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Dave Hawker DATALOG Hydrocarbon Evaluation and Interpretation

4 Gas Ratios

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Page 1: 4 Gas Ratios

Dave Hawker

DATALOG

Hydrocarbon Evaluation and Interpretation

Page 2: 4 Gas Ratios

Gas Normalization

• Porosity, saturation, permeability• hole depth and diameter• penetration rate• bit type• flowrate• differential pressure• mud type and rheology• fluid movements• pressure and temperature change• trap efficiency and losses

Page 3: 4 Gas Ratios

Gas Normalization

• Normalize the ‘geometric’ factors so that they can be eliminated as variables

• Cannot normalize Total Gas values since they are qualitative, not an absolute measurement

• Chromatographic components are totaled to give a Total Chromatograph Gas value

Page 4: 4 Gas Ratios

Gas Normalization

• Can only normalize the gas measurement that we have; cannot account for: -

• losses of gas to atmosphere

• gas retained by cuttings

• phase and solubility changes

• fluid movements in terms of flushing and incursions

Page 5: 4 Gas Ratios

Normalization Formula

dc

ba

N

100

22000

N = normalized gas (%)

a = pump output (m3/min)

b = ROP (min/m)

c = hole diameter (mm)

d = total chromatograph gas (%)

Page 6: 4 Gas Ratios

Comparing Adjacent Shows 0 min/m 15 0.1 Gas 100

10%3 min/m

1 min/m 20%

10 min/m BG 1%

Page 7: 4 Gas Ratios

Possible Causes of Difference

• Lower porosity and bulk volume of gas

• Lower gas saturation

• Reduced permeability

• Increased permeability resulting in flushing

• Different gas composition

Page 8: 4 Gas Ratios

Porosity

Permeability (increase or decrease)

Composition

Saturation

Page 9: 4 Gas Ratios

3 min/m 10%

1 min/m 20%

12 1/4” hole

Flow 2m3/min

8 1/2” hole

1.4 m3/min

Shale Background 1%, 10min/m

Page 10: 4 Gas Ratios

Rule of Thumb vs Normalization

• Sand 1 ~ 3 times ‘better’ than shale

• Sand 2 ~ 2 times ‘better’ than shale

• Sand 1 normalized 24.8% / BG 0.84%

• Sand 2 normalized 18.0% / BG 1.22%

Page 11: 4 Gas Ratios

Shows in different wells/hole sectionsFlowrate m3/min Normalized Gas %

ROP min/m Total Chromatograph %

0 312 ¼ “

8 ½ “

Page 12: 4 Gas Ratios
Page 13: 4 Gas Ratios

Ratio Analysis

• Comparison of chromatographic values for individual hydrocarbon components

• reservoir fluid type

• gas/oil/water contacts

• oil gravity

• production potential; wet zones/permeability

Page 14: 4 Gas Ratios

Pixler Ratio Plot

• Comparison of the methane content to each other alkane

• Only the value of the gas show above the background level is used– eliminates variables since they affect both– only information concerning the relative

production potential is used

Page 15: 4 Gas Ratios

Pixler Ratio Plot Information

• Reservoir Fluid

• Oil Gravity and Gas Wetness

• Production Potential

• Permeability

• Presence of Formation Water

Page 16: 4 Gas Ratios

Ratio Plot

NON-PRODUCTIVE GAS

PRODUCTIVE GAS

PRODUCTIVE OIL

NON-PRODUCTIVE RESIDUAL OIL

C1/C2 C1/C3 C1/C4 C1/C5

1

10

1000

100

Page 17: 4 Gas Ratios

Ratio Plot Zones

• Determined from the comparison of gas ratio data to production and test results

