Upload
mohamed-karim-mohamed
View
219
Download
2
Embed Size (px)
Citation preview
7/29/2019 1- Heat Treatment
1/61
HEAT TREATMENT
7/29/2019 1- Heat Treatment
2/61
7/29/2019 1- Heat Treatment
3/61
7/29/2019 1- Heat Treatment
4/61
The Fe-C diagram in Fig. 1 is of experimental origin.
The knowledge of the thermodynamic principles and modern
thermodynamic data now permits very accurate calculations of
this diagram.
If alloying elements are added to the iron-carbon alloy (steel),
the position of the A1, A3, and Acm boundaries and the
eutectoid composition are changed
(1) all important alloying elements decrease the eutectoidcarbon content, (2) the austenite-stabilizing elements
manganese and nickel decrease A1
(3) the ferrite-stabilizing elements chromium, silicon,
molybdenum, and tungsten increase A1.
7/29/2019 1- Heat Treatment
5/61
Table 1 Important metallurgical phases and microconstituents
CharacteristicsCrystal structure of phases
Phase
(microc
onstitu
ent)
Relatively soft low-temperature phase; stable equilibrium phasebccFerrite (-iron)
Isomorphous with -iron; high-temperature phase; stable equilibrium phasebcc-ferrite (-
iron)
Relatively soft medium-temperature phase; stable equilibrium phasefccAustenite (-
iron)
Hard metastable phaseComplex orthorhombicCementite
(Fe3C)
Stable equilibrium phaseHexagonalGraphite
Metastable microconstituent; lamellar mixture of ferrite and cementitePearlite
Hard metastable phase; lath morphology when 1.0 wt% C and mixture of those in
between
bct (supersaturated solution
of carbon in ferrite)
Martensite
Hard metastable microconstituent; nonlamellar mixture of ferrite and cementite on an extremely fine scale; upper bainite
formed at higher temperatures has a feathery appearance; lower bainite formed at lower temperatures has an
acicular appearance. The hardness of bainite increases with decreasing temperature of formation.
. . .Bainite
7/29/2019 1- Heat Treatment
6/61
Accm. In hypereutectoid steel, the temperature at which the solution of cementite in austenite is
completed during heating.
Ac1. The temperature at which austenite begins to form during heating, with the c being derived fromthe French chauffant.
Ac3. The temperature at which transformation of ferrite to austenite is completed during heating.
Aecm, Ae1, Ae3. The temperatures of phase changes at equilibrium.
Arcm. In hypereutectoid steel, the temperature at which precipitation of cementite starts during
cooling, with the r being derived from the French refroidissant.
Ar1. The temperature at which transformation of austenite to ferrite or to ferrite plus cementite is
completed during cooling.
Ar3. The temperature at which austenite begins to transform to ferrite during cooling.
Ar4. The temperature at which delta ferrite transforms to austenite during cooling.
Ms(or Ar''). The temperature at which transformation of austenite to martensite starts duringcooling.
Mf. The temperature at which martensite formation finishes during cooling.
7/29/2019 1- Heat Treatment
7/61
7/29/2019 1- Heat Treatment
8/61
One can conveniently describe what is happening during
transformation with transformation diagrams. Four differenttypes of such diagrams can be distinguished. These include:
Isothermal transformation diagrams describing the
formation of austenite, which will be referred to as
IT diagrams
Isothermal transformation (IT) diagrams, also referred to
as time-temperature-transformation (TTT)
diagrams, describing the decomposition of austenite
Continuous heating transformation (CHT) diagrams
Continuous cooling transformation (CCT) diagrams
7/29/2019 1- Heat Treatment
9/61
ITh Diagrams (Formation of Austenite).
During the formation of austenite from anoriginal microstructure of ferrite and pearlite or
tempered martensite, the volume (and hence the
length) decreases with the formation of the
dense austenite phase (see Fig. 3). From the
elongation curves, the start and finish times for
austenite formation, usually defined as 1% and
99% transformation, respectively, can bederived.
