00022443THE APPLICATION OF A CONTINUOUS LEAK DETECTION SYSTEM TO PIPELINES AND ASSOCIATED EQUIPMENT

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    THE APPL ICATION O F A C ON T I N U OU S L EAK D ET EC T I ON SYSTEM

    TO PIPELINES A ND ASSOCIATED EQ UIPMENT

    Copyright Materail

    IEEE

    Paper

    No

    PCIC-88-45

    Chet Sandberg PE, Jim Holmes, Ken McCoy, Heinrich Koppitsch

    Raychem Corporation

    300

    Consti tution Dr. Menlo Park CA 94025

    Abstract

    In recent years the problem of leak detection in pipelines,

    tanks, and process vessels has been the focus of many man-

    hours of effort.

    This paper will look some examples of leaks

    occurring in pipelines, give a overview of classical eak detec-

    tion systems and give the engineering basis of a new type of

    detector system. This system is a flexible hydrocarbon sens-

    ing cable that can be installed along pipelines, in double con-

    tainment tanks and piping or in trenches to detect and locate

    leaks of common ndustrial hydrocarbon solvents or fuels while

    ignoring the presence of water. The simple electrical circuit is

    also described hat locates and detects a leak anywhere along

    the length of the sensor.

    Introduction

    Leaks of hazardqus fluids such as crude oil, gasoline, or

    chlorinated solvents can result in very serious environmental

    pollution f the leak is not quickly detected and repaired. Even

    domestic drinking water may become contaminated with toxic

    chemicals f the groundwater supplying aquifers and wells be-

    come contaminated with leaking Hydrocarbons. The

    U.S

    En-

    vironmental Protection Agency (EPA) has proposed

    regulations designed to prevent contamination of groundwater

    from the estimated 1.4 million underground storage tanks in

    service. This focus on leak detection is just as serious in the

    area of transmission pipelines. In one instance approximate-

    ly

    30,000

    arrels of No. 2 fuel oil was lost as a result of a leak

    in a buried pipeline n suburban New Castle County, Delaware.

    When the leak was investigated, t was found to be less than 1

    gallon per minute. The fuel oil seeped into the water table and

    threatened a downgradient stream and irrigation pond. Even

    though recovery wells were drilled, only about 10%of the fuel

    oil was recovered and significant economic resources were ex-

    pended(1). Continuous eak detection of small eaks has been

    difficult in the past, but a new technology is available to con-

    tinuously monitor pipeline transmission of hydrocarbons.

    Types of leaks in pipelines and piping systems

    Various types of leaks can occur in pipelines and piping sys-

    tems and there are various types of leak detectors to analyze

    each. The rupture eak is east common, but very dangerous.

    Catastrophic failure can cause significant damage to the en-

    vironment, especially in under sea and remote land applica-

    tion. These leaks are, however, he easiest to detect since hey

    are accompanied by easily measured pressure drops or

    volume discrepancies.

    A

    more difficult and equally dangerous leak is the small, hard

    to detect leak. Corrosion, erosion, weld or joint failure and

    fatigue can all lead to small leaks. Leaks as small as

    1

    gallon

    per hour can build up large lost volumes before they are

    noticed. Up to now, these types of leaks have been almost im-

    possible to detect with conventional means described below

    in the section Current Leak Detection Methods. The

    hydrocarbon sensor described later in this paper is the first

    economically feasible distributed system available to monitor

    pipelines or small or large leaks.

    Current Leak Detection Methods

    Leak detection systems are classified nto wo main categories,

    static and dynamic. Dynamic systems are preferred since they

    can be used while the pipeline is operating. Static leak detec-

    tion methods are useful after a leak has been detected n order

    to find its location. Continuous monitoring of pipelines gives

    rise to a number of leak detection echniques. Meter variance

    or compensated volume balance is the predominate method.

    This method s limited by the accuracy of the volume measure-

    ment and the variations associated with it. Pressure monitor-

    ing and rate of flow can detect large leaks and over-and-short

    calculations can detect smaller leaks. Differential-pressure

    transmitters across sectionalizing valves can continuously

    monitor for a negative pressure which indicates a large leak.