• Can be used as a guide or reference

• Regional calibration will improve the effectiveness of the ratio plot

Page 18: 4 Gas Ratios

C1/C2 Ratio

<2 very low gravity, high density and viscosity, non-productive, residual oil

2 - 4 low gravity oil, 10-15 API

4 - 8 medium gravity oil, 15-35 API

8 - 15 high gravity oil, API >35

10 - 20 gas condensate

15 - 65 gas

> 65 light gas, principally methane, non-productive

Page 19: 4 Gas Ratios

Slope of the Curve

• A fully positive slope confirms productive hydrocarbons

• A negative slope indicates a water bearing zone• Gradient similar to the zone lines indicates good

permeability• The steeper the slope, the tighter the formation• if C1/C2 is low in the oil section, with C1/C4 high

in the gas section, zone is probably non-productive

Page 20: 4 Gas Ratios

Evaluation of Oil Bearing Zones

GAS

OIL

NON-PRODUCTIVE

C1/C2 C1/C3 C1/C4 C1/C5

1

10

100

1000

NON-PRODUCTIVE

Medium-High API

Good Permeability

himed

lo

API

Page 21: 4 Gas Ratios

Evaluation of Oil Bearing Zones

GAS

OIL

NON-PRODUCTIVE

C1/C2 C1/C3 C1/C4 C1/C5

1

10

100

1000

NON-PRODUCTIVE

Medium-High API

Tight

himed

lo

Page 22: 4 Gas Ratios

Evaluation of Oil Bearing Zones

GAS

OIL

NON-PRODUCTIVE

C1/C2 C1/C3 C1/C4 C1/C5

1

10

100

1000

NON-PRODUCTIVE

Medium-Low API

Fair-Good Permeability

himed

lo

Page 23: 4 Gas Ratios

Evaluation of Oil Bearing Zones

GAS

OIL

NON-PRODUCTIVE

C1/C2 C1/C3 C1/C4 C1/C5

1

10

100

1000

NON-PRODUCTIVE

Medium-Low API

Water Bearing

himed

lo

Permeability?

Page 24: 4 Gas Ratios

Evaluation of Oil Bearing Zones

GAS

OIL

NON-PRODUCTIVE

C1/C2 C1/C3 C1/C4 C1/C5

1

10

100

1000

NON-PRODUCTIVE

Very low API

non-productive?

Water Bearinghi

med

lo

Page 25: 4 Gas Ratios

Evaluation of Gas Bearing Zones

GAS

OIL

NON-PRODUCTIVE

C1/C2 C1/C3 C1/C4 C1/C5

1

10

100

1000

NON-PRODUCTIVE

1 3

2

4

1. Methane

Tight, non-productive

2. Productive Gas

Good Permeability

3. Productive Gas

Tight

4. Light Gas

Permeability?

Water Bearing

Page 26: 4 Gas Ratios

Condensates ?

• Indicated by C1/C2 between 10 and 20

• 10 - 15 also indicates high gravity oil

• 15 - 20 also indicates gas

20

15

10

Hi API Oil

Gas

Condensate

Page 27: 4 Gas Ratios

Condensates ?

• Gas, typically yields a more definitive C1/C2 ratio

• Complication with light oils having high Gas Oil Ratio

Page 28: 4 Gas Ratios

Prediction of Gas Condensate

GAS

OIL

NON-PRODUCTIVE

C1/C2 C1/C3 C1/C4 C1/C5

1

10

100

1000

NON-PRODUCTIVEPlots follow a similar gradient to the upper gas limit

C1/C2 ratio suggests a higher proportion of heavier hydrocarbons

Wet Gas or

Condensate ?