7/29/2019 1- Heat Treatment
10/61
Fig. 3 The procedure for determining isothermal heating (ITh)
diagrams. Line 1: Temperature versus time. Line 2: Elongation versus
time. S represents the start and F the finish of the transformation of theoriginal microstructure to austenite transformation, respectively.
7/29/2019 1- Heat Treatment
11/61
(Fig. 4). Below Ac1 no austenite can form, and between Ac1 and Ac3
the end product is a mixture of ferrite and austenite.
7/29/2019 1- Heat Treatment
12/61
Volume change, %(a)Transformation
4.64-2.21 (%C)Spheroidized pearlite-austenite
4.64-0.53 (%C)Austenite-martensite
4.64-1.43 (%C)Austenite-lower bainite
4.64-2.21 (%C)Austenite-upper bainite
Volume changes due to different transformations
7/29/2019 1- Heat Treatment
13/61
Hardenability Concepts The goal of heat treatment of
steel is very often to attain asatisfactory hardness. Theimportant microstructural
phase is then normallymartensite
The hardness of martensite isprimarily dependent on itscarbon content as is shown inFig
In practical heat treatment, itis important to achieve fullhardness to a certainminimum depth after cooling,that is, to obtain a fullymartensitic microstructure to acertain minimum depth, which
also represents a criticalcooling rate.
CCT diagrams constructedaccording to Atkins orThelning can serve thispurpose if one knows the
cooling rate at the minimumdepth
S f l h d i ll hi i th
7/29/2019 1- Heat Treatment
14/61
Successful hardening usually means achieving therequired microstructure, hardness, strength, ortoughness while minimizing residual stress, distortion,and the possibility of cracking.
The selection of a quenchant medium depends on thehardenability of the particular alloy, the section thicknessand shape involved, and the cooling rates needed toachieve the desired microstructure. The most commonquenchant media are either liquids or gases.
The liquid quenchants commonly used include:
Oil that may contain a variety of additives Water
Aqueous polymer solutions
Water that may contain salt or caustic additives
The most common gaseous quenchants are inert gasesincluding helium, argon, and nitrogen. These quenchantsare sometimes used after austenitizing in a vacuum.
7/29/2019 1- Heat Treatment
15/61
Jominy End-Quench Test.
The most commonly used experimental method forhardenability is the well-known Jominy test
For this test a round bar specimen that is 100 mm (4 in.)in length and 25 mm (1 in.) in diameter is used. The
specimen is heated to the austenitizing temperature ofthe steel with a holding time of 20 min. One end face ofthe specimen is quenched by spraying it with a jet ofwater. This causes the rate of cooling to decreaseprogressively from the quenched end along the length of
the bar. The hardness values are plotted on a diagram at
specified intervals from the quenched end.
7/29/2019 1- Heat Treatment
16/61
Fig. Calculated hardness (dashed line) and reported hardness (solid
line) from a Jominy test of AISI 4130 steel.
7/29/2019 1- Heat Treatment
17/61
Principles of Tempering of Steels
Martensite is a very hard phase in steel. It owe its high
hardness to a strong supersaturation of carbon in the iron
lattice and to a high density of crystal defects, especiallydislocations, and high- and low-angle boundaries. However,except at low carbon contents, martensitic steels haveinsufficient toughness for many applications.
Tempering of martensitic steels, by heating for a certain timeat temperatures below the A1, is therefore introduced to
exchange some of the strength for greater ductility throughreduction of the carbon super saturation initially present andreplacing it with more stable structures. Additionally, theretained austenite associated with martensite in steelscontaining more than about 0.7 wt% C can be decomposedduring the tempering process. In carbon steels containing
small percentages of the common alloying elements, onedistinguishes the following stages during tempering
In steels alloyed with chromium, molybdenum, vanadium, ortungsten, formation of alloy carbides occurs in the temperaturerange 500 to 700 C During stage 1, the hardness increases slightlywhile during stage 2, 3, and 4 the hardness decreases.
