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2010 Long-Term Surveillance and Maintenance Conference 2010 Long-Term Surveillance and Maintenance Conference Old Rifle Title I Processing Site, Rifle, Colorado What Are They Doing on My Site? Richard Bush, Rifle Site Manager November 16, 2010

2010 Long-Term Surveillance and Maintenance Conference Old Rifle Title I Processing Site, Rifle, Colorado What Are They Doing on My Site? Richard Bush,

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Old Rifle Title I Processing Site, Rifle, Colorado

What Are They Doing on My Site?

Richard Bush, Rifle Site ManagerNovember 16, 2010

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U.S. Vanadium Company Mill—1924

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Union Carbide Mill—circa 1957

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Old Rifle Site—1967 After Umetco Cleanup

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Old Rifle Site—1999Post-UMTRA Cleanup

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Old Rifle Mill Site—Today

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Site Conceptual Model

Groundwater contamination from raffinate ponds and tailings

Surface cleanup standard Ra-226; metals left Inflow of water from the north via seeps and drainage

ditch contributes groundwater to site Colorado River contributes to flushing

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Site Conceptual Model Diagram

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Regulatory History

1996: Surface cleanup completed 1998: Licensed 1999: Final Site Observational Work Plan for the

UMTRA Project Old Rifle Site 2002: Ground Water Compliance Action Plan for the

Old Rifle, Colorado, UMTRA Project Site meets Nuclear Regulatory Commission approval

Compliance Natural flushing for uranium, maximum contaminant level

(MCL) 0.044 mg/L Alternate concentration limits for vanadium and selenium,

higher than MCL based on background

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Office of Science Investigations Two basic questions posed

Can we immobilize uranium in the groundwater? How long will it last after amendments cease?

Can we better predict uranium removal? Natural flushing relies on modeling

Approach – to support compliance strategy Enhance microbial reduction of soluble uranium(VI) to

precipitated or sorbed uranium(IV) Improved reactive transport simulations to predict removal

of uranium from groundwater

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Recent Developments, Plume Map

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Recent Developments, T/C Plots

0

0.05

0.1

0.15

0.2

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0.3

0.35

0.4

Ura

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mg

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Date

Rifle Old Processing Site (RFO01)Uranium Concentration

Loc 0304

Loc 0305

Loc 0309

Loc 0310

Loc 0655

Loc 0656

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Groundwater Surface Map—Spring 2007

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Conclusions

Site not flushing as predicted Site more complex than expected Additional characterization/new modeling effort? Revisit compliance strategy in light of low risk U.S. Department of Science adding insights to uranium

sequestration, cycling Integrated Field-Research Challenge provides an

outdoor lab Leveraged funding for science and technology Future to expand to floodplain-wide analysis?