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Standard STD 100-0002Volvo Group

Issue date March 2013 Issue 8 Page 1(16)

The English language version is the original and thereference in case of dispute.

Den engelska sprkversionen r originalversion och skaberopas i hndelse av tvist.

Chemical substances whichmust not be present inprocesses or productswithin the Volvo Group

Kemiska mnen som intefr frekomma i processereller produkter inomVolvokoncernen

Volvos black list Volvos svarta lista

Orientation Orientering

This standard effectuates a decision made by theVolvo Group Environmental Council concerningrestrictions with respect to the use of certain chemicalsubstances.

Denna standard verkstller ett beslut som fattats avVolvokoncernens miljrd avseende begrnsningarfr anvndandet av vissa kemiska mnen.

The contents of this standard are revised annually. Incase of any updating, the new version is published on15 March.

Innehllet i denna standard gs igenom rligen. Videventuella uppdateringar publiceras den nya utgvan15 mars.

Associated standards are: Angrnsande standarder r:

S 000003 Ch i l b hi h S 00 0003 i k i b

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STD 1000003 Ch i l b t hi h STD 100 0003 K i k i t b


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the biocides Kathon CG, CAS No. 55965-84-9,and CIT, (5-Chloro-N-Methylisotiazolin-3), CASNo. 26172-55-4, from Volvos grey list have beenadded

biociderna Kathon CG, CAS-nr 55965-84-9, ochCIT, (5-Klor-N-Methylisotiazolin-3), CAS-nr 26172-55-4 frn Volvos gr lista har lagts till

all applications regarding lead and chromium(VI)and their compounds from Volvos grey list havebeen added

alla tillmpningar avseende bly och krom(VI) medfreningar frn Volvos gr lista har lagts till

diorganotin compounds, when used as antifoulingbiocide, from Volvos grey list have been added

diorganiska tennfreningar anvnda somantifouling biocid frn Volvos gr lista har lagts till

phenolfphtalein, CAS No. 77-09-8, has beenadded.

fenolftalein, CAS-nr 77-09-8, har lagts till.

Substances that have been added or changed in thisissue of the standard are shaded in the list.

mnen som har lagts till eller ndrats i denna utgvaav standarden har grmarkerats i listan.

1 Scope and field of application 1 Omfattning och tillmpningThis standard lists substances which must not bepresent in products used in product development, inproduction processes, or for transportation of productsbetween/within the facilities of the Volvo Group andapplies when it is referred to.

Denna standard omfattar mnen som inte frfrekomma i produkter som anvnds vid produkt-utveckling, inom produktionsprocesser eller frtransport av produkter mellan/inom Volvokoncernensanlggningar och gller nr den hnvisas till.

The standard also applies when referred to in other

ti

Standarden gller ocks nr det hnvisas till den i

d h

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chemical product materialschemical products that are used within the VolvoGroup and that are included in Volvo Group productsplaced on the market. These products shall have beenassessed with respect to human health and theenvironment (e.g. KOLA Part Type Y) and specified inthe technical documentation for each product placedon the market. This means that they are also covered

bySTD 100-0005Chemical substances which mustnot be present in Volvo Group products placed on themarket Volvos red list.

kemiska produktmaterialkemiska produkter som anvnds inom Volvo-koncernen och som ingr i Volvokoncernensmarknadsfrda produkter. Dessa produkter ska varahlso- och miljbedmda (t.ex. KOLA Part Type Y)och specificerade i teknisk dokumentation frrespektive marknadsfrd produkt. Detta innebr att deocks omfattas avSTD 100-0005Kemiska mnen

som inte fr frekomma i Volvokoncernensmarknadsfrda produkter Volvos rda lista.

Belonging to these this group of materials are alsochemical products that are fully enclosed in partshandled in manufacturing processes.Examples: brake fluids, fuels, damping compounds,paints, adhesives, oils, fillers, sealants, etc.