7/29/2019 1- Heat Treatment
18/61
TEMPERING OF STEEL
is a process in which previously hardened or normalized steel isusually heated to a temperature below the lower critical temperatureand cooled at a suitable rate, primarily to increase ductility andtoughness, but also to increase the grain size of the matrix. Steelsare tempered by reheating after hardening to obtain specific valuesof mechanical properties and also to relieve quenching stresses andto ensure dimensional stability.
Tempering usually follows quenching from above the upper critical
temperature; however, tempering is also used to relieve the stressesand reduce the hardness developed during welding and to relievestresses induced by forming and
machining.
Principal Variables
Variables associated with tempering that affect the microstructure
and the mechanical properties of a tempered steel include: Tempering temperature
Time at temperature
Cooling rate from the tempering temperature
Composition of the steel, including carbon content, alloy content,
and residual elements
7/29/2019 1- Heat Treatment
19/61
Fig. Tempering curves for some current steels. The steel 42CrMo4is equivalent to AISI 4142 and C45 to AISI 1045.
7/29/2019 1- Heat Treatment
20/61
Temper embrittlement The toughness of a steel increases with decreasing hardness.
However, when certain impurities such as arsenic, phosphorus,antimony, and tin are present, a toughness minimum "temperembrittlement" may occur in the temperature range 350 to 600C due to segregation of impurities to grain boundaries.
Temper embrittlement is a problem when parts are exposed totemperatures in the critical range for rather long times and is aconcern for parts exposed to these temperatures while inservice or when heat treating very massive parts which requirelong times to heat and cool.
It is not a concern, even for susceptible alloys, if small partsare exposed to these temperatures for an hour or so duringheat treatment, then used at ambient temperatures. Nuts andbolts, for example, made of various types of steels, are
tempered in this temperature range with no problems as longas they are used at lower temperatures. The time forembrittlement to occur at differing tempering temperaturesshows a C-shaped curve behavior
. Temper embrittlement can be removed by reheating the steelabove 600 C (1110 F) followed by rapid cooling, for example,
water quenching.
7/29/2019 1- Heat Treatment
21/61
Martensite embrittlement
Another type of embrittlement that affects high-strength alloysteels is tempered martensite embrittlement (also known as 350C, or 500 F, embrittlement), which occurs upon tempering inthe range of 205 to 370 C (400 to 700 F). It differs from temperembrittlement in the strength of the material and thetemperature exposure range. In temper embrittlement, the steel
is usually tempered at a relatively high temperature, producinglower strength and hardness, and embrittlement occurs uponslow cooling after tempering and during service attemperatures within the embrittlement range. In temperedmartensite embrittlement, the steel is tempered within theembrittlement range, and service exposure is usually at room
temperature. Therefore, temper embrittlement is often calledtwo-step temper embrittlement, while tempered martensiteembrittlement is often called one-step temper embrittlement
7/29/2019 1- Heat Treatment
22/61
MARTEMPERING
is a term used to describe an interrupted quench from theaustenitizing temperature of certain alloy, cast, tool, and stainless
steels. The purpose is to delay the cooling just above the martensitictransformation for a length of time to equalize the temperaturethroughout the piece. This will minimize the distortion, cracking, andresidual stress. The term martempering is somewhat misleading andis better described as marquenching. The microstructure aftermartempering is essentially primary martensitic that is untemperedand brittle.
Figure 1(a and b) shows the significant difference betweenconventional quenching and martempering. Martempering of steel(and of cast iron) consists of:
Quenching from the austenitizing temperature into a hot fluidmedium (hot oil, molten salt, molten metal, or a fluidized particlebed) at a temperature usually above the martensite range (Ms point)
Holding in the quenching medium until the temperature throughoutthe steel is substantially uniform
Cooling (usually in air) at a moderate rate to prevent largedifferences in temperature between the outside and the
center of the section
7/29/2019 1- Heat Treatment
23/61
Time temperature transformation diagrams with superimposed cooling
curves showing quenching and tempering.(a) Conventional process. (b) Martempering. (c) Modified martempering
The advantage of martempering lies in the reduced thermal gradientbetween surface and center as the part is quenched to
the isothermal temperature and then is air cooled to room temperature.