Page 29: 4 Gas Ratios

Prediction of Gas Condensate

GAS

OIL

NON-PRODUCTIVE

C1/C2 C1/C3 C1/C4 C1/C5

1

10

100

1000

NON-PRODUCTIVE

Light Oil, reduced permeability

Light Oil with high GOR

Condensate

Page 30: 4 Gas Ratios

Correlation with Fluorescence

C1/C2 Ratio API Gravity Fluid Type NaturalColour

Colour ofFluorescence

2 – 4 10 – 15 Low Gravity Oil Dark brown toblack

Orange to brown

4 – 8 15 – 35 Medium GravityOil

Light to mediumbrown

Cream to yellowgreen, gold

8 – 15 > 35 High Gravity Oil Clear White to bluishwhite to blue

10 – 20 ~ 50 Gas Condensate ‘Gasoline’ Violet if visible

Page 31: 4 Gas Ratios

Ratio Plot Summary

C1/C2 C1/C3 C1/C4 C1/C5

1

10

100

1000

himed

lo

API

Dry gas

Wet Gas

Non-productive gas Geopressure methane

Heavy, viscous, non-productive Residual oil, tars, waxes

Gas Condensate

Page 32: 4 Gas Ratios

Drawbacks to the Gas Ratio Plot

• Difficult to determine condensate reservoirs

• Optimally, requires regional re-calibration

• Limited number of plots for each potential zone

• Plots are offline, so that information is apart from the mud log

Page 33: 4 Gas Ratios

Wetness, Balance and Character Ratios

• Calculated real-time for immediate evaluation and recognition of reservoir changes and contacts

• Plotted on a depth-based log for comparison with other mud logging and wireline data for effective reservoir evaluation

Page 34: 4 Gas Ratios

Wetness Ratio

• Increasing trend as proportion of heavy gas increases, i.e. as gas or oil density increases

• Determination of gas wetness and oil density

10054321

5432

CCCCC

CCCCWh

Page 35: 4 Gas Ratios

Wetness Ratio

<0.5 non-productive dry gas; non-associated or geopressured methane

0.5 - 17.5 gas, increasing in wetness

17.5 - 40 oil, increasing in density (decreasing gravity)

>40 non-productive oil, very low gravity, residual

Page 36: 4 Gas Ratios

Wetness Ratio

1 10 100

NON-PRODUCTIVE, RESIDUALOIL

POTENTIAL OIL PRODUCTION

POTENTIALGAS PRODUCTION

NON-PRODUCTIVEDRY GAS

Increasing density or wetness

Increasing density

Page 37: 4 Gas Ratios

Balance Ratio

• Compares light to heavy gases

• Responds inversely to Wh as fluid density increases

• Used in conjunction with Wh for interpretation

543

21

CCC

CCBh

Page 38: 4 Gas Ratios

Interpretation of Wetness and Balance

Balance Ratio Wetness Ratio Reservoir Fluid and Production Potential

> 100 Very light, dry gasTypically non-associated and non-productive such asthe occurrence of geopressured methane

< 100 < 0.5 Possible production of light, dry gas

Wh < Bh < 100 0.5 – 17.5 Productive gas, increasing in wetness as the curvesconverge

< Wh 0.5 – 17.5 Productive, very wet gas or condensate or high gravityoil with high GOR

< Wh 17.5 – 40 Productive oil with decreasing gravity as the curvesdiverge

<< Wh 17.5 – 40 Lower production potential of low gravity, low gassaturation oil

> 40 non productive, very low gravity, residual oil

Page 39: 4 Gas Ratios

Wetness and Balance Curves0.1 0.5 1.0 10 17.5 40 100

NON-PRODUCTIVE GAS

POSSIBLE PRODUCTIVE GAS

PRODUCTIVE GAS

GAS, OIL or CONDENSATE

PRODUCTIVE OIL

RESIDUAL OIL

DRY

WET

HI GRAV

LO GRAV

Wh

Bh

Page 40: 4 Gas Ratios

Character Ratio

• Ch < 0.5– confirms productive gas phase, either Wet

Gas or Condensate

• Ch > 0.5– indicates productive liquid phase, so that gas

is associated with oil

3

54

C

CCCh

Page 41: 4 Gas Ratios

Combining all Gas Ratios

1 10 17.5 40 1000 3

Dry Gas

IncreasingWetness

Gas or Condensate

High Gravity Oil with High GOR

DecreasingGravity

Residual Oil

Wetness RatioBalance Ratio

Character Ratio

Page 42: 4 Gas Ratios

Summary

• Ratio curves provide very effective trend analysis on a real-time and mud log basis