Till dessa produkter rknas ocks kemiska produktersom r helt inneslutna i artiklar som hanteras itillverkningsprocesser.Exempel: bromsvtskor, brnslen, dmpmassa, fett,frg, lim, oljor, spackel, ttningsmedel, etc.

new designnewly created part(s) with newly allocated partnumber(s). The applicable date is the date when thepart number was registered.For the supplier, the applicable date is the date ofrequest for quotation

nykonstruktionnyutvecklad(e) artikel/artiklar med nyuttaget/nyuttagnaartikel-nummer. Datumet som gller r nrartikelnumret registrerats(des).Fr leverantren gller datumet fr request forquotation

3 R i t 3 K
http://100-0005.pdf/http://100-0005.pdf/http://100-0005.pdf/http://100-0005.pdf/http://100-0005.pdf/http://100-0005.pdf/http://100-0005.pdf/http://100-0005.pdf/

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When exemption is granted, special protectivemeasures shall be taken to prevent harm to humanhealth and the environment.

Nr undantag medges ska srskilda skyddstgrdervidtas fr att frhindra skada p mnniska och milj.

Decisions on exemption shall be made by therespective Volvo Group company and shall bereported to the Volvo Groups EnvironmentalCommittee.

Beslut om undantag fattas av respektive fretag inomVolvokoncernen och ska redovisas fr Volvo-koncernens Miljkommitt.

5 List of substance groups 5 mnesgruppsfrteckningThe lists below show the substance groups covered

b th t d d

Nedanstende listor visar vilka mnesgrupper som

f tt t d d

4 Reference in documentation 4 Hnvisning i dokumentationReference to this standard shall be made in controldocuments for the Volvo Groups facilities and indocumentation sent to supplier.

Hnvisning till denna standard ska gras iVolvokoncernens anlggningars styrandedokumentation och i dokumentation som skickas tillleverantr.

Example of reference to this standard: Exempel p hnvisning till denna standard:

CHEMICAL SUBSTANCES WHICH MUST NOT BE PRESENT

STD 100-0002

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Table 1E Expandable substance group lis t in Excel format

Substance group/Substance CAS No.

1)

Generic examples Application Threshold (0,1 % unlessotherwise specified) Risk

2)

Inclusiondate

Ami nes, c arci nogenic Various Curing agents in paints andadhesives, antioxidants inlubricants

C, E, T Before2006-02-01

4-Aminobiphenyl and itssalts

Various Impurities in textile andleather paints, antioxidantsin lubricants, rubber/latex,plastics

C, T Before2006-02-01

Asb esto s fi bres Various Insulation C Before2006-02-01

Asb esto s miner als Various Insulation C 2010-03-15

Azoc olo rants Various Colorants or additives intextiles and leather

A, C, E Before2006-02-01

Benzene 71-43-2 Solvent, fuel Exemption may be granted forbenzene in engine fuel

C, R, T Before2006-02-01

Benzidine and its salts Various Antioxidants in lubricants,component in dyes

C Before2006-02-01

Biocides Various Biocides in paints,lubricants, cutting fluids andmetal-working fluids

0,0015 % A, E, T 2013-03-15

Cadmium and itscompounds

7440-43-9 Pigments in paints andplastics, electronics

0,01 % C, E Before2006-02-01
http://100-0002l1.xlsx/http://100-0002l1.xlsx/

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Substance group/Substance

CAS No. 1) Generic examples Application Threshold (0,1 % unlessotherwise specified)

Risk 2) Inclusiondate

Chlorinated hydrocarbons Various Solvents and dispersiveapplications

C, E, T Before2006-02-01

Chlorinated or brominateddioxins or furans

Various Impurities in products C, E, T 2010-03-15

Chlorinated paraffins Various Additives in process oils,metal working fluids,adhesives and sealants

E Before2006-02-01

Chloroaniline 106-47-8 Hardeners or cross linkingagents for polymers andepoxy resins