7/29/2019 1- Heat Treatment
24/61
Thermal Stresses during and Residual Stresses after
Heat Treatment
Heat treatment of steel, is usually accompanied by thelarge residual stresses, that is, stresses that existwithout any external load on the part considered.Causes for such stresses include:
1. Thermal expansion or contraction of a homogeneousmaterial in a temperature gradient field
2. Different thermal expansion coefficients of the variousphases in a multiphase material
3. Density changes due to phase transformations in themetal
4. Growth stresses of reaction products formed on thesurface or as precipitates, for example, external andinternal oxidation
7/29/2019 1- Heat Treatment
25/61
Cracking and Distortion due to Hardening.
Hardening is usually accompanied by distortion of a
workpiece. The degree of distortion depends on the
magnitude of the residual stresses.
Hardening procedures that minimize transient and residual
stresses are beneficial as well as the use of
fixtures (press hardening). Distortion can also occur during
tempering or annealing due to release of residual stresses or
phase transformations during tempering as describedpreviously
There is a risk for cracking of a workpiece if large tensile
stresses, transient or residual, are combined with the
presence of a brittle microstructure (particularly martensite).
Thermal stresses during cooling generally increase with thesize of a workpiece.
7/29/2019 1- Heat Treatment
26/61
Formation of residual stress on cooling considering thermal expansion and the austenite to
martensite transformation. The dashed line is the yield stress, s, at the surface.
7/29/2019 1- Heat Treatment
27/61
HARDENABILITY STEELS
H-steels, offer a wide range of mechanical properties thatdepend on the development of tempered martensite afterquenching and tempering. Typical room-temperatureproperties of quenched and tempered steels can vary as
follows: Hardness values of 130 to 700 HV (30 kgf load)
Tensile strengths of 400 to 2000 MPa (58 to 290 ksi)
Yield strengths of 300 to 1800 MPa (43 to 261 ksi)
Elongation of 8 to 28% in 50 mm (2 in.)
7/29/2019 1- Heat Treatment
28/61
Rockwell C hardness (HRC) with martensite contents of:Carbon, %
99.9%95%90%80%50%
433937.535310.18
464240.537.5340.23
4944.54340.536.50.28
5248.546.543.5390.33
54514946420.38
5753.55148440.43
6057545246.50.48
7/29/2019 1- Heat Treatment
29/61
Relationship between IT, CCT, and Jominy Curves
Relationship of CCT
(heavy lines) and IT
(light lines) diagrams of
eutectoid steel. Fourcooling rates from
different positions on a
Jominy end-quench
specimen are
superimposed on the
CCT diagram
7/29/2019 1- Heat Treatment
30/61
Comparison of IT
diagram for steel
with German
designation 42
CrMo 4 (0.38% C,
0.99% Cr, and
0.16% Mo)
determined by
dilatometry
7/29/2019 1- Heat Treatment
31/61
Stress-Relief Heat Treating of Steel
STRESS-RELIEF HEAT TREATINGis used torelieve stresses that remain locked in a structure as aconsequence of a manufacturing sequence.
This definition separates stress-relief heat treating from
post weld heat treating in that the goal of post weld heat
treating is to provide, in addition to the relief of residualstresses, some preferred metallurgical structure or
properties For example, most ferritic weldments are
given postweld heat treatment to improve the fracture
toughness of the heat-affected zones (HAZ). Moreover,austenitic and nonferrous alloys are commonly postweld
heat treated to improve resistance to environmental
damage.
7/29/2019 1- Heat Treatment
32/61
Stress-relief heat treating is the uniform heating of astructure, or portion, to a suitable temperature below thetransformation range (Ac1 for ferritic steels), holding atthis temperature for a predetermined period of time,followed by uniform cooling. Care must be taken toensure uniform cooling, particularly when a component iscomposed of variable section sizes. If the rate of coolingis not constant and uniform, new residual stresses canresult that are equal to or greater than those that the
heat-treating process was intended to relieve. Stress-relief heat treating can reduce distortion and high
stresses from welding that can affect serviceperformance. The presence of residual stresses can leadto stress-corrosion cracking (SCC) near welds and in
regions of a component that has been cold strainedduring processing.
