667

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


7739 12110567 13653

19.50 19.55 19.600

10000

20000

30000

Time-->

Abundance19.563

#91d-LimoneneConcen: 0.45 ng mRT: 20.72 min Scan# 3145Delta R.T. -0.011 minLab File: 09281824.DAcq: 28 Sep 2018 18:32


Ref

Raw

Sub

40 60 80 100 120 140 160 180 2000

50

m/z-->


93

11139 53

80123

40 60 80 100 120 140 160 180 2000

50

m/z-->


93

41 12153 107 13681207

40 60 80 100 120 140 160 180 2000

50

m/z-->


93

121 13653 81 20710540

20.65 20.70 20.750

2000

4000

6000

8000

Time-->

Abundance20.719

09281824.D R8091218.M Sat Sep 29 09:40:30 2018 Page 7

93 of 142

00915123




20.45 20.50 20.55 20.60 20.65 20.70 20.75 20.80 20.85 20.90 20.95 21.00 21.05 21.10 21.15

0

1000

2000

3000

4000

5000

6000

7000

Time-->

Abundance Ion 68.10 (67.80 to 68.80): 09281824.D\data.ms20.719|

|

|

|

|

|||||| 5d4d 3d2d1

Ion 93.10 (92.80 to 93.80): 09281824.D\data.ms

30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210

5000

m/z-->


93

7941 53 121107 136

20763 11558 9873

30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210

5000

m/z-->


93

79 11139 53 121 13674

10563 8447 58 15199 116 131


0.00 0.00 0.00

0.00 0.00 0.00

93.10 67.30 124.77#

68.10 100 100

Ion Exp% Act%

response 14416

20.719min (-0.011) 0.47ng

(91) d-Limonene (T)

R8091218.M Sat Sep 29 09:38:04 2018 Page: 1

94 of 142

00915124




20.45 20.50 20.55 20.60 20.65 20.70 20.75 20.80 20.85 20.90 20.95 21.00 21.05 21.10 21.15

0

1000

2000

3000

4000

5000

6000

7000

Time-->

Abundance Ion 68.10 (67.80 to 68.80): 09281824.D\data.ms20.719|

|

|

|

|

|||||| 5d4d 3d2d1

Ion 93.10 (92.80 to 93.80): 09281824.D\data.ms

30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210

5000

m/z-->


93

7941 53 121107 136

20763 11558 9873

30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210

5000

m/z-->


93

79 11139 53 121 13674

10563 8447 58 15199 116 131


0.00 0.00 0.00

0.00 0.00 0.00

93.10 67.30 127.73#

68.10 100 100

Ion Exp% Act%

response 14082

20.719min (-0.011) 0.45ng m

(91) d-Limonene (T)

R8091218.M Sat Sep 29 09:38:10 2018 Page: 1

95 of 142

00915125

anusha.bayyarapu

Anusha

anusha.bayyarapu

IPC

chris.parnell

Chris

Response Factor Report MS08

Method Path : I:\MS08\Methods\

Method File : R8091218.M

Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS)

Last Update : Thu Sep 13 10:44:42 2018

Response Via : Initial Calibration

Calibration Files

0.1 =09121805.D 0.2 =09121806.D 0.5 =09121807.D 1.0 =09121808.D 5.0 =09121809.D 25 =09121810.D 50 =09121811.D

100 =09121812.D

Compound 0.1 0.2 0.5 1.0 5.0 25 50 100 Avg %RSD

--------------------------------------------------------------------------------------

1) IR Bromochloromethane... ----------------ISTD---------------------

2) T Propene 1.613 1.584 1.480 1.712 1.427 1.415 1.320 1.484 1.504 8.34

3) T Dichlorodifluo... 2.840 2.710 2.640 2.775 2.304 2.217 2.008 2.021 2.439 14.00

4) T Chloromethane 2.264 2.451 2.134 2.479 1.886 1.856 1.705 1.417 2.024 18.46

5) T 1,2-Dichloro-1... 1.497 1.599 1.399 1.608 1.300 1.239 1.130 1.145 1.365 14.01

6) T Vinyl Chloride 1.944 2.067 1.935 2.354 1.932 1.837 1.590 1.724 1.923 11.87

7) T 1,3-Butadiene 1.398 1.658 1.540 1.879 1.613 1.601 1.356 1.591 1.579 10.22

8) T Bromomethane 1.064 1.115 1.033 1.200 1.009 1.020 0.855 0.972 1.034 9.80

9) T Chloroethane 0.895 1.019 1.147 1.304 1.047 0.956 0.863 0.908 1.017 14.60

10) T Ethanol 0.912 1.013 1.077 1.241 0.897 1.015 0.852 0.984 0.999 12.26

11) T Acetonitrile 2.831 2.578 3.028 3.326 2.392 2.476 2.291 2.398 2.665 13.64

12) T Acrolein 0.808 1.065 0.819 0.792 0.749 0.774 0.834 13.86

13) T Acetone 1.338 1.378 1.417 1.009 1.038 0.848 0.954 1.140 20.25

14) T Trichlorofluor... 2.258 2.108 2.233 1.882 1.785 1.552 1.726 1.935 13.97

15) T 2-Propanol (Is... 3.299 3.422 3.370 3.971 3.525 3.649 3.086 3.124 3.431 8.41

16) T Acrylonitrile 1.346 1.574 1.876 1.730 1.751 1.622 1.730 1.661 10.20

17) T 1,1-Dichloroet... 1.075 1.163 1.116 1.254 1.086 1.111 1.037 1.089 1.116 5.94

18) T 2-Methyl-2-Pro... 3.005 3.093 3.095 3.655 3.240 3.425 2.840 2.574 3.116 10.75

19) T Methylene Chlo... 1.407 1.300 1.264 1.379 1.181 1.170 1.094 1.173 1.246 8.85

20) T 3-Chloro-1-pro... 1.628 1.805 1.735 2.040 1.771 1.882 1.715 1.853 1.804 6.92

21) T Trichlorotrifl... 1.112 1.150 1.123 1.226 1.013 0.995 0.943 0.959 1.065 9.57

22) T Carbon Disulfide 4.699 5.041 4.116 4.120 3.842 3.968 4.298 10.89

23) T trans-1,2-Dich... 1.554 1.845 1.753 2.035 1.747 1.767 1.605 1.717 1.753 8.39

24) T 1,1-Dichloroet... 2.573 2.523 2.301 2.566 2.155 2.075 1.891 2.000 2.260 11.95

25) T Methyl tert-Bu... 3.769 3.908 3.779 4.262 3.653 3.604 3.162 3.283 3.678 9.42

26) T Vinyl Acetate 0.222 0.386 0.355 0.360 0.302 0.358 0.330 18.14

27) T 2-Butanone (MEK) 0.891 1.002 0.927 0.916 0.834 0.912 0.914 5.96

28) T cis-1,2-Dichlo... 1.918 1.791 1.761 2.012 1.712 1.702 1.505 1.650 1.756 8.93

29) T Diisopropyl Ether 1.302 1.339 1.352 1.534 1.296 1.164 0.951 1.117 1.257 14.04

30) T Ethyl Acetate 0.291 0.400 0.460 0.521 0.476 0.485 0.389 0.469 0.436 16.75

31) T n-Hexane 2.474 2.531 2.350 2.529 2.137 1.974 1.571 1.889 2.182 16.06

32) T Chloroform 2.252 2.256 2.167 2.418 2.030 1.991 1.731 1.905 2.094 10.59

33) S 1,2-Dichloroet... 1.621 1.638 1.633 1.616 1.615 1.604 1.422 1.615 1.595 4.45

34) T Tetrahydrofura... 0.695 0.774 0.850 0.981 0.862 0.854 0.791 0.845 0.832 9.93

35) T Ethyl tert-But... 1.412 1.546 1.571 1.723 1.529 1.577 1.433 1.566 1.545 6.20

36) T 1,2-Dichloroet... 1.848 1.893 1.759 1.997 1.650 1.599 1.310 1.492 1.694 13.35

37) IR 1,4-Difluorobenzen... ----------------ISTD---------------------

38) T 1,1,1-Trichlor... 0.439 0.447 0.407 0.474 0.402 0.412 0.364 0.395 0.417 8.21

39) T Isopropyl Acetate 0.156 0.168 0.179 0.210 0.191 0.204 0.170 0.197 0.184 10.37

40) T 1-Butanol 0.279 0.332 0.335 0.399 0.331 0.394 0.345 13.05

41) T Benzene 1.264 1.246 1.176 1.334 1.119 1.114 0.984 1.097 1.167 9.56

42) T Carbon Tetrach... 0.356 0.355 0.342 0.400 0.351 0.362 0.319 0.348 0.354 6.38

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43) T Cyclohexane 0.489 0.511 0.482 0.555 0.477 0.494 0.429 0.473 0.489 7.27

44) T tert-Amyl Meth... 0.740 0.797 0.782 0.863 0.782 0.846 0.772 0.830 0.801 5.19

45) T 1,2-Dichloropr... 0.292 0.299 0.298 0.326 0.277 0.276 0.253 0.267 0.286 7.89

46) T Bromodichlorom... 0.351 0.369 0.343 0.414 0.358 0.374 0.331 0.367 0.363 6.89

47) T Trichloroethene 0.326 0.317 0.299 0.406 0.295 0.291 0.267 0.289 0.311 13.64

48) T 1,4-Dioxane 0.237 0.228 0.269 0.235 0.251 0.232 0.258 0.244 6.31

49) T 2,2,4-Trimethy... 1.388 1.392 1.336 1.518 1.294 1.321 1.180 1.245 1.334 7.69

50) T Methyl Methacr... 0.108 0.131 0.120 0.126 0.116 0.125 0.121 6.84

51) T n-Heptane 0.295 0.315 0.313 0.360 0.301 0.291 0.261 0.282 0.302 9.63

52) T cis-1,3-Dichlo... 0.342 0.371 0.384 0.467 0.444 0.468 0.423 0.459 0.420 11.56

53) T 4-Methyl-2-pen... 0.220 0.247 0.308 0.287 0.301 0.269 0.295 0.275 11.59

54) T trans-1,3-Dich... 0.308 0.396 0.398 0.431 0.392 0.421 0.391 11.14

55) T 1,1,2-Trichlor... 0.257 0.267 0.268 0.300 0.257 0.262 0.243 0.257 0.264 6.26

56) IR Chlorobenzene-d5 (... ----------------ISTD---------------------

57) S Toluene-d8 (SS2) 2.486 2.492 2.467 2.445 2.434 2.401 2.431 2.335 2.436 2.09

58) T Toluene 3.022 2.895 2.704 2.992 2.494 2.458 2.271 2.266 2.638 11.72

59) T 2-Hexanone 1.355 1.735 1.571 1.589 1.389 1.475 1.519 9.31

60) T Dibromochlorom... 0.555 0.622 0.610 0.732 0.638 0.661 0.623 0.634 0.635 7.85

61) T 1,2-Dibromoethane 0.541 0.592 0.611 0.701 0.626 0.635 0.609 0.608 0.616 7.26

62) T n-Butyl Acetate 1.060 1.217 1.360 1.775 1.724 1.714 1.521 1.586 1.495 17.38

63) T n-Octane 0.554 0.580 0.589 0.652 0.567 0.565 0.511 0.549 0.571 7.09

64) T Tetrachloroethene 0.733 0.772 0.710 0.797 0.664 0.661 0.635 0.642 0.702 8.70

65) T Chlorobenzene 1.885 1.854 1.722 1.946 1.620 1.617 1.498 1.518 1.708 10.03

66) T Ethylbenzene 2.946 3.005 2.940 3.372 2.929 2.976 2.706 2.684 2.945 7.18

67) T m- & p-Xylenes 2.297 2.372 2.281 2.646 2.211 2.302 2.020 1.996 2.266 9.06

68) T Bromoform 0.429 0.490 0.457 0.575 0.522 0.573 0.559 0.562 0.521 10.85

69) T Styrene 1.363 1.442 1.545 1.941 1.728 1.844 1.705 1.659 1.653 11.83

70) T o-Xylene 2.257 2.387 2.290 2.640 2.249 2.343 2.079 2.022 2.283 8.33

71) T n-Nonane 1.308 1.370 1.408 1.618 1.394 1.409 1.206 1.183 1.362 10.01

72) T 1,1,2,2-Tetrac... 1.024 1.040 1.029 1.211 1.046 1.102 0.998 0.998 1.056 6.70

73) S Bromofluoroben... 0.716 0.720 0.727 0.721 0.734 0.734 0.767 0.773 0.737 2.96

74) T Cumene 3.053 3.057 2.964 3.443 2.911 2.979 2.682 2.519 2.951 9.28

75) T alpha-Pinene 1.307 1.393 1.400 1.584 1.461 1.552 1.434 1.418 1.444 6.17

76) T n-Propylbenzene 3.344 3.424 3.408 3.986 3.442 3.513 3.110 2.935 3.395 9.05

77) T 3-Ethyltoluene 2.678 2.980 2.794 3.275 2.889 2.956 2.747 2.478 2.850 8.31

78) T 4-Ethyltoluene 2.682 2.604 2.755 3.192 2.706 2.867 2.395 2.401 2.700 9.55

79) T 1,3,5-Trimethy... 2.481 2.489 2.404 2.837 2.400 2.488 2.224 2.132 2.432 8.62

80) T alpha-Methylst... 0.920 1.027 1.109 1.368 1.277 1.356 1.223 1.176 1.182 13.32

81) T 2-Ethyltoluene 2.872 3.000 2.879 3.318 2.827 2.923 2.568 2.428 2.852 9.43

82) T 1,2,4-Trimethy... 2.181 2.309 2.312 2.803 2.462 2.687 2.210 2.023 2.373 11.09

83) T n-Decane 0.039 0.052 0.071 0.063 0.065 0.056 0.056 0.058 17.99

84) T Benzyl Chloride 1.306 1.665 2.159 1.979 2.010 1.824 18.69

85) T 1,3-Dichlorobe... 1.277 1.297 1.248 1.532 1.330 1.416 1.264 1.209 1.321 7.96

86) T 1,4-Dichlorobe... 1.351 1.327 1.291 1.547 1.312 1.409 1.289 1.240 1.346 7.08

87) T sec-Butylbenzene 3.068 3.256 3.164 3.776 3.248 3.334 2.913 2.729 3.186 9.76

88) T 4-Isopropyltol... 2.848 2.953 3.003 3.602 3.140 3.328 2.647 2.299 2.978 13.47

89) T 1,2,3-Trimethy... 2.207 2.373 2.355 2.847 2.493 2.740 2.242 2.030 2.411 11.36

90) T 1,2-Dichlorobe... 1.240 1.309 1.265 1.479 1.281 1.399 1.190 1.083 1.281 9.49

91) T d-Limonene 0.855 0.920 1.148 1.073 1.179 0.987 0.916 1.011 12.31

92) T 1,2-Dibromo-3-... 0.304 0.345 0.388 0.473 0.473 0.502 0.494 0.482 0.433 17.59

93) T n-Undecane 1.598 1.503 1.488 1.313 1.224 1.425 10.71

94) T 1,2,4-Trichlor... 0.641 0.858 0.885 1.002 0.978 0.942 0.884 14.80

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95) T Naphthalene 2.224 2.580 2.689 2.969 3.621 3.158 2.858 2.871 15.52

96) T n-Dodecane 1.451 1.529 1.403 1.200 1.126 1.342 12.78

97) T Hexachlorobuta... 0.521 0.614 0.563 0.647 0.581 0.614 0.599 0.587 0.591 6.45

98) T Cyclohexanone 0.708 0.783 0.856 1.038 0.967 1.063 0.982 0.995 0.924 13.80

99) T tert-Butylbenzene 2.350 2.452 2.407 2.835 2.431 2.599 2.102 1.897 2.384 12.02

100) T n-Butylbenzene 2.119 2.310 2.421 2.947 2.639 2.721 2.369 2.179 2.463 11.53

----------------------------------------------------------------------------

(#) = Out of Range

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00915128

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Upd

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: 08/

22/1

8V

ersi

on: 0

99 of 142

00915129

anusha.bayyarapu

Anusha

1ng/

L St

d. ID

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2 of

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Upd

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: 08/

22/1

8V

ersi

on: 0

100 of 142

00915130

Calibration Status Report MS08

Method : I:\MS08\Methods\R8091218.M (RTE Integrator) Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) Last Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration

# ID Conc ISTD Path\File Conc -- ---- ---- ---- ------------------------------------------------- 1 0.1 0 13 I:\MS08\Data\2018_09\12\09121805.D 2 0.2 0 13 I:\MS08\Data\2018_09\12\09121806.D 3 0.5 1 13 I:\MS08\Data\2018_09\12\09121807.D 4 1.0 1 13 I:\MS08\Data\2018_09\12\09121808.D 5 5.0 5 13 I:\MS08\Data\2018_09\12\09121809.D 6 25 26 13 I:\MS08\Data\2018_09\12\09121810.D 7 50 52 13 I:\MS08\Data\2018_09\12\09121811.D 8 100 103 13 I:\MS08\Data\2018_09\12\09121812.D