    Another method was attempted by wrapping an oil soluble

    tubing around certain critical sections of pipeline. The internal

    pressure of this tubing was then monitored for

    loss

    of pres-

    sure. However, this system was a complete failure and aban-

    doned

    (2).

    Compensated Volume Balance

    The current major method of leak detection is the compen-

    sated volume balance method. This method essentially

    measures the volume in and subtracts the volume out .

    There are meters which are guaranteed repeatable to within

    .05 . In a typical system such as one in operation in Alaska

    from the Tesoro Nikiski refinery on the Kenai Peninsula to

    Anchorage 3), n alarm will sound when there is a significant

    difference in volume. The pump station management will

    determine

    f

    the difference in the two measured volumes is the

    result of an operational change or

    if

    the pipe s leaking. Opera-

    tional changes can result from a change in product grade,

    change of pumps or pumping pressure, or a change in

    temperature because of storage tank changes.

    If

    there has not been a change in operational criteria, the

    pipeline will be shut down and sections blocked with valves to

    isolate he possible eak. If before shutting down the pipeline,

    the discrepant volume should increase by a factor

    of

    2 the

    pumping stations will automatically be shut down. Should a

    241

    88CH2661-7/88/0000-0241 01.00 988 IEEE

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    rupture of the pipeline occur a negative surge will travel back

    to a pumping station and will be detected by a suction- pres-

    sure switch and the pipeline will be shut down. Vibratory sen-

    sors are located at the pumping stations and will detect an

    earthquake of 3.0 on the Richter scale and shut down the

    pipeline.

    The problem in the compensated volume method is there

    usually needs to be a large volume before conclusive leak

    detection can be made. Leaks of 2% for liquids and 10% for

    gasses are needed for detection, accord ing to some

    authorities. Smaller leaks can be can be detected with a non-

    linear adaptive state basis

    on

    pressure and flow measure-

    ments at the inlet and outlet. 4) However, based on flows of

    IO bb/hr., the leaks can be significant before they are

    detected.

    Acoustic Traveling Pig

    A

    novel leak detector is the Texaco pig which detects a leak

    by sensing the acoustic energy generated by escaping fluid.

    The location is recorded by an on-board odometer and this

    data correlated to the ultrasonic data thereby detecting the

    leak. The leak detector instrument is articulated in four sec-

    tions: two for rechargeable batteries, one for a printer, and

    one for the hydrophone and circuit cards. The articulated Pig

    is used on pipe sizes from

    6

    in to

    10

    in. Twelve inch pipe is

    checked by a model having all components in a single section.

    5)

    Leaks were successfully detected and located by the pig

    in field pipelines in Canada and Texas.

    Thermal and electro-optical methods

    An airborne remote sensor can detect leaks from natural gas

    pipelines by monitoring he methane and ethane gas in the at-

    mosphere above the pipeline. The sensor is a passive electro-

    optical system, operating in a downward-looking mode. It is

    designed to detect low levels of methane and ethane by look-

    ing at their infra-red spectral signatures using a non-dispersive

    gas filter correlation technique. This system is experimental

    and the results of the field trials are unknown to the authors.

    6)

    A

    similar airborne system using thermal infrared images has

    been tested on water distribution systems in South Dakota. A

    typical system has from

    640

    to 2400 KM of pipeline and the

    normal line water loss is 10 to 15 per cent. Major leaks,

    generally from

    10

    to 200 cubic meters per day, are easy to

    identify because they usually pond. Minor leaks, called

    seeper leaks, which generally range from 2 to

    10

    cubic

    meters per day are more common and are difficult to detect

    using conventional ground surveys. Fifteen possible leaks

    were identified from thermal images. Five of these sites were

    eventually confirmed as leaks.

    7)

    Hydrocarbon distributed sensor cable

    The hydrocarbon sensor system

    8 )

    consist of an alarm

    module and sensing cable. This sensing cable provides dis-

    tributed coverage by detecting eaks of most uels and solvents

    at any point along its length. The cable can be used in engths

    of up to

    2

    Kilometers with a resolution of approximately

    1%

    of

    the length for leak detection. The core of the cable, Figure 1,

    is constructed of an alarm signal wire, a continuity wire and

    two sensor wires. It is encased in a conductive-polymer ayer

    242

    signal

    sensor

    .