Residual stresses in a ferritic steel cause significantreduction in resistance to brittle fracture
7/29/2019 1- Heat Treatment
33/61
Sources of Residual Stress Bending a bar during fabrication at a temperature where recovery
cannot occur (cold forming, for example) will result in one surface
location containing residual tensile stresses, whereas a location180 away will contain residual compressive
Quenchingof thick sections results in high residual compressivestresses on the surface of the material. These high compressivestresses are balanced by residual tensile stresses in the internalareas of the section
Grinding is another source of residual stresses; these can becompressive or tensile in nature, depending on the grindingoperation. Although these stresses tend to be shallow in depth, theycan cause warping of thin parts
Welding. The cause of residual stresses that has received the mostattention in the open literature is welding. The residual stressesassociated with the steep thermal gradient of welding can occur on amacroscale over relatively long distances (reaction stresses) or canbe highly localized (microscale) (Fig.). Welding usually results inlocalized residual stresses that approach levels equal to or greaterthan the yield strength of the material at room temperature.
7/29/2019 1- Heat Treatment
34/61
Examples of the causes of residual stresses:
(a) Thermal distortion in a structure due to heating by solar radiation.(b) Residual stresses due to welding. (c) Residual stresses due to grinding.
7/29/2019 1- Heat Treatment
35/61
Relationship between time and temperature in the relief of
residual stresses in steel.
7/29/2019 1- Heat Treatment
36/61
Typical stress-relief temperatures for low-alloy
ferritic steels are between 595 and 675 C (1100 and 1250 F).
For high-alloy steels, these temperatures may range from 900 to1065 C (1650 to 1950 F).
For high-alloy steels, such as the austenitic stainless steels,stress relieving is sometimes done at temperatures as low as400 C (750 F). However, at these temperatures, only modestdecreases in residual stress are achieved.
Residual stresses can be significantly reduced by stress-relief
heat treating those austenitic materials in the temperature rangefrom 480 to 925 C (900 to 1700 F). At the higher end of thisrange, nearly 85% of the residual stresses may be relieved.Stress-relief heat treating in this range, however, may result insensitizing susceptible material. This metallurgical effect canlead to
SCC in service. Frequently, solution-annealing temperatures ofabout 1065 C (1950 F) are used to achieve a reduction ofresidual stresses to acceptably low values.
NORMALIZING OF STEEL
7/29/2019 1- Heat Treatment
37/61
NORMALIZING OF STEEL
NORMALIZING OF STEEL is a heat-
treating process that is often
considered from both thermal and
microstructural standpoints.
Normalizing is an austenitizing heatingcycle followed by cooling in still or
slightly agitated air.
Typically, the work is heated to a
temperature about 55 C (100 F) above
the upper critical line of the iron-iron
carbide phase diagram, as shown inFig. that is, above Ac3 for
hypoeutectoid steels and above Acm
for hypereutectoid steels. To be
properly classed as a normalizing
treatment, the heating portion of the
process must produce a homogeneous
austenitic phase (face-centered cubic,
or fcc, crystal structure) prior to
cooling.
Typical normalizing temperatures for
many standard steels are given in
Table 1.
