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11/18/14
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chemistry
© Copyright Pearson Prentice Hall
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Electron Arrangement in Atoms
If this rock were to tumble over, it would end up at a lower height. It would have less energy than before, but its position would be more stable. You will learn that energy and stability play an important role in determining how electrons are configured in an atom.
5.2
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Electron Arrangement in Atoms
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Electron Configurations
Electron Configurations
What are the three rules for writing the electron configurations of elements?
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© Copyright Pearson Prentice Hall
Electron Arrangement in Atoms
> Electron Configurations
The ways in which electrons are arranged in various orbitals around the nuclei of atoms are called electron configurations.
Three rules—the aufbau principle, the Pauli exclusion principle, and Hund’s rule—tell you how to find the electron configurations of atoms.
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Slide 5 of 20
© Copyright Pearson Prentice Hall
Electron Arrangement in Atoms
> Electron Configurations
Aufbau Principle
According to the aufbau principle, electrons occupy the orbitals of lowest energy first. In the aufbau diagram below, each box represents an atomic orbital.
5.2
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© Copyright Pearson Prentice Hall
Electron Arrangement in Atoms
> Electron Configurations
Pauli Exclusion Principle
According to the Pauli exclusion principle, an atomic orbital may describe at most two electrons. To occupy the same orbital, two electrons must have opposite spins; that is, the electron spins must be paired.
5.2
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Slide 7 of 20
© Copyright Pearson Prentice Hall
Electron Arrangement in Atoms
> Electron Configurations
Hund’s Rule
Hund’s rule states that electrons occupy orbitals of the same energy in a way that makes the number of electrons with the same spin direction as large as possible.
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Electron Arrangement in Atoms
> Electron Configurations
Orbital Filling Diagram
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Electron Arrangement in Atoms
> Electron Configurations
Simulation 2
Fill atomic orbitals to build the ground state of several atoms.
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Practice Problems for Conceptual Problem 1.1
Problem Solving 5.9 Solve Problem 9 with the help of an interactive guided tutorial.
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Electron Arrangement in Atoms
>
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Exceptional Electron Configurations
Exceptional Electron Configurations
Why do actual electron configurations for some elements differ from those assigned using the aufbau principle?
5.2
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Electron Arrangement in Atoms
> Exceptional Electron Configurations
Some actual electron configurations differ from those assigned using the aufbau principle because half-filled sublevels are not as stable as filled sublevels, but they are more stable than other configurations.
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Electron Arrangement in Atoms
> Exceptional Electron Configurations
Exceptions to the aufbau principle are due to subtle electron-electron interactions in orbitals with very similar energies.
Copper has an electron configuration that is an exception to the aufbau principle.
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