12.04.07 Arlypon TT incosmetics

Chart no. 1

Arlypon® TTA turbo thickener that tames surfactants

Keriman Albaha and Werner Seipel

17th of April 2007

Chart no. 2

OUR THICKENING

Turbo Thickener that tames surfactantsTurbo Thickener that tames surfactantsTurbo Thickener that tames surfactants

Chart no. 3

Performance profile of thickeners

Thickeners today

Arlypon® TT – the synergistic thickener

Temperature / viscosity relationship with Arlypon® TT

Sensorial benefits of Arlypon® TT on Skin

Frame formulations body / hair

Summary

OUR THICKENING

INTRODUCTION

Chart no. 4

High thickening power for all clear and pearlescent surfactant systems

Effective even at low surfactant concentration

Easy to handle

Cold processable

Liquid – pumpable

Good compatibility with shampoo and body wash ingredients


Chart no. 5


Thickeners today





Summary

OUR THICKENING

Chart no. 6

MicellarMicellar thickenerthickener

Thickeners Today

From Sphere to Rod Like Micelle

A micellar thickener

forms rod micelles and

stabilizes these.

Chart no. 7

MicellarMicellar thickenerthickener

useful for:

standard surfactant combinations

viscosity adjustment with low amount

of electrolytes

stabilizing heterogeneous systems by

adjustment of the density

e.g. pearl shine waxes

Viscosity adjustment with NaCl

Thickening by NaCl only

Thickening by

Fatty Alcohol EO and NaCl

0

2000

4000

6000

8000

10000

12000

14000

16000

18000

20000

0 0,5 1 1,5 2 2,5 3 3,5 4 4,5 5 5,5 6 6,5 7 7,5 [%] NaCl

10% as SLESη [mPa •s ] viscosity

Thickeners Today

Chart no. 8

MicellarMicellar thickenerthickenerViscosity adjustment with

Laureth-2 and NaCl

Advantages: Disadvantages:

Easy to handle = liquid

Sufficient temperature – viscosity stability

For standard surfactant systems only

Limited viscosity potential

1800

5800

12600

10

100

1000

10000

100000

+23°C +30°C +40°C

η [mPa•s] viscosity

temp.

Thickeners Today

Chart no. 9

Associative thickener

micellemicelle

water

hydrophobichydrophilic

general chemical structure

Thickeners Today

PEGPEG’s

An associative thickener links micelles andbuilds up an agglomerate of thickener and

micelles.

Chart no. 10

Associative thickener

Advantages: Disadvantages:

Sufficient thickening potential

useful for low surfactant concentrations and

difficult to thicken ingredients

Additional benefits e.g. skin and hair conditioning

No sufficient temperature / viscosity stability at +40°C

(Temperature stability is important for heterogeneous systems)

Rheological behavior = newtonian viscosity

useful for:

alternative and standard surfactant combinations

low surfactant concentrations

difficult to thicken ingredients

Standard surfactant formulation with associative thickener

Stable pearl shine formulations at least

need a viscosity of 200 mPa•s at +40°C. 50

1425

8900

10

100

1000

10000

100000

+23°C +30°C +40°C


PEG-120 Methyl Glucose Dioleate

temp.

Thickeners Today

Chart no. 11


Thickeners today





Summary

OUR THICKENING

Chart no. 12

INCI PEG/PPG-120/10 Trimethylolpropane Trioleate (and) Laureth-2

Technical Data

Appearance : clear liquid

Water : 9 – 11 %

pH value (1% in water /IPA 1:1) : 5.0 – 6.5

Density (20°C, g/cm³) : 0.95 – 1.00

cold processable

preservative free

Chart no. 13

Arlypon® TT combines the advantages of different mechanisms

PEG/PPG-120/10 Trimethylolpropane Trioleateas an associative thickener

Laureth-2as a micellar thickener

(and)

micellemicelle

water

hydrophobichydrophilic

An associative thickener links micelles andbuilds up an agglomerate of thickener and

micelles.