Table 1 Typical normalizing temperatures for standard carbon and alloy steels
7/29/2019 1- Heat Treatment
38/61
Grade Temperature(a) Grade Temperature(a) Grade Temperature(a) Grade Temperature(a)
C F C F C F C F
Plain carbon steels 1090 830 1525 3310 925 1700 4140 870 1600
1015 915 1675 1095 845 1550 4027 900 1650 4142 870 1600
1020 915 1675 1117 900 1650 4028 900 1650 4145 870 1600
1022 915 1675 1137 885 1625 4032 900 1650 4147 870 1600
1025 900 1650 1141 860 1575 4037 870 1600 4150 870 1600
1030 900 1650 1144 860 1575 4042 870 1600 4320 925 1700
1035 885 1625 Standard alloy steels 4047 870 1600 4337 870 1600
1040 860 1575 1330 900 1650 4063 870 1600 4340 870 1600
1045 860 1575 1335 870 1600 4118 925 1700 4520 925 1700
1050 860 1575 1340 870 1600 4130 900 1650 4620 925 1700
1060 830 1525 3135 870 1600 4135 870 1600 4621 925 1700
1080 830 1525 3140 870 1600 4137 870 1600 4718 925 1700
Grade Temperature(a) Grade Temperature(a) Grade Temperature(a) Grade Temperature(a)
7/29/2019 1- Heat Treatment
39/61
C F C F C F C F
4720 925 1700 5155 870 1600 8642 870 1600 9840 870 1600
4815 925 1700 5160 870 1600 8645 870 1600 9850 870 1600
4817 925 1700 6118 925 1700 8650 870 1600 50B40 870 1600
4820 925 1700 6120 925 1700 8655 870 1600 50B44 870 1600
5046 870 1600 6150 900 1650 8660 870 1600 50B46 870 1600
5120 925 1700 8617 925 1700 8720 925 1700 50B50 870 1600
5130 900 1650 8620 925 1700 8740 925 1700 60B60 870 1600
5132 900 1650 8622 925 1700 8742 870 1600 81B45 870 1600
5135 870 1600 8625 900 1650 8822 925 1700 86B45 870 1600
5140 870 1600 8627 900 1650 9255 900 1650 94B15 925 1700
5145 870 1600 8630 900 1650 9260 900 1650 94B17 925 1700
5147 870 1600 8637 870 1600 9262 900 1650 94B30 900 1650
5150 870 1600 8640 870 1600 9310 925 1700 94B40 900 1650
7/29/2019 1- Heat Treatment
40/61
Comparison of time-temperature cycles for normalizing and fullannealing. The slower cooling of annealing results in higher
temperature transformation to ferrite and pearlite and coarser
microstructures than does normalizing.
7/29/2019 1- Heat Treatment
41/61
Applications of Normalizing Based on Steel Classification
All of the standard low-carbon, medium-carbon,
and high-carbon wrought steels can benormalized, as well as many castings. Many
steel weldments are normalized to refine the
structure within the weld-affected area.
Austenitic steels, stainless steels, and maraging
steels either cannot be normalized or are not
usually normalized. Tool steels are generally
annealed by the steel supplier.
The purpose of normalizing varies considerably
7/29/2019 1- Heat Treatment
42/61
Normalization may increase or decrease thestrength and hardness of a given steel in a
given product form, depending on the thermaland mechanical history of the product.Actually, the functions of normalizing mayoverlap with or be confused with those of
annealing, hardening, and stress relieving. Improved machinability, grain refinement,
homogenization, and modification of residualstresses are among the reasons normalizing is
done.
The purpose of normalizing varies considerably
7/29/2019 1- Heat Treatment
43/61
Part Steel Heat treatment Properties after treatment Reason for normalizing
Cast 50 mm (2 in.) Ni-
Full annealed at 955 C
(1750 Tensile strength, 620 MPa (90 ksi); To meet mechanical-
valve body, 19 to 25 Cr- F), normalized at 870 C 0.2% yield strength, 415 MPa (60 property requirements
mm ( 3 4 to 1 in.)in
Mo (1600 F), tempered at 665
C (1225 F)
ksi); elongation in 50 mm, or 2 in.,
20%; reduction in area, 40%
section thickness
Forged flange 4137 Normalized at 870 C (1600 Hardness, 200 to 225 HB To refine grain size andF), tempered at 570 C
(1060
obtain required hardness
F)
Valve-bonnet forging 4140 Normalized at 870 C (1600 Hardness, 220 to 240 HB To obtain uniform
F) and tempered structure, improved
machinability, and
requiredhardness
Typical applications of normalizing and tempering of steel components
Annealing of Steel
7/29/2019 1- Heat Treatment
44/61
Annealing of Steel
ANNEALING is a generic term denoting a treatment that consists of
heating and holding at a suitable temperature followed by cooling at
an appropriate rate, primarily for the softening of metallic materials.