    --

    cbnductive Halar'

    polymer layer braid

    Figure 1

    that swells during exposure to most hydrocarbon-based

    sol-

    vents and fuels. This material is surrounded with a Halar (9)

    braid that restrains outward swelling. When a solvent or fuel

    contacts the cable, the conductive- polymer swells inward and

    makes electrical contact with the two sensor wires. The cable

    must be replaced once it has contacted a solvent or fuel.

    This sensor has combined unique radiation chemistry and con-

    ductive polymer technologies to develop an industrial system.

    The conductive polymer formulation is key to the success of

    the device. The formulationmust swell rapidly and remain con-

    ductive if the sensor is to detect the fluid of interest. Addition-

    ally, the polymer must develop sufficient swelling pressure to

    force the conductive formulation through the apertures of the

    braided sensing cable to contact the sensor wires. If the

    polymer is not crosslinked t will not swell, but simply dissolve.

    Therefore, the formulation

    is

    crosslinked using radiation

    chemistry to form a solvent-swellable, three dimensional

    polymer network. The expansion pressure generated by this

    network is a function of the crosslink density and interaction

    between the polymer and solvent. (10 and 11)

    Two formulations were developed to cover the range of com-

    mon industrial solvents and fuels. One formulation was

    developed to swell rapidly in non-polar hydrocarbons such as

    diesel fuel and gasoline and was used to prepare a fuel sens-

    ing cable. Another formulation was used o fabricate a solvent

    sensing cable for the detection of polar fluids such as

    chlorinated solvents.

    Although the time taken for the sensing cables to respond in

    a given fluid is a key property of the sensor, other factors must

    also be considered. The cable must be rugged, yet flexible,

    so that it can be easily pulled through double containment

    enclosures. The formulations must not beso soft that any ac-

    cidental oading will cause the conductive polymer formulation

    to contact the sensor wires and trigger the circuit. Finally the

    conductive polymer layer must be continuous and act as a

    water barrier to prevent the sensor from triggering.

    Testing was conducted on several thousand feet of sensor

    cable with a nominal outside diameter of 0.3 inches. The con-

    ductive polymer layer was cross-linked using a high energy

    electron beam. The cable was cut into convenient engths. An

    initial resistance of greater than 30 megohm was measured

    and specified to be equivalent to a sensor in its non-triggered

    state. Five cm. of the cable was completely mmersed n a fluid

    and the time taken for the resistance o fall below 20 kilo-ohms

    was measured. This time represents the response time of

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    the sensor since the alarm and locator module register the

    presence of a fluid at this resistance value. Response time

    after water immersion, bend diameter and pressure triggering

    were also measured. The tests showed the resistance be-

    tween sensor wires remained greater than 30megohms after

    water immersion, a bend radius of less than 5 cm was needed

    to trigger the cable and a minimum trigger load of 20 pounds

    per linear inch was needed to trigger the alarm.

    Fuel sensing cable response times are dependent on the

    molecular weight of the target hydrocarbon.

    Gasoline takes

    15

    minutes, while diesel

    2

    and Toluene take

    60

    minutes.

    Automatic ransmission luid takes 4 to 6 hours. This response

    time is based on 2 inches of cable length immersed n the liq-

    uid whose temperature is 20 deg C.

    Response times are af-

    fected by operating temperature.

    Electrical Circuitry for Leak Detection

    The hydrocarbon sensor makes use of a four wire circuit

    shown schematically n Figure2. The sensing electrodes are

    represented by the zigzag lines, while the insulated telemetry

    pair are indicated by the solid lines on the top and bottom of

    the circuit. The key elements of the leak locating circuitry are

    High lmpedence Voltmeter

    onstant Current Source

    Hydrocarbon Sensor Electrical Schematic

    Figure

    2

    the constant current source and the high impedance volt

    meter. Also note that the four conductors are joined to form

    two loops at the far end of the monitored section.

    If

    the cable has not been swollen by a hydrocarbon eak, there

    is no path between the two electrodes and no current flows

    from the constant current source. As shown in Figure3, a leak

    that swells the polymer between he two electrodes completes

    the loop and the current source can now generate a current

    flow in the closed circuit.