A, C, E Before2006-02-01

Chlorofluor ocarbons (CFC)and other ozone-depletingsubstances

Various Coolants, cleaners,solvents

E Before2006-02-01

Chromium(VI) and i tscompounds

Various Chromium pigments,corrosion inhibitors

Chromium(VI) surface treatedproducts introduced before2012-01-01 and unmodified afterthis date are exempted if the meanvalue of free hexavalent chromium

does not exceed 0,3 g/cm whentested in accordance with STD5713,102

A, C, E Before2006-02-01

Cobalt dichloride 7646-79-9 Drying agents A,C,E,T 2011-03-15

Diorganotin compounds Various Stabilizers, catalysts andcuring agent

When used as antifouling biocides E, R, T 2013-03-15

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Ethyl-, methyl-glycols andtheir acetates

Various Solvents and blowingagents

R Before2006-02-01

Halons Various Fire-extinguishingequipment

E Before2006-02-01

Hexabromocyclododecane(HBCDD)

Various Flame retardants E Before2006-02-01

Hydrazine 302-01-2 Foaming agentand pre-cursor to polymerization.

Corrosion inhibitor in paints

C 2012-03-15

Hydrobromofluorocarbons(HBFC)

Various Refrigerants E 2010-03-15

Hydrochlorofluorocarbons(HCFC)

Various Solvents and blowingagents

All applications except coolingagents in industrial applications

E Before2006-02-01

Lead and its compounds Various Lead-containing stabilizersand pigments, corrosioninhibitors

The prohibition refers to the use oflead chromates in all applications.For other applications, theprohibition is effective for new

design from 2012-01-01

E, N, R Before2006-02-01

Mercury and itscompounds

Various Pigments, preservatives,constituents in electricequipment

E, N Before2006-02-01
http://en.wikipedia.org/wiki/Foaming_agenthttp://en.wikipedia.org/wiki/Precursor_(chemistry)http://en.wikipedia.org/wiki/Precursor_(chemistry)http://en.wikipedia.org/wiki/Polymerizationhttp://en.wikipedia.org/wiki/Polymerizationhttp://en.wikipedia.org/wiki/Precursor_(chemistry)http://en.wikipedia.org/wiki/Precursor_(chemistry)http://en.wikipedia.org/wiki/Foaming_agent

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Mineral oils with PAH Various Constituent in base oils,lubricants

Not applicable when thresholdcriteria are fulfilled

Considered to contain PAHif standard test (Institute ofPetroleum, IP 346 method)produces the resultDMSO extract 3 %.

Applicable to base oilsused in lubricants andother chemical products

C Before2006-02-01

4-Nitrobiphenyl 92-93-3 Impurities in textile andleather paints, antioxidantsin lubricants, rubber/latex,plastics

C 2010-03-15

Nonyl- and octylphenols Various Surface-active agents E Before2006-02-01

Nonyl- and octylphenolethoxylates

Various Surfactants, corrosioninhibitors

All applications except octylphenolethoxylates used as additives intransmission oils in amounts below0,5 %. The exemption is valid until

2014-01-01

E Before2006-02-01

Phenolphtalein 77-09-8 pH indicator C, R 2013-03-15

Perfluorooctane sulfonates(PFOS)

Various Surface coatings, polish,firefigthing foam

E 2010-03-15

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Phthalates, selected Various Plasticizers in adhesivesand sealants

R Before2006-02-01

Polybrominated biphenyls(PBB)

Various Flame retardants in plasticsand textiles

E Before2006-02-01

Polybrominated diphenylethers (PBDE)

Various Flame retardants in plasticsand textiles

E Before2006-02-01

Polychlorinated biphenyls-

(PCB )

Various Insulation fluids in electrical

systems, constituent intransformer oils andcondensers

E Before

2006-02-01

Polychlorinated terphenyls(PCT )

61788-33-8 Insulation fluids in electricalsystems, constituent intransformer oils andcondensers

E 2010-03-15

Refractory Ceramic Fibres N.A. Insulation materials The prohibition refers to RCF fibresextracted from index number650-017-00-8 fulfilling the criteriaset forth in the REACH CandidateList. High-temperature insulationapplications are exempted fromthis prohibition