# ID Update Time Quant Time Acquisition Time -- -- -------------------- ----------------- --------------------- 1 0.1 Sep 13 10:40 2018 Sep 13 10:35 2018 12 Sep 2018 12:35 2 0.2 Sep 13 10:40 2018 Sep 13 10:35 2018 12 Sep 2018 13:08 3 0.5 Sep 13 10:41 2018 Sep 13 10:35 2018 12 Sep 2018 13:41 4 1.0 Sep 13 10:41 2018 Sep 13 10:35 2018 12 Sep 2018 14:14 5 5.0 Sep 13 10:41 2018 Sep 13 10:35 2018 12 Sep 2018 14:47 6 25 Sep 13 10:43 2018 Sep 13 10:43 2018 12 Sep 2018 15:20 7 50 Sep 13 10:44 2018 Sep 13 10:44 2018 12 Sep 2018 15:53 8 100 Sep 13 10:44 2018 Sep 13 10:44 2018 12 Sep 2018 16:26

R8091218.M Thu Sep 13 15:04:49 2018

101 of 142

00915131

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Anusha

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121805.D Acq On : 12 Sep 2018 12:35 Operator: AB Sample : 0.1ng TO-15 ICAL Std. Misc : S31-09081801/S31-08201809 (9/18) ALS Vial : 14 Sample Multiplier: 1 Quant Time: Sep 13 10:35:45 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:35:17 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.28 130 127116 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 13.41 114 583702 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 257909 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 205992 12.697 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 101.60% 57) Toluene-d8 (SS2) 15.86 98 641050 12.753 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 102.00% 73) Bromofluorobenzene (SS3) 19.09 174 184622 12.147 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 97.20% Target Compounds Qvalue 2) Propene 4.26 42 1691 0.111 ng 99 3) Dichlorodifluoromethan... 4.41 85 3018 0.122 ng # 94 4) Chloromethane 4.70 50 2321 0.113 ng 88 5) 1,2-Dichloro-1,1,2,2-t... 4.95 135 1565 0.113 ng 81 6) Vinyl Chloride 5.12 62 2078 0.106 ng 89 7) 1,3-Butadiene 5.39 54 1491 0.093 ng 98 8) Bromomethane 5.82 94 1092 0.104 ng 99 9) Chloroethane 6.16 64 930 0.090 ng # 43 10) Ethanol 6.52 45 4766 0.469 ng 93 11) Acetonitrile 6.81 41 2974 0.110 ng # 59 12) Acrolein 6.99 56 403 0.054 ng # 50 13) Acetone 7.19 58 7855 0.656 ng # 73 14) Trichlorofluoromethane 7.42 101 2548 0.126 ng 97 15) 2-Propanol (Isopropanol) 7.72 45 6920 0.198 ng 98 16) Acrylonitrile 7.98 53 1230 0.076 ng # 54 17) 1,1-Dichloroethene 8.37 96 1174 0.103 ng 97 18) 2-Methyl-2-Propanol (t... 8.61 59 6551 0.207 ng 91 19) Methylene Chloride 8.58 84 1531 0.121 ng 99 20) 3-Chloro-1-propene (Al... 8.75 41 1766 0.096 ng 78 21) Trichlorotrifluoroethane 9.00 151 1204 0.111 ng 92 22) Carbon Disulfide 8.87 76 7374 0.153 ng 79 23) trans-1,2-Dichloroethene 9.86 61 1678 0.094 ng 86 24) 1,1-Dichloroethane 10.11 63 2695 0.117 ng 91 25) Methyl tert-Butyl Ether 10.27 73 4174 0.112 ng 89 26) Vinyl Acetate 10.37 86 623 0.215 ng # 1 27) 2-Butanone (MEK) 10.68 72 430 0.051 ng # 1 28) cis-1,2-Dichloroethene 11.12 61 2056 0.115 ng 81 29) Diisopropyl Ether 11.45 87 1431 0.112 ng # 94 30) Ethyl Acetate 11.45 61 642 0.145 ng 79 31) n-Hexane 11.40 57 2722 0.123 ng # 96 32) Chloroform 11.46 83 2466 0.116 ng 98 34) Tetrahydrofuran (THF) 11.94 72 755 0.089 ng # 72 35) Ethyl tert-Butyl Ether 12.03 87 1522 0.097 ng # 85 36) 1,2-Dichloroethane 12.26 62 1994 0.116 ng 91 38) 1,1,1-Trichloroethane 12.54 97 2215 0.114 ng 94 39) Isopropyl Acetate 12.99 61 1504 0.175 ng # 79 40) 1-Butanol 13.04 56 1634 0.113 ng 90 41) Benzene 13.02 78 6096 0.112 ng 98 42) Carbon Tetrachloride 13.18 117 1722 0.104 ng 99 43) Cyclohexane 13.32 84 4768 0.209 ng 93 44) tert-Amyl Methyl Ether 13.68 73 3709 0.099 ng 93 45) 1,2-Dichloropropane 13.87 63 1465 0.110 ng 89 46) Bromodichloromethane 14.07 83 1749 0.103 ng 98 47) Trichloroethene 14.11 130 1617 0.111 ng 97 48) 1,4-Dioxane 14.13 88 877 0.080 ng # 40 49) 2,2,4-Trimethylpentane... 14.18 57 6875 0.110 ng 96

R8091218.M Thu Sep 13 15:01:47 2018 Page: 1

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00915132

anusha.bayyarapu

Anusha

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121805.D Acq On : 12 Sep 2018 12:35 Operator: AB Sample : 0.1ng TO-15 ICAL Std. Misc : S31-09081801/S31-08201809 (9/18) ALS Vial : 14 Sample Multiplier: 1 Quant Time: Sep 13 10:35:45 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:35:17 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.34 100 598 0.117 ng # 32 51) n-Heptane 14.45 71 1481 0.105 ng 90 52) cis-1,3-Dichloropropene 15.00 75 1788 0.091 ng 85 53) 4-Methyl-2-pentanone 15.05 58 868 0.071 ng # 48 54) trans-1,3-Dichloropropene 15.52 75 943 0.058 ng # 43 55) 1,1,2-Trichloroethane 15.67 97 1290 0.105 ng 91 58) Toluene 15.96 91 6559 0.121 ng 94 59) 2-Hexanone 16.25 43 2033 0.071 ng # 66 60) Dibromochloromethane 16.37 129 1232 0.094 ng 96 61) 1,2-Dibromoethane 16.64 107 1202 0.095 ng 100 62) n-Butyl Acetate 16.86 43 2374 0.077 ng # 72 63) n-Octane 16.96 57 1229 0.104 ng 97 64) Tetrachloroethene 17.11 166 1601 0.111 ng 94 65) Chlorobenzene 17.76 112 4147 0.118 ng 99 66) Ethylbenzene 18.12 91 6278 0.103 ng 95 67) m- & p-Xylenes 18.28 91 10063 0.215 ng 95 68) Bromoform 18.34 173 940 0.087 ng 81 69) Styrene 18.61 104 2982 0.087 ng 92 70) o-Xylene 18.70 91 4946 0.105 ng 98 71) n-Nonane 18.88 43 2891 0.103 ng 94 72) 1,1,2,2-Tetrachloroethane 18.68 83 2248 0.103 ng 97 74) Cumene 19.22 105 6659 0.109 ng 96 75) alpha-Pinene 19.57 93 2791 0.094 ng 97 76) n-Propylbenzene 19.67 91 7425 0.106 ng 96 77) 3-Ethyltoluene 19.76 105 5867 0.100 ng 99 78) 4-Ethyltoluene 19.80 105 5871 0.105 ng 96 79) 1,3,5-Trimethylbenzene 19.86 105 5410 0.108 ng 92 80) alpha-Methylstyrene 20.00 118 2008 0.082 ng 83 81) 2-Ethyltoluene 20.03 105 6353 0.108 ng # 22 82) 1,2,4-Trimethylbenzene 20.22 105 4806 0.098 ng 96 83) n-Decane 20.22 58 106 0.064 ng # 1 84) Benzyl Chloride 20.35 91 1564 0.052 ng 70 85) 1,3-Dichlorobenzene 20.36 146 2845 0.104 ng # 60 86) 1,4-Dichlorobenzene 20.42 146 3013 0.109 ng 92 87) sec-Butylbenzene 20.46 105 6728 0.102 ng 97 88) 4-Isopropyltoluene (p-... 20.60 119 6124 0.100 ng 94 89) 1,2,3-Trimethylbenzene 20.60 105 4744 0.095 ng 95 90) 1,2-Dichlorobenzene 20.72 146 2787 0.105 ng 92 91) d-Limonene 20.72 68 1441 0.072 ng 93 92) 1,2-Dibromo-3-Chloropr... 21.10 157 654 0.073 ng # 73 93) n-Undecane 21.41 57 1262 0.053 ng 83 94) 1,2,4-Trichlorobenzene 22.24 180 1142 0.069 ng # 86 95) Naphthalene 22.35 128 4022 0.071 ng # 71 96) n-Dodecane 22.33 57 106 0.006 ng # 30 97) Hexachlorobutadiene 22.66 225 1131 0.093 ng 86 98) Cyclohexanone 18.42 55 1434 0.075 ng # 86 99) tert-Butylbenzene 20.22 119 5174 0.105 ng 96 100) n-Butylbenzene 20.97 91 4652 0.092 ng 91 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Thu Sep 13 15:01:47 2018 Page: 2

103 of 142

00915133


Data File: I:\MS08\Data\2018_09\12\09121805.D Acq On : 12 Sep 2018 12:35 Operator: AB Sample : 0.1ng TO-15 ICAL Std. Misc : S31-09081801/S31-08201809 (9/18) ALS Vial : 14 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

800000

850000

900000

950000

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

tert-

Buty

lben

zene

,T1,

2,4-

Trim

ethy

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

1,4-

Dio

xane

,TTr

ichl

oroe

then

e,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

T1-

Buta

nol,T

Benz

ene,

TIs

opro

pyl A

ceta

te,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,T

Chl

orof

orm

,TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,T2-

Met

hyl-2

-Pro

pano

l (te

rt-Bu

tyl A

lcoh

ol,T

Met

hyle

ne C

hlor

ide,

T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R8091218.M Thu Sep 13 15:01:48 2018 Page: 3

104 of 142

00915134




19.30 19.40 19.50 19.60 19.70 19.80 19.90 20.00 20.10 20.20 20.30 20.40 20.50 20.60 20.70 20.80 20.90 21.00 21.10 21.20

0

200

400

600

800

1000

Time-->


20.224

|

|

|

|

|

| |||||

|

Ion 71.10 (70.80 to 71.80): 09121805.D\data.msIon 85.10 (84.80 to 85.80): 09121805.D\data.ms

30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150

1000

2000

3000

m/z-->


91

1347741 51 1156358

30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150

5000

m/z-->


7185

3999 1429153 11365 12662 77 8149


0.00 0.00 0.00

85.10 653.30 0.00#

71.10 901.50 0.00#

58.10 100 100

Ion Exp% Act%

response 106

20.224min (-0.081) 0.06ng

(83) n-Decane (T)

R8091218.M Thu Sep 13 10:38:26 2018 Page: 1

105 of 142

00915135




19.40 19.50 19.60 19.70 19.80 19.90 20.00 20.10 20.20 20.30 20.40 20.50 20.60 20.70 20.80 20.90 21.00 21.10 21.20

0

200

400

600

800

1000

Time-->


|||||

|

Ion 71.10 (70.80 to 71.80): 09121805.D\data.msIon 85.10 (84.80 to 85.80): 09121805.D\data.ms

30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150

200

250

m/z-->

Abundance Scan 3061 (20.267 min): 09121805.D\data.ms

44

30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150

5000

m/z-->


7185

3999 1429153 11365 12662 77 8149


0.00 0.00 0.00

85.10 653.30 0.00#

71.10 901.50 0.00#

58.10 100 0.00

Ion Exp% Act%

response 0

20.267min (-0.038) 0.00ng m

(83) n-Decane (T)

R8091218.M Thu Sep 13 10:38:41 2018 Page: 1

106 of 142

00915136

anusha.bayyarapu

Anusha

anusha.bayyarapu

WP

widayati.ang

Wida

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121806.D Acq On : 12 Sep 2018 13:08 Operator: AB Sample : 0.2ng TO-15 ICAL Std. Misc : S31-09081801/S31-08201809 (9/18) ALS Vial : 14 Sample Multiplier: 1 Quant Time: Sep 13 10:35:48 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:35:17 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.28 130 128159 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 13.41 114 588731 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 262343 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 209882 12.831 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 102.64% 57) Toluene-d8 (SS2) 15.86 98 653766 12.787 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 102.32% 73) Bromofluorobenzene (SS3) 19.09 174 188840 12.214 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 97.68% Target Compounds Qvalue 2) Propene 4.26 42 3348 0.217 ng 93 3) Dichlorodifluoromethan... 4.40 85 5808 0.232 ng 96 4) Chloromethane 4.70 50 5066 0.244 ng 96 5) 1,2-Dichloro-1,1,2,2-t... 4.95 135 3371 0.241 ng 94 6) Vinyl Chloride 5.11 62 4454 0.226 ng 91 7) 1,3-Butadiene 5.38 54 3567 0.220 ng 95 8) Bromomethane 5.81 94 2307 0.218 ng 91 9) Chloroethane 6.15 64 2135 0.205 ng 89 10) Ethanol 6.50 45 10680 1.043 ng 90 11) Acetonitrile 6.78 41 5460 0.200 ng # 70 12) Acrolein 6.98 56 1107 0.146 ng # 73 13) Acetone 7.19 58 14737 1.221 ng 96 14) Trichlorofluoromethane 7.40 101 4907 0.241 ng 98 15) 2-Propanol (Isopropanol) 7.70 45 14475 0.412 ng 89 16) Acrylonitrile 7.94 53 2853 0.174 ng 100 17) 1,1-Dichloroethene 8.37 96 2561 0.224 ng 99 18) 2-Methyl-2-Propanol (t... 8.59 59 13598 0.426 ng 96 19) Methylene Chloride 8.58 84 2852 0.223 ng 93 20) 3-Chloro-1-propene (Al... 8.74 41 3949 0.214 ng 82 21) Trichlorotrifluoroethane 9.01 151 2512 0.230 ng 95 22) Carbon Disulfide 8.87 76 11987 0.246 ng 93 23) trans-1,2-Dichloroethene 9.85 61 4018 0.224 ng 90 24) 1,1-Dichloroethane 10.10 63 5328 0.230 ng 96 25) Methyl tert-Butyl Ether 10.25 73 8727 0.231 ng 96 26) Vinyl Acetate 10.37 86 1927 0.660 ng # 33 27) 2-Butanone (MEK) 10.66 72 1466 0.174 ng # 32 28) cis-1,2-Dichloroethene 11.12 61 3870 0.215 ng 99 29) Diisopropyl Ether 11.43 87 2969 0.230 ng # 76 30) Ethyl Acetate 11.44 61 1775 0.397 ng 87 31) n-Hexane 11.41 57 5615 0.251 ng 96 32) Chloroform 11.46 83 4982 0.232 ng 98 34) Tetrahydrofuran (THF) 11.92 72 1696 0.199 ng # 75 35) Ethyl tert-Butyl Ether 12.03 87 3361 0.212 ng 92 36) 1,2-Dichloroethane 12.27 62 4118 0.237 ng 93 38) 1,1,1-Trichloroethane 12.54 97 4551 0.231 ng 99 39) Isopropyl Acetate 12.99 61 3268 0.376 ng # 85 40) 1-Butanol 13.03 56 4627 0.317 ng 90 41) Benzene 13.02 78 12121 0.221 ng 100 42) Carbon Tetrachloride 13.18 117 3466 0.208 ng 100 43) Cyclohexane 13.31 84 10036 0.436 ng 97 44) tert-Amyl Methyl Ether 13.67 73 8064 0.214 ng 94 45) 1,2-Dichloropropane 13.87 63 3019 0.224 ng 97 46) Bromodichloromethane 14.06 83 3709 0.217 ng 97 47) Trichloroethene 14.12 130 3170 0.216 ng 99 48) 1,4-Dioxane 14.13 88 2376 0.214 ng 91 49) 2,2,4-Trimethylpentane... 14.18 57 13908 0.221 ng 99

