4._11301200_Metal & Equipment for HB LED_Semicon Taiwan 2011

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    Material and Equipment

    Technologies for HB-LED

    Manufacturing

    2011 Brewer Science, Inc.

    Ram K. Trichur

    Director, Strategic Business Unit

    SEMICON West 2011

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    Slide 2Brewer Science, Inc., SEMICON Taiwan, 2011

    Brewer Science Delivers Solutions

    to These Markets

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    Slide 3Brewer Science, Inc., SEMICON Taiwan, 2011

    Brewer Science

    In 1981, invented the anti-reflective coatingsmarketplace Maintain market share dominance for BARC 30 years of innovation enabling our customers to

    overcome critical industry challenges

    Global supply and support network

    Corporate Headquarters, Rolla, Missouri Dr. Terry Brewer, President, CEO, Founder

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    Slide 4Brewer Science, Inc., SEMICON Taiwan, 2011

    Brewer ScienceSolutions for Advanced Packaging

    Generic LED Fab Process Flow

    Backend

    ProcessesSubstrate

    Growth

    MOCVD

    Processes

    Front-End Chip

    Manufacturing

    Thin Wafer

    Handling

    TSV Creation/

    Micromachining

    Advanced

    Interconnects

    Surface

    Modification

    Planarization

    Brewer Science offers varioustechnology solutions for advancedpackaging in LED manufacturing

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    Slide 5Brewer Science, Inc., SEMICON Taiwan, 2011

    Brewer ScienceSolutions for Advanced Packaging

    Thin WaferHandling

    TSV Creation/

    Micromachining

    Advanced

    Interconnects

    Surface

    Modification

    Planarization

    Temporary Bonding Materials

    Benchtop Wafer Debonding Tools

    Adhesion Promoters

    Low-Surface-Energy Materials

    Self-Leveling Planarization Materials

    Contact Planarization

    Acid- & Base-Resistant Materials

    Scratch-Resistant Materials for DRIE

    Carbon NanotubeBased Conductors

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    Slide 6Brewer Science, Inc., SEMICON Taiwan, 2011

    Chemical Release

    Technology

    Slide Debonding

    Technology

    ZoneBONDTM

    Technology

    Brewer ScienceSolutions for Thin Wafer

    HandlingHigh-Temperature-CapableTemporary Bonding Technology

    Perforated Carrier

    Solvent for Chemical Release

    Low cost of ownershipand low initial investment Suitable for low-volumeoperations

    Commercial technologyusing WaferBOND

    CR-200 coating

    Slide

    Slide

    Heat

    Wafer sizes up to 300 mm

    Automated and semi-automated debondingtools available

    Commercial technologyusing WaferBOND

    HT-10.10 coating

    ZB Carrier

    Release

    Zone

    Adhesive on Device

    Stiction Zone

    Alpha-stage technology

    Room temperaturedebonding capability Higher throughput

    capability

    Compatibility - 100 mm to300 mm wafers possible

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    Slide 7Brewer Science, Inc., SEMICON Taiwan, 2011

    Motivation for Temporary Bonding

    Wafer-Level Electrical Redistribution An intermediate 3-D TSV interposer can be

    used between the LED component and the

    PCB to drive electrical current and heataway from the LED chip

    Temporary bonding is widely used in thefabrication of Si-based TSV interposers

    AlN

    LED chip

    Si submountwith Cu TSVsCu-filledTSVs

    Layer Transfer or Laser Lift-Off (LLO)Process Temporary bonding demands are increasing with

    need for LLO technique - creating need to handlethin wafers using temporary bonding

    Carrier

    Sapphire

    Laser

    GaNMirror

    Thin Wafer

    handling

    Courtesy of Shinko

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    Slide 8Brewer Science, Inc., SEMICON Taiwan, 2011

    Layer Transfer ProcessSapphire wafer with

    active epi layer

    Coat WaferBOND

    material and bond totemporary carrier

    Growth substrate

    separation and n-side processing

    Debond chip wafer

    from temporary

    carrier and cleanWaferBONDmaterial

    Material Requirements for Layer Transfer Processes:

    Stability during high-temperature processing (~ 250C)Ability to withstand acid or alkaline treatmentsStability during vacuum, CVD processesThin wafer handling capability to support epi and chip carrierSupport high shear stress during backgrinding (if not using LLO process)

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    Slide 9Brewer Science, Inc., SEMICON Taiwan, 2011

    Temporary Wafer Bonding Process

    Supports all thin-wafer processes:

    Layer transfer processes Grinding and thinning growth

    substrates (sapphire or other)

    Interposer layer orthrough-viaprocessing

    Brewer Science provides complete

    solution:

    Uses standard bonding tools Brewer Science provides bonding

    materials and process support

    Brewer Science suppliesdebonding equipment

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    Slide 10

    Chemical Resistance of

    WaferBONDHT-10.10 Material

    15-m film on 4-inch Si wafer hot plate baked at 100C for 2 min

    followed by a hot plate bake at 160C for 2 min

    *HMDS pretreatment must be used for TMAH processing stability

    Chemistry BathTemperature

    Time Results

    Acetone 25C 25 min film unchanged

    0.26N TMAH* 60C 30 min film unchanged

    6N HCL 60C 30 min film unchanged

    15% H2O2 60C 40 min film unchanged

    30% NH4OH 25C 30 min film unchanged10% KI in H2O 25C 20 min film unchanged

    EtOH 25C 5 min film unchanged

    MeOH 25C 5 min film unchanged

    IPA 25C 5 min film unchanged

    Cyclohexanone 25C 5 min film unchanged

    Ethyl Lactate 25C 5 min film unchanged

    PGMEA 25C 5 min film unchanged

    PGME 25C 5 min film unchanged

    30% HCL 25C 90 min film unchanged

    70% HNO3 25C 1 hr film unchanged

    30% KOH 85C 1 hr film intact, but peeling atedges

    WaferBONDHT-10.10 bonding material has been shown to be stable through a widevariety of wet chemical processes used during TSV creation

    I will insert 2 images

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    Slide 11

    WaferBONDTechnology in TSV Application

    WaferBONDHT-10.10material coated on

    device wafer

    Bonded tocarrier

    Thinneddevice wafer

    TSV creation

    Debonded

    TSV wafer

    70-m thick wafer, 1:1

    aspect ratio vias, copper

    redistribution layer

    Silicon interposer, RDL - Fuji

    All processing, including via etching, passivation, and

    metallization, is completed at wafer level

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    Chemical Release

    Technology

    Slide Debonding

    Technology

    ZoneBONDTM

    Technology

    Brewer ScienceSolutions for Thin Wafer

    HandlingHigh-Temperature-CapableTemporary Bonding Technology

    Perforated Carrier

    Solvent for Chemical Release

    Low cost of ownershipand low initial investment

    Suitable for low-volumeoperations

    Commercial technologyusing WaferBOND

    CR-200 coating

    Slide

    Slide

    Heat

    Wafer sizes up to 300 mm

    Automated and semi-automated debondingtools available

    Commercial technologyusing WaferBOND

    HT-10.10 coating

    ZB Carrier

    Release

    Zone

    Adhesive on Device

    Stiction Zone

    Alpha-stage technology

    Room temperaturedebonding capability Higher throughput

    capability

    Compatibility - 100 mm to300 mm wafers possible

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    Debonding Process Chemical Release

    Slide 13

    Thinned device

    substrate

    Perforated wafer

    as carrier

    Features Spin-applied thermoplastic bonding material - WaferBOND CR-200

    material

    Debonded and released in a solvent low-stress process Compatible with most wafer sizes Low equipment cost for demounting Suitable for low-volume applications

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    Debonding Process Chemical Release

    Slide 14

    SeparationJig

    Removal Solvent Perforated Carrier

    Low-stress solvent bath demounting from carrier

    Separated Device Wafer

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    Slide 15Brewer Science, Inc., SEMICON Taiwan, 2011

    Debonding Process - Slide Debonding

    Slide

    Slide

    Heat

    Spin rinse with

    solvent & spin dry

    Thinned device

    substrate

    Reuse carrier

    Thinned device

    carrier

    Enabled by

    WaferBOND family of temporary bonding materials Cee 1300DB thermal slide-off debonding tool

    Features

    Semi-automated or automated debonding process Compatible with wafer sizes up to 300 mm Suitable for R&D to high-volume applications

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    Slide 16Brewer Science, Inc., SEMICON Taiwan, 2011

    Cee1300DB Slide Debonding Tool

    Proven on:

    Sapphire Silicon Silicon carbide GaAs, InP Multiple diameters

    (3, 4, 6, 8, and 12 in)

    Semiautomatic, tabletop thermal slide-off debonding tool for use

    with WaferBONDtemporary bonding material.

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    Room Temperature Separation ZoneBOND

    System

    Basic Process Flow:

    1. Coat polymer adhesive on device

    2. Create carrier: Release zone & stiction zone

    3. Bond face to face

    4. User processes: Thin, pattern, etc.

    5. Remove stiction zone adhesive

    6. Mount device side on film frame

    7. Separate carrier from adhesive

    8. Clean adhesive from device

    Device

    Carrier

    Stiction ZoneRelease ZoneZB Carrier

    Adhesive on Device

    1

    2

    Device

    Carrier

    Polymer Adhesive3

    4

    Thin Device

    7

    8

    5 6&

    Alpha-stage technology

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    Room Temperature Separation ZoneBOND

    System

    Slide 18

    Features Low mechanical & thermal stress on

    device wafer

    Separate carrier away from adhesive,not device

    Room temperature debonding Enables the use of adhesives that are

    tolerant of higher temperatures

    Eliminates the conflict of adhesivetemperature capability versustemperature requirements fordebonding

    Designed for higher debondingthroughput

    Compatible with wafer sizes 100 mm to300 mm

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    Summary

    Brewer Science is an established technologypartner in the microelectronics industry with

    strong expertise in IC, MEMS, optoelectronics,

    nanotechnology, and compound

    semiconductors

    We provide strong expertise in thin waferhandling and advanced packaging with material

    and equipment technologies for LED

    manufacturing

    Slide 19