C 2011-03-15

Triorganotin compounds Various Biocides and biocidalcoatings

E, T, R 2011-03-15

Tris-(1-aziridinyl)phosphine oxide

545-55-1 Flame retardants T 2010-03-15

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Tris-(2,3-dibromo-propyl)phosphate [TRIS]

126-72-7 Flame retardants C, E 2010-03-15

Vinyl chloride 75-01-4 Residual monomer in PVC-based adhesives andsealants

Threshold 5 ppm vinylchloride monomer

C 2010-03-15

1) CAS No. =Chemical Abstract Service registry number. Internationally applied scientific index identifying chemical substances.2) A =Allergy, C =Cancer, T =Toxic, E =Environmentally hazardous, N =Neurotoxic, R =Reproductive hazards.

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Tabell 1S

mn esgrupp/mneSorterade efter engelskbenmning

CAS-nr1) Exempel panvndningsomrde

Tillmpning Grnsvrde (0,1 % ominte annat specificerats)

Risk 2) Infrd

Aminer, canc erogena Flera Hrdare i frg och lim,antioxidanter i smrjmedel

C, E, T Fre2006-02-01

4-aminobifenyler ink l.salter

Flera Froreningar i textil ochlderfrger, antioxidanter ismrjmedel, gummi/latex,plast

C, T Fre2006-02-01

Asb estf ibr er Flera Isoleringsmaterial C Fre

2006-02-01

Asb estm ineral Flera Isoleringsmaterial C 2010-03-15

Azofrgmnen Flera Frgmnen eller additiv itextilier och lder

A, C, E Fre2006-02-01

Bensen 71-43-2 Lsningsmedel, brnslen Undantag kan medges fr benseni motorbrnsle

C, R, T Fre2006-02-01

Benzidin, inkl. salter ochdess freningar

Flera Antioxidanter i smrjmedel,bestndsdel i frgmnen

C Fre2006-02-01

Biocider Flera Biocider i frger,smrjmedel, skrvtskoroch metallbearbetnings-vtskor

0,0015 % A, E, T 2013-03-15

Kadmium och dessfreningar

7440-43-9 Pigment i frg och plast,elektronik

0,01 % C, E Fre2006-02-01

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Risk 2) Infrd

Klorerade kolvten Flera Lsningsmedel ochdispergeringsmedel

C, E, T Fre2006-02-01

Klorerade eller bromeradedioxiner eller furaner

Flera Froreningar i produkter C, E, T 2010-03-15

Klorparaffiner Flera Tillsatsmedel iprocessoljor, skrvtskor,lim, ttningar

E Fre2006-02-01

Kloranilin 106-47-8 Hrdare ellertvrbindningsmedel fr

polymerer och epoxiplast

A, C, E Fre2006-02-01

Klorfluo rkarboner (CFC)och andraozonnedbrytande mnen

Flera Kldmedium,rengringsmedel,lsningsmedel

E Fre2006-02-01

Krom(VI) och dessfreningar

Flera Pigment med krom,rostskyddsmedel

Krom(VI)-ytbehandlade produkterintroducerade innan 2012-01-01och som inte modifierats efterdetta datum r undantagna ommedelvrdet fr den fria halten

sexvrt krom inte verstiger0,3 g/cm vid provning enligtSTD 5713,102

A, C, E Fre2006-02-01

Koboltdiklorid 7646-79-9 Torkmedel A,C,E,T 2011-03-15

Diorganiskatennfreningar

Flera Stabilisatorer, katalysatoreroch vulkmedel

Vid anvndning somantifoulingbiocider

E, R, T 2013-03-15

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Risk 2) Infrd

Etyl-, metylglykol ochderas acetater

Flera Lsningsmedel ochskumningsmedel

R Fre2006-02-01

Haloner Flera Brandslckningsutrustning E Fre2006-02-01

Hexabromcyklododekan(HBCDD)

Flera Flamskyddsmedel E Fre2006-02-01

Hydrazin 302-01-2 Skummedel och prekursorvid polymerisation.Korrosionsinhibitor i frger