R8091218.M Thu Sep 13 15:01:49 2018 Page: 1

107 of 142

00915137

anusha.bayyarapu

Anusha

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121806.D Acq On : 12 Sep 2018 13:08 Operator: AB Sample : 0.2ng TO-15 ICAL Std. Misc : S31-09081801/S31-08201809 (9/18) ALS Vial : 14 Sample Multiplier: 1 Quant Time: Sep 13 10:35:48 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:35:17 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.32 100 1789 0.348 ng # 84 51) n-Heptane 14.45 71 3197 0.225 ng 94 52) cis-1,3-Dichloropropene 14.98 75 3910 0.198 ng 94 53) 4-Methyl-2-pentanone 15.04 58 2197 0.177 ng # 67 54) trans-1,3-Dichloropropene 15.51 75 2604 0.158 ng 87 55) 1,1,2-Trichloroethane 15.68 97 2710 0.218 ng 96 58) Toluene 15.96 91 12784 0.231 ng 97 59) 2-Hexanone 16.23 43 4966 0.170 ng 97 60) Dibromochloromethane 16.37 129 2808 0.211 ng 91 61) 1,2-Dibromoethane 16.63 107 2673 0.207 ng 97 62) n-Butyl Acetate 16.86 43 5544 0.177 ng 89 63) n-Octane 16.97 57 2619 0.219 ng 98 64) Tetrachloroethene 17.10 166 3427 0.233 ng 92 65) Chlorobenzene 17.76 112 8297 0.232 ng 97 66) Ethylbenzene 18.11 91 13031 0.211 ng 100 67) m- & p-Xylenes 18.27 91 21138 0.445 ng 97 68) Bromoform 18.34 173 2185 0.200 ng 92 69) Styrene 18.60 104 6415 0.185 ng 98 70) o-Xylene 18.70 91 10642 0.222 ng 97 71) n-Nonane 18.89 43 6161 0.216 ng 98 72) 1,1,2,2-Tetrachloroethane 18.67 83 4645 0.210 ng 99 74) Cumene 19.22 105 13561 0.219 ng 99 75) alpha-Pinene 19.57 93 6051 0.200 ng 100 76) n-Propylbenzene 19.67 91 15463 0.217 ng 97 77) 3-Ethyltoluene 19.76 105 13282 0.222 ng 99 78) 4-Ethyltoluene 19.79 105 11598 0.205 ng 99 79) 1,3,5-Trimethylbenzene 19.86 105 11044 0.216 ng 96 80) alpha-Methylstyrene 20.00 118 4562 0.184 ng 89 81) 2-Ethyltoluene 20.03 105 13497 0.226 ng # 17 82) 1,2,4-Trimethylbenzene 20.22 105 10351 0.208 ng 98 83) n-Decane 20.31 58 176 0.104 ng # 19 84) Benzyl Chloride 20.34 91 3360 0.110 ng 86 85) 1,3-Dichlorobenzene 20.36 146 5879 0.212 ng # 67 86) 1,4-Dichlorobenzene 20.41 146 6023 0.213 ng 99 87) sec-Butylbenzene 20.46 105 14528 0.217 ng 98 88) 4-Isopropyltoluene (p-... 20.60 119 12914 0.207 ng 98 89) 1,2,3-Trimethylbenzene 20.60 105 10377 0.205 ng 98 90) 1,2-Dichlorobenzene 20.72 146 5983 0.223 ng 95 91) d-Limonene 20.72 68 3625 0.178 ng 99 92) 1,2-Dibromo-3-Chloropr... 21.10 157 1507 0.166 ng # 79 93) n-Undecane 21.40 57 3258 0.134 ng 95 94) 1,2,4-Trichlorobenzene 22.23 180 2717 0.161 ng 96 95) Naphthalene 22.34 128 9568 0.166 ng 90 96) n-Dodecane 22.34 57 682 0.036 ng # 61 97) Hexachlorobutadiene 22.66 225 2715 0.219 ng 97 98) Cyclohexanone 18.42 55 3228 0.166 ng 96 99) tert-Butylbenzene 20.22 119 10982 0.219 ng 99 100) n-Butylbenzene 20.97 91 10316 0.200 ng 94 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Thu Sep 13 15:01:49 2018 Page: 2

108 of 142

00915138




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

800000

850000

900000

950000

1000000

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

1,4-

Dio

xane

,TTr

ichl

oroe

then

e,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

T1-

Buta

nol,T

Benz

ene,

TIs

opro

pyl A

ceta

te,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,T

Chl

orof

orm

,TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,T2-

Met

hyl-2

-Pro

pano

l (te

rt-Bu

tyl A

lcoh

ol,T

Met

hyle

ne C

hlor

ide,

T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R8091218.M Thu Sep 13 15:01:50 2018 Page: 3

109 of 142

00915139

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121807.D Acq On : 12 Sep 2018 13:41 Operator: AB Sample : 0.5ng TO-15 ICAL Std. Misc : S31-09081801/S31-08201809 (9/18) ALS Vial : 14 Sample Multiplier: 1 Quant Time: Sep 13 10:35:50 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:35:17 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.28 130 137919 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 13.41 114 633533 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 284667 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 225258 12.797 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 102.40% 57) Toluene-d8 (SS2) 15.86 98 702139 12.656 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 101.28% 73) Bromofluorobenzene (SS3) 19.09 174 206892 12.333 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 98.64% Target Compounds Qvalue 2) Propene 4.24 42 8416 0.507 ng 97 3) Dichlorodifluoromethan... 4.39 85 15220 0.566 ng 99 4) Chloromethane 4.68 50 11867 0.531 ng 96 5) 1,2-Dichloro-1,1,2,2-t... 4.94 135 7936 0.527 ng 100 6) Vinyl Chloride 5.10 62 11219 0.529 ng 95 7) 1,3-Butadiene 5.37 54 8912 0.511 ng 98 8) Bromomethane 5.80 94 5751 0.504 ng 95 9) Chloroethane 6.14 64 6469 0.576 ng 96 10) Ethanol 6.47 45 30529 2.771 ng 99 11) Acetonitrile 6.76 41 17256 0.587 ng 86 12) Acrolein 6.96 56 4583 0.562 ng 88 13) Acetone 7.17 58 40822 3.142 ng 97 14) Trichlorofluoromethane 7.40 101 12329 0.562 ng 98 15) 2-Propanol (Isopropanol) 7.66 45 38353 1.013 ng 89 16) Acrylonitrile 7.93 53 8981 0.509 ng 97 17) 1,1-Dichloroethene 8.36 96 6613 0.537 ng 95 18) 2-Methyl-2-Propanol (t... 8.56 59 36603 1.065 ng 95 19) Methylene Chloride 8.58 84 7462 0.543 ng 100 20) 3-Chloro-1-propene (Al... 8.74 41 10210 0.513 ng 94 21) Trichlorotrifluoroethane 9.00 151 6597 0.561 ng 98 22) Carbon Disulfide 8.86 76 27865 0.532 ng 94 23) trans-1,2-Dichloroethene 9.85 61 10273 0.531 ng 96 24) 1,1-Dichloroethane 10.09 63 13077 0.524 ng 98 25) Methyl tert-Butyl Ether 10.23 73 22704 0.560 ng 98 26) Vinyl Acetate 10.36 86 6424 2.045 ng # 73 27) 2-Butanone (MEK) 10.64 72 5046 0.555 ng # 86 28) cis-1,2-Dichloroethene 11.12 61 10240 0.528 ng 96 29) Diisopropyl Ether 11.42 87 8063 0.581 ng # 84 30) Ethyl Acetate 11.43 61 5496 1.141 ng 97 31) n-Hexane 11.40 57 14025 0.583 ng 97 32) Chloroform 11.45 83 12875 0.557 ng 100 34) Tetrahydrofuran (THF) 11.90 72 5010 0.546 ng 94 35) Ethyl tert-Butyl Ether 12.02 87 9188 0.539 ng 96 36) 1,2-Dichloroethane 12.26 62 10298 0.551 ng 99 38) 1,1,1-Trichloroethane 12.54 97 11144 0.527 ng 98 39) Isopropyl Acetate 12.98 61 9385 1.004 ng # 98 40) 1-Butanol 13.00 56 14611 0.931 ng # 73 41) Benzene 13.02 78 30788 0.521 ng 98 42) Carbon Tetrachloride 13.18 117 8980 0.500 ng 97 43) Cyclohexane 13.31 84 25468 1.028 ng 97 44) tert-Amyl Methyl Ether 13.67 73 21285 0.524 ng 95 45) 1,2-Dichloropropane 13.87 63 8101 0.559 ng 95 46) Bromodichloromethane 14.06 83 9287 0.504 ng 100 47) Trichloroethene 14.11 130 8036 0.510 ng 99 48) 1,4-Dioxane 14.11 88 6143 0.514 ng 98 49) 2,2,4-Trimethylpentane... 14.18 57 35926 0.531 ng 97

R8091218.M Thu Sep 13 15:01:52 2018 Page: 1

110 of 142

00915140

anusha.bayyarapu

Anusha

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121807.D Acq On : 12 Sep 2018 13:41 Operator: AB Sample : 0.5ng TO-15 ICAL Std. Misc : S31-09081801/S31-08201809 (9/18) ALS Vial : 14 Sample Multiplier: 1 Quant Time: Sep 13 10:35:50 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:35:17 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.32 100 5829 1.053 ng 100 51) n-Heptane 14.44 71 8539 0.557 ng 97 52) cis-1,3-Dichloropropene 14.98 75 10902 0.512 ng 96 53) 4-Methyl-2-pentanone 15.03 58 6642 0.499 ng 87 54) trans-1,3-Dichloropropene 15.51 75 8237 0.464 ng 99 55) 1,1,2-Trichloroethane 15.67 97 7319 0.547 ng 96 58) Toluene 15.96 91 32391 0.539 ng 98 59) 2-Hexanone 16.22 43 16568 0.523 ng 93 60) Dibromochloromethane 16.37 129 7466 0.517 ng 99 61) 1,2-Dibromoethane 16.63 107 7490 0.534 ng 99 62) n-Butyl Acetate 16.84 43 16798 0.493 ng 96 63) n-Octane 16.96 57 7221 0.555 ng 98 64) Tetrachloroethene 17.11 166 8556 0.535 ng 97 65) Chlorobenzene 17.76 112 20904 0.538 ng 99 66) Ethylbenzene 18.11 91 34577 0.516 ng 99 67) m- & p-Xylenes 18.27 91 55142 1.069 ng 97 68) Bromoform 18.34 173 5532 0.466 ng 98 69) Styrene 18.59 104 18643 0.495 ng 99 70) o-Xylene 18.70 91 27695 0.533 ng 98 71) n-Nonane 18.88 43 17176 0.554 ng 96 72) 1,1,2,2-Tetrachloroethane 18.68 83 12466 0.518 ng 99 74) Cumene 19.22 105 35677 0.531 ng 100 75) alpha-Pinene 19.57 93 16503 0.502 ng 95 76) n-Propylbenzene 19.66 91 41759 0.540 ng 98 77) 3-Ethyltoluene 19.76 105 33788 0.521 ng 96 78) 4-Ethyltoluene 19.79 105 33285 0.541 ng 94 79) 1,3,5-Trimethylbenzene 19.86 105 28937 0.523 ng 98 80) alpha-Methylstyrene 19.99 118 13357 0.496 ng 90 81) 2-Ethyltoluene 20.03 105 35137 0.541 ng # 16 82) 1,2,4-Trimethylbenzene 20.22 105 28122 0.520 ng 99 83) n-Decane 20.31 58 637 0.346 ng # 84 84) Benzyl Chloride 20.34 91 11998 0.363 ng 93 85) 1,3-Dichlorobenzene 20.35 146 15347 0.510 ng # 66 86) 1,4-Dichlorobenzene 20.41 146 15897 0.519 ng 97 87) sec-Butylbenzene 20.46 105 38298 0.528 ng 99 88) 4-Isopropyltoluene (p-... 20.60 119 35634 0.526 ng 98 89) 1,2,3-Trimethylbenzene 20.60 105 27947 0.509 ng 98 90) 1,2-Dichlorobenzene 20.71 146 15688 0.538 ng 96 91) d-Limonene 20.72 68 10576 0.478 ng 99 92) 1,2-Dibromo-3-Chloropr... 21.10 157 4606 0.467 ng 85 93) n-Undecane 21.40 57 10038 0.380 ng 99 94) 1,2,4-Trichlorobenzene 22.23 180 7770 0.424 ng 98 95) Naphthalene 22.34 128 30109 0.481 ng 97 96) n-Dodecane 22.32 57 2618 0.129 ng 92 97) Hexachlorobutadiene 22.65 225 6745 0.501 ng 95 98) Cyclohexanone 18.41 55 9573 0.455 ng 96 99) tert-Butylbenzene 20.22 119 29242 0.539 ng 99 100) n-Butylbenzene 20.96 91 29326 0.523 ng 97 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Thu Sep 13 15:01:52 2018 Page: 2

111 of 142

00915141




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250000

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400000

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Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

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zene

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ane,

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3-C

hlor

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pane

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Buty

lben

zene

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onen

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hlor

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ene

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ymen

e),T

sec-

Buty

lben

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ichl

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enze

ne,T

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hlor

oben

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nzyl

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e,T

n-D

ecan

e,T1

,2,4

-Trim

ethy

lben

zene

,Tte

rt-Bu

tylb

enze

ne,T

2-Et

hylto

luen

e,T

alph

a-M

ethy

lsty

rene

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ethy

lben

zene

,T4-

Ethy

ltolu

ene,

T3-

Ethy

ltolu

ene,

Tn-

Prop

ylbe

nzen

e,T

alph

a-Pi

nene

,TC

umen

e,T

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oflu

orob

enze

ne (S

S3),S

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o-Xy

lene

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1,2,

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trach

loro

etha

ne,T

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ene,

TC

yclo

hexa

none

,TBr

omof

orm

,Tm

- & p

-Xyl

enes

,TEt

hylb

enze

ne,T

Chl

orob

enze

ne,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

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Buty

l Ace

tate

,T1,

2-D

ibro

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than

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rom

ochl

orom

etha

ne,T

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exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

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ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

1,4-

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xane

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ichl

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odic

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omet

hane

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orop

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ne,T

tert-

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yl M

ethy

l Eth

er,T

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uoro

benz

ene

(IS2)

,IRC

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ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T

1-Bu

tano

l,TIs

opro

pyl A

ceta

te,T

1,1,

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than

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hlor

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ane,

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e-d4

(SS1

),SEt

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ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,T

Chl

orof

orm

,TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

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Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

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hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

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hlor

o-1,

1,2,

2-te

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oroe

than

e ,T

Chl

orom

etha

ne,T

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hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R8091218.M Thu Sep 13 15:01:52 2018 Page: 3

112 of 142

00915142

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121808.D Acq On : 12 Sep 2018 14:14 Operator: AB Sample : 1.0ng TO-15 ICAL Std. Misc : S31-09081801/S31-08231804 (9/21) ALS Vial : 15 Sample Multiplier: 1 Quant Time: Sep 13 10:35:52 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:35:17 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.29 130 128496 12.500 ng -0.01 37) 1,4-Difluorobenzene (IS2) 13.41 114 576853 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 259895 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 207637 12.661 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 101.28% 57) Toluene-d8 (SS2) 15.86 98 635317 12.543 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 100.32% 73) Bromofluorobenzene (SS3) 19.09 174 187487 12.241 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 97.92% Target Compounds Qvalue 2) Propene 4.24 42 18145 1.173 ng 99 3) Dichlorodifluoromethan... 4.40 85 29807 1.189 ng 99 4) Chloromethane 4.68 50 25688 1.235 ng 97 5) 1,2-Dichloro-1,1,2,2-t... 4.94 135 16991 1.211 ng 98 6) Vinyl Chloride 5.10 62 25431 1.287 ng 98 7) 1,3-Butadiene 5.37 54 20265 1.248 ng 99 8) Bromomethane 5.80 94 12451 1.172 ng 100 9) Chloroethane 6.14 64 13698 1.310 ng 97 10) Ethanol 6.48 45 65545 6.385 ng 99 11) Acetonitrile 6.75 41 35314 1.289 ng 91 12) Acrolein 6.96 56 11253 1.480 ng 97 13) Acetone 7.16 58 78203 6.461 ng 98 14) Trichlorofluoromethane 7.40 101 24333 1.190 ng 100 15) 2-Propanol (Isopropanol) 7.65 45 84221 2.388 ng 93 16) Acrylonitrile 7.92 53 19943 1.213 ng 98 17) 1,1-Dichloroethene 8.37 96 13843 1.206 ng 93 18) 2-Methyl-2-Propanol (t... 8.53 59 80551 2.515 ng 96 19) Methylene Chloride 8.58 84 15167 1.184 ng 97 20) 3-Chloro-1-propene (Al... 8.74 41 22375 1.207 ng 94 21) Trichlorotrifluoroethane 9.00 151 13421 1.226 ng 99 22) Carbon Disulfide 8.86 76 55708 1.142 ng 97 23) trans-1,2-Dichloroethene 9.85 61 22219 1.233 ng 96 24) 1,1-Dichloroethane 10.10 63 27166 1.169 ng 100 25) Methyl tert-Butyl Ether 10.22 73 47711 1.262 ng 99 26) Vinyl Acetate 10.36 86 20834 7.118 ng # 80 27) 2-Butanone (MEK) 10.62 72 10580 1.249 ng # 90 28) cis-1,2-Dichloroethene 11.12 61 21799 1.207 ng 95 29) Diisopropyl Ether 11.42 87 17045 1.319 ng # 86 30) Ethyl Acetate 11.42 61 11609 2.588 ng 98 31) n-Hexane 11.40 57 28134 1.254 ng 96 32) Chloroform 11.46 83 26775 1.244 ng 100 34) Tetrahydrofuran (THF) 11.89 72 10769 1.260 ng 96 35) Ethyl tert-Butyl Ether 12.02 87 18771 1.182 ng 97 36) 1,2-Dichloroethane 12.26 62 21776 1.251 ng 97 38) 1,1,1-Trichloroethane 12.54 97 23640 1.227 ng 97 39) Isopropyl Acetate 12.97 61 20016 2.352 ng # 99 40) 1-Butanol 12.99 56 31627 2.214 ng # 76 41) Benzene 13.02 78 63582 1.181 ng 98 42) Carbon Tetrachloride 13.18 117 19127 1.170 ng 99 43) Cyclohexane 13.31 84 53424 2.369 ng 99 44) tert-Amyl Methyl Ether 13.66 73 42797 1.157 ng 96 45) 1,2-Dichloropropane 13.87 63 16165 1.224 ng 97 46) Bromodichloromethane 14.06 83 20422 1.218 ng 97 47) Trichloroethene 14.11 130 19911 1.387 ng 98 48) 1,4-Dioxane 14.10 88 13230 1.215 ng 97 49) 2,2,4-Trimethylpentane... 14.18 57 74323 1.207 ng 96