Generally, in plain carbon steels, annealing produces a ferrite-pearlite
microstructure. Steels may be annealed to facilitate cold working or
machining, to improve mechanical or electrical properties, or to
promote dimensional stability.
The following equations will give an approximate critical temperaturefor a hypoeutectoid steel
Ac1(C) = 723 - 20.7(% Mn) - 16.9(%Ni) + 9.1(%Si) - 16.9(%Cr)
Standard deviation = 11.5 CAc3(C) = 910 - 203 %C - 15.2(% Ni) + 44.7(% Si) + 104(% V) +
31.5(% Mo)
Standard deviation = 16.7 C
7/29/2019 1- Heat Treatment
45/61
7/29/2019 1- Heat Treatment
46/61
Annealing Cycles
In practice, specific thermal cycles of an almost infinite
variety are used to achieve the various goals ofannealing. These cycles fall into several broad
categories that can be classified according to the
temperature to which the steel is heated and the method
of cooling used.
The maximum temperature may be below the lower
critical temperature, A1 (subcritical annealing);
above A1 but below the upper critical temperature, A3 in
hypoeutectoid steels,
or Acm in hypereutectoid steels (intercritical annealing);
or above A3 (full annealing).
7/29/2019 1- Heat Treatment
47/61
Subc ri t ical Anneal ing
Subcritical annealing does not involve formation of austenite. Theprior condition of the steel is modified by such thermally activatedprocesses as recovery, recrystallization, grain growth, andagglomeration of carbides.
In as-rolled or forged hypoeutectoid steels containing ferrite and
pearlite, subcritical annealing can adjust the hardness of bothconstituents, but excessively long times at temperature may berequired for substantial softening.
The subcritical treatment is most effective when applied to hardenedor cold-worked steels, which recrystallize readily to form new ferritegrains. The rate of softening increases rapidly as the annealing
temperature approaches A1. Cooling practice from the subcriticalannealing temperature has very little effect on the establishedmicrostructure and resultant properties.
7/29/2019 1- Heat Treatment
48/61
lntercr i t ical Anneal ing Austenite begins to form when the temperature of the steel
exceeds A1. The solubility of carbon increases abruptly(nearly1%) near the A1 temperature.
In hypoeutectoid steels, the equilibrium structure in theintercritical range between A1 and A3 consists of ferrite andaustenite, and above A3 the structure becomes completelyaustenitic.
In hypereutectoid steels, carbide and austenite coexist in theintercritical range between A1 and Acm; and the homogeneityof the austenite depends on time and temperature. The degreeof homogeneity in the structure at the austenitizingtemperature is an important consideration in the development
of annealed structures and properties. The more homogeneous structures developed at higheraustenitizing temperatures tend to promote lamellar carbidestructures on cooling, whereas lower austenitizingtemperatures in the intercritical range result in lesshomogeneous austenite, which promotes formation ofspheroidal carbides.
7/29/2019 1- Heat Treatment
49/61
A common annealing
practice is to heat
hypoeutectoid steels
above the upper critical
temperature (A3) toattain full
austenitization. The
process is called full
annealing.
