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1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2 , BeBr 2 , BeI 2 , HgCl 2 , CdCl 2 All of these examples are linear, nonpolar molecules. Important exceptions occur when the two substituents are not the same! BeClBr or BeIBr will be linear and polar!

1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

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Page 1: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

1

Linear Electronic Geometry:AB

2 Species (No Lone Pairs of

Electrons on A) Some examples of molecules with this

geometry are: BeCl

2, BeBr

2, BeI

2, HgCl

2, CdCl

2

All of these examples are linear, nonpolar molecules.

Important exceptions occur when the two substituents are not the same!BeClBr or BeIBr will be linear and polar!

Page 2: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

2

Linear Electronic Geometry:AB

2 Species (No Lone Pairs of

Electrons on A)

Electronic Geometry

H

C

HHH

Page 3: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

3

Linear Electronic Geometry:AB

2 Species (No Lone Pairs of

Electrons on A)

Polarity

Page 4: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

4

Linear Electronic Geometry:AB

2 Species (No Lone Pairs of

Electrons on A)Valence Bond Theory (Hybridization)

Page 5: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

5

Page 6: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

6

Linear Electronic Geometry:AB2 Species (No Lone Pairs of

Electrons on A)

Page 7: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

7

Trigonal Planar Electronic Geometry: AB3 Species (No Lone Pairs of

Electrons on A) Some examples of molecules with this

geometry are: BF3, BCl3

All of these examples are trigonal planar, nonpolar molecules.

Important exceptions occur when the three substituents are not the same!BF2Cl or BCI2Br will be trigonal planar

and polar!

Page 8: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

8

Trigonal Planar Electronic Geometry: AB3 Species (No Lone Pairs of

Electrons on A)

Dot Formula Electronic Geometry

H

C

HHH

Page 9: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

9

Trigonal Planar Electronic Geometry: AB3 Species (No Lone Pairs of

Electrons on A)

Polarity

Page 10: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

10

Trigonal Planar Electronic Geometry: AB3 Species (No Lone Pairs of

Electrons on A)Valence Bond Theory (Hybridization)

3s 3p

Cl [Ne]

Page 11: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

11

Page 12: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

12

Trigonal Planar Electronic Geometry: AB3 Species (No Lone Pairs of

Electrons on A)

Page 13: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

13

Tetrahedral Electronic Geometry: AB

4 Species (No Lone Pairs of

Electrons on A)

Some examples of molecules with this geometry are: CH

4, CF

4, CCl

4,

SiH

4,

SiF

4

All of these examples are tetrahedral, nonpolar molecules.

Important exceptions occur when the four substituents are not the same!CF3Cl or CH2CI2 will be tetrahedral and polar!

Page 14: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

14

Tetrahedral Electronic Geometry: AB

4 Species (No Lone Pairs of

Electrons on A)

Page 15: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

15

Tetrahedral Electronic Geometry: AB

4 Species (No Lone Pairs of

Electrons on A)

Page 16: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

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Page 17: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

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Page 18: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

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Page 19: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

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Page 20: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

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Page 21: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

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Page 22: 1 Linear Electronic Geometry: AB 2 Species (No Lone Pairs of Electrons on A) Some examples of molecules with this geometry are: BeCl 2, BeBr 2, BeI 2,

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