R8091218.M Thu Sep 13 15:01:54 2018 Page: 1

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00915143

anusha.bayyarapu

Anusha

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121808.D Acq On : 12 Sep 2018 14:14 Operator: AB Sample : 1.0ng TO-15 ICAL Std. Misc : S31-09081801/S31-08231804 (9/21) ALS Vial : 15 Sample Multiplier: 1 Quant Time: Sep 13 10:35:52 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:35:17 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.32 100 12884 2.556 ng 99 51) n-Heptane 14.44 71 17874 1.281 ng 99 52) cis-1,3-Dichloropropene 14.98 75 24163 1.247 ng 99 53) 4-Methyl-2-pentanone 15.02 58 15058 1.242 ng 90 54) trans-1,3-Dichloropropene 15.50 75 19282 1.194 ng 97 55) 1,1,2-Trichloroethane 15.67 97 14876 1.222 ng 99 58) Toluene 15.96 91 65444 1.193 ng 99 59) 2-Hexanone 16.21 43 38743 1.339 ng 94 60) Dibromochloromethane 16.37 129 16364 1.240 ng 95 61) 1,2-Dibromoethane 16.63 107 15685 1.226 ng 97 62) n-Butyl Acetate 16.84 43 40050 1.289 ng 99 63) n-Octane 16.96 57 14593 1.229 ng 99 64) Tetrachloroethene 17.10 166 17531 1.201 ng 100 65) Chlorobenzene 17.76 112 43122 1.215 ng 100 66) Ethylbenzene 18.11 91 72424 1.183 ng 98 67) m- & p-Xylenes 18.27 91 116811 2.480 ng 97 68) Bromoform 18.34 173 12712 1.174 ng 98 69) Styrene 18.59 104 42769 1.244 ng 99 70) o-Xylene 18.70 91 58292 1.228 ng 98 71) n-Nonane 18.89 43 36028 1.272 ng 98 72) 1,1,2,2-Tetrachloroethane 18.68 83 26787 1.220 ng 99 74) Cumene 19.22 105 75657 1.233 ng 97 75) alpha-Pinene 19.57 93 34091 1.136 ng 99 76) n-Propylbenzene 19.67 91 89178 1.263 ng 99 77) 3-Ethyltoluene 19.76 105 72324 1.221 ng 100 78) 4-Ethyltoluene 19.79 105 70419 1.254 ng 100 79) 1,3,5-Trimethylbenzene 19.86 105 62338 1.233 ng 97 80) alpha-Methylstyrene 19.99 118 30084 1.224 ng 91 81) 2-Ethyltoluene 20.03 105 73946 1.247 ng # 14 82) 1,2,4-Trimethylbenzene 20.22 105 62233 1.261 ng 98 83) n-Decane 20.31 58 1588 0.946 ng 99 84) Benzyl Chloride 20.34 91 28533 0.946 ng 96 85) 1,3-Dichlorobenzene 20.35 146 34395 1.252 ng # 64 86) 1,4-Dichlorobenzene 20.41 146 34778 1.243 ng 97 87) sec-Butylbenzene 20.46 105 83453 1.260 ng 98 88) 4-Isopropyltoluene (p-... 20.60 119 78035 1.260 ng 98 89) 1,2,3-Trimethylbenzene 20.60 105 61687 1.231 ng 98 90) 1,2-Dichlorobenzene 20.71 146 33482 1.257 ng 98 91) d-Limonene 20.72 68 24103 1.194 ng 100 92) 1,2-Dibromo-3-Chloropr... 21.10 157 10245 1.139 ng 85 93) n-Undecane 21.40 57 35125 1.458 ng 99 94) 1,2,4-Trichlorobenzene 22.23 180 18973 1.135 ng 98 95) Naphthalene 22.33 128 57305 1.002 ng 99 96) n-Dodecane 22.32 57 31107 1.677 ng 98 97) Hexachlorobutadiene 22.66 225 14164 1.153 ng 99 98) Cyclohexanone 18.41 55 21189 1.103 ng 97 99) tert-Butylbenzene 20.22 119 62892 1.269 ng 99 100) n-Butylbenzene 20.96 91 65188 1.273 ng 98 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Thu Sep 13 15:01:54 2018 Page: 2

114 of 142

00915144




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

800000

850000

900000

950000

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T

1-Bu

tano

l,TIs

opro

pyl A

ceta

te,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,T

Chl

orof

orm

,TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R8091218.M Thu Sep 13 15:01:55 2018 Page: 3

115 of 142

00915145

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121809.D Acq On : 12 Sep 2018 14:47 Operator: AB Sample : 5.0ng TO-15 ICAL Std. Misc : S31-09081801/S31-08231804 (9/21) ALS Vial : 15 Sample Multiplier: 1 Quant Time: Sep 13 10:35:54 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:35:17 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.29 130 142125 12.500 ng 0.00 37) 1,4-Difluorobenzene (IS2) 13.41 114 636454 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 292297 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 229550 12.655 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 101.20% 57) Toluene-d8 (SS2) 15.86 98 711320 12.487 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 99.92% 73) Bromofluorobenzene (SS3) 19.09 174 214672 12.462 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 99.68% Target Compounds Qvalue 2) Propene 4.22 42 83625 4.889 ng 98 3) Dichlorodifluoromethan... 4.38 85 136887 4.936 ng 99 4) Chloromethane 4.66 50 108076 4.696 ng 100 5) 1,2-Dichloro-1,1,2,2-t... 4.93 135 75957 4.895 ng 99 6) Vinyl Chloride 5.08 62 115442 5.280 ng 100 7) 1,3-Butadiene 5.36 54 96215 5.358 ng 98 8) Bromomethane 5.79 94 57886 4.925 ng 98 9) Chloroethane 6.12 64 60848 5.260 ng 100 10) Ethanol 6.49 45 261992 23.075 ng 99 11) Acetonitrile 6.75 41 140460 4.636 ng 98 12) Acrolein 6.95 56 47879 5.693 ng 99 13) Acetone 7.16 58 307931 23.000 ng 91 14) Trichlorofluoromethane 7.39 101 113437 5.017 ng 99 15) 2-Propanol (Isopropanol) 7.64 45 413442 10.599 ng 97 16) Acrylonitrile 7.91 53 101696 5.591 ng 99 17) 1,1-Dichloroethene 8.36 96 66305 5.223 ng 94 18) 2-Methyl-2-Propanol (t... 8.52 59 394872 11.146 ng 98 19) Methylene Chloride 8.58 84 71859 5.072 ng 98 20) 3-Chloro-1-propene (Al... 8.74 41 107404 5.238 ng 97 21) Trichlorotrifluoroethane 9.00 151 61303 5.063 ng 99 22) Carbon Disulfide 8.85 76 251551 4.662 ng 99 23) trans-1,2-Dichloroethene 9.85 61 105484 5.293 ng 98 24) 1,1-Dichloroethane 10.11 63 126169 4.909 ng 100 25) Methyl tert-Butyl Ether 10.21 73 226152 5.409 ng 100 26) Vinyl Acetate 10.35 86 106035 32.752 ng # 83 27) 2-Butanone (MEK) 10.61 72 54124 5.778 ng 94 28) cis-1,2-Dichloroethene 11.12 61 102611 5.138 ng 97 29) Diisopropyl Ether 11.41 87 79625 5.572 ng # 83 30) Ethyl Acetate 11.42 61 58627 11.816 ng 100 31) n-Hexane 11.40 57 131471 5.299 ng 98 32) Chloroform 11.46 83 124284 5.221 ng 100 34) Tetrahydrofuran (THF) 11.88 72 52315 5.533 ng 97 35) Ethyl tert-Butyl Ether 12.00 87 92167 5.248 ng 97 36) 1,2-Dichloroethane 12.26 62 99532 5.169 ng 99 38) 1,1,1-Trichloroethane 12.54 97 110520 5.199 ng 98 39) Isopropyl Acetate 12.97 61 100515 10.703 ng # 99 40) 1-Butanol 12.98 56 176299 11.186 ng 87 41) Benzene 13.02 78 294269 4.954 ng 100 42) Carbon Tetrachloride 13.18 117 92652 5.137 ng 100 43) Cyclohexane 13.31 84 253199 10.178 ng 99 44) tert-Amyl Methyl Ether 13.66 73 213737 5.238 ng 99 45) 1,2-Dichloropropane 13.87 63 75548 5.185 ng 100 46) Bromodichloromethane 14.06 83 97399 5.264 ng 100 47) Trichloroethene 14.11 130 79656 5.028 ng 100 48) 1,4-Dioxane 14.09 88 63643 5.297 ng 99 49) 2,2,4-Trimethylpentane... 14.18 57 349427 5.144 ng 97

R8091218.M Thu Sep 13 15:01:57 2018 Page: 1

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00915146

anusha.bayyarapu

Anusha

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121809.D Acq On : 12 Sep 2018 14:47 Operator: AB Sample : 5.0ng TO-15 ICAL Std. Misc : S31-09081801/S31-08231804 (9/21) ALS Vial : 15 Sample Multiplier: 1 Quant Time: Sep 13 10:35:54 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:35:17 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.32 100 65175 11.720 ng 99 51) n-Heptane 14.44 71 82473 5.359 ng 99 52) cis-1,3-Dichloropropene 14.97 75 126547 5.921 ng 100 53) 4-Methyl-2-pentanone 15.01 58 77408 5.784 ng 94 54) trans-1,3-Dichloropropene 15.50 75 106969 6.001 ng 99 55) 1,1,2-Trichloroethane 15.67 97 70470 5.245 ng 99 58) Toluene 15.96 91 306791 4.974 ng 100 59) 2-Hexanone 16.20 43 197235 6.061 ng 98 60) Dibromochloromethane 16.37 129 80242 5.408 ng 99 61) 1,2-Dibromoethane 16.63 107 78784 5.474 ng 100 62) n-Butyl Acetate 16.84 43 218689 6.256 ng 99 63) n-Octane 16.96 57 71345 5.344 ng 99 64) Tetrachloroethene 17.10 166 82148 5.006 ng 100 65) Chlorobenzene 17.76 112 201960 5.058 ng 99 66) Ethylbenzene 18.11 91 353744 5.137 ng 99 67) m- & p-Xylenes 18.27 91 548804 10.358 ng 99 68) Bromoform 18.34 173 64890 5.328 ng 100 69) Styrene 18.59 104 214122 5.539 ng 99 70) o-Xylene 18.70 91 279245 5.230 ng 100 71) n-Nonane 18.89 43 174526 5.479 ng 99 72) 1,1,2,2-Tetrachloroethane 18.68 83 130075 5.268 ng 100 74) Cumene 19.22 105 359726 5.213 ng 99 75) alpha-Pinene 19.57 93 176781 5.237 ng 99 76) n-Propylbenzene 19.66 91 432977 5.453 ng 99 77) 3-Ethyltoluene 19.76 105 358763 5.384 ng 99 78) 4-Ethyltoluene 19.79 105 335742 5.317 ng 99 79) 1,3,5-Trimethylbenzene 19.86 105 296548 5.215 ng 98 80) alpha-Methylstyrene 19.99 118 157923 5.714 ng 92 81) 2-Ethyltoluene 20.03 105 354375 5.314 ng # 14 82) 1,2,4-Trimethylbenzene 20.22 105 307456 5.540 ng 99 83) n-Decane 20.31 58 7913 4.191 ng # 95 84) Benzyl Chloride 20.34 91 204555 6.031 ng 98 85) 1,3-Dichlorobenzene 20.35 146 167887 5.433 ng # 64 86) 1,4-Dichlorobenzene 20.41 146 165783 5.268 ng 100 87) sec-Butylbenzene 20.46 105 403634 5.418 ng 99 88) 4-Isopropyltoluene (p-... 20.60 119 382551 5.494 ng 99 89) 1,2,3-Trimethylbenzene 20.59 105 303702 5.387 ng 99 90) 1,2-Dichlorobenzene 20.71 146 163086 5.445 ng 99 91) d-Limonene 20.72 68 126764 5.582 ng 100 92) 1,2-Dibromo-3-Chloropr... 21.10 157 57682 5.701 ng 91 93) n-Undecane 21.40 57 185784 6.855 ng 98 94) 1,2,4-Trichlorobenzene 22.23 180 110046 5.851 ng 100 95) Naphthalene 22.33 128 355755 5.532 ng 99 96) n-Dodecane 22.32 57 184279 8.831 ng 98 97) Hexachlorobutadiene 22.65 225 71563 5.180 ng 100 98) Cyclohexanone 18.40 55 111082 5.141 ng 98 99) tert-Butylbenzene 20.22 119 303234 5.439 ng 99 100) n-Butylbenzene 20.96 91 328284 5.700 ng 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Thu Sep 13 15:01:57 2018 Page: 2

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00915147




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

800000

850000

900000

950000

1000000

1050000

1100000

1150000

1200000

1250000

1300000

1350000

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

1,2,

3-Tr

imet

hylb

enze

ne,T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,TCum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T

1-Bu

tano

l,TIs

opro

pyl A

ceta

te,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,T

Chl

orof

orm

,TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acr

ylon

itrile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAcet

onitr

ile,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T1,

3-Bu

tadi

ene,

TVi

nyl C

hlor

ide,

T1,

2-D

ichl

oro-

1,1,

2,2-

tetra

fluor

oeth

ane

,TC

hlor

omet

hane

,TD

ichl

orod

ifluo

rom

etha

ne (C

FC 1

2),T

Prop

ene,

T

R8091218.M Thu Sep 13 15:01:58 2018 Page: 3

118 of 142

00915148

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121810.D Acq On : 12 Sep 2018 15:20 Operator: AB Sample : 25ng TO-15 ICAL Std. Misc : S31-09081801/S31-08231801 (9/21) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Sep 13 10:43:23 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:42:37 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.30 130 147587 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 13.41 114 641565 12.500 ng -0.01 56) Chlorobenzene-d5 (IS3) 17.72 82 301088 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.15 65 236662 12.564 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 100.48% 57) Toluene-d8 (SS2) 15.86 98 722954 12.320 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 98.56% 73) Bromofluorobenzene (SS3) 19.09 174 221128 12.462 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 99.68% Target Compounds Qvalue 2) Propene 4.21 42 430623 24.246 ng 99 3) Dichlorodifluoromethan... 4.37 85 683750 23.741 ng 100 4) Chloromethane 4.66 50 552167 23.106 ng 99 5) 1,2-Dichloro-1,1,2,2-t... 4.92 135 376077 23.340 ng 100 6) Vinyl Chloride 5.08 62 569794 25.099 ng 99 7) 1,3-Butadiene 5.35 54 495657 26.584 ng 98 8) Bromomethane 5.79 94 303713 24.886 ng 99 9) Chloroethane 6.13 64 288493 24.016 ng 100 10) Ethanol 6.52 45 1540056 130.614 ng 100 11) Acetonitrile 6.77 41 754915 23.993 ng 99 12) Acrolein 6.95 56 240330 27.518 ng 99 13) Acetone 7.16 58 1645866 118.381 ng 100 14) Trichlorofluoromethane 7.40 101 558500 23.788 ng 99 15) 2-Propanol (Isopropanol) 7.66 45 2221967 54.855 ng 100 16) Acrylonitrile 7.92 53 534510 28.298 ng 99 17) 1,1-Dichloroethene 8.36 96 352283 26.726 ng 98 18) 2-Methyl-2-Propanol (t... 8.53 59 2167526 58.922 ng 100 19) Methylene Chloride 8.59 84 369602 25.122 ng 100 20) 3-Chloro-1-propene (Al... 8.75 41 592739 27.836 ng 99 21) Trichlorotrifluoroethane 9.00 151 312667 24.868 ng 98 22) Carbon Disulfide 8.85 76 1307237 23.328 ng 100 23) trans-1,2-Dichloroethene 9.86 61 553807 26.760 ng 98 24) 1,1-Dichloroethane 10.11 63 630908 23.639 ng 99 25) Methyl tert-Butyl Ether 10.20 73 1158445 26.680 ng 100 26) Vinyl Acetate 10.36 86 558403 166.097 ng 98 27) 2-Butanone (MEK) 10.61 72 277744 28.555 ng 96 28) cis-1,2-Dichloroethene 11.12 61 529465 25.531 ng 97 29) Diisopropyl Ether 11.41 87 371552 25.039 ng # 67 30) Ethyl Acetate 11.42 61 310139 60.195 ng 99 31) n-Hexane 11.40 57 630489 24.474 ng 98 32) Chloroform 11.47 83 632895 25.603 ng 100 34) Tetrahydrofuran (THF) 11.87 72 269285 27.425 ng 99 35) Ethyl tert-Butyl Ether 12.00 87 493443 27.056 ng 99 36) 1,2-Dichloroethane 12.26 62 500708 25.041 ng 100 38) 1,1,1-Trichloroethane 12.54 97 571976 26.694 ng 98 39) Isopropyl Acetate 12.97 61 540523 57.097 ng # 94 40) 1-Butanol 12.99 56 1057661 66.581 ng 96 41) Benzene 13.02 78 1476874 24.664 ng 100 42) Carbon Tetrachloride 13.18 117 481146 26.464 ng 100 43) Cyclohexane 13.32 84 1322520 52.739 ng 98 44) tert-Amyl Methyl Ether 13.66 73 1165843 28.343 ng 100 45) 1,2-Dichloropropane 13.87 63 380425 25.903 ng 99 46) Bromodichloromethane 14.06 83 512220 27.465 ng 100 47) Trichloroethene 14.12 130 396645 24.840 ng 100 48) 1,4-Dioxane 14.09 88 343328 28.345 ng 98 49) 2,2,4-Trimethylpentane... 14.18 57 1798445 26.265 ng 97

