0022-3727_39_15_E01

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    Tribocorrosion: fundamentals, materials and applications

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    2006 J. Phys. D: Appl. Phys. 39

    (http://iopscience.iop.org/0022-3727/39/15/E01)

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    INSTITUTE OF PHYSICS PUBLISHING JOURNAL OF PHYSICS D: APPLIED PHYSICS

    EDITORIAL

    Tribocorrosion: fundamentals, materialsand applications

    Guest Editors

    Alfons FischerUniversitat Duisburg-Essen,Germany

    Stefano MischlerEcole Polytechnique Federale

    de Lausanne, Switzerland

    Tribocorrosion covers the science of surface transformations resulting from theinteraction of mechanical loading and chemical reactions that occur betweenelements of a tribosystem exposed to corrosive environments. Thus it combinesthe mechanical and chemical interactions of body, counterbody, interfacialmedium, and environment including friction, lubrication, wear and tribologicallyactivated chemical and electrochemical reactions. During friction the adhesivedissipation of energy is often influenced by chemical effects, while during wear

    the wear mechanisms of adhesion as well as tribochemical reactions areaffected. The latter mechanism is of interest in mechanical engineeringparticularly, because it might prevent adhesion, which would bring about a muchhigher wear rate or even seizure. Nevertheless, in electronics as well as forMEMS and NEMS, chemical reactions are often avoided because they change thenature (e.g. conductivity, reactivity) of surfaces of sensors or alter the dimensionsof parts within the nm- and m-range by the growth of a reaction layer. Thus,depending on the structure and loading of the tribosystem, tribocorrosionphenomena could be either beneficial or detrimental.

    In order to benefit from tribocorrosion phenomena it is crucial to control them aswell as the nature of rubbed or worn surfaces, which have undergone tribologicalstresses. Unfortunately, the tribocorrosion mechanisms are still not well

    understood. Reasons for this stem not only from the complex interactions ofchemical and mechanical factors but also from the experimental difficulty ofcharacterizing mechanically and/or thermally induced surface phenomenaoccurring inside small contacts. Due to the fact that the duration of a singleasperity contact is short and that it takes place directly at the interface ofcontacting bodies, even modern surface analysing techniques often fail. Manyreactions could take place at the same time and the quantity of reaction productsmight be very small. In addition, metastable phases might be important inside acontact, which then transform into stable reaction products outside of the contact.Thus, in situ techniques are most suitable for tribocorrosion investigations. In thecase of electronically conducting materials exposed to ionic conductive liquids,such as aqueous solutions, triboelectrochemical techniques offer interesting

    possibilities to control, in situ and in real time, the surface reactions occurring in acontact. However, further experimental developments are needed to obtain aclearer picture of the processes involved. Thus, tribocorrosion has been a point ofbasic research for more than 40 years and will remain as such in the near future.

    This special cluster issue within Journal of Physics D: Applied Physics providesstate-of-the-art information on tribocorrosion. Due to the fact that this researcharea is very large and complex, the given selection of papers will certainly not berepresentative of the entire field. The editors have tried, however, to offer aglimpse of what happens with metals, ceramics, and polymers when exposed tothe combined action of friction and corrosion. Thus, this issue begins with a viewon general and basic aspects of tribocorrosion. This is followed by papers whichconcentrate on the materials response to tribocorrosion and contributions related

    to abrasion and surface fatigue wear mechanisms. Finally the influence oftribocorrosion on certain applications is presented. This cluster should encourage

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