    Hydrocarbon Sensor Electrical Schematic

    Figure

    3

    The high mpedancevoltmeter s now used o measure the volt-

    age drop,

    V,

    between the leak location and the instrument.

    Since the current is known (i. e. a constant current source) and

    the voltage is measured, the resistance of the cable between

    the leak and the instrument can be calculated using Ohms

    R=V/I . Finally, if the resistance per meter of cable is known

    (this is controlled by accurate manufacturing olerances) then

    the location in terms of distance is a simple scale conversion.

    Long Pipeline Telemetry

    Since the effective range of the hydrocarbon sensor is about

    2 KM, continuous surveillance of a long pipeline needs some

    sort of telemetry o relay leak detection nformation o a central

    location. The type of telemetry equipment chosen is common-

    ly used in the telephone industry to monitor pressure

    transducers attached to pressurized telephone cable. The

    variations n air pressure are converted o a variable resistance

    by the pressure transducer. The variation in resistance is in

    turn used to modulate a signal on the two wire telemetry cir-

    cuit

    so

    that the equipment located at the end of the line is able

    to determine the air pressure at each of the transducer loca-

    tions. The transducers are each assigned an individual iden-

    tity at the time of installation. The multiplexingscheme is based

    on a time splice echnique so that only one of the many trans-

    mitters on a given line is transmitting ts measured value at any

    given time. The master unit at the head of the line starts the

    report ing sequence by a voltage step monitored by all units.

    For detection of a hydrocarbon leak, the pressure transducer

    is replaced by a loop formed from the sensor pair in the

    hydrocarbon sensor cable and an end of line resistor.

    If

    the

    cable is in a non-triggered state, then the transducer circuit

    sees a predicted resistance value and the signal returned to

    the monitoring equipment is within the normal range.

    If

    the

    cable has been soaked by a hydrocarbon, he resistance seen

    by the transducer on the monitoring equipment is shifted

    downward in frequency and the monitor recognizes the leak

    occurrence. If the sensing oop is broken, the transducer sees

    a sudden rise in resistance. The signal returned o the monitor

    is shifted up n requency and he monitor recognizes an open

    in the sensor.

    When a leak is detected, maintance personnel must go to the

    monitor location and hook up a Portable Test Box (PTB) to

    determine he exact location in the 2 KM section of leak detec-

    tion cable. Three different situations can occur to trigger an

    alarm. There can be a continuity fault, a single contamination

    site on the sensing cable or multiple contamination sites on the

    sensing cable. The PTB can be used to determine which of

    the three possibilities are present.

    Conclusion

    The hydrocarbon sensor has shown itself to be a significant

    advancement in the technology available for leak detection.

    Distributed systems have in the past not been economically

    feasible for pipelines and other large systems, leaving volume

    balance systems o determine eaks.

    As

    discussed, he volume

    systems have limitations on low leak rates, which the sensor

    cable system does not have. The hydrocarbon sensor can be

    used for tank farms, ponds, and double containment piping

    systems(l2). The same electronic systems can be used for

    water sensor cables and acid and base sensor cables.

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    References:

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    from Groundwater Beneath a Densely Populated Housing

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    Alaska’s Nikishi Product Line Com-

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    of

    a Pipeline

    Leak Detector, Journal of Canadian Petroleum Technology

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    6. Lee, H. S. et al, Gas Pipeline Leak Sensor Gaspils) for

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    tion. Edmonton, Alberta, Can June 1983 p 555-565

    7. Eidenshink, J. C., Detection of Leaks in Buried Rural

    Water Pipelines Using Thermal Infrared Images,

    Photogrammetric Engineering and Remote Sensing v51 n5

    May

    1985

    p 561-564

    8. Raychem Corporation,TraceTek Fuel and Solvent Sens-

    ing Cables, Literature Number H52858 August 1987

    Halar is a registered trademark of Allied Corporation

    10. Treloar, L. R. G., The Physics of Rubber Elasticity,Ox-

    ford University Press, London, p 123, 1985

    11. Gehman, S .

    D.,

    Rubber Chem. Technology, 40(21), p

    632, 1967

    12. National Engineer, New Pipe System Stops Leaking

    Fluid Lines,v91 n4 April 1987 p 15

    13. Williams,

    R.