R8091218.M Thu Sep 13 15:02:00 2018 Page: 1

119 of 142

00915149

anusha.bayyarapu

Anusha

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121810.D Acq On : 12 Sep 2018 15:20 Operator: AB Sample : 25ng TO-15 ICAL Std. Misc : S31-09081801/S31-08231801 (9/21) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Sep 13 10:43:23 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:42:37 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.32 100 344022 61.371 ng 99 51) n-Heptane 14.45 71 401447 25.876 ng 99 52) cis-1,3-Dichloropropene 14.98 75 672201 31.201 ng 99 53) 4-Methyl-2-pentanone 15.01 58 408781 30.304 ng 98 54) trans-1,3-Dichloropropene 15.50 75 583750 32.489 ng 100 55) 1,1,2-Trichloroethane 15.67 97 362157 26.741 ng 100 58) Toluene 15.96 91 1557388 24.511 ng 100 59) 2-Hexanone 16.20 43 1027658 30.659 ng 99 60) Dibromochloromethane 16.37 129 427659 27.978 ng 100 61) 1,2-Dibromoethane 16.63 107 411201 27.735 ng 100 62) n-Butyl Acetate 16.84 43 1120173 31.110 ng 100 63) n-Octane 16.96 57 365952 26.613 ng 99 64) Tetrachloroethene 17.10 166 420995 24.904 ng 99 65) Chlorobenzene 17.76 112 1038207 25.240 ng 99 66) Ethylbenzene 18.11 91 1851458 26.103 ng 100 67) m- & p-Xylenes 18.28 91 2943315 53.931 ng 100 68) Bromoform 18.34 173 366581 29.221 ng 100 69) Styrene 18.59 104 1177152 29.561 ng 99 70) o-Xylene 18.70 91 1498145 27.239 ng 100 71) n-Nonane 18.89 43 908998 27.704 ng 100 72) 1,1,2,2-Tetrachloroethane 18.67 83 706313 27.770 ng 100 74) Cumene 19.22 105 1896196 26.677 ng 100 75) alpha-Pinene 19.57 93 967110 27.812 ng 98 76) n-Propylbenzene 19.66 91 2276195 27.832 ng 100 77) 3-Ethyltoluene 19.76 105 1890469 27.542 ng 100 78) 4-Ethyltoluene 19.79 105 1831969 28.165 ng 99 79) 1,3,5-Trimethylbenzene 19.86 105 1583453 27.033 ng 99 80) alpha-Methylstyrene 19.99 118 864172 30.355 ng 99 81) 2-Ethyltoluene 20.03 105 1886724 27.467 ng # 13 82) 1,2,4-Trimethylbenzene 20.22 105 1728357 30.232 ng 99 83) n-Decane 20.30 58 42112 31.048 ng 98 84) Benzyl Chloride 20.34 91 1366389 39.110 ng 99 85) 1,3-Dichlorobenzene 20.36 146 921008 28.937 ng # 64 86) 1,4-Dichlorobenzene 20.41 146 917185 28.293 ng 99 87) sec-Butylbenzene 20.46 105 2134128 27.810 ng 100 88) 4-Isopropyltoluene (p-... 20.60 119 2088174 29.115 ng 99 89) 1,2,3-Trimethylbenzene 20.60 105 1719037 29.603 ng 98 90) 1,2-Dichlorobenzene 20.71 146 917632 29.745 ng 100 91) d-Limonene 20.72 68 716840 30.645 ng 100 92) 1,2-Dibromo-3-Chloropr... 21.10 157 314886 30.214 ng 93 93) n-Undecane 21.40 57 946860 33.915 ng 100 94) 1,2,4-Trichlorobenzene 22.23 180 641777 33.128 ng 100 95) Naphthalene 22.33 128 2235060 33.742 ng 100 96) n-Dodecane 22.32 57 871228 40.531 ng 100 97) Hexachlorobutadiene 22.66 225 389648 27.381 ng 99 98) Cyclohexanone 18.41 55 628612 28.243 ng 99 99) tert-Butylbenzene 20.22 119 1669600 29.075 ng 100 100) n-Butylbenzene 20.96 91 1743400 29.386 ng 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Thu Sep 13 15:02:00 2018 Page: 2

120 of 142

00915150


Data File: I:\MS08\Data\2018_09\12\09121810.D Acq On : 12 Sep 2018 15:20 Operator: AB Sample : 25ng TO-15 ICAL Std. Misc : S31-09081801/S31-08231801 (9/21) ALS Vial : 16 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

7500000

8000000

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,TCum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-O

ctan

e,T

n-Bu

tyl A

ceta

te,T

1,2-

Dib

rom

oeth

ane,

TD

ibro

moc

hlor

omet

hane

,T2-

Hex

anon

e,TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBenz

ene,

T1-

Buta

nol,T

Isop

ropy

l Ace

tate

,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),SEthy

l ter

t-But

yl E

ther

,TTe

trahy

drof

uran

(TH

F),T

Chl

orof

orm

,TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAcet

onitr

ile,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R8091218.M Thu Sep 13 15:02:00 2018 Page: 3

121 of 142

00915151

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121811.D Acq On : 12 Sep 2018 15:53 Operator: AB Sample : 50ng TO-15 ICAL Std. Misc : S31-09081801/S31-08231801 (9/21) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Sep 13 10:44:17 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:43:51 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.31 130 160950 12.500 ng 0.00 37) 1,4-Difluorobenzene (IS2) 13.42 114 690144 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 313064 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.16 65 228835 11.140 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 89.12% 57) Toluene-d8 (SS2) 15.87 98 761126 12.475 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 99.76% 73) Bromofluorobenzene (SS3) 19.09 174 240202 13.019 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 104.16% Target Compounds Qvalue 2) Propene 4.21 42 876063 45.231 ng 100 3) Dichlorodifluoromethan... 4.37 85 1350648 43.003 ng 100 4) Chloromethane 4.66 50 1106537 42.459 ng 99 5) 1,2-Dichloro-1,1,2,2-t... 4.92 135 747803 42.557 ng 100 6) Vinyl Chloride 5.09 62 1076077 43.464 ng 99 7) 1,3-Butadiene 5.36 54 915567 45.029 ng 98 8) Bromomethane 5.80 94 555621 41.747 ng 99 9) Chloroethane 6.14 64 567998 43.358 ng 99 10) Ethanol 6.55 45 2818111 219.162 ng 100 11) Acetonitrile 6.79 41 1523867 44.411 ng 99 12) Acrolein 6.96 56 495380 52.013 ng 99 13) Acetone 7.18 58 2932442 193.408 ng 87 14) Trichlorofluoromethane 7.40 101 1058933 41.358 ng 99 15) 2-Propanol (Isopropanol) 7.68 45 4098910 92.791 ng 97 16) Acrylonitrile 7.94 53 1079907 52.424 ng 99 17) 1,1-Dichloroethene 8.37 96 717123 49.887 ng 94 18) 2-Methyl-2-Propanol (t... 8.55 59 3919399 97.700 ng 97 19) Methylene Chloride 8.60 84 753657 46.974 ng 93 20) 3-Chloro-1-propene (Al... 8.76 41 1178377 50.744 ng 99 21) Trichlorotrifluoroethane 9.00 151 646284 47.134 ng 98 22) Carbon Disulfide 8.86 76 2658863 43.509 ng 100 23) trans-1,2-Dichloroethene 9.86 61 1097055 48.608 ng 99 24) 1,1-Dichloroethane 10.12 63 1253875 43.080 ng 99 25) Methyl tert-Butyl Ether 10.21 73 2217161 46.823 ng 100 26) Vinyl Acetate 10.37 86 1020041 278.220 ng # 79 27) 2-Butanone (MEK) 10.61 72 551705 52.011 ng 92 28) cis-1,2-Dichloroethene 11.13 61 1021141 45.152 ng 98 29) Diisopropyl Ether 11.42 87 661580 40.882 ng # 85 30) Ethyl Acetate 11.43 61 542061 96.474 ng 96 31) n-Hexane 11.41 57 1094343 38.952 ng 98 32) Chloroform 11.48 83 1199918 44.511 ng 99 34) Tetrahydrofuran (THF) 11.88 72 544078 50.811 ng 96 35) Ethyl tert-Butyl Ether 12.01 87 978094 49.176 ng 97 36) 1,2-Dichloroethane 12.27 62 895044 41.045 ng 99 38) 1,1,1-Trichloroethane 12.55 97 1087142 47.165 ng 96 39) Isopropyl Acetate 12.97 61 970055 95.257 ng # 82 40) 1-Butanol 13.00 56 1889440 110.570 ng 98 41) Benzene 13.03 78 2805331 43.552 ng 100 42) Carbon Tetrachloride 13.19 117 913427 46.704 ng 100 43) Cyclohexane 13.32 84 2473717 91.703 ng 99 44) tert-Amyl Methyl Ether 13.66 73 2288036 51.710 ng 98 45) 1,2-Dichloropropane 13.88 63 750735 47.519 ng 100 46) Bromodichloromethane 14.06 83 976347 48.666 ng 99 47) Trichloroethene 14.12 130 782098 45.531 ng 100 48) 1,4-Dioxane 14.09 88 682764 52.401 ng 100 49) 2,2,4-Trimethylpentane... 14.19 57 3454846 46.905 ng 95

R8091218.M Thu Sep 13 15:02:03 2018 Page: 1

122 of 142

00915152

anusha.bayyarapu

Anusha


R8091218.M Thu Sep 13 15:02:03 2018 Page: 2

123 of 142

00915153




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

7500000

8000000

8500000

9000000

9500000

1e+07

1.05e+07

1.1e+07

1.15e+07

1.2e+07

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IRTetra

chlo

roet

hene

,Tn-O

ctan

e,T

n-Bu

tyl A

ceta

te,T

1,2-

Dib

rom

oeth

ane,

TD

ibro

moc

hlor

omet

hane

,T2-

Hex

anon

e,T

Tolu

ene,

TTo

luen

e-d8

(SS2

),S1,

1,2-

Tric

hlor

oeth

ane,

Ttra

ns-1

,3-D

ichl

orop

rope

ne,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T

1-Bu

tano

l,TIs

opro

pyl A

ceta

te,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,TC

hlor

ofor

m,T

Ethy

l Ace

tate

,TD

iisop

ropy

l Eth

er,T

n-H

exan

e,T

Brom

ochl

orom

etha

ne (I

S1),I

Rci

s-1,

2-D

ichl

oroe

then

e,T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEt

hano

l,T

Chl

oroe

than

e,T

Brom

omet

hane

,T1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T1,

2-D

ichl

oro-

1,1,

2,2-

tetra

fluor

oeth

ane

,TC

hlor

omet

hane

,TD

ichl

orod

ifluo

rom

etha

ne (C

FC 1

2),T

Prop

ene,

T

R8091218.M Thu Sep 13 15:02:03 2018 Page: 3

124 of 142

00915154

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121812.D Acq On : 12 Sep 2018 16:26 Operator: AB Sample : 100ng TO-15 ICAL Std. Misc : S31-09081801/S31-08231801 (9/21) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Sep 13 10:44:35 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:25 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.32 130 157527 12.500 ng 0.00 37) 1,4-Difluorobenzene (IS2) 13.42 114 683702 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 324615 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.16 65 254477 12.657 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 101.28% 57) Toluene-d8 (SS2) 15.87 98 757916 11.980 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.84% 73) Bromofluorobenzene (SS3) 19.10 174 251012 13.121 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 104.96% Target Compounds Qvalue 2) Propene 4.22 42 1928193 101.716 ng 98 3) Dichlorodifluoromethan... 4.38 85 2661283 86.572 ng 99 4) Chloromethane 4.67 50 1799911 70.565 ng 99 5) 1,2-Dichloro-1,1,2,2-t... 4.94 135 1483698 86.270 ng 99 6) Vinyl Chloride 5.10 62 2282865 94.210 ng 99 7) 1,3-Butadiene 5.37 54 2102615 105.635 ng 99 8) Bromomethane 5.81 94 1235973 94.885 ng 99 9) Chloroethane 6.15 64 1168966 91.171 ng 99 10) Ethanol 6.59 45 6372792 506.371 ng 99 11) Acetonitrile 6.81 41 3121985 92.963 ng 100 12) Acrolein 6.98 56 1002780 107.576 ng 99 13) Acetone 7.21 58 6453808 434.908 ng # 83 14) Trichlorofluoromethane 7.42 101 2306044 92.022 ng 100 15) 2-Propanol (Isopropanol) 7.71 45 8122109 187.862 ng 98 16) Acrylonitrile 7.96 53 2253867 111.789 ng 100 17) 1,1-Dichloroethene 8.38 96 1474189 104.781 ng 99 18) 2-Methyl-2-Propanol (t... 8.58 59 6954255 177.117 ng 99 19) Methylene Chloride 8.61 84 1581504 100.714 ng 98 20) 3-Chloro-1-propene (Al... 8.77 41 2491727 109.632 ng 99 21) Trichlorotrifluoroethane 9.01 151 1286765 95.884 ng 98 22) Carbon Disulfide 8.87 76 5375618 89.877 ng 99 23) trans-1,2-Dichloroethene 9.87 61 2297644 104.015 ng 99 24) 1,1-Dichloroethane 10.12 63 2596340 91.142 ng 99 25) Methyl tert-Butyl Ether 10.21 73 4505278 97.212 ng 98 26) Vinyl Acetate 10.39 86 2367600 659.804 ng # 64 27) 2-Butanone (MEK) 10.63 72 1180663 113.724 ng 97 28) cis-1,2-Dichloroethene 11.14 61 2192292 99.043 ng 99 29) Diisopropyl Ether 11.43 87 1521319 96.051 ng # 89 30) Ethyl Acetate 11.44 61 1279195 232.613 ng 96 31) n-Hexane 11.41 57 2576139 93.688 ng 97 32) Chloroform 11.49 83 2585692 98.000 ng 100 34) Tetrahydrofuran (THF) 11.88 72 1137300 108.519 ng 99 35) Ethyl tert-Butyl Ether 12.02 87 2091451 107.438 ng 98 36) 1,2-Dichloroethane 12.28 62 1995507 93.499 ng 99 38) 1,1,1-Trichloroethane 12.55 97 2336643 102.328 ng 98 39) Isopropyl Acetate 12.98 61 2231403 221.183 ng # 77 40) 1-Butanol 13.02 56 4455007 263.127 ng 97 41) Benzene 13.03 78 6198737 97.140 ng 99 42) Carbon Tetrachloride 13.19 117 1971886 101.774 ng 100 43) Cyclohexane 13.32 84 5397556 201.978 ng 97 44) tert-Amyl Methyl Ether 13.67 73 4874364 111.199 ng 99 45) 1,2-Dichloropropane 13.88 63 1569455 100.276 ng 100 46) Bromodichloromethane 14.07 83 2143251 107.838 ng 100 47) Trichloroethene 14.12 130 1676706 98.532 ng 100 48) 1,4-Dioxane 14.10 88 1502779 116.423 ng 98 49) 2,2,4-Trimethylpentane... 14.19 57 7225679 99.024 ng 98

R8091218.M Thu Sep 13 15:02:05 2018 Page: 1

125 of 142

00915155

anusha.bayyarapu

Anusha


R8091218.M Thu Sep 13 15:02:05 2018 Page: 2

126 of 142

00915156




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

9000000

1e+07

1.1e+07

1.2e+07

1.3e+07

1.4e+07

1.5e+07

1.6e+07

1.7e+07

1.8e+07

1.9e+07

2e+07

2.1e+07

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-Xy

lene

,T1,

1,2,

2-Te

trach

loro

etha

ne,T

Styr

ene,

TC

yclo

hexa

none

,TBr

omof

orm

,Tm

- & p

-Xyl

enes

,TEt

hylb

enze

ne,T

Chl

orob

enze

ne,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,Ttert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T

1-Bu

tano

l,TIs

opro

pyl A

ceta

te,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,TC

hlor

ofor

m,T

Ethy

l Ace

tate

,TD

iisop

ropy

l Eth

er,T

n-H

exan

e,T

Brom

ochl

orom

etha

ne (I

S1),I

Rcis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEtha

nol,T

Chl

oroe

than

e,T

Brom

omet

hane

,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T1,

2-D

ichl

oro-

1,1,

2,2-

tetra

fluor

oeth

ane

,TC

hlor

omet

hane

,TDic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R8091218.M Thu Sep 13 15:02:06 2018 Page: 3