C 2012-03-15

Hydrobromfluor-karboner (HBFC)

Flera Kldmedium E 2010-03-15

Hydroklorfluorkarboner(HCFC)

Flera Lsningsmedel,skumningsmedel

Alla applikationer utomkldmedium fr industrielltillmpning

E Fre2006-02-01

Bly och dess freningar Flera Blystabilisatorer ochpigment,korrosionshmmare

Fr blykromater gller frbudetalla applikationer.Fr andra applikationer gllerfrbudet fr nykonstruktion frn2012-01-01

E, N, R Fre2006-02-01

Kvicksilver och dessfreningar

Flera Pigment, konserverings-medel

E, N Fre2006-02-01
http://en.wikipedia.org/wiki/Precursor_(chemistry)http://en.wikipedia.org/wiki/Precursor_(chemistry)

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Risk 2) Infrd

Mineraloljor med PAH(polyaromatiska kolvten)

Flera Bestndsdel i basolja,smrjolja

Tilltet om grnsvrdeskriteriernar uppfyllda

Rknas som PAH-innehllande omstandardprov (Institute ofPetroleum, IP 346-metoden) ger resultatetDMSO-extrakt 3 %.Gller basoljor ingende ismrjmedel eller andrakemiska produkter

C Fre2006-02-01

4-nitrobifenyl 92-93-3 Froreningar i textil- och

lderfrger, antioxidanter ismrjmedel, gummi/latex,plast

C 2010-03-15

Nonyl- och oktylfenoler Flera Ytaktiva agens E Fre2006-02-01

Nonyl- och oktylfenol-etoxylater

Flera Ytaktiva agens,korrosionshmmare

Alla tillmpningar frutomoktylfenoletoxylater anvnda somadditiv i transmissionsoljor imngder under 0,5 %.Undantaget gller till och med2014-01-01

E Fre2006-02-01

Fenolftalein 77-09-8 pH-indikator C, R 2013-03-15

Perfluoroktan-sulfonater(PFOS)

Flera Ytimpregnering, polishers,brandslckningsskum

E 2010-03-15

Ftalater, ut valda Flera Mjukgrare i lim ochttningsmedel

R Fre2006-02-01

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Risk 2) Infrd

Polybromerade bifelyler(PBB)

Flera Flamskyddsmedel i plastoch textilier

E Fre2006-02-01

Polybromeradedifenyletrar (PBDE)

Flera Flamskyddsmedel i plastoch textilier

E Fre2006-02-01

Polyklorerade bifenyler(PCB)

Flera Isoleringsvtska ielektriska system,bestndsdel i trans-formatorolja ochkondensatorer

E Fre2006-02-01

Polyklorerade terfenyler(PCT)

61788-33-8 Isoleringsvtska ielektriska system,bestndsdel i trans-formatorolja ochkondensatorer

E 2010-03-15

Eldfasta keramiska fibrer N.A. Isoleringsmaterial Frbudet avser extraheradeRCF-fibrer frn indexnummer650-017-00-8 och framt vilkauppfyller kriterierna i REACHCandidate list.Hgtemperatursisolering rundantagen frn detta frbud

C 2011-03-15

Triorganiska tenn-freningar

Various Biocider ochbiocidbelggning

E, T, R 2011-03-15

Tris-(1-aziridinyl)fosfinoxid

545-55-1 Flamskyddsmedel T 2010-03-15

Tris-(2,3-dibrompropyl)fosfat

126-72-7 Flamskyddsmedel C, E 2010-03-15

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Risk 2) Infrd

Vinylklorid 75-01-4 Restmonomer i PVC-baserade lim ochttningsmedel

Grnsvrde 5 ppmvinylkloridmonomer

C 2010-03-15

1) CAS-nr =Chemical Abstract Service-nummer. Internationellt anvnd vetenskaplig nummerserie fr att identifiera kemiskamnen.

2) A =Allergi, C =Cancer, T =Toxiskt, E =Miljfarligt, N =Neurotoxiskt, R =Reproduktionsstrande.

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100-0002