• Accurate determination of reservoir fluid changes and contacts

• Immediate evaluation as reservoir is being drilled

• Definitive values require, optimally, regional calibration with test or production results

Page 43: 4 Gas Ratios

Oil Indicator

• Compares Methane to Heavy Gases

• Ranges 0.01 to 1, increasing with gas and oil density

1543

CCCCO

Page 44: 4 Gas Ratios

Inverse Oil Indicator

• Inverse of the oil indicator

• Ranges 1 to 100, increasing as the fluid density decreases

5431

CCCCI

Page 45: 4 Gas Ratios

Evaluation of the Oil Indicator Ratios

Oil Indicator Evaluation Inverse Oil Indicator

0.01 - 0.07 dry gas, gas charged water 100 - 14.3

0.07 - 0.10 condensate, light oil with 14.3 - 10.0high GOR

0.10 - 0.40 oil 10.0 - 2.5

0.40 - 1.0 residual oil 2.5 - 1

Page 46: 4 Gas Ratios

Using the Inverse Oil Indicator

1 10 100

Dry Gas

Condensate orLight Oil/Hi GOR

Oil

Residual Oil

Page 47: 4 Gas Ratios

Ratio Summary

• Correctly interpreted, chromatographic gas ratios provide an excellent means of reservoir evaluation and determination of fluid type, contacts, permeability and the presence of water

• Regional calibration against known data will improve their accuracy

• Ratio comparisons and trend evaluation should be used rather than direct quantitative analysis

Page 48: 4 Gas Ratios

Ratio Limitations

• Heavier oils that do not possess the lighter range of hydrocarbons

• Oils with low gas saturation

• Large proportion of produced gas may lead to false proportions

• If mud type, rheology, surface system lead to suspect gas measurements

Page 49: 4 Gas Ratios

Conventional Fluorescence

• Colour under ultra-violet light being an indication of the density of the petroleum fluid

• The intensity of the fluorescence being an indication of the presence of water

• Solvent cut as an indication of density and mobility

Page 50: 4 Gas Ratios

Fluorescence Colour

High API gravity oil

Medium API gravity oil

Low API gravity oil

Very low gravity, typically low intensity

Condensate

10

15

35

45

Page 51: 4 Gas Ratios

Solvent Cut

• Solvent takes the fluid into solution and leaches it out of the cutting

• Speed and nature of the ‘cut’ reflects fluid density, viscosity, solubility and permeability

• The better the permeability, the faster the cut

• The lower the viscosity, the faster the cut

• Uniform blooming indicates good permeability and mobility

• Streaming cut indicates reduced permeability and/or high viscosity

Page 52: 4 Gas Ratios

Limitations to UV Fluorescence

• Subjective colour descriptions

• Presence of contaminants

• Much of the fluorescence emissions fall in the ultra-violet range of the spectrum– any fluorescence visible is only a fraction of the

total emission– Some emissions may go completely undetected

Page 53: 4 Gas Ratios

Quantitative Fluorescence Technique™

• Measurement of the fluorescence intensity which is proportional to the quantity of oil

• Old, stored cuttings can be re-evaluated with this technique

• How representative are the cuttings?

• How much fluid has been retained by the cuttings?

• Fluorescence intensity is not linear across the range of oil gravities

• Cannot be used in gas wells

Page 54: 4 Gas Ratios

Quantitative Fluorescence Technique™

• Elimination of subjective descriptions

• QFT™ measures the oil content as given by the fluorescence intensity so that increases can represent an increased amount or a change in composition

• Total Scanning Fluorescence (TSF™) measures the entire excitation wavelengths of a given crude, with the peak defining the dominant composition

Page 55: 4 Gas Ratios

QFT™ vs Gas/Fluorescence

Reservoir Top

Reservoir Base

Fluoresence

QFT Total Gas

Page 56: 4 Gas Ratios