127 of 142

00915157

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121815.D Acq On : 12 Sep 2018 18:04 Operator: AB Sample : 25ng ICV Std. Misc : S31-09081801/S31-08211801 (9/19) ALS Vial : 1 Sample Multiplier: 1 Quant Time: Sep 13 10:54:53 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.30 130 167566 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 13.41 114 700819 12.500 ng -0.01 56) Chlorobenzene-d5 (IS3) 17.72 82 342266 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.15 65 264229 12.355 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 98.80% 57) Toluene-d8 (SS2) 15.86 98 796124 11.935 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.44% 73) Bromofluorobenzene (SS3) 19.09 174 253791 12.582 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 100.64% Target Compounds Qvalue 2) Propene 4.21 42 431314 21.390 ng 99 3) Dichlorodifluoromethan... 4.37 85 689001 21.071 ng 100 4) Chloromethane 4.66 50 599038 22.078 ng 100 5) 1,2-Dichloro-1,1,2,2-t... 4.92 135 391379 21.393 ng 99 6) Vinyl Chloride 5.09 62 606838 23.543 ng 100 7) 1,3-Butadiene 5.36 54 507515 23.970 ng 98 8) Bromomethane 5.80 94 321573 23.208 ng 99 9) Chloroethane 6.13 64 320850 23.525 ng 99 10) Ethanol 6.52 45 1606234 119.981 ng 100 11) Acetonitrile 6.76 41 753556 21.094 ng 99 12) Acrolein 6.95 56 248623 22.226 ng 99 13) Acetone 7.16 58 1648437 107.843 ng 100 14) Trichlorofluoromethane 7.40 101 572886 22.087 ng 99 15) 2-Propanol (Isopropanol) 7.66 45 2240800 48.724 ng 100 16) Acrylonitrile 7.92 53 538158 24.164 ng 99 17) 1,1-Dichloroethene 8.36 96 355413 23.748 ng 98 18) 2-Methyl-2-Propanol (t... 8.53 59 2130509 51.011 ng 99 19) Methylene Chloride 8.59 84 372362 22.292 ng 99 20) 3-Chloro-1-propene (Al... 8.75 41 620885 25.681 ng 98 21) Trichlorotrifluoroethane 9.00 151 317645 22.251 ng 99 22) Carbon Disulfide 8.85 76 1322710 22.960 ng 100 23) trans-1,2-Dichloroethene 9.86 61 550950 23.447 ng 98 24) 1,1-Dichloroethane 10.11 63 643933 21.250 ng 99 25) Methyl tert-Butyl Ether 10.20 73 1154363 23.416 ng 100 26) Vinyl Acetate 10.36 86 531728 120.057 ng 100 27) 2-Butanone (MEK) 10.61 72 272074 22.211 ng 96 28) cis-1,2-Dichloroethene 11.12 61 518710 22.030 ng 97 29) Diisopropyl Ether 11.41 87 416982 24.750 ng 98 30) Ethyl Acetate 11.42 61 295926 50.588 ng 98 31) n-Hexane 11.41 57 587403 20.083 ng 98 32) Chloroform 11.47 83 618851 22.050 ng 100 34) Tetrahydrofuran (THF) 11.87 72 262956 23.588 ng 99 35) Ethyl tert-Butyl Ether 12.01 87 500074 24.150 ng 99 36) 1,2-Dichloroethane 12.26 62 493577 21.741 ng 99 38) 1,1,1-Trichloroethane 12.54 97 564816 24.131 ng 98 39) Isopropyl Acetate 12.97 61 522786 50.554 ng # 93 40) 1-Butanol 12.99 56 974863 50.412 ng 95 41) Benzene 13.03 78 1447221 22.125 ng 100 42) Carbon Tetrachloride 13.18 117 486887 24.516 ng 100 43) Cyclohexane 13.32 84 1305354 47.654 ng 98 44) tert-Amyl Methyl Ether 13.66 73 1177475 26.206 ng 99 45) 1,2-Dichloropropane 13.87 63 368897 22.994 ng 100 46) Bromodichloromethane 14.06 83 505826 24.829 ng 100 47) Trichloroethene 14.12 130 384857 22.064 ng 100 48) 1,4-Dioxane 14.09 88 336495 24.548 ng 99 49) 2,2,4-Trimethylpentane... 14.18 57 1787772 23.902 ng 97

R8091218.M Thu Sep 13 12:37:31 2018 Page: 1

128 of 142

00915158

anusha.bayyarapu

Anusha

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\12\09121815.D Acq On : 12 Sep 2018 18:04 Operator: AB Sample : 25ng ICV Std. Misc : S31-09081801/S31-08211801 (9/19) ALS Vial : 1 Sample Multiplier: 1 Quant Time: Sep 13 10:54:53 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.32 100 334367 49.369 ng 100 51) n-Heptane 14.45 71 384814 22.707 ng 99 52) cis-1,3-Dichloropropene 14.98 75 624232 26.525 ng 100 53) 4-Methyl-2-pentanone 15.01 58 400732 25.961 ng 98 54) trans-1,3-Dichloropropene 15.50 75 578280 26.366 ng 100 55) 1,1,2-Trichloroethane 15.67 97 355353 24.020 ng 99 58) Toluene 15.96 91 1518073 21.018 ng 100 59) 2-Hexanone 16.20 43 974212 23.424 ng 99 60) Dibromochloromethane 16.37 129 420872 24.222 ng 100 61) 1,2-Dibromoethane 16.63 107 401945 23.849 ng 100 62) n-Butyl Acetate 16.84 43 1073438 26.226 ng 100 63) n-Octane 16.96 57 356389 22.799 ng 99 64) Tetrachloroethene 17.10 166 415557 21.625 ng 99 65) Chlorobenzene 17.76 112 1014745 21.702 ng 100 66) Ethylbenzene 18.11 91 1816561 22.530 ng 100 67) m- & p-Xylenes 18.28 91 2882885 46.469 ng 100 68) Bromoform 18.34 173 358721 25.154 ng 100 69) Styrene 18.59 104 1144637 25.286 ng 99 70) o-Xylene 18.70 91 1478389 23.646 ng 100 71) n-Nonane 18.89 43 884944 23.726 ng 99 72) 1,1,2,2-Tetrachloroethane 18.68 83 684483 23.674 ng 100 74) Cumene 19.22 105 1882227 23.294 ng 100 75) alpha-Pinene 19.57 93 964763 24.407 ng 99 76) n-Propylbenzene 19.66 91 2237326 24.065 ng 100 77) 3-Ethyltoluene 19.76 105 1785682 22.886 ng 95 78) 4-Ethyltoluene 19.79 105 1884991 25.494 ng 95 79) 1,3,5-Trimethylbenzene 19.86 105 1562120 23.460 ng 98 80) alpha-Methylstyrene 19.99 118 839515 25.941 ng 100 81) 2-Ethyltoluene 20.03 105 1855620 23.764 ng # 13 82) 1,2,4-Trimethylbenzene 20.22 105 1695353 26.087 ng 99 83) n-Decane 20.31 58 40967 26.005 ng 97 84) Benzyl Chloride 20.34 91 1375989 27.556 ng 99 85) 1,3-Dichlorobenzene 20.36 146 902606 24.947 ng # 64 86) 1,4-Dichlorobenzene 20.41 146 898543 24.382 ng 100 87) sec-Butylbenzene 20.46 105 2105189 24.132 ng 100 88) 4-Isopropyltoluene (p-... 20.60 119 2085462 25.579 ng 98 89) 1,2,3-Trimethylbenzene 20.60 105 1750496 26.518 ng 98 90) 1,2-Dichlorobenzene 20.72 146 902083 25.723 ng 100 91) d-Limonene 20.72 68 698498 25.230 ng 100 92) 1,2-Dibromo-3-Chloropr... 21.10 157 329207 27.788 ng 97 93) n-Undecane 21.40 57 985387 25.253 ng 100 94) 1,2,4-Trichlorobenzene 22.23 180 695985 28.745 ng 100 95) Naphthalene 22.33 128 2204156 28.037 ng 100 96) n-Dodecane 22.32 57 995314 27.092 ng 100 97) Hexachlorobutadiene 22.66 225 412225 25.483 ng 100 98) Cyclohexanone 18.41 55 555693 21.963 ng 98 99) tert-Butylbenzene 20.22 119 1659891 25.428 ng 100 100) n-Butylbenzene 20.96 91 1723669 25.558 ng 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Thu Sep 13 12:37:31 2018 Page: 2

129 of 142

00915159


Data File: I:\MS08\Data\2018_09\12\09121815.D Acq On : 12 Sep 2018 18:04 Operator: AB Sample : 25ng ICV Std. Misc : S31-09081801/S31-08211801 (9/19) ALS Vial : 1 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

7500000

8000000

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,Tn-

Dod

ecan

e,T

1,2,

4-Tr

ichl

orob

enze

ne,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,2,

3-Tr

imet

hylb

enze

ne,T

4-Is

opro

pylto

luen

e (p

-Cym

ene)

,Tse

c-Bu

tylb

enze

ne,T

1,4-

Dic

hlor

oben

zene

,T1,

3-D

ichl

orob

enze

ne,T

Benz

yl C

hlor

ide,

Tn-

Dec

ane,

Tte

rt-Bu

tylb

enze

ne,T

1,2,

4-Tr

imet

hylb

enze

ne,T

2-Et

hylto

luen

e,T

alph

a-M

ethy

lsty

rene

,T1,

3,5-

Trim

ethy

lben

zene

,T4-

Ethy

ltolu

ene,

T3-

Ethy

ltolu

ene,

Tn-

Prop

ylbe

nzen

e,T

alph

a-Pi

nene

,TC

umen

e,T

Brom

oflu

orob

enze

ne (S

S3),S

n-N

onan

e,T

o-Xy

lene

,T1,

1,2,

2-Te

trach

loro

etha

ne,T

Styr

ene,

TC

yclo

hexa

none

,TBr

omof

orm

,Tm

- & p

-Xyl

enes

,TEt

hylb

enze

ne,T

Chl

orob

enze

ne,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,Tn-O

ctan

e,T

n-Bu

tyl A

ceta

te,T

1,2-

Dib

rom

oeth

ane,

TD

ibro

moc

hlor

omet

hane

,T2-

Hex

anon

e,T

Tolu

ene,

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R8091218.M Thu Sep 13 12:37:32 2018 Page: 3

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Page 1 of 3 I:\MS08\0-Instrument Info\0-Security Certificates\ICV_LCS_2018_08171803.CRT 9/13/2018 12:38 PM

Initial Calibration Verification/LABORATORY CONTROL SAMPLE CHECK SHEET

Data File Name: 09121815.D Acq. Method File: TO15.MData File Path: I:\MS08\Data\2018_09\12\ Sample Name: 25ng ICV Std.

Operator: AB Misc Info: S31-09081801/S31-08211801 (Date Acquired: 9/12/2018 18:04 Instrument Name: MS08

Compound Ret. Amt. Spike % Lower Upper * OR ICV/AZ # Name Time (ng) Amt.(ng) Rec. Limit Limit Fail 70-130%2) Propene 4.21 21.4 26.43 81 54 133 * *3) Dichlorodifluoromethane (CFC 12 4.37 21.1 26.30 80 64 115 * *4) Chloromethane 4.66 22.1 26.38 84 47 140 * *5) 1,2-Dichloro-1,1,2,2-tetrafluoroeth 4.92 21.4 26.38 81 60 112 * *6) Vinyl Chloride 5.09 23.5 26.73 88 63 127 * *7) 1,3-Butadiene 5.36 24.0 26.28 91 57 149 * *8) Bromomethane 5.80 23.2 26.48 88 63 132 * *9) Chloroethane 6.13 23.5 26.75 88 68 129 * *10) Ethanol 6.52 120 128.10 94 62 131 * *11) Acetonitrile 6.76 21.1 25.73 82 56 136 * *12) Acrolein 6.95 22.2 25.63 87 60 132 * *13) Acetone 7.16 108 132.33 82 63 124 * *14) Trichlorofluoromethane 7.40 22.1 26.40 84 65 113 * *15) 2-Propanol (Isopropanol) 7.66 48.7 51.60 94 62 135 * *16) Acrylonitrile 7.92 24.2 25.88 94 68 138 * *17) 1,1-Dichloroethene 8.36 23.7 27.23 87 72 118 * *18) 2-Methyl-2-Propanol (tert-Butyl Alco 8.53 51.0 54.25 94 61 128 * *19) Methylene Chloride 8.59 22.3 27.08 82 67 116 * *20) 3-Chloro-1-propene (Allyl Chlorid 8.75 25.7 27.00 95 61 143 * *21) Trichlorotrifluoroethane 9.00 22.3 26.95 83 68 113 * *22) Carbon Disulfide 8.85 23.0 27.20 85 68 120 * *23) trans-1,2-Dichloroethene 9.86 23.4 26.73 88 71 125 * *24) 1,1-Dichloroethane 10.11 21.3 26.95 79 68 118 * *25) Methyl tert-Butyl Ether 10.20 23.4 26.80 87 60 123 * *26) Vinyl Acetate 10.36 120 133.03 90 73 135 * *27) 2-Butanone (MEK) 10.61 22.2 25.95 86 70 129 * *28) cis-1,2-Dichloroethene 11.12 22.0 26.35 83 69 121 * *29) Diisopropyl Ether 11.41 24.7 27.18 91 65 117 * *30) Ethyl Acetate 11.42 50.6 54.45 93 66 140 * *31) n-Hexane 11.41 20.1 26.95 75 61 124 * *32) Chloroform 11.47 22.0 27.08 81 69 113 * *34) Tetrahydrofuran (THF) 11.87 23.6 27.00 87 66 121 * *35) Ethyl tert-Butyl Ether 12.01 24.1 26.80 90 69 120 * *36) 1,2-Dichloroethane 12.26 21.7 26.85 81 62 120 * *38) 1,1,1-Trichloroethane 12.54 24.1 26.90 90 65 116 * *39) Isopropyl Acetate 12.97 50.6 51.55 98 70 126 * *40) 1-Butanol 12.99 50.4 51.58 98 62 141 * *41) Benzene 13.03 22.1 26.38 84 66 111 * *42) Carbon Tetrachloride 13.18 24.5 26.45 93 64 122 * *43) Cyclohexane 13.32 47.7 52.05 92 69 115 * *44) tert-Amyl Methyl Ether 13.66 26.2 27.08 97 68 119 * *45) 1,2-Dichloropropane 13.87 23.0 26.98 85 69 121 * *46) Bromodichloromethane 14.06 24.8 26.83 92 69 123 * *47) Trichloroethene 14.12 22.1 26.68 83 69 112 * *48) 1,4-Dioxane 14.09 24.5 26.73 92 74 123 * *49) 2,2,4-Trimethylpentane (Isooctane) 14.18 23.9 26.65 90 67 120 * *

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Initial Calibration Verification/LABORATORY CONTROL SAMPLE CHECK SHEET

Data File Name: 09121815.D TO15.MData File Path: I:\MS08\Data\2018_09\12\ Sample Name: 25ng ICV Std.