A micellar thickenerforms rod micelles and

stabilizes these.

+

++

From Sphere to Rod Like Micelle

anionic cationic ion nonionic

+

++Both components are linked to aneffective thickener compound

with synergistic effects.

The Synergistic Thickener

Chart no. 14

8500

11300

14000

0 5000 10000 15000

8% WAS + 1%Arlypon TT




SLES – free surfactant combination:Sodium Cocoamphoacetate (and) Glycerin (and) Lauryl Glucoside (and)

Sodium Cocoyl Glutamate (and) Sodium Lauryl Glucose Carboxylate

difficult to

thicken

surfactant blend

Measurement:

Brookfieldspindle LV2 / LV4speed 6 / 12 / 60 rpmroom temperature

Performance in SLES - Free Surfactant Systems

Chart no. 15

8% WASSurfactant combination that contains

Sodium Cocoamphoacetate (and)Glycerin (and)

Lauryl Glucoside (and)Sodium Cocoyl Glutamate (and)

Sodium Lauryl Glucose Carboxylate

thickener 1% as is

8

20

25

8500

0 5000 10000 15000

without


PEG-200 Hydrogenated Glyceryl Palmate[and] PEG-7 Glyceryl Cocoate

PEG/PPG-120/10 TrimethylolpropaneTrioleate [and] Laureth-2


Viscosity improvement in SLES Viscosity improvement in SLES -- Free formulationsFree formulations

Measurement:



Chart no. 16

Ingredient INCI weight % (as is) (active) function

Plantapon® LGC Sorb Sodium Lauryl Glucose Carboxylate 32.3 10.0 Surfactant(and) Lauryl Glucoside

Dehyton® MC Sodium Cocoamphoacetate 6.0 2.0 SurfactantDehyton® PK 45 Cocamidopropyl Betaine 4.1 1.5 SurfactantCetiol® LDO Dicaprylyl Ether (and) Lauryl Alcohol 0.3 EmollientArlypon® TT PEG/PPG-120/10 Trimethylolpropane Trioleate

[and] Laureth-2 0.97 Thickenerperfume fragrance 0.3 Fragrancepreservative preservative 0.1 PreservativeCitric Acid 50% Citric Acid 0.56 pH adjustmentwater 55.37pH-value 5.5

viscosity mPa·s 8800WAS 13.5% (no.: HB-DE/06/146/13)

Specific Mild Shower Bath for Sensitive Skin


Chart no. 17

Very good thickening power without additional NaCl

Arlypon® TT shows better viscosity in SLES-free surfactant systems than benchmarks

Viscosity Performance in SLES - Free surfactant systems


Chart no. 18

Ingredient INCI weight % (as is)

Plantapon® LGC Sorb Sodium Lauryl Glucose Carboxylate(and)Lauryl glucoside 15.0

Texapon® N70 Sodium Laureth Sulfate 6.0Dehyton® MC Sodium Cocoamphoacetate 6.0Texapon® SB 3KC Disodium Laureth Sulfosuccinate 6.0Plantapon® LC7 Laureth-7 Citrate 2.0Gluadin® WQTM Hydroxypropyltrimonium

Hydrolyzed Wheat Protein 1.5Cetiol® LDO Dicaprylyl Ether (and) Lauryl Alcohol 0.3Polymer JR 400 Polyquaternium-10 0.05Arlypon® TT PEG/PPG-120/10 Trimethylolpropane Trioleate

[and] Laureth-2 0 - 3.0perfume Fragrance 0.3preservative Preservative 0.1MgCl2•6H2O Magnesium Chloride 0.4water water add to 100.0

pH-value 5.5washing active substance 11.9%

(no.: HB-DE/06/090/....)

Performance in SLES - Poor Surfactant Systems

Chart no. 19

5000

19200

0

20000

40000

60000

80000

without 0,5 1 1,5 2 2,5 3

spindle no 4, 10 rpmspindle no TE, 4 rpm

Measurement:

Brookfieldspindle no 4 / TEspeed 4 / 10 rpmroom temperature


[%] Arlypon TT

(no.: HB-DE/06/090/....)