    I. Fundamentals of Pipeline Instrumenta-

    tion, Automation, and Supervisory Control, ISA Transactions

    v 21 n l 1982 p 45-54

    14. Fannelop, Torstein K. Flow Processes and Leak Rates

    Associated with Broken Underwater Oil Pipelines, Nor-

    wegian Maritime Research v5 n l 1977 p 6 13

    15. Nicholas, R. E., Leak Detection by Model Compensated

    Volume Balance, Pipeline Engineering Symposium 1987 Dal-

    las Texas Feb 15- 18, 1987, p 13-20

    16. Pipes and Pipelines International,

    New Pipeline Leak

    Detection Pig, v21 n4 Aug 1976 p 26-28

    18. Fukuda, T., et al, Leak Detection and Localization in a

    Pipeline System Based on Time Series Analysis Techni-

    ques, Journalof Fluid ControlVIn4 Dec 1983 p 5-17

    19. Lippitt, T.,

    Williams Pipe Leak Detection System,

    Pipeline Engineering Symposium 1987 Dallas Texas ASME

    PD v6 p 35-41

    20

    Atherton, David, Magnetic Detection

    of

    Pipeline Cor-

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    Chet

    Sandberg,PE,

    received his

    BS

    degree from MIT

    in

    1967 and his

    MS

    from Stanford University n 1972. In 1972 he oined the Raychem Corpora-

    tion in the Chemelex Heating Systems Division. He has held various posi -

    tions at Raychem including Technical Strategy Manager, Electrical

    Engineering Manager of the Chemelex Division and Consumer Products

    Division Manager. He has managed and participated in research and

    development of fiber optic sensors, conductive polymer heating elements

    and process instrumentation systems. Chet is a Professional Electrical En-

    gineer

    in

    he State of California, hdds

    5

    patents and has published Over

    I5

    technical papers on fiber optics, sensor technology, and electric heat trac-

    ing. Chet is a member of IEEE, ASME and ISA. and is chairman of the IEEE

    622 Working Group on Heat Tracing. He s a founder of several small star-

    tup companies in the Palo Alto area where he l i e s with his wife and

    daughter. When not inventing, he loves to ski, sail and keep his 80286 PC

    humming.

    Jim Holmes

    is

    the Technical Director

    of

    Raychem’s TraceTek Products

    Group. He started with Raychem n 1977 and

    has

    worked in development

    and technical positions with Raychem’s elecommunications products and

    pipeline corrosion protect ionproducts prior o his current position. He has

    a B.

    S. in

    Product Design rom Stanford University and anM

    S.

    n Engineer-

    ing Management rom Stanford University.

    Ken McCoyreceivedhis BSEEdegreefrom NorthwesternUniversity n 1971

    and an MBA from the University of Santa Clara in 1976. After serving with

    the United States Navy and a period of consulting work with SRI Internation-

    al, he joined Raychem in 1977. Ken held various positions with the

    PetrdeumTechndogy Divisionand was involvedwitha number of corrosion

    control products used as pipeline coatings and for cathodic protection. In

    1984, Ken was part of a small start-up group that formed the TraceTek

    Division. He is now the operations manager or TraceTek and combines his

    manufacturing responsibilities with sales support and marketing in the

    Pacific Rim countries. Ken spends his free time on the ski slopes or sailing

    on San Francisco Bay.

    HeinrichKoppRsch received his Dipl. Ing. degree from Technical Univer-

    sity, Graz, Austria in 1974. He then worked at Waagner- Biro in technical

    sales of turnkey power plants. Heinrich received his MBA at h e a d , France

    in 1980. He oined Raychem n 1980 and has held various sales and market-

    ing positions with the Chemelex Division n Germany, France and he United

    States. He is currently Marketing Manager for the TraceTek Products

    Group.

    17.

    Butts,

    E. O., Detecting Leaks in Pipelines and Storage

    Tanks, Engineering Journal (Montreal)v6 n3 May-Jun 1977

    p45-47

    244 -