Operator: AB Misc Info: S31-09081801/S31-08211801 (Date Acquired: 9/12/2018 18:04 Instrument Name: MS08

Compound Ret. Amt. Spike % Lower Upper * OR ICV/AZ # Name Time (ng) Amt.(ng) Rec. Limit Limit Fail 70-130%

50) Methyl Methacrylate 14.32 49.4 53.88 92 75 125 * *51) n-Heptane 14.45 22.7 26.90 84 68 118 * *52) cis-1,3-Dichloropropene 14.98 26.5 26.78 99 74 129 * *53) 4-Methyl-2-pentanone 15.01 26.0 26.15 99 66 138 * *54) trans-1,3-Dichloropropene 15.50 26.4 26.60 99 75 130 * *55) 1,1,2-Trichloroethane 15.67 24.0 26.85 89 73 117 * *58) Toluene 15.96 21.0 26.50 79 66 114 * *59) 2-Hexanone 16.20 23.4 26.78 87 58 146 * *60) Dibromochloromethane 16.37 24.2 26.60 91 67 130 * *61) 1,2-Dibromoethane 16.63 23.8 27.03 88 70 127 * *62) n-Butyl Acetate 16.84 26.2 27.35 96 62 140 * *63) n-Octane 16.96 22.8 27.13 84 65 121 * *64) Tetrachloroethene 17.10 21.6 26.60 81 62 119 * *65) Chlorobenzene 17.76 21.7 26.83 81 66 115 * *66) Ethylbenzene 18.11 22.5 26.53 85 69 117 * *67) m- & p-Xylenes 18.28 46.5 53.28 87 67 117 * *68) Bromoform 18.34 25.2 26.68 94 67 135 * *69) Styrene 18.59 25.3 26.50 95 70 128 * *70) o-Xylene 18.70 23.6 26.75 88 67 118 * *71) n-Nonane 18.89 23.7 26.83 88 61 127 * *72) 1,1,2,2-Tetrachloroethane 18.68 23.7 26.80 88 70 125 * *74) Cumene 19.22 23.3 26.80 87 68 116 * *75) alpha-Pinene 19.57 24.4 26.40 92 69 122 * *76) n-Propylbenzene 19.66 24.1 27.23 89 70 118 * *77) 3-Ethyltoluene 19.76 22.9 26.83 85 68 117 * *78) 4-Ethyltoluene 19.79 25.5 26.80 95 69 124 * *79) 1,3,5-Trimethylbenzene 19.86 23.5 26.73 88 65 117 * *80) alpha-Methylstyrene 19.99 25.9 26.75 97 71 132 * *81) 2-Ethyltoluene 20.03 23.8 27.08 88 67 119 * *82) 1,2,4-Trimethylbenzene 20.22 26.1 26.90 97 67 124 * *83) n-Decane 20.31 26.0 26.88 97 63 129 * *84) Benzyl Chloride 20.34 27.6 27.08 102 75 142 * *85) 1,3-Dichlorobenzene 20.36 24.9 26.98 92 70 124 * *86) 1,4-Dichlorobenzene 20.41 24.4 27.00 90 63 124 * *87) sec-Butylbenzene 20.46 24.1 26.55 91 68 119 * *88) 4-Isopropyltoluene (p-Cymene) 20.60 25.6 26.95 95 65 122 * *89) 1,2,3-Trimethylbenzene 20.60 26.5 26.95 98 66 128 * *90) 1,2-Dichlorobenzene 20.72 25.7 26.95 95 66 125 * *91) d-Limonene 20.72 25.2 26.38 96 64 135 * *92) 1,2-Dibromo-3-Chloropropane 21.10 27.8 26.15 106 73 136 * *93) n-Undecane 21.40 25.3 27.03 94 67 135 * *94) 1,2,4-Trichlorobenzene 22.23 28.7 26.78 107 70 141 * *95) Naphthalene 22.33 28.0 25.38 110 71 146 * *96) n-Dodecane 22.32 27.1 25.63 106 69 152 * *97) Hexachlorobutadiene 22.66 25.5 26.13 98 63 126 * *98) Cyclohexanone 18.41 22.0 24.45 90 58 138 * *99) tert-Butylbenzene 20.22 25.4 26.88 95 65 121 * *

100) n-Butylbenzene 20.96 25.6 27.00 95 71 125 * *

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Bold = 75 Compound List* = Pass

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Evaluate Continuing Calibration Report Data File: I:\MS08\Data\2018_09\28\09281803.D Acq On : 28 Sep 2018 5:27 Operator: AB Sample : CCV R8092818_5ng Misc : S31-09081801/S31-09041803 (10/3) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Sep 28 10:58:07 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Min. RRF : 0.000 Min. Rel. Area : 50% Max. R.T. Dev 0.33min Max. RRF Dev : 30% Max. Rel. Area : 200% Compound AvgRF CCRF %Dev Area% Dev(min) ------------------------------------------------------------------------- 1 IR Bromochloromethane (IS1) 1.000 1.000 0.0 120 -0.03 2 T Propene 1.504 1.113 26.0 94 0.00 3 T Dichlorodifluoromethane (CF 2.439 1.878 23.0 98 -0.01 4 T Chloromethane 2.024 1.603 20.8 102 -0.02 5 T 1,2-Dichloro-1,1,2,2-tetraf 1.365 1.158 15.2 107 -0.02 6 T Vinyl Chloride 1.923 1.592 17.2 99 -0.03 7 T 1,3-Butadiene 1.579 1.473 6.7 110 -0.03 8 T Bromomethane 1.034 1.051 -1.6 125 -0.03 9 T Chloroethane 1.017 0.993 2.4 114 -0.03 10 T Ethanol 0.999 1.003 -0.4 134 -0.11 11 T Acetonitrile 2.665 2.513 5.7 126 -0.07 12 T Acrolein 0.834 0.850 -1.9 125 -0.04 13 T Acetone 1.140 1.011 11.3 120 -0.06 14 T Trichlorofluoromethane 1.935 1.787 7.6 114 -0.03 15 T 2-Propanol (Isopropanol) 3.431 3.492 -1.8 119 -0.08 16 T Acrylonitrile 1.661 1.761 -6.0 122 -0.05 17 T 1,1-Dichloroethene 1.116 1.193 -6.9 132 -0.03 18 T 2-Methyl-2-Propanol (tert-B 3.116 3.296 -5.8 122 -0.07 19 T Methylene Chloride 1.246 1.256 -0.8 128 -0.03 20 T 3-Chloro-1-propene (Allyl C 1.804 1.840 -2.0 125 -0.03 21 T Trichlorotrifluoroethane 1.065 1.110 -4.2 132 -0.02 22 T Carbon Disulfide 4.298 4.464 -3.9 130 -0.03 23 T trans-1,2-Dichloroethene 1.753 1.742 0.6 120 -0.02 24 T 1,1-Dichloroethane 2.260 2.080 8.0 116 -0.02 25 T Methyl tert-Butyl Ether 3.678 3.645 0.9 120 -0.01 26 T Vinyl Acetate 0.330 0.342 -3.6 116 -0.04 27 T 2-Butanone (MEK) 0.914 0.906 0.9 117 -0.03 28 T cis-1,2-Dichloroethene 1.756 1.665 5.2 117 -0.03 29 T Diisopropyl Ether 1.257 1.245 1.0 115 -0.02 30 T Ethyl Acetate 0.436 0.441 -1.1 111 -0.03 31 T n-Hexane 2.182 1.807 17.2 101 -0.02 32 T Chloroform 2.094 1.982 5.3 117 -0.03 33 S 1,2-Dichloroethane-d4(SS1) 1.595 1.351 15.3 100 -0.02 34 T Tetrahydrofuran (THF) 0.832 0.855 -2.8 119 -0.01 35 T Ethyl tert-Butyl Ether 1.545 1.573 -1.8 123 -0.01 36 T 1,2-Dichloroethane 1.694 1.484 12.4 108 -0.02 37 IR 1,4-Difluorobenzene (IS2) 1.000 1.000 0.0 107 -0.02 38 T 1,1,1-Trichloroethane 0.417 0.442 -6.0 118 -0.02 39 T Isopropyl Acetate 0.184 0.203 -10.3 114 -0.01 40 T 1-Butanol 0.345 0.366 -6.1 117 -0.04 41 T Benzene 1.167 1.210 -3.7 116 -0.02 42 T Carbon Tetrachloride 0.354 0.390 -10.2 119 -0.02 43 T Cyclohexane 0.489 0.513 -4.9 115 -0.01 44 T tert-Amyl Methyl Ether 0.801 0.893 -11.5 122 -0.01 45 T 1,2-Dichloropropane 0.286 0.303 -5.9 117 -0.02 46 T Bromodichloromethane 0.363 0.392 -8.0 117 -0.01 47 T Trichloroethene 0.311 0.334 -7.4 122 -0.01 48 T 1,4-Dioxane 0.244 0.270 -10.7 123 -0.01 49 T 2,2,4-Trimethylpentane (Iso 1.334 1.421 -6.5 118 -0.02 50 T Methyl Methacrylate 0.121 0.136 -12.4 121 -0.02 51 T n-Heptane 0.302 0.316 -4.6 112 -0.01 52 T cis-1,3-Dichloropropene 0.420 0.490 -16.7 118 -0.01 53 T 4-Methyl-2-pentanone 0.275 0.307 -11.6 115 -0.01 54 T trans-1,3-Dichloropropene 0.391 0.436 -11.5 117 -0.01

R8091218.M Fri Sep 28 12:27:20 2018 Page: 1

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Evaluate Continuing Calibration Report Data File: I:\MS08\Data\2018_09\28\09281803.D Acq On : 28 Sep 2018 5:27 Operator: AB Sample : CCV R8092818_5ng Misc : S31-09081801/S31-09041803 (10/3) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Sep 28 10:58:07 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Min. RRF : 0.000 Min. Rel. Area : 50% Max. R.T. Dev 0.33min Max. RRF Dev : 30% Max. Rel. Area : 200% Compound AvgRF CCRF %Dev Area% Dev(min) ------------------------------------------------------------------------- 55 T 1,1,2-Trichloroethane 0.264 0.297 -12.5 124 -0.01 56 IR Chlorobenzene-d5 (IS3) 1.000 1.000 0.0 117 0.00 57 S Toluene-d8 (SS2) 2.436 2.304 5.4 111 -0.01 58 T Toluene 2.638 2.558 3.0 120 -0.01 59 T 2-Hexanone 1.519 1.496 1.5 111 -0.01 60 T Dibromochloromethane 0.635 0.690 -8.7 126 -0.01 61 T 1,2-Dibromoethane 0.616 0.665 -8.0 124 -0.01 62 T n-Butyl Acetate 1.495 1.649 -10.3 112 0.00 63 T n-Octane 0.571 0.549 3.9 113 -0.01 64 T Tetrachloroethene 0.702 0.749 -6.7 132 0.00 65 T Chlorobenzene 1.708 1.712 -0.2 124 0.00 66 T Ethylbenzene 2.945 2.995 -1.7 120 0.00 67 T m- & p-Xylenes 2.266 2.238 1.2 118 -0.01 68 T Bromoform 0.521 0.607 -16.5 136 -0.01 69 T Styrene 1.653 1.854 -12.2 125 0.00 70 T o-Xylene 2.283 2.324 -1.8 121 0.00 71 T n-Nonane 1.362 1.342 1.5 113 -0.01 72 T 1,1,2,2-Tetrachloroethane 1.056 1.107 -4.8 124 -0.01 73 S Bromofluorobenzene (SS3) 0.737 0.879 -19.3 140 0.00 74 T Cumene 2.951 3.064 -3.8 123 0.00 75 T alpha-Pinene 1.444 1.522 -5.4 122 0.00 76 T n-Propylbenzene 3.395 3.574 -5.3 121 0.00 77 T 3-Ethyltoluene 2.850 3.112 -9.2 126 -0.01 78 T 4-Ethyltoluene 2.700 2.819 -4.4 122 -0.01 79 T 1,3,5-Trimethylbenzene 2.432 2.524 -3.8 123 0.00 80 T alpha-Methylstyrene 1.182 1.342 -13.5 123 0.00 81 T 2-Ethyltoluene 2.852 2.997 -5.1 124 -0.01 82 T 1,2,4-Trimethylbenzene 2.373 2.542 -7.1 121 -0.01 83 T n-Decane 0.058 0.063 -8.6 117 0.00 84 T Benzyl Chloride 1.824 1.898 -4.1 133 -0.01 85 T 1,3-Dichlorobenzene 1.321 1.486 -12.5 131 -0.01 86 T 1,4-Dichlorobenzene 1.346 1.515 -12.6 135 -0.01 87 T sec-Butylbenzene 3.186 3.436 -7.8 124 0.00 88 T 4-Isopropyltoluene (p-Cymen 2.978 3.282 -10.2 122 -0.01 89 T 1,2,3-Trimethylbenzene 2.411 2.585 -7.2 121 -0.01 90 T 1,2-Dichlorobenzene 1.281 1.436 -12.1 131 0.00 91 T d-Limonene 1.011 1.044 -3.3 114 -0.01 92 T 1,2-Dibromo-3-Chloropropane 0.433 0.551 -27.3 136 0.00 93 T n-Undecane 1.425 1.499 -5.2 117 0.00 94 T 1,2,4-Trichlorobenzene 0.884 1.099 -24.3 145 0.00 95 T Naphthalene 2.871 3.530 -23.0 139 0.00 96 T n-Dodecane 1.342 1.476 -10.0 113 0.00 97 T Hexachlorobutadiene 0.591 0.716 -21.2 144 0.00 98 T Cyclohexanone 0.924 1.044 -13.0 126 -0.02 99 T tert-Butylbenzene 2.384 2.551 -7.0 123 0.00 100 T n-Butylbenzene 2.463 2.739 -11.2 121 0.00 -------------------------------------------------------------------------- (#) = Out of Range SPCC's out = 0 CCC's out = 0

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Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281803.D Acq On : 28 Sep 2018 5:27 Operator: AB Sample : CCV R8092818_5ng Misc : S31-09081801/S31-09041803 (10/3) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Sep 28 10:58:07 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.29 130 170590 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 13.41 114 681914 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 17.72 82 341722 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 230525 10.588 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 84.72% 57) Toluene-d8 (SS2) 15.86 98 787230 11.820 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 94.56% 73) Bromofluorobenzene (SS3) 19.09 174 300231 14.908 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 119.28% Target Compounds Qvalue 2) Propene 4.21 42 78309 3.815 ng 99 3) Dichlorodifluoromethan... 4.37 85 133921 4.023 ng 100 4) Chloromethane 4.65 50 110234 3.991 ng 99 5) 1,2-Dichloro-1,1,2,2-t... 4.92 135 81207 4.360 ng 99 6) Vinyl Chloride 5.08 62 114153 4.350 ng 100 7) 1,3-Butadiene 5.34 54 105471 4.893 ng 98 8) Bromomethane 5.78 94 72382 5.131 ng 99 9) Chloroethane 6.12 64 69234 4.986 ng 99 10) Ethanol 6.48 45 351800 25.813 ng 100 11) Acetonitrile 6.74 41 177110 4.870 ng 99 12) Acrolein 6.94 56 59632 5.236 ng 99 13) Acetone 7.15 58 370463 23.806 ng 94 14) Trichlorofluoromethane 7.39 101 129250 4.895 ng 99 15) 2-Propanol (Isopropanol) 7.64 45 491518 10.498 ng 100 16) Acrylonitrile 7.91 53 124265 5.481 ng 99 17) 1,1-Dichloroethene 8.35 96 87443 5.739 ng 94 18) 2-Methyl-2-Propanol (t... 8.51 59 482267 11.342 ng 99 19) Methylene Chloride 8.58 84 91727 5.394 ng 93 20) 3-Chloro-1-propene (Al... 8.74 41 133980 5.444 ng 99 21) Trichlorotrifluoroethane 8.99 151 80642 5.549 ng 97 22) Carbon Disulfide 8.84 76 327417 5.583 ng 100 23) trans-1,2-Dichloroethene 9.85 61 126213 5.276 ng 96 24) 1,1-Dichloroethane 10.10 63 146212 4.740 ng 99 25) Methyl tert-Butyl Ether 10.20 73 270861 5.397 ng 99 26) Vinyl Acetate 10.35 86 122578 27.186 ng 97 27) 2-Butanone (MEK) 10.60 72 63483 5.091 ng 95 28) cis-1,2-Dichloroethene 11.11 61 119754 4.996 ng 98 29) Diisopropyl Ether 11.41 87 91809 5.353 ng 97 30) Ethyl Acetate 11.41 61 65158 10.941 ng 97 31) n-Hexane 11.40 57 133406 4.480 ng 97 32) Chloroform 11.46 83 145624 5.097 ng 99 34) Tetrahydrofuran (THF) 11.87 72 62313 5.490 ng 97 35) Ethyl tert-Butyl Ether 12.00 87 113748 5.396 ng 97 36) 1,2-Dichloroethane 12.26 62 107450 4.649 ng 100 38) 1,1,1-Trichloroethane 12.54 97 130326 5.722 ng 96 39) Isopropyl Acetate 12.97 61 114160 11.346 ng # 88 40) 1-Butanol 12.98 56 206441 10.971 ng 96 41) Benzene 13.02 78 340912 5.356 ng 99 42) Carbon Tetrachloride 13.18 117 110086 5.697 ng 99 43) Cyclohexane 13.31 84 291810 10.948 ng 100 44) tert-Amyl Methyl Ether 13.66 73 261596 5.983 ng 98 45) 1,2-Dichloropropane 13.87 63 88739 5.685 ng 100 46) Bromodichloromethane 14.06 83 114144 5.758 ng 100 47) Trichloroethene 14.11 130 96888 5.709 ng 99 48) 1,4-Dioxane 14.09 88 78376 5.876 ng 99 49) 2,2,4-Trimethylpentane... 14.18 57 411357 5.652 ng 95

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anusha.bayyarapu

Anusha

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2018_09\28\09281803.D Acq On : 28 Sep 2018 5:27 Operator: AB Sample : CCV R8092818_5ng Misc : S31-09081801/S31-09041803 (10/3) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Sep 28 10:58:07 2018 Quant Method : I:\MS08\Methods\R8091218.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Sep 13 10:44:42 2018 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.31 100 79067 11.998 ng 95 51) n-Heptane 14.44 71 92707 5.622 ng 99 52) cis-1,3-Dichloropropene 14.97 75 149602 6.533 ng 100 53) 4-Methyl-2-pentanone 15.01 58 88863 5.917 ng 100 54) trans-1,3-Dichloropropene 15.49 75 125592 5.885 ng 100 55) 1,1,2-Trichloroethane 15.67 97 87043 6.047 ng 98 58) Toluene 15.96 91 367779 5.100 ng 100 59) 2-Hexanone 16.20 43 219548 5.287 ng 99 60) Dibromochloromethane 16.37 129 101334 5.841 ng 99 61) 1,2-Dibromoethane 16.62 107 97841 5.815 ng 100 62) n-Butyl Acetate 16.84 43 244507 5.983 ng 98 63) n-Octane 16.96 57 80696 5.171 ng 99 64) Tetrachloroethene 17.10 166 108321 5.646 ng 99 65) Chlorobenzene 17.76 112 249497 5.344 ng 100 66) Ethylbenzene 18.11 91 422927 5.254 ng 100 67) m- & p-Xylenes 18.27 91 649567 10.487 ng 99 68) Bromoform 18.33 173 88172 6.193 ng 99 69) Styrene 18.59 104 268646 5.944 ng 99 70) o-Xylene 18.70 91 337368 5.405 ng 99 71) n-Nonane 18.88 43 196446 5.275 ng 98 72) 1,1,2,2-Tetrachloroethane 18.67 83 161047 5.579 ng 99 74) Cumene 19.22 105 442719 5.488 ng 99 75) alpha-Pinene 19.56 93 215274 5.455 ng 97 76) n-Propylbenzene 19.67 91 525632 5.663 ng 100 77) 3-Ethyltoluene 19.75 105 451753 5.799 ng 100 78) 4-Ethyltoluene 19.79 105 408811 5.538 ng 99 79) 1,3,5-Trimethylbenzene 19.86 105 364651 5.485 ng 100 80) alpha-Methylstyrene 19.99 118 194067 6.006 ng 93 81) 2-Ethyltoluene 20.03 105 439151 5.633 ng # 13 82) 1,2,4-Trimethylbenzene 20.22 105 371037 5.718 ng 100 83) n-Decane 20.31 58 9288 5.905 ng 99 84) Benzyl Chloride 20.33 91 272655 5.469 ng 100 85) 1,3-Dichlorobenzene 20.35 146 219403 6.074 ng # 65 86) 1,4-Dichlorobenzene 20.41 146 223800 6.083 ng 98 87) sec-Butylbenzene 20.46 105 499250 5.732 ng 99 88) 4-Isopropyltoluene (p-... 20.59 119 467391 5.742 ng 98 89) 1,2,3-Trimethylbenzene 20.59 105 368195 5.587 ng 100 90) 1,2-Dichlorobenzene 20.71 146 213707 6.104 ng 99 91) d-Limonene 20.72 68 144073 5.212 ng 99 92) 1,2-Dibromo-3-Chloropr... 21.10 157 78431 6.631 ng 92 93) n-Undecane 21.40 57 216588 5.559 ng 99 94) 1,2,4-Trichlorobenzene 22.23 180 159764 6.609 ng 99 95) Naphthalene 22.33 128 494509 6.300 ng 99 96) n-Dodecane 22.32 57 207954 5.669 ng 100 97) Hexachlorobutadiene 22.65 225 102992 6.377 ng 100 98) Cyclohexanone 18.40 55 140116 5.547 ng 97 99) tert-Butylbenzene 20.22 119 372011 5.708 ng 100 100) n-Butylbenzene 20.96 91 398409 5.917 ng 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8091218.M Fri Sep 28 12:27:04 2018 Page: 2

137 of 142

00915167


Data File: I:\MS08\Data\2018_09\28\09281803.D Acq On : 28 Sep 2018 5:27 Operator: AB Sample : CCV R8092818_5ng Misc : S31-09081801/S31-09041803 (10/3) ALS Vial : 16 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

100000

200000

300000

400000

500000

600000

700000

800000

900000

1000000

1100000

1200000

1300000

1400000

1500000

1600000

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

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n-U

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3-C

hlor

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pane

,Tn-

Buty

lben

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1,2-

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ltolu

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pha-

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hyls

tyre

ne,T

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hylb

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ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

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n-Pr

opyl

benz

ene,

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pha-

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ne,TC

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R8091218.M Fri Sep 28 12:27:05 2018 Page: 3

138 of 142

00915168

BFB

Data Path : I:\MS08\Data\2018_09\12\ Data File : 09121804.D Acq On : 12 Sep 2018 12:02 Operator : AB Sample : BFB Check Misc : S31-09081801 ALS Vial : 1 Sample Multiplier: 1

Integration File: LSCINT.P

Method : I:\MS08\Methods\R8091218.M Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) Last Update : Wed Sep 12 15:55:14 2018

17.20 17.40 17.60 17.80 18.00 18.20 18.40 18.60 18.80 19.00 19.20 19.40 19.60 19.80 20.00 20.20 20.40 20.60 20.80 21.000

100000

200000

300000

400000

500000

600000

700000

800000

Time-->


25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165 170 175 180 1850

20000

40000

60000

80000

100000

120000

m/z-->

Abundance Average of 19.089 to 19.100 min.: 09121804.D\data.ms (-)95

174

75

50

6837 61 878156 14345 117106 128 155148137 161

AutoFind: Scans 2842, 2843, 2844; Background Corrected with Scan 2834

| Target | Rel. to | Lower | Upper | Rel. | Raw | Result || Mass | Mass | Limit% | Limit% | Abn% | Abn | Pass/Fail |----------------------------------------------------------------------| 50 | 95 | 8 | 40 | 19.5 | 23963 | PASS || 75 | 95 | 30 | 66 | 48.8 | 59925 | PASS || 95 | 95 | 100 | 100 | 100.0 | 122821 | PASS || 96 | 95 | 5 | 9 | 6.7 | 8261 | PASS || 173 | 174 | 0.00 | 2 | 0.0 | 0 | PASS || 174 | 95 | 50 | 120 | 89.5 | 109952 | PASS || 175 | 174 | 4 | 9 | 7.7 | 8446 | PASS || 176 | 174 | 93 | 101 | 96.9 | 106547 | PASS || 177 | 176 | 5 | 9 | 6.6 | 7052 | PASS |----------------------------------------------------------------------

R8091218.M Wed Sep 12 16:07:10 2018 Page: 1

139 of 142

00915169

anusha.bayyarapu

Anusha

BFB

Data Path : I:\MS08\Data\2018_09\28\ Data File : 09281803.D Acq On : 28 Sep 2018 5:27 Operator : AB Sample : CCV R8092818_5ng Misc : S31-09081801/S31-09041803 (10/3) ALS Vial : 16 Sample Multiplier: 1

Integration File: LSCINT.P

Method : I:\MS08\Methods\R8091218.M Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) Last Update : Thu Sep 13 10:44:42 2018

17.20 17.40 17.60 17.80 18.00 18.20 18.40 18.60 18.80 19.00 19.20 19.40 19.60 19.80 20.00 20.20 20.40 20.60 20.80 21.000

200000

400000

600000

800000

1000000

1200000

Time-->


25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165 170 175 180 1850

20000

40000

60000

80000

100000

120000

140000

160000

m/z-->

Abundance Average of 19.089 to 19.100 min.: 09281803.D\data.ms (-)17495

75

5069

8737 6257 81 14345 117 128104 155148137 161

AutoFind: Scans 2842, 2843, 2844; Background Corrected with Scan 2833

| Target | Rel. to | Lower | Upper | Rel. | Raw | Result || Mass | Mass | Limit% | Limit% | Abn% | Abn | Pass/Fail |----------------------------------------------------------------------| 50 | 95 | 8 | 40 | 16.7 | 27325 | PASS || 75 | 95 | 30 | 66 | 45.0 | 73461 | PASS || 95 | 95 | 100 | 100 | 100.0 | 163157 | PASS || 96 | 95 | 5 | 9 | 6.6 | 10758 | PASS || 173 | 174 | 0.00 | 2 | 0.0 | 0 | PASS || 174 | 95 | 50 | 120 | 100.4 | 163755 | PASS || 175 | 174 | 4 | 9 | 7.5 | 12270 | PASS || 176 | 174 | 93 | 101 | 97.3 | 159253 | PASS || 177 | 176 | 5 | 9 | 6.6 | 10472 | PASS |----------------------------------------------------------------------

R8091218.M Fri Sep 28 12:27:32 2018 Page: 1

140 of 142

00915170

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Anusha

Date/Time File Name Sample ID Misc Info Operator Vial Comment

1 9/12/18 10:23 09121801.D Blank S31-09081801 AB 4

2 9/12/18 10:56 09121802.D Std Check S31-09081801 AB 16

3 9/12/18 11:29 09121803.D Blank S31-09081801 AB 4

4 9/12/18 12:02 09121804.D BFB Check S31-09081801 AB 1 Passes

5 9/12/18 12:35 09121805.D 0.1ng TO-15 ICAL Std. S31-09081801/S31-08201809 (9/18) AB 14




9 9/12/18 14:47 09121809.D 5.0ng TO-15 ICAL Std. S31-09081801/S31-08231804 (9/21) AB 15 R8091218.M

10 9/12/18 15:20 09121810.D 25ng TO-15 ICAL Std. S31-09081801/S31-08231801 (9/21) AB 16



13 9/12/18 16:59 09121813.D Blank S31-09081801 AB 1


15 9/12/18 18:04 09121815.D 25ng ICV Std. S31-09081801/S31-08211801 (9/19) AB 1 Passes

16 9/12/18 18:37 09121816.D 25ng ICV Std. S31-09081801/S31-08211801 (9/19) AB 1

17 9/12/18 19:10 09121817.D Blank S31-09081801 AB 4

Acrolein, CS2, Vinyl acetate, MEK, 1-butanol, methyl methacrylate, trans-1,3-dichloropropene, 2-hexanone, 1,2,4-trichlorobenzene: 0.5ng --> 100ng

Benzyl Chloride, n-undecane, n-dodecane: 1.0ng --> 100ng

Injection Log

Directory: I:\MS08\Data\2018_09\12\

ICAL R8091218.M passed for all compounds

Specific Ranges: Acetone, Trichlorofluoromethane, Acrylonitrile, 1,4-dioxane, MIBK, n-decane, d-limonene, Naphthalene: 0.2ng --> 100ng

J:\EXCEL\REPORT\TO15\Msd08\MS08day\2018\09\D08091218 Page 1 of 1141 of 142

00915171

anusha.bayyarapu

Anusha

Date/Time File Name Sample ID Misc Info Operator Vial Comment

1 9/28/18 4:20 09281801.D Blank S31-09081801 AB 4

2 9/28/18 4:54 09281802.D CCV C8092818_25ng S31-09081801/S31-09241803 (10/23) AB 1 Passes

3 9/28/18 5:27 09281803.D CCV R8092818_5ng S31-09081801/S31-09041803 (10/3) AB 16 Passes

4 9/28/18 6:00 09281804.D Blank S31-09081801 AB 4

5 9/28/18 6:45 09281805.D MB R8092818_1000mL S31-09081801 AB 1 Passes

6 9/28/18 7:18 09281806.D LCxS R8092818_25ng S31-09081801/S31-09171803 (10/16) AB 1

7 9/28/18 7:51 09281807.D LCxS R8092818_25ng S31-09081801/S31-09171803 (10/16) AB 1

8 9/28/18 8:24 09281808.D LCSxD R8092818_25ng S31-09081801/S31-09171803 (10/16) AB 1

9 9/28/18 8:57 09281809.D Blank S31-09081801 AB 4

10 9/28/18 9:33 09281810.D LCS R8092818_25ng S31-09081801/S31-09281801 (10/27) AB 1 Passes

11 9/28/18 10:29 09281811.D LCSD R8092818_25ng S31-09081801/S31-09281801 (10/27) AB 1 Passes

12 9/28/18 11:01 09281812.D Blank S31-09081801 AB 4

13 9/28/18 11:34 09281813.D P1804944-001dil (3.0mL) S31-09081801 AB 4

14 9/28/18 12:34 09281814.D P1804944-001 (15mL) S31-09081801 AB 2

15 9/28/18 13:07 09281815.D P1804884-001 (1000mL) S31-09081801 AB 5

16 9/28/18 13:40 09281816.D P1804884-002 (1000mL) S31-09081801 AB 6

17 9/28/18 14:13 09281817.D P1804884-003 (1000mL) S31-09081801 AB 7

18 9/28/18 14:46 09281818.D P1804884-004 (1000mL) S31-09081801 AB 3

19 9/28/18 15:25 09281819.D P1804830-001dil (4.0mL) S31-09081801 AB 4

20 9/28/18 15:58 09281820.D P1804830-001 (10mL) S31-09081801 AB 4

21 9/28/18 16:31 09281821.D P1804830-002 (6.0mL) S31-09081801 AB 4

22 9/28/18 17:26 09281822.D P1804830-003 (1000mL) S31-09081801 AB 2

23 9/28/18 17:59 09281823.D P1804830-004 (1000mL) S31-09081801 AB 3

24 9/28/18 18:32 09281824.D P1804830-004dup (1000mL) S31-09081801 AB 3 Passes for dup

25 9/28/18 19:05 09281825.D P1804804-001 (200mL) S31-09081801 AB 5

26 9/28/18 19:38 09281826.D P1804804-001dil (50mL) S31-09081801 AB 5

27 9/28/18 20:12 09281827.D P1804804-002 (100mL) S31-09081801 AB 6

28 9/28/18 20:45 09281828.D P1804804-002dil (25mL) S31-09081801 AB 6

29 9/28/18 21:18 09281829.D P1804804-003 (75mL) S31-09081801 AB 7

30 9/28/18 21:51 09281830.D P1804804-003dil (15mL) S31-09081801 AB 7

31 9/28/18 22:25 09281831.D P1804950-004 (500mL) S31-09081801 AB 9

32 9/28/18 22:58 09281832.D Blank S31-09081801 AB 4

33 9/28/18 23:31 09281833.D P1804950-011 (1000mL) S31-09081801 AB 8

34 9/29/18 0:05 09281834.D P1804950-012 (1000mL) S31-09081801 AB 10

35 9/29/18 0:38 09281835.D P1804950-013 (1000mL) S31-09081801 AB 11 IS fail

36 9/29/18 1:11 09281836.D P1804950-014 (1000mL) S31-09081801 AB 12

37 9/29/18 1:45 09281837.D P1804950-015 (1000mL) S31-09081801 AB 13

38 9/29/18 2:18 09281838.D P1804950-016 (1000mL) S31-09081801 AB 14

Injection Log

Directory: I:\MS08\Data\2018_09\28\

I:\EXCEL\REPORT\TO15\Msd08\MS08day\2018\09\D08092818 Page 1 of 1142 of 142

00915172

anusha.bayyarapu

Anusha

1

DEPARTMENT OF THE ARMY LONGHORN ARMY AMMUNITION PLANT

POST OFFICE BOX 220 RATCLIFF, AR 72951

December 27, 2018 DAIM-ODB-LO Mr. Rich Mayer U.S. Environmental Protection Agency Federal Facilities Section R6 1445 Ross Avenue Dallas, TX 75202-2733 Re: Draft Remedial Design/Remedial Action Work Plan, LHAAP-17 Burning Ground

No. 2 / Flashing Area, Group 2, Longhorn Army Ammunition Plant, Karnack, Texas, December 2018

Dear Mr. Mayer, One hard copy and one compact disc (CD) of the above-referenced document is being transmitted to you for your review. Review comments are requested by February 1, 2019. The document was prepared by Bhate Environmental Associates, Inc., (Bhate) team, on behalf of the Army as part of Bhate’s Performance Based Remediation contract for the facility. I ask that Kim Nemmers, Bhate’s Project Manager, be copied on any communications related to the project. The point of contact for this action is the undersigned. I may be contacted at 479-635-0110, or by email at [email protected]. Sincerely, Rose M. Zeiler, Ph.D. Longhorn AAP Site Manager Copies furnished: A. Palmie, TCEQ, Austin, TX (letter) P. Bruckwicki, Caddo Lake NWR, TX (1 hard copy and 1 CD) A. Williams, USACE, Tulsa District, OK (1 CD) N. Smith, USAEC, San Antonio, TX (1 CD) K. Nemmers, Bhate, Lakewood, CO (1 hard copy and 1 CD) P. Srivastav, APTIM, Houston, TX (letter)

00915173

1

DEPARTMENT OF THE ARMY LONGHORN ARMY AMMUNITION PLANT

POST OFFICE BOX 220 RATCLIFF, AR 72951

December 27, 2018 DAIM-ODB-LO Ms. April Palmie Texas Commission on Environmental Quality, Superfund Section, MC-136 12100 Park 35 Circle, Bldg D Austin, TX 78753 Re: Draft Remedial Design/Remedial Action Work Plan, LHAAP-17 Burning Ground

No. 2 / Flashing Area, Group 2, Longhorn Army Ammunition Plant, Karnack, Texas, December 2018

Dear Ms. Palmie, One hard copy and one compact disc (CD) of the above-referenced document are being transmitted to you for your review. Review comments are requested by February 1, 2019. The document was prepared by Bhate Environmental Associates, Inc., (Bhate) team, on behalf of the Army as part of Bhate’s Performance Based Remediation contract for the facility. I ask that Kim Nemmers, Bhate’s Project Manager, be copied on any communications related to the project. The point of contact for this action is the undersigned. I may be contacted at 479-635-0110, or by email at [email protected]. Sincerely, Rose M. Zeiler, Ph.D. Longhorn AAP Site Manager Copies furnished (letter only): R. Mayer, USEPA Region 6, Dallas, TX P. Bruckwicki, Caddo Lake NWR, TX A. Williams, USACE, Tulsa District, OK N. Smith, USAEC, San Antonio, TX K. Nemmers, Bhate, Lakewood, CO P. Srivastav, APTIM, Houston, TX

00915174

Documents

longhornaap.comlonghornaap.com/system/assets/AdminRecord/2018/2018...September 29, 2018 Marcia Olive Bhate Environmental Associates, Inc. 445 Union Blvd Ste 129 Lakewood, CO 80228