Viscosity improvementViscosity improvement in a SLES in a SLES -- Poor formulationPoor formulation


Chart no. 20

Thickening behavior in a formulation with low SLES content

(no.: HB-DE/06/090/....)

1,63

2

1

0 1 2 3

PEG-120 Methyl GlucoseDioleate

PEG-200 HydrogenatedGlyceryl Palmate [and]PEG-7 Glyceryl Cocoate

PEG/PPG-120/10Trimethylolpropane

Trioleate [and] Laureth-2

Viscosity adjustment of 5000 mPa•s

[%] Thickener


Chart no. 21

different pH adjustments

15800

6800

3400

10200

3200

14000

5000

10000

15000

20000

5,0 6.0 7,0 [pH value]


(no.: HB-DE/06/090/....)



Chart no. 22

Ingredient INCI weight % (as is) active function

Plantapon® LGC Sorb Sodium Lauryl Glucose Carboxylate(and) Lauryl Glucoside 15.0 4.7 surfactant

Texapon® N70 Sodium Laureth Sulfate 6.0 4.2 surfactantDehyton® MC Sodium Cocoamphoacetate 6.0 1.0 surfactantTexapon® SB 3KC Disodium Laureth Sulfosuccinate 6.0 2.0 surfactantPlantapon® LC7 Laureth-7 Citrate 2.0 conditioning agentGluadin® WQTM Hydroxypropyltrimonium

Hydrolyzed Wheat Protein 1.5 conditioning agentCetiol® LDO Dicaprylyl Ether (and) Lauryl Alcohol 0.7 emollientPolymer JR 400 Polyquaternium-10 0.05 conditioning agentArlypon® TT PEG/PPG-120/10 Trimethylolpropane Trioleate

[and] Laureth-2 1.1 viscosity adjustmentperfume Fragrance 0.3preservative Preservative 0.1MgCl2•6H2O Magnesium Chloride 0.4 complexing agent and

viscosity adjustmentNaOH 50% Sodium Hydroxide 0.12water water 60.73

pH-value 5.5viscosity mPa•s 5400washing active substance 11.9% (no.: HB-DE/06/146/17)

SLES poor Mild Shampoo

Chart no. 23


Superior viscosity profile compared to benchmarks

Very effective even at low surfactant concentrations


Chart no. 24

SLES : CAPBratio 10:2

1% Arlypon® TT

Viscosity adjustment in a standard SLES formulation

1,95

1,53

1,31

0 1 2 3

8% WAS with 4000mPa.s



Viscosity adjustment

[%] NaCl

Performance in SLES / CAPB Surfactant System

Measurement:


Chart no. 25

SLES : CAPB8% WAS

ratio 6,7:1,3thickener 1% as is

2,23

1,85

5,42

1,95

0 1 2 3 4 5 6

without




Viscosity adjustment of 4000 mPa•s

[%] NaCl

Measurement:



Chart no. 26

2600

9000

31000

40000

22500

13750

10000

20000

30000

40000

50000

0 1 2 3 4 5 6 7 [%] NaCl

12% WAS

with 1% Arlypon TT

22000

8400

1800

28000

11200

0

5000

10000

15000

20000

25000

30000

0 1 2 3 4 5 6 7 [%] NaCl

5600

1200

11500

13400

4200

0

5000

10000

15000

20000

0 1 2 3 4 5 6 7 [%] NaCl

3300

1200770

5200

0

5000

10000

15000

0 1 2 3 4 5 6 7 [%] NaCl


10% WAS

with 1% Arlypon TTη [mPa•s] viscosity

8% WAS

with 1% Arlypon TT

η [mPa•s] viscosity η [mPa•s] viscosity6% WAS

with 1% Arlypon TT

Viscosity Profile in

Standard Surfactant System

at different NaCl concentrations

Measurement:

Brookfieldspindle LV2 / LV4

speed 6 / 12 / 60 rpmroom temperature

Surfactant ratioSLES : CAPB

10 : 2 AS


Chart no. 27


Texapon® N 70 Sodium Laureth Sulfate 11.9 8.3 SurfactantDehyton® PK 45 Cocamidopropyl Betaine 4.6 1.7 SurfactantArlypon® TT PEG/PPG-120/10 Trimethylolpropane Trioleate

[and] Laureth-2 1.0 ThickenerDehyquart® 701/NA Polyquaternium-7 1.7 Conditionerperfume fragrance 0.3 Fragrancepreservative preservative 0.1 PreservativeCitric Acid 50% Citric Acid 0.08 pH adjustmentNaCl Sodium Chloride 1.5 viscosity adjustmentwater 78.82

pH-value 5.5viscosity mPa·s 9000WAS 10.0%

(no.: HB-DE/06/146/05)

Standard Surfactant / Clear Shower Bath

Clear Shower Bath

Chart no. 28


Texapon® N 70 Sodium Laureth Sulfate 14.3 10.0 SurfactantPlantacare® 818 UP Coco-Glucoside 3.8 2.0 SurfactantCetiol® LDO Dicaprylyl Ether (and) Lauryl Alcohol 0.7 EmollientArlypon® TT PEG/PPG-120/10 Trimethylolpropane Trioleate

[and] Laureth-2 1.0 ThickenerPolymer® JR 400 Polyquaternium-10 0.2 Conditionerperfume fragrance 0.3 Fragrancepreservative preservative 0.1 PreservativeCitric Acid 50% Citric Acid 0.22 pH adjustmentNaCl Sodium Chloride 1.5 viscosity adjustmentwater 77.88


(no.: HB-DE/06/146/02)

Standard Surfactant / Care Shampoo

Super Care Shampoo

Chart no. 29

The synergistic thickening effect of Arlypon® TT enables to build up

sufficient viscosity in all standard surfactant formulations

Thickening in Standard Surfactant System


Chart no. 30


Thickeners today





Summary

OUR THICKENING

Chart no. 31

Formulation no.: DE-HB/06/159/ 10 11 12------------------- weight % ---------------

Texapon® N70 13.9 13.9 13.9Dehyton® PK 45 5.2 5.2 5.2Dehyquart® 701/NA 1.5 1.5 1.5Lamesoft® PO 65 1.0 1.0 1.0Arlypon® TT 1.0 --- ---PEG-200 Hydrogenated Glyceryl Palmate [and] PEG-7 Glyceryl Cocoate --- 1.0 ---PEG-120 Methyl Glucose Dioleate --- --- 1.0Wax dispersion 2.0 2.0 2.0perfume 0.3 0.3 0.3preservative 0.1 0.1 0.1NaCl 0.5 0.6 0.5water --------------- add to 100% ---------------pH value 5.6 5.6 5.6viscosity mPa•s 7100 8000 5200

The viscosity / temperature behavior of a formulation with pearlized wax Stability

Temperature / Viscosity behavior

Chart no. 32

The viscosity / temperature behavior of a formulation with pearlized wax

Formulation no.: DE-HB/06/159/ 10 11 12

viscosity mPa•s 23°C 7100 8000 5200viscosity mPa•s 40°C 200 < 100 < 100density g/cm³ 20°C 1.0245 1.0242 1.0256


PEG-200 HydrogenatedGlyceryl Palmate(and)

PEG-7 Glyceryl Cocoate


Arlypon® TT

Stable after 12 weeksStability

Chart no. 33

Arlypon® TT maintains sufficient viscosity also at higher

temperature in pearlized formulations



Chart no. 34


Thickeners today





Summary

OUR THICKENING

Chart no. 35

Formulation no.: DE-HB/06/146/ 35 37------- weight % -------

Texapon® N70 11.9 11.9Dehyton® PK 45 4.6 4.6Dehyquart® 701/NA 1.7 1.7Arlypon® TT --- 1.5perfume 0.3 0.3preservative 0.1 0.1citric acid 50% 0.08 0.08NaCl 2.2 0.6water ------ add to 100% -----

pH value 5.5 5.5viscosity mPa•s 8000 6600

Skin Sensory Assessment

Sensory benefits on Skin

Chart no. 36

placebo with 1.5% Arlypon® TT

1.5% Arlypon® TTsignificantly improves the foam parameters

and the softness of the skin

Pairwise comparison of developed formulation 06/146/037with reference 06/146/35 in different variables

-1 -0,5 0 0,5 1

[easy] Distribution

[easy] Flash foam

[more] Amount of foam

[much] Foam cushion

[small] Foam bubble size

[high] Foam stability

[more] Body

[more] Creaminess

[easy] Rinse off

[more] Softness (after 8min)

[more] Softness (after 30min)

[more] Smoothness (after 8min)

[more] Smoothness (after 30min)

[less] Dryness (after 8min)

[less] Dryness (after 30min)

[high] Acceptance>=0,1

<0,1<0,05<0,01

p-Valuen = 11


Flash foam

Amount of foam

Softness (after 8min)

Softness (after 30min)

Acceptance

Chart no. 37

Sensorial Assessment showed that Arlypon® TT improves skin softness

Sensorial Assessment showed perceivable foam improvement


Additional benefits for Arlypon® TT

Chart no. 38

The dermatological behavior was tested by HET-CAM and RBC tests

The results showed that Arlypon® TT has a neutral influence

Additional information

The Arlypon® TT wasn’t tested on animals

Chart no. 39


Thickeners today





Summary

OUR THICKENING

Chart no. 40

Specific Mild Shower Bath for Sensitive Skin HB-DE/06/146/13

Super Mild Shampoo HB-DE/06/146/17

Clear Shower Bath HB-DE/06/146/05

Super Care Shampoo HB-DE/06/146/02

Soft Care Shower Bath HB-DE/06/146/37

Extra Care Shampoo HB-DE/06/146/04

Frame Formulations

Chart no. 41



[and] Laureth-2 1.5 ThickenerDehyquart® 701/NA Polyquaternium-7 1.7 Conditionerperfume fragrance 0.3 Fragrancepreservative preservative 0.1 PreservativeCitric Acid 50% Citric Acid 0.08 pH adjustmentNaCl Sodium Chloride 0.6 viscosity adjustmentwater 79.22


(no.: HB-DE/06/146/37)

Performance in standard Surfactant Systems

Soft Care Shower Bath

Chart no. 42





(no.: HB-DE/06/146/04)

Performance in standard Surfactant Systems

Extra Care Shampoo

Chart no. 43


Thickeners today





Summary

OUR THICKENING

Chart no. 44

Easy to handle

Cold processable

Liquid – pumpable

Preservative free

Synergistic combination for all types of surfactants

Our thickening

Applicational Summary

Turbo Thickenerthat tames surfactants

Chart no. 45

Excellent thickening power

Very effective even at low surfactant concentrations

Better stabilization of viscosity at higher temperature (pearlized systems)

Perceivable skin softness improvement

Performance Summary

Turbo Thickenerthat tames surfactants

Chart no. 46

OUR THICKENING

Turbo Thickener that tames surfactantsTurbo Thickener that tames surfactantsTurbo Thickener that tames surfactants

Chart no. 47

OUR THICKENING

[All products in the text marked with an ® are trademarks of the Cognis Group]

The information on product specifications provided herein is only binding to the extent confirmed by Cognis in a written Sales Agreement. COGNIS expressly disclaims any responsibility for the suitability of the products for any specific or particular purposes intended by the user. Suggestions for the use and application of the products and guide formulations are given for information purposes only and without commitment. Such suggestions do not release Cognis´ customers from testing the products as to their suitability for the customer’s intended processes and purposes. Cognis does not assume any liability or risk involved in the use of its products as the conditions of use are beyond its control. The user of the products is solely responsible for compliance with all laws and regulations applying to the useof the products, including intellectual property rights of third parties.

BACK-UP CHARTS

Chart no. 51

12% WAS Plantapon® SF

Sodium Cocoamphoacetate (and)Glycerin (and)

Lauryl Glucoside (and)Sodium Cocoyl Glutamate (and)

Sodium Lauryl Glucose Carboxylate

thickener 1% as is

10

8100

5600

14000

0 5000 10000 15000

without




Measurement:


Viscosity proof in SLES Viscosity proof in SLES -- Free formulations Free formulations



Chart no. 52

Thickening behavior in a SLES Thickening behavior in a SLES -- Poor formulationPoor formulationtemperature influencetemperature influence

19600

10400

3000

4000

5000

10000

15000

20000

5 23 30 40 [°C] Temperature


(no.: HB-DE/06/090/....)


Chart no. 53

SLES : CAPBratio 10:2

without thickener

33002500190013250

10000

20000

30000

40000

50000

0 1 2 3 4 5 6 7 [%] NaCl

Thickening behavior in a standard SLES formulationsThickening behavior in a standard SLES formulationswith different salt concentrations with different salt concentrations Performance

Measurement:


70007800

570043502500

0

10000

20000

30000

40000

50000

0 1 2 3 4 5 6 7 [%] NaCl

54004700350028000

10000

20000

30000

40000

50000

0 1 2 3 4 5 6 7 [%] NaCl


SLES : CAPBratio 8.3:1.7

without thickener

η [mPa•s] viscosity SLES : CAPBratio 6.7:1.3

without thickener

η [mPa•s] viscosityη [mPa•s] viscosity SLES : CAPB

ratio 5:1without thickener

Performance in Standard Surfactant System

7850076000

53000

21600

0

20000

40000

60000

80000

100000

0 1 2 3 4 5 6 7 [%] NaCl

Chart no. 54

0

100

200

300

400

500

600

700

800

900

1000

0 10 20 30 40 50

Shower Bathwithout Arlypon TT

Shower Bath with0,5% Arlypon TT

Shower Bath with1% Arlypon TT

Shower Bath with1,5% Arlypon TT

foam volume [ml]

stirring time [s]

Test Design:solution 10 g/l water hardness 255 ppm CaCO3

15°dH = 2,68 mmol/Ca2+

temperature = 30°Ctime intervals = 10 sec rotation speed: 1300 r.p.m.

Foam properties measuredby the

“Rotor-Foam-Test”

flash foam

Foam Behavior in a Standard Surfactant System

Chart no. 55


Texapon® N 70 Sodium Laureth Sulfate 14.3 10.0 SurfactantDehyton® PK 45 Cocamidopropyl Betaine 4.1 1.5 SurfactantCetiol® LDO Dicaprylyl Ether (and) Lauryl Alcohol 0.7 EmollientArlypon® TT PEG/PPG-120/10 Trimethylolpropane Trioleate



(no.: HB-DE/06/146/01)

Standard Surfactant / Care Shampoo

Chart no. 56

Formulation no.: DE-HB/06/146/ 31 32 4--------- weight % ---------

Texapon® N70 11.9 11.9 11.9Dehyton® PK 45 4.6 4.6 4.6Polymer® JR 400 0.2 0.2 0.2Arlypon® TT --- 0.5 1.0perfume 0.3 0.3 0.3preservative 0.1 0.1 0.1citric acid 50% 0.05 0.07 0.1NaCl 1.5 1.4 1.0water -------- add to 100% ------

pH value 5.5 5.5 5.5viscosity mPa•s 6200 7800 6800

Hair Combing TestHair Combing Test

Additional Benefits / Hair Conditioning

Chart no. 57

77%

86%

89%

0 20 40 60 80 100 120

Combing test on hair strandsCombing test on hair strands

[%] residue in wet combing work

%

Shampoo HB-DE/06/146/31with 0.2% PQ-10

Shampoo HB-DE/06/146/32with PQ-10 + 0.5%Arlypon TT

Shampoo HB-DE/06/146/04with PQ-10 + 1% Arlypon TT

Additional Benefits / Hair Conditioning

WS9

Folie 57

WS9 Report: AH 2006/017 A.Huhn CTPP 06-00329 05.12.2006

Seipel; 22.01.2007

Chart no. 58

The viscosity / temperature

behavior of a

Pearlized formulation

with different thickeners

Formulation no.: DE-HB/06/159/ 05 06 07------------------------ weight % ----------

Texapon® N70 13.9 13.9 13.9Dehyton® PK 45 5.2 5.2 5.2Dehyquart® 701/NA 1.5 1.5 1.5Arlypon® TT 1.0 --- ---PEG-120 Methyl Glucose Dioleate --- 1.0 ---PEG-200 Hydrogenated Glyceryl Palmate [and] PEG-7 Glyceryl Cocoate --- --- 1.0Euperlan® PK 3000 OK 2.0 2.0 2.0perfume 0.3 0.3 0.3preservative 0.1 0.1 0.1NaOH 10% --- 0.4 0.03NaCl 0.5 0.3 0.3water ---------------------- add to 100% ----------

pH value 5.5 5.5 5.5viscosity mPa•s 23°C 13.000 5000 8300density g/cm³ 20°C 1.0268 1.025 1.0273

Temperature / Viscosity behaviorin a standard Surfactant System

Chart no. 59

1800

<50 <50

400

10

100

1000

10000

Laureth-2 PEG-200Hydrogenated

Glyceryl Palmate[and] PEG-7

Glyceryl Cocoate

PEG-120 MethylGlucose Dioleate

PEG/PPG-120/10Trimethylolpropane

Trioleate [and]Laureth-2

η [mPa•s] viscosity at +40°C

A higher viscosity

[at +40°C] has a

positive influence

on the stability.

Viscosity behavior at +40Viscosity behavior at +40°°CC

DE-HB/06/159/5, 6, 7, 9

Temperature / Viscosity behaviorin a standard Surfactant System

Chart no. 60

Viscosity improvement in a surfactant system with SLESViscosity improvement in a surfactant system with SLES

Test formulation DE/06/084/....-------- weight % -------

Texapon® N70 Sodium Laureth Sulfate 12.8Plantacare® 818 UP Coco-Glucoside 2.9Dehyton® PK45 Cocamidopropyl Betaine 3.8

Arlypon® TT PEG/PPG-120/10 Trimethylolpropane Trioleate 1.0 / 2.0(and) Laureth-2

Citric Acid (20%) Citric Acid ~NaCl Sodium Chloride 1 – 6%water water ---- add to 100% ----

pH value 5.5

WAS % 12.0

viscosity mPa•s ~


Chart no. 61

SLES : APG : CAPBratio 9 : 1.5 : 1.5

Arlypon TT 1% / 2% [mPa.s] viscosity

0

10000

20000

30000

40000

50000

60000

70000

0 1 2 3 4 5 6 [%] NaCl

Arlypon TT 1%Arlypon TT 2%

Thickening behavior in a surfactant system with SLES

Measurement:

Brookfield RVFspindle 4 / 5speed 4 / 10 rpmroom temperature +23°C

no. HB-DE/06/084/....


Chart no. 62

Formulation no.: DE-HB/06/146/ 35 36 5 37------------------------ weight % ----------------------

Texapon® N70 11.9 11.9 11.9 11.9Dehyton® PK 45 4.6 4.6 4.6 4.6Dehyquart® 701/NA 1.7 1.7 1.7 1.7Arlypon® TT --- 0.5 1.0 1.5perfume 0.3 0.3 0.3 0.3preservative 0.1 0.1 0.1 0.1citric acid 50% 0.08 0.09 0.08 0.08NaClwater ---------------------- add to 100% --------------------

pH value 5.5 5.5 5.5 5.5viscosity mPa•s 8000 9600 9000 6600

Arlypon® TT Dermatological Behavior


Chart no. 63

Test concentration: 3% as ispH appr. 6.5

severely irritating> 2.0

irritating> 0.12 < 2.0

moderately irritating

> 0.8 < 1.2

slightly irritating< 0.8

ClassificationQ

Classification of the mucous membrane irritation potentialbased on the relative irritation potential Q

High irritationpotential

Low irritationpotential

0

0,5

1

1,5

2

2,5

3

DE-HB/06/146/35

DE-HB/06/146/36

DE-HB/06/146/05

DE-HB/06/146/37

The test results show no significant difference

withoutthickener

with 0,5%Arlypon® TT

Q [relative irritation score]



Hen’s egg test – chorionallantoicmembrane (HET-CAM)

WS4

Folie 63

WS4 Study report Schraderno 857-CCT-06-000-06-55115. December 2006Seipel; 03.01.2007

Chart no. 64

Formulation no.: DE-HB/06/146/ 38 14 40 39------------------ weight % ------------------

Plantapon® SF 33.3 33.3 33.3 33.3Arlypon® TT --- 0.43 --- ---Antil® 200 --- --- 0.8 ---Glucamate® DOE120 --- --- --- 0.6Perfume 0.3 0.3 0.3 0.3preservative 0.1 0.1 0.1 0.1citric acid 50% 0.58 0.7 0.58 0.58water ------------------ add to 100% --------------

pH value 5.5 5.5 5.5 5.5viscosity mPa•s <100 5600 5200 5000

Arlypon® TT Dermatological Behavior vs. Benchmarks


Chart no. 65

Test concentration: 2,5% ASpH appr. 6.5

severely irritating> 2.0

irritating> 1.2 < 2.0

moderately irritating

> 0.8 < 1.2

slightly irritating< 0.8

ClassificationQ

Classification of the mucous membrane irritation potentialbased on the relative irritation potential Q

High irritationpotential

Low irritationpotential

0

0,5

1

1,5

2

2,5

3

DE-HB/06/146/38

DE-HB/06/146/14

DE-HB/06/146/40

DE-HB/06/146/39

withoutthickener

withArlypon® TT

withPEG-200 HGP

PEG-7 GC

withPEG-120 MGD

Q [relative irritation score]

Hen’s egg test – chorionallantoicmembrane (HET-CAM)

The test results show no significant difference WS8

Folie 65

WS8 Study report Schraderno 857-CCT-06-48214. November 2006Seipel; 03.01.2007

Chart no. 66

Ingredient INCI weight % (as is) function

1. Aqua water 52.62. Edenor C 12-98 Lauric acid 11.6 Soap3. Edenor C 14-98 Myristic Acid 5.3 Soap4. Glycerine Glycerine 2.0 Moisturizer/solvent5. Aqua water 9.06. KOH [95%] Potassium Hydroxide 4.5 pH adjustment7. Dehyton® ML Sodium Lauroamphoacetate 6.0 Surfactant8. Comperlan® KD T Cocamide DEA 6.0 Surfactant9. Arlypon® TT PEG/PPG-120/10 Trimethylolpropane

Trioleate [and] Laureth-2 3.0 Thickener10. perfume fragrance q.s. Fragrance11. preservative preservative q.s. Preservative

pH-value 9.3viscosity mPa·s 2000 (no.: HB-KR/07/027/01)

Soft Care Body Wash

1. Heat 1, 2, 3, 4 to 75~80℃, premix solution of 5 and 6 slowly add while stirring at 75~80℃2. Neutralization step. Keep the temp. stirring until homogenous, Adjust the pH around 9.53. Cool down to 50℃, add 7, 8, 9, and cool down to 40℃, add other raw materials

Documents

12.04.07 Arlypon TT incosmetics