7/29/2019 1- Heat Treatment
50/61
Recommended
temperatures and
cooling cycles for
full annealing
Recommended annealing temperatures for alloy steels (furnace cooling)
7/29/2019 1- Heat Treatment
51/61
Recommended annealing temperatures for alloy steels (furnace cooling)
Hardness (max), HBAnnealing temperatureAISI/SAE steel
C
1791550-1650845-9001330
1871550-1650845-9001335
1921550-1650845-9001340
. . .1550-1650845-9001345
1871500-1600815-8703140
1831500-1575815-8554037
1921500-1575815-8554042
2011450-1550790-8454047
2231450-1550790-8454063
1741450-1550790-8454130
. . .1450-1550790-8454135
1921450-1550790-8454137
1971450-1550790-8454140
2071450-1550790-8454145
. . .1450-1550790-8454147
2121450-1550790-8454150
. . .1450-155790-844161
AISI Temp Hardness
7/29/2019 1- Heat Treatment
52/61
. . .1450-155790-844337
2231450-155790-844340
HardnessTempAISI
1871500-1600815-87050B40
1971500-1600815-87050B44
1921500-1600815-8705046
1921500-1600815-87050B46
2011500-1600815-87050B50
2171500-1600815-87050B60
1701450-1550790-8455130
1701450-1550790-8455132
AISI Temp Hardness
AISI Temp Hardness
7/29/2019 1- Heat Treatment
53/61
1701450-1550790-8455132
1741500-1600815-8705135
1871500-1600815-8705140
1971500-1600815-8705145
1971500-1600815-8705147
2011500-1600815-8705150
2171500-1600815-8705155
2231500-1600815-8705160
2231500-1600815-87051B60
1971350-1450730-79050100
1971350 1450730 79051100
7/29/2019 1- Heat Treatment
54/61
1971350-1450730-79051100
2071350-1450730-79052100
2011550-1650845-9006150
1921550-1650845-90081B45
1741500-1600815-8708627
1791450-1550790-8458630
1921500-1600815-8708637
1971500 1600815 8708640
7/29/2019 1- Heat Treatment
55/61
1971500-1600815-8708640
2011500-1600815-8708642
2071500-1600815-8708645
2071500-1600815-87086B45
2121500-1600815-8708650
2231500-1600815-8708655
2291500-1600815-8708660
2021500-1600815-8708740
. . .1500-1600815-8708742
2291500-1600815-8709260
1741450-1550790-84594B30
1921450-1550790-84594B40
7/29/2019 1- Heat Treatment
56/61
As the hardness of steel increases during cold working,ductility decreases and additional cold reduction becomes sodifficult that the material must be annealed to restore itsductility. Such annealing between processing steps is referredto as in-process or simply process annealing. It may consist ofany appropriate treatment. In most instances, however, a
subcritical treatment is adequate and least costly, and the term"process annealing" without further qualification usually refersto an in-process subcritical anneal.
is often necessary to specify process annealing for parts thatare cold formed by stamping, heading, or extrusion. Hotworked high-carbon and alloy steels also are process annealedto prevent them from cracking and to soften them for shearing,turning, or straightening.
Process Annealing
7/29/2019 1- Heat Treatment
57/61
T f F
7/29/2019 1- Heat Treatment
58/61
Types of Furnaces
Types of Furnaces
Furnaces for annealing are of two basic types:1. Batch furnaces and
2. Continuous furnaces.
Batch-type furnaces are necessary for large parts suchas heavy forgings and often are preferred for small lots
of a given part or grade of steel and for the morecomplex alloy grades requiring long cycles. Specifictypes of batch furnaces include car-bottom, box, bell,and pit furnaces. Annealing in bell furnaces can producethe greatest degree of spheroidization (up to 100%).
However, the spheroidizing cycles in bell furnaces arelong and last from 24 to 48 h depending on the grade ofmaterial being annealed and the size of the load.
7/29/2019 1- Heat Treatment
59/61
Continuous furnaces such as roller-hearth,
rotary-hearth, and pusher types are ideal forisothermal annealing of large quantities of partsof the same grade of steel. These furnaces canbe designed with various individual zones,
allowing the work to be consecutively brought totemperature, held at temperature, and cooled atthe desired rate. Continuous furnaces
are not able to give complete spheroidization
and should not be used for products that requiresevere cold forming..
7/29/2019 1- Heat Treatment
60/61
A low-carbon sheet steel in the (a) as-cold-rolled unannealed condition,(b) partially recrystallized annealed condition, and (c) fully
recrystallized annealed condition. Marshall's etch. 1000
7/29/2019 1- Heat Treatment
61/61
(a) In the as-received hot-rolled condition, microstructure is blockypearlite. Hardness is 87 to 88HRB.
(b) In the partially spheroidized condition following annealing in a
continuous furnace. Hardness is 81 to 82 HRB.
(c) In the nearly fully spheroidized condition following annealing in a bell
furnace. Hardness is 77 